AU2014335384B2 - Composite amine absorption solution, and method and device for removing CO2 and/or H2S - Google Patents

Composite amine absorption solution, and method and device for removing CO2 and/or H2S Download PDF

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Publication number
AU2014335384B2
AU2014335384B2 AU2014335384A AU2014335384A AU2014335384B2 AU 2014335384 B2 AU2014335384 B2 AU 2014335384B2 AU 2014335384 A AU2014335384 A AU 2014335384A AU 2014335384 A AU2014335384 A AU 2014335384A AU 2014335384 B2 AU2014335384 B2 AU 2014335384B2
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AU
Australia
Prior art keywords
compound
absorbent
amine
amine compound
composite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU2014335384A
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English (en)
Other versions
AU2014335384A1 (en
Inventor
Takahiko Endo
Takuya Hirata
Shimpei KAWASAKI
Tsuyoshi Oishi
Hiroshi Tanaka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kansai Electric Power Co Inc
Mitsubishi Heavy Industries Ltd
Original Assignee
Kansai Electric Power Co Inc
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kansai Electric Power Co Inc, Mitsubishi Heavy Industries Ltd filed Critical Kansai Electric Power Co Inc
Publication of AU2014335384A1 publication Critical patent/AU2014335384A1/en
Application granted granted Critical
Publication of AU2014335384B2 publication Critical patent/AU2014335384B2/en
Ceased legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1425—Regeneration of liquid absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1462—Removing mixtures of hydrogen sulfide and carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1468—Removing hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1475—Removing carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493—Selection of liquid materials for use as absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18—Absorbing units; Liquid distributors therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20405—Monoamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/2041—Diamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20421—Primary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20426—Secondary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20431—Tertiary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20436—Cyclic amines
    • B01D2252/20442—Cyclic amines containing a piperidine-ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20436—Cyclic amines
    • B01D2252/20447—Cyclic amines containing a piperazine-ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20478—Alkanolamines
    • B01D2252/20484—Alkanolamines with one hydroxyl group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20478—Alkanolamines
    • B01D2252/20489—Alkanolamines with two or more hydroxyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/205—Other organic compounds not covered by B01D2252/00 - B01D2252/20494
    • B01D2252/2056—Sulfur compounds, e.g. Sulfolane, thiols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/50—Combinations of absorbents
    • B01D2252/502—Combinations of absorbents having two or more functionalities in the same molecule other than alkanolamine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/50—Combinations of absorbents
    • B01D2252/504—Mixtures of two or more absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/60—Additives
    • B01D2252/604—Stabilisers or agents inhibiting degradation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
AU2014335384A 2013-10-15 2014-10-10 Composite amine absorption solution, and method and device for removing CO2 and/or H2S Ceased AU2014335384B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2013-215064 2013-10-15
JP2013215064A JP5984776B2 (ja) 2013-10-15 2013-10-15 複合アミン吸収液、ｃｏ２又はｈ２ｓ又はその双方の除去装置及び方法
PCT/JP2014/077264 WO2015056657A1 (ja) 2013-10-15 2014-10-10 複合アミン吸収液、ｃｏ２又はｈ２ｓ又はその双方の除去装置及び方法

Publications (2)

Publication Number Publication Date
AU2014335384A1 AU2014335384A1 (en) 2016-04-07
AU2014335384B2 true AU2014335384B2 (en) 2017-03-16

Family

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Family Applications (1)

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AU2014335384A Ceased AU2014335384B2 (en) 2013-10-15 2014-10-10 Composite amine absorption solution, and method and device for removing CO2 and/or H2S

Country Status (6)

Country Link
US (1) US20160220947A1 (enExample)
EP (1) EP3034152A4 (enExample)
JP (1) JP5984776B2 (enExample)
AU (1) AU2014335384B2 (enExample)
CA (1) CA2924300A1 (enExample)
WO (1) WO2015056657A1 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EA035776B1 (ru) * 2015-11-09 2020-08-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ удаления меркаптанов из газового потока
US10710020B2 (en) * 2017-06-30 2020-07-14 Uop Llc Processes for gas separation by solvent or absorbent
CN108854459B (zh) * 2018-09-25 2022-03-15 天津工业大学 一种低能耗无水co2相变吸收剂及再生方法和应用
JP7178911B2 (ja) 2019-01-24 2022-11-28 三菱重工エンジニアリング株式会社 複合アミン吸収液、ｃｏ２又はｈ２ｓ又はその双方の除去装置及び方法
JP2025086680A (ja) * 2023-11-28 2025-06-09 川崎重工業株式会社 固体吸収材ならびにそれを用いた酸性ガスの吸収および脱離方法
CN121177915A (zh) * 2025-10-31 2025-12-23 华碳科技(扬州)有限公司 一种适用于低压工业烟气co2捕集的抗降解型复合胺吸收体系及其使用方法
CN121971958B (zh) * 2026-04-07 2026-06-23 合肥工业大学 一种非对称结构双仲胺基丙二胺碳捕集剂及制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012143745A (ja) * 2010-12-22 2012-08-02 Toshiba Corp 酸性ガス吸収剤、酸性ガス除去方法および酸性ガス除去装置

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US4020144A (en) * 1975-05-02 1977-04-26 Exxon Research And Engineering Company Method for removal of gaseous sulfur and nitrogen compounds from gas streams
US4804485A (en) * 1987-05-08 1989-02-14 Pennwalt Corporation Polyalkyleneoxyamine catalysts for dialkyl disulfides and/or polysulfides used in dissolving sulfur
US4959177A (en) * 1987-10-09 1990-09-25 Shell Oil Company Reducing stress corrosion cracking in treating gases with alkanol amines
JPH0751537A (ja) 1993-06-30 1995-02-28 Mitsubishi Heavy Ind Ltd Ｃｏ２ 含有ガス中のｃｏ２ を除去する方法
JP4690659B2 (ja) 2004-03-15 2011-06-01 三菱重工業株式会社 Ｃｏ２回収装置
FR2877858B1 (fr) * 2004-11-12 2007-01-12 Inst Francais Du Petrole Procede de desacidification d'un gaz avec une solution absorbante a regeneration fractionnee
CA2576454C (en) * 2005-04-04 2010-06-08 Mitsubishi Heavy Industries, Ltd. Absorbing solution that removes any one of co2 and h2s or both, and method and apparatus that uses the absorbing solution
FR2898284B1 (fr) * 2006-03-10 2009-06-05 Inst Francais Du Petrole Procede de desacidification d'un gaz par solution absorbante avec regeneration fractionnee par chauffage.
JP5215595B2 (ja) * 2007-06-18 2013-06-19 三菱重工業株式会社 吸収液、吸収液を用いたｃｏ２又はｈ２ｓ除去装置及び方法
FR2933001B1 (fr) * 2008-06-27 2010-08-20 Inst Francais Du Petrole Solution absorbante contenant un inhibiteur de degradation a fonction thiocarbonyle et methode pour limiter la degradation d'une solution absorbante
JP5679995B2 (ja) * 2009-02-02 2015-03-04 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 酸性ガスの除去のための環式アミン含有吸収剤
CN103237587B (zh) * 2010-12-06 2016-02-17 国际壳牌研究有限公司 用于从气流中除去硫醇的方法
JP5659084B2 (ja) * 2011-05-30 2015-01-28 株式会社東芝 酸性ガス吸収剤、酸性ガス除去方法および酸性ガス除去装置

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012143745A (ja) * 2010-12-22 2012-08-02 Toshiba Corp 酸性ガス吸収剤、酸性ガス除去方法および酸性ガス除去装置

Also Published As

Publication number Publication date
EP3034152A4 (en) 2016-12-21
US20160220947A1 (en) 2016-08-04
CA2924300A1 (en) 2015-04-23
JP5984776B2 (ja) 2016-09-06
WO2015056657A1 (ja) 2015-04-23
JP2015077537A (ja) 2015-04-23
AU2014335384A1 (en) 2016-04-07
EP3034152A1 (en) 2016-06-22

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FGA Letters patent sealed or granted (standard patent)
MK14 Patent ceased section 143(a) (annual fees not paid) or expired