JP5865723B2 - 水性フロアーポリッシュ及びアレルゲン抑制製品 - Google Patents
水性フロアーポリッシュ及びアレルゲン抑制製品 Download PDFInfo
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- JP5865723B2 JP5865723B2 JP2012027719A JP2012027719A JP5865723B2 JP 5865723 B2 JP5865723 B2 JP 5865723B2 JP 2012027719 A JP2012027719 A JP 2012027719A JP 2012027719 A JP2012027719 A JP 2012027719A JP 5865723 B2 JP5865723 B2 JP 5865723B2
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- Japan
- Prior art keywords
- styrene
- sulfonic acid
- weight
- allergen
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000013566 allergen Substances 0.000 title claims description 105
- 230000001629 suppression Effects 0.000 title description 3
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 83
- 229920000642 polymer Polymers 0.000 claims description 68
- 239000003112 inhibitor Substances 0.000 claims description 49
- 239000000178 monomer Substances 0.000 claims description 43
- 229920001577 copolymer Polymers 0.000 claims description 36
- 229920005604 random copolymer Polymers 0.000 claims description 36
- 150000003839 salts Chemical class 0.000 claims description 36
- 239000011248 coating agent Substances 0.000 claims description 33
- 238000000576 coating method Methods 0.000 claims description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 32
- 125000001424 substituent group Chemical group 0.000 claims description 17
- 229920003002 synthetic resin Polymers 0.000 claims description 10
- 239000000057 synthetic resin Substances 0.000 claims description 10
- 239000001257 hydrogen Substances 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 6
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 52
- -1 sulfonic acid sodium salt Chemical class 0.000 description 42
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 24
- 239000004793 Polystyrene Substances 0.000 description 20
- 229920002223 polystyrene Polymers 0.000 description 20
- XFTALRAZSCGSKN-UHFFFAOYSA-M sodium;4-ethenylbenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=C(C=C)C=C1 XFTALRAZSCGSKN-UHFFFAOYSA-M 0.000 description 20
- 230000002401 inhibitory effect Effects 0.000 description 19
- 239000001993 wax Substances 0.000 description 17
- 150000001875 compounds Chemical class 0.000 description 16
- 239000007864 aqueous solution Substances 0.000 description 15
- 238000000034 method Methods 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 11
- 239000011734 sodium Substances 0.000 description 11
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 10
- MAGFQRLKWCCTQJ-UHFFFAOYSA-N 4-ethenylbenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=C(C=C)C=C1 MAGFQRLKWCCTQJ-UHFFFAOYSA-N 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- 238000009408 flooring Methods 0.000 description 10
- 229920001897 terpolymer Polymers 0.000 description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 9
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 9
- 239000004925 Acrylic resin Substances 0.000 description 8
- 229920000178 Acrylic resin Polymers 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
- 239000002253 acid Substances 0.000 description 8
- 239000002585 base Substances 0.000 description 8
- 238000010538 cationic polymerization reaction Methods 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- 239000004593 Epoxy Substances 0.000 description 7
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 7
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 7
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 6
- 229920001519 homopolymer Polymers 0.000 description 6
- 150000002431 hydrogen Chemical class 0.000 description 6
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 6
- 239000011976 maleic acid Substances 0.000 description 6
- 229920000573 polyethylene Polymers 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- ATBDZSAENDYQDW-UHFFFAOYSA-N 3-ethenylbenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC(C=C)=C1 ATBDZSAENDYQDW-UHFFFAOYSA-N 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 5
- GQRBFTZNEJKRNT-UHFFFAOYSA-N C=CC1=CC=CC=C1.C(=CC1=CC=CC=C1)S(=O)(=O)O.C(=CC1=CC=CC=C1)S(=O)(=O)O Chemical compound C=CC1=CC=CC=C1.C(=CC1=CC=CC=C1)S(=O)(=O)O.C(=CC1=CC=CC=C1)S(=O)(=O)O GQRBFTZNEJKRNT-UHFFFAOYSA-N 0.000 description 5
- 229940048053 acrylate Drugs 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000005191 phase separation Methods 0.000 description 5
- 239000003505 polymerization initiator Substances 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- 238000006277 sulfonation reaction Methods 0.000 description 5
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- 150000008065 acid anhydrides Chemical class 0.000 description 4
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 4
- 229920003986 novolac Polymers 0.000 description 4
- 239000002685 polymerization catalyst Substances 0.000 description 4
- 159000000000 sodium salts Chemical class 0.000 description 4
- GUCXXOFNASDXOJ-UHFFFAOYSA-M sodium;4-ethenylbenzenesulfonate;styrene Chemical compound [Na+].C=CC1=CC=CC=C1.[O-]S(=O)(=O)C1=CC=C(C=C)C=C1 GUCXXOFNASDXOJ-UHFFFAOYSA-M 0.000 description 4
- 150000008054 sulfonate salts Chemical class 0.000 description 4
- 208000024891 symptom Diseases 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 208000026935 allergic disease Diseases 0.000 description 3
- 230000000172 allergic effect Effects 0.000 description 3
- 229910052787 antimony Inorganic materials 0.000 description 3
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 3
- 208000010668 atopic eczema Diseases 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000003472 neutralizing effect Effects 0.000 description 3
- 229920000620 organic polymer Polymers 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 3
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 description 2
- DCTOHCCUXLBQMS-UHFFFAOYSA-N 1-undecene Chemical compound CCCCCCCCCC=C DCTOHCCUXLBQMS-UHFFFAOYSA-N 0.000 description 2
- VMSBGXAJJLPWKV-UHFFFAOYSA-N 2-ethenylbenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1C=C VMSBGXAJJLPWKV-UHFFFAOYSA-N 0.000 description 2
- ONUXAGYOFJLIQM-UHFFFAOYSA-N 2-ethenylnaphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=C(C=C)C=CC2=C1 ONUXAGYOFJLIQM-UHFFFAOYSA-N 0.000 description 2
- JESXATFQYMPTNL-UHFFFAOYSA-N 2-ethenylphenol Chemical compound OC1=CC=CC=C1C=C JESXATFQYMPTNL-UHFFFAOYSA-N 0.000 description 2
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 2
- 241000238876 Acari Species 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 125000005250 alkyl acrylate group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- WTSSRZUUXRDFPD-UHFFFAOYSA-N azane;4-ethenylbenzenesulfonic acid Chemical compound [NH4+].[O-]S(=O)(=O)C1=CC=C(C=C)C=C1 WTSSRZUUXRDFPD-UHFFFAOYSA-N 0.000 description 2
- IVKZBYBXOFUZME-UHFFFAOYSA-N azanium;2-ethenylbenzenesulfonate Chemical compound [NH4+].[O-]S(=O)(=O)C1=CC=CC=C1C=C IVKZBYBXOFUZME-UHFFFAOYSA-N 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- HHKWQFVQMZJXNC-UHFFFAOYSA-L calcium;2-phenylethenesulfonate Chemical compound [Ca+2].[O-]S(=O)(=O)C=CC1=CC=CC=C1.[O-]S(=O)(=O)C=CC1=CC=CC=C1 HHKWQFVQMZJXNC-UHFFFAOYSA-L 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000004581 coalescence Methods 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- YAUZJFRMTBUCGL-UHFFFAOYSA-N ethyl 4-ethenylbenzenesulfonate Chemical compound CCOS(=O)(=O)C1=CC=C(C=C)C=C1 YAUZJFRMTBUCGL-UHFFFAOYSA-N 0.000 description 2
- 210000003608 fece Anatomy 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 description 2
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 159000000001 potassium salts Chemical class 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 229940006186 sodium polystyrene sulfonate Drugs 0.000 description 2
- MNCGMVDMOKPCSQ-UHFFFAOYSA-M sodium;2-phenylethenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C=CC1=CC=CC=C1 MNCGMVDMOKPCSQ-UHFFFAOYSA-M 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- WTLBZVNBAKMVDP-UHFFFAOYSA-N tris(2-butoxyethyl) phosphate Chemical compound CCCCOCCOP(=O)(OCCOCCCC)OCCOCCCC WTLBZVNBAKMVDP-UHFFFAOYSA-N 0.000 description 2
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 2
- 239000011667 zinc carbonate Substances 0.000 description 2
- 229910000010 zinc carbonate Inorganic materials 0.000 description 2
- 235000004416 zinc carbonate Nutrition 0.000 description 2
- JIRHAGAOHOYLNO-UHFFFAOYSA-N (3-cyclopentyloxy-4-methoxyphenyl)methanol Chemical compound COC1=CC=C(CO)C=C1OC1CCCC1 JIRHAGAOHOYLNO-UHFFFAOYSA-N 0.000 description 1
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 description 1
- LTVUCOSIZFEASK-MPXCPUAZSA-N (3ar,4s,7r,7as)-3a-methyl-3a,4,7,7a-tetrahydro-4,7-methano-2-benzofuran-1,3-dione Chemical compound C([C@H]1C=C2)[C@H]2[C@H]2[C@]1(C)C(=O)OC2=O LTVUCOSIZFEASK-MPXCPUAZSA-N 0.000 description 1
- KNDQHSIWLOJIGP-UMRXKNAASA-N (3ar,4s,7r,7as)-rel-3a,4,7,7a-tetrahydro-4,7-methanoisobenzofuran-1,3-dione Chemical compound O=C1OC(=O)[C@@H]2[C@H]1[C@]1([H])C=C[C@@]2([H])C1 KNDQHSIWLOJIGP-UMRXKNAASA-N 0.000 description 1
- MUTGBJKUEZFXGO-OLQVQODUSA-N (3as,7ar)-3a,4,5,6,7,7a-hexahydro-2-benzofuran-1,3-dione Chemical compound C1CCC[C@@H]2C(=O)OC(=O)[C@@H]21 MUTGBJKUEZFXGO-OLQVQODUSA-N 0.000 description 1
- KMOUUZVZFBCRAM-OLQVQODUSA-N (3as,7ar)-3a,4,7,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C=CC[C@@H]2C(=O)OC(=O)[C@@H]21 KMOUUZVZFBCRAM-OLQVQODUSA-N 0.000 description 1
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- DTCCVIYSGXONHU-CJHDCQNGSA-N (z)-2-(2-phenylethenyl)but-2-enedioic acid Chemical compound OC(=O)\C=C(C(O)=O)\C=CC1=CC=CC=C1 DTCCVIYSGXONHU-CJHDCQNGSA-N 0.000 description 1
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
- RXYPXQSKLGGKOL-UHFFFAOYSA-N 1,4-dimethylpiperazine Chemical compound CN1CCN(C)CC1 RXYPXQSKLGGKOL-UHFFFAOYSA-N 0.000 description 1
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 1
- NDZFNTHGIIQMQI-UHFFFAOYSA-N 1-benzylpyridin-1-ium Chemical compound C=1C=CC=C[N+]=1CC1=CC=CC=C1 NDZFNTHGIIQMQI-UHFFFAOYSA-N 0.000 description 1
- JOLQKTGDSGKSKJ-UHFFFAOYSA-N 1-ethoxypropan-2-ol Chemical compound CCOCC(C)O JOLQKTGDSGKSKJ-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
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- RXFZJKXZSLVQJV-UHFFFAOYSA-N icosa-8,12-dienedihydrazide Chemical compound NNC(=O)CCCCCCC=CCCC=CCCCCCCC(=O)NN RXFZJKXZSLVQJV-UHFFFAOYSA-N 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 208000030603 inherited susceptibility to asthma Diseases 0.000 description 1
- 238000004255 ion exchange chromatography Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- MXWIATCUFNBIIF-UHFFFAOYSA-M lithium;2-ethenylbenzenesulfonate Chemical compound [Li+].[O-]S(=O)(=O)C1=CC=CC=C1C=C MXWIATCUFNBIIF-UHFFFAOYSA-M 0.000 description 1
- YSKIQSYEHUCIFO-UHFFFAOYSA-M lithium;4-ethenylbenzenesulfonate Chemical compound [Li+].[O-]S(=O)(=O)C1=CC=C(C=C)C=C1 YSKIQSYEHUCIFO-UHFFFAOYSA-M 0.000 description 1
- 229940018564 m-phenylenediamine Drugs 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- GZPUKKQAJUVQHX-UHFFFAOYSA-L magnesium;2-phenylethenesulfonate Chemical compound [Mg+2].[O-]S(=O)(=O)C=CC1=CC=CC=C1.[O-]S(=O)(=O)C=CC1=CC=CC=C1 GZPUKKQAJUVQHX-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000007974 melamines Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- IKSBUASJFRTIPW-UHFFFAOYSA-N methyl 2-ethenylbenzenesulfonate Chemical compound COS(=O)(=O)C1=CC=CC=C1C=C IKSBUASJFRTIPW-UHFFFAOYSA-N 0.000 description 1
- NHLDKDYUMJJCHD-UHFFFAOYSA-N methyl 4-ethenylbenzenesulfonate Chemical compound COS(=O)(=O)C1=CC=C(C=C)C=C1 NHLDKDYUMJJCHD-UHFFFAOYSA-N 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- VYKXQOYUCMREIS-UHFFFAOYSA-N methylhexahydrophthalic anhydride Chemical compound C1CCCC2C(=O)OC(=O)C21C VYKXQOYUCMREIS-UHFFFAOYSA-N 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- OMNKZBIFPJNNIO-UHFFFAOYSA-N n-(2-methyl-4-oxopentan-2-yl)prop-2-enamide Chemical compound CC(=O)CC(C)(C)NC(=O)C=C OMNKZBIFPJNNIO-UHFFFAOYSA-N 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 125000006502 nitrobenzyl group Chemical group 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- YAFOVCNAQTZDQB-UHFFFAOYSA-N octyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OCCCCCCCC)OC1=CC=CC=C1 YAFOVCNAQTZDQB-UHFFFAOYSA-N 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229910001562 pearlite Inorganic materials 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229940044654 phenolsulfonic acid Drugs 0.000 description 1
- 239000008363 phosphate buffer Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N phthalic anhydride Chemical compound C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000013573 pollen allergen Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 150000003077 polyols Chemical group 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- OBRRLBBTAKVBRN-UHFFFAOYSA-M potassium;2-ethenylbenzenesulfonate Chemical compound [K+].[O-]S(=O)(=O)C1=CC=CC=C1C=C OBRRLBBTAKVBRN-UHFFFAOYSA-M 0.000 description 1
- HWDDJFFLFNQAFQ-UHFFFAOYSA-M potassium;4-ethenylbenzenesulfonate Chemical compound [K+].[O-]S(=O)(=O)C1=CC=C(C=C)C=C1 HWDDJFFLFNQAFQ-UHFFFAOYSA-M 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical group CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000009938 salting Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000001542 size-exclusion chromatography Methods 0.000 description 1
- UUYLNFFNUZLZOQ-UHFFFAOYSA-M sodium 2-phenylethenesulfonate 2-phenylethenesulfonic acid styrene Chemical compound C=CC1=CC=CC=C1.C(=CC1=CC=CC=C1)S(=O)(=O)O.C(=CC1=CC=CC=C1)S(=O)(=O)[O-].[Na+] UUYLNFFNUZLZOQ-UHFFFAOYSA-M 0.000 description 1
- 229940047670 sodium acrylate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- XESUCHPMWXMNRV-UHFFFAOYSA-M sodium;2-ethenylbenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1C=C XESUCHPMWXMNRV-UHFFFAOYSA-M 0.000 description 1
- SONHXMAHPHADTF-UHFFFAOYSA-M sodium;2-methylprop-2-enoate Chemical compound [Na+].CC(=C)C([O-])=O SONHXMAHPHADTF-UHFFFAOYSA-M 0.000 description 1
- PGTLVXOZIGEXJA-UHFFFAOYSA-M sodium;2-phenylethenesulfonate;styrene Chemical compound [Na+].C=CC1=CC=CC=C1.[O-]S(=O)(=O)C=CC1=CC=CC=C1 PGTLVXOZIGEXJA-UHFFFAOYSA-M 0.000 description 1
- JJMIAJGBZGZNHA-UHFFFAOYSA-N sodium;styrene Chemical compound [Na].C=CC1=CC=CC=C1 JJMIAJGBZGZNHA-UHFFFAOYSA-N 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 150000003458 sulfonic acid derivatives Chemical class 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 125000005591 trimellitate group Chemical group 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 229920003176 water-insoluble polymer Polymers 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Landscapes
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
(m,n及びpはそれぞれ0〜2の整数を示し、R1〜R19はそれぞれ、水素、スルホン酸基、スルホン酸基の塩又はスルホン酸基の誘導体の何れかであって、R1〜R5のうちの少なくとも一つは、スルホン酸基、スルホン酸基の塩又はスルホン酸基の誘導体であり、R6〜R12のうちの少なくとも一つは、スルホン酸基、スルホン酸基の塩又はスルホン酸基の誘導体であり、R13〜R19のうちの少なくとも一つは、スルホン酸基、スルホン酸基の塩又はスルホン酸基の誘導体である。)
(R20〜R24はそれぞれ、水素、スルホン酸基、スルホン酸基の塩又はスルホン酸基の誘導体の何れかであって、R20〜R24のうちの少なくとも一つは、スルホン酸基、スルホン酸基の塩又はスルホン酸基の誘導体である。)
カラム:(昭和電工社製Shodex GF-7M HQ 7.6mmI.D.×30cm 1本)
溶離液:(0.05M硫酸ナトリウム水溶液:THF=7:3)
流速:0.6ミリリットル/分
温度:40℃
検出:UV(210nm)
標準ポリスチレンスルホン酸ナトリウム: scientific polymer products社製を使用
水性ウレタン樹脂(米国BF Goodrich社製 商品名「サンキュア1818」、ウレタン樹脂の含有量:35重量%)20重量部、アクリル系樹脂エマルジョン(アクリル系樹脂の含有量:40重量%)40重量部、スチレン−マレイン酸共重合体のアンモニア溶液(米国アルコケミカル社製 商品名「SMA2625A」、スチレン−マレイン酸共重合体の含有量:20重量%)8.5重量部、ポリエチレンワックスエマルジョン(ポリエチレンワックスの含有量:20重量%)9.5重量部、炭酸亜鉛のアンモニア水溶液(炭酸亜鉛の含有量:8重量%)5重量部、ジエチレングリコールモノエチルエーテル4重量部、トリブトキシエチルホスフェート1重量部及び水12重量部を混合してベース水性フロアーポリッシュを作製した。なお、ベース水性フロアーポリッシュ中において、ウレタン樹脂、アクリル系樹脂及びスチレン−マレイン酸の総量は24.7重量%、水の総量は68重量%であった。
撹拌機、冷却器及び温度計を配設した2リットルのセパラブルフラスコにp−スチレンスルホン酸ナトリウム(東ソー社製 商品名「スピノマー NaSS」純度88.2%)210重量部、脱イオン水312重量部、スチレンモノマー(和光純薬社製 商品名「スチレン,モノマー」)57重量部、変性エタノール(和光純薬社製 商品名「86%エタノール−ME,変性」)407重量部を加え、撹拌しながら窒素ガスで置換した後、加熱して78℃に維持した。
p−スチレンスルホン酸ナトリウムを148.5重量部に、スチレンモノマーを50重量部に、ペリオキソ二硫酸カリウムを3.25重量部に変更したこと以外は、実施例1と同様の要領でp−スチレンスルホン酸ナトリウム−スチレンランダム共重合体を得た。なお、p−スチレンスルホン酸ナトリウム−スチレンランダム共重合体において、p−スチレンスルホン酸ナトリウム成分は72重量%、スチレン成分は28重量%であった。p−スチレンスルホン酸ナトリウム−スチレンランダム共重合体の重量平均分子量は9万であった。p−スチレンスルホン酸ナトリウム−スチレンランダム共重合体は水溶性であった。
p−スチレンスルホン酸ナトリウムを165重量部に、スチレンモノマーを35.7重量部に、ペリオキソ二硫酸カリウムを3.09重量部に変更したこと以外は、実施例1と同様の要領でp−スチレンスルホン酸ナトリウム−スチレンランダム共重合体を得た。なお、p−スチレンスルホン酸ナトリウム−スチレンランダム共重合体において、p−スチレンスルホン酸ナトリウム成分は80重量%、スチレン成分は20重量%であった。p−スチレンスルホン酸ナトリウム−スチレンランダム共重合体の重量平均分子量は8万であった。p−スチレンスルホン酸ナトリウム−スチレンランダム共重合体は水溶性であった。
p−スチレンスルホン酸ナトリウムを59.5重量部に、スチレンモノマーを30重量部に、ペリオキソ二硫酸カリウムを1.56重量部に変更したこと以外は、実施例1と同様の要領でp−スチレンスルホン酸ナトリウム−スチレンランダム共重合体を得た。なお、p−スチレンスルホン酸ナトリウム−スチレンランダム共重合体において、p−スチレンスルホン酸ナトリウム成分は64重量%、スチレン成分は36重量%であった。p−スチレンスルホン酸ナトリウム−スチレンランダム共重合体の重量平均分子量は8万であった。p−スチレンスルホン酸ナトリウム−スチレンランダム共重合体は水溶性であった。
p−スチレンスルホン酸ナトリウムを127.3に重量部に、スチレンモノマーを150重量部に、ペリオキソ二硫酸カリウムを2.8重量部に変更したこと以外は、実施例1と同様の要領でp−スチレンスルホン酸ナトリウム−スチレンランダム共重合体を得た。なお、p−スチレンスルホン酸ナトリウム−スチレンランダム共重合体において、p−スチレンスルホン酸ナトリウム成分は43重量%、スチレン成分は57重量%であった。p−スチレンスルホン酸ナトリウム−スチレンランダム共重合体の重量平均分子量は15万であった。p−スチレンスルホン酸ナトリウム−スチレンランダム共重合体は水溶性であった。
p−スチレン−マレイン酸共重合体(スチレン成分:75重量%、マレイン酸成分:25重量%)のベンゼン環の一部をスルホン化してなる重合体のスルホン酸ナトリウム(アクゾノーベル社製 商品名「VERSA TL−3」、スチレン成分のスルホン化率:99モル%以上、p−スチレンスルホン酸ナトリウム成分:74重量%、スチレン成分:1重量%、マレイン酸成分:25重量%、重量平均分子量:2万)を用意した。p−スチレン−マレイン酸共重合体のベンゼン環の一部をスルホン化してなる重合体のスルホン酸ナトリウムは水溶性であった。
アレルゲン抑制剤としてp−スチレンスルホン酸ナトリウム単独重合体(p−スチレンスルホン酸ナトリウムホモポリマ−)の水溶液(東ソ−有機化学社製 商品名「PS−100」、p−スチレンスルホン酸ナトリウム単独重合体の含有量:20重量%、重量平均分子量:72万)10重量部とベース水性フロアーポリッシュ90重量部とを均一に混合させて水性フロアーポリッシュを得た。実施例1と同様の要領で試験片を作製した。
アレルゲン抑制剤としてp−スチレンスルホン酸ナトリウム単独重合体(p−スチレンスルホン酸ナトリウムホモポリマ−)の水溶液(東ソ−有機化学社製 商品名「PS−50」、p−スチレンスルホン酸ナトリウム単独重合体の含有量:20重量%、分子量:57万)10重量部とベース水性フロアーポリッシュ90重量部とを均一に混合させて水性フロアーポリッシュを得た。実施例1と同様にして試験片を切り出した。
p−スチレンスルホン酸ナトリウムを250重量部に、スチレンモノマーを30重量部に、ペリオキソ二硫酸カリウムを4重量部に変更したこと以外は、実施例1と同様の要領でp−スチレンスルホン酸ナトリウム−スチレンランダム共重合体を得た。なお、p−スチレンスルホン酸ナトリウム−スチレンランダム共重合体において、p−スチレンスルホン酸ナトリウム成分は88重量%、スチレン成分は12重量%であった。p−スチレンスルホン酸ナトリウム−スチレンランダム共重合体の重量平均分子量は9万であった。p−スチレンスルホン酸ナトリウム−スチレンランダム共重合体の溶解度は水溶性であった。
p−スチレンスルホン酸ナトリウムを63重量部に、スチレンモノマーを180重量部に、ペリオキソ二硫酸カリウムを4.65重量部に変更したこと以外は、実施例1と同様の要領でp−スチレンスルホン酸ナトリウム−スチレンランダム共重合体を得た。なお、p−スチレンスルホン酸ナトリウム−スチレンランダム共重合体において、p−スチレンスルホン酸ナトリウム成分は24重量%、スチレン成分は76重量%であった。p−スチレンスルホン酸ナトリウム−スチレンランダム共重合体の重量平均分子量は11万であった。p−スチレンスルホン酸ナトリウム−スチレンランダム共重合体は非水溶性であった。
ベース水性フロアーポリッシュ30gを木質床材1m2に均一に塗布して室温にて16時間に亘って乾燥させた後、木質床材から一辺が5cmの平面正方形状の試験片を切り出した。
アレルゲンの冷結乾燥粉末(コスモ・バイオ社製 商品名「MiteExtract−Df」)をリン酸バッファー(pH7.6)に溶解させて、タンパク量が20μg/ミリリットルのアレルゲン水溶液を調製した。
5・・・濃く、太くはっきりとしたラインが観測された。
4・・・ラインであることがはっきりと分かる。
3・・・ライン状にうっすらと発色している。
2・・・うっすらと発色している。
1・・・全く発色していない。
実施例及び比較例で得られた試験片の表面を目視観察して下記基準に基づいて判断した。
○・・・塗膜に曇りがなく透明であった。
△・・・塗膜に僅かな曇りがあった。
×・・・塗膜に曇りがあり、塗膜がくすんでいた。
実施例及び比較例で得られた試験片における水性フロアーポリッシュの塗布面に水を0.1ミリリットル滴下した後、試験片を室温にて60分間に亘って保持した後、試験片上の水分を除去し、水を載せた塗膜部分に白いシミがあるか否かを目視観察し、下記の基準により評価した。
◎・・・シミが認められなかった。
○・・・僅かにシミが認められたが、更に、30分経過後にはシミが消失した。
× ・・・明確にシミが認められた。
Claims (4)
- 重合体は、スチレンスルホン酸ナトリウム−スチレン共重合体であることを特徴とする請求項1に記載の水性フロアーポリッシュ。
- 重合体は、p−スチレンスルホン酸ナトリウム−スチレンランダム共重合体であることを特徴とする請求項1に記載の水性フロアーポリッシュ。
- 請求項1乃至請求項3の何れか1項に記載の水性フロアーポリッシュを塗布、乾燥させてなる塗膜を有していることを特徴とするアレルゲン抑制製品。
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