JP6028688B2 - Printing apparatus and printing method - Google Patents

Description

  The present invention relates to a printing apparatus and a printing method for printing ink on a strip-shaped base material such as a steel strip (hereinafter referred to as a long base material).

  Conventionally, gravure offset printing is known in which a photo or painting is printed on a medium such as paper using a gravure roll in which a large number of fine concave portions (hereinafter referred to as gravure cells) constituting the printing plate are formed on the roll surface. . In gravure offset printing, ink is filled into each gravure cell of the gravure roll by drawing ink with the gravure roll. After the excess ink is scraped off from the gravure roll, the ink in each gravure cell is transferred to the offset roll, and the ink is transferred (printed) to the surface of the long substrate that is sequentially conveyed via the offset roll. By repeating these processes corresponding to the conveyance of the long base material, a desired print pattern is formed on the surface of the long base material. The pattern of the printed pattern on the surface of the long substrate is the same as the pattern represented by a number of gravure cells on the surface of the gravure roll.

  Moreover, the gravure offset printing mentioned above is performed, a resist is printed on the predetermined part of the steel strip surface as an etching prevention mask, and a portion of the steel strip surface where the resist is not printed (hereinafter referred to as a non-printing part) is etched. Thus, a method for forming a desired pattern on the surface of the steel strip is known. In general, a flat plate offset method is known as a method for printing a resist on a metal plate such as a steel strip. However, the resist printed on the metal plate by the flat plate offset method is not suitable as a resist coating for preventing etching because the coating thickness on the surface of the metal plate is thin. The photo-etching method used in the semiconductor manufacturing field is a technique that can print a resist on the surface of a metal plate with high accuracy, but the cost is high when printing the resist on the surface of a long substrate such as a steel strip. Become. In contrast to these methods, the above-described gravure offset printing makes it possible to inexpensively print a resist on the surface of a large number of long substrates. For this reason, gravure offset printing is a suitable printing method for resist printing on the steel strip surface.

  Note that a large number of the above gravure cells are formed at regular intervals on the plate surface of the gravure roll used for gravure offset printing. That is, a boundary portion that separates adjacent gravure cells exists in the formation portion of these many gravure cells. This boundary portion is a plate surface portion where ink transfer is not performed. In the part on the surface of the steel strip corresponding to such a boundary part (hereinafter referred to as a cell boundary part), there is a situation where the resist is not printed unintentionally, or the thickness of the printed resist becomes extremely thin. Can happen. For this reason, when the intentional non-printing part of the steel strip surface is etched, the cell boundary part which should not be etched may be etched. In order to solve such a problem, for example, a technique for defining the viscosity range of resist ink, the number of gravure cell meshes, and the contact length (nip width) between the offset roll and the steel strip surface is disclosed ( Patent Document 1).

Japanese Patent No. 3255498

  For example, in order to uniformly form the pattern of the target pattern on the surface of the steel strip by the etching process, unintentional etching of the portion of the steel strip surface on which the resist ink is printed is avoided and the surface of the steel strip is not printed. It is essential to make the shape of the portion (the portion to be etched) uniform. In order to achieve this, gravure offset printing is used to print resist ink on the surface of the steel strip that is not subject to etching so that there is no uneven printing and to form a uniform print pattern of resist ink. There is a need to. However, a gravure offset printing technique that can form a uniform print pattern on a surface of a long base material such as a steel strip without uneven printing has not been clarified conventionally.

  The present invention has been made in view of the above circumstances, and provides a printing apparatus and a printing method capable of realizing gravure offset printing that forms a printing pattern uniformly on a surface of a long base material without uneven printing. The purpose is to do.

In order to solve the above-described problems and achieve the object, a printing apparatus according to the present invention includes an intaglio part formed by a plurality of recesses, and a gravure roll that sequentially fills the plurality of recesses with ink, An offset roll that sequentially transfers the ink in the plurality of recesses by the gravure roll, and that sequentially prints the transferred ink on the surface of the long substrate that is continuously conveyed, The volume of the recess per unit area is 6 [cm ³ / m ² ] or more and 50 [cm ³ / m ² ] or less, and the viscosity of the ink is 150 [mPa · s] or more and 2500 [mPa · s]. s] or less, and the pressure of the offset roll applied to the surface of the long base material is 12 [kg / m] or more and 100 [kg / m] or less.

  In the printing apparatus according to the present invention, in the above invention, the gravure roll is arranged such that the intaglio part and the non-recessed parts other than the intaglio part are regularly arranged in a circumferential direction of the gravure roll. The angle formed by each concave portion of the intaglio part and the non-concave portion is 20 [deg.] Or less, or more than 70 [deg.] And 90 [deg.] Or less.

  The printing apparatus according to the present invention is characterized in that, in the above invention, the ink is a resist ink.

Further, the printing method according to the present invention is a printing method in which ink is printed on the surface of a long substrate that is continuously conveyed using a gravure roll in which a plurality of concave portions constituting an intaglio portion is formed. The ink is drawn up by a roll, and the ink drawing step for sequentially filling the plurality of recesses with the ink; the ink in the plurality of recesses is sequentially transferred from the gravure roll to the offset roll; A transfer printing step of transferring and printing from the offset roll onto the surface of the long substrate, and the volume of the concave portion per unit area in the intaglio portion is 6 [cm ³ / m ² ] or more and 50 [ and cm ³ / m ^2] or less, the viscosity of the ink 150 [mPa · s] or higher, 2500 [the mPa · s] or less, the surface of the long substrate The offset pressure roll 12 [kg / m] or more to obtain, characterized by a 100 [kg / m] or less.

  In the printing method according to the present invention, in the above invention, the intaglio part and a non-recessed part other than the intaglio part are arranged on the outer peripheral surface of the gravure roll so as to have regularity in the circumferential direction of the gravure roll. In addition, an angle formed between each concave portion of the intaglio part and the non-concave portion is set to 20 [degrees] or less, or more than 70 [degrees] and 90 [degrees] or less.

  The printing method according to the present invention is characterized in that, in the above invention, a resist ink is used as the ink.

  According to the present invention, there is an effect that a print pattern can be uniformly formed on the surface of a long base material without uneven printing.

FIG. 1 is a diagram illustrating a configuration example of a printing apparatus according to an embodiment of the present invention. FIG. 2 is a diagram illustrating a configuration example of the intaglio part and the non-recessed part of the gravure roll. FIG. 3 is a diagram showing another example of the configuration of the intaglio part and the non-recessed part of the gravure roll. FIG. 4 is a diagram showing an example of a gravure cell constituting the intaglio part of the gravure roll. FIG. 5 is a flowchart showing an example of the printing method according to the embodiment of the present invention. FIG. 6 is a diagram for explaining the state after the etching treatment of the steel strip surface that differs depending on the ink film thickness on the steel strip surface. FIG. 7 is a diagram showing the correlation between the cell volume of the gravure roll and the ink film thickness on the steel strip surface. FIG. 8 is a diagram for explaining the formation accuracy of the etching target portion of the steel strip surface affected by the cell inclination angle of the gravure roll. FIG. 9 is a diagram showing the correlation between the cell inclination angle of the gravure roll and the etching width difference on the steel strip surface.

  Exemplary embodiments of a printing apparatus and a printing method according to the present invention will be described below in detail with reference to the accompanying drawings. In the following, the present invention will be described by exemplifying a steel strip as an example of a long base material to be printed and a resist ink as an example of ink to be printed on the long base material. However, the present invention is not limited. Moreover, the same code | symbol is attached | subjected to the same component in each drawing.

(Process line)
First, the configuration of a process line to which a printing apparatus according to an embodiment of the present invention is applied will be described. FIG. 1 is a diagram illustrating a configuration example of a printing apparatus according to an embodiment of the present invention. FIG. 1 shows a part of the process line, specifically, a line for performing resist printing and etching processing on the steel strip 15.

  As shown in FIG. 1, the process line in the present embodiment includes a printing device 1 that performs a resist printing process on the steel strip 15, and a drying device 11 that dries the resist ink 3 applied to the surface of the steel strip 15. And an etching apparatus 12 that performs an etching process on the steel strip 15. In this process line, as shown in FIG. 1, a printing device 1, a drying device 11, and an etching device 12 are arranged in the transport direction of the steel strip 15 along the transport path of the steel strip 15. The process line also includes a plurality of transport rolls (not shown) that transport the steel strip 15.

  The printing apparatus 1 prints the resist ink 3 on the surface of the steel strip 15 that is sequentially conveyed by a gravure offset printing method. In this case, the printing apparatus 1 does not print the resist ink 3 on the etching target portion of the surface of the steel strip 15, and applies the resist ink 3 to a portion other than the etching target portion (hereinafter referred to as an etching prevention target portion). Print. Details of the configuration of the printing apparatus 1 will be described later.

  The steel strip 15 on which the resist ink 3 is printed by the printing apparatus 1 proceeds continuously in the conveying direction and is carried into the drying apparatus 11. The drying device 11 performs the baking process of the resist ink 3 on the steel strip 15 being continuously conveyed. Thereby, the drying device 11 dries and hardens the resist ink 3 on the surface of the steel strip 15. The etching device 12 sequentially receives the steel strips 15 after the resist ink 3 is baked by the drying device 11. The etching apparatus 12 performs an etching process on the surface of the steel strip 15 being continuously conveyed. In this case, the etching apparatus 12 performs an etching process on a non-printing portion (etching target portion) of the resist ink 3 in the surface of the steel strip 15. On the other hand, the resist ink 3 on the surface of the steel strip 15 acts as a resist mask for preventing etching. That is, the film of the resist ink 3 prevents the etching process on the etching prevention target portion of the steel strip 15. By such an etching process, a pattern corresponding to the shape of the non-printing portion is formed on the surface of the steel strip 15. The steel strip 15 after the etching process is sent out from the etching apparatus 12 and sequentially conveyed toward the downstream side of the etching apparatus 12. The film of the resist ink 3 remaining on the surface of the steel strip 15 is removed by, for example, predetermined equipment (not shown) arranged on the downstream side of the etching apparatus 12.

(Configuration of printing device)
Next, the configuration of the printing apparatus 1 according to the embodiment of the present invention will be described with reference to FIG. As shown in FIG. 1, the printing apparatus 1 includes a coater pan 2 that stores resist ink 3, a gravure roll 4 and an offset roll 8 for printing the resist ink 3 on the surface of the steel strip 15 (gravure offset printing), , A blade 7 for removing excess resist ink 3 on the gravure roll 4, a blade 9 for removing excess resist ink 3 on the offset roll 8, and a backup roll 10.

  The coater pan 2 is a container for storing the resist ink 3 to be printed on the surface of the steel strip 15. The resist ink 3 is automatically supplied to the coater pan 2 by a predetermined supply facility. Alternatively, the resist ink 3 is appropriately supplied to the coater pan 2 by the operator. The coater pan 2 contains the resist ink 3 scraped from the gravure roll 4 or the offset roll 8 by the blades 7 and 9. The viscosity of the resist ink 3 in the coater pan 2 (hereinafter referred to as ink viscosity as appropriate) is in the range of 150 [mPa · s] to 2500 [mPa · s].

  The gravure roll 4 is a roll body that sequentially draws the resist ink 3 from the coater pan 2 and sequentially transfers the drawn resist ink 3 to the offset roll 8. As shown in FIG. 1, the gravure roll 4 is arranged so that a part thereof is immersed in the resist ink 3 in the coater pan 2. And the gravure roll 4 is arrange | positioned so that the offset roll 8 and outer peripheral surfaces may contact partially.

  As shown in FIG. 1, the gravure roll 4 has an intaglio part 5 and a non-recessed part 6 on the outer peripheral surface thereof. FIG. 2 is a diagram illustrating a configuration example of the intaglio part and the non-recessed part of the gravure roll. FIG. 3 is a diagram showing another example of the configuration of the intaglio part and the non-recessed part of the gravure roll. FIG. 4 is a diagram showing an example of a gravure cell constituting the intaglio part of the gravure roll. 2 and 3 show a part of the plurality of intaglio portions 5 and non-recess portions 6 formed on the outer peripheral surface of the gravure roll 4.

The intaglio part 5 is formed by a plurality of gravure cells 5a as shown in FIGS. Each of the plurality of gravure cells 5a is, for example, a quadrangular frustum-shaped recess as shown in FIG. The plurality of gravure cells 5 a are formed on the outer peripheral surface of the gravure roll 4 corresponding to the printing pattern of the resist ink 3 printed on the surface of the steel strip 15. That is, the intaglio part 5 represents a pattern (including the same shape) corresponding to this print pattern on the outer peripheral surface of the gravure roll 4 by a plurality of gravure cells 5a. The volume of the gravure cell 5a per unit area (hereinafter referred to as cell volume) in the intaglio part 5 is in the range of 6 [cm ³ / m ² ] or more and 50 [cm ³ / m ² ] or less.

  The non-recessed portion 6 is a portion other than the intaglio portion 5 on the outer peripheral surface of the gravure roll 4, that is, a portion where the gravure cell 5 a is not formed. On the outer peripheral surface of the gravure roll 4, the non-recessed portion 6 is a boundary portion between the intaglio portions 5 having a predetermined pattern, as shown in FIGS. Corresponds to a portion where the resist ink 3 is not printed. The angle formed between the non-recessed portion 6 and each gravure cell 5a of the intaglio portion 5 (hereinafter referred to as a cell inclination angle) is 20 [degrees] or less, or more than 70 [degrees] and 90 [degrees] or less. In the present embodiment, as shown in FIG. 2, the cell inclination angle θ is an inclination angle of the gravure cell 5a with respect to the non-recessed portion 6, and one side 5b (see FIG. 4) at the opening end of the gravure cell 5a. It is defined as the angle formed with the end side of the non-recess 6. For example, one side 5 b of the gravure cell 5 a is a side that faces or contacts the non-recessed portion 6, and an end side of the non-recessed portion 6 is a boundary line between the intaglio part 5 and the non-recessed portion 6.

  Here, as shown in FIG. 3, the arrangement of the gravure cell 5a parallel to the non-recessed portion 6 is one of the arrangement modes of the gravure cell 5a that satisfies the above-described range of the cell inclination angle θ. That is, when the gravure cell 5a is arranged in parallel to the non-recessed portion 6, the cell inclination angle θ formed by the non-recessed portion 6 and the gravure cell 5a is 0 [degree], which is equal to or less than 20 [degree] described above. Included in the range.

  The gravure roll 4 has the intaglio part 5 and the non-recessed parts 6 other than the intaglio part 5 so as to be arranged with regularity in the circumferential direction of the gravure roll 4. For example, as shown in FIGS. 2 and 3, the gravure roll 4 has a plurality of intaglio parts 5 and non-recess parts 6 so that the intaglio parts 5 and the non-recess parts 6 are alternately arranged at regular intervals in the circumferential direction. Have. The circumferential direction of the gravure roll 4 shown in FIGS. 2 and 3 is the same direction as the rotation direction of the gravure roll 4. As shown in FIG. 1, the gravure roll 4 sequentially fills a plurality of gravure cells 5a of each intaglio part 5 with resist ink 3 while rotating in the circumferential direction, and offsets the resist ink 3 in each gravure cell 5a. Transfer is sequentially performed on the outer peripheral surface of the roll 8.

  As shown in FIG. 1, the blade 7 is disposed so that the tip portion thereof is in contact with the outer peripheral surface of the gravure roll 4. The blade 7 scrapes off excess resist ink 3 of the gravure roll 4 by using the rotational force of the gravure roll 4. Specifically, the blade 7 scrapes off the excess resist ink 3 from each of the plurality of gravure cells 5a as compared with the volume of the gravure cell 5a. Thus, the amount of the resist ink 3 in each gravure cell 5a is adjusted to an amount suitable for resist printing on the steel strip 15. The blade 7 scrapes off the resist ink 3 attached to the non-recessed portion 6 of the gravure roll 4. As a result, the blade 7 suppresses unintended printing of the resist ink 3 on the etching target portion (non-printing portion) of the steel strip 15. The resist ink 3 scraped off from the gravure roll 4 by such a blade 7 is collected into the coater pan 2 and then reused.

  The offset roll 8 is a roll body that sequentially prints the resist ink 3 on the surface of the steel strip 15 that is continuously conveyed. Specifically, the offset roll 8 is realized using, for example, a rubber roll formed by lining rubber on the outer peripheral surface of a steel roll, and is disposed between the gravure roll 4 and the backup roll 10 as shown in FIG. The In this arrangement state, as shown in FIG. 1, the offset roll 8 brings the gravure roll 4 and the outer peripheral surfaces into partial contact. The offset roll 8 sandwiches the steel strip 15 from both the front and back surfaces in cooperation with the backup roll 10. As shown in FIG. 1, the offset roll 8 is rotated in the circumferential direction while the resist ink 3 in the plurality of gravure cells 5a is sequentially transferred from each intaglio part 5 by the gravure roll 4, and the transferred resist ink 3 is It transfers and prints on the surface of the steel strip 15 in continuous conveyance sequentially. In this printing process, the offset roll 8 transfers the resist ink 3 to the surface of the steel strip 15 by pressing the steel strip 15 supported by the backup roll 10. At this time, the pressure of the offset roll 8 (hereinafter referred to as nip pressure) applied to the surface of the steel strip 15 is a linear pressure, and is in the range of 12 [kg / m] or more and 100 [kg / m] or less. . On the other hand, the offset roll 8 cooperates with the backup roll 10 while continuing the rotation described above, and sequentially sends the steel strip 15 after printing the resist ink 3 in the transport direction.

  The offset roll 8 performs a natural rotation that rotates in the same direction as the gravure roll 4 at a close point or a close point to the gravure roll 4, and also performs a natural rotation similar to this for the backup roll 10. As a result, the offset roll 8 can accurately transfer the pattern of the resist ink 3 represented by the plurality of gravure cells 5 a of the gravure roll 4 to the surface of the steel strip 15. Moreover, since the outer peripheral surface of the offset roll 8 is covered with rubber, it is possible to prevent the surface of the steel strip 15 from being damaged when the steel strip 15 supported by the backup roll 10 is pressed.

  As shown in FIG. 1, the blade 9 is disposed so that the tip portion thereof is in contact with the outer peripheral surface of the offset roll 8. The blade 9 uses the rotational force of the offset roll 8 to scrape off excess resist ink 3 from the offset roll 8. Specifically, the blade 9 scrapes off the resist ink 3 remaining on the outer peripheral surface of the offset roll 8 after transferring the resist ink 3 to the surface of the steel strip 15. If the resist ink 3 remains on the offset roll 8 after transfer, the resist ink 3 newly transferred from the gravure roll 4 to the offset roll 8 and the remaining resist ink 3 overlap. As a result, a printing defect occurs in which the resist ink 3 is printed on a portion of the surface of the steel strip 15 that should not be printed (for example, a portion to be etched). The blade 9 prevents the above-mentioned printing failure by scraping off the remaining resist ink 3 on the offset roll 8. The resist ink 3 scraped off from the offset roll 8 by such a blade 9 is collected into the coater pan 2 and then reused.

  The material of the blades 7 and 9 described above may be a metal or an elastic resin such as rubber. In other words, in the present invention, the blades 7 and 9 need only be able to evenly scrape off the excess resist ink 3 of the gravure roll 4 or the offset roll 8, and the material thereof is not particularly limited.

  As shown in FIG. 1, the backup roll 10 is disposed so that the offset roll 8 and the outer peripheral surface face each other with the steel strip 15 interposed therebetween. As shown in FIG. 1, the backup roll 10 rotates in the circumferential direction and cooperates with the offset roll 8 to sandwich the steel strip 15 from both the front and back sides, and the steel strip 15 after transferring the resist ink 3 is transferred in the transport direction. Sequentially. At this time, the backup roll 10 supports the steel strip 15 on which the resist ink 3 is printed by the offset roll 8 described above on the back surface (the surface opposite to the surface on which the resist ink 3 is printed). At the same time, the backup roll 10 rotates in the outer circumferential direction to guide the steel strip 15 after the printing process toward the drying device 11.

(Printing method)
Next, a printing method according to the embodiment of the present invention will be described. FIG. 5 is a flowchart showing an example of the printing method according to the embodiment of the present invention. In the printing method according to the present embodiment, as shown in FIG. 1, the printing apparatus 1 having the gravure roll 4 and the offset roll 8 is used to print the resist ink 3 on the surface of the steel strip 15 that is continuously conveyed. To do.

Specifically, as illustrated in FIG. 5, the printing apparatus 1 draws the resist ink 3 as ink by the gravure roll 4 (step S <b> 101). In this step S101, the printing apparatus 1 rotates the gravure roll 4 set to a predetermined cell volume in the circumferential direction, and applies the resist ink 3 having a predetermined ink viscosity by each intaglio part 5 of the gravure roll 4 to the coater. Sequentially draw from bread 2. As a result, the printing apparatus 1 sequentially fills the plurality of gravure cells 5 a of the intaglio part 5 with the resist ink 3. In the present embodiment, the ink viscosity of the resist ink 3 is adjusted within a range of 150 [mPa · s] to 2500 [mPa · s]. As shown in FIGS. 2 and 3, the intaglio part 5 and the non-recessed part 6 are arranged on the outer peripheral surface of the gravure roll 4 so as to have regularity in the circumferential direction of the gravure roll 4. The cell volume of the plurality of gravure cells 5a is set in the range of 6 [cm ³ / m ² ] or more and 50 [cm ³ / m ² ] or less. Furthermore, the cell inclination angle θ (see FIG. 2) of each gravure cell 5a is set within a range of 20 [degrees] or less, or exceeding 70 [degrees] and 90 [degrees] or less.

  Next, the printing apparatus 1 removes excess ink from the gravure roll 4 (step S102). In step S <b> 102, the printing apparatus 1 scrapes excess resist ink 3 from each of the plurality of gravure cells 5 a with the blade 7. Accordingly, the printing apparatus 1 adjusts the amount of the resist ink 3 in each gravure cell 5a to an amount suitable for printing, and holds the amount of the resist ink 3 after the adjustment. Further, the printing apparatus 1 scrapes and removes the resist ink 3 adhering to the non-recessed portion 6 of the gravure roll 4 with the blade 7.

  Next, the printing apparatus 1 transfers ink from the gravure roll 4 to the offset roll 8 and transfers and prints ink from the offset roll 8 to the steel strip 15 (step S103). In step S103, the printing apparatus 1 rotates the offset roll 8 together with the gravure roll 4 in the circumferential direction, and sequentially transfers the resist ink 3 in the plurality of gravure cells 5a from the gravure roll 4 to the offset roll 8. . Subsequently, the printing apparatus 1 sequentially transfers the resist ink 3 transferred as described above from the offset roll 8 to the surface of the steel strip 15 being continuously conveyed. In this way, the printing apparatus 1 sequentially prints the resist ink 3 on the surface of the steel strip 15 being continuously conveyed. In the present embodiment, the nip pressure when sequentially transferring and printing the resist ink 3 from the offset roll 8 to the surface of the steel strip 15 is set within a range of 12 [kg / m] to 100 [kg / m]. doing. On the other hand, the printing apparatus 1 continuously performs each rotation operation of the gravure roll 4, the offset roll 8, and the backup roll 10, and thereby sequentially sends the steel strip 15 after printing the resist ink in the transport direction.

  Thereafter, the printing apparatus 1 removes ink remaining on the offset roll 8 (step S104). In step S <b> 104, the printing apparatus 1 scrapes and removes the resist ink 3 remaining on the outer peripheral surface of the offset roll 8 after the transfer of the resist ink 3 on the surface of the steel strip 15 with the blade 9. As a result, the printing apparatus 1 makes the outer peripheral surface of the offset roll 8 newly transferable with the resist ink 3 from the gravure roll 4.

  After executing the processing step of step S104, the printing apparatus 1 returns to step S101 described above, and sequentially repeats the processing steps after step S101. Thereby, the printing apparatus 1 can form the target print pattern of the resist ink 3 on the surface of the steel strip 15 that is continuously conveyed.

(Range of gravure roll cell volume)
Below, the volume (cell volume C) of the gravure cell 5a per unit area in the gravure roll 4 of the printing apparatus 1 concerning embodiment of this invention is demonstrated. The present inventors conducted a basic survey to confirm a suitable range of the cell volume C for forming a uniform print pattern of the resist ink 3 without uneven printing on the surface of the steel strip 15 to be processed. In this basic survey, the cell volume C of the gravure roll 4 of the printing apparatus 1 shown in FIG. 1 is changed to 4.0 to 65 [cm ³ / m ² ], and the printing apparatus in which the cell volume C is changed in this way. 1 was used to investigate the ink film thickness d of the resist ink 3 transferred to the surface of the steel strip 15 and the state after the etching process on the surface of the steel strip 15 after ink printing. As the state of the steel strip 15 after the etching treatment, the presence or absence of etching in the portion of the surface of the steel strip 15 where the resist ink 3 is printed (etching prevention target portion) and the resist ink 3 are not printed. The shape of the non-printed part (etching target part) was investigated.

  The conditions for this basic investigation are that the conveying speed of the steel strip 15 (hereinafter referred to as the line speed V) is 60 [m / min], the ink viscosity B of the resist ink 3 is 1500 [mPa · s], and the gravure cell 5a Was a square pyramid (see FIG. 4), and the cell inclination angle θ of the gravure cell 5a was set to 0 [degrees]. As the steel strip 15, a cold-rolled steel plate having a thickness of 0.23 [mm] was used.

  FIG. 6 is a diagram for explaining the state after the etching treatment of the steel strip surface that differs depending on the ink film thickness on the steel strip surface. FIG. 7 is a diagram showing the correlation between the cell volume of the gravure roll and the ink film thickness on the steel strip surface. The ink film thickness d shown in FIGS. 6 and 7 is the film thickness of the resist ink 3 transferred and printed on the surface of the steel strip 15 from the gravure roll 4 through the offset roll 8. This ink film thickness d was obtained by the following method. That is, after the resist ink 3 printed on the surface of the steel strip 15 is dried, a sample of the steel strip 15 after printing is collected. Next, a boundary region between the printed portion and the non-printed portion of the resist ink 3 on the surface of the collected steel strip 15 is observed using a laser microscope. The ink film thickness d of this printed part was calculated from the difference in height between the observed printed part and the non-printed part.

As shown in state A1 in FIG. 6, the resist ink 3 is printed on the surface of the steel strip 15 except the etching target portion 15a, that is, the etching prevention target portion 15b. Thereby, a film of the resist ink 3 having the ink film thickness d is formed on the etching prevention target portion 15b of the steel strip 15 after printing. Here, when the cell volume C of the gravure roll 4 is less than 6 [cm ³ / m ² ], the ink film thickness d on the surface of the steel strip 15 after the drying treatment is 0.5, as shown in FIG. It was less than [μm]. In this case, due to insufficient film thickness of the resist ink 3, printing unevenness of the resist ink 3 occurs in the etching prevention target portion 15 b of the steel strip 15, and the surface portion of the steel strip 15 where the printing unevenness occurs is exposed. End up. When the sample after the etching process of such a steel strip 15 was confirmed, the following results were obtained. That is, not only the etching target portion 15a is etched but also a portion etched into the etching prevention target portion 15b that should be prevented from being etched as exemplified by the etching portion 16 in the state A2 shown in FIG. Many were confirmed.

On the other hand, when the cell volume C of the gravure roll 4 is within the range of 6 [cm ³ / m ² ] or more and 50 [cm ³ / m ² ] or less, as shown in FIG. The ink film thickness d on the surface was 0.51 to 6.8 [μm]. In this case, printing unevenness did not occur in the resist ink 3 printed on the etching prevention target portion 15b of the steel strip 15, and the etching prevention target portion 15b was covered with the resist ink 3 without being exposed. When the sample after the etching process of such a steel strip 15 was confirmed, the following results were obtained. That is, as shown in state A3 in FIG. 6, a resist mask that prevents etching of the etching prevention target portion 15b is formed by the resist ink 3 film, and etching of the etching prevention target portion 15b is prevented by this resist mask. It was done. It was confirmed that there was no etched portion in the etching prevention target portion 15b. Further, on the surface of the steel strip 15, the shape of the portion other than the etching prevention target portion 15 b, that is, the pattern of the etching processing target portion 15 a was made uniform corresponding to the uniform printing pattern of the resist ink 3. As a result, the width of the actually etched portion of the etching target portion 15a (hereinafter referred to as the etching width W) is set such that the etching processing target portion 15a and the etching prevention target portion 15b are as shown in the state A3 of FIG. It was made uniform along the boundary.

On the other hand, when the cell volume C of the gravure roll 4 exceeds 50 [cm ³ / m ² ], as shown in FIG. 7, the ink film thickness d on the surface of the steel strip 15 after the drying treatment is 7 [μm]. Exceeded. When the sample after the etching process of such a steel strip 15 was confirmed, the following results were obtained. That is, since the film thickness of the resist ink 3 is excessive, the resist ink 3 flows by its leveling action before drying. Such resist ink 3 significantly flows from the etching prevention target portion 15b to the etching processing target portion 15a as shown in a state A4 in FIG. As a result, a portion (see state A4 in FIG. 6) in which the etching width W is unintentionally narrowed compared to the target width of the etching processing target portion 15a is generated. As a result, the non-printing portion of the surface of the steel strip 15 The shape became uneven.

From the above results, in order to form a uniform print pattern of the resist ink 3 on the surface of the steel strip 15 to be treated without printing unevenness, the cell volume C of the gravure roll 4 is 6 [cm ³ / m ² ] or more, It became clear that it was necessary to set within a range of 50 [cm ³ / m ² ] or less.

(Range of ink viscosity)
Next, the viscosity (ink viscosity B) of the resist ink 3 printed on the surface of the steel strip 15 by the printing apparatus 1 according to the embodiment of the present invention will be described. The present inventors conducted a basic investigation to confirm a suitable range of the ink viscosity B for forming a uniform print pattern of the resist ink 3 without uneven printing on the surface of the steel strip 15 to be processed. In this basic survey, the printing apparatus 1 shown in FIG. 1 is used to print the resist ink 3 with the ink viscosity B changed in the range of 50 to 3000 [mPa · s] on the surface of the steel strip 15 to obtain the ink. After printing, after drying the ink, and after etching treatment, the presence or absence of etching in the etching prevention target portion 15b (printing portion) of each steel strip 15 and the shape of the etching treatment target portion 15a (non-printing portion) were investigated.

As conditions for this basic survey, the line speed V of the steel strip 15 is 60 [m / min], the shape of the gravure cell 5a is a quadrangular pyramid (see FIG. 4), and the cell volume C of the gravure roll 4 is 6 [ cm ³ / m ² ] or more and 50 [cm ³ / m ² ] or less, and the cell inclination angle θ of the gravure cell 5a was set to 0 [degrees]. As the steel strip 15, a cold-rolled steel plate having a thickness of 0.23 [mm] was used.

  When the ink viscosity B is less than 150 [mPa · s], the resist ink 3 has its own leveling action promoted due to the excessive viscosity. For this reason, the resist ink 3 flows from the etching prevention target portion 15b to the etching processing target portion 15a after being printed on the etching prevention target portion 15b of the steel strip 15 until it is dried and hardened (see state A4 in FIG. 6). ). As a result, a portion where the exposure width is unintentionally narrowed in the etching target portion 15a occurs, or in the etching target portion 15a (non-printed portion of the steel strip 15) where the resist ink 3 should not be printed. A portion where the resist ink 3 was printed occurred. As a result, the shape of the non-printing part on the surface of the steel strip 15 became non-uniform.

  On the other hand, when the ink viscosity B is in the range of 150 [mPa · s] or more and 2500 [mPa · s] or less, the resist ink 3 is dried and cured after being printed on the etching prevention target portion 15b of the steel strip 15. In the meantime, the narrowing of the etching target portion 15a due to its own leveling and the flow into the etching target portion 15a do not occur. It was confirmed that the etching prevention target portion 15b covered with the resist ink 3 has no etched portion. Further, on the surface of the steel strip 15, the shape of the portion other than the etching prevention target portion 15b, that is, the pattern of the etching processing target portion 15a is made uniform corresponding to the uniform printing pattern of the resist ink 3. . That is, the shape of the non-printing portion of the steel strip 15 was made uniform along the boundary between the etching target portion 15a and the etching prevention target portion 15b.

  On the other hand, when the ink viscosity B exceeds 2500 [mPa · s], the resist ink 3 slips through between the outer peripheral surface of the gravure roll 4 and the blade 7 shown in FIG. Due to this, the resist ink 3 remains in the non-recessed portion 6 of the gravure roll 4, whereby the resist ink 3 is unintentionally printed on the etching target portion 15 a of the steel strip 15. As a result, the printing pattern of the resist ink 3 on the surface of the steel strip 15 becomes non-uniform, so that the intended etching shape of the steel strip 15 (target pattern of the etching target portion 15a) cannot be obtained.

  From the above results, in order to form a uniform printing pattern of the resist ink 3 without uneven printing on the surface of the steel strip 15 to be processed, the ink viscosity B of the resist ink 3 is 150 [mPa · s] or more and 2500 [ mPa · s] It has become clear that it must be set within the following range.

(Nip pressure range)
Next, the pressure (nip pressure f) applied to the surface of the steel strip 15 from the offset roll 8 when the resist ink 3 is printed on the surface of the steel strip 15 by the printing apparatus 1 according to the embodiment of the present invention will be described. . The present inventors conducted a basic survey in order to confirm a suitable range of the nip pressure f for forming a uniform print pattern of the resist ink 3 on the surface of the steel strip 15 to be processed without printing unevenness. In this basic survey, the nip pressure f between the offset roll 8 and the steel strip 15 of the printing apparatus 1 shown in FIG. 1 is changed to 5 to 150 [kg / m], and the nip pressure f is changed in this way. The printing apparatus 1 is used to print the resist ink 3 on the surface of the steel strip 15, the surface appearance of each steel strip 15 after ink printing and ink drying, and the etching target portion 15a of the steel strip 15 after the etching process. The shape of (non-printing part) was investigated.

As conditions for this basic survey, the line speed V of the steel strip 15 is 60 [m / min], the shape of the gravure cell 5a is a quadrangular pyramid (see FIG. 4), and the cell volume C of the gravure roll 4 is 6 [ cm ³ / m ² ] or more and 50 [cm ³ / m ² ] or less, and the cell inclination angle θ of the gravure cell 5a was set to 0 [degrees]. The ink viscosity B of the resist ink 3 was 150 [mPa · s] or more and 2500 [mPa · s] or less, and a cold-rolled steel plate having a thickness of 0.23 [mm] was used as the steel strip 15. As the offset roll 8, a rubber roll obtained by lining rubber on a steel roll as described above was used. In this offset roll 8, the rubber lining thickness was 10 [mm], and the rubber hardness was Hs80 degrees.

  When the nip pressure f is less than 12 [kg / m], the transfer of the resist ink 3 from the offset roll 8 to the surface of the steel strip 15 becomes insufficient due to the eccentricity of the offset roll 8. For this reason, sufficient resist ink 3 is not transferred to the printing part (etching prevention target part 15b) of the steel strip 15, and due to this, printing unevenness of the resist ink 3 occurs in the etching prevention target part 15b. As a result, on the surface of the steel strip 15 after the etching treatment, a large number of etching portions were observed in the printed portion that should not be etched, that is, the etching prevention target portion 15b.

  On the other hand, when the nip pressure f is in the range of 12 [kg / m] to 100 [kg / m], the contact state between the outer peripheral surface of the offset roll 8 and the surface of the steel strip 15 is determined by the resist ink 3. It becomes possible to ensure a state suitable for printing. For this reason, the resist ink 3 can be appropriately transferred from the offset roll 8 to the etching prevention target portion 15b of the steel strip 15 without uneven printing. In the etching prevention target portion 15b covered with such a resist ink 3, no etching portion was generated. Further, it was confirmed that the pattern of the etching target portion 15a of the steel strip 15 (the shape of the non-printing portion) was made uniform corresponding to the uniform printing pattern of the resist ink 3.

  On the other hand, when the nip pressure f exceeds 100 [kg / m], the deformation of the offset roll 8 is increased, and etching is performed from the etching prevention target portion 15b (printed portion) of the steel strip 15 along with the deformation of the offset roll 8. The resist ink 3 flows into the processing target portion 15a (non-printing portion). As a result, a portion where the width of the exposure is unintentionally narrowed occurs in the etching target portion 15a, or a portion where the resist ink 3 is printed in the etching target portion 15a where the resist ink 3 should not be printed originally. Occurred. As a result, the shape of the non-printing part on the surface of the steel strip 15 after the etching treatment became non-uniform.

  From the above results, in order to form a uniform printing pattern of the resist ink 3 on the surface of the steel strip 15 to be processed without uneven printing, the nip pressure f between the offset roll 8 and the steel strip 15 is 12 [kg. / M] and 100 [kg / m] or less, it has become clear that it is necessary to set.

(Range of gravure roll cell tilt angle)
Next, an arrangement mode of the plurality of gravure cells 5a in the gravure roll 4 of the printing apparatus 1 according to the embodiment of the present invention, specifically, the cell inclination angle θ of the gravure cell 5a shown in FIG. 2 will be described. The present inventors conducted a basic investigation to confirm a suitable range of the cell inclination angle θ for forming a printed pattern of the resist ink 3 on the surface of the steel strip 15 to be processed with high accuracy. In this basic survey, the cell inclination angle θ of the plurality of gravure cells 5a constituting each intaglio part 5 of the gravure roll 4 of the printing apparatus 1 shown in FIG. 1 is changed, and the printing apparatus in which the cell inclination angle θ is changed. 1 was used to print the resist ink 3 on the surface of the steel strip 15. The correlation between the shape of the etching target portion 15a (non-printing portion) of each steel strip 15 after the ink printing and the etching processing and the cell inclination angle θ was investigated.

  As conditions for this basic survey, the line speed V of the steel strip 15 was set to 60 [m / min], and a cold-rolled steel plate having a thickness of 0.23 [mm] was used as the steel strip 15. Each condition other than the cell inclination angle θ, such as the shape of the gravure cell 5a, the cell volume C, the ink viscosity B, or the nip pressure f, was set in the same manner as in the above-described embodiment.

FIG. 8 is a diagram for explaining the formation accuracy of the etching target portion of the steel strip surface affected by the cell inclination angle of the gravure roll. FIG. 9 is a diagram showing the correlation between the cell inclination angle of the gravure roll and the etching width difference on the steel strip surface. In FIG. 8, the target etching width W _t is a target value of the etching width of the etching target portion 15 a formed on the surface of the steel strip 15. This target etching width W _t is determined in accordance with the target print pattern of the resist ink 3, that is, the target pattern represented by the plurality of gravure cells 5 a of the gravure roll 4. The maximum etching width W _max is the maximum value of the etching width W (see FIG. 6) of the etching target portion 15a. This maximum etching width W _max varies depending on the influence of the cell inclination angle θ. On the other hand, in FIG. 9, the etching width difference ΔW is a value for evaluating the accuracy of the etching shape (pattern of the etching target portion 15a) formed on the surface of the steel strip 15, and the maximum etching width W _max and the target etching width. It is calculated by the difference between the W _t.

First, when the cell inclination angle θ is 20 degrees or less, the maximum etching width W _max of the etching target portion 15a of the steel strip 15 shown in FIG. 8 is a value close to or equal to the target etching width W _t . . Specifically, as shown in FIG. 9, the etching width difference ΔW of the etching target portion 15a is less than 20 [μm]. Thereby, it became possible to ensure the etching shape of the surface of the steel strip 15 with high accuracy. That is, the printing pattern of the resist ink 3 having such an etching shape can be formed on the surface of the steel strip 15 with high accuracy.

On the other hand, when the cell inclination angle θ exceeds 20 [degrees] and is within the range of 70 [degrees] or less, the maximum etching width W _max of the etching target portion 15a increases the difference from the target etching width W _t. I let you. Specifically, as shown in FIG. 9, the etching width difference ΔW of the etching target portion 15a increases to a value exceeding 20 [μm], and is maximum when the cell inclination angle θ is 45 [degrees]. Thus, etching failure occurred. As the cell inclination angle θ changes from 20 [degrees] or 70 [degrees] to 45 [degrees], each of the adjacent portions at the boundary between the intaglio part 5 and the non-recessed part 6 shown in FIG. This is presumably because the non-recessed portion 6 was enlarged between the gravure cells 5a. Under such conditions of the cell inclination angle θ, the formation accuracy of the etching shape on the surface of the steel strip 15 deteriorated. That is, it is difficult to accurately form a printing pattern of the resist ink 3 having an etching shape on the surface of the steel strip 15.

  On the other hand, when the cell inclination angle θ exceeds 70 [degrees] and is in the range of 90 [degrees] or less, as in the case where the cell inclination angle θ is 20 [degrees] or less, the etching target portion 15a. The etching width difference ΔW was less than 20 [μm]. In this case, the etching shape of the surface of the steel strip 15 can be ensured with high accuracy. That is, the printing pattern of the resist ink 3 having such an etching shape can be formed on the surface of the steel strip 15 with high accuracy.

  From the above results, in order to form the printing pattern of the resist ink 3 on the surface of the steel strip 15 to be processed with high accuracy, the cell inclination angle θ is 20 [degrees] or less, or exceeds 70 [degrees] and It has become clear that it must be set within a range of 90 [deg.] Or less (hereinafter abbreviated as a preferable range of the cell tilt angle θ). That is, on the outer peripheral surface of the gravure roll 4, by disposing each of the plurality of gravure cells 5 a so as to satisfy the preferred range of the cell inclination angle θ with respect to the non-recessed portion 6, It has been clarified that the printing pattern of the resist ink 3 can be formed with high accuracy, and that the etching shape can be secured on the surface of the steel strip 15 with high accuracy.

  The ranges of the cell volume C, the ink viscosity B, the nip pressure f, and the cell inclination angle θ described above are not limited to the case where the concave shape of the gravure cell 5a is a quadrangular pyramid, and the bottom surface is triangular or other The same applies to a polygonal pyramid-shaped gravure cell or a polygonal pyramid-shaped gravure cell such as a triangular pyramid or a quadrangular pyramid.

Example 1
Next, Example 1 of the present invention will be described. In Example 1, the resist ink 3 was printed (gravure offset printing) on the surface of the steel strip 15 using the printing apparatus 1 shown in FIG. In the printing apparatus 1, the gravure roll 4 includes, as described above, an intaglio part 5 formed by a plurality of gravure cells 5a and a non-recessed part 6 in which no concave part is formed on the outer peripheral surface. It is a metal roll with hard chrome plating on the outermost layer. The offset roll 8 is a rubber roll having a rubber lining on the outer peripheral surface. The rubber lining thickness was 10 [mm], and the rubber hardness was Hs80 degrees.

As conditions of Example 1, the cell volume C of the gravure roll 4, the ink viscosity B of the resist ink 3, and the nip pressure f of the offset roll 8 were set within a preferable range in the above-described embodiment. That is, the cell volume C is 6 [cm ³ / m ² ] or more and 50 [cm ³ / m ² ] or less. The ink viscosity B is 150 [mPa · s] or more and 2500 [mPa · s] or less. The nip pressure f is 12 [kg / m] or more and 100 [kg / m] or less. The cell inclination angle θ of the gravure cell 5a is set to a predetermined angle (for example, 0 [degrees]) within the above-described preferable range (20 [degrees] or less, or more than 70 [degrees] and 90 [degrees] or less).

  Moreover, in the present Example 1, as the steel strip 15 to be processed, a cold-rolled steel plate sequentially discharged from a coil having a plate thickness of 0.23 [mm] and a plate width of 1000 [mm] was used. . The line speed V of the steel strip 15 when printing the resist ink 3 on the surface of the steel strip 15 was set to 30 [m / min] or more and 80 [m / min] or less.

  Each condition of the first embodiment described above is changed within the preferable range, and the resist ink 3 is sequentially printed on the surface of the steel strip 15 by the printing apparatus 1, and the appearance evaluation of the steel strip 15 after printing and after the etching treatment is performed. Went. This appearance evaluation is performed by collecting samples # 1 to # 22 at a plurality of locations in the width direction and the conveying direction of the steel strip 15, and observing the appearance of each surface of the samples # 1 to # 22 using a laser microscope. went.

  Further, as Comparative Example 1 with respect to Example 1, the above-described cell volume C, ink viscosity B, and nip pressure f conditions are set outside the preferred ranges of the present invention, and other conditions are the same as in Example 1. Thus, samples # 23 to # 29 of the steel strip 15 after printing and after the etching treatment were collected. The appearances of Samples # 23 to # 29 of Comparative Example 1 were also evaluated in the same manner as Samples # 1 to # 22 of Example 1.

  Table 1 shows the results of the appearance evaluations of Samples # 1 to # 22 of Example 1 and Samples # 23 to # 29 of Comparative Example 1. In the external appearance evaluation in Example 1, when printing unevenness of the resist ink 3 occurs in the printed portion of the steel strip 15 (etching prevention target portion 15b), as well as the non-printed portion of the steel strip 15 that should not be printed ( When an unintended flow or printing of the resist ink 3 occurred in the etching target portion 15a) and the print pattern became non-uniform, it was determined that the printing was defective. Note that the printing unevenness is a phenomenon in which a film portion of the resist ink 3 that is too thin is generated in the printed portion of the steel strip 15 or a portion in which the resist ink 3 is not printed on the printed portion of the steel strip 15. is there. On the other hand, when an etched portion occurs in the printed portion of the steel strip 15, and when an uneven shape occurs in the etched shape of the non-printed portion of the steel strip 15 due to a non-uniform print pattern or the like, that is, etching. When the shape was non-uniform, it was determined that the etching was defective.

  As shown in Table 1, in any of Samples # 1 to # 22 of Example 1, printing unevenness and a nonuniform portion of the printing pattern are not seen on the surface of the steel strip 15 after printing, and printing failure occurs. I didn't. Moreover, the etching part and the non-uniform | heterogenous part of an etching shape were not seen on the surface of the steel strip 15 after an etching process, and the etching defect did not generate | occur | produce. The result of Example 1 is considered to be because the resist ink 3 was printed on the surface of the steel strip 15 in accordance with the conditions within the preferable range in the above-described embodiment. In particular, the gravure offset printing is performed with the cell volume C, the ink viscosity B, and the nip pressure f within the preferred ranges in the above-described embodiments, so that the resist ink 3 is uniformly applied to the surface of the steel strip 15 according to the target pattern. As a result, it was found that a uniform printed shape corresponding to the target pattern could be formed on the surface of the steel strip 15.

  On the other hand, as can be seen with reference to Table 1, etching failure occurred in samples # 23 and # 27 among samples # 23 to # 29 of Comparative Example 1, and printing failure occurred in samples # 24 to # 26. . In Samples # 28 and # 29, both etching failure and printing failure occurred. When the cell volume C, the ink viscosity B, and the nip pressure f are set outside the preferable ranges in the above-described embodiment as in Comparative Example 1, the printing unevenness or nonuniform printing of the resist ink 3 on the surface of the steel strip 15 is performed. The occurrence of the pattern became remarkable. In addition, unevenness in etching shape or non-uniform portions on the surface of the steel strip 15 became remarkable.

(Example 2)
Next, a second embodiment of the present invention will be described. In Example 2, the resist ink 3 was printed (gravure offset printing) on the surface of the steel strip 15 using the printing apparatus 1 shown in FIG. In the printing apparatus 1, the gravure roll 4 includes, as described above, an intaglio part 5 formed by a plurality of gravure cells 5a and a non-recessed part 6 in which no concave part is formed on the outer peripheral surface. It is a metal roll with hard chrome plating on the outermost layer. The offset roll 8 is a rubber roll having a rubber lining on the outer peripheral surface. The rubber lining thickness was 10 [mm], and the rubber hardness was Hs80 degrees.

  As a condition of the present Example 2, the cell inclination angle θ of the gravure cell 5a was set within a preferable range in the above-described embodiment. That is, the cell inclination angle θ is 20 [degrees] or less, or exceeds 70 [degrees] and is 90 [degrees] or less. Further, the cell volume C of the gravure roll 4, the ink viscosity B of the resist ink 3, and the nip pressure f of the offset roll 8 were each set to a predetermined value within the above-described preferred range.

  Moreover, in the present Example 2, as the steel strip 15 to be processed, a cold-rolled steel plate sequentially discharged from a coil having a plate thickness of 0.23 [mm] and a plate width of 1000 [mm] was used. . The line speed V of the steel strip 15 when printing the resist ink 3 on the surface of the steel strip 15 was set to 30 [m / min] or more and 80 [m / min] or less.

  The condition of the cell inclination angle θ of the second embodiment described above is changed within the preferable range, that is, the arrangement mode of each gravure cell 5a in the gravure roll 4 is changed within the preferable range, and the steel strip is printed by the printing apparatus 1. Resist ink 3 was sequentially printed on the surface of 15. An ink drying process and an etching process were sequentially performed on the steel strip 15 after printing, and the formation accuracy of the shape of the non-printed portion (that is, the etching shape) on the surface of the steel strip 15 after the etching treatment was evaluated. The accuracy evaluation of this etching shape is performed by taking samples # 31 to # 49 at a plurality of locations in the width direction and the conveyance direction of the steel strip 15, and using a laser microscope, the error of the width of each etching shape of samples # 31 to # 49 That is, the measurement was performed by measuring the etching width difference ΔW (see FIGS. 8 and 9).

  Further, as Comparative Example 2 with respect to Example 2, the above-described cell inclination angle θ condition was set outside the preferred range of the present invention, and the other conditions were the same as in Example 2, and the steel strip after the etching treatment was performed. Fifteen samples # 50 to # 56 were collected. For Samples # 50 to # 56 of Comparative Example 2, the etching shape formation accuracy was evaluated in the same manner as Samples # 31 to # 49 of Example 2.

  Table 2 shows the evaluation results of Samples # 31 to # 49 of Example 2 and Samples # 50 to # 56 of Comparative Example 2. In the evaluation in Example 2, when the etching width difference ΔW of the etching shape formed on the steel strip 15 is outside the allowable range of accuracy as the etching process, specifically, the etching width difference ΔW is 20 [μm] or more. In this case, it was determined that the etching was defective.

  As shown in Table 2, in any of samples # 31 to # 49 of Example 2, the etching width difference ΔW of the etching shape formed on the surface of the steel strip 15 after the etching treatment is less than 20 [μm]. There was no etching failure. The result of Example 2 is considered to be because the resist ink 3 was printed on the surface of the steel strip 15 in accordance with the conditions within the preferred range in the above-described embodiment. In particular, by performing gravure offset printing with the cell inclination angle θ within the preferred range in the above-described embodiment, the printing pattern of the resist ink 3 can be formed with high accuracy in accordance with the target pattern on the surface of the steel strip 15, As a result, it has been found that the etching shape can be formed on the surface of the steel strip 15 with high accuracy according to the target pattern.

  On the other hand, as can be seen with reference to Table 2, etching failure occurred in any of Samples # 50 to # 56 of Comparative Example 2. When the cell inclination angle θ is set outside the preferred range in the above-described embodiment as in Comparative Example 2, it becomes difficult to form the printing pattern of the resist ink 3 on the surface of the steel strip 15 with high accuracy. The deterioration of the etching shape formation accuracy on the surface of the steel strip 15 became remarkable.

As described above, in the embodiment of the present invention, the cell volume in the intaglio portion of the plurality of gravure cells constituting the intaglio portion on the outer peripheral surface of the gravure roll is 6 [cm ³ / m ² ] or more and 50 [cm ³ / M ² ] or less, the viscosity of the ink printed on the surface of the long substrate to be processed is 150 [mPa · s] or more and 2500 [mPa · s] or less, and the long substrate to be processed from the offset roll. The nip pressure applied to the surface of the ink is set to 12 [kg / m] or more and 100 [kg / m] or less, and the ink filling each gravure cell of the gravure roll is continuously applied to the surface of the long base material. Gravure offset printing is sequentially performed via an offset roll.

  For this reason, it is possible to transfer and print an appropriate amount of ink uniformly on a portion intended for printing without flowing or printing on a portion of the long base material surface to be processed which is not intended for printing. As a result, an ink print pattern corresponding to the target pattern represented by the plurality of gravure cells of the gravure roll can be uniformly formed on the surface of the long substrate to be processed without printing unevenness.

  By applying the printing apparatus and the printing method according to the present invention to gravure offset printing of resist ink on the surface of the steel strip, the resist ink is applied to portions other than the etching target on the surface of the steel strip so that there is no printing unevenness. In addition to printing, a uniform print pattern of resist ink can be formed. Accordingly, unintended etching of the portion of the steel strip surface on which the resist ink is printed can be avoided, and the shape of the non-printed portion (etching target portion) of the steel strip surface can be made uniform. As a result, the etching shape of the target pattern can be uniformly formed on the surface of the steel strip by the etching process.

  Further, in the embodiment of the present invention, the intaglio portion by the plurality of gravure cells and the non-recess portions other than the intaglio portion are arranged with regularity in the circumferential direction of the gravure roll, and the plurality of gravure cells The cell inclination angle formed by each non-recessed portion is set to 20 [degrees] or less, or more than 70 [degrees] and 90 [degrees] or less. For this reason, it is possible to transfer and print the ink with high accuracy on the portion of the long base material surface to be processed which is intended to be printed. As a result, an ink print pattern corresponding to the target pattern represented by the plurality of gravure cells of the gravure roll can be formed on the surface of the long substrate to be processed with high accuracy.

  By applying such printing technology to gravure offset printing of resist ink on the surface of the steel strip, the resist ink is printed with high accuracy according to the target pattern on the surface of the steel strip other than the etching target. Thus, the intended print pattern of the resist ink can be formed with high accuracy. Thereby, the shape of the part to be etched can be formed on the steel strip surface along the print pattern with high accuracy. As a result, the etching width difference between the etched shapes formed on the surface of the steel strip by the etching process can be reduced as much as possible, so that the etched shape of the target pattern can be formed on the surface of the steel strip with high accuracy.

  In the above-described embodiment, the intaglio part 5 constituted by the plurality of gravure cells 5a and the non-recessed parts 6 other than the intaglio part 5 are alternately arranged along the circumferential direction of the gravure roll 4. The invention is not limited to this. That is, the regularity of the arrangement of the intaglio part 5 and the non-recessed part 6 on the outer peripheral surface of the gravure roll 4 is not limited to an alternating pattern, and may be a predetermined pattern such as a spiral shape, a lattice shape, or a mesh shape. Moreover, the intaglio part 5 and the non-recessed part 6 should just be arrange | positioned in the outer peripheral surface of the gravure roll 4 so that the pattern corresponding to the printing pattern formed in the surface of the elongate base material of a process target may be represented. The arrangement of the intaglio part 5 and the non-recessed part 6 in the roll 4 may not have regularity along the circumferential direction of the gravure roll 4.

  Moreover, although the case where the gravure cell 5a formed in the gravure roll 4 is a recessed part of a quadrangular pyramid was illustrated in embodiment mentioned above, this invention is not limited to this. That is, the concave shape of the gravure cell 5a may be a shape other than the above-described quadrangular pyramid, for example, the bottom surface may be a polygonal truncated pyramid shape, or a polygonal pyramid shape. There may be.

  Furthermore, in the above-described embodiment, the resist ink is exemplified as the ink to be transferred and printed on the surface of the long base material, but the present invention is not limited to this. That is, what is necessary is just to use a desired ink according to the processing content of a long base material, a use, a printing pattern, etc. for the ink in this invention. For example, a resist ink mainly containing any resin such as alkyd resin, epoxy resin, and polyethylene resin can be used.

  Moreover, in embodiment mentioned above, although the steel strip 15 was illustrated as a long base material of a process target, this invention is not limited to this. That is, the long base material in the present invention is not limited to a steel strip but may be a strip of a metal or alloy other than steel, or a non-metallic strip such as paper or film.

  Further, the present invention is not limited by the above-described embodiment, and the present invention includes a configuration in which the above-described constituent elements are appropriately combined. In addition, all other embodiments, examples, operation techniques, and the like made by those skilled in the art based on the above-described embodiments are included in the present invention.

DESCRIPTION OF SYMBOLS 1 Printing apparatus 2 Coater pan 3 Resist ink 4 Gravure roll 5 Intaglio part 5a Gravure cell 5b Side 6 Non-recessed part 7,9 Blade 8 Offset roll 10 Backup roll 11 Drying apparatus 12 Etching apparatus 15 Steel strip 15a Etching process part 15b Etching prevention Target part 16 Etched part

Claims (6)

A gravure roll having an intaglio part formed by a plurality of concave parts and a non-concave part other than the intaglio part, and sequentially filling ink into the plurality of concave parts ;
An offset roll that sequentially transfers the ink in the plurality of recesses by the gravure roll, and sequentially prints the transferred ink on the surface of a long substrate that is continuously conveyed;
With
The volume of the concave part per unit area in the intaglio part is 6 [cm ³ / m ² ] or more and 50 [cm ³ / m ² ] or less, and the viscosity of the ink is 150 [mPa · s] or more. The pressure of the offset roll applied to the surface of the long base material is 12 [kg / m] or more and 100 [kg / m] or less , and the intaglio part and the non-printing part are not more than 2500 [mPa · s]. The printing apparatus is characterized in that an angle formed between a boundary line with a concave portion and an opening end side of each concave portion of the intaglio portion is 20 [deg.] Or less, or more than 70 [deg.] And 90 [deg.] Or less . The gravure roll, the printing apparatus according to claim 1, characterized in that the perforated and said non-recessed and the intaglio portion, so as to be arranged with regularity in the circumferential direction of the gravure roll.   The printing apparatus according to claim 1, wherein the ink is a resist ink. In a printing method for printing ink on the surface of a long substrate that is continuously conveyed using a gravure roll in which a plurality of concave portions constituting an intaglio portion and non-concave portions other than the intaglio portion are formed,
An ink pumping step of pumping up the ink by the gravure roll and sequentially filling the ink into the plurality of recesses;
A transfer printing step of sequentially transferring the ink in the plurality of recesses from the gravure roll to the offset roll, and transferring and printing the transferred ink from the offset roll to the surface of the long substrate;
Including
The volume of the concave portion per unit area in the intaglio portion is 6 [cm ³ / m ² ] or more and 50 [cm ³ / m ² ] or less, and the viscosity of the ink is 150 [mPa · s] or more and 2500 [mPa]. S] or less, and the pressure of the offset roll applied to the surface of the long base material is 12 [kg / m] or more and 100 [kg / m] or less , and the boundary line between the intaglio part and the non-recessed part The printing method according to claim 1, wherein an angle formed between the opening end side of each concave portion of the intaglio portion is 20 [deg.] Or less, or more than 70 [deg.] And 90 [deg.] Or less . The printing method according to claim 4, wherein the intaglio part and the non-recessed part are arranged on an outer peripheral surface of the gravure roll so as to have regularity in a circumferential direction of the gravure roll. The printing method according to claim 4, wherein a resist ink is used as the ink.

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