JP5984776B2 - 複合アミン吸収液、ｃｏ２又はｈ２ｓ又はその双方の除去装置及び方法 - Google Patents

複合アミン吸収液、ｃｏ２又はｈ２ｓ又はその双方の除去装置及び方法 Download PDF

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Publication number
JP5984776B2
JP5984776B2 JP2013215064A JP2013215064A JP5984776B2 JP 5984776 B2 JP5984776 B2 JP 5984776B2 JP 2013215064 A JP2013215064 A JP 2013215064A JP 2013215064 A JP2013215064 A JP 2013215064A JP 5984776 B2 JP5984776 B2 JP 5984776B2
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Japan
Prior art keywords
compound
amine compound
amine
disulfide
absorbent
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Expired - Fee Related
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JP2013215064A
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English (en)
Japanese (ja)
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JP2015077537A (ja
JP2015077537A5 (enExample
Inventor
田中　裕士
裕士 田中
琢也 平田
琢也 平田
大石　剛司
剛司 大石
遠藤　崇彦
崇彦 遠藤
晋平 川▲崎▼
晋平 川▲崎▼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kansai Electric Power Co Inc
Mitsubishi Heavy Industries Ltd
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Kansai Electric Power Co Inc
Mitsubishi Heavy Industries Ltd
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Priority to JP2013215064A priority Critical patent/JP5984776B2/ja
Application filed by Kansai Electric Power Co Inc, Mitsubishi Heavy Industries Ltd filed Critical Kansai Electric Power Co Inc
Priority to EP14853761.6A priority patent/EP3034152A4/en
Priority to CA2924300A priority patent/CA2924300A1/en
Priority to PCT/JP2014/077264 priority patent/WO2015056657A1/ja
Priority to AU2014335384A priority patent/AU2014335384B2/en
Priority to US15/022,125 priority patent/US20160220947A1/en
Publication of JP2015077537A publication Critical patent/JP2015077537A/ja
Publication of JP2015077537A5 publication Critical patent/JP2015077537A5/ja
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1462—Removing mixtures of hydrogen sulfide and carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1425—Regeneration of liquid absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1468—Removing hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1475—Removing carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493—Selection of liquid materials for use as absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18—Absorbing units; Liquid distributors therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20405—Monoamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/2041—Diamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20421—Primary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20426—Secondary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20431—Tertiary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20436—Cyclic amines
    • B01D2252/20442—Cyclic amines containing a piperidine-ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20436—Cyclic amines
    • B01D2252/20447—Cyclic amines containing a piperazine-ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20478—Alkanolamines
    • B01D2252/20484—Alkanolamines with one hydroxyl group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20478—Alkanolamines
    • B01D2252/20489—Alkanolamines with two or more hydroxyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/205—Other organic compounds not covered by B01D2252/00 - B01D2252/20494
    • B01D2252/2056—Sulfur compounds, e.g. Sulfolane, thiols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/50—Combinations of absorbents
    • B01D2252/502—Combinations of absorbents having two or more functionalities in the same molecule other than alkanolamine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/50—Combinations of absorbents
    • B01D2252/504—Mixtures of two or more absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/60—Additives
    • B01D2252/604—Stabilisers or agents inhibiting degradation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2013215064A 2013-10-15 2013-10-15 複合アミン吸収液、ｃｏ２又はｈ２ｓ又はその双方の除去装置及び方法 Expired - Fee Related JP5984776B2 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
JP2013215064A JP5984776B2 (ja) 2013-10-15 2013-10-15 複合アミン吸収液、ｃｏ２又はｈ２ｓ又はその双方の除去装置及び方法
CA2924300A CA2924300A1 (en) 2013-10-15 2014-10-10 Composite amine absorbent, and apparatus and method for removing co2 and/or h2s
PCT/JP2014/077264 WO2015056657A1 (ja) 2013-10-15 2014-10-10 複合アミン吸収液、ｃｏ２又はｈ２ｓ又はその双方の除去装置及び方法
AU2014335384A AU2014335384B2 (en) 2013-10-15 2014-10-10 Composite amine absorption solution, and method and device for removing CO2 and/or H2S
EP14853761.6A EP3034152A4 (en) 2013-10-15 2014-10-10 COMPOUND AMINE ABSORPTION SOLUTION AND PROCESS AND DEVICE FOR REMOVING CO2 AND / OR H2S
US15/022,125 US20160220947A1 (en) 2013-10-15 2014-10-10 Composite amine absorbent, and apparatus and method for removing co2 and/or h2s

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JP2013215064A JP5984776B2 (ja) 2013-10-15 2013-10-15 複合アミン吸収液、ｃｏ２又はｈ２ｓ又はその双方の除去装置及び方法

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JP2015077537A JP2015077537A (ja) 2015-04-23
JP2015077537A5 JP2015077537A5 (enExample) 2015-06-18
JP5984776B2 true JP5984776B2 (ja) 2016-09-06

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US (1) US20160220947A1 (enExample)
EP (1) EP3034152A4 (enExample)
JP (1) JP5984776B2 (enExample)
AU (1) AU2014335384B2 (enExample)
CA (1) CA2924300A1 (enExample)
WO (1) WO2015056657A1 (enExample)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA3003795A1 (en) * 2015-11-09 2017-05-18 Shell Internationale Research Maatschappij B.V. Process for removing mercaptans from a gas stream
US10710020B2 (en) * 2017-06-30 2020-07-14 Uop Llc Processes for gas separation by solvent or absorbent
CN108854459B (zh) * 2018-09-25 2022-03-15 天津工业大学 一种低能耗无水co2相变吸收剂及再生方法和应用
JP7178911B2 (ja) * 2019-01-24 2022-11-28 三菱重工エンジニアリング株式会社 複合アミン吸収液、ｃｏ２又はｈ２ｓ又はその双方の除去装置及び方法
JP2025086680A (ja) * 2023-11-28 2025-06-09 川崎重工業株式会社 固体吸収材ならびにそれを用いた酸性ガスの吸収および脱離方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4020144A (en) * 1975-05-02 1977-04-26 Exxon Research And Engineering Company Method for removal of gaseous sulfur and nitrogen compounds from gas streams
US4804485A (en) * 1987-05-08 1989-02-14 Pennwalt Corporation Polyalkyleneoxyamine catalysts for dialkyl disulfides and/or polysulfides used in dissolving sulfur
US4959177A (en) * 1987-10-09 1990-09-25 Shell Oil Company Reducing stress corrosion cracking in treating gases with alkanol amines
JPH0751537A (ja) 1993-06-30 1995-02-28 Mitsubishi Heavy Ind Ltd Ｃｏ２ 含有ガス中のｃｏ２ を除去する方法
JP4690659B2 (ja) 2004-03-15 2011-06-01 三菱重工業株式会社 Ｃｏ２回収装置
FR2877858B1 (fr) * 2004-11-12 2007-01-12 Inst Francais Du Petrole Procede de desacidification d'un gaz avec une solution absorbante a regeneration fractionnee
EP1872846B1 (en) * 2005-04-04 2013-07-24 Mitsubishi Heavy Industries, Ltd. Absorbing solution and method for absorbing co2 or h2s or both
FR2898284B1 (fr) * 2006-03-10 2009-06-05 Inst Francais Du Petrole Procede de desacidification d'un gaz par solution absorbante avec regeneration fractionnee par chauffage.
JP5215595B2 (ja) * 2007-06-18 2013-06-19 三菱重工業株式会社 吸収液、吸収液を用いたｃｏ２又はｈ２ｓ除去装置及び方法
FR2933001B1 (fr) * 2008-06-27 2010-08-20 Inst Francais Du Petrole Solution absorbante contenant un inhibiteur de degradation a fonction thiocarbonyle et methode pour limiter la degradation d'une solution absorbante
ES2443307T3 (es) * 2009-02-02 2014-02-18 Basf Se Absorbente que comprende aminas cíclicas para la eliminación de gases ácidos
WO2012076378A1 (en) * 2010-12-06 2012-06-14 Shell Internationale Research Maatschappij B.V. Process for removing mercaptans from a gas stream
JP5659127B2 (ja) * 2010-12-22 2015-01-28 株式会社東芝 酸性ガス吸収剤、酸性ガス除去方法および酸性ガス除去装置
JP5659084B2 (ja) * 2011-05-30 2015-01-28 株式会社東芝 酸性ガス吸収剤、酸性ガス除去方法および酸性ガス除去装置

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Publication number Publication date
WO2015056657A1 (ja) 2015-04-23
EP3034152A4 (en) 2016-12-21
AU2014335384B2 (en) 2017-03-16
JP2015077537A (ja) 2015-04-23
EP3034152A1 (en) 2016-06-22
AU2014335384A1 (en) 2016-04-07
US20160220947A1 (en) 2016-08-04
CA2924300A1 (en) 2015-04-23

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