JP6106999B2 - Absorption heat pump device - Google Patents

Description

  The present invention relates to an absorption heat pump apparatus.

  2. Description of the Related Art Conventionally, there is known an absorption heat pump device that uses an absorbing liquid that can absorb a large amount of refrigerant vapor when the refrigerant evaporates, and performs air conditioning and air conditioning using the heat of vaporization of the refrigerant and the heat of condensation of the refrigerant (for example, , See Patent Document 1).

  Patent Document 1 discloses a cold / hot air direct blow type absorption air conditioner (absorption heat pump device) including a regenerator, a condenser, an evaporator, and an absorber. In the cold / hot air direct blow type absorption air conditioner described in Patent Document 1, during cooling operation, the evaporator utilizes a low-pressure state generated when the absorbing liquid (concentrated liquid) absorbs the refrigerant (water) in the absorber. When the refrigerant (water) is evaporated in the room air, the indoor air is cooled by utilizing the heat of vaporization (heat of vaporization) of the refrigerant at that time. Further, during heating operation, refrigerant vapor (water vapor) generated (separated) by heating the absorption liquid (dilute liquid) with a burner in the regenerator is condensed (liquefied) in the evaporator after passing through the condenser. Thereby, indoor air is heated using the condensation heat of the refrigerant | coolant in that case. In Patent Document 1, the absorption liquid (concentrated liquid) after the refrigerant vapor (water vapor) is separated in the regenerator is returned to the absorber via a connection pipe connected to the bottom of the regenerator.

Japanese Patent Laid-Open No. 5-60414

  However, in the cold / hot air direct blow type absorption air conditioner (absorption heat pump device) described in Patent Document 1, the absorption liquid (concentrated liquid) after the refrigerant vapor (water vapor) is separated by heating with a burner in the regenerator. ) Is returned to the absorber via the connecting pipe, the connecting pipe from the regenerator to the absorber is unnecessarily heated, and heat loss occurs in the piping system. Due to this heat loss, it takes time to raise the temperature of the absorption liquid until it becomes a state where high-temperature refrigerant vapor (water vapor) can be continuously generated in the regenerator. There is an inconvenience that it takes time until the hot air is supplied. As a result, there is a problem that the responsiveness during cooling and heating operation is lowered.

  The present invention has been made to solve the above-described problems, and one object of the present invention is to provide an absorption heat pump apparatus capable of improving the responsiveness during cooling and heating operations. That is.

In order to achieve the above object, an absorption heat pump device according to a first aspect of the present invention includes a heating unit that heats an absorption liquid, and a gas-liquid separation unit that separates refrigerant vapor from the absorption liquid heated by the heating unit. A circulation passage part connecting the heating part and the gas-liquid separation part, an absorber for absorbing the refrigerant in the absorption liquid, and a gas-liquid so that the absorption liquid can circulate between the heating part and the gas-liquid separation part A first valve that blocks the absorption liquid from the separation unit from flowing into the absorber, a first pump that sucks the absorption liquid from the gas-liquid separation unit and circulates the circulation passage unit, and an evaporator including a refrigerant storage unit And a second pump for supplying the refrigerant in the refrigerant storage part of the evaporator to the circulation passage part during the heating operation .

In the absorption heat pump device according to the first aspect of the present invention, as described above, the circulation passage portion connecting the heating portion and the gas-liquid separation portion, and the absorption liquid of the gas-liquid separation portion flow into the absorber. By providing the first valve that shuts off and the first pump that sucks the absorbing liquid from the gas-liquid separating section and circulates the circulation passage section, the absorbing liquid is separated from the gas-liquid separating section by closing the first valve. Since the absorption liquid can be repeatedly circulated in the circulation path section as the minimum necessary circulation path without flowing out from the (circulation path section) to the absorber, heat loss is unlikely to occur, Temperature) can be performed efficiently. Thereby, since a high-temperature refrigerant | coolant vapor | steam can be generated in a shorter time, cold air or warm air can be generated in a shorter time. As a result, responsiveness during cooling and heating operations can be improved.
Moreover, the evaporator further including a refrigerant | coolant storage part and the 2nd pump which supplies the refrigerant | coolant of the refrigerant | coolant storage part of an evaporator to a circulation channel part at the time of heating operation are further provided. If comprised in this way, even when the 1st valve is closed at the time of heating operation and the path | route between an absorber and a gas-liquid separation part is interrupted | blocked, after the refrigerant | coolant vapor | steam in a circulation channel part is isolate | separated The refrigerant in the refrigerant storage part of the evaporator can be supplied (supplemented) to the absorbing liquid (concentrated liquid) with a low refrigerant content by using the second pump. Thereby, since the absorption liquid in which the refrigerant content is appropriately adjusted can be circulated through the circulation passage portion, the refrigerant vapor can be easily and continuously generated from the absorption liquid using the heating unit. In addition, even in a situation where the pressure in the circulation passage section that has become high is higher than the pressure of the evaporator at a relatively low temperature, the refrigerant in the refrigerant storage section of the evaporator is reliably supplied to the circulation passage section using the second pump. Can be supplied to.

In the absorption heat pump device according to the first aspect , preferably, in the second pump, the outlet side of the second pump is connected to the inlet side of the first pump, and the inlet side of the second pump is the refrigerant storage part of the evaporator. In the heating operation, the second pump supplies the refrigerant in the refrigerant reservoir between the gas-liquid separator and the inlet of the first pump. If comprised in this way, since the refrigerant | coolant of the evaporator pressure-fed by the 2nd pump is supplied to the inlet_port | entrance (intake | inhalation) side of the 1st pump for circulating absorption liquid, the pressure of the inlet vicinity of the 1st pump will be set. It can suppress that it falls. Thereby, it is possible to suppress the occurrence of a cavitation phenomenon in which bubbles are generated in the vicinity of the inlet of the first pump. Further, by connecting the outlet side of the second pump to the inlet (suction) side of the first pump, the required power of the second pump can be reduced by the amount of the suction force that the first pump has.

Oite the absorption heat pump apparatus according to the first aspect, preferably, it provided at the outlet side of the second pump, further comprising a second valve absorbing liquid is blocked from flowing into the evaporator, the second The valve is configured to be opened when the second pump is driven during the heating operation. If comprised in this way, at the time of heating operation, the refrigerant | coolant of the evaporator which the 2nd valve opened and was pumped by the 2nd pump can be reliably supplied to a circulation channel | path part. Further, when the second pump is stopped (cooling operation), the second valve is closed so that the high-temperature (high-pressure) absorbing liquid in the circulation passage section flows back into the evaporator through the second pump. It can be surely prevented.

Absorption heat pump equipment according to a second aspect of the invention, a heating unit for heating the absorbing solution, and gas-liquid separator for separating the refrigerant vapor from the absorbent solution that has been heated by the heating unit, and the absorption liquid heating unit The circulation passage section that connects the heating section and the gas-liquid separation section, the absorber that absorbs the refrigerant into the absorption liquid, and the absorption liquid of the gas-liquid separation section are absorbed so that the gas-liquid separation section can be circulated. A first valve that shuts off the flow into the cooler, and a first pump that sucks the absorption liquid from the gas-liquid separation part and circulates the circulation passage part. Based on the fact that the pressure of the refrigerant vapor in the gas-liquid separation unit has reached a predetermined reference value, a circulation path through which the absorption liquid in the gas-liquid separation unit flows into the absorber is formed by opening the first valve. It is configured as follows. As described above, after the cooling operation is started, when the temperature of the absorption liquid or the pressure of the refrigerant vapor in the gas-liquid separation unit reaches a predetermined reference value, the absorption liquid circulating through the circulation passage unit is appropriately heated. In that case, by opening the first valve and allowing the absorption liquid (concentrated liquid) of the gas-liquid separation part to flow into the absorber, After the cool air can be properly supplied, it is possible to shift to a normal cooling operation using the absorber.

  In the configuration in which the circulation path is formed by opening the first valve, it is preferable to further include a third valve for blocking the absorption liquid of the absorber from flowing into the circulation passage portion, and to circulate during the cooling operation. Based on the fact that the temperature of the absorbing liquid or the pressure of the refrigerant vapor in the gas-liquid separator has reached a predetermined reference value, the absorbing liquid in the gas-liquid separator is changed by opening the first valve and the third valve. The absorption liquid of the absorber flows into the circulation passage part and flows into the absorber so that a circulation path is formed through which the absorption liquid circulates between the gas-liquid separation part, the absorber and the heating part. Yes. According to this configuration, after the start of the cooling operation, the temperature of the absorption liquid circulating in the circulation passage section or the pressure of the refrigerant vapor in the gas-liquid separation section reaches a predetermined reference value, so that cold air is appropriately supplied. After reaching the possible state, by opening not only the first valve but also the third valve, the absorbing liquid diluted with the absorber (dilute liquid) is returned to the circulation passage section through the third valve. Therefore, it is possible to easily shift to a normal cooling operation using the absorber after the cool air can be supplied appropriately.

  In this case, preferably, during cooling operation, the heat of the absorption liquid flowing from the gas-liquid separation unit toward the absorber is applied to the absorption liquid flowing from the absorber toward the circulation passage unit, so that the gas-liquid separation unit A heat exchanger is further provided for lowering the temperature of the absorbent flowing toward the absorber and increasing the temperature of the absorbent flowing from the absorber toward the circulation passage. If comprised in this way, when opening a 1st valve and a 3rd valve and distribute | circulating (circulating) absorption liquid to a circulation path, the absorption liquid (concentrated liquid) heated (heated) by the circulation channel part Part of the heat can be transferred to the absorption liquid (dilute liquid) returned from the absorber to the circulation passage part via this heat exchanger, so that the absorption liquid (dilute liquid) is transferred from the absorber to the circulation passage part. It can suppress that the temperature of the absorption liquid which circulates through a circulation channel part in flowing in falls. Thereby, even after shifting to a normal cooling operation using the absorber, it is possible to maintain the temperature in which the circulating absorbing liquid is maintained and to be able to supply cold air appropriately. On the other hand, the absorption liquid (concentrated liquid) that passes through the heat exchanger from the gas-liquid separation part (circulation passage part) and goes to the absorber is cooled by the absorption liquid (dilute liquid) that goes to the circulation passage part from the absorber. Therefore, a lower temperature absorption liquid (concentrated liquid) is supplied to the absorber, and the pressure in the absorber is maintained at a lower pressure state. Thereby, since the pressure (evaporation temperature of the refrigerant) in the evaporator communicating with the absorber is also kept low, it is possible to stably supply cold air.

Absorption heat pump equipment according to a third aspect of the invention, a heating unit for heating the absorbing solution, and gas-liquid separator for separating the refrigerant vapor from the absorbent solution that has been heated by the heating unit, and the absorption liquid heating unit The circulation passage section that connects the heating section and the gas-liquid separation section, the absorber that absorbs the refrigerant into the absorption liquid, and the absorption liquid of the gas-liquid separation section are absorbed so that the gas-liquid separation section can be circulated. A first valve that shuts off the flow into the vessel, a first pump that sucks the absorption liquid from the gas-liquid separation unit and circulates the circulation passage unit , an evaporator including a refrigerant storage unit, an evaporator and an absorber a fourth valve, e Bei and a fifth valve disposed between the evaporator and the gas-liquid separator, in the cooling operation, by opening the fourth valve provided between, Refrigerant vapor generated by evaporating the refrigerant in the refrigerant storage part of the evaporator is returned to the absorber, and during heating operation , By opening the fifth valve it is constituted refrigerant vapor separated by the gas-liquid separator so as to flow directly into the evaporator. If comprised in this way, at the time of air_conditionaing | cooling operation, the low-temperature refrigerant | coolant vapor | steam evaporated with the evaporator can be easily flowed in (returned) to an absorber via a 4th valve. Further, during the heating operation, the high-temperature refrigerant vapor separated by the gas-liquid separation unit can be directly supplied to the evaporator via the fifth valve, so that the high-temperature refrigerant vapor is condensed in the evaporator. Can generate hot air efficiently.

Absorption heat pump equipment according to a fourth aspect of the present invention comprises a heating unit for heating the absorbing solution, and gas-liquid separator for separating the refrigerant vapor from the absorbent solution that has been heated by the heating unit, and the absorption liquid heating unit The circulation passage section that connects the heating section and the gas-liquid separation section, the absorber that absorbs the refrigerant into the absorption liquid, and the absorption liquid of the gas-liquid separation section are absorbed so that the gas-liquid separation section can be circulated. A first valve that shuts off the flow into the cooler, a first pump that sucks the absorption liquid from the gas-liquid separation unit and circulates the circulation passage unit, and the refrigerant vapor separated by the gas-liquid separation unit during cooling operation a condenser for condensing, during a heating operation, obtain Preparations and sixth valve refrigerant vapor separated by the gas-liquid separator is shut off from entering the condenser, the. If comprised in this way, while a 6th valve is opened at the time of air_conditionaing | cooling operation, while letting a high-temperature refrigerant | coolant vapor | steam flow in into a condenser and condense, it closes a 6th valve at the time of heating operation, and a high-temperature refrigerant | coolant is supplied to a condenser. Steam can be prevented from flowing in. Accordingly, during the heating operation, it is possible to prevent the high-temperature refrigerant vapor heated (heated) by the heating unit and separated by the gas-liquid separation unit from unnecessarily heating the condenser. Since all the refrigerant vapor can be supplied directly to the evaporator, the hot air can be efficiently generated by condensing the high-temperature refrigerant vapor in the evaporator.

In the absorption heat pump device according to any one of the first to fourth aspects, preferably, a condenser that condenses the refrigerant vapor separated by the gas-liquid separator during cooling operation, and a condenser and an absorber. And a seventh valve that is opened when the refrigerant in the condenser is supplied to the absorber to dilute the absorbent to prevent crystallization of the absorbent. With this configuration, when the apparatus is stopped after the cooling operation, the concentration of the absorbing liquid is kept within a predetermined range by opening the seventh valve and returning a part of the refrigerant accumulated in the condenser to the absorber. Can be maintained. Thereby, even when the absorption heat pump device is stopped, crystallization of the absorption liquid can be prevented and the state of the absorption liquid can be appropriately maintained.

In the absorption heat pump device according to any one of the first to fourth aspects, preferably, the heating unit is configured to heat the absorbing liquid by utilizing heat exchange with engine exhaust gas. . If comprised in this way, the heat energy (renewable energy) contained in the exhaust gas discharged | emitted from an engine can be exhausted-heat-recovered as a heat source of an absorption heat pump apparatus, and can be utilized effectively. In addition, since the absorption heat pump device can be configured using the exhaust heat of the engine, the absorption heat pump device of the present invention can be widely applied as an air conditioner for vehicles equipped with the engine.

In addition, in this application, the following structures can be considered separately from the absorption heat pump apparatus according to the first to fourth aspects.

(Additional item 1)
That is, an absorption heat pump device according to another configuration of the present application includes a heating unit that heats the absorption liquid, a gas-liquid separation unit that separates refrigerant vapor from the absorption liquid heated by the heating unit, and the absorption liquid is a heating unit. In order to be able to circulate between the gas-liquid separation unit, the absorption liquid is sucked from the circulation passage unit connecting the heating unit and the gas-liquid separation unit, the evaporator including the refrigerant storage unit, and the gas-liquid separation unit. A first pump that circulates the circulation passage portion, and a refrigerant supply passage portion that supplies the refrigerant in the refrigerant storage portion of the evaporator directly from the evaporator to the circulation passage portion during heating operation. If comprised in this way, at the time of heating operation, when the absorption liquid is circulated through the circulation passage part and is efficiently heated (heated up) by the heating part, the refrigerant content after the refrigerant vapor is separated in the gas-liquid separation part It is possible to supply (replenish) the refrigerant in the refrigerant storage section of the evaporator directly and rapidly via the refrigerant supply passage section to the absorption liquid (concentrated liquid) with a small amount. Accordingly, the absorption liquid whose refrigerant content is appropriately adjusted is circulated through the circulation passage section, and the refrigerant vapor can be easily and continuously generated from the absorption liquid using the heating section. Can be obtained in a shorter time. As a result, since cool air or warm air can be generated in a shorter time, responsiveness during cooling and heating operations can be improved.

(Appendix 2)
The absorption heat pump device according to another configuration of the present application preferably further includes a second pump that is provided in the refrigerant supply passage portion and supplies the refrigerant in the refrigerant storage portion of the evaporator to the circulation passage portion during heating operation. . If comprised in this way, the refrigerant | coolant of the refrigerant | coolant storage part of an evaporator is circulated using a 2nd pump also in the situation where the pressure in the circulation channel | path part used as high temperature is higher than the pressure of the evaporator which is relatively low temperature. It can supply reliably to a channel | path part.

  According to the present invention, as described above, responsiveness during cooling and heating operations can be improved.

It is the figure which showed the whole structure of the absorption heat pump apparatus by one Embodiment of this invention. It is a figure for demonstrating the state at the time of the start of the cooling operation in the absorption heat pump apparatus by one Embodiment of this invention. It is a figure for demonstrating the state at the time of normal operation after absorption liquid temperature rising of the cooling operation in the absorption heat pump apparatus by one Embodiment of this invention. It is a figure for demonstrating the state at the time of the start of the heating operation in the absorption heat pump apparatus by one Embodiment of this invention. It is a figure for demonstrating the state at the time of the normal operation after the absorption liquid temperature rising of the heating operation in the absorption heat pump apparatus by one Embodiment of this invention. It is a figure for demonstrating the crystallization prevention operation performed after the cooling operation stop in the absorption heat pump apparatus by one Embodiment of this invention. It is a figure for demonstrating the crystallization prevention operation performed after the heating operation stop in the absorption heat pump apparatus by one Embodiment of this invention. It is the figure which showed the whole structure of the absorption heat pump apparatus by the 1st modification of one Embodiment of this invention. It is the figure which showed the whole structure of the absorption heat pump apparatus by the 2nd modification of one Embodiment of this invention. It is the figure which showed the whole structure of the absorption heat pump apparatus by the 3rd modification of one Embodiment of this invention.

  Hereinafter, embodiments of the present invention will be described with reference to the drawings.

  First, with reference to FIG. 1, the structure of the absorption heat pump apparatus 100 by one Embodiment of this invention is demonstrated. In the absorption heat pump apparatus 100 according to the present embodiment, water is used as the refrigerant and a lithium bromide (LiBr) aqueous solution is used as the absorbing liquid. The absorption heat pump device 100 is mounted on a vehicle such as a passenger car, a bus, and a truck provided with an engine (internal combustion engine) 90, and is configured to be applied to an in-vehicle air conditioning system.

  As shown in FIG. 1, the absorption heat pump apparatus 100 according to the present embodiment includes a heating unit 11, a gas-liquid separation unit 12, a condenser 20, an evaporator 30, and an absorber 40. The heating unit 11 and the gas-liquid separation unit 12 constitute the regenerator 10 (portion in the two-dot chain line frame in FIG. 1) in the absorption heat pump apparatus 100.

  The heating unit 11 is a plate heat exchanger, and has a role of heating the absorbing liquid using the heat of the exhaust gas of the engine 90. Here, the absorbing liquid normally flows through the heating unit 11 in a state where the LiBr concentrated liquid is diluted with the refrigerant (water). The gas-liquid separation unit 12 has a function of separating refrigerant vapor (high-temperature water vapor) from the absorption liquid heated by the heating unit 11. Further, the condenser 20 has a role of condensing (liquefying) the refrigerant vapor separated by the gas-liquid separation unit 12 during the cooling operation. Moreover, the evaporator 30 has a role which evaporates (vaporizes) the refrigerant | coolant which became condensed water at the time of air_conditionaing | cooling operation on the conditions of low temperature low pressure. Further, during the heating operation, the evaporator 30 is used as a condenser. Further, the absorber 40 has a role of absorbing the refrigerant vapor (low-temperature water vapor) vaporized by the evaporator 30 into the concentrated absorption liquid.

  Further, the absorption heat pump device 100 includes absorption liquid circulation lines 51a and 51b, refrigerant vapor transfer lines 52a, 52b and 53, refrigerant transfer lines 54, absorption liquid transfer lines 55 and 56, and refrigerant supply. Lines 57 and 58 are provided.

  Here, in the present embodiment, as shown in FIG. 1, the absorption liquid circulation pipes 51 a and 51 b make an arrow between the heating unit 11 and the gas-liquid separation unit 12 without the absorption liquid flowing through the absorber 40. A circulation passage part 51 that connects the heating part 11 and the gas-liquid separation part 12 is configured so as to be circulated along the P direction. That is, the path through which the absorption liquid flowing out from the gas-liquid separation part 12 flows into the heating part 11 is constituted by the absorption liquid circulation pipe 51a, and the absorption liquid containing the bubble-like water vapor heated by the heating part 11 is gas. The path to flow into the liquid separation unit 12 is constituted by the absorption liquid circulation pipe 51b. Further, the absorption liquid circulation pipe 51 a is provided with a pump 71 that sucks the concentrated absorption liquid stored in the gas-liquid separation unit 12 and repeatedly circulates it in the circulation passage unit 51. In addition, a valve 61 that blocks the absorption liquid stored in the gas-liquid separation unit 12 from flowing into the absorber 40 into the absorption liquid transfer line 55 branched from the absorption liquid circulation line 51a to the absorber 40. Is provided. The pump 71 is an example of the “first pump” in the present invention.

  Further, in the portion of the absorbent liquid transfer pipe 56 before the merge with the absorbent liquid circulation pipe 51a, the diluted liquid stored in the absorber 40 is circulated through the circulation passage 51 (absorbing liquid circulation pipe 51a). A valve 62 is provided to block the flow into the valve. The valve 61 and the valve 62 are electromagnetic valves (two-way valves) that are opened or closed by a solenoid coil (not shown) in either a fully open state or a fully closed state. Further, the absorbing liquid transfer pipe 56 is connected to the outlet side of the pump 71 (the part between the pump 71 and the heating unit 11) in the absorbing liquid circulation pipe 51a. The valve 61 and the valve 62 are examples of the “first valve” and the “third valve” in the present invention, respectively.

  The absorption liquid transfer pipe 56 having the valve 62 has a pump 72 that sucks the absorption liquid (dilute liquid) stored in the absorber 40 and supplies it to the circulation passage 51 (absorption liquid circulation pipe 51a). Is provided. Specifically, the pump 72 has an outlet (discharge) side of the pump 72 connected to the inlet side of the valve 62, and an inlet (suction) side of the pump 72 connected to the absorbent storage part 40 a side of the absorber 40. Yes. In addition, a temperature sensor 5 is attached to a portion immediately before the absorbing liquid circulation pipe 51b is connected to the gas-liquid separator 12. The temperature sensor 5 is a thermistor sensor and has a function of detecting the temperature of the absorbing liquid (concentrated liquid) flowing through the absorbing liquid circulation pipe 51b.

  In the present embodiment, the refrigerant supply pipe 57 is provided to supply the refrigerant (condensed water) stored in the evaporator 30 directly to the circulation passage 51. Specifically, the refrigerant supply line 57 connects between the refrigerant storage part 30a located at the bottom of the evaporator 30 and a part on the inlet (intake) side of the pump 71 in the absorbing liquid circulation line 51a. doing. The refrigerant supply pipe 57 is provided with a pump 73 that sucks the refrigerant (condensed water) stored in the evaporator 30 and supplies it to the circulation passage 51 (absorbing liquid circulation pipe 51a). In the pump 73, the outlet (discharge) side of the pump 73 is connected to the inlet (suction) side of the pump 71, and the inlet (suction) side of the pump 73 is connected to the refrigerant reservoir 30 a side of the evaporator 30. The refrigerant supply pipe 57 is an example of the “refrigerant supply passage portion” in the present invention, and the pump 73 is an example of the “second pump” in the present invention.

  Further, in the present embodiment, in addition to the pump 73, the refrigerant supply pipe 57 is provided with a valve 63 (electromagnetic valve) between the outlet side of the pump 73 and the junction with the absorbing liquid circulation pipe 51a. . The valve 63 is closed when the driving of the pump 73 is stopped during the cooling operation, so that the absorption liquid (LiBr aqueous solution) circulating in the circulation passage portion 51 flows back through the refrigerant supply line 57 to the evaporator 30. It has a role of blocking inflow (mixing). The valve 63 is an example of the “second valve” in the present invention.

  In addition, the refrigerant vapor transfer pipe line 52 b is provided to allow the refrigerant vapor (high-temperature water vapor) separated by the gas-liquid separator 12 to directly flow into the evaporator 30. Specifically, the refrigerant vapor transfer pipe 52b branches from the refrigerant vapor transfer pipe 52a that connects the gas-liquid separator 12 and the condenser 20, and then connects the evaporator 30 and the absorber 40. It is connected to the path 53. Note that, at the joining portion of the refrigerant vapor transfer pipe line 52 b with respect to the refrigerant vapor transfer pipe line 53, the first flow path connecting the evaporator 30 and the absorber 40, and the first flow path connecting the gas-liquid separator 12 and the evaporator 30. One three-way valve 64 (solenoid valve) capable of selectively switching between the two flow paths is provided. Thus, when the three-way valve 64 is switched to the first flow path side (for cooling operation), the refrigerant vapor generated by evaporation (vaporization) of the refrigerant (condensed water) in the evaporator 30 (refrigerant storage unit 30a). The path (first flow path) of the refrigerant vapor transfer pipe 53 that supplies (low temperature water vapor) to the absorber 40 is opened. Further, when the three-way valve 64 is switched to the second flow path side (for heating operation), the refrigerant vapor (high-temperature steam) separated by the gas-liquid separator 12 is converted into the evaporator 30 (in this case, becomes a condenser). The path (second flow path) of the refrigerant vapor transfer pipe 52b that directly flows into the pipe is opened. The three-way valve 64 is an example of the “fourth valve” and the “fifth valve” in the present invention.

  In the present embodiment, a valve 65 (solenoid valve) is provided in the refrigerant vapor transfer pipe 52 a that connects the gas-liquid separator 12 and the condenser 20. That is, the valve 65 is provided on the refrigerant vapor transfer pipe 52a on the condenser 20 side after the refrigerant vapor transfer pipe 52b branches from the refrigerant vapor transfer pipe 52a. The refrigerant vapor (high-temperature steam) separated by 12 has a role of blocking the flow into the condenser 20. The valve 65 is an example of the “sixth valve” in the present invention.

  Further, a valve 66 (electromagnetic valve) is provided in the refrigerant transfer line 54 connecting the condenser 20 and the evaporator 30. The valve 66 is opened during the cooling operation, and is closed during the heating operation. That is, the valve 66 has a role of blocking the refrigerant (condensed water) of the evaporator 30 (refrigerant reservoir 30a) functioning as a condenser during heating operation from flowing into the condenser 20 (backflow) for some reason. doing. Thereby, the three-way valve 64 is switched to the second flow path (flow path through which the refrigerant vapor flows through the refrigerant vapor transfer pipe 52b) connecting the gas-liquid separator 12 and the evaporator 30 during the heating operation, and the valve When both 65 and the valve 66 are closed, the path from the outlet of the valve 65 to the inlet of the valve 66 (path including the condenser 20) is disconnected. Therefore, at the time of heating operation, almost all of the high-temperature refrigerant vapor separated by the gas-liquid separator 12 is configured to flow through the refrigerant vapor transfer pipe 52b and directly flow into the evaporator 30.

  The refrigerant supply pipe 58 is provided to supply the refrigerant (condensed water) stored in the condenser 20 directly to the absorber 40. Specifically, the refrigerant supply pipe 58 connects the refrigerant reservoir 20a located at the bottom of the condenser 20 and a portion in the vicinity of the absorber 40 (absorption liquid reservoir 40a) of the absorption liquid transfer pipe 55. ing. Further, the refrigerant supply pipe 58 is provided with a valve 67 (electromagnetic valve). By opening the valve 67 when the apparatus is stopped after the cooling operation, a part of the refrigerant (condensed water) of the condenser 20 is supplied to the absorber 40 and contains all of the absorbing liquid stored in the absorber 40. The absorbent is diluted. Thereby, even when the absorption heat pump apparatus 100 is stopped, the absorption liquid staying in each part of the apparatus including the circulation passage section 51 and the absorption liquid transfer pipes 55 and 56 is prevented from crystallizing. Yes. The valve 67 is an example of the “seventh valve” in the present invention.

  As shown in FIG. 1, the absorption heat pump device 100 includes a cooling water circuit unit 80. The cooling water circuit unit 80 is configured to be driven only during the cooling operation, and cools (liquefies) the refrigerant vapor (high-temperature steam) in the condenser 20 during the cooling operation and the refrigerant (low-temperature steam) in the absorber 40. ) In the absorption liquid (LiBr concentrated liquid) is absorbed (heat removal).

  Specifically, the cooling water circuit unit 80 includes a cooling water circulation circuit unit 81 through which cooling water (coolant (antifreeze)) flows, and a water supply pump 82 for circulating the cooling water in the cooling water circulation circuit unit 81 in the arrow direction. And a heat exchanger 83 for cooling (liquefying) the refrigerant vapor by heat exchange between the cooling water and the refrigerant vapor, and an absorber 40 for arranging the cooling water and the absorbed heat. A heat exchanger 84 for cooling (removing heat) the absorbing liquid by heat exchange with the generated absorbing liquid and a cooler 85 for cooling the cooling water warmed by the heat exchange are included. In the cooler 85, the cooling water flowing through the heat exchanger 85a is cooled by the air (outside air) blown by the blower 85b. In this case, the temperature of the cooling water just before returning to the heat exchanger 85a is around 40 ° C., and the temperature of the cooling water just after leaving the heat exchanger 85a is around 35 ° C.

  Further, the evaporator 30 includes a heat exchange part 30b installed inside the container and an injector 30c attached near the ceiling part inside the container. In addition, a pump 32 is provided outside the evaporator 30 in a refrigerant transfer pipe 31 that connects the refrigerant reservoir 30a and the injector 30c. Thereby, the refrigerant | coolant (water) of the refrigerant | coolant storage part 30a is pumped up by the pump 32, and it is comprised so that it may be injected in the shape of a mist toward the heat exchange part 30b below from the injector 30c. Therefore, during the cooling operation, the air (suction air) before heat exchange in the vehicle blown by the blower 33 evaporates the refrigerant (water) sprayed from above when passing through the heat exchanging unit 30b, and the refrigerant vapor ( It is cooled using the heat of vaporization when it becomes low-temperature steam. The cooled air (cold air) is blown out into the vehicle.

  Moreover, the absorber 40 contains the injector 40b attached near the ceiling part inside a container. In addition, a pump 42 is provided outside the absorber 40 in an absorbing liquid transfer pipe 41 that connects the absorbing liquid reservoir 40a and the injector 40b. Thereby, the absorption liquid of the absorption liquid storage part 40a is pumped up by the pump 42, and it is comprised so that it may be sprayed in the shape of a mist toward the heat exchanger 84 below from the injector 40b. Therefore, during the cooling operation, the refrigerant vapor (low temperature water vapor) generated in the evaporator 30 and sucked from the refrigerant vapor transfer pipe 53 and the sprayed absorption liquid (concentrated liquid) are mixed in the absorber 40 and diluted. A liquid absorbent is made and stored in the absorbent reservoir 40a.

  Further, in the present embodiment, the absorption heat pump device 100 includes an absorption liquid (concentrated liquid) flowing through a portion between the valve 61 of the absorption liquid transfer pipe 55 and the absorber 40, and an absorption liquid transfer pipe 56. A heat exchanger 45 is provided for heat exchange with an absorbing liquid (dilute liquid) flowing through a portion between the pump 72 and the valve 62. The heat exchanger 45 is a plate heat exchanger, and is an absorption that supplies an absorbing liquid (concentrated liquid) to the absorber 40 and supplies an absorbing liquid (diluted liquid) from the absorber 40 to the circulation passage portion 51. The liquid transfer pipes 55 and 56 are provided. The heat exchanger 45 is a so-called “liquid-liquid heat exchanger”, and circulates the heat of the absorbent (LiBr concentrated liquid) flowing from the gas-liquid separator 12 toward the absorber 40 during the cooling operation from the absorber 40. By applying to the absorption liquid (dilute liquid) flowing toward the passage part 51, the temperature of the absorption liquid (concentrated liquid) flowing from the gas-liquid separation part 12 toward the absorber 40 is lowered and circulated from the absorber 40. It has the role of increasing the temperature of the absorption liquid (dilute liquid) that flows toward the passage portion 51.

  The heating unit 11 is a heat exchanger for heating the absorption liquid (dilute liquid) in which the refrigerant (water) is absorbed by the LiBr concentrated liquid. The heating unit 11 draws from the engine 90 of the passenger car (not shown). The high-temperature (about 300 ° C. to about 400 ° C.) exhaust gas flowing through the rotated exhaust gas pipe 91 and the absorption liquid flowing through (circulating) the circulation passage portion 51 are configured to exchange heat. The exhaust gas pipe 91 includes a gas pipe part 91 a that passes through the heating part 11 and a bypass part 91 b that does not pass through the heating part 11. Further, a valve 92 (electromagnetic valve) is provided in the gas pipe portion 91 a between the engine 90 and the heating unit 11. When the valve 92 is opened during the cooling operation and the heating operation, a part of the exhaust gas discharged from the engine 90 is circulated to the heating unit 11 via the gas pipe portion 91a. Further, when the valve 92 is closed, the exhaust gas is discharged via the bypass portion 91b. In this way, the absorption heat pump apparatus 100 is configured.

[Operation during cooling operation]
Next, with reference to FIG. 2 and FIG. 3, the detail of the operation | movement at the time of performing a cooling operation using the absorption heat pump apparatus 100 by one Embodiment of this invention is demonstrated.

(At the time of cooling operation start)
First, as shown in FIG. 2, when the cooling operation is requested in the air conditioning system, the valve 92 is opened at the start of operation, and a part of the exhaust gas of the engine 90 is circulated to the heating unit 11. Then, the pump 71 provided in the absorbing liquid circulation line 51a is started with the valve 61 on the absorbing liquid transfer line 55 and the valve 62 on the absorbing liquid transfer line 56 being closed. As a result, the absorption liquid stored in the gas-liquid separation unit 12 circulates in the circulation passage unit 51, and the absorption liquid is heated (heated) by obtaining heat of the exhaust gas in the heating unit 11. Further, a high-temperature refrigerant vapor is generated from the absorbing liquid as the temperature of the absorbing liquid rises, and is sent to the gas-liquid separation unit 12 together with the absorbing liquid. In the gas-liquid separation unit 12, the absorbing liquid (concentrated liquid) having an increased LiBr concentration and the refrigerant vapor (water vapor) are separated, and the refrigerant vapor is controlled to the valve 65 (refrigerant vapor transfer) which is controlled to be open at the start of operation. It passes through line 52a) and is supplied to condenser 20.

  Here, in the present embodiment, the absorption liquid is repeatedly circulated in the direction of the arrow P in the circulation passage 51 at the start of the cooling operation, so that the heating (heating) of the absorption liquid by the heating unit 11 is efficiently performed. . As a result, a high-temperature refrigerant vapor having a temperature of about 100 ° C. is generated in a shorter time and fills the gas-liquid separation unit 12, and the high-temperature refrigerant vapor starts to be supplied to the condenser 20 immediately.

(Normal operation after temperature rise of absorbent)
As shown in FIG. 3, based on the temperature detection result by the temperature sensor 5, when the temperature of the absorbing liquid circulating in the circulation passage portion 51 reaches a predetermined reference value (about 100 ° C.), the valve 61 And opens the valve 62. In addition, the pump 72 on the absorption liquid transfer line 56 is started together with the opening control of the valve 61 and the valve 62. Thereby, in FIG. 2, a part of the absorption liquid (LiBr concentrated liquid stored in the gas-liquid separation part 12) circulating only in the circulation passage part 51 is absorbed into the absorption liquid transfer pipe as shown in FIG. 55 and 56 are also distributed in the direction of arrow Q. That is, a circulation path 151 is formed through which the absorbing liquid circulates between the gas-liquid separator 12, the absorber 40, and the heating unit 11 in the arrow Q direction.

  Further, when the temperature of the absorbing liquid circulating in the circulation passage portion 51 reaches a predetermined reference value (about 100 ° C.), the blower 33 and the pump 32 of the evaporator 30 are started and the pump of the absorber 40 is started. 42 is started. Moreover, the water supply pump 82 is started and the cooling water is circulated through the cooling water circuit unit 80 (cooling water circulation circuit unit 81). Thereby, the high-temperature refrigerant vapor supplied to the condenser 20 is cooled by the cooling water flowing through the heat exchanger 83. Then, the refrigerant (condensed water) condensed (liquefied) by the condenser 20 is supplied to the evaporator 30 through the valve 66 (refrigerant transfer line 54) controlled to be in an open state when the operation is started.

  In the evaporator 30, the refrigerant (water) that has begun to be stored in the refrigerant storage unit 30a is pumped up by the pump 32 and injected from the injector 30c. The sprayed refrigerant evaporates (vaporizes) under low temperature and low pressure conditions to become refrigerant vapor (low temperature water vapor). At this time, the air in the vehicle passing through the heat exchanging portion 30b is cooled by the heat of evaporation (heat of vaporization) of the refrigerant and blown out as cold air. On the other hand, the low-temperature refrigerant vapor passes through the three-way valve 64 in which the first channel (the channel through which the refrigerant vapor (low-temperature water vapor) flows through the refrigerant vapor transfer pipe 53) is switched to the open state, and the evaporator 30 The pressure is sucked into the absorber 40 having a lower pressure.

  Further, in the heat exchanger 45, the heat of the absorbing liquid (LiBr concentrated liquid) flowing through the absorbing liquid transfer pipe 55 from the gas-liquid separator 12 toward the absorber 40 flows from the absorber 40 toward the circulation passage 51. To the absorbing liquid (dilute liquid) flowing through the absorbing liquid transfer pipe 56. As a result, the absorption liquid (concentrated liquid) from the gas-liquid separator 12 flows into the absorber 40 with the temperature lowered, and the absorption liquid (dilute liquid) from the absorber 40 circulates with the temperature raised. It flows into the passage 51 (absorbing liquid circulation pipe 51a). Therefore, the absorber 40 is supplied with a lower-temperature absorption liquid (concentrated liquid), and the pressure in the absorber 40 is maintained at a lower pressure state. On the contrary, the absorbing liquid (dilute liquid) flowing from the absorber 40 into the circulation passage portion 51 flows into the circulation passage portion 51 in a state where it is closer to the temperature of the absorption liquid circulating through the circulation passage portion 51.

  Moreover, in the absorber 40, the absorption liquid (concentrated liquid) supplied from the gas-liquid separation part 12 via the absorption liquid transfer pipeline 55 is pumped up by the pump 42, and is injected from the injector 40b. Then, the refrigerant vapor (low temperature water vapor) sucked from the evaporator 30 and the sprayed absorption liquid are mixed in the absorber 40 to become a dilute absorption liquid and dropped into the absorption liquid storage section 40a. The absorption heat when the refrigerant vapor is absorbed by the absorption liquid is removed by the cooling water flowing through the heat exchanger 84.

  Further, the absorbing liquid (dilute liquid) returned to the circulation passage section 51 by the pump 72 through the absorbing liquid transfer pipe 56 is sucked from the gas-liquid separation section 12 by the pump 71 and flows through the absorbing liquid circulation pipe 51a. It is also mixed with the absorption liquid (concentrated liquid), heated again (heated up) by the heating unit 11 and sent to the gas-liquid separation unit 12. At this time, the refrigerant in the absorbent is regenerated as high-temperature water vapor. In the present embodiment, the transfer amounts (pressure feed amounts) of the pump 71 and the pump 72 are controlled. Thereby, the storage amount of the absorption liquid (LiBr concentrated liquid) stored in the gas-liquid separator 12 and the storage amount of the absorption liquid (LiBr dilute liquid) stored in the absorber 40 (absorption liquid storage section 40a) are obtained. , Adjusted to be within a predetermined range.

  During the cooling operation, the valve 63 and the valve 67 are always closed. Further, the pump 73 is also kept stopped. In the cooling operation, such driving operation is repeated and the air conditioning in the vehicle is continued.

[Operation during heating operation]
Next, with reference to FIG. 4 and FIG. 5, operation | movement when heating operation is requested | required in an air conditioning system is demonstrated.

(At the start of heating operation)
In this case, first, as shown in FIG. 4, when the heating operation is started, the valve 92 is opened and a part of the exhaust gas of the engine 90 is circulated to the heating unit 11. Then, the pump 71 is started in a state where both the valve 61 on the absorbent liquid transfer line 55 and the valve 62 on the absorbent liquid transfer line 56 are closed. As a result, the absorption liquid repeatedly circulates in the circulation passage 51 in the direction of the arrow P at the start of the heating operation, similarly to the start of the cooling operation, so that the heating (heating) of the absorption liquid by the heating unit 11 is efficiently performed. Done. Thereby, a high-temperature refrigerant | coolant vapor | steam generate | occur | produces in a short time and begins to fill the gas-liquid separation part 12. FIG.

  Here, in the present embodiment, during the heating operation, the valve 65 and the valve 66 provided before and after the condenser 20 are both closed to disconnect the path of the condenser 20. Further, the three-way valve 64 is switched from the first flow path side (during cooling operation) to the second flow path (flow path through which the refrigerant vapor (high temperature steam) flows through the refrigerant vapor transfer pipe line 52b). Accordingly, almost all of the high-temperature refrigerant vapor separated by the gas-liquid separator 12 starts to flow directly into the evaporator 30.

(Normal operation after temperature rise of absorbent)
Thereafter, as shown in FIG. 5, when the temperature of the absorbing liquid circulating in the circulation passage 51 reaches a predetermined reference value (about 100 ° C.) based on the temperature detection result by the temperature sensor 5, the evaporator The 30 blowers 33 and the pump 32 are started. During the heating operation, the pump 42 of the absorber 40 and the water supply pump 82 of the cooling water circuit unit 80 are not driven. Further, the valve 61 and the valve 62 are controlled so as to always remain closed during the heating operation. Therefore, during the heating operation, the absorbing liquid is not circulated through the absorbing liquid transfer pipes 55 and 56, and the absorber 40 is not used.

  In the evaporator 30 (in this case, a condenser), heat exchange is performed between the high-temperature refrigerant vapor directly flowing from the gas-liquid separator 12 and the air before heat exchange in the vehicle. That is, the refrigerant vapor is condensed (liquefied) in the heat exchange unit 30b and stored in the refrigerant storage unit 30a in the state of refrigerant (condensed water). On the contrary, the air in the vehicle passing through the heat exchanging part 30b is heated by the heat of condensation of the refrigerant and blown out as hot air.

  Here, in this embodiment, as shown in FIG. 5, the pump 73 provided in the refrigerant supply line 57 is started and the valve 63 on the refrigerant supply line 57 is opened. As a result, the refrigerant (condensed water) in the refrigerant reservoir 30a is directly supplied to the circulation passage 51 (absorbed liquid circulation pipe 51a) via the refrigerant supply pipe 57. Therefore, since the absorption liquid (LiBr aqueous solution) whose refrigerant content is appropriately adjusted is always circulated through the circulation passage 51, the refrigerant vapor heated from the heating section 11 causes insufficient generation of refrigerant vapor. A sufficient amount of refrigerant vapor is continuously regenerated without any problems. In the heating operation, the transfer amounts (pressure feed amounts) of the pump 71 and the pump 73 are controlled. As a result, the concentration of the absorption liquid circulating in the circulation passage 51 (the dilution ratio of the refrigerant (water) with respect to the LiBr aqueous solution) is adjusted so as to be within a predetermined range. Further, the valve 67 is always closed even during the heating operation. In the heating operation, such driving operation is repeated and the air conditioning in the vehicle is continued.

[Operation to prevent crystallization]
Next, with reference to FIG. 6 and FIG. 7, the crystallization prevention operation at the time of operation stop of the absorption heat pump apparatus 100 will be described.

(When stopped after cooling operation)
In the absorption heat pump apparatus 100, when the crystallization prevention operation for preventing the absorption liquid from crystallizing is performed after the cooling operation is stopped (when the apparatus is stopped), the cooling operation is stopped as shown in FIG. At a later predetermined timing, the valve 67 on the refrigerant supply line 58 is opened. As a result, a part of the refrigerant (condensed water) stored in the condenser 20 (refrigerant storage part 20a) flows through the refrigerant supply pipe 58 in the direction of the arrow R and is maintained at a low pressure in the absorber 40. Sucked. Further, in synchronism with the opening operation of the valve 67, the valves 61 and 62 are opened, and the pumps 71, 72 and 42 are started. As a result, the diluted absorbent in the absorber 40 circulates in the apparatus and all the absorbent is diluted. Then, after a predetermined time has elapsed, the crystallization preventing operation is completed by the closing operation of the valves 61, 62 and 67 and the stopping operation of the pumps 71, 72 and 42 described above.

(When stopped after heating operation)
Further, when the crystallization prevention operation is performed after the operation is stopped from the state where the heating operation is performed (when the apparatus is stopped), as shown in FIG. 7, at a predetermined timing after the heating operation is stopped. The valve 61 and the valve 63 are opened, and the pump 73 is driven. As a result, a part of the refrigerant (condensed water) of the evaporator 30 (refrigerant reservoir 30a) used as a condenser passes along the arrow S direction in the refrigerant supply line 57, the absorption liquid circulation line 51a, and the absorption liquid. It is pumped to the absorber 40 via the transfer line 55. In synchronism with this, the valve 62 is opened and the pumps 72 and 42 are started. As a result, the absorbing liquid circulates in the apparatus and all the absorbing liquid is diluted. At this time, due to the structure of the circulation passage 51, a part of the refrigerant (condensed water) also flows through the absorption liquid circulation pipe 51b. Then, after the lapse of a predetermined time, the crystallization preventing operation is completed by the above-described closing operation of the valves 61 to 63 and the stopping operation of the pumps 72, 73 and 42.

  By performing the above-described crystallization preventing operation, the concentration of the absorbing liquid is maintained within a predetermined range when the absorption heat pump apparatus 100 is stopped.

  In the present embodiment, as described above, the circulation passage 51 (the closed circuit including the absorption liquid circulation pipe 51a and the absorption liquid circulation pipe 51b in FIG. 1) that connects the heating section 11 and the gas-liquid separation section 12 is used. ), The valve 61 for blocking the absorption liquid (concentrated liquid) of the gas-liquid separation part 12 from flowing into the absorber 40, and the absorption liquid (concentrated liquid) from the gas-liquid separation part 12 to suck the absorption liquid (concentrated liquid). And a pump 71 that circulates in the direction of the arrow P, and by closing the valve 61, the circulation path 51 as a minimum necessary circulation path without causing the absorption liquid to flow out from the circulation path 51 to the absorber 40. Since the absorption liquid can be circulated repeatedly in the inside, heat loss is unlikely to occur, and the heating (heating) of the absorption liquid by the heating unit 11 can be performed efficiently. Thereby, since the high-temperature refrigerant vapor (water vapor) can be generated in a shorter time, cold air or hot air can be generated in the evaporator 30 in a shorter time. As a result, responsiveness during cooling and heating operations can be improved.

  Moreover, in this embodiment, the evaporator 30 containing the refrigerant | coolant storage part 30a and the pump 73 which supplies the refrigerant | coolant of the refrigerant | coolant storage part 30a of the evaporator 30 to the circulation channel part 51 at the time of heating operation are provided. Thus, even when the valve 61 is closed during the heating operation and the path between the absorber 40 and the gas-liquid separator 12 (the flow path of the absorbing liquid transfer pipe 55) is blocked, the inside of the circulation path 51 The refrigerant (water) in the refrigerant reservoir 30a of the evaporator 30 is supplied for the purpose of diluting the solution to the absorbing liquid (LiBr concentrated liquid) with a small refrigerant content after the refrigerant vapor is separated by using the pump 73. be able to. Therefore, since the absorption liquid whose refrigerant content is appropriately adjusted can be circulated through the circulation passage portion 51, the refrigerant vapor (water vapor) can be easily and continuously generated from the absorption liquid using the heating unit 11. it can. Further, even in a situation where the pressure in the circulation passage portion 51 that has become high is higher than the pressure in the evaporator 30 that is relatively low in temperature, the refrigerant (water) in the refrigerant storage portion 30a of the evaporator 30 using the pump 73 is used. ) Can be reliably supplied to the circulation passage portion 51.

  In the present embodiment, the pump 73 has an outlet (discharge) side of the pump 73 connected to an inlet (suction) side of the pump 71, and an inlet (suction) side of the pump 73 to the refrigerant reservoir 30 a of the evaporator 30. It is connected and configured to supply the refrigerant (water) in the refrigerant reservoir 30a between the gas-liquid separator 12 and the inlet of the pump 71 in the absorption liquid circulation pipe 51a by the pump 73 during heating operation. . As a result, the refrigerant of the evaporator 30 pumped by the pump 73 is supplied to the inlet (intake) side of the pump 71 for circulating the absorbing liquid, so that the pressure near the inlet of the pump 71 is prevented from decreasing. be able to. Therefore, it is possible to suppress the occurrence of a cavitation phenomenon in which bubbles are generated near the inlet of the pump 71. Further, by connecting the outlet side of the pump 73 to the inlet side of the pump 71, the required power of the pump 73 can be reduced by the amount of the suction force that the pump 71 has.

  Further, in the present embodiment, the refrigerant supply pipe 57 is provided on the outlet side of the pump 73 and includes a valve 63 that blocks the absorption liquid from flowing into the evaporator 30. Configure to open when driven. Thereby, at the time of heating operation, the refrigerant of the evaporator 30 pumped by the pump 73 with the valve 63 opened can be reliably supplied to the circulation passage portion 51 (absorbing liquid circulation conduit 51a). Further, when the pump 73 is stopped (cooling operation), the valve 63 is closed, and the high-temperature (high-pressure) absorbing liquid in the circulation passage 51 flows backward (flows into the evaporator 30) through the pump 73. Can be surely prevented. That is, even if the evaporator 30 is configured using aluminum metal or the like, corrosion in the container due to LiBr is effectively suppressed.

  Further, in the present embodiment, during the cooling operation, the gas liquid is opened by opening the valve 61 based on the fact that the temperature of the absorbing liquid circulating through the circulation passage 51 has reached a predetermined reference value (about 100 ° C.). A circulation path 151 (see the circulation path indicated by the arrow Q in FIG. 3) through which the absorption liquid of the separation unit 12 flows into the absorber 40 is formed. As described above, after the cooling operation is started, when the temperature of the absorbing liquid reaches a predetermined reference value (about 100 ° C.), the absorbing liquid circulating through the circulation passage 51 is appropriately heated and the evaporator 30, it can be determined that cold air can be properly supplied. In that case, the valve 61 is opened to allow the absorption liquid (LiBr concentrated liquid) of the gas-liquid separation unit 12 to flow into the absorber 40. Thus, after the cooling air can be properly supplied, it is possible to shift to a normal cooling operation using the absorber 40.

  In the present embodiment, a valve 62 for blocking the absorption liquid of the absorber 40 from flowing into the circulation passage section 51 is provided in the absorption liquid transfer pipe 56, and the absorption liquid that circulates through the circulation passage section 51 during the cooling operation. Based on the fact that the temperature of the gas reaches a predetermined reference value (about 100 ° C.), the valve 61 and the valve 62 are opened, whereby the absorption liquid in the gas-liquid separation unit 12 flows into the absorber 40 and the absorber 40. The absorption liquid flows into the circulation passage 51 and a circulation path 151 is formed through which the absorption liquid circulates between the gas-liquid separator 12, the absorber 40, and the heating unit 11. As a result, after the start of the cooling operation, after the temperature of the absorbing liquid circulating through the circulation passage portion 51 has reached a predetermined reference value (about 100 ° C.), the cooling air can be properly supplied. By opening not only the valve 61 but also the valve 62, it is possible to form a circulation path 151 that returns the absorption liquid (diluted liquid) diluted by the absorber 40 to the circulation passage section 51 through the valve 62. It is possible to easily shift to a normal cooling operation using the absorber 40 after the cold air can be properly supplied.

  Further, in the present embodiment, during the cooling operation, the absorption liquid (LiBr concentrated liquid) flowing from the gas-liquid separation unit 12 toward the absorber 40 is absorbed into the absorption liquid (LiBr concentrated liquid) flowing from the absorber 40 toward the circulation passage unit 51 ( (Dilute liquid) to reduce the temperature of the absorption liquid (LiBr concentrated liquid) flowing from the gas-liquid separation part 12 toward the absorber 40 and also flowing from the absorber 40 toward the circulation passage part 51. A heat exchanger 45 for increasing the temperature of the (dilute liquid) is provided. As a result, when the valve 61 and the valve 62 are opened and the absorbent is circulated (circulated) in the circulation path 151, a part of the heat of the absorbent (concentrated liquid) heated (heated) in the circulation passage 51 is generated. Since the heat can be transferred to the absorption liquid (diluted liquid) returned from the absorber 40 to the circulation passage portion 51 via the heat exchanger 45, the absorption liquid (diluted liquid) flows into the circulation passage portion 51 from the absorber 40. In this case, it is possible to suppress the temperature of the absorbing liquid circulating through the circulation passage portion 51 from being lowered. Therefore, even after shifting to a normal cooling operation using the absorber 40, it is possible to maintain a state where the temperature of the circulating absorbing liquid is maintained and cold air can be supplied appropriately. On the other hand, the absorption liquid (concentrated liquid) that passes from the gas-liquid separation part 12 (circulation passage part 51) through the heat exchanger 45 toward the absorber 40 is absorbed from the absorber 40 toward the circulation passage part 51. Since it is cooled by (dilute liquid), a lower temperature absorption liquid (concentrated liquid) is supplied to the absorber 40, and the pressure in the absorber 40 is maintained at a lower pressure state. Thereby, since the pressure (evaporation temperature of the refrigerant (water)) in the evaporator 30 communicating with the absorber 40 via the refrigerant vapor transfer pipe 53 is also maintained at a low state, the cold air can be stably supplied. Can do.

  In the present embodiment, the evaporator 30 including the refrigerant reservoir 30 a and the refrigerant vapor transfer pipe 53 between the evaporator 30 and the absorber 40 are connected to the gas-liquid separator 12. And a three-way valve 64 provided at a portion of the refrigerant vapor transfer pipe 52b that merges with the refrigerant vapor transfer pipe 53, and during the cooling operation, when the three-way valve 64 is switched to the "first flow path side" The refrigerant vapor generated by evaporating the refrigerant in the refrigerant reservoir 30a of the evaporator 30 is returned to the absorber 40 via the refrigerant vapor transfer pipe 53, and the three-way valve 64 is set to “second flow” during the heating operation. When switching to the “road side”, the refrigerant vapor separated by the gas-liquid separation unit 12 is configured to directly flow into the evaporator 30 via the refrigerant vapor transfer pipe line 52b. As a result, during cooling operation, the low-temperature refrigerant vapor evaporated by the evaporator 30 can easily flow into the absorber 40 (differential pressure suction) via the three-way valve 64 and the refrigerant vapor transfer conduit 53. Moreover, since the high-temperature refrigerant | coolant vapor | steam isolate | separated by the gas-liquid separation part 12 can be supplied to the evaporator 30 directly via the refrigerant | coolant vapor | steam transfer conduit 52b and the three-way valve 64 at the time of heating operation, the evaporator 30 The hot refrigerant can be efficiently generated by condensing this high-temperature refrigerant vapor.

  In the present embodiment, the condenser 20 that condenses the refrigerant vapor separated by the gas-liquid separation unit 12 during the cooling operation, and the gas-liquid separation unit 12 are provided in the refrigerant vapor transfer pipe 52a during the heating operation. And a valve 65 for shutting off the refrigerant vapor separated by the flow into the condenser 20. Thus, the high-temperature refrigerant vapor is caused to flow into the condenser 20 to be condensed by opening the valve 65 during the cooling operation, while the high-temperature refrigerant vapor is prevented from flowing into the condenser 20 by closing the valve 65 during the heating operation. can do. As a result, it is possible to prevent the high-temperature refrigerant vapor (water vapor) heated (heated) by the heating unit 11 and separated by the gas-liquid separation unit 12 from heating the condenser 20 unnecessarily during the heating operation. In addition, since all of this high-temperature refrigerant vapor can be supplied directly to the evaporator 30 via the refrigerant vapor transfer line 52b and the three-way valve 64, the high-temperature refrigerant vapor is condensed in the evaporator 30 for efficiency. Warm air can be generated.

  In the present embodiment, the condenser 20 that condenses the refrigerant vapor separated by the gas-liquid separator 12 during the cooling operation, and between the condenser 20 and the absorber 40 (flow path of the refrigerant supply pipe 58). And a valve 67 that opens when the refrigerant (condensed water) of the condenser 20 is supplied directly to the absorber 40 to dilute the absorbent to prevent crystallization of the absorbent. Thereby, when the apparatus is stopped after the cooling operation, the concentration of the absorbing liquid staying in each part of the apparatus by opening the valve 67 and returning a part of the refrigerant (condensed water) accumulated in the condenser 20 to the absorber 40. Can be maintained within a predetermined range. Therefore, even when the absorption heat pump device 100 is stopped without performing the cooling operation, crystallization of the absorption liquid in the apparatus can be prevented and the state of the absorption liquid can be appropriately maintained.

  In the present embodiment, the heating unit 11 is configured to heat the absorbing liquid by utilizing heat exchange by the exhaust gas of the engine 90. Thereby, the heat energy (renewable energy) contained in the exhaust gas discharged from the engine 90 can be recovered as exhaust heat as the heat source of the absorption heat pump device 100 and effectively used. In addition, since the absorption heat pump apparatus 100 can be configured using the exhaust heat of the engine 90, the absorption heat pump apparatus 100 can be widely applied as an air conditioner for vehicles equipped with the engine 90.

(First modification)
Next, a first modification of the above embodiment will be described with reference to FIGS. In this first modification, unlike the above embodiment, instead of one three-way valve 64 (see FIG. 1), a valve 201 and a valve 202 each consisting of a two-way valve are respectively connected to a refrigerant vapor transfer line 253 and An example of providing the refrigerant vapor transfer pipe 252b will be described. The valve 201 and the valve 202 are examples of the “fourth valve” and the “fifth valve” in the present invention, respectively. In addition, in the figure, the same code | symbol as the said embodiment is attached | subjected and illustrated to the structure similar to the said embodiment.

  In the absorption heat pump device 200 according to the first modified example, as shown in FIG. 8, the refrigerant vapor transfer pipe 253 that connects the evaporator 30 and the absorber 40, and the evaporator 30 and the gas-liquid separator 12 are connected. The refrigerant vapor transfer pipeline 252b to be connected is separately connected to the evaporator 30 without joining. The refrigerant vapor transfer pipe 253 is provided with a valve 201 (electromagnetic valve), and the refrigerant vapor transfer pipe 252b is provided with a valve 202 (electromagnetic valve). Thus, as shown in FIG. 8, during the cooling operation, the valve 201 is opened, and the refrigerant vapor (low-temperature water vapor) generated by evaporating the refrigerant in the refrigerant reservoir 30a of the evaporator 30 is absorbed by the absorber 40. In addition, during heating operation, the valve 202 is opened so that the refrigerant vapor (high-temperature steam) separated by the gas-liquid separation unit 12 flows directly into the evaporator 30. The valve 202 is closed when the valve 201 is opened, and the valve 201 is closed when the valve 202 is opened. Thereby, the 1st flow path which connects the evaporator 30 and the absorber 40, and the 2nd flow path which connects the gas-liquid separation part 12 and the evaporator 30 are switched alternatively.

  In addition, the other structure of the absorption heat pump apparatus 200 by a 1st modification is the same as that of the said embodiment.

  In the first modification, as described above, instead of the three-way valve 64 (see FIG. 1) used in the above embodiment, the valve 201 and the valve 202 are replaced with a refrigerant vapor transfer line 253 and a refrigerant vapor transfer line, respectively. Provided at 252b. Also by this, the first flow path connecting the evaporator 30 and the absorber 40 and the second flow path connecting the gas-liquid separator 12 and the evaporator 30 are selectively switched to be equivalent to the three-way valve 64. It can have the function of. The remaining effects of the first modified example are similar to those of the aforementioned embodiment.

(Second modification)
Next, a second modification of the above embodiment will be described with reference to FIGS. 4 and 9. In the second modified example, unlike the embodiment shown in FIG. 4, the connection point of the refrigerant supply pipe 357 connecting the evaporator 30 and the circulation passage 51 to the circulation passage 51 is the outlet of the heating unit 11. An example configured to be a part of the absorption liquid circulation pipe 51b on the side will be described. The refrigerant supply pipe 357 is an example of the “refrigerant supply passage” in the present invention. In addition, in the figure, the same code | symbol as the said embodiment is attached | subjected and illustrated to the structure similar to the said embodiment.

  In the absorption heat pump device 300 according to the second modified example, as shown in FIG. 9, the refrigerant supply line 357 includes the evaporator 30 (refrigerant storage part 30a) and the heating part 11 in the absorption liquid circulation line 51b. Connected to the exit side. This also enables the pump 73 to be driven and the refrigerant (water) in the refrigerant reservoir 30a to be replenished (supplied) to the circulation passage 51 during the heating operation.

  In addition, the other structure of the absorption heat pump apparatus 300 by a 2nd modification is the same as that of the said embodiment.

  In the second modification example, as described above, the refrigerant supply pipe 357 is connected to the portion of the absorbing liquid circulation pipe 51b on the outlet side of the heating unit 11, thereby driving the pump 73 during the heating operation and the refrigerant storage unit. Since the refrigerant (water) of 30a can be supplied (supplemented) to the circulation passage 51, the absorbing liquid whose refrigerant content is appropriately adjusted can be circulated through the circulation passage 51. The remaining effects of the second modification are similar to those of the aforementioned embodiment.

(Third Modification)
Next, a third modification of the embodiment will be described with reference to FIGS. In this third modification, unlike the above embodiment, a method of using the pump 73 (refrigerant supply line 57) during the crystallization prevention operation after stopping the heating operation (refer to the path indicated by the arrow S in FIG. 7). An example of returning a part of the refrigerant (condensed water) of the evaporator 30 (refrigerant storage unit 30a) to the absorber 40 by a method different from the method of FIG. In addition, in the figure, the same code | symbol as the said embodiment is attached | subjected and illustrated to the structure similar to the said embodiment.

  In the absorption heat pump apparatus 400 according to the third modification, as shown in FIG. 10, the valve 66 and the valve 67 are opened as a crystallization preventing operation at a predetermined timing after the heating operation is stopped. Further, the valves 61 and 62 are opened, and the pumps 71, 72 and 42 are started. Thus, an absorber in which a part of the refrigerant (condensed water) of the evaporator 30 (refrigerant reservoir 30a) flows along the refrigerant transfer pipe 54 and the refrigerant supply pipe 58 along the direction of the arrow T and is maintained at a low pressure. The pressure difference is aspirated to 40, and the diluted absorbent in the absorber 40 circulates in the apparatus to dilute all the absorbent. Then, after a predetermined time has elapsed, the crystallization preventing operation is terminated by the closing operation of the valves 61, 62, 66 and 67 and the stop of the pumps 71 to 73 and 42 described above.

  In addition, the other structure of the absorption heat pump apparatus 400 by a 3rd modification is the same as that of the said embodiment.

  In the third modification, as described above, by opening the valve 66 and the valve 67 after stopping the heating operation, a part of the refrigerant of the evaporator 30 is absorbed through the refrigerant transfer line 54 and the refrigerant supply line 58. Supply to the container 40. As a result, unlike the above embodiment (see FIG. 7), the pump 73 provided in the refrigerant supply line 57 is driven to supply the refrigerant (water) to the absorber 40. It is possible to reduce the amount of refrigerant (water) supplied to the absorber 40 and dilute the absorbing liquid, so that it is possible to reduce power consumption when the absorption heat pump device 400 is stopped. The remaining effects of the third modification are similar to those of the aforementioned embodiment.

  The embodiment disclosed this time should be considered as illustrative in all points and not restrictive. The scope of the present invention is shown not by the above description of the embodiments but by the scope of claims for patent, and further includes all modifications within the meaning and scope equivalent to the scope of claims for patent.

  For example, in the above-described embodiment and the first to third modified examples, examples of using the water and the lithium bromide (LiBr) aqueous solution as the refrigerant and the absorbing liquid have been described, respectively, but the present invention is not limited thereto. Absent. For example, the present invention may be applied to an absorption heat pump apparatus using ammonia and water as the refrigerant and the absorbing liquid, respectively. In this case, the condition (temperature condition of the absorbing liquid) when the valve 61 (valve 62) is opened and the operation is shifted to the normal operation using the absorber 40 from the state where the absorbing liquid is circulated only in the circulation passage 51 and heated during the cooling operation. ) Is appropriately determined depending on the thermophysical value of the ammonia-water system.

  In the embodiment and the first to third modifications, the temperature sensor 5 is attached to the portion of the absorbing liquid circulation pipe 51b immediately before entering the gas-liquid separator 12, but the present invention is not limited to this. It is not limited to this. If the temperature of the heated absorbent (LiBr aqueous solution) circulating through the circulation passage 51 can be grasped, for example, the temperature in the portion of the absorbent circulation line 51a immediately after coming out of the gas-liquid separator 12 The sensor 5 may be attached, or the temperature sensor 5 is placed in the gas-liquid separation unit 12 (absorption liquid storage unit) so as to directly grasp the temperature of the absorption liquid (concentrated liquid) stored in the gas-liquid separation unit 12. You may attach to.

  Moreover, in the said embodiment and a 1st modification-a 3rd modification, based on the temperature of the absorption liquid (LiBr aqueous solution) which circulates through the circulation channel | path part 51 using the temperature sensor 5 reached about 100 degreeC. Although an example in which the valve 61 and the valve 62 are opened to shift to a normal cooling operation cycle is shown, the present invention is not limited to this. In the present invention, the temperature sensor 5 is used to open the valve 61 and the valve 62 based on the fact that the temperature of the refrigerant vapor (high-temperature steam) separated by the gas-liquid separator 12 has reached a predetermined reference value. Good. In this case, the temperature sensor 5 is attached to the gas phase part (near the ceiling in the container) in the gas-liquid separator 12 so that the temperature of the refrigerant vapor separated in the gas-liquid separator 12 can be directly grasped. Also good.

  Moreover, in the said embodiment and a 1st modification-a 3rd modification, it is along the direction through which a refrigerant | coolant (condensed water) distribute | circulates from the evaporator 30 toward the circulation channel | path part 51 regarding the refrigerant | coolant supply conduit 57 (357). ) Although an example in which the pump 73 and the valve 63 are arranged in this order is shown, the present invention is not limited to this. The arrangement order of the pump 73 and the valve 63 may be opposite to the above.

  Moreover, in the said embodiment and a 1st modification-a 3rd modification, the absorption liquid transfer pipe 56 is made into the exit side (part between the pump 71 and the heating part 11) of the pump 71 in the absorption liquid circulation pipe 51a. Although an example of connection is shown, the present invention is not limited to this. In the present invention, the absorption liquid transfer line 56 may be connected to the inlet (intake) side of the pump 71 in the absorption liquid circulation line 51a. Thereby, during cooling operation (during normal operation), the absorption liquid from the absorber 40 pumped by the pump 72 is supplied to the inlet (intake) side of the pump 71 for circulating the absorption liquid. It is possible to suppress the pressure in the vicinity of the inlet from decreasing and to prevent the cavitation phenomenon from occurring.

  Moreover, in the said embodiment and the 1st modification-a 3rd modification, it is based on the temperature of the absorption liquid (LiBr aqueous solution) which circulates through the circulation channel | path part 51 having reached about 100 degreeC after starting the cooling operation. Although the example in which the valve 61 and the valve 62 are opened to shift to a normal cooling operation cycle using the absorber 40 is shown, the present invention is not limited to this. In the present invention, based on the fact that the pressure of the refrigerant vapor in the gas-liquid separation unit 12 when the absorbing liquid circulates in the circulation passage unit 51 has reached a predetermined reference value (for example, around 10 kPa in absolute pressure), the valve 61 The valve 62 may be opened to shift to a normal cooling operation cycle. The pressure sensor for measuring the pressure is preferably provided at a position where the pressure of the refrigerant vapor in the gas-liquid separator 12 can be measured.

  Moreover, in the said embodiment and a 1st modification-a 3rd modification, after starting heating operation, it is based on the temperature of the absorption liquid (LiBr aqueous solution) which circulates through the circulation channel part 51 having reached about 100 degreeC vicinity. Although the valve 63 is opened and the pump 73 is started and the refrigerant (condensed water) stored in the evaporator 30 is supplied to the circulation passage 51, the present invention is not limited to this. In the present invention, the valve 63 is opened and the pump 73 is started based on the fact that the refrigerant vapor pressure in the gas-liquid separation unit 12 when the absorption liquid circulates in the circulation passage unit 51 has reached a predetermined reference value. The refrigerant (condensed water) stored in the evaporator 30 may be supplied to the circulation passage portion 51. Also in this case, the pressure sensor for measuring the pressure is preferably provided at a position where the pressure of the refrigerant vapor in the gas-liquid separator 12 can be measured.

  Moreover, in the said embodiment and a 1st modification-a 3rd modification, the absorption liquid stored in the gas-liquid separation part 12 by controlling each transfer amount (pressure feed amount) of the pump 71 and the pump 72 at the time of air_conditionaing | cooling operation. Although an example in which the storage amount (liquid level height) and the storage amount (liquid level height) of the absorbing liquid stored in the absorber 40 is adjusted to be within a predetermined range has been shown, It is not limited to this. For example, the transfer amount of each of the pump 71 and the pump 72 is controlled by using an electric linear valve or the like that can control the valve opening from the fully closed state to the fully open state stepwise or steplessly as the valve 61. Alternatively, the opening of the valve 61 (electric linear valve) may be controlled to adjust the amount of stored liquid in each of the gas-liquid separator 12 and the absorber 40. In addition, the transfer amount may be controlled by applying an electric linear valve not only to the valve 61 but also to the valve 63. Moreover, you may adjust the storage amount (liquid level height) of an absorption liquid combining the control of both the transfer amount of a pump, and the opening degree of an electric linear valve.

  Moreover, in the said embodiment and a 1st modification-a 3rd modification, the density | concentration of the absorption liquid which circulates through the circulation channel | path part 51 by controlling each transfer amount (pressure feed amount) of the pump 71 and the pump 73 at the time of heating operation. Although an example in which the (dilution ratio of the refrigerant (water) with respect to the LiBr aqueous solution) is adjusted to be within a predetermined range is shown, the present invention is not limited to this. That is, an electric linear valve may be applied to the valve 63 to adjust the supply amount of the refrigerant (water) to the circulation passage 51, the transfer amount of the pump 73 and the opening degree of the valve 63 (electric linear valve). The supply amount of the refrigerant (water) may be adjusted by combining both of these controls.

  Moreover, in the said embodiment and the 1st modification-the 3rd modification, although shown about the example which comprised the heating part 11 and the heat exchanger 45 using the plate-type heat exchanger, this invention is not limited to this. . In the present invention, the heating unit 11 and the heat exchanger 45 may be configured by using, for example, a double tube heat exchanger other than the plate heat exchanger, and the outer walls of the circular tubes are along the tube axis direction. The heating unit 11 and the heat exchanger 45 may be configured by using a spiral heat exchanger in which a circular tube (elliptical tube) or a flat tube is spirally wound in a joined state.

  In the embodiment and the first to third modifications, the “absorption heat pump device” of the present invention is applied to an air conditioning system for vehicles such as passenger cars, buses and trucks equipped with an engine (internal combustion engine). However, the present invention is not limited to this. For example, you may apply to air-conditioning systems, such as a train and a ship provided with the diesel engine.

  Moreover, although the said embodiment and the 1st modification-the 3rd modification showed about the example which heats absorption liquid using the heat | fever of the exhaust gas of an engine (internal combustion engine), this invention is not limited to this. . For example, the “absorption heat pump device” of the present invention may be applied to an air conditioning system of a hybrid vehicle that travels by using both an engine drive and an electric motor drive, or applied to an air conditioning system of a passenger car equipped with a fuel cell system. May be. That is, the heat source for heating the absorption liquid may be not only the exhaust gas of the engine but also, for example, the exhaust heat of the battery or motor of the electric vehicle or the exhaust heat during power generation in the fuel cell.

DESCRIPTION OF SYMBOLS 10 Regenerator 11 Heating part 12 Gas-liquid separation part 20 Condenser 30 Evaporator 30a Refrigerant storage part 40 Absorber 45 Heat exchanger 51 Circulation passage part 52a, 52b, 53, 252b, 253 Refrigerant vapor transfer pipe 54 Refrigerant transfer pipe Channels 55, 56 Absorbing liquid transfer channel 57, 357 Refrigerant supply channel (refrigerant supply channel)
58 Refrigerant supply line 61 Valve (first valve)
62 Valve (third valve)
63 Valve (second valve)
64 Three-way valve (4th valve, 5th valve)
65 valve (sixth valve)
67 Valve (seventh valve)
71 Pump (first pump)
73 Pump (second pump)
90 Engine 100, 200, 300, 400 Absorption heat pump device 151 Circulation path 201 Valve (fourth valve)
202 Valve (fifth valve)

Claims (10)

A heating unit for heating the absorbent;
A gas-liquid separation unit that separates refrigerant vapor from the absorption liquid heated by the heating unit;
A circulation passage section connecting the heating section and the gas-liquid separation section so that an absorbing liquid can circulate between the heating section and the gas-liquid separation section;
An absorber that absorbs the refrigerant in the absorbing liquid;
A first valve for blocking the absorption liquid of the gas-liquid separation unit from flowing into the absorber;
A first pump that sucks the absorbing liquid from the gas-liquid separation unit and circulates the circulation passage unit ;
An evaporator including a refrigerant reservoir;
An absorption heat pump device comprising: a second pump that supplies the refrigerant in the refrigerant storage part of the evaporator to the circulation passage part during heating operation . In the second pump, the outlet side of the second pump is connected to the inlet side of the first pump, and the inlet side of the second pump is connected to the refrigerant storage part of the evaporator,
During the heating operation, the the second pump, wherein the refrigerant in the refrigerant reservoir is configured to supply between the inlet of the first pump and the gas-liquid separator, the absorption type according to claim 1 Heat pump device. A second valve provided on the outlet side of the second pump for blocking the absorption liquid from flowing into the evaporator;
The absorption heat pump device according to claim 1 or 2 , wherein the second valve is configured to be opened when the second pump is driven during heating operation. A heating unit for heating the absorbent;
A gas-liquid separation unit that separates refrigerant vapor from the absorption liquid heated by the heating unit;
A circulation passage section connecting the heating section and the gas-liquid separation section so that an absorbing liquid can circulate between the heating section and the gas-liquid separation section;
An absorber that absorbs the refrigerant in the absorbing liquid;
A first valve for blocking the absorption liquid of the gas-liquid separation unit from flowing into the absorber;
A first pump that sucks the absorption liquid from the gas-liquid separation unit and circulates the circulation passage unit,
During the cooling operation, based on the fact that the temperature of the circulating absorbing liquid or the pressure of the refrigerant vapor in the gas-liquid separation unit has reached a predetermined reference value, the first valve is opened, so that the gas-liquid separation unit absorbing liquid is configured circulation path flowing into the absorber are formed, suction Osamushiki heat pump apparatus. A third valve for blocking the absorption liquid of the absorber from flowing into the circulation passage portion;
By opening the first valve and the third valve based on the fact that the temperature of the circulating absorbing liquid or the pressure of the refrigerant vapor in the gas-liquid separation unit has reached a predetermined reference value during the cooling operation, The absorption liquid of the gas-liquid separation part flows into the absorber and the absorption liquid of the absorber flows into the circulation passage part to absorb between the gas-liquid separation part, the absorber and the heating part. The absorption heat pump apparatus according to claim 4 , wherein the circulation path through which the liquid circulates is formed. At the time of cooling operation, the heat of the absorption liquid flowing from the gas-liquid separation unit toward the absorber is applied to the absorption liquid flowing from the absorber toward the circulation passage unit, so that the gas-liquid separation unit 6. The absorption according to claim 5 , further comprising a heat exchanger for lowering the temperature of the absorbing liquid flowing toward the absorber and increasing the temperature of the absorbing liquid flowing from the absorber toward the circulation passage portion. Type heat pump device. A heating unit for heating the absorbent;
A gas-liquid separation unit that separates refrigerant vapor from the absorption liquid heated by the heating unit;
A circulation passage section connecting the heating section and the gas-liquid separation section so that an absorbing liquid can circulate between the heating section and the gas-liquid separation section;
An absorber that absorbs the refrigerant in the absorbing liquid;
A first valve for blocking the absorption liquid of the gas-liquid separation unit from flowing into the absorber;
A first pump that sucks the absorbing liquid from the gas-liquid separation unit and circulates the circulation passage unit;
An evaporator including a refrigerant reservoir;
A fourth valve provided between the evaporator and the absorber;
Bei example and a fifth valve disposed between said evaporator and the gas-liquid separation unit,
During the cooling operation, the fourth valve is opened to return the refrigerant vapor generated by the evaporation of the refrigerant in the refrigerant reservoir of the evaporator to the absorber, and during the heating operation, the fifth valve by opening the valve, the refrigerant vapor separated by the gas-liquid separator is configured to directly flow into the evaporator, suction Osamushiki heat pump apparatus. A heating unit for heating the absorbent;
A gas-liquid separation unit that separates refrigerant vapor from the absorption liquid heated by the heating unit;
A circulation passage section connecting the heating section and the gas-liquid separation section so that an absorbing liquid can circulate between the heating section and the gas-liquid separation section;
An absorber that absorbs the refrigerant in the absorbing liquid;
A first valve for blocking the absorption liquid of the gas-liquid separation unit from flowing into the absorber;
A first pump that sucks the absorbing liquid from the gas-liquid separation unit and circulates the circulation passage unit;
A condenser for condensing the refrigerant vapor separated by the gas-liquid separator during cooling operation;
During a heating operation, the refrigerant vapor separated by the gas-liquid separator and the sixth valve for blocking from flowing into the condenser, Bei El and absorption Osamushiki heat pump apparatus. A condenser for condensing the refrigerant vapor separated by the gas-liquid separator during cooling operation;
A seventh valve provided between the condenser and the absorber, and opened when the refrigerant is diluted by supplying refrigerant to the absorber to prevent crystallization of the absorption liquid The absorption heat pump device according to any one of claims 1 to 8 , further comprising: The absorption heat pump device according to any one of claims 1 to 9 , wherein the heating unit is configured to heat the absorbing liquid by utilizing heat exchange by an exhaust gas of the engine.

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