JP6053922B2 - Oil-in-water cosmetic - Google Patents

Description

  The present invention relates to an oil-in-water cosmetic.

  Conventionally, various organic ultraviolet absorbers have been used to impart a UV protection effect to cosmetics. In particular, an ultraviolet shielding powder obtained by combining an inorganic powder with an ultraviolet absorber that is an organic compound is known.

  For example, International Publication No. 2010/098249 pamphlet discloses a composite powder obtained by coating the surface of a powder serving as a base material with an organic compound having an ultraviolet absorbing ability. This composite powder is a composite of an organic compound having an ultraviolet absorbing ability and an inorganic pigment having an ultraviolet scattering ability, and is a powder that can be stably incorporated into cosmetics and has a high ultraviolet absorbing ability. It is described that it is an organic ultraviolet absorber that maintains its effect and has good dispersibility. As such a composite powder, a composite powder in which butylmethoxydibenzoylmethane is coated on the surface of fine particle titanium oxide is disclosed.

  In addition, in Japanese translations of PCT publication No. 2003-528027, a light shielding preparation for imparting an ultraviolet ray preventing effect is selected from organic UV filter components in a solid form in a standard state, alkyl glucosides having a specific structure, and the like. Cosmetic or dermatological W / O emulsions containing nonionic surfactants, silicone emulsifiers and the like are disclosed.

However, when formulating a powder having a butyl methoxy di benzoyl methane to the surface emulsion, which may cause aggregation emulsion in over time. Also, in the cosmetic use, including emulsion blended composite powder having a butyl methoxy di benzoyl methane on the surface, freshness during application, there may feeling of stickiness and the like after the coating is impaired.
Furthermore, in cosmetics containing an emulsion, it is desirable to apply an oil-in-water emulsion rather than a water-in-oil emulsion in order to suppress a decrease in feeling of use such as stickiness after application. For this reason, the request | requirement with respect to cosmetics which has the temporal stability and the usability | use_condition while having an ultraviolet-ray shielding effect is increasing.

  An object of the present invention is to provide an oil-in-water cosmetic having a high ultraviolet shielding effect, excellent temporal stability, and excellent usability.

The present invention includes the following aspects .
[1] comprises at least one selected from titanium oxide and the group consisting of zinc oxide, and, 4-tert-butyl-4 '- and the surface-treated powder having a methoxy di benzoyl methane to the surface, dilauroyl glutamate lysine at least one compound selected from salts and polyquaternium -65, silicone oil, ester oil, and at least one oil agent selected from the group consisting of hydrocarbon oils and vegetable oils, and water, only containing, oil-in-water The content of the surface-treated powder in the mold cosmetic is 1% by mass to 30% by mass, the content of the compound in the oil-in-water cosmetic is 0.1% by mass to 5% by mass, Oil- in- water cosmetics in which surface-treated powder is contained in the aqueous phase .
[2] The oil-in-water cosmetic according to [1], further comprising at least one copolymer containing acryloyldimethyltaurine salt as a copolymerization component.
[3] The acrylic least one copolymer containing acryloyl dimethyl taurate as a copolymerization component, ammonium acryloyldimethyltaurate / vinylpyrrolidone copolymers, acrylic acid Na / acryloyldimethyltaurate Na copolymers, and ammonium acryloyldimethyltaurate / methacrylic acid Behenez-25 The oil-in-water cosmetic according to [2 ], which is at least one selected from the group consisting of cross polymers.
[4] The ratio of the oil phase / water phase in the oil-in-water emulsion composition is any one of [1] to [3] in a range of 0.5 / 99.5 to 30/70 on a mass basis. The oil-in-water cosmetic described.

  ADVANTAGE OF THE INVENTION According to this invention, the oil-in-water type cosmetics provided with the high ultraviolet-ray shielding effect, the outstanding temporal stability, and the outstanding usability can be provided.

Oil-in-water type cosmetic composition of the present invention, (a) comprises at least one member selected from the group consisting of titanium oxide and zinc oxide, and, 4-tert-butyl-4 '- having a methoxy di benzoylmethane surface Selected from the group consisting of a surface-treated powder, (b) at least one compound selected from dilauroylglutamic acid lysine salt and polyquaternium-65, and (c) silicone oil, ester oil, hydrocarbon oil and vegetable oil. At least one oil agent; and (d) water.

The oil-in-water type cosmetic composition of the present invention, 4-tert-butyl-4 '- methoxy-di benzoyl methane and predetermined surface-treated powder having the surface, dilauroyl glutamate lysine, from dilauroyl glutamate lysine salt and polyquaternium -65 By including a combination of at least one selected compound and at least one oil selected from the group consisting of silicone oil, ester oil, hydrocarbon oil and vegetable oil, a high ultraviolet shielding effect and excellent aging Stability and excellent usability are obtained.

That, 4-tert-butyl-4 '- considered specific surface-treated powder having a methoxy di benzoyl methane on the surface is a surface-treated powder having a high ultraviolet shielding ability, tend to produce an aggregate It is done. In the oil-in-water cosmetic of the present invention, at least one compound selected from dilauroyl glutamate lysine, dilauroyl glutamate lysine salt and polyquaternium-65, and a group consisting of silicone oil, ester oil, hydrocarbon oil and vegetable oil By containing at least one selected oil agent, the dispersibility of the specific surface-treated powder is improved, the aging stability of the cosmetic is improved, and further, the feeling of use of the cosmetic is increased accordingly. Presumed to increase.

In addition, when the surface-treated powder is contained in an oil-in-water cosmetic, particularly when the surface-treated powder is contained in an aqueous phase, it is generally said that it is easy to feel powdery and squeaky. The surface-treated powder of the present invention, 4-tert-butyl-4 shows the hydrophobic '- for surface treatment using the methoxy-di benzoyl methane has been subjected, prone to aggregation, such a surface treatment There is a risk that the cosmetics containing the powder will deteriorate in use feeling. However, in the present invention, since at least one compound selected from dilauroyl glutamic acid lysine salt and polyquaternium-65 is blended with the surface-treated powder, these compounds are present on the surface of the surface-treated powder. -tert- butyl-4 '- by the methoxydipropylene benzoylmethane interact, with markedly improve the dispersibility of the surface-treated powder, it is considered possible to impart good feeling in cosmetics .
However, the present invention is not bound by a specific theory.

In this specification, the term “process” is not limited to an independent process, and is included in the term if the intended effect of the process is achieved even when it cannot be clearly distinguished from other processes. .
In the present specification, a numerical range indicated by using “to” indicates a range including the numerical values described before and after “to” as the minimum value and the maximum value, respectively.
Further, in the present specification, the amount of each component in the composition is the total amount of the plurality of substances present in the composition unless there is a specific indication when there are a plurality of substances corresponding to each component in the composition. Means.

  In the present invention, the “oil phase component” is a component capable of preparing an oil phase composition by combining with an oil agent when preparing an oil-in-water cosmetic, and the oil droplets of the oil-in-water cosmetic It means a component that can be dispersed or dissolved therein. In the present invention, the “water phase component” is a component capable of preparing an aqueous phase composition by combining with an aqueous medium such as water when preparing an oil-in-water cosmetic, It means an ingredient (excluding oil droplets) that can be present in a dispersed or dissolved state in the water phase of the type cosmetic.

In the present invention, “stability over time” means that, when a cosmetic is produced and time passes, a change in physical properties of the cosmetic is suppressed. For example, in the present invention, the change in physical properties includes aggregation of the surface-treated powder, or phase separation and / or gelation in the emulsion.
The present invention will be described below.

Oil-in-water type cosmetic composition of the present invention comprises at least one member selected from the group consisting of titanium oxide and zinc oxide, and, 4-tert-butyl-4 '- surface-treated powder having a methoxy di benzoyl methane on the surface A body, at least one compound selected from dilauroylglutamic acid lysine salt and polyquaternium-65, and at least one oil selected from the group consisting of silicone oil, ester oil, hydrocarbon oil and vegetable oil. , Containing other ingredients as needed.

(A) Surface-treated powder The surface-treated powder in the present invention contains at least one selected from the group consisting of titanium oxide (TiO ₂ ) and zinc oxide (ZnO), and 4-tert-butyl-4 '- methoxy di benzoyl methane, the surface-treated powder having the surface. Surface treatment powder, 4-tert-butyl-4 '- because it contains a methoxy di benzoyl methane, has a high ultraviolet shielding ability.

Surface treated powder comprises at least one member selected from the group consisting of titanium oxide and zinc oxide, 4-tert-butyl-4 '- methoxy-di benzoyl methane and ultraviolet shielding wavelength region is different by ultraviolet protective effect From the viewpoint, titanium oxide is preferable. In this specification, at least one selected from the group consisting of titanium oxide and zinc oxide may be collectively referred to as “inorganic powder”.
The crystal form of titanium oxide may be any of anatase, rutile, brookite and the like. The crystal type of titanium oxide is preferably a rutile type. When the crystal type is a rutile type, ultraviolet rays can be shielded more effectively.
Zinc oxide is preferably one having a wurtzite crystal structure.
If the inorganic powder is generally used in cosmetics, it may have a spherical shape, a plate shape, a needle shape, a haze shape, a particle size such as a fine particle, a pigment grade, a porous or non-porous particle structure, etc. It can be used without any particular limitation.

  The average primary particle diameter of the inorganic powder is preferably 200 nm or less from the viewpoint of ultraviolet shielding ability. The average primary particle diameter of the inorganic powder is preferably 1 nm to 90 nm, more preferably 5 nm to 50 nm, from the viewpoint of the transparency of the cosmetic and the feeling of use. The average primary particle size of the inorganic powder is equivalent to a circle after dispersing the inorganic powder, taking 1000 or more images with a transmission electron microscope, performing image processing on each imaged particle with an image analysis type particle size distribution measuring device The average value of the diameters is taken. When using a commercial item, the average primary particle diameter in a commercial item can be applied as it is.

  Examples of the inorganic powder include those treated with an inorganic substance such as aluminum oxide, silicon oxide and zirconium oxide, and those treated with an organic substance such as stearic acid in order to suppress the surface activity of the inorganic powder. Can be used. Hydrophobic treatment such as silicone treatment, fatty acid treatment, metal soap treatment, fluorine treatment, etc., or hydrophilic treatment such as polyacrylic acid treatment on inorganic powder surface-treated with inorganic material or inorganic powder surface-treated with organic matter What was obtained by performing can also be used.

Surface treatment powder, 4-tert-butyl-4 '- having a methoxy di benzoyl methane to the surface. Surface treatment powder, 4-tert-butyl-4 '- it is preferable methoxy di benzoyl methane has the entire of the outermost surface. However, on the outermost surface of the surface-treated powder, without impairing the effect of the present invention, 4-tert-butyl-4 '- may be a portion having no methoxy-di benzoyl methane. Surface treated powder surface (if the inorganic powder is further surface-treated with inorganic or organic, in which inorganic or organic disposed on the surface) and, 4-tert-butyl-4 '- methoxy-di benzoyl methane binding mode of a, 4-tert-butyl-4 '- methoxy-di benzoyl methane, and the inorganic powder is not particularly limited as long as it behaves integrally. The bonding mode may be a chemical bond such as a covalent bond or a non-chemical bond such as adsorption.
The presence of 4-tert-butyl- 4′ -methoxydibenzoylmethane on the surface of the surface-treated powder means that ethanol is added to the surface-treated powder and stirred, and the absorbance at 355 nm wavelength of the supernatant is measured spectrophotometrically. This can be confirmed by measuring using a meter.

The average particle size of the surface-treated powder is preferably less than 1 μm. If the average particle diameter of the surface-treated powder is less than 1 μm, it is considered that coloring of the cosmetic by the surface-treated powder itself tends to be suppressed and so-called whitening does not occur. The average particle diameter of the surface-treated powder is preferably 1 nm to 500 nm, and more preferably 3 nm to 100 nm, from the viewpoints of ultraviolet shielding ability and usability.
The average particle diameter of the surface-treated powder can be measured by the same method as the above-mentioned average primary particle diameter.

  Examples of the surface-treated powder include those disclosed in International Publication No. 2010/098249 pamphlet. As the surface-treated powder, commercially available products such as HXMT-100ZA (manufactured by Teika), HXMT-10EXA (manufactured by Teika), HXLT-02 (manufactured by Teika) and the like can be used.

The content of the surface-treated powder in the oil-in-water cosmetic of the present invention is not particularly limited, but is preferably 0.1% by mass to 30% by mass. When the surface-treated powder is used in a content within this range, an oil-in-water cosmetic that is excellent in use feeling such as elongation spread at the time of application and has better stability with time can be obtained.
The content of the surface-treated powder is more preferably 1% by mass to 30% by mass, and further preferably 1% by mass to 20% by mass, from the viewpoints of ultraviolet shielding performance, stability over time, and usability. .

The surface-treated powder is contained in the oil phase or water phase of the oil-in-water cosmetic. From the viewpoint of usability, the surface-treated powder is preferably contained in the aqueous phase.
That the surface-treated powder is contained in the oil phase means that the surface-treated powder is dispersed in the oil droplets of the oil-in-water cosmetic. That the surface-treated powder is contained in the water phase means that the surface-treated powder is dispersed in the water phase of the oil-in-water cosmetic.

  When the oil-in-water cosmetic contains the surface-treated powder in the aqueous phase, for example, the surface-treated powder may be directly blended with other components in the aqueous phase composition, water, 1,3-butylene glycol, etc. An aqueous slurry containing the surface-treated powder may be prepared using the aqueous medium as a dispersion medium, and blended with other components in the form of a slurry.

  When the oil-in-water cosmetic contains the surface-treated powder in the oil phase, for example, a volatile oil such as silicone oil is used as a dispersion medium to prepare an oil-based slurry containing the surface-treated powder. You may mix with an ingredient.

  The content of the surface-treated powder in the aqueous slurry or oily slurry is not particularly limited, but is generally preferably 10% by mass to 80% by mass, and preferably 20% by mass to 60% by mass with respect to the total mass of the slurry. More preferred. If the content of the surface-treated powder is 10% by mass or more, it is preferable because the surface-treated powder can be more stably blended into the oil-in-water cosmetic. If the content of the surface-treated powder is 20% by mass to 60% by mass, it is preferable because the surface-treated powder can be further stably blended into the oil-in-water cosmetic.

(B) At least one compound selected from dilauroylglutamic acid lysine salt and polyquaternium-65 The oil-in-water cosmetic of the present invention is at least one compound selected from dilauroylglutamic acid lysine salt and polyquaternium-65 ( Hereinafter, it may be simply referred to as “b component”).

  The b component dilauroylglutamic acid lysine salt and polyquaternium-65 are both water-soluble components that are anionic and amphiphilic. In the oil-in-water cosmetic of the present invention, the dispersibility and dispersion stability of the surface-treated powder (component a) are further improved by selectively including the component b together with the component c described later. Aggregation of the surface-treated powder is effectively suppressed. Thereby, it is thought that the oil-in-water cosmetic of the present invention improves both high ultraviolet shielding ability and excellent temporal stability, and further improves the feeling of use.

  As the component b, any one type may be used alone, or two or more types may be used in combination.

<Dilauroyl glutamic acid lysine salt>
The dilauroyl glutamic acid lysine salt is not particularly limited as long as it is a salt of a compound obtained by reacting lysine with N-lauroyl-L-glutamic acid. Examples of the dilauroyl glutamic acid lysine salt include dilauroyl glutamic acid lysine Na.
One kind of dilauroylglutamic acid lysine salt may be used alone, or two or more kinds may be used in combination.
As the dilauroyl glutamic acid lysine salt, a commercially available product may be used. Examples of commercially available products are Perisea L-30 (29% aqueous dispersion of dilauroyl glutamic acid ricin Na, manufactured by Asahi Kasei Chemicals Corporation), Pericea LB-10 (aqueous dispersion containing 10% BG of dilauroyl glutamic acid ricin Na) Etc.

<Polyquaternium-65>
Polyquaternium-65 is a quaternary ammonium salt consisting of methacryloyloxyethylene phosphorylcholine, butyl methacrylate and sodium methacrylate.
A commercially available product may be used as polyquaternium-65. Examples of commercially available products include Lipidure-A (aqueous dispersion, manufactured by NOF Corporation).

  The total content of component b in the oil-in-water cosmetic is preferably 0.01% by mass to 20% by mass, and 0.05% by mass from the viewpoints of dispersibility and dispersion stability of the surface-treated powder and feeling of use. 10 mass% is more preferable, 0.1 mass%-5 mass% is still more preferable.

(C) At least one oil selected from the group consisting of silicone oil, ester oil, hydrocarbon oil and vegetable oil The oil-in-water cosmetic of the present invention is a group consisting of silicone oil, ester oil, hydrocarbon oil and vegetable oil. It contains at least one kind of oil selected from the following (hereinafter sometimes simply referred to as “component c”).
As the component c, any one type may be used alone, or two or more types may be used in combination.
In the oil-in-water cosmetic of the present invention, a mode in which silicone oil and ester oil are used in combination is more preferable.

<Silicone oil>
The silicone oil is not particularly limited as long as it is a silicone oil that can be applied to cosmetics.
Examples of silicone oils include linear polysiloxanes (eg, dimethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane, etc.); cyclic polysiloxanes (eg, cyclopentasiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane) , Dodecamethylcyclohexasiloxane, etc.), silicone resin, silicone rubber, various modified polysiloxanes (amino-modified polysiloxane, polyether-modified polysiloxane, alkyl-modified polysiloxane, fluorine-modified polysiloxane forming a three-dimensional network structure) Etc.) and acrylic silicones.
A commercially available product may be used as the silicone oil.

<Ester oil>
The ester oil is not particularly limited as long as it is an ester oil applicable to cosmetics.
Examples of ester oils include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyl decyl dimethyloctanoate, cetyl lactate, lactic acid Myristyl, lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexanoate, dipentaerythritol fatty acid ester, monoisostearate N-alkyl glycol, neopentyl glycol dicaprate, Diisostearyl malate, glycerin di-2-heptylundecanoate, trimethylolpropane tri-2-ethylhexanoate, Trimethylolpropane phosphate, pentaerythritol tetra-2-ethylhexanoate, glycerin tri-2-ethylhexanoate, glycerin trioctanoate, glyceryl triisopalmitate, trimethylolpropane triisostearate, cetyl 2-ethylhexanoate, 2-ethylhexyl palmitate, glyceryl trimyristate, tri-2-heptylundecanoic acid glyceride, castor oil fatty acid methyl ester, oleyl oleate, acetoglyceride, 2-heptylundecyl palmitate, diisobutyl adipate, N-lauroyl-L -Glutamic acid-2-octyldodecyl ester, di-2-heptylundecyl adipate, ethyl laurate, di-2-ethylhexyl sebacate, 2-hexyldemyristate Le, palmitic acid 2-hexyl decyl, 2-hexyldecyl adipate, diisopropyl sebacate, 2-ethylhexyl succinate, and triethyl citrate.
A commercially available product may be used as the ester oil.

<Hydrocarbon oil>
The hydrocarbon oil is not particularly limited as long as it is a hydrocarbon oil applicable to cosmetics.
The hydrocarbon oil may be a hydrocarbon oil derived from a natural product or a hydrocarbon oil obtained by synthesis.
Examples of hydrocarbon oils include liquid paraffin, squalane, isododecane, isohexadecane, ozokerite, pristane, paraffin, ceresin, squalene, petrolatum, microcrystalline wax, polyethylene wax, and Fischer Tropus wax.
Commercial products may be used as the hydrocarbon oil.

<Vegetable oil>
The vegetable oil is not particularly limited as long as it is a vegetable oil that can be applied to cosmetics. As the vegetable oil, an oil component extracted from a plant may be used as it is, an oil component obtained by further purifying an oil component extracted from a plant, or an oil component obtained by hydrogenating an oil component extracted from a plant. It may be present or a derivative derived from these oil components.
Examples of vegetable oils include olive oil, camellia oil, macadamia nut oil, castor oil, avocado oil, evening primrose oil, corn oil, rapeseed oil, sesame oil, persic oil, wheat germ oil, sasanqua oil, linseed oil, safflower oil, cottonseed oil, Eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnagiri oil, Japanese kiri oil, jojoba oil, germ oil, palm oil, coconut oil, peanut oil, almond oil, hazelnut oil, walnut oil , Grape seed oil and the like.
A commercial product may be used as the vegetable oil.

  The total content of component c in the oil-in-water cosmetic is preferably 0.1% by mass to 50% by mass, more preferably 0.5% by mass to 40% by mass, from the viewpoint of usability, and 1% by mass to 30 mass% is still more preferable.

  The content ratio (d / c, based on mass) of the c component and the d component in the oil-in-water cosmetic is preferably 0.5 to 800, more preferably 1 to 100, from the viewpoint of fresh usage. 50 is more preferable.

(D) Water The oil-in-water cosmetic of the present invention contains water.
The water contained in the oil-in-water cosmetic of the present invention is not particularly limited as long as it is water applicable to cosmetics. In the cosmetic of the present invention, water is included as one of the components contained in the aqueous phase composition constituting the aqueous phase.

As content of the water in the oil-in-water cosmetic of this invention, 1 mass%-90 mass% are preferable with respect to the total mass of cosmetics, 10 mass%-80 mass% are more preferable, 30 mass%- 70 mass% is still more preferable.
Moreover, as content of the water with respect to the total mass of an aqueous phase composition, 30 mass%-95 mass% are more preferable, 40 mass%-90 mass% are more preferable, 45 mass%-85 mass% are still more preferable.

(E) Copolymer containing acryloyldimethyltaurine salt as copolymerization component The oil-in-water cosmetic of the present invention may contain at least one copolymer containing acryloyldimethyltaurine salt as a copolymerization component. At least one copolymer containing acryloyldimethyltaurine salt as a copolymerization component improves the dispersibility and dispersion stability of the surface-treated powder, and improves the stability over time and the feeling of use of the oil-in-water cosmetic. Increase.

  Examples of the acryloyldimethyltaurine salt as a copolymerization component include an inorganic salt or an organic salt of acryloyldimethyltaurine. Examples of inorganic salts include lithium salts, sodium salts, potassium salts, magnesium salts, calcium salts, aluminum salts, ammonium salts, and the like. Examples of the organic salt include a monoalkyl ammonium salt, a dialkyl ammonium salt, a trialkyl ammonium salt, and a tetraalkyl ammonium salt. Examples of the alkyl substituent of the amine include an alkyl group having 1 to 22 carbon atoms and a hydroxyalkyl group having 2 to 10 carbon atoms.

  Other copolymerization components that can constitute a copolymer with acryloyldimethyltaurate salt include N-vinylpyrrolidone (VP); inorganic salts of acrylic acid and methacrylic acid, such as sodium salts and ammonium salts; polyoxyethylene behenyl ether Methacrylic acid esters, for example, esters with Behenes-5, Behenes-10, Behenes-15 or Behenes-25.

  From the viewpoint of the salt resistance of cosmetics, the copolymer containing acryloyldimethyltaurine salt as a copolymerization component includes acryloyldimethyltaurine ammonium / vinylpyrrolidone copolymer, Na acrylate / acryloyldimethyltaurine Na copolymer, and (acryloyldimethyltaurine ammonium). / Beheneth-25 methacrylic acid is preferably at least one selected from the group consisting of cross polymers.

  In the oil-in-water cosmetic, the total content of the copolymer containing acryloyldimethyltaurine salt as a copolymerization component is the amount of polymer (pure) from the viewpoint of cosmetic stability over time and use feeling. It is preferably 0.01% by mass to 8% by mass, more preferably 0.05% by mass to 5% by mass, and 0.1% by mass to 2% by mass with respect to the total mass of Is more preferable. If it is in this range, it will be excellent in the stability with time of cosmetics, and the elongation at the time of application | coating to skin will be good, It will be fresh after application | coating and it will tend to be excellent in skin familiarity.

(F) Other components The oil-in-water cosmetic of the present invention may contain other oil phase components and water phase components other than water, if necessary, in addition to the above components.

(Surfactant)
The oil-in-water cosmetic of the present invention can contain a surfactant as long as the effects of the present invention are not impaired. The surfactants shown below do not include the components b to e in the present invention.
Surfactants (hereinafter simply referred to as “surfactants” unless otherwise specified) include anionic surfactants, cationic surfactants and ionic surfactants of amphoteric surfactants and nonionic surfactants. Any of surfactants may be used. Examples of the ionic surfactant include alkyl sulfonate, alkyl sulfate, monoalkyl phosphate, lecithin and the like. Examples of nonionic surfactants include sorbitan fatty acid ester, glycerin fatty acid ester, organic acid monoglyceride, polyglycerin fatty acid ester, propylene glycol fatty acid ester, polyglycerin condensed ricinoleic acid ester, sucrose fatty acid ester, polyethylene glycol fatty acid ester, Polyoxyethylene alkyl ether, polyoxypropylene alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitol fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene propylene Examples include glycol fatty acid esters.

  The content of the surfactant is preferably 0.01% by mass to 30% by mass of the total mass of the cosmetic, more preferably 0.05% by mass to 20% by mass, and 0.1% by mass to More preferably, it is 10 mass%. If the content of the surfactant is 0.01% by mass or more, the aging stability of the cosmetic tends to be improved, and if it is 30% by mass or less, the feeling of use tends to be improved.

(fatty acid)
The oil-in-water cosmetic can contain a fatty acid. By containing a fatty acid, the temporal stability and usability of the cosmetic can be further improved.
The fatty acid may be either a saturated or unsaturated fatty acid. The fatty acid may be a linear or branched fatty acid. Although there is no restriction | limiting in particular as the total carbon number of a fatty acid, From a viewpoint of temporal stability of a cosmetics and a usability | use_condition, it is preferable that it is total carbon number 8-total carbon number 20, and total carbon number 10-total carbon number. 18 is more preferable. Of these, linear unsaturated fatty acids, branched saturated fatty acids, or branched unsaturated fatty acids are preferred from the viewpoint of the temporal stability of the cosmetic and the feeling of use.

  Examples of fatty acids include caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid, isostearic acid, coconut oil fatty acid, arachidonic acid, undecylenic acid, etc. Can do. Among these, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, linolenic acid, isostearic acid and the like can be mentioned in terms of the stability over time and the feeling of use of the cosmetic. Each fatty acid may be used alone or in combination of two or more.

  The content of the fatty acid is preferably 0.01% by mass to 20% by mass of the total mass of the cosmetic, more preferably 0.5% by mass to 10% by mass, and 0.5% by mass to 5% by mass. % Is more preferable. If the fatty acid content is 0.01% by mass or more, there is a tendency to improve the temporal stability of the cosmetic, and if it is 20% by mass or less, the dispersibility of the surface-treated powder tends to be improved. is there.

(4-tert-butyl-4 '- methoxy-di benzoyl methane other than ultraviolet absorber)
Oil-in-water cosmetic, within a range not to impair the effects of the present invention, 4-tert-butyl-4 described above '- it can contain methoxydipropylene benzoylmethane other UV absorber.
As such other ultraviolet absorbers, any known oil-soluble or water-soluble ones can be used.

  Examples of oil-soluble UV absorbers include paraaminobenzoic acid, methyl paraaminobenzoate, glyceryl paraaminobenzoate, amyl paradimethylaminobenzoate, octyl paradimethylaminobenzoate, ethylene glycol salicylate, phenyl salicylate, octyl salicylate, butylphenyl salicylate, Homomentyl salicylate, octyl methoxycinnamate, ethoxyethyl methoxycinnamate, hexylhexyl methoxycinnamate, glyceryl monoethylhexanoate dimethoxycinnamate, hydroxymethoxybenzophenone, dihydroxydimethoxybenzophenone, butylmethoxybenzoylmethane, octyl triazone, etc. Can be mentioned.

  Examples of water-soluble ultraviolet absorbers include benzophenone ultraviolet absorbers such as 2,4-dihydroxybenzophenone and 2,2′-dihydroxy-4-methoxybenzophenone; phenylbenzoimidazole-5-sulfonic acid and its salts, phenylenebisbenzimidazole Benzimidazole ultraviolet absorbers such as tetrasulfonic acid and its salts; urocanic acid, urocanic acid ethyl ester, 2,2- (1,4-phenylene) bis- (1H-benzimidazole-4,6-disulfonic acid), Examples include terephthalylidene dicamphorsulfonic acid.

The content of UV absorbers other than 4-tert-butyl- 4′ -methoxydibenzoylmethane is 0.001% to 30% by mass of the total mass of the cosmetic in terms of supplementing UV protection performance. Is preferable, 0.01 mass% to 20 mass% is more preferable, and 0.1 mass% to 10 mass% is still more preferable. 4-tert-butyl-4 '- methoxy-di benzoyl If the other ultraviolet absorbers other than methane used in a range that does not impair the effects of the present invention, 4-tert-butyl-4' - other for methoxydipropylene benzoylmethane The ratio of other ultraviolet absorbers other than may be 0.01% by mass to 10% by mass, and may be 0.1% by mass to 8% by mass.
The total amount of the ultraviolet absorber in the oil-in-water cosmetic is preferably 0.001% to 70% by mass, and 0.01% to 50% by mass with respect to the total mass of the cosmetic in terms of usability. It is more preferable that it is 0.1 mass%-30 mass%.

(Polyhydric alcohol)
The oil-in-water cosmetic can contain a polyhydric alcohol. By including the polyhydric alcohol, it is possible to improve the feeling of use (humidity retention).
Examples of the polyhydric alcohol include glycerin, 1,3-butanediol, ethylene glycol, or polysaccharides such as reduced starch syrup, sucrose, erythritol, xylitol, glucose, galactose, sorbitol, maltotriose, trehalose, and the like. Can be mentioned. A polyhydric alcohol can be used individually by 1 type or in combination of 2 or more types.

  The content of the polyhydric alcohol is preferably 0.01% by mass to 20% by mass, and preferably 0.05% by mass to 10% by mass with respect to the total mass of the cosmetic in terms of imparting moisture retention. It is more preferable that the content is 0.1% by mass to 10% by mass.

(Other ingredients)
The oil-in-water cosmetic can contain other components usually used in cosmetics based on the application. Examples of such other components include water-soluble organic solvents such as ethanol, chelating agents, whitening agents, emollients such as triisodecyl isononanoate, moisturizers, antioxidants, hydrophilic thickeners such as agar and xanthan gum. , Coloring agents, preservatives, fragrances, various oil components, various aqueous components, and the like.

(Production method)
The oil-in-water cosmetic can be produced by a production method including mixing an oil phase composition containing the above-described components and an aqueous phase composition and emulsifying by a conventional method.
When blending the surface-treated powder as an oil phase component, the surface-treated powder is combined with other oil phase components to prepare an oil phase composition, and the obtained oil phase composition and aqueous phase composition are combined. An oil-in-water cosmetic can be produced in combination.
When blending the surface-treated powder as an aqueous phase component, prepare the aqueous phase composition by combining the surface-treated powder with other aqueous phase components, and combine the resulting aqueous phase composition and oil phase composition. Thus, an oil-in-water cosmetic can be produced. Alternatively, an aqueous phase composition that does not include surface-treated powder is prepared, and the obtained aqueous phase composition is combined with an oil phase composition to prepare a preliminary oil-in-water composition that does not include surface-treated powder. The oil-in-water cosmetic can be produced by adding the surface-treated powder to the aqueous phase of the obtained preliminary oil-in-water composition. When adding the surface-treated powder to the water phase of the preliminary oil-in-water composition, the surface-treated powder may be added alone or in combination with other water phase components. The surface-treated powder may be added as a component of the obtained aqueous phase composition.

An emulsification method for obtaining an oil-in-water cosmetic as an oil-in-water emulsion by combining the oil phase composition and the water phase composition is not particularly limited, and can be performed according to a conventional method.
The ratio (mass) of the oil phase composition and the aqueous phase composition when preparing the emulsion is not particularly limited, and is 0.1 / 99.9 as the oil phase / water phase ratio (mass%). -50/50 is preferable, 0.5 / 99.5-30 / 70 is more preferable, and 1 / 99-20 / 80 is still more preferable.

(Form)
There are no particular restrictions on the form of the oil-in-water cosmetic, and lotions, emulsions, creams, eye creams, cosmetics, massages, packs, sprays, ointments, body creams, and other skin care cosmetics and makeup. Examples include makeup cosmetics such as foundations, and scalp cosmetics such as leave on essence.
The oil-in-water cosmetic of the present invention is particularly preferably used as a sunscreen cosmetic because it has a good ultraviolet shielding ability and a good feeling of use.

(Feeling of use)
The oil-in-water cosmetic of the present invention exhibits an excellent feeling of use. In the present invention, the feeling of use means, for example, freshness at the time of application and no stickiness after application. Freshness at the time of application means that the formulation is separated when applied and a change occurs in which water oozes out. The non-stickiness after application means that the feel of the application part after spreading the cosmetic does not tend to stick as much as when water is applied instead of the cosmetic.

  Hereinafter, the present invention will be described in detail with reference to examples. However, the present invention is not limited to them.

[Example 1 to Example 6]
The oil phase composition and the water phase composition are prepared using the a component, the b component, the c component, the d component, the e component, and other components so that the final concentrations (% by mass) shown in Table 1 and Table 3 are obtained. The oil phase composition and the obtained oil phase composition and water phase composition were emulsified by a conventional method to obtain an oil-in-water cosmetic.
In Examples 1 to 6, a half of the a component and the b component, 1,3-butylene glycol, and purified water were combined and dispersed, and the aqueous phase containing the surface-treated powder in combination with other aqueous phase components A composition was prepared and warmed to 80 ° C. The oil phase components were combined and mixed to prepare an oil phase composition and heated to 80 ° C. Then, the oil phase: water phase = 12.5: 87.5 ratio (mass ratio), the water phase composition and the oil phase composition were combined and emulsified under conditions of 80 ° C. and homomixer 5000 rpm for 5 minutes. The oil-in-water cosmetic was obtained.
Details of each component described in Table 1, Table 2, and Table 3 will be described later.
The types and amounts of common components 13 to 22 shown in Table 1 and Table 3 are as shown in Table 2.

[Comparative Examples 1 to 5]
In the oil-in-water cosmetic of Example 1, No. 1 described in Table 1 was used instead of dilauroylglutamate lysine Na (component b). An oil-in-water cosmetic was obtained in the same manner as in Example 1 except that 5 to 9 comparative compounds were used.

[Comparative Examples 6 to 29]
In the oil-in-water cosmetic of Example 1, instead of polyquaternium-65 (component b), the comparative compound described in Table 4 was added in the amount (1% by mass) described in Table 3, and further, Na / Acrylate An oil-in-water cosmetic was obtained in the same manner as in Example 1 except that the amount (0.6% by mass) shown in Table 3 was added to the acryloyldimethyltaurine Na copolymer (component e).
Details of each component described in Table 4 will be described later.

[Examples 7 to 9]
In the oil-in-water cosmetic of Example 1, common component Nos. In place of 19 sorbitan oleate, No. 1 shown in Table 5 An oil-in-water cosmetic was obtained in the same manner as in Example 1 except that 23 to 25 fatty acids were added in the amounts shown in Table 5 (0.5% by mass).
Details of each component described in Table 5 will be described later.

[Evaluation]
The following evaluation was performed using each test sample fractionated from the oil-in-water cosmetics of Examples 1 to 9 and Comparative Examples 1 to 29 obtained above. The evaluation results are shown in Table 6.

(1) Evaluation of stability over time Regarding the stability over time of each test sample of Examples 1 to 9 and Comparative Examples 1 to 29, “dispersion stability over time” and “time stability of emulsion (gelation) ) ”From two viewpoints.

(1-1) Dispersion stability over time 50 g of each test sample of Examples 1 to 9 and Comparative Examples 1 to 29 was taken in a vial and subjected to an accelerated test for one month in a 50 ° C. thermostat. It was. The sample after the acceleration test was observed with an optical microscope, and the presence or absence of an aggregate and the emulsified state were visually evaluated based on the following criteria.
In the following index, it is judged that “aggregates are recognized” when a plurality of black lumps of 10 μm or more can be confirmed in the visual field, and “slight agglomerates” when the size of black lumps is 10 μm to 50 μm. It is determined that “a large aggregate is recognized” when the size of the black block exceeds 50 μm.
Also, if oil droplets (emulsified particles) of less than 1 μm (major axis) are uniformly distributed in the field of view and no other particles are confirmed, it is judged as “a very uniform emulsified state as a whole”. When the dispersion of oil droplets (emulsified particles) of less than 1 μm (major axis) is slightly biased, it is judged as “uniformly emulsified state”, and when there are oil droplets (emulsified particles) that vary in size, or oil When there is a large bias in the dispersion of the droplets (emulsified particles), it is judged as “a non-uniform emulsified state”.
AA: There is no aggregate and it is a very uniform emulsified state as a whole.
A: There is no aggregate and it is a uniform emulsified state.
B: Although a slight aggregate is recognized, it is a uniform emulsified state.
C: Slight agglomerates are observed and the emulsion is in a non-uniform emulsified state.
D: Large aggregates are observed.

(1-2) Stability over time of emulsion (gelation)
50 g of each test sample of Examples 1 to 9 and Comparative Examples 1 to 29 was taken in a vial and subjected to an acceleration test in a thermostatic bath at 50 ° C. For the sample subjected to the test, as an evaluation of the stability of the emulsion, the presence or absence of gelation and phase separation was observed after 1 week (hereinafter simply referred to as “1 week later”) and 1 month after the start of the test. (Hereinafter, simply referred to as “after one month”), and evaluated based on the following criteria.
The presence or absence of gelation was evaluated by scooping the sample with a spatula and visually observing whether the sample was solidified.
Phase separation is performed by visually observing the top surface of the sample from the outside of the bottle and visually confirming that the liquid does not ooze from the top surface of the sample or whether the sample flows as one piece without tilting the vial. Observed and evaluated.
A: Gelation and phase separation were not observed after 1 week and 1 month. B: Gelation was not observed after 1 week and 1 month. Phase separation was not observed after 1 week, but was observed after 1 month.
C: Gelation and phase separation were not observed after one week, but were observed after one month.
D: Both gelation and phase separation were observed after 1 week.

(2) Ultraviolet shielding performance Based on the in vitro measurement method of ISO 24443, 32.5 mg of each sample of Examples 1 to 9 and Comparative Examples 1 to 29 was applied to a PMMA plate (HELIOPLATE HD6) with a uniform thickness. Then, the transmittance was measured using an SPF analyzer (UV-2000S manufactured by Labsphere), and the protective effect of UVB and UVA was evaluated according to the following criteria.
(2-1) [UVB protective effect evaluation criteria]
A: SPF value is 40 or more B: SPF value is 30 or more and less than 40 C: SPF value is 20 or more and less than 30 D: SPF value is less than 20 (2-2) [UVA protective effect evaluation criteria]
A: The transmittance at 400 nm is less than 20% B: The transmittance at 400 nm is 20% or more and less than 40% C: The transmittance at 400 nm is 40% or more and less than 70% D: The transmittance at 400 nm is 70% or more

(3) Usability Each sample 0.5 of Examples 1 to 9 and Comparative Examples 1 to 29 is used by 20 panelists specializing in cosmetics evaluation. The non-stickiness immediately after spreading over the whole was evaluated according to the following criteria.
AA: Very good A: Good B: Somewhat good C: Normal D: Poor

Comparative compounds of component a, component b, component b, component c, component e, common component No. The following were used as 13-24.
In Tables 1 to 3 and Table 5, the numerical values related to each component mean mass%.

(Component a)
· 4-tert-butyl-4 '- methoxy-di benzoyl methane-coated titanium oxide: HXMT-10EXA, Tayca Corporation (average primary particle diameter: 10 [mu] m)

(Component b and comparative compound)
-Dilauroyl glutamate lysine Na: Perisea L-30, manufactured by Asahi Kasei Chemicals Corporation-Polyquaternium-65: Lipidure-A, manufactured by NOF Corporation-Cocoglucoside: Plantacare 818, manufactured by BASF Japan-Polyquaternium-51: Lipidure-PMB, NOF CORPORATION, Polyquaternium-61: Lipidure-NA, NOF Corporation, Polyquaternium-64: Lipidure-C, NOF Corporation, laurylcarbamic acid inulin: NOF Corporation, polyhydroxystearic acid: Saracos HS-6C, manufactured by Nisshin Oillio Group, Caprylyl / Capryl Glucoside: Plantacare 2000, manufactured by BASF Japan, Decyl Glucoside: Plantacare 1000, BASF・ Lapin glucoside manufactured by Capain Corporation: Plantacare 1200, manufactured by BASF Japan Co., Ltd. ・ PPG-4 SETES-20: NIKKOL PBC-34, manufactured by Nikko Chemicals Co., Ltd. ・ PCA isosteria phosphate PEG-40 hydrogenated castor oil: PYROTER CPI-40, Nippon Emulsion Co., Ltd.-PCA isostearic acid glyceres-25: PYROTER GPI-25, Nihon Emulsion Co., Ltd. diisostearic acid polyglyceryl-10: NIKKOL Decaglyn 2-ISV, Nikko Chemicals Co., Ltd., isostearic acid PEG-20 sorbitan: NIKKOL TI-10V, manufactured by Nikko Chemicals Co., Ltd., Pseudogimatsukubaensis / olive oil / glycerin / fermented soybean protein: Surf Mellow, Toyobo Co., Ltd. -Polymethacryloyloxyethyl phosphorylcholine: Lipidure-HM, manufactured by NOF Corporation-PEG-240 / decyltetradeceth-20 / HDI copolymer: Adecanol GT-700, manufactured by ADEKA, cholesteryl pullulan hexyl dicarbamate: MEDUSEEDS -C1, manufactured by NOF Corporation, trimethylpentanediol / adipic acid copolymer: LEXOREZ 200 manufactured by Inorex, polyacrylic acid Na: Lubragel NP, manufactured by ISP Japan, acacia gum: Instant Gum AA, manufactured by Nexia, Galactarabi Nan: LARACARE A200, manufactured by Lonza, Spherical hydroxyapatite: Spherical HAP, manufactured by Taihei Chemical Industrial Co., Ltd.

・ Cyclopentasiloxane: KF-995, manufactured by Shin-Etsu Chemical Co., Ltd. ・ Octyldodecyl myristate: NIKKOL ODM-100, manufactured by Nikko Chemicals Co., Ltd.

(E component)
Na acrylate / acryloyl dimethyl taurine Na copolymer: SIMULGEL EG, SEPPIC S. Company A, acryloyldimethyltaurate ammonium / vinyl pyrrolidone copolymer: Aristoflex AVC, manufactured by Clariant Japan

・ Butylene glycol (BG): 1,3-butylene glycol, manufactured by Daicel Corporation ・ Methyl paraben: Mekins M, manufactured by Ueno Pharmaceutical Co., Ltd. ・ EDTA-2Na: Cylest 2B-SD, manufactured by Chubu Crest Corporation ・ Xanthan gum: Nomucoat Z, Japan Seioirio Group Co., Ltd., polymethylsilsesquioxane: KMP-590, Shin-Etsu Chemical Co., Ltd., sorbitan stearate: NIKKOL SS-10V, Nikko Chemicals Co., Ltd., palm oil fatty acid sucrose: Arlacel 2121, Croda Japan Co., Ltd. -Polysorbate 80: NIKKOL TO-10V, manufactured by Nikko Chemicals Co., Ltd.-Steareth-2: BRIJ S2, manufactured by Croda Japan Co., Ltd.-Ethylhexyl methoxycinnamate: Ubinal MC80, manufactured by BASF Japan-Diethylamino Nohydroxybenzoyl hexyl benzoate: Ubinal A Plus Granular, manufactured by BASF Japan

(fatty acid)
・ Capric acid: New Nippon Rika Co., Ltd. ・ Oleic acid: New Nippon Rika Co., Ltd. ・ Isostearic acid: Higher alcohol industry

As shown in Table 6, 4-tert-butyl-4 '- methoxy-di benzoyl methane-coated titanium oxide or 4-tert-butyl-4' - methoxy-di benzoyl methane-coated zinc oxide (a component), a compound of component b And the oil-in-water emulsions of Example 1 to Example 9 combined with the oil component c were found to have high UV shielding ability and excellent temporal stability and usability. It was.

  Furthermore, it was found that the stability over time of the oil-in-water cosmetic was further improved by combining a copolymer containing acryloyldimethyltaurine salt as a copolymerization component (Examples 3 to 6).

[Example 10] Milk cosmetic A milk cosmetic is prepared by a conventional method according to the following formulation. The following numerical value means the mass% with respect to the total mass of prescription.
<Composition> (mass%)
・ Ethanol 15.0
・ 1,3-Butylene glycol 7.0
・ Magnesium phosphate ascorbate appropriate amount ・ Chelating agent appropriate amount ・ Glycerin 3.0
· 4-tert-butyl-4 '- methoxy-di benzoyl methane-coated titanium oxide 8.0
・ Polyquaternium-65 1.0
・ Phenylbenzimidazolesulfonic acid 1.0
-Na acrylate / acryloyl dimethyl taurine Na
Copolymer 0.4
・ Astaxanthin 0.005
・ Sorbitan sesquiisostearate 0.6
Polyglyceryl diisostearate-10 0.7
・ Isostearic acid 0.1
PEG / PPG-19 / 19 dimethicone 1.5
・ Dimethicone 4.0
・ Cyclopentasiloxane 2.0
-Pentaerythrityl tetraethylhexanoate 3.0
・ Persic oil 0.5
・ Isododecane 0.8
Trimethylsilylsiloxysilicate 1.2
・ Ethylhexyl methoxycinnamate 3.0
2,4,6-tris [4- (2-ethylhexyloxycarbonyl)
Anilino] -1,3,5-triazine 0.1
Diethylaminohydroxybenzoyl hexyl benzoate 0.2
・ Mica 2.0
・ Kaolin 1.0
・ Ethylhexylglycerin 0.1
・ Phenoxyethanol appropriate amount ・ Purified water remaining

[Example 11] Liquid foundation A liquid foundation is prepared by a conventional method according to the following formulation. The following numerical value means the mass% with respect to the total mass of prescription.
<Composition> (mass%)
1,3-butylene glycol 11.0
Methylparaben qs-4-tert-butyl-4 '- methoxy-di benzoyl methane-coated titanium oxide 10.0
・ Dilauroyl glutamic acid ricin sodium 1.0
・ Astaxanthin 0.02
・ Sorbitan sesquioleate 1.2
Polyglyceryl diisostearate-10 1.5
Palm oil fatty acid sucrose 1.2
・ Glyceryl stearate 0.5
・ Lecithin 0.5
・ Nacrylate / acryloyldimethyltaurine Na
Copolymer 0.4
・ Isostearic acid 2.0
・ Zinc oxide 2.0
・ Cetanol 2.5
Jojoba seed oil 15.0
・ Meticon 7.0
・ Ethylhexyl methoxycinnamate 5.0
・ Methylenebisbenzotriazolyl tetramethylbutylphenol 0.2
Decyl glucoside 0.1
・ Pigment grade titanium oxide 10.0
-Stearyl glycyrrhetinate 0.1
・ Bengara 0.05
・ Yellow iron oxide 0.6
・ Black iron oxide 0.2
・ Purified water remaining

[Example 12] Sunscreen lotion spray (filled with nitrogen)
According to the following formulation, a sunscreen lotion spray (filled with nitrogen) is prepared by a conventional method. The following numerical value means the mass% with respect to the total mass of prescription.
<Composition> (mass%)
1,3-butylene glycol 3.0
・ Ethanol 5.0
Dilauroyl glutamic acid ricin sodium 1.5
· 4-tert-butyl-4 '- methoxy-di benzoyl methane-coated titanium oxide 1.5
・ Phenylbenzimidazolesulfonic acid 2.0
-Potassium hydroxide appropriate amount-Methylparaben appropriate amount-Dipotassium glycyrrhizinate 0.01
・ 1-Menthol 0.05
・ Camphor 0.02
・ Sorbitan isostearate 0.15
Polyglyceryl diisostearate-10 0.15
PEG-60 hydrogenated castor oil 0.1
・ Nacrylate / acryloyldimethyltaurine Na
Copolymer 0.01
・ Purified water remaining

[Example 13] Gel cosmetics Gel cosmetics are prepared by a conventional method according to the following formulation. The following numerical value means the mass% with respect to the total mass of prescription.
<Composition> (mass%)
・ 1,3-butylene glycol 8.0
・ Glycerin 2.0
・ Ethanol 10.0
・ Xanthan gum 0.1
・ Kanten 0.1
Dilauroyl glutamic acid ricin sodium 0.5
・ Acryloyldimethyltaurate ammonium / VP
Copolymer 0.05
· 4-tert-butyl-4 '- methoxy-di benzoyl methane-coated titanium oxide 7.0
・ Octocrylene 2.0
・ Astaxanthin 0.001
・ Sorbitan oleate 0.4
Polyglyceryl diisostearate-10 0.4
・ Hydrogenated lecithin 0.1
・ Polysilicone-15 0.1
・ Ethylhexyltriazone 0.5
・ Nylon powder 2.0
・ Perfume appropriate amount ・ Phenoxyethanol appropriate amount ・ Purified water remaining

  Thus, according to the present invention, it is possible to provide an oil-in-water cosmetic that has a high ultraviolet shielding effect, excellent temporal stability, and excellent usability.

The disclosure of Japanese Patent Application 2013-103553 filed on May 15, 2013 is incorporated herein by reference.
All documents, patent applications, and technical standards mentioned in this specification are to the same extent as if each individual document, patent application, and technical standard were specifically and individually stated to be incorporated by reference, Incorporated herein by reference.

Claims (4)

It comprises at least one selected from titanium oxide and the group consisting of zinc oxide, and, 4-tert-butyl-4 '- and the surface-treated powder having a methoxy di benzoyl methane to the surface,
At least one compound selected from dilauroylglutamic acid lysine salt and polyquaternium-65;
At least one oil selected from the group consisting of silicone oil, ester oil, hydrocarbon oil and vegetable oil;
And water, only including,
The content of the surface-treated powder in the oil-in-water cosmetic is 1% by mass to 30% by mass,
The content of the compound in the oil-in-water cosmetic is 0.1% by mass to 5% by mass,
An oil- in- water cosmetic in which the surface-treated powder is contained in an aqueous phase .   The oil-in-water cosmetic according to claim 1, further comprising at least one copolymer containing acryloyldimethyltaurine salt as a copolymerization component. At least one copolymer comprising the acryloyl dimethyl taurate salt as a copolymerization component is an acryloyl dimethyl taurine ammonium / vinyl pyrrolidone copolymer, an acrylic acid Na / acryloyl dimethyl taurine Na copolymer, and an acryloyl dimethyl taurine ammonium / beheneth methacrylate-25. The oil-in-water cosmetic according to claim 2, which is at least one selected from the group consisting of cross polymers.   The ratio of the oil phase / water phase in the oil-in-water emulsion composition is in the range of 0.5 / 99.5 to 30/70 on a mass basis, and the water according to any one of claims 1 to 3. Oil-type cosmetics.