JP5972588B2 - Manufacturing method of sintered bearing - Google Patents

Description

  The present invention relates to a method for manufacturing a sintered bearing made of a sintered metal.

  For example, as a bearing for a precision small motor mounted on an information device such as a hard disk drive, a sintered bearing excellent in quietness may be used. With the recent high performance of motors, this type of sintered bearing is required to improve the limit PV value to PV> 200 MPa · m / min. Further, it is also necessary to reduce torque fluctuations (improvement of initial conformability), improve durability (improve seizure resistance), improve quietness (improve acoustic characteristics), and the like.

  Iron-based sintered bearings are known as sintered bearings, but iron-based ones have the disadvantage that they are inferior in initial conformability and quietness, although they are excellent in durability. Therefore, bronze sintered bearings are often used as bearings for precision small motors. As an example of a bronze-based sintered oil-impregnated bearing, for example, JP 2001-107162 A (Patent Document 1) contains 6 to 11% by weight of Sn, 1 to 5% by weight of Fe and / or Ni, and the balance is copper. Is disclosed (claim 1).

  Patent No. 3873275 (Patent Document 2) uses iron-based and copper-based raw material powder, the copper-based raw material powder is a flat powder, segregates copper on the surface side, and moves from the surface side toward the inside. A sliding component in which the ratio of copper is reduced and the ratio of iron is increased is disclosed (claim 1). Also, by filling the filling part with copper-based raw material powder and iron-based raw material powder and applying vibration, the copper-based flat powder is segregated to the surface side, the surface side is covered with copper, and from the surface side to the inside Thus, a bearing having a concentration gradient in which the ratio of iron is higher than copper is obtained (paragraph 0028).

JP 2001-107162 A Japanese Patent No. 3873275

  In recent years, the price of copper has soared, and bronze sintered bearings containing a large amount of copper as described in Patent Document 1 cannot meet the demand for cost reduction.

  In that respect, in the sintered bearing using the flat copper powder as described in Patent Document 2, the amount of copper powder used can be suppressed, and the cost can be reduced. However, since the apparent density of the flat copper powder is considerably smaller than the other powders contained in the raw material powder, when each powder containing the flat copper powder is mixed at the same time, the flat copper powder is uniformly dispersed in the raw powder. It is difficult to let Therefore, the content ratio of flat copper powder differs in individual bearings during mass production of sintered bearings, and as a result, the bearing performance may become unstable.

  Therefore, the present invention uses flat copper powder to reduce the amount of copper used and reduce the cost of sintered bearings, while suppressing variation in the content of flat copper powder during mass production. It aims at providing the manufacturing method of the sintered bearing from which the stable bearing performance is obtained by this.

To achieve the above object, the raw material manufacturing method of sintered bearing according to the present invention, including iron powder, and more flattened copper powder aspect ratio 13.3, and the low melting point metal powder, a solid lubricant powder When the powder is mixed and filled into the mold, and the green compact molded with the mold is sintered to produce a sintered bearing, the solid lubricant powder is made into a foil shape, and the raw material powder is mixed into a flat copper powder. In addition, it is characterized in that it is divided into primary mixing in which the solid lubricant powder is mixed and then secondary mixing in which iron powder and low melting point metal powder are added and mixed.

  In general, flat copper powder and foil-like solid lubricant powder tend to adhere to each other. Therefore, when the flat copper powder and the foil-like solid lubricant powder are mixed in advance by primary mixing, the flat copper powder and the solid lubricant powder can be adhered to each other and stacked in layers. As a result, the apparent density of the flat copper powder is increased, so that it is possible to uniformly disperse the flat copper powder in the raw material powder even when the iron powder and the low melting point metal powder are added and mixed by secondary mixing. Become. As a result, the amount of flat copper powder contained in each sintered bearing can be made uniform during mass production, and the bearing performance can be stabilized. An example of a foil-like solid lubricant powder is scaly graphite.

  If the green compact is formed with the raw material powder filled in the mold and the flat copper powder adhered to the mold forming surface in layers, the surface of the green compact after molding contains a lot of copper. In the core, the copper content is reduced. Therefore, a surface layer with a high copper content and a base portion with a lower copper content are formed in the sintered body after sintering. In this case, many foil-like solid lubricants are attached to the mold surface along with the flat copper powder, so that the content of the solid lubricant as well as copper can be increased on the surface of the green compact. This is more effective in reducing the friction of the bearing surface.

  Thus, by increasing the content of copper in the surface layer, it is possible to improve initial conformability and quietness. In addition, since the aggression against the shaft is reduced, the durability life is improved. These functions and effects can be obtained more conspicuously by forming a copper structure (structure containing copper as a main component) having a surface ratio of 60% or more on the surface of the surface layer.

  If the fluid lubricant is adhered to the flat copper powder before the primary mixing, the adhesion force to the foil-like solid lubricant and further the adhesion force of the flat copper powder to the mold forming surface are increased. If the ratio of the fluid lubricant to the flat copper powder is too small, the adhesion of the flat copper powder to the mold will be reduced, and the amount of flat copper powder on the mold forming surface will be insufficient. Moreover, when there is too much, flat copper powder will adhere and the problem which aggregates arises. According to the verification by the present inventors, 0.1 wt% to 0.8 wt%, preferably 0.2 wt% to 0.7 wt% of a fluid lubricant is blended in a weight ratio to the flat copper powder. It was found that the above problems can be solved.

As the fluid lubricant, fatty acids, particularly linear saturated fatty acids are preferred. This type of fatty acid is represented by the general formula C _n-1 H _2n-1 COOH. In the present invention, it is desirable to use one having a Cn in the range of 12-22.

If the apparent density of the flat copper powder is 1.0 g / cm ³ or less, the thickness is 1.5 μm or less, and the length is 20 μm or more and 80 μm or less, the adhesion to the mold surface is further increased, and the copper content A large number of surface layers can be reliably formed.

  If the ratio of the flat copper powder in the raw material powder is 8% by weight or more, a sufficient amount of the flat copper powder can be adhered to the molding surface.

  If only flat copper powder is used as the copper powder, the density of the flat copper powder is small, so that it is difficult to solidify during compacting of the green compact. Therefore, the moldability of a green compact can be improved by adding copper powder normally and using it together with flat copper powder. This normal copper powder can be uniformly dispersed in the raw material powder by adding and mixing during secondary mixing.

  In order to reduce the aggressiveness to the shaft when the surface layer is worn and the base portion is exposed, the base portion S2 needs to have a copper structure of at least 10% by weight or more. Therefore, the blending ratio of the copper powder in the raw material powder is 18% by weight or more in total of the flat copper powder and the normal copper powder. On the other hand, when the proportion of the copper powder exceeds 40% by weight, the content of the iron structure in the base portion is insufficient, and the strength is reduced. Moreover, the usage-amount of copper powder becomes excessive and the cost merit by using flat copper powder becomes scarce. From the above, the ratio of the flat copper powder and the normal copper powder in the raw material powder is made 18 wt% to 40 wt% in total.

  Generally, as the content of the low melting point metal increases, the strength of the bearing increases accordingly. On the other hand, in the liquid phase state of Cu-Sn, the flat copper powder is rounded and spherical due to surface tension. When the spheroidized flat copper increases, the area occupied by the copper structure on the bearing surface decreases, and the object of the invention (improvement of initial conformability / quietness, reduction of attack on the counterpart material) cannot be achieved. From the above viewpoint, the ratio of the low melting point metal to copper is less than 10% by weight.

  If the iron structure is formed in the ferrite phase without reacting iron and carbon during sintering, even when the base part containing a large amount of iron structure (structure containing iron as a main component) is exposed due to wear of the surface layer, Since the iron structure is a ferrite phase, even if the copper content is small, the aggressiveness against the shaft can be weakened and the durability is increased.

  In this case, the iron structure of the base portion becomes a soft ferrite phase, but the base portion has high strength because the iron structure-copper structure and the copper structures are firmly bonded with a low melting point metal. Accordingly, the strength of the entire bearing is increased and the load resistance can be improved. The base portion occupies most of the volume of the bearing. However, since the copper content in the base portion can be reduced, the amount of copper used in the entire bearing can be reduced and the cost can be reduced.

  For this reason, the distribution of iron and copper in the bearing can be optimized, and both improvement in durability and cost reduction of the bearing can be achieved. Therefore, according to the said structure, the sintered bearing which has the advantage of both an iron-type sintered bearing and a copper-type sintered bearing (an iron-copper-type sintered bearing is also included) can be obtained at low cost.

  In order to sinter the iron in the green compact without reacting with carbon, it is desirable that the sintering temperature is 700 ° C. to 840 ° C. In this case, it is more desirable to sinter in an atmosphere containing no carbon.

  On the other hand, when the iron structure is formed only of the ferrite phase as described above, the wear resistance of the bearing surface may be lowered when the surface layer is worn and the base portion is exposed.

  In this case, if iron is reacted with carbon during sintering, and the iron structure is formed of a ferrite phase and a pearlite phase present at the grain boundary of the ferrite phase, the iron structure is a two-phase structure of a ferrite phase and a pearlite phase. Thus, since the hard pearlite phase supplements the wear resistance, the wear of the bearing surface can be suppressed. On the other hand, when carbon diffuses and the pearlite is present in excess, the aggression against the shaft increases and the shaft tends to wear. From this point of view, the pearlite is present at the grain boundaries of the ferrite phase (see FIG. 12).

  In order to form an iron structure with a ferrite phase and a pearlite phase existing at the grain boundary of ferrite, it is desirable that the sintering temperature is 820 ° C to 900 ° C. In this case, it is more desirable to sinter in an atmosphere containing carbon.

  According to the present invention, by using flat copper powder, the amount of copper used can be reduced and the cost of the sintered bearing can be reduced. In addition, since variation in the content of the flat copper powder in individual bearings during mass production is suppressed, a sintered bearing having stable bearing performance can be provided.

It is sectional drawing of a sintered bearing. The upper part is a side view of the flat copper powder, and the lower part is a plan view of the flat copper powder. It is a side view which shows the flat copper powder and scaly graphite which mutually adhered. It is sectional drawing which shows the formation process of the green compact by a metal mold | die. FIG. 5 is an enlarged sectional view of a region Q in FIG. 4. It is an organization chart showing the pearlite structure in steel. It is an expanded sectional view of the area | region P in FIG. It is a figure which shows the content rate of the copper in the radial direction of a bearing. It is a figure which shows the measurement result of initial conformability. It is a figure which shows the measurement result of a limit PV value. It is a figure which shows the measurement result of the abrasion loss which arises in a bearing after bearing operation. It is an organization chart showing the grain boundary organization of a base part. It is a component table | surface of the sintered bearing concerning this invention. It is a flowchart which shows the manufacturing method of the sintered bearing concerning this invention.

  Hereinafter, embodiments of the present invention will be described with reference to the accompanying drawings.

  As shown in FIG. 1, the sintered bearing 1 is formed in a cylindrical shape having a bearing surface 1a on the inner periphery. When the shaft 2 made of stainless steel or the like is inserted into the inner periphery of the sintered bearing 1 and the shaft is rotated in this state, or the bearing 1 is rotated, the lubricating oil retained in the countless holes of the sintered bearing 1 Oozes out to the bearing surface 1a as the temperature rises. The oil that has oozed out forms an oil film in the bearing gap between the outer peripheral surface of the shaft and the bearing surface 1 a, and the shaft 2 is supported by the bearing 1 so as to be relatively rotatable.

  The bearing 1 of the present invention is formed by filling raw material powder mixed with various powders in a mold, compressing this to form a green compact, and then sintering the green compact.

  The raw material powder is a mixed powder mainly composed of iron powder, copper powder, low melting point metal powder, and solid lubricant powder. To this mixed powder, various molding aids, for example, a lubricant (metal soap or the like) for improving releasability are added as necessary. Hereinafter, the raw material powder and the manufacturing procedure will be described in detail for the first embodiment of the sintered bearing.

[Iron powder]
As the iron powder, known powders such as reduced iron powder and water atomized iron powder can be widely used. In this embodiment, reduced iron powder excellent in oil impregnation is used. The reduced iron powder is also called spongy iron powder because it has a substantially spherical shape, an irregular shape and a porous shape, and a spongy shape having minute irregularities on the surface. As the iron powder, one having a particle size of 40 μm to 150 μm and an apparent density of about 2.0 to 2.8 g / cm ³ is used. The definition of the apparent density conforms to the rules of JIS Z 8901 (hereinafter the same). The amount of oxygen contained in the iron powder is 0.2% by weight or less.

[Copper powder]
As the copper powder, two types of foil-like flat copper powder and normal copper powder are used.

The flat copper powder is flattened by stamping raw material copper powder made of water atomized powder or the like. As the flat copper powder, one having a length L of 20 μm to 80 μm and a thickness t of 0.5 μm to 1.5 μm (aspect ratio L / t = 13.3 to 160) is mainly used. Here, “length” and “thickness” refer to the geometric maximum dimension of each flat copper powder 3 as shown in FIG. The apparent density of the flat copper powder is 1.0 g / cm ³ or less. If the flat copper powder has the above size and apparent density, the adhesion of the flat copper powder to the mold forming surface is increased, so that a large amount of flat copper powder can be attached to the mold forming surface.

Usually, as the copper powder, spherical and dendritic copper powders widely used for sintered bearings can be widely used. For example, reduced powder, electrolytic powder, water atomized powder and the like are used. These mixed powders can also be used. Usually, the particle size of copper powder is about 20 μm to 100 μm, and the apparent density is about 2.0 to 3.3 g / cm ³ . If only flat copper powder is used as the copper powder, the density of the flat copper powder will be small, so it will be hard to solidify when forming the green compact, but it is usually used together with the copper powder to form the green compact. Can increase the sex. In addition, if there is no particular problem, it is also possible to use only flat copper powder without using copper powder.

[Fluid lubricant]
In order to attach the flat copper powder to the molding surface, a fluid lubricant is previously attached to the flat copper powder. This fluid lubricant only needs to be attached to the flat copper powder before filling the raw material powder mold, preferably before mixing the raw material powder (primary mixing), more preferably at the stage of crushing the raw material copper powder. Adhere to copper powder. The fluid lubricant may be attached to the flat copper powder by means such as supplying the fluid lubricant to the flat copper powder and stirring it after mixing and before mixing with other raw material powders. In order to secure the amount of flat copper powder adhering to the molding surface, the ratio of the fluid lubricant to the flat copper powder should be 0.1% by weight or more, and aggregation due to the adhesion of flat copper powder is prevented. Therefore, the ratio is 0.8% by weight or less. Desirably, the lower limit of the ratio is 0.2% by weight or more, and the upper limit is 0.7% by weight. As the fluid lubricant, fatty acids, particularly linear saturated fatty acids are preferred. This type of fatty acid is represented by the general formula C _n-1 H _2n-1 COOH. As this fatty acid, Cn is in the range of 12 to 22, and for example, stearic acid can be used as a specific example.

[Low melting point metal powder]
The low melting point metal powder is a metal powder having a melting point lower than the sintering temperature. In the present invention, a metal powder having a melting point of 700 ° C. or lower, for example, a powder of tin, zinc, phosphorus or the like is used. Of these, tin is preferred because it causes less transpiration during sintering. Since these low melting point metal powders have high wettability with respect to copper, liquid phase sintering proceeds by blending with the raw material powder, and the bond strength between the iron structure and the copper structure or between the copper structures is enhanced. The strength of the metal structure increases as the blending amount of the low melting point metal increases, but when the flat copper powder is used as in the present invention, if the amount of the low melting point metal is too large, the flat copper powder becomes spherical as described above, There is a problem that the copper area on the bearing surface is reduced. In conventional copper-based sintered bearings and copper-iron-based sintered bearings, it is common to blend a low melting point metal of about 10% by weight with respect to copper. The ratio of the melting point metal is less than 10% by weight (desirably 8.0% by weight or less).

[Solid lubricant powder]
The solid lubricant powder is added to reduce friction during metal contact due to sliding with the shaft 2, and a foil-like one having the same size as the flat copper powder is used. As an example of the foil-like solid lubricant powder, scaly graphite is used. As solid lubricant powder, molybdenum disulfide powder can be used in addition to graphite. Molybdenum disulfide powder has a layered crystal structure and peels into layers, and thus adheres to flat copper powder in the same manner as scale graphite.

[Combination ratio]
The raw material powder blended with each of the above powders is copper powder of 18 wt% to 40 wt%, low melting point metal powder (for example, tin powder) of 1 wt% to 4 wt%, solid lubricant powder (for example, graphite powder) Is preferably blended in an amount of 0.5 to 2.5% by weight, with the balance being iron powder.

  In the present invention, as will be described later, the flat copper powder is adhered to the mold in layers when the raw powder is filled into the mold. If the blending ratio of flat copper in the raw material powder is less than 8% by weight, the amount of flat copper adhering to the mold becomes insufficient, and the effect of the present invention cannot be expected. Further, in the present embodiment, as described later, when the copper-rich surface layer portion S1 (described later) disappears due to wear, the surface of the base portion S2 serving as a bearing surface is configured by the ferrite phase αFe and the copper structure. Thus, the aggression with respect to the shaft is reduced, but in order to obtain such an effect, the base portion S2 needs to have a copper structure of at least 10% by weight or more. Therefore, the compounding ratio of the copper powder is 18% by weight or more, which is the total of both. On the other hand, when the proportion of the copper powder exceeds 40% by weight, the content of the iron structure in the base portion is insufficient, and the strength is reduced. Moreover, the usage-amount of copper powder becomes excessive and the cost merit by using flat copper powder becomes scarce. From the above, the blending amount of the copper powder in the raw material powder is 18 wt% or more and 40 wt% or less. Moreover, the compounding quantity of the flat copper powder in raw material powder shall be 8 to 40 weight%, desirably 8 to 20 weight%. The reason why 20% by weight or less is preferable is that the amount of flat copper powder adhering to the mold saturates at about 20% by weight, and even if the blending amount is further increased, the cost is increased by using high-cost flat copper powder. Is a problem.

  If the ratio of the low melting point metal powder is less than 1% by weight, the strength of the bearing cannot be secured, and if it exceeds 4% by weight, the problem of spheroidizing the flat copper powder occurs as described above. On the other hand, if the ratio of the solid lubricant powder is less than 0.5% by weight, the friction reducing effect on the bearing surface cannot be obtained, and if it exceeds 2.5% by weight, the strength is reduced. From the above, the low melting point metal powder is blended in an amount of 1 to 4% by weight, and the solid lubricant powder is blended in an amount of 0.5 to 2.5% by weight. As described above, the blending ratio of the low melting point metal powder to the copper powder is preferably less than 10% by weight (desirably 8% by weight or less).

  FIG. 13 shows a particularly preferable ratio of the various raw material powders described above. As shown, the copper powder is usually 8% by weight to 12% by weight, the flat copper powder is 10% by weight to 15% by weight, the low melting point metal powder is 1.0% by weight to 2.0% by weight, solid It is particularly preferable that the lubricant powder be 0.6 wt% or more and 1.0 wt% or less.

[mixture]
The above-mentioned mixing of each powder is performed in two steps. First, as primary mixing, scaly graphite powder and flat copper powder to which a fluid lubricant is previously attached are mixed with a known mixer. Next, as secondary mixing, iron powder, normal copper powder, and low melting point metal powder are added to and mixed with the primary mixed powder, and graphite powder is also added and mixed as necessary. Since flat copper powder has a low apparent density among various raw material powders, it is difficult to disperse uniformly in the raw material powder, but it is premixed with flat copper powder and scaly graphite powder that have the same apparent density by primary mixing. As shown in FIG. 3, the flat copper powder 3 and the graphite powder 4 adhere to each other and overlap in layers due to the fluid lubricant or the like adhering to the flat copper powder, and the apparent density of the flat copper powder increases. Therefore, it becomes possible to uniformly disperse the flat copper powder in the raw material powder during the secondary mixing. If a lubricant is added separately during the primary mixing, the adhesion between the flat copper powder and the graphite powder is further promoted, so that the flat copper powder can be more uniformly dispersed during the secondary mixing. As the lubricant to be added, a powdery lubricant can be used in addition to the same or different fluid lubricant as the fluid lubricant. For example, the above-mentioned forming aid such as metal soap is generally powdery and has a certain degree of adhesion, which can be promoted by adhesion of flat copper powder and graphite powder.

  Since the adhesion state between the flat copper powder 3 and the scaly graphite powder 4 shown in FIG. 3 is maintained to some extent even after secondary mixing, when the raw material powder is filled in the mold, the flat copper powder is put on the mold surface. A lot of graphite powder will adhere.

[Molding]
The raw material powder after the secondary mixing is supplied to the mold 6 of the molding machine. As shown in FIG. 4, the mold 6 includes a core 6 a, a die 6 b, an upper punch 6 c, and a lower punch 6 d, and a raw material powder is filled into a cavity partitioned by these. When the upper and lower punches 6c and 6d are brought close to each other and the raw material powder is compressed, the raw material powder is formed by the molding surface composed of the outer peripheral surface of the core 6a, the inner peripheral surface of the die 6b, the end surface of the upper punch 6c, and the end surface of the lower punch 6d. A cylindrical green compact 9 is obtained by molding.

  Among the metal powders in the raw material powder, the apparent density of the flat copper powder 3 is the smallest. Moreover, the flat copper powder 3 is a foil shape having the above-mentioned length L and thickness t, and the area of the wide surface per unit weight is large. Therefore, the flat copper powder is easily affected by the adhesive force due to the fluid lubricant adhering to the surface thereof, and further by the coulomb force. After filling the raw material powder into the mold 6, it is enlarged in FIG. 5. As described above, the flat copper powder 3 adheres to the entire area of the molding surface 61 in a layered state in which the wide surface is directed to the molding surface 61 and a plurality of layers (about 1 to 3 layers) overlap. At this time, scaly graphite adhering to the flat copper powder 3 also adheres to the flat copper powder 3 and adheres to the molding surface 61 of the mold (illustration of graphite is omitted in FIG. 5). On the other hand, iron powder (Fe), normal copper powder (Cu), and low-melting-point metal powder (Sn) are dispersed substantially uniformly in the inner region (region on the cavity center side) of the layered structure of flat copper 3. It becomes a state. The green compact 9 after molding retains such a distribution state of each powder almost as it is.

[Sintering]
Thereafter, the green compact 9 is sintered in a sintering furnace. The sintering conditions are such that carbon contained in graphite does not react with iron (carbon does not diffuse). In the iron-carbon equilibrium state, there is a transformation point at 723 ° C., and the reaction between iron and carbon exceeding this occurs, and a pearlite phase γFe is generated in the steel structure as shown in FIG. The reaction between carbon (graphite) and iron begins after the temperature exceeds, and a pearlite phase γFe is produced. Since the pearlite phase γFe is a hard structure (HV300 or higher) and has a strong attacking property on the counterpart material, excessive precipitation of the pearlite phase may cause wear of the shaft 2.

  In the conventional sintered bearing manufacturing process, an endothermic gas (RX gas) obtained by mixing liquefied petroleum gas (butane, propane, etc.) and air and thermally decomposing with a Ni catalyst is used as the sintering atmosphere. There are many. However, the endothermic gas (RX gas) may cause carbon to diffuse and harden the surface, resulting in the same problem.

  From the above viewpoint, in the present invention, sintering is performed at a low temperature of 900 ° C. or lower, specifically, 700 ° C. (preferably 760 ° C.) to 840 ° C. The sintering atmosphere is a gas atmosphere containing no carbon (hydrogen gas, nitrogen gas, argon gas, etc.) or a vacuum. By these measures, the reaction between carbon and iron does not occur in the raw material powder, and therefore the iron structure after sintering becomes a soft ferrite phase αFe (HV200 or less). With the sintering, the fluid lubricant, other lubricants, and various molding aids are volatilized from the inside of the sintered body.

  By passing through the sintering step described above, a porous sintered body can be obtained. The sintered bearing 1 shown in the drawing is completed by sizing the sintered body and further impregnating with a lubricating oil by a technique such as vacuum impregnation. As described above, carbon and iron are not reacted at the time of sintering, and the iron structure is made into a soft ferrite phase, so that the sintered body is likely to cause plastic flow during sizing, and high-precision sizing can be performed. . In addition, depending on a use, the impregnation process of lubricating oil can be abbreviate | omitted and it can also be set as the sintered bearing 1 used under oil-free.

  The flow of the above manufacturing process is as shown in FIG. FIG. 7 schematically shows the metal structure near the surface of the sintered bearing 1 (region P in FIG. 1) that has undergone this manufacturing process. In FIG. 7, the copper structure is hatched, and the dotted pattern is added to the graphite.

  As shown in FIG. 7, in the sintered bearing 1 of the present invention, the green compact 9 is formed in a state in which the flat copper 3 is adhered in a layered manner on the mold forming surface 61, and the layered flat copper 3 is sintered. As a result, a surface layer S1 having a high copper concentration is formed on the entire surface including the bearing surface 1a of the bearing 1. In addition, the wide surface of the flat copper 3 may have adhered to the molding surface 61, so that most of the copper structure of the surface layer S1 is flat and oriented so that the wide surface faces the surface. The thickness of the surface layer S1 corresponds to the thickness of the flat copper adhering to the mold forming surface 61 in a layer form, and is about 1 μm to 6 μm. In the arbitrary cross section of the surface layer S1, the area of the copper structure is larger than the area of the iron structure, specifically, 60% or more of the copper structure is the copper structure.

  The base portion S2 inside the surface layer S1 is basically entirely covered with the surface layer S1. As shown in FIG. 8, the copper content in the base portion S2 is less than the copper content in the surface layer S1, and the copper content rapidly decreases when the surface layer S1 moves to the base portion S2. doing. Further, the copper content (% by weight) in each part of the base part S2 is uniform in each part.

  From the above configuration, the area ratio of the copper structure to the iron structure is 60% or more over the entire surface of the surface layer S1 including the bearing surface 1a. Therefore, the initial conformability and quietness of the sintered bearing 1 can be improved. Further, since all the iron structure contained in the bearing 1 is the ferrite phase αFe, even if the surface layer S1 is worn and the iron structure of the base portion S2 appears on the surface, the bearing surface can be softened, Aggressiveness against the axis 2 can be weakened.

  On the other hand, the base portion S2 inside the surface layer S1 has a hard structure with a small copper content and a large iron content compared to the surface phase S1. As described above, since the iron content is increased in the base portion S2 that occupies most of the bearing 1, the amount of copper used in the entire bearing 1 can be reduced, and compared with a copper-based sintered bearing. Significant cost reduction can be achieved. Furthermore, when the surface layer S1 is worn by sliding with the shaft 2 and the base portion S2 containing a large amount of iron structure appears on the bearing surface 1a, the iron structure is the ferrite phase αFe. Even in a reduced state, the aggressiveness against the shaft 2 can be weakened, and the durability as a bearing can be ensured. This durability is sufficiently obtained if the content of the copper structure in the base portion S2 is at least 10% by weight or more.

  Thus, in this invention, while using flat copper powder and shape | molding a compact in the state which made this adhere to the metal mold | die molding surface 61, while increasing copper content in surface layer S1, surface Except for the layer S1, the iron content is increased to realize an optimal distribution of the copper structure and the iron structure. In addition, by intentionally setting the iron structure to the ferrite phase αFe, the wear of the shaft 2 is suppressed when the copper-rich surface layer S1 is worn. Therefore, it is possible to achieve both improvement in durability and cost reduction by reducing the amount of copper used.

  In addition, free graphite is deposited on the entire surface including the bearing surface 1a, and since the scaly graphite is attached to the mold forming surface 61 in a form accompanying the flat copper powder 3, the free graphite in the surface layer S1. The content of is also high. Therefore, the bearing surface 1a can be reduced in friction, and the durability of the bearing 1 can be increased. In addition, the copper structure and the iron structure are bonded with a low melting point metal in both the surface layer S1 and the base portion S2, and a high bonding strength is obtained between the copper structure and the iron structure and between the copper structures. . Therefore, the strength of the entire bearing 1 is increased and the durability is improved as compared with the conventional bronze-based sintered bearing. Furthermore, it is also possible to achieve a limit PV value of PV> 200 MPa · m / min, and it is possible to cope with further increase in load capacity and high-speed rotation that are expected in the future because of low friction even under such use conditions. . Therefore, according to the present invention, a sintered bearing having only the merit of both a bronze bearing and an iron sintered bearing (or an iron copper sintered bearing) can be obtained.

  In order to confirm the above-mentioned effects achieved by the present invention, the initial conformability, the limit PV value, and the amount of wear are compared between the product of the present invention and the conventional bronze-based sintered bearing and copper-iron-based sintered bearing. A test was conducted.

The composition (weight ratio) of each bearing in the comparative test was as follows.
Invention product: Iron: 80.2%, Copper: 18.0% (flat copper powder 8%), Tin: 1.0%, Graphite 0.8%
Bronze bearings: Copper: 88.8%, Tin: 9.9%, Graphite: 1.3%
Copper-iron sintered bearings: Iron: 77.2%, Copper: 20.0%, Tin: 2.0%, Graphite 0.8%

  Each test condition is as follows.

[Initial conformability measurement test]
・ Peripheral speed: 38 m / min
・ Load: 1.1 MPa
・ Shaft specifications: SUS420J2 (HRC55)
Bearing size: 6 × 12 × 6 (Inner diameter diameter dimension, outer diameter diameter dimension, and length are expressed in millimeters. The same applies hereinafter.)
・ Operation gap: 0.020mm
・ Temperature: Normal temperature

[Limit PV value measurement test]
・ Shaft specifications: SUS420J2 (HRC55)
・ Bearing size: 6 × 12 × 6
・ Operation gap: 0.020mm
・ Temperature: Normal temperature

[Abrasion test]
・ Peripheral speed: 38 to 75 m / min
・ Load: 0.7-4.0MPa
・ Shaft specifications: SUS420J2 (HRC55)
・ Bearing size: 6 × 12 × 6
・ Operation gap: 0.020mm
・ Temperature: Normal temperature ・ Time: 8 hours

  FIG. 9 shows the results of the initial conformability characteristic measurement test, FIG. 10 shows the results of the limit PV value measurement test, and FIG. 11 shows the results of the wear amount test.

  From FIG. 9, in the product of the present invention, even when the blending ratio of copper is the above lower limit value, the friction is low immediately after the start of operation, which is good compared to the copper iron system, and is equal to or better than the bronze bearing. It was found to have a good initial conformability. Further, it can be understood from FIG. 10 that even with a PV value exceeding 200 MPa · m / min, the friction is sufficiently low, and a PV value of about 500 MPa · m / min is practical. Furthermore, it can be understood from FIG. 11 that the wear amount of the product of the present invention is small and has durability equal to or higher than that of bronze-based and copper-iron-based products.

[Other Embodiments]
In the first embodiment described above, the iron structure is entirely formed of a soft ferrite phase. However, in such a configuration, the surface layer is worn due to the use conditions of the bearing (for example, when used at a high surface pressure). When the base portion is exposed, the wear resistance of the bearing surface may be insufficient.

  In this case, if the iron structure is a two-phase structure consisting of a ferrite phase and a pearlite phase, the hard pearlite phase contributes to the improvement of wear resistance, and the wear of the bearing surface under high surface pressure is suppressed and the bearing life is extended. It can be improved (second embodiment). Due to the diffusion of carbon, as shown in FIG. 6, when the proportion of pearlite γFe becomes excessive and the proportion is the same level as that of ferrite αFe, the aggressiveness of the pearlite against the shaft increases remarkably and the shaft is likely to wear. In order to prevent this, as shown in FIG. 12, the pearlite phase (γFe) is suppressed to the extent that it exists (is scattered) at the grain boundary of the ferrite phase (αFe). The “grain boundary” here means both the grain boundary formed between the ferrite phases and between the ferrite phase and other particles, as well as the crystal grain boundary 10 in the ferrite phase (αFe). In FIG. 12, the pearlite phase existing at the former grain boundary is represented by γFe1, and the pearlite phase present at the latter grain boundary is represented by γFe2. The ratio of the pearlite phase γFe (γFe1 + γFe2) to the ferrite phase αFe is preferably 5 to 20% in area ratio in the arbitrary cross section of the base portion S2.

  The growth rate of pearlite mainly depends on the sintering temperature. Therefore, in order to allow the pearlite phase to exist at the grain boundary of the ferrite phase in the above-described manner, the sintering temperature is raised to about 820 ° C. to 900 ° C. as compared with the first embodiment (see FIG. 14), and the furnace Sintering is performed using a gas containing carbon as the inner atmosphere, such as natural gas or endothermic gas (RX gas). As a result, carbon contained in the gas diffuses into iron during sintering, and pearlite phase γFe can be formed. When sintered at a temperature exceeding 900 ° C., carbon in the graphite powder reacts with iron. Other configurations, such as the composition of the raw material powder and the manufacturing procedure, are the same as those in the first embodiment, and a duplicate description is omitted.

  In the above description, the case where the present invention is applied to a perfect circle bearing having a perfect circle shape on the bearing surface 1a is illustrated. However, the present invention is not limited to a perfect circle bearing, and the outer circumference of the bearing surface 1a and the shaft 2 is exemplified. The present invention can be similarly applied to a fluid dynamic pressure bearing in which a dynamic pressure generating portion such as a herringbone groove or a spiral groove is provided on the surface.

DESCRIPTION OF SYMBOLS 1 Bearing 1a Bearing surface 2 Shaft 3 Flat copper powder 4 Scale-like graphite 6 Mold 9 Compact 10 Grain boundary 61 Forming surface L Flat powder length t Flat powder thickness

Claims (17)

And iron powder, and the aspect ratio of 13.3 or more flat copper powder, and a low melting metal powder, a mixture of raw material powder containing a solid lubricant powder was filled in a mold, a green compact molded by a die When producing sintered bearings by sintering
Solid lubricant powder is made into foil,
The raw material powder is mixed by performing primary mixing in which flat copper powder and the solid lubricant powder are mixed, and then secondary mixing in which iron powder and low melting point metal powder are added and mixed. Manufacturing method of sintered bearing.   2. The method for manufacturing a sintered bearing according to claim 1, wherein the green compact is formed in a state where flat copper powder is adhered in a layered manner to the mold forming surface.   The method for manufacturing a sintered bearing according to claim 1 or 2, wherein a fluid lubricant is adhered to the flat copper powder before the primary mixing.   The method for producing a sintered bearing according to claim 3, wherein 0.1 to 0.8% by weight of a fluid lubricant is adhered to the flat copper powder before the primary mixing in a weight ratio with respect to the flat copper powder.   The manufacturing method of the sintered bearing of Claim 4 which uses a fatty acid as a fluid lubricant. The method for producing a sintered bearing according to any one of claims 1 to 5, wherein the apparent density of the flat copper powder is 1.0 g / cm ³ or less, the thickness is 1.5 µm or less, and the length is 20 µm or more and 80 µm or less. .   The manufacturing method of the sintered bearing of any one of Claims 1-6 which makes the ratio of the flat copper powder in raw material powder 8 weight% or more.   The manufacturing method of the sintered bearing in any one of Claims 1-7 which add and mix copper powder normally at the time of secondary mixing.   The method for producing a sintered bearing according to claim 8, wherein the ratio of the flat copper powder and the normal copper powder in the raw material powder is adjusted to 18 wt% or more and 40 wt% or less.   The manufacturing method of the sintered bearing of Claim 9 which makes the ratio of the low melting metal powder with respect to copper powder less than 10% by weight ratio.   The method for producing a sintered bearing according to any one of claims 1 to 10, wherein scaly graphite is used as the foil-like solid lubricant powder.   The method for producing a sintered bearing according to any one of claims 1 to 11, wherein the iron structure is formed of a ferrite phase without causing iron and carbon to react during sintering.   The method for manufacturing a sintered bearing according to claim 12, wherein the sintering temperature is 700 ° C. to 840 ° C.   The method for manufacturing a sintered bearing according to claim 13, wherein sintering is performed in an atmosphere containing no carbon.   The method for producing a sintered bearing according to any one of claims 1 to 11, wherein iron is reacted with carbon during sintering to form an iron structure with a ferrite phase and a pearlite phase existing at a ferrite grain boundary.   The method for manufacturing a sintered bearing according to claim 15, wherein the sintering temperature is 820 ° C. to 900 ° C.   The method for manufacturing a sintered bearing according to claim 16, wherein the sintering is performed in an atmosphere containing carbon.

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