JP6085724B2 - 接合用組成物 - Google Patents
接合用組成物 Download PDFInfo
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- JP6085724B2 JP6085724B2 JP2016542777A JP2016542777A JP6085724B2 JP 6085724 B2 JP6085724 B2 JP 6085724B2 JP 2016542777 A JP2016542777 A JP 2016542777A JP 2016542777 A JP2016542777 A JP 2016542777A JP 6085724 B2 JP6085724 B2 JP 6085724B2
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- MUMZUERVLWJKNR-UHFFFAOYSA-N oxoplatinum Chemical compound [Pt]=O MUMZUERVLWJKNR-UHFFFAOYSA-N 0.000 description 1
- HFPZCAJZSCWRBC-UHFFFAOYSA-N p-cymene Chemical compound CC(C)C1=CC=C(C)C=C1 HFPZCAJZSCWRBC-UHFFFAOYSA-N 0.000 description 1
- CFJYNSNXFXLKNS-UHFFFAOYSA-N p-menthane Chemical compound CC(C)C1CCC(C)CC1 CFJYNSNXFXLKNS-UHFFFAOYSA-N 0.000 description 1
- 150000002940 palladium Chemical class 0.000 description 1
- 229910003445 palladium oxide Inorganic materials 0.000 description 1
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
- YJVFFLUZDVXJQI-UHFFFAOYSA-L palladium(ii) acetate Chemical compound [Pd+2].CC([O-])=O.CC([O-])=O YJVFFLUZDVXJQI-UHFFFAOYSA-L 0.000 description 1
- GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(ii) nitrate Chemical compound [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229940100684 pentylamine Drugs 0.000 description 1
- 235000005693 perillyl alcohol Nutrition 0.000 description 1
- CMCWWLVWPDLCRM-UHFFFAOYSA-N phenidone Chemical compound N1C(=O)CCN1C1=CC=CC=C1 CMCWWLVWPDLCRM-UHFFFAOYSA-N 0.000 description 1
- MJRKFYKONYYOJX-UHFFFAOYSA-J phosphonato phosphate;tin(4+) Chemical compound [Sn+4].[O-]P([O-])(=O)OP([O-])([O-])=O MJRKFYKONYYOJX-UHFFFAOYSA-J 0.000 description 1
- 229930006728 pinane Natural products 0.000 description 1
- LCYXQUJDODZYIJ-UHFFFAOYSA-N pinocarveol Chemical compound C1C2C(C)(C)C1CC(O)C2=C LCYXQUJDODZYIJ-UHFFFAOYSA-N 0.000 description 1
- 229930006721 pinocarveol Natural products 0.000 description 1
- 239000001739 pinus spp. Substances 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 150000003057 platinum Chemical class 0.000 description 1
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
- 229910003446 platinum oxide Inorganic materials 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- NEYLGXVZJUUZMY-UHFFFAOYSA-K potassium;trichlorogold Chemical compound [K].Cl[Au](Cl)Cl NEYLGXVZJUUZMY-UHFFFAOYSA-K 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- XOJVVFBFDXDTEG-UHFFFAOYSA-N pristane Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 150000003378 silver Chemical class 0.000 description 1
- CQLFBEKRDQMJLZ-UHFFFAOYSA-M silver acetate Chemical compound [Ag+].CC([O-])=O CQLFBEKRDQMJLZ-UHFFFAOYSA-M 0.000 description 1
- 229940071536 silver acetate Drugs 0.000 description 1
- SDLBJIZEEMKQKY-UHFFFAOYSA-M silver chlorate Chemical compound [Ag+].[O-]Cl(=O)=O SDLBJIZEEMKQKY-UHFFFAOYSA-M 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- KKKDGYXNGYJJRX-UHFFFAOYSA-M silver nitrite Chemical compound [Ag+].[O-]N=O KKKDGYXNGYJJRX-UHFFFAOYSA-M 0.000 description 1
- 229910001923 silver oxide Inorganic materials 0.000 description 1
- YPNVIBVEFVRZPJ-UHFFFAOYSA-L silver sulfate Chemical compound [Ag+].[Ag+].[O-]S([O-])(=O)=O YPNVIBVEFVRZPJ-UHFFFAOYSA-L 0.000 description 1
- 229910000367 silver sulfate Inorganic materials 0.000 description 1
- 229940056910 silver sulfide Drugs 0.000 description 1
- XUARKZBEFFVFRG-UHFFFAOYSA-N silver sulfide Chemical compound [S-2].[Ag+].[Ag+] XUARKZBEFFVFRG-UHFFFAOYSA-N 0.000 description 1
- FTNNQMMAOFBTNJ-UHFFFAOYSA-M silver;formate Chemical compound [Ag+].[O-]C=O FTNNQMMAOFBTNJ-UHFFFAOYSA-M 0.000 description 1
- 238000000235 small-angle X-ray scattering Methods 0.000 description 1
- 229960000230 sobrerol Drugs 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- DTNJZLDXJJGKCM-UHFFFAOYSA-K sodium;trichlorogold Chemical compound [Na].Cl[Au](Cl)Cl DTNJZLDXJJGKCM-UHFFFAOYSA-K 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- LRBQNJMCXXYXIU-NRMVVENXSA-N tannic acid Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-NRMVVENXSA-N 0.000 description 1
- 235000015523 tannic acid Nutrition 0.000 description 1
- 229920002258 tannic acid Polymers 0.000 description 1
- 229940033123 tannic acid Drugs 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 229930006978 terpinene Natural products 0.000 description 1
- 150000003507 terpinene derivatives Chemical class 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- OMDMTHRBGUBUCO-UHFFFAOYSA-N trans-sobrerol Natural products CC1=CCC(C(C)(C)O)CC1O OMDMTHRBGUBUCO-UHFFFAOYSA-N 0.000 description 1
- YJGJRYWNNHUESM-UHFFFAOYSA-J triacetyloxystannyl acetate Chemical compound [Sn+4].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O YJGJRYWNNHUESM-UHFFFAOYSA-J 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
- 229940036248 turpentine Drugs 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 125000005314 unsaturated fatty acid group Chemical group 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000011345 viscous material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/22—Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
- C09J9/02—Electrically-conducting adhesives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/005—Additives being defined by their particle size in general
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L33/00—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L33/48—Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Dispersion Chemistry (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Conductive Materials (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Die Bonding (AREA)
- Led Device Packages (AREA)
Description
無機粒子及び有機成分を含む接合用組成物であって、
前記無機粒子の平均粒径が1〜200nmであり、
略25℃における粘度が、せん断速度10s-1において10〜30Pa・sであり、
略25℃においてせん断速度1s-1で測定した粘度V1を、略25℃においてせん断速度10s-1で測定した粘度V10で除した値で定義されるチクソ比Rが3〜7であること、
を特徴とする接合用組成物を提供する。
前記接合用組成物を塗布した前記基板に前記LED(発光ダイオード)チップを積層させ、前記接合用組成物を焼成することで前記基板と前記LED(発光ダイオード)チップとを接合させる場合において、
前記基板と前記LED(発光ダイオード)チップとの略全界面に前記接合用組成物の焼成層が形成し、
前記LED(発光ダイオード)チップの側面に形成される前記接合用組成物のフィレットの高さが10μm未満となること、が好ましい。
基板にLED(発光ダイオード)チップが接合された電子部品接合体であって、
前記基板と前記LED(発光ダイオード)チップとが、本発明の接合用組成物を用いて接合されていること、
を特徴とする電子部品接合体も提供する。
本実施形態の接合用組成物は、無機粒子を主成分、有機成分を副成分とする。以下においてこれら各成分について説明する。
本実施形態の接合用組成物の無機粒子としては、特に限定されるものではないが、本実施形態の接合用組成物を用いて得られる接着層の導電性を良好にすることができるため、亜鉛よりもイオン化傾向が小さい(貴な)金属で構成される金属粒子であるのが好ましい。
D=Kλ/Bcosθ
ここで、K:シェラー定数(0.9)、λ:X線の波長、B:回折線の半値幅、θ:ブラッグ角である。
本実施形態の接合用組成物において、無機粒子の表面の少なくとも一部に付着している有機成分、即ち、無機コロイド粒子中の「有機成分」は、いわゆる分散剤として上記無機粒子とともに実質的に無機コロイド粒子を構成する。当該有機成分には、金属中に最初から不純物として含まれる微量有機物、後述する製造過程で混入して金属成分に付着した微量有機物、洗浄過程で除去しきれなかった残留還元剤、残留分散剤等のように、無機粒子に微量付着した有機物等は含まれない概念である。なお、上記「微量」とは、具体的には、無機コロイド粒子中1質量%未満が意図される。
前記接合用組成物を塗布した前記基板に前記LED(発光ダイオード)チップを積層させ、前記接合用組成物を焼成することで前記基板と前記LED(発光ダイオード)チップとを接合させる場合において、
前記基板と前記LED(発光ダイオード)チップとの略全界面に前記接合用組成物の焼成層が形成し、
前記LED(発光ダイオード)チップの側面に形成される前記接合用組成物のフィレットの高さが10μm未満となること、が好ましい。
本実施形態の接合用組成物は、各状況における重量減少の制御によって、接合用組成物としての特性が最適化されている。
本実施形態の接合用組成物を製造するためには、副成分である有機成分で被覆された主成分である無機粒子(無機コロイド粒子)を調製する。
本実施形態の接合用組成物を用いれば、加熱を伴う部材同士の接合において比較的低い接合温度で高い接合強度を得ることができる。即ち、上記接合用組成物を第1の被接合部材(LED(発光ダイオード)チップ)と第2の被接合部材(基板)との間に塗布する接合用組成物塗布工程と、第1の被接合部材と第2の被接合部材との間に塗布した接合用組成物を、所望の温度(例えば300℃以下、好ましくは150〜200℃)で焼成して接合する接合工程と、により、第1の被接合部材と第2の被接合部材とを接合することができる。この際、加圧することもできるが、特に加圧しなくとも十分な接合強度を得ることができるのも本発明の利点のひとつである。また、焼成を行う際、段階的に温度を上げたり下げたりすることもできる。また、予め被接合部材表面に界面活性剤又は表面活性化剤等を塗布しておくことも可能である。
本実施形態の電子部品接合体は、基板にLED(発光ダイオード)チップが接合された電子部品接合体であって、基板とLED(発光ダイオード)チップとが、本発明の接合用組成物を用いて接合されている。
ドデシルアミン(和光純薬工業(株)製の試薬一級)0.60gと、ヘキシルアミン(和光純薬工業(株)製の試薬一級)7.0gと、ブチルアミン(和光純薬工業(株)製の試薬一級)3.0gと、を混合して、マグネティックスターラーで十分に撹拌した。ここに、撹拌を行いながらシュウ酸銀(東洋化学工業(株)製の試薬特級)7.0gを添加して増粘させた。
(1)接合組成物のせん断粘度
接合用組成物1の粘度を、コーンプレート型粘度計(アントンパール社製レオメーター,MCR301)を用いて測定した。測定条件は、測定モード:せん断モード、せん断速度:1s-1又は10s-1、測定治具:コーンプレート(CP−50−2;直径50mm,アングル2°,ギャップ0.045mm)、サンプル量:5g、測定温度:25℃とした。せん断速度が1s-1の場合のせん断粘度、せん断速度が10s-1の場合のせん断粘度、及び(せん断速度1s-1で測定時のせん断粘度)/(せん断速度10s-1で測定時のせん断粘度)で求めたチクソ比を、それぞれ表1に示した。
ダイボンダー(ハイソル社製)を用いて、表面に銀メッキを施したアルミナ板(3mm×3mm)に接合用組成物1を10μg載せ、その上に、市販の青色LEDチップ(エピスター社製ES−CADBV24H、底面積:600μm×600μm、高さ:150μm、重量:0.2mg)を積層した。
ボンドテスター(レスカ社製)を用いて、上記焼成処理後の積層体のせん断強度試験を行った。剥離時の接合強度をチップの底面積で除し、単位面積当たりの接合強度(MPa)を算出した。判断基準として、20MPa以上を○、20MPa未満を×とし、得られた結果を表1に示した。
分光測光装置(浜松ホトニクス社製)を用いて、上記焼成処理後の青色LEDチップの輝度を測定した。初期の輝度を100とし、温度85℃、湿度85%の環境下で1000時間連続点灯後の輝度を相対値で示し、得られた結果を表1に示した。なお、表1に示している比較例の発光強度(初期)は、実施例1の発光強度を100とした場合の相対強度を示している。
分散媒をジヒドロターピニルアセテート0.15g及び1−デカノール(和光純薬工業(株)製の試薬一級)0.1gにした以外は、実施例1と同様にして接合用組成物2を調製し、実施例1と同様にして各種特性を評価した。得られた結果を表1に示した。
分散媒をジヒドロターピニルアセテート0.15g及びテルソルブMTPH(日本テルペン(株)製)0.1gにした以外は、実施例1と同様にして接合用組成物3を調製し、実施例1と同様にして各種特性を評価した。得られた結果を表1に示した。
分散媒をテルピネオール(和光純薬工業(株)製の試薬一級)0.15g及びオレイン酸0.1gにした以外は、実施例1と同様にして接合用組成物4を調製し、実施例1と同様にして各種特性を評価した。得られた結果を表1に示した。
分散媒をテルピネオール(和光純薬工業(株)製の試薬一級)0.15gと1−デカノール0.1gにした以外は、実施例1と同様にして接合用組成物5を調製し、実施例1と同様にして各種特性を評価した。得られた結果を表1に示した。
分散媒として加えたジヒドロターピニルアセテートの重量を0.10gにしたこと以外は、実施例1と同様にして比較接合用組成物1を調製し、実施例1と同様にして各種特性を評価した。得られた結果を表1に示した。
分散媒として加えたジヒドロターピニルアセテートの重量を0.40gにしたこと以外は、実施例1と同様にして比較接合用組成物2を調製し、実施例1と同様にして各種特性を評価した。得られた結果を表1に示した。
分散媒を1−デカノール0.15gにしたこと以外は、実施例1と同様にして比較接合用組成物3を調製し、実施例1と同様にして各種特性を評価した。得られた結果を表1に示した。
分散媒を1−デカノール0.30gにしたこと以外は、実施例1と同様にして比較接合用組成物4を調製し、実施例1と同様にして各種特性を評価した。得られた結果を表1に示した。
分散媒を1−ノナノール(和光純薬工業(株)製の試薬一級)0.1gにしたこと以外は、実施例1と同様にして比較接合用組成物5を調製し、実施例1と同様にして各種特性を評価した。得られた結果を表1に示した。
分散媒を1−ノナノール(和光純薬工業(株)製の試薬一級)0.2gにしたこと以外は、実施例1と同様にして比較接合用組成物6を調製し、実施例1と同様にして各種特性を評価した。得られた結果を表1に示した。
分散媒を1−デカノール0.2gとジペンテンT(日本テルペン化学(株)社製)0.1gにしたこと以外は、実施例1と同様にして比較接合用組成物7を調製し、実施例1と同様にして各種特性を評価した。得られた結果を表1に示した。
分散媒を1−ノナノール(和光純薬工業(株)製の試薬一級)0.2gとジペンテンT(日本テルペン化学(株)社製)0.1gにしたこと以外は、実施例1と同様にして比較接合用組成物8を調製し、実施例1と同様にして各種特性を評価した。得られた結果を表1に示した。
Claims (4)
- 金属粒子及びアミン及び/又はカルボン酸を含む接合用組成物であって、
前記金属粒子の平均粒径が1〜200nmであり、
略25℃における粘度が、せん断速度10s−1において10〜30Pa・sであり、
せん断速度1s−1で測定した略25℃における粘度V1を、せん断速度10s−1で測定した略25℃における粘度V10で除した値で定義されるチクソ比Rが3〜7であること、
を特徴とする接合用組成物。 - LED(発光ダイオード)チップと基板との接合に用いること、
を特徴とする請求項1に記載の接合用組成物。 - 前記接合用組成物を塗布した前記基板に前記LED(発光ダイオード)チップを積層させ、前記接合用組成物を焼成することで前記基板と前記LED(発光ダイオード)チップとを接合させる場合において、
前記基板と前記LED(発光ダイオード)チップとの略全界面に前記接合用組成物の焼成層が形成し、
前記LED(発光ダイオード)チップの側面に形成される前記接合用組成物のフィレットの高さが10μm未満となること、
を特徴とする請求項1又は2に記載の接合用組成物。 - 基板にLED(発光ダイオード)チップが接合された電子部品接合体であって、
前記基板と前記LED(発光ダイオード)チップとが、請求項1〜3のうちのいずれかに記載の接合用組成物を用いて接合されていること、
を特徴とする電子部品接合体。
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