JP5977345B2 - 組み込みアジュバントを含む除草剤乳剤 - Google Patents
組み込みアジュバントを含む除草剤乳剤 Download PDFInfo
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
- A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/60—1,4-Diazines; Hydrogenated 1,4-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
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- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
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- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
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Description
本出願は、その全体が参照により本明細書に組み込まれる、2011年6月22日出願の米国仮特許出願第61/499879号の利益を主張する。
a)総組成物に対して1リットル当たり約25グラム(g/L)〜約225g/Lを構成するアリールオキシフェノキシプロピオン酸除草剤と;
b)総組成物に対して約600g/L〜約950g/Lを構成する非石油由来組み込みアジュバントと;
c)総組成物に対して約10g/L〜約150g/Lを構成する界面活性剤と
を含み、除草剤と非石油由来組み込みアジュバントの重量比が約1:3〜約1:33である、組み込みアジュバントを含有する除草剤乳剤に関する。
a)総組成物に対して約25gai/L〜約225gai/Lのシハロホップブチルを含むアリールオキシフェノキシプロピオン酸除草剤有効成分と;
b)総組成物に対して約600g/L〜約950g/Lのダイズ油脂肪酸メチルを含む非石油由来組み込みアジュバントと;
c)総組成物に対して約10g/L〜約150g/Lのポリグリコール26−2を含む界面活性剤と
を含み、シハロホップブチルとダイズ油脂肪酸メチルの重量比は約1:3〜約1:33である。
溶融シハロホップブチルをダイズ油脂肪酸メチルアジュバント(Agnique(登録商標)ME 18S−U;Cognisの登録商標)および乳化剤と混合して表1に示す組成物を得ることにより、本発明の乳剤を調製する。
模擬水田調製:無機質土壌2kgおよび蒸留水500mlを容器(4.163L(1.1ガロン)、15cm ht×20.55cm直径、HDPE丸形容器;処理目的で、表面積を、1ヘクタールが108cm2に相当するとして331cm2として計算する)に添加し、スパーテルで約5分間徹底的に混合して、滑らかな泥混合物を作った。泥を混合したら、容器の中央を横切って3cmの畝間を作り、そこに18g(0.6oz.)Osmocote(登録商標)(The Scotts Company LCCまたはその関連会社の登録商標;17:6:10 N:P:K)を添加する。次いで、Osmocote(登録商標)が土壌表面より下になるよう維持しながら、畝間を塞ぐ。
雑草植物−チャイニーズスプラングルトップ、レプトクロアキネンシス(Leptochloa chinensis)(LEFCH):小さい容器中で、無機質土壌80グラムを蒸留水40ミリリットル(mL)と混合して、粘着性スラリーを作る。レプトクロア(Leptochloa)種子1/4tsp(2〜4000個)をスラリーに添加し、徹底的に混合して種子を均等に分布させる。このスラリー約3グラムを各容器の片側に調製した泥の頂上に配置し、容器を横切って1〜2cmのバンドに薄く伸ばす。これは、1鉢当たり25〜50植物を産する。透明な収縮包装フィルムを使用して、テラリウムとしての役割を果たす容器を覆う。レプトクロア(Leptochloa)種子が発芽するまで、約5日間、マスキングテープにより包装フィルムを固定する。被覆した鉢を温室中18〜22℃の定温および50〜60%相対湿度に維持する。自然光に500のマイクロアインシュタイン(μEm)−2s−1光合成有効放射(PAR)の平均照度の1000ワット金属ハロゲン化物頭上ランプで補った。日長は16時間とした。
植物が適当なサイズ(種々の種の成長段階は2〜4葉期に及んだ)に達したら、各植物の1〜2cmを表面より上にして容器を蒸留水で3cmの深さまで浸水する。表面積に調節した率で、液体製剤として除草剤処理剤を水田水に直接施用する。処理を2〜3回反復する。時折、未処理防除植物と比較して0〜100%のスケールで視覚的傷害の割合および雑草防除評価を行った(0は傷害無しまたは対照に相当し、100は植物の完全な枯死に相当する)。
Claims (19)
- a)組成物に対して1リットル当たり25グラム(g/L)〜225g/Lのアリールオキシフェノキシプロピオン酸除草剤と;
b)組成物に対して600g/L〜950g/Lの非石油由来組み込みアジュバントと;
c)組成物に対して10g/L〜150g/Lの非イオン性界面活性剤と
を含み、前記非石油由来組み込みアジュバントは植物、藻類もしくは動物由来油または植物、藻類もしくは動物由来油のC 1 〜C 10 エステルの少なくとも1種であり、前記除草剤と前記非石油由来組み込みアジュバントの重量比が1:3〜1:33である、除草剤乳剤組成物。 - 前記アリールオキシフェノキシプロピオン酸除草剤がシハロホップブチル、フェノキサプロップエチル、フルアジホップPブチル、ハロキシホップメチル、ハロキシホップRメチル、メタミホップ、プロパキザホップ、キザロホップPエチルまたはキザロホップPテフリルである、請求項1に記載の組成物。
- 前記アリールオキシフェノキシプロピオン酸除草剤がシハロホップブチルである、請求項1に記載の組成物。
- 組成物に対して25g/L〜150g/Lの前記アリールオキシフェノキシプロピオン酸を含む、請求項1に記載の組成物。
- 1種または複数の追加の不活性成分をさらに含む、請求項1に記載の組成物。
- 植物、藻類または動物由来油の前記C1〜C10エステルがダイズ油脂肪酸メチルである、請求項1に記載の組成物。
- 600g/L〜850g/Lの前記非石油由来組み込みアジュバントを含む、請求項1に記載の組成物。
- 前記界面活性剤がアルキルフェノール−アルキレンオキシド付加物、ソルビトールエステル、脂肪酸のポリエチレングリコールエステル、エチレンオキシドおよびプロピレンオキシドのブロック共重合体、またはこれらの混合物である、請求項1に記載の組成物。
- 50g/L〜150g/Lの前記界面活性剤を含む、請求項1に記載の組成物。
- 前記除草剤と前記非石油由来組み込みアジュバントの重量比が1:4〜1:33である、請求項1に記載の組成物。
- (A)前記アリールオキシフェノキシプロピオン酸除草剤がシハロホップブチル、フェノキサプロップエチル、フルアジホップPブチル、ハロキシホップメチル、ハロキシホップRメチル、メタミホップ、プロパキザホップ、キザロホップPエチルまたはキザロホップPテフリルであり;
(B)前記非石油由来組み込みアジュバントが植物、藻類もしくは動物由来油または植物、藻類もしくは動物由来油のC1〜C10エステルの少なくとも1種であり;
(C)前記界面活性剤がアルキルフェノール−アルキレンオキシド付加物、ソルビトールエステル、脂肪酸のポリエチレングリコールエステル、エチレンオキシドおよびプロピレンオキシドのブロック共重合体、またはこれらの混合物である、
請求項1に記載の組成物。 - 前記アリールオキシフェノキシプロピオン酸除草剤がシハロホップブチルであり;前記非石油由来組み込みアジュバントがダイズ油脂肪酸メチルであり;前記界面活性剤がポリグリコール26−2である、請求項1に記載の組成物。
- 1種または複数の追加の殺有害生物剤有効成分をさらに含む、請求項1に記載の組成物。
- 除草剤解毒剤をさらに含む、請求項1に記載の組成物。
- 望ましくない植生またはその隣接領域に請求項1に記載の乳剤またはその希釈物を接触させるステップを含む、望ましくない植生を防除する方法。
- (A)葉に請求項1に記載の組成物またはその希釈物を噴霧するステップ、または
(B)請求項1に記載の組成物を水中環境に潅注または添加するステップ
を含む、水中環境の望ましくない植生を防除する方法。 - 前記水中環境が湛水田または畑である、請求項16に記載の方法。
- (A)または(B)が前記望ましくない植生の発生前に行われる、請求項16に記載の方法。
- (A)または(B)が前記望ましくない植生の発生後に行われる、請求項16に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201161499879P | 2011-06-22 | 2011-06-22 | |
US61/499,879 | 2011-06-22 | ||
PCT/US2012/043478 WO2012177832A1 (en) | 2011-06-22 | 2012-06-21 | Herbicide emulsifiable concentrates with built-in adjuvant |
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JP2014520154A JP2014520154A (ja) | 2014-08-21 |
JP5977345B2 true JP5977345B2 (ja) | 2016-08-24 |
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US (2) | US9247731B2 (ja) |
EP (1) | EP2723171A4 (ja) |
JP (1) | JP5977345B2 (ja) |
KR (1) | KR102002184B1 (ja) |
CN (2) | CN103687485A (ja) |
AR (1) | AR086728A1 (ja) |
AU (1) | AU2012272925B2 (ja) |
BR (1) | BR102012017225B1 (ja) |
CL (1) | CL2013003649A1 (ja) |
CO (1) | CO6852093A2 (ja) |
IL (1) | IL229979A (ja) |
IN (1) | IN2014DN00073A (ja) |
MX (1) | MX341077B (ja) |
MY (1) | MY164944A (ja) |
PE (1) | PE20140870A1 (ja) |
RU (1) | RU2606771C2 (ja) |
TW (1) | TWI601481B (ja) |
UA (1) | UA113964C2 (ja) |
WO (1) | WO2012177832A1 (ja) |
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PE20141327A1 (es) * | 2011-06-22 | 2014-10-03 | Dow Agrosciences Llc | Granulos de herbicida con adyuvante integrado |
BR102012027933A2 (pt) * | 2011-11-01 | 2015-11-17 | Dow Agrosciences Llc | composições pesticidas estáveis |
WO2014092704A1 (en) * | 2012-12-12 | 2014-06-19 | Galata Chemicals Llc | Bio-based biocide compositions and methods of preserving therewith |
RU2693723C2 (ru) * | 2014-06-10 | 2019-07-04 | ДАУ АГРОСАЙЕНСИЗ ЭлЭлСи | Твердые гербицидные композиции, содержащие антидот |
MX2016013287A (es) | 2014-10-09 | 2017-01-18 | Huntsman Petrochemical Llc | Acondicionadores de agua con sulfato de alcanolamina. |
CN107136079B (zh) * | 2017-05-12 | 2020-01-07 | 扬州大学 | 一种氰氟草酯水乳剂及其制备方法 |
US10306888B2 (en) * | 2017-08-24 | 2019-06-04 | Valent U.S.A., Llc | Imazosulfuron mixtures |
MX2020002043A (es) * | 2017-08-24 | 2020-03-24 | Valent Usa Llc | Mezclas de inhibidores de la protoporfirinogeno oxidasa. |
CA3014953A1 (en) * | 2017-08-24 | 2019-02-24 | Valent U.S.A. Llc | Bispyribac mixtures |
JP7369707B2 (ja) | 2018-10-10 | 2023-10-26 | クミアイ化学工業株式会社 | 油性懸濁農薬組成物 |
BR112022004662A2 (pt) * | 2019-09-16 | 2022-05-31 | Eastman Chem Co | Combinação de composições, kit, métodos para matar pragas e ervas daninhas ao redor das plantas e para aumentar o crescimento de plantas, e, uso da combinação de composições |
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ES2032793T3 (es) * | 1985-03-25 | 1993-03-01 | Dowelanco | Procedimiento para preparar fosforotioactos y fosfatos. |
CN1325269B (zh) * | 1998-11-04 | 2010-04-21 | 辛根塔参与股份公司 | 除草组合物 |
DE10020671A1 (de) | 2000-04-27 | 2001-11-08 | Aventis Cropscience Gmbh | Flüssige Formulierungen |
WO2005048706A2 (en) * | 2003-11-17 | 2005-06-02 | Syngenta Participations Ag | Emulsifiable concentrates containing adjuvants |
EP1933621A1 (en) | 2005-09-16 | 2008-06-25 | Nufarm Australia Limited | Herbicide composition |
US20070184980A1 (en) * | 2006-01-25 | 2007-08-09 | Helena Holding Company | Manufacture and use of herbicide chlorinated phenoxy formulation |
ATE500729T1 (de) * | 2007-08-30 | 2011-03-15 | Dow Agrosciences Llc | Formulierung für eine stabile emulsion zur verhinderung von übergängen an einer wasser-öl- schnittstelle |
CN101401569B (zh) * | 2008-11-13 | 2011-01-05 | 湖南大方农化有限公司 | 环保型水稻田漂浮性农化制剂及其制备方法 |
CN101606517B (zh) * | 2009-07-27 | 2013-03-20 | 深圳诺普信农化股份有限公司 | 一种农药乳油制剂 |
CN102027902A (zh) | 2009-09-28 | 2011-04-27 | 南京华洲药业有限公司 | 一种含氰氟草酯与2,4-二氯苯氧乙酸的增效除草组合物及其应用 |
JP5764567B2 (ja) | 2009-10-28 | 2015-08-19 | ダウ アグロサイエンシィズ エルエルシー | フルロキシピル及びシハロホップ、メタミホップ又はプロホキシジムを含有する相乗的除草剤組成物 |
CN101785457A (zh) | 2010-02-25 | 2010-07-28 | 深圳诺普信农化股份有限公司 | 一种水稻田除草油悬浮剂及其制备方法 |
CN101785465A (zh) * | 2010-02-25 | 2010-07-28 | 深圳诺普信农化股份有限公司 | 一种水稻田除草可分散液剂及其制备 |
CN101953340A (zh) | 2010-06-03 | 2011-01-26 | 深圳诺普信农化股份有限公司 | 一种含氰氟草酯的除草油悬剂组合物 |
CN101961011A (zh) | 2010-10-12 | 2011-02-02 | 北京颖新泰康国际贸易有限公司 | 一种除草剂组合物及其应用 |
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MX2013015318A (es) | 2014-02-17 |
CL2013003649A1 (es) | 2014-10-03 |
JP2014520154A (ja) | 2014-08-21 |
AR086728A1 (es) | 2014-01-15 |
RU2014100244A (ru) | 2015-07-27 |
MY164944A (en) | 2018-02-15 |
US20120329651A1 (en) | 2012-12-27 |
CN103687485A (zh) | 2014-03-26 |
EP2723171A1 (en) | 2014-04-30 |
IL229979A (en) | 2016-12-29 |
UA113964C2 (xx) | 2017-04-10 |
AU2012272925A1 (en) | 2014-01-23 |
US9247731B2 (en) | 2016-02-02 |
CO6852093A2 (es) | 2014-01-30 |
BR102012017225A2 (pt) | 2014-01-14 |
WO2012177832A1 (en) | 2012-12-27 |
US9456603B2 (en) | 2016-10-04 |
US20160044920A1 (en) | 2016-02-18 |
EP2723171A4 (en) | 2015-01-14 |
KR102002184B1 (ko) | 2019-07-19 |
RU2606771C2 (ru) | 2017-01-10 |
TWI601481B (zh) | 2017-10-11 |
BR102012017225B1 (pt) | 2019-06-18 |
MX341077B (es) | 2016-08-04 |
TW201302060A (zh) | 2013-01-16 |
NZ618877A (en) | 2016-09-30 |
KR20140037191A (ko) | 2014-03-26 |
CN110250182A (zh) | 2019-09-20 |
IN2014DN00073A (ja) | 2015-05-15 |
AU2012272925B2 (en) | 2016-03-17 |
PE20140870A1 (es) | 2014-07-18 |
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