JP5859190B2 - Method for producing fragrance composition - Google Patents

Description

The present invention relates to a method for producing a fragrance composition, and more particularly to a method for producing a fragrance close to natural from a fragrance, and further, using the obtained fragrance composition, effects equivalent to natural aging are provided. It also includes a method for producing a perfume composition such as perfume that can be obtained quickly.
In addition, the fragrance composition described here includes perfume, eau de parfan, eau de toilette, eau de cologne, colon, deodorant colon, colon spray, colon lotion, room fragrance, room fragrance aerosol and the like.

In general, as means for obtaining a fragrance component from a fragrance (natural fragrance), various methods such as separation and extraction of the fragrance component by hydrolysis or distillation, dilution extraction with an organic solvent containing alcohol, etc. are employed, and synthetic fragrances are also used. In this case, a method of diluting with alcohol is widely used.
However, since each method performs operations such as decomposition or extraction of natural products and dilution of synthetic products, it cannot be denied that the obtained aroma components are separated from natural aroma.
On the other hand, in the development of perfume and other perfume compositions, we first tried blending several tens to hundreds of fragrances, and specialized fragrances for the selected trial ingredients (fragrance composition samples). The teacher evaluates and repeats the operation of trying a new formulation based on the result, and a desired fragrance composition (perfume sample) in which the fragrance is in a chaos state is aged for a predetermined period of time. It is manufactured by adding an organic solvent such as alcohols to extract and dilute it.

However, perfume extracted and diluted with an organic solvent is not shipped immediately as a product, but it is usually shipped after standing for a few months or longer and half a year to more than one year and naturally aging. .
This is done to disperse the pungent odor of organic solvents and stabilize many fragrance components in a well-balanced and fragrant state, and through this natural ripening process, high quality perfume Sex is guaranteed.

  In other words, the fragrance of the perfume immediately after extraction has an impression that the fragrance itself is discrete and pointed, such as the fragrance of the fragrance component with a high blending ratio stands out and the fragrance of the spice system and other trace fragrance components is not so much felt. Although there is a tendency to give, all the fragrance components contained in the fragrance composition are felt in a well-balanced manner and reach a stable fragrance state through the natural aging process described above.

  However, the process of natural ripening not only requires the storage location at all times, but also requires energy to maintain the environment of the storage location, resulting in excessive economic costs and a great deal of time in product development. It was causing cost problems.

  Under such circumstances, a method of promoting ripening by performing heat treatment or ultrasonic irradiation treatment in the presence of a dehydrating agent during the perfume production process (Patent Document 1), or a flower essential oil such as rose, jasmine, lavender, etc. A method (patent document 2) for mitigating the irritating odor of organic solvents such as alcohols using the above residue has been proposed and implemented.

  JP-A-8-92589   JP 61-204116 A

However, in the method of performing the heat treatment or the ultrasonic irradiation treatment, the fragrance tone may change greatly depending on the type of the dehydrating agent, and it is difficult to obtain the intended sufficient effect from the fragrancer or the developer. It was pointed out.
In addition, the method of using the flower essential oil residue not only limits the production of the flower essential oil residue used as a raw material, but also may affect the delicate aroma, and may cause precipitation in rare cases. It was not always satisfactory because there was.

  Therefore, in the present invention, a perfume that provides a method for producing a natural fragrance composition from a fragrance and can quickly obtain an effect equivalent to natural ripening using the obtained natural fragrance composition. It is an object of the present invention to provide a method for producing a fragrance composition such as the above, and also a fragrance composition or a card attached with the fragrance composition.

  That is, in the present invention, a high voltage treatment is performed on a fragrance (fragrance component) to which a divalent or higher metal ion-containing liquid is added, and then a divalent or higher metal ion-containing liquid is added to the fragrance and a high voltage treatment is performed. The fragrance composition is extracted and produced by adding ethyl alcohol.

  In this case, the divalent or higher-valent metal ion-containing liquid is charged into a fermentation tank with a pulverized mixture containing starch and / or cereals, seeds and eggshells in a weight ratio of 2.5: 3.0: 0.5. Water 3 is added to the mixed raw material 1 and heated to 50 to 100 ° C. while stirring to pre-gelatinize the starch, then kept at 30 to 40 ° C. to make a viscous mixed solution. In addition, a water-soluble mineral-containing liquid produced by complex fermentation and further aging the mixed liquid subjected to complex fermentation for about 1 to 2 months is used.

  Moreover, the metal ion containing liquid more than bivalence added to each of a fragrance | flavor and ethyl alcohol is set to the range of 0.05 weight%-3.0 weight%, and a high voltage process is 5000V-10000V, 120Hz-360Hz. It is preferable to carry out within a range of about 3 to 6 hours, and further includes the fragrance composition itself thus obtained.

  On the other hand, ethyl alcohol in which a divalent or higher metal ion-containing liquid is added to each of a variety of fragrances (perfume ingredients) subjected to high voltage treatment by adding a divalent or higher metal ion-containing liquid and subjected to high voltage treatment To extract the fragrance composition, and then the obtained fragrance composition is mixed and allowed to stand in a closed space, and a high voltage treatment is performed at the time of standing to produce a fragrance composition.

  Also in this case, the metal ion-containing liquid having a valence of 2 or more is used in a weight ratio of 2.5: 3.0: 0.5 between starch and / or cereals, seeds and eggshells in the same manner as in the production of the fragrance composition described above. Add the pulverized mixture to the fermentation tank, add water 3 to the mixed raw material 1 and heat to 50-100 ° C with stirring to gelatinize the starch, and then keep it warm at 30-40 ° C for viscous mixing. It is preferable to use a water-soluble mineral-containing liquid produced by adding a koji mold to this liquid mixture and then subjecting it to complex fermentation, and further aging this mixed fermentation liquid for about 1 to 2 months. is there.

Moreover, the metal ion containing liquid more than bivalence added to each of a fragrance | flavor and ethyl alcohol is set to the range of 0.05 weight%-3.0 weight%, and a high voltage process is 5000V-10000V, 120Hz-360Hz. It is preferable to carry out for 3 hours to 6 hours in the range, and further, the mixed solution of the fragrance composition is accommodated in a glass container and allowed to stand, and at about 5000 V to 10000 V, 120 Hz to 360 Hz for about 3 hours to 6 hours. It is preferable to perform a high-voltage treatment and further maintain the static temperature of the fragrance composition mixture in the range of 20 ° C to 40 ° C.
In addition, this invention includes the fragrance | flavor composition itself obtained by the above-mentioned method.

  Furthermore, in the present invention, a resin transparent sheet coated with an adhesive on the back side is attached to a card-like mount, and the above-mentioned fragrance composition or fragrance composition is silk-printed on the surface of the resin transparent sheet. A fragrance composition-attached card or a fragrance composition formed by adhering a peelable resin transparent sheet to the printed surface and further adhering a surface sheet having a desired print indication to the peelable transparent sheet. An attachment card is also provided.

According to the present invention, it is possible not only to easily produce a natural fragrance component (fragrance composition) from a fragrance in a short time, but also by using the obtained natural fragrance composition, a fragrance composition such as perfume. It is possible not only to greatly shorten the development period, but also to easily impart an effect equivalent to natural aging to a perfume composition containing perfume and the like.
In addition, it is possible to provide high quality perfume at a lower price, and can greatly contribute to the realization of a new business model of tailor-made perfume.

  Furthermore, the card attached with the fragrance composition or the fragrance composition can retain the natural fragrance of each composition over a long period of time without being affected by the ingredients such as the card material and the adhesive. It can be suitably used as a fragrance sample of a composition or a simple fragrance composition or fragrance composition card.

It is a schematic process explanatory drawing which shows suitable embodiment of the manufacturing method of the fragrance composition which concerns on this invention. It is a schematic process explanatory drawing which shows suitable embodiment of the manufacturing method of the fragrance | flavor composition which concerns on this invention. It is explanatory drawing of the attachment card | curd which uses the fragrance composition or fragrance | flavor composition which concerns on this invention.

  Next, preferred embodiments of the method for producing an aroma composition according to the present invention will be exemplified and described in detail below with reference to the accompanying drawings.

In FIG. 1, the method for producing a fragrance composition according to the present invention is based on adding an alcohol 12 to a fragrance component (fragrance) 10 and extracting the fragrance component as a fragrance composition 14.
In this case, the fragrance component (fragrance) 10 uses the fragrance 10a that has been previously added with the metal ion-containing liquid 16 having a valence of 2 or higher and has been subjected to the high-voltage treatment 18. It is characterized by using ethyl alcohol (ethanol) 20 to which a metal ion-containing liquid 16 is added and subjected to a high voltage treatment 18.

In addition, as the metal ion-containing liquid 16 having a valence of 2 or more, for example, a ground mixture containing starch and / or cereals, seeds and eggshells in a weight ratio of 2.5: 3.0: 0.5 is put into the fermentation tank. Then, water 3 is added to the mixed raw material 1 and heated to 50 to 100 ° C. with stirring to gelatinize the starch, and then kept at 30 to 40 ° C. to make a viscous mixed solution. Calcium, magnesium, iron, copper, zinc, manganese, etc. contained in seeds and eggshells as raw materials are dissociated by adding gonococci and other complex fermentation, and then aging the mixed fermentation mixture for about 1 to 2 months A water-soluble mineral-containing liquid (fermentation extraction) is used.
In addition, although the addition amount to the fragrance | flavor 10 and the ethyl alcohol 20 of the water-soluble mineral containing liquid (metal ion containing liquid) 16 obtained in this way is set to the range of 0.05 weight%-3.0 weight%. When the added amount is 0.05% by weight or less, the mineral neutralization of the fragrance component and the electronic reduction of ethyl alcohol cannot be sufficiently performed, and when the added amount exceeds 3.0% by weight, there is a problem due to the raw material odor. Become.
Further, the high voltage treatment is preferably performed in the range of 5000 V to 10000 V and 120 Hz to 360 Hz for about 3 hours to 6 hours.

Thus, the fragrance | flavor component (fragrance | flavor) 10a which added the metal ion containing liquid 16 more than bivalence and performed the high voltage process 18 is the mineral neutralization of the essential oil as an aroma component by the metal ion containing liquid 16, and ethyl alcohol. A natural fragrance composition 14 can be obtained by the synergistic action of electron reduction.
Further, in the ethyl alcohol 20 itself to which the metal ion-containing liquid 16 is added, the divalent or higher-valent ions (minerals) in the metal ion-containing liquid 16 subdivide the water molecule group of the alcohol and the alkoxide (alcoholate = alcohol). Alkaline metal binding salts) are also created, and coexisting with organic acids that are alcohol degradation products, so activation of not only water molecules but also calcium and magnesium is promoted, and as a result, movement of each molecular group is activated. The fragrance component (fragrance) 10a quickly permeates into the fragrance component (fragrance) 10a, and the fragrance component is rapidly eluted.
In addition, divalent ions, such as calcium, combine two alcohols with one calcium, minimizing the population of water molecules and at the same time minimizing the population of alcohol molecules, so that fusion and hydration can be done for a short time. Since it is performed at the same time, it also has the effect of reducing the pungent odor of alcohol.
Furthermore, when the high voltage process 18 is given to the fragrance | flavor component of such a state, sufficient electronic reduction will be performed and the fragrance composition 14 nearer natural can be obtained.
In this case, if the high voltage treatment is 5000 V or less, sufficient electron reduction cannot be expected, and if the treatment is carried out at 10000 V for more than 6 hours, there will be a disadvantage due to temperature rise.

  According to the present invention, it is possible to easily produce a natural fragrance component (fragrance composition) from a fragrance as a raw material in a short time.

  FIG. 2 explains the procedure for producing a fragrance composition such as perfume using the fragrance production method according to the present invention shown in FIG.

That is, in FIG. 2, the manufacturing method of the perfume which concerns on this invention adds the metal ion containing liquid 16 to each of many fragrance | flavor components (fragrance | flavor) 10 selected by experts, such as a perfumer, and these fragrance | flavors. By subjecting the component 10 to high-voltage treatment 18, mineral neutralization and electronic reduction of the aroma component are performed, and to each of the obtained fragrances 10 a, the metal ion-containing liquid 16 is also added and subjected to the high-voltage treatment 18. Ethanol 20 which is alcoholated and electronically reduced with two-valued ions is added to extract the fragrance component as a fragrance composition 14, and then these fragrance compositions 14 are mixed according to a desired blending ratio. The product liquid mixture 22 is sorted into a container 24 such as a glass bottle, and the fragrance composition liquid mixture 22 is allowed to stand in a suitable closed space 26 and is high in the closed space 26. Subjected to electron reduction in the pressure processing 18, it is intended to produce a designed the scent perfume composition (perfume) 28 by an expert such as a perfumer.
In this case, the addition amount of the water-soluble mineral-containing liquid (metal ion-containing liquid) 16 to the fragrance 10 and the ethyl alcohol 20 is set in the range of 0.05 wt% to 3.0 wt%, and the high voltage treatment 18 is Although it is set as about 3 hours-6 hours in the range of 5000V-10000V and 120Hz-360Hz, this is the same as that of manufacture of the above-mentioned aromatic composition.

  In addition, the kind of the fragrance | flavor component (fragrance | flavor) 10 is not limited in this manufacturing method including FIG. 1, Citrus type | system | group, floral type | system | group, green type | system | group, spice type | system | group, yonon type | system | group, an oris type | system | group, a fruity type | system | group, aliphatic Aldehide, Herbal, Rustic, Balsam, Sweet, Milky, Marine Ozone, Leather, Shinnam, Woody, Animal, Leather, Tabac, Amber, Musk, etc. It goes without saying that the fragrance used in the production of the fragrance or perfume can be appropriately selected and used.

Further, as the alcohols 12, ethyl alcohol 20 (ethanol) is basically used, but depending on the intended fragrance composition, known alcohols that are added to ordinary fragrance compositions, for example, Propylene glycol, glycerin, trans-2-hexanol and the like can also be used.
Further, ethyl alcohol 20 (ethanol) used in the method of the present invention may be a commercially available product such as 95 ° unmodified ethanol, various modified ethanols, etc., and the water content in the ethanol used in the present embodiment. Is generally 0.5% to 20% by weight.

In FIG. 2, when the extracted fragrance liquid mixture 22 sorted into a container 24 such as a glass bottle is left standing while being subjected to the high-voltage treatment 18, the temperature of the extracted fragrance liquid mixture 22 is used by a known heating or heat retaining means 30. And it is preferable to comprise so that a ripening reaction may be accelerated | stimulated by hold | maintaining in the range of 20 to 40 degreeC.
In this case, when the temperature is 20 ° C. or lower, the ripening reaction is not sufficiently performed, and when the temperature is 40 ° C. or higher, an undesirable side reaction occurs.

  As described above, according to the method for producing a fragrance composition (perfume) according to the present invention, a stable state of a fragrance of a perfume can be realized in a shorter time than a conventional method. This eliminates the storage costs for perfume ripening, thus reducing the manufacturing cost of the perfume and providing high quality perfume at a lower price. is there.

  Next, a sensory test was performed on the fragrance composition obtained by the method of the present invention.

Sensory test

(Preparation of perfume composition)
Synthetic rose, synthetic muguet, synthetic jasmine, natural rose and natural jasmine were each weighed in predetermined amounts as the fragrance (fragrance component) 10 and separated into containers to form three groups.
For each fragrance 10 in the first group, commercially available ethyl alcohol is added to prepare a 10% solution (fragrance composition extract) containing the fragrance component of each fragrance, and the glass jar is separated and left in a cool and dark place. By doing this, the fragrance | flavor composition (= conventional sample, 5 types, A1-A5) by the conventional method was obtained.
On the other hand, 0.05% by weight (second group) and 0.1% by weight (third group) of a metal ion-containing liquid 16 having a valence of 2 or more are added to each of the fragrances 10 of the second and third groups. High voltage treatment 18 (5 hours at 7500 V, 240 Hz) and 0.05% by weight (second group) and 0.1% by weight (third group) of divalent or higher metal ion-containing liquid 16 in commercially available ethyl alcohol Add 10% solution (fragrance component extract) containing fragrance components of each fragrance by adding ethyl alcohol 20 that has been subjected to high-voltage treatment 18 ((7500 V, 240 Hz for 5 hours)) in a similar manner Further, the fragrance component extract is subjected to high voltage treatment 18 (7500 V, 240 Hz for 5 hours) in a closed space and allowed to stand for a predetermined time, so that the total amount of the metal ion-containing liquid 16 is 0.1% by weight. The perfume composition according to .2% by weight the added invention (= treated sample, five × 2 sets, B1 to B5, C1 to C5) was obtained.

(Sensory test (1))
Sensory tests were performed on both the fragrance composition sample obtained as described above (conventional sample) and the fragrance composition sample obtained by the method of the present invention (treated sample).
The sensory test was conducted on a total of 20 panelists, including 10 perfumers and 10 ordinary people. In this test, each panelist asked a question in a state of concealing the contents of the sample and asked for evaluation (answer).
The following questions were asked to each paneler, and the number of corresponding composition samples was counted, and the results shown in Table 1 were obtained (however, question 5 is the longest distance, unit cm).
Question 1: What are the highest quality (harmonious) and low scents?
Question 2: What is the closest fragrance to natural fragrances?
Question 3: What has the highest and lowest scents?
(1) Freshly attached, (2) One hour later, (3) Three hours later Question 4: What is the closest to and far from the natural (natural) scent?
Question 5: What is the longest distance you can smell?

(Analysis of sensory test (1))
Question 1: Synthetic fragrance ⇒ Muguet has a slightly different evaluation, but in Jasmine the processed samples are overwhelmingly harmonized.
Natural fragrance ⇒ The treated sample is evaluated as a high quality fragrance compared to the conventional sample.
Question 2: Synthetic fragrance ⇒ None of the conventional samples are evaluated as being close to natural. The treated sample is evaluated as being almost natural, although there is a difference depending on the amount added.
Question 3; Synthetic fragrance ⇒ The conventional sample has a fragrance when it is freshly applied, but halves with time. The treated sample is evaluated to have a strong scent over time.
Natural fragrance ⇒ Conventional samples are clearly evaluated as having low titers over time, but processed samples are rated as having high titers throughout.
Question 4: Synthetic fragrance ⇒ All the conventional samples are evaluated as being far from the natural state. Jasmine had little difference between the conventional sample and the treated sample, but the treated sample is evaluated as having a natural aroma.
Natural fragrance ⇒ Processed samples are evaluated to be closer to natural, despite being natural.
Question 5: Synthetic fragrance ⇒ All of the conventional samples are short in distance, and the treated sample is evaluated to be fragrant from a distance of 2 to 10 times that of the conventional sample.
Natural fragrance ⇒ There was no difference in rose, but the treated sample of jasmine is evaluated as fragrant even from a distance as it is 8 times the conventional sample.

(Sensory test (2))
Next, the synthetic rose, synthetic muguet, and synthetic jasmine obtained in the preparation of the fragrance composition are mixed in the same proportions for each group (A1 + A2 + A3, B1 + B2 + B3, C1 + C2 + C3), and the above-mentioned fragrance that is superior over time is mixed. Table 20 results were obtained when 20 panelists (10 incense teachers and 10 ordinary people) responded.

(Analysis of sensory test (2))
Group A; Newly rose rose as a top note, but Jasmine wins after 1 hour, Rose again scents after 3 hours, Jasmine becomes weaker, and Muguet has no advantage.
Group B: Freshly added jasmine, rose, and muguet scent, especially jasmine being the top scent. As time goes by, Rose stands out, Jasmine remains as a second note, and Muguet just stands out.
Group C; freshly added jasmine and rose are similar, and muguet smells a little. .

(Sensory test (3))
In addition, the natural rose obtained by the preparation of the above fragrance composition and the natural jasmine are mixed in equal amounts for each group (A4 + A5, B4 + B5, C4 + C5), and the above perfumer 10 When the panelists of 20 people in total, 10 people and 10 ordinary people, answered, the results shown in Table 3 were obtained.

(Analysis of sensory test (3))
Group A; Rose smells in the middle, but Jasmine's scent of the top note is always strong.
Group B: Jasmine is suppressed on the top note rose. Conventionally, jasmine has a strong fragrance, but a weak rose is felt strongly, and jasmine also has a strong scent.
Group C; Rose and jasmine are equally scented and do not change significantly over time. Both rose and jasmine have the same scent, and the scent continues to remain balanced.

(Analysis and comprehensive evaluation of the whole sensory test),
In the case of synthetic fragrances, Group B and Group C (fragrance compositions according to the present invention with 0.1% and 0.2% added) are more harmonious than Group A (fragrance composition according to the conventional method) as it is. The scent has become a high scent and has changed to a scent that is close to nature.
The blend (sensory test {circle around (2)}) is also the same, and the groups B and C have average scents, widths and strengths over time, and a stable state can be realized as compared with the group A.
On the other hand, in the case of natural fragrances, despite being natural, the B and C groups (the fragrance composition according to the present invention with 0.1% and 0.2% added) are more natural than the A group. High quality, titer, and scent sustainability have been improved. In addition, Group A of the blend (Sensory Test (3)) has a strong tendency to feel the scent of jasmine, but Group B has a broader scent because of the rose scent and jasmine scent. Jasmine is also maintained with the same fragrance balance and improved fragrance, titer, and sustainability.

  This is because the fragrance component (fragrance) that has been subjected to high-voltage treatment with the addition of a metal ion-containing liquid is more natural due to the synergistic effect of mineral neutralization of essential oil as the fragrance component by metal ions and electron reduction of ethyl alcohol. As a result, the oxidation is slow, there is little irritation of the scent, and a sweet scent is emitted over a wide range. Accordingly, it is possible to design a desired scent by appropriately adjusting the addition amount of the metal ion-containing liquid and the high voltage treatment conditions.

  FIG. 3 shows an aroma composition 14 or a fragrance composition obtained by sticking a PET transparent sheet 32 coated with an acrylic adhesive on the back side to a card-like mount 34 and the surface of the transparent sheet 32 obtained by the method described above. 28 and an ink containing water-based medium, silk printing is performed, and a peelable PET transparent sheet 38 coated with a silicon coat is pasted on the silk printed surface 36. Further, a desired print indication is displayed on the peelable transparent sheet 38. It is an aroma composition attachment card or a fragrance composition attachment card 42 constituted by sticking the applied surface sheet 40.

  The attached card 42 is a scent produced from the fragrance composition 14 or the fragrance composition 28 contained in the silk print surface 36 applied to the surface of the transparent sheet 32 by peeling off the surface sheet 40 and the peelable transparent sheet 38 from the card-like mount 34. However, since the fragrance composition 14 or the fragrance composition 28 is a natural fragrance itself without being affected by the odor of the constituent material itself including the adhesive and the ink composition, it is an accurate testing. As well as being able to enjoy, the scent can be fully enjoyed, and furthermore, since the fragrance itself lasts longer than before, it can be used over a long period of time.

  According to the method of the present invention, it is possible to significantly shorten the development period of the perfume, that is, to achieve a stable state of the fragrance of the perfume in a short period of time. The image of the desired scent can be presented as a sample in real time, and it will be possible to build a new business model that provides perfume of the desired scent on demand to consumers. is there.

10 .. Fragrance (fragrance ingredient)
12 ..Alcohols 14 ..Aroma composition (fragrance component extract)
16 ·· Metal ion-containing liquid 18 ·· High voltage treatment 20 ·· Ethyl alcohol (ethanol)
22 ..Aroma composition mixture 24 ..Container (glass bottle)
26..Closed space 28..Perfume composition (perfume)
30 .. Insulation means 32 .. PET transparent sheet 34.. Card-like mount 36.. Silk printing surface 38.. Peelable PET transparent sheet 40.. Top sheet 42.. Aroma composition-attached card or fragrance composition attachment card

Claims (7)

A ground mixture containing starch and / or cereals, seeds and eggshell in a weight ratio of 2.5: 3.0: 0.5 is put into a fermentation tank, and water 3 is added to the mixed raw material 1 while stirring. After heating to 50 to 100 ° C. and pregelatinizing the starch, the mixture is kept at 30 to 40 ° C. to obtain a viscous mixed solution, then koji molds are added to this mixed solution for complex fermentation, and this mixed fermentation mixture is further mixed Natural fragrance or synthetic fragrance to which a metal ion-containing liquid having a valence of 2 or more, which is a water-soluble mineral-containing liquid produced by aging for 1 to 2 months, is subjected to high voltage treatment, and then the fragrance has the above valence of 2 or more. production of the metal ion-containing solution was added and extracted by adding ethyl alcohol of performing a high voltage process, 5000V～10000V the high voltage treatment, aroma composition which is characterized in that in the range of 120Hz~360Hz Law.   The fragrance composition according to claim 1, wherein the divalent or higher-valent metal ion-containing liquid added to each of the fragrance and ethyl alcohol is set in a range of 0.05 wt% to 3.0 wt%. Production method. A ground mixture containing starch and / or cereals, seeds and eggshell in a weight ratio of 2.5: 3.0: 0.5 is put into a fermentation tank, and water 3 is added to the mixed raw material 1 while stirring. After heating to 50 to 100 ° C. and pregelatinizing the starch, the mixture is kept at 30 to 40 ° C. to obtain a viscous mixed solution, then koji molds are added to this mixed solution for complex fermentation, and this mixed fermentation mixture is further mixed Each of the above-mentioned two kinds of natural or synthetic fragrances that have been subjected to high-voltage treatment by adding a divalent or higher-valent metal ion-containing liquid that is a water-soluble mineral-containing liquid produced by aging for 1 to 2 months. The fragrance composition is extracted by adding ethyl alcohol that has been subjected to high voltage treatment and a metal ion-containing liquid that is higher than the valence, and then the obtained fragrance composition is mixed and left in a closed space. There line of high voltage processing to standing time, before 5000V~10000V a high voltage process, the manufacturing method of a perfume composition characterized rows Ukoto range of 120Hz～360Hz. The fragrance composition according to claim 3 , wherein the divalent or higher-valent metal ion-containing liquid added to each of the fragrance and ethyl alcohol is set in a range of 0.05 wt% to 3.0 wt%. Production method. The manufacturing method of the fragrance | flavor composition of Claim 3 or 4 which accommodates the liquid mixture of an fragrance composition in a glass container, and carries out still processing. The method for producing a fragrance composition according to any one of claims 3 to 5 , comprising maintaining a stationary temperature of the mixed liquid of the fragrance composition in a range of 20 ° C to 40 ° C. A resin transparent sheet having an adhesive applied to the back surface was attached to a card-like mount and manufactured on the surface of the resin transparent sheet by the method for manufacturing an aroma composition according to claim 1. The fragrance composition or the fragrance composition produced by the method for producing the fragrance composition according to any one of claims 3 to 6 is silk-printed, and a peelable resin transparent sheet is adhered to the silk-printed surface. Further, a method for producing a fragrance composition or a fragrance composition-attached card , wherein a surface sheet having a desired print indication is attached to the peelable transparent sheet.

Images