JP5824878B2 - Method for producing anti-counterfeit particles - Google Patents

Description

  The present invention includes credit cards, cash cards, ID cards, membership cards and other cards, banknotes, stock certificates, gift certificates, lottery tickets, bills, checks, admission tickets, and other securities, cash certificates, various certificates, and high-priced products. It relates to anti-counterfeit particles used as so-called taggants.

  Conventionally, an anti-counterfeit additive called taggant (also called taggent) has been used in articles such as securities that need to prevent forgery. The taggant is required to be highly difficult to counterfeit, to be able to easily and quickly perform authenticity determination, and to be inexpensive.

  As such taggant particles, a micro marker that is configured to be observable using an optical magnifying device and is patterned is disclosed. These micro-markers are formed by lithographic techniques in the integrated circuit technology field, or formed by other micro-machining technology field methods, such as graphics, logos, personal It is configured to be recognized as having information based on the contents of the design, such as a signature, date, and words (see Patent Document 1).

JP 2002-230512 A

  However, as conventional taggant particles, those made of resin are generally used, and there is a problem that the mechanical strength is low, and the durability is low, that is, it becomes damaged when applied to an article and cannot be identified. In addition, the taggant particles made of resin have a problem of low designability in applications that require metallic luster.

  The present invention has been made in view of the above-described problems, and an object of the present invention is to obtain anti-counterfeit particles having high durability and excellent design, which are used as taggant particles.

In order to achieve the above-mentioned object, the following invention is provided.
(1) A forgery-preventing particle characterized in that at least two kinds of metal layers are laminated, and the shape can be identified by observing it in an enlarged manner.
(2) The shape of the anti-counterfeit particles is a flat plate shape, and the contour of the anti-counterfeit particles and / or the shape of the penetrating portion is any one or more of letters, numbers, symbols, and figures. The anti-counterfeit particle according to (1), wherein
(3) The anti-counterfeit particle according to (1) or (2), wherein at least one of the metal layers is an alkali-soluble metal layer.
(4) The anti-counterfeit particle according to (1), wherein the surface of the metal layer has a concavo-convex shape, and the concavo-convex shape is identifiable by magnifying and observing.
(5) The anti-counterfeiting according to (4), wherein the anti-counterfeit particle is formed with one or more three-dimensional shapes of letters, numbers, symbols, and figures by the uneven shape. Particles.
(6) The concavo-convex shape is a diffraction grating or a hologram, and any one or more of letters, numbers, symbols, and figures are displayed on the surface of the anti-counterfeit particles by the diffraction grating or the hologram. (4) The anti-counterfeit particle according to (4).
(7) The counterfeit according to any one of (4) to (6), wherein the shape of the anti-counterfeit particle is one or more of letters, numbers, symbols, and figures. Prevention particles.
(8) The anti-counterfeit particle according to any one of (1) to (7), wherein the size is 10 to 300 μm and the thickness is 1 to 25 μm.
(9) An anti-counterfeit ink, wherein the anti-counterfeit particles according to any one of (1) to (8) are dispersed in a dispersion medium.
(10) A forgery-preventing sheet, wherein the anti-counterfeit particles according to any one of (1) to (8) are dispersed in a resin.
(11) A securities characterized in that the anti-counterfeit particles according to any one of (1) to (8) are provided on the surface.
(12) A card, wherein the anti-counterfeit particles according to any one of (1) to (8) are provided on the surface.
(13) Enlarging and observing the base material preparation step of preparing a base material in which a sacrificial layer, an alkali-soluble metal layer, and a photosensitive resin layer are laminated in this order, and the photosensitive resin layer on the base material An exposure step of exposing to a pattern having a shape identifiable by the above, a patterning step of patterning the photosensitive resin layer and the alkali-soluble metal layer by developing with an alkaline developer, and the photosensitive resin layer, A photosensitive resin layer peeling step for peeling from the alkali-soluble metal layer; a second metal layer forming step for forming a second metal layer on the alkali-soluble metal layer; A method for producing anti-counterfeit particles, comprising: a peeling step of peeling particles having a layer and the second metal layer from the substrate.
(14) The method for producing anti-counterfeit particles according to (13), wherein the second metal layer is formed by electroplating.

  According to the present invention, anti-counterfeit particles that are used as taggant particles and have high durability and excellent design properties can be obtained.

(A)-(c) Perspective view which shows particle | grains 1a-1c concerning this invention. (A)-(f) The schematic sectional drawing which shows the manufacturing method of the particle | grains 1a concerning the 1st Embodiment of this invention. (A)-(f) The schematic sectional drawing which shows the manufacturing method of particle | grains 1b and 1c concerning the 2nd Embodiment of this invention. (A) Top view which shows the securities 41 concerning this invention, (b) Sectional drawing which shows the A-A 'cross section in (a). (A) The top view which shows the card | curd 51 concerning this invention, (b) Sectional drawing which shows the B-B 'cross section in (a).

  Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.

[First Embodiment]
(Configuration of particle 1a)
Fig.1 (a) is a figure which shows the particle | grains 1a concerning the 1st Embodiment of this invention. The particle 1a shown in FIG. 1 (a) is formed by laminating a first metal layer 3a and a second metal layer 5b, and has a substantially flat plate shape, but the outline and the shape of the penetrating part 5 are enlarged and observed. Can be identified. That is, it can be identified by magnifying and observing the outline of the base body and the penetrating portion provided in the base body. In FIG. 1A, the letter “DNP” consisting of the penetrating portion 5 is formed on the disk-shaped base, but the outline of the base is not limited to the disk, but an ellipse, polygon, heart Various shapes such as a shape, a star shape, an outline of an animal, an outline of a character, an outline of a number, an outline of a symbol, and an outline of a figure can be adopted. Moreover, as a shape of the penetration part 5, various numbers, a symbol, a figure, etc. can be given besides a character. In FIG. 1, the penetrating part 5 is provided. However, the penetrating part 5 is not essential as long as either the outline of the particle or the penetrating part 5 is enlarged and observed.

  Note that that the shape is identifiable means that an artificial shape is formed and can be distinguished from a shape that is naturally formed without intention. Therefore, when forging an article to which particles 1a are applied, even if the outer shape of the article can be copied, it is difficult to copy the particles 1a, so that it is possible to distinguish between a genuine article and a forged article. In addition, since the shape can be identified, it is possible to discriminate the production time, the usage, and the like even between genuine articles by changing the shape of the particles 1a applied to each article.

  The metal constituting the first metal layer 3a and the second metal layer 4a is not particularly limited, but is easy to obtain, easy to form, difficult to oxidize in the atmosphere, and cost of raw materials. Therefore, nickel, aluminum, iron, tin, and zinc are preferable.

  The thickness of the particle 1a is preferably 1 μm or more, and preferably 25 μm or less. If the thickness is too thin, the strength cannot be maintained, and the particles are easily damaged during handling. On the other hand, if the thickness is too thick, it becomes difficult to form a thick film of the photosensitive resin during production, and the dispersibility in the resin or dispersion medium is poor, which is inconvenient during handling.

The size of the particles 1a is preferably 10 to 300 μm. If it is too small, particles cannot be observed using a simple magnifying device such as a magnifying glass, and authentication cannot be performed unless a more complicated device such as a microscope is used. On the other hand, if the size is too large, the characteristics of the particles can be recognized with the naked eye without using a magnifying device, and the effect of preventing forgery is reduced. In addition, since the particle | grains 1a are flat form, it is preferable that thickness is below half of a size. Here, the size is the longest length when the particle is viewed in plan, for example, the length of the diagonal line if the shape is a quadrangle, and the length of the long axis if the shape is an ellipse. is there.
In addition, the character “DNP” in FIG. 1 a cannot be recognized with the naked eye, but is large enough to be recognized using a loupe or the like.

(Effect of particle 1a)
Since the particle 1a of the present invention includes a metal layer, it has excellent mechanical strength, excellent durability, metallic luster, and excellent design.

  Since the particle 1a of the present invention cannot grasp the characteristics of the particle 1a with the naked eye and can grasp the characteristics for the first time with an apparatus such as a magnifying glass, it is not easy to know that the imparted article has been subjected to anti-counterfeiting technology. Therefore, the particles 1a can exhibit a higher anti-counterfeit effect than the anti-counterfeit technology that can be visually confirmed.

  Since the particle 1a of the present invention has a metal layer laminated, even if it is possible to forge the features that can be identified by magnifying and observing the outline and penetration of the particle 1a, Since it is not known that la contains the laminated metal, it is considered that particles composed of a single layer of metal are formed. Therefore, if the particles are analyzed and found to consist of a single layer of metal, a counterfeit product can be detected. That is, the particle 1a according to the present invention is forensic. Forensic means that authenticity is determined by an analytical instrument. Since an analytical instrument is required for overt (authentication determination by the five senses) and covert (authentication determination by a simple instrument), a high anti-counterfeiting effect can be obtained.

(Use of particle 1a)
When the particles 1a are dispersed in a dispersion medium such as a water-soluble binder, an anti-counterfeit ink can be obtained. By using such anti-counterfeiting ink and printing by silk screen printing or the like, particles can be easily imparted to the article.

  The anti-counterfeit sheet can be obtained by dispersing the particles 1a in an ultraviolet curable resin or the like and drying or curing. For example, by applying a transparent ultraviolet curable resin in which particles are dispersed onto an article, irradiating with ultraviolet rays and curing the article, a sheet provided with particles can be formed on the article. In addition, resin particles containing particles can be obtained by mixing particles 1a with PVC, PP, ABS, AES, PS, etc. in an extrusion molding machine or injection molding machine, and performing extrusion molding or injection molding. It is done. As a result, various resin molded products such as sheets and cards to which particles are applied and forgery prevention technology is incorporated are obtained.

  Moreover, the securities and the card | curd with which the particle | grains were provided are obtained by printing on the securities or the card | curd with the ink containing the particle | grains 1a, or sticking the sheet | seat containing the particle | grains 1a, or forming by application | coating. . For example, as shown in FIG. 4, the securities 41 form a band-shaped particle-containing portion 43. The particle-containing part 43 is obtained by printing ink containing particles in a band shape, or by pasting or forming a belt-like sheet containing particles. Further, as shown in FIG. 5, the card 51 forms a patchy particle-containing portion 53. The particle-containing portion 53 can be obtained by printing ink containing particles in a patchy manner, or pasting or forming a patchy sheet containing particles. In addition, in order to make it easy to handle with machines, such as ATM, the particle | grain containing part 53 is formed in the recessed part of the card | curd 51 so that it may not protrude from the surface of a card | curd. Note that securities include banknotes, stock certificates, gift certificates, lottery tickets, bills, checks, admission tickets, and cards include credit cards, cash cards, ID cards, and membership cards.

(Method for producing particle 1a)
Next, the manufacturing method of the particle | grains 1a concerning this invention is demonstrated.
FIG. 2A shows a base material preparation step. The base material preparation step is a step of preparing a base material in which a sacrificial layer, an alkali-soluble metal layer, and a photosensitive resin layer are laminated in this order.
FIG. 2B shows the exposure process. An exposure process is a process of exposing to the pattern of the shape which can be identified by magnifying and observing the said photosensitive resin layer on the said base material.
FIG. 2C shows a patterning process. The patterning step is a step of developing with an alkaline developer and patterning the photosensitive resin layer and the alkali-soluble metal layer. FIG. 2D shows the photosensitive resin layer peeling step. The photosensitive resin layer peeling step is a step of peeling the photosensitive resin layer from the alkali-soluble metal layer.
FIG. 2E shows a second metal layer forming step. The second metal layer forming step is a step of forming the second metal layer on the alkali-soluble metal layer.
FIG. 2F shows the peeling process. The peeling step is a step of immersing the substrate in water, dissolving the sacrificial layer, and peeling the particles having the alkali-soluble metal layer and the second metal layer from the substrate.

  First, as shown in FIG. 2A, the sacrificial layer 11, the alkali-soluble metal layer 13, and the photosensitive resin layer 15 are formed on the base material 9.

  The base material 9 is not specifically limited, The base material generally used for photolithography can be used. For example, non-flexible transparent rigid materials such as borosilicate glass, aluminoborosilicate glass, alkali-free glass, quartz glass, synthetic quartz glass, soda lime glass, white sapphire, transparent resin film, optical resin film A transparent flexible material having flexibility such as can be used. As the flexible material, acrylic such as polymethyl methacrylate, polyamide, polyacetal, polybutylene terephthalate, polyethylene terephthalate, polyethylene naphthalate, triacetyl cellulose, syndiotactic polystyrene, polyphenylene sulfide, polyether ketone, polyether ether ketone, Examples include fluororesin, polyether nitrile, polycarbonate, modified polyphenylene ether, polycyclohexene, polynorbornene resin, polysulfone, polyethersulfone, polyarylate, polyamideimide, polyetherimide, thermoplastic polyimide, and the like. However, those made of general plastics can also be used.

  As the water-soluble resin used for the sacrificial layer 11, polyvinyl alcohol, polyethylene oxide, gelatin or the like is used. The sacrificial layer 11 serves to hold the particles on the substrate until they are separated into individual pieces. The sacrificial layer is a layer formed on the assumption that it is finally removed, and is often used when a film is partially formed or two films are separated. Alternatively, instead of the sacrificial layer 11, a dry film resist (DFR) or the like that dissolves in an organic solvent such as acetone is used as the sacrificial layer, and the sacrificial layer is dissolved using an organic solvent at the time of particle peeling described later. Also good. In other words, the sacrificial layer is not limited to the water-soluble resin, but may be any solvent that does not affect the material forming the particles.

  As the alkali-soluble metal used for the alkali-soluble metal layer 13, at least one alkali-soluble metal selected from the group consisting of aluminum, zinc, silicon, lead, and tin can be used. It is preferable to use aluminum. As a method for forming the alkali-soluble metal layer 13, a known film formation method such as sputtering or vacuum deposition can be used.

The photosensitive resin layer 15 is obtained by applying a positive or negative photosensitive resin composition over the entire surface.
The negative photosensitive resin is not particularly limited, and a commonly used negative photosensitive resin can be used. For example, a chemically amplified photosensitive resin based on a crosslinked resin, specifically, a chemically amplified photosensitive resin in which a crosslinking agent is added to polyvinylphenol and an acid generator is further added. In addition, as an acrylic negative photosensitive resin, a photopolymerization initiator that generates a radical component upon irradiation with ultraviolet rays, a component that has an acrylic group in the molecule, causes a polymerization reaction by the generated radical, and cures thereafter, What contains the functional group (for example, the component which has an acidic group in the case of image development by an alkaline solution) which can melt | dissolve an unexposed part by image development can be used. Among the above-mentioned components having an acrylic group, relatively low molecular weight polyfunctional acrylic molecules include dipentaerythritol hexaacrylate (DPHA), dipentaerythritol pentaacrylate (DPPA), tetramethylpentatriacrylate (TMPTA) and the like. Can be mentioned. In addition, examples of high molecular weight polyfunctional acrylic molecules include polymers in which an acrylic group is introduced via an epoxy group into a part of the carboxylic acid group of the styrene-acrylic acid-benzyl methacrylate copolymer, and methyl methacrylate-styrene- An acrylic acid copolymer etc. are mentioned.
The positive photosensitive resin is not particularly limited, and a commonly used one can be used. Specifically, a chemically amplified photosensitive resin using a novolac resin as a base resin can be used.

  The photosensitive resin layer 15 may be formed by attaching a dry film resist (DFR).

  Thereafter, as shown in FIG. 2B, the photosensitive resin layer 15 is exposed in a predetermined pattern through a mask 18 having a predetermined pattern. The photosensitive resin 15 is exposed with a pattern corresponding to the outline of the particle 1 a and the penetrating part 5. The mask 18 is provided with a light shielding film 20 on a transparent substrate 19, and a transmissive part through which the exposure light 17 is transmitted and a light shielding part through which the exposure light 17 is hardly transmitted are formed by the light shielding film.

  The step of exposing the photosensitive resin layer 15 with a predetermined pattern is not particularly limited. However, in addition to the method using a mask as shown in FIG. 2B, a digital micromirror device is used and the mask is not interposed. You may expose to. A digital micromirror device (also called a digital mirror device or DMD) is an element in which a number of micromirror surfaces (micromirrors) that can be individually driven are arranged in a plane. By individually driving each mirror, light projection can be controlled for each display pixel, so that exposure can be performed in a predetermined pattern without using a mask.

  In addition to the method using a mask as shown in FIG. 2B, exposure can be performed with a predetermined pattern by direct drawing with a laser or an electron beam.

  Thereafter, as shown in FIG. 2 (c), the photosensitive resin layer 15 is dissolved with an alkaline developer, and the underlying alkali-soluble metal layer 13 is further dissolved. The photosensitive resin layer 15 and the alkali-soluble metal layer are then dissolved. 13 is patterned.

  Thereafter, as shown in FIG. 2D, the photosensitive resin layer 15 is peeled or removed using an organic solvent or the like.

  Thereafter, as shown in FIG. 2 (e), the second metal layer 4 a is selectively formed on the alkali-soluble metal layer 13. In order not to form the second metal layer 4a on the sacrificial layer 11 or the like other than on the alkali-soluble metal layer 13, the second metal layer 4a is preferably formed by electroplating. The material of the second metal layer 4a is not particularly limited as long as it is a metal that can be electroplated. For example, nickel, chromium, iron, cobalt, titanium, gold, silver, copper, a platinum group, or the like is used. it can. In addition, in order to perform electroplating, the patterns of the alkali-soluble metal layer 13 are electrically connected by a thin line pattern or a thin bridge.

  Thereafter, as shown in FIG. 2 (f), when the base material 9 is immersed in water, the sacrificial layer 11 made of a water-soluble resin is dissolved, and the alkali-soluble metal layer 13 formed on the sacrificial layer 11 and the first layer Particles 1a composed of two metal layers 4a are peeled off from the base material 9, and particles 1a having penetrating portions 1a are obtained. Here, the alkali-soluble metal layer 13 corresponds to the first metal layer 3a constituting the particle 1a.

  By the manufacturing method according to the first embodiment of the present invention, the particle 1a in which the first metal layer 3a and the second metal layer 4a are laminated can be obtained.

  Moreover, according to the manufacturing method concerning the 1st Embodiment of this invention, several particle | grains 1a can be formed on the base material 9 of 1 sheet, and a lot of particle | grains 1a can be manufactured by one exposure and image development. In particular, it is preferable to form a large number of particles on almost the entire surface of the substrate 9 by performing stepper exposure capable of exposing the entire surface of the wafer while moving the exposure area where the photomask is reduced and projected.

  In addition, the manufacturing method according to the first embodiment of the present invention can be realized with facilities that have been generally used so far, and it is not necessary to introduce special facilities, so that the particles 1a can be manufactured at low cost. can do.

  In the manufacturing method according to the first embodiment of the present invention shown in FIG. 2, particles 1 b and 1 c described later can be manufactured by forming uneven shapes 21 described later on the surface of the sacrificial layer 11.

[Second Embodiment]
(Configuration of particle 1b)
FIGS. 1B and 1C are views showing particles 1b and 1c according to the second embodiment of the present invention. The particle 1b shown in FIG. 1 (b) has a concavo-convex shape that can be identified by magnifying and observing it on a substantially flat substrate formed by laminating a first metal layer 3b and a second metal layer 4b. As shown, a diffraction grating or hologram identification portion 6b for displaying characters is formed. The diffraction grating or hologram of the identification unit 6b reproduces a three-dimensional image by recording light interference fringes on a substrate with a fine unevenness process having a depth of 1 μm or less. The shape of the substrate can be identified by magnifying and observing, and the shape is not limited to a disk, and various shapes such as an ellipse, a polygon, and a star can be used. Moreover, as the identification part 6a provided on a base | substrate, a flower, a design, etc. can be given besides a various figure, a number, a symbol besides a character. That is, it can be identified by magnifying and observing the identification portion 6b made of a design such as the outline of the substrate and the shape, pattern or color applied to the substrate.

  In the particle 1b, two or more kinds of metal layers are laminated. It is made of an alkali-insoluble metal that is not affected by an alkaline developer during production. Although it does not specifically limit as an alkali-insoluble metal, Since it is preferable to form into a film by electroplating at the time of manufacture, it is preferable to use nickel, chromium, iron, cobalt, titanium, gold | metal | money, silver, copper, platinum group, etc. In particular, it is preferable to use nickel which has excellent electroplating characteristics and can be used at low cost in order to reproduce a fine uneven shape.

  The thickness of the particles 1b is preferably 1 μm or more and 25 μm or less. If the thickness is too thin, the strength cannot be maintained, and the particles are damaged during handling. On the other hand, if the thickness is too thick, it becomes difficult to form a thick metal film during production, and the dispersibility in a resin or dispersion medium is poor, which is inconvenient in handling.

The size of the particles 1b is preferably 10 to 300 μm. If it is too small, particles 1b cannot be observed using a simple magnifying instrument such as a magnifying glass, and authenticity cannot be determined unless a more complicated device such as a microscope is used. On the other hand, if the size is too large, the features of the particles 1b can be recognized with the naked eye without using a magnifying device, and the effect of preventing forgery is reduced. In addition, since the particle | grains 1b are flat form, it is preferable that thickness is below half of a size. Here, the size is the longest length when the particle is viewed in plan, for example, the length of the diagonal line if the shape is a quadrangle, and the length of the long axis if the shape is an ellipse. is there.
In addition, the character “DNP” in FIG. 1B cannot be recognized with the naked eye, but is large enough to be recognized using a loupe or the like.

(Effect of particle 1b)
Since the particles 1b of the present invention are made of metal, they have excellent mechanical strength, excellent durability, metallic luster, and excellent design.

  Since the particle 1b of the present invention has a concavo-convex shape such as a hologram or a diffraction grating that is difficult to manufacture on the surface, the forgery prevention effect is improved.

  When the particles 1b of the present invention are applied to an article, the characteristics of the particles cannot be grasped with the naked eye and it cannot be confirmed that the anti-counterfeiting technology is applied. The effect can be demonstrated.

  Since the particle 1b of the present invention is composed of a plurality of types of metals, it can be analyzed only by using other analysis means that are composed of a plurality of types of metals in addition to the features that can be observed optically such as the outer shape. It has characteristics and is forensic. Forensic means that authenticity is determined by an analytical instrument. Since an analytical instrument is required for overt (authentication determination by the five senses) and covert (authentication determination by a simple instrument), a high anti-counterfeiting effect can be obtained. That is, since the particle 1b is composed of a plurality of types of metals, even if the features such as the shape and identification part of the particle 1b can be replicated, the particles 1b usually include a metal laminated. Since it is not known, it is considered that particles made of a single layer of metal are formed. Therefore, if the particles are analyzed and found to consist of a single layer of metal, a counterfeit product can be detected.

  The use of the particle 1b is the same as that of the particle 1a.

(Configuration of particle 1c)
In the particle 1c shown in FIG. 1C, a three-dimensional character identification portion 6c is formed on a substantially flat substrate formed by laminating a first metal layer 3c and a second metal layer 4c. Yes. In FIG. 1C, thick characters are formed on the disk, but the shape of the substrate is not limited to the disk, and various shapes such as an ellipse, a polygon, and a star are available. Can be used. Moreover, as a shape provided on the base material, in addition to letters, various figures, numbers, symbols, three-dimensional flowers and designs can be applied. Moreover, since the three-dimensional structure of the identification part 6c is observed three-dimensionally, it is preferable that the depth is 1 μm or more.

  The configuration of the particle 1c is the same except that the identification part is different. The effect and use of the particle 1c are the same as those of the particle 1b.

  The thickness of the particle 1c, that is, the thickness including not only the thickness of the substrate but also the thickness of the identification portion 6c is preferably 2 μm or more, and preferably 25 μm or less. If the thickness is too thin, the strength cannot be maintained, the particles are easily damaged during handling, and the three-dimensional structure formed in the particles is not observed three-dimensionally. On the other hand, if the thickness is too thick, it becomes difficult to form a thick metal film during production, and the dispersibility in a resin or dispersion medium is poor, which is inconvenient in handling.

(Method for producing particles 1b and 1c)
Next, the manufacturing method of particle | grains 1b and 1c concerning this invention is demonstrated. The fine particle 1b having the diffraction grating or hologram identification portion 6b and the particle 1c having the three-dimensional identification portion 6c can be manufactured by the same manufacturing method except that the shape of the concavo-convex shape 21 is different.

  First, as shown in FIG. 3A, a sacrificial layer 25 containing an alkali-soluble resin is formed on the base material 23. The sacrificial layer 25 is formed by applying an alkali-soluble resin. The base material 23 can use the same base material as that used for the base material 9. Moreover, it is although it does not specifically limit as alkali-soluble resin, Generally used alkali-soluble resin for photoresists can be used.

  Thereafter, as shown in FIG. 3B, the concavo-convex shape 21 is formed in the sacrificial layer 25. The uneven shape 21 is formed by photolithography through a mask or a gradation mask, photolithography using a digital micromirror device, photolithography by direct drawing with a laser, or the like.

  Thereafter, as shown in FIG. 3C, a metal uneven layer 27 containing an alkali-insoluble metal is formed on the sacrificial layer 25. The metal uneven layer 27 is formed by sputtering or vapor deposition.

  Thereafter, as shown in FIG. 3D, after forming the metal uneven layer 27, a second metal layer 29 containing an alkali-insoluble metal is formed. The second metal layer 29 is preferably formed by electroplating because it is necessary to form a relatively thick film. Although it does not specifically limit as an alkali insoluble metal which comprises the metal uneven | corrugated layer 27 and the 2nd metal layer 29, Since it is preferable to form into a film by electroplating at the time of manufacture, nickel, chromium, iron, cobalt, titanium, gold | metal | money, Silver, copper, platinum group and the like are preferably used.

  Thereafter, as shown in FIG. 3E, a resist layer 31 containing an alkali-soluble resin having a predetermined pattern corresponding to the contours of the particles 1b and 1c is formed on the second metal layer 29.

  The step of forming the resist layer 31 containing the alkali-soluble resin having a predetermined pattern is not limited as long as a desired resist layer is obtained, but the following three methods are conceivable.

  The first method is a method of patterning a resist layer using photolithography. The method includes a step of applying a positive or negative photosensitive resin composition to the entire surface to form a resist layer, a step of exposing the resist layer through a mask having a predetermined pattern, and the resist Developing the layer.

  Further, instead of performing exposure through a mask, a digital micromirror device may be used for exposure without using a mask. A digital micromirror device (also called a digital mirror device or DMD) is an element in which a number of micromirror surfaces (micromirrors) that can be individually driven are arranged in a plane. By individually driving each mirror, light projection can be controlled for each display pixel, so that exposure can be performed in a predetermined pattern without using a mask.

  The second method is a method of patterning a resist layer by direct writing. The method comprises a step of applying a photosensitive resin composition to the entire surface to form a resist layer, a step of exposing the resist layer in a predetermined pattern by direct drawing with a laser or an electron beam, and the resist layer, Developing.

  The third method is a method of directly forming a resist layer having a predetermined pattern using a printing technique. Specifically, the method includes a step of printing a resist material by silk screen printing or the like. As the printing technique, a conventional intaglio printing or stencil printing technique is used.

  Thereafter, as shown in FIG. 3F, the metal uneven layer 27 and the second metal layer 29 are etched using the resist layer 31 as a mask. At this time, wet etching, dry etching, or the like can be appropriately used depending on the metal constituting the metal uneven layer 27 and the second metal layer 29. The metal uneven layer 27 corresponds to the first metal layers 3b and 3c, and the second metal layer 29 corresponds to the second metal layers 4b and 4c.

  Thereafter, as shown in FIG. 3G, the sacrificial layer 25 and the resist layer 31 are dissolved with an alkaline developer or the like, and the particles 1 b and 1 c are peeled off from the substrate 23.

  As a result, as shown in FIG. 3H, individualized particles 1b and 1c are obtained.

  According to the manufacturing method according to the second embodiment of the present invention, particles 1b and 1c having irregularities on the surface are obtained.

  By the manufacturing method according to the second embodiment of the present invention, particles 1b and 1c in which two or more kinds of metals are laminated can be obtained.

  Moreover, according to the manufacturing method concerning the 2nd Embodiment of this invention, several particle | grains 1b and 1c can be formed on the base material 23 of 1 sheet, and a lot of particle | grains 1b and 1c are manufactured by one exposure and image development. Is possible. In particular, it is preferable to form a large number of particles on almost the entire surface of the substrate 23 by performing stepper exposure capable of exposing the entire surface of the wafer while moving the exposure area where the photomask is reduced and projected.

  In addition, the manufacturing method according to the second embodiment of the present invention can be realized with facilities that have been generally used so far, and it is not necessary to introduce special facilities, so that the particles 1b and 1c can be manufactured at low cost. Can be manufactured.

  In the manufacturing method according to the second embodiment of the present invention shown in FIG. 3, the resist layer 31 is formed in a pattern corresponding to the outline of the particle 1 a and the penetrating part 5 without providing the concave-convex shape 21 in the sacrificial layer 23. By forming it, the particle 1a according to the first embodiment can be manufactured.

Hereinafter, the present invention will be specifically described with reference to examples.
[Example 1]
A 1 wt% aqueous solution of polyvinyl alcohol was applied on the entire surface of a glass substrate (NA-35 manufactured by HOYA) with a bar coater. A sacrificial layer made of polyvinyl alcohol having a thickness of 0.2 μm was obtained by drying at 90 ° C. for 5 minutes.
Aluminum was sputtered on the sacrificial layer to obtain an alkali-soluble metal layer made of aluminum having a thickness of 40 nm.
A negative photosensitive resin (IT-GR 1501-5 manufactured by DNP Fine Chemical) is spin-coated on the alkali-soluble metal layer (film formation conditions: slope 2 seconds—550 rpm for 3 seconds—slope 2 seconds), and room temperature for 5 minutes. After vacuum drying, it was baked at 80 ° C. for 10 minutes. A photosensitive resin layer having a thickness of 2.5 μm was obtained.
Using an aligner, pattern exposure was performed at 60 mJ / cm ² , followed by development with a 10 wt% aqueous potassium hydroxide solution for 15 seconds. At this time, the unexposed negative photosensitive resin was dissolved, and the lower layer aluminum was dissolved and patterned.
After the exposed negative photosensitive resin layer was peeled off, nickel was electroplated (electroformed) on the patterned alkali-soluble metal layer to form a second metal layer made of nickel having a thickness of 6 μm.
When this substrate was immersed in water, the sacrificial layer was dissolved to obtain particles formed by laminating a first metal layer of aluminum and a second metal layer of nickel. Thereafter, the particles were collected and dispersed in pure water to obtain an aqueous dispersion.
These particles had a size of 200 μm and a thickness of 6 μm.

  0.5 g of an initiator (Merck Darocur 1173) was added to 5 g of water-soluble ultraviolet curable resin (AQ-9 manufactured by Arakawa Chemical) and stirred, and 1 g of an aqueous taggant solution was added to the resulting solution and stirred. It apply | coated with the bar coater on the glass base material (HOYA NA-35) with the spin coater. Irradiation with a UV aligner (20 mW / s 360 sec) was performed to form a film. The printed anti-counterfeit ink could not grasp the shape of the particles with the naked eye, but the particles could be identified when enlarged using a magnifying glass.

[Example 2]
As the support film, a 16 μm thick polyester resin film (manufactured by Toray Industries Inc., Lumirror) was used. A negative dry film resist (ORDYL PR manufactured by Tokyo Ohka Kogyo Co., Ltd., thickness 20 μm) was used as a sacrificial layer on the support film.
After that, it is exposed by a parallel ultraviolet light irradiation device through a photomask engraved with a diffraction grating pattern and developed with an alkali developer (aqueous solution containing sodium hydroxide as a main component: concentration 1 wt%), and sacrificed. A diffraction grating pattern for hologram was formed as an uneven shape on the surface of the layer.
Further, chromium was vacuum deposited on the surface of the sacrificial layer to a thickness of 40 nm as a metal uneven layer.
Further, a nickel layer having a thickness of 10 μm was formed on the metal uneven layer by electroplating.
Further, a negative photoresist (acrylic resist PMER-N manufactured by Tokyo Ohka Kogyo Co., Ltd.) was applied and dried and heated at 70 ° C. for 30 minutes to obtain a uniform resist film having a thickness of 10 μm. After that, through a photomask capable of exposing a desired pattern, the ultraviolet light of 365 nm is exposed at an exposure amount of 250 mJ / cm ² by a parallel ultraviolet light irradiation device, and an alkali developer (mainly sodium hydroxide is used as a main component). A resist layer having a desired pattern for forming the contours of the metal particles was formed by development with an aqueous solution (concentration: 1 wt%) and dried at 130 ° C.
Then, it was immersed in etching liquid (nitric acid: phosphoric acid: acetic acid: water = 7: 10: 10: 3), and the nickel layer and the chromium layer were etched using the resist layer as a mask.
Further, the resist layer and the sacrificial layer were dissolved by developing with an alkali developer (aqueous solution containing sodium hydroxide as a main component: concentration 5 wt%).
At this time, metal particles obtained by laminating nickel and chromium having a diffraction grating on the surface were obtained in the developer.
By substituting this developer with water, an aqueous dispersion of metal particles was obtained.

  This aqueous dispersion of metal particles was mixed with a water-soluble ultraviolet curable resin (AQ-9 manufactured by Arakawa Chemical Co., Ltd.) to produce an anti-counterfeit ink. At this time, adjustment was made so that 65 million metal particles per 1 L of ink were contained. This anti-counterfeit ink was printed on a gift certificate by silk screen printing using a 180 mesh plate. In the printed anti-counterfeit ink, the shape of the metal particles could not be grasped with the naked eye, but the metal particles could be identified when enlarged using a 100 times magnifier. The size of the metal particles was 100 μm and the thickness was 10 μm.

  The preferred embodiments of the present invention have been described above with reference to the accompanying drawings, but the present invention is not limited to such examples. It will be apparent to those skilled in the art that various changes and modifications can be made within the scope of the technical idea disclosed in the present application, and these are naturally within the technical scope of the present invention. Understood.

1a, 1b, 1c ......... Particles 3a, 3b, 3c ......... First metal layer 4a, 4b, 4c ......... Second metal layer 5 ......... Penetration part 6b, 6c ......... Identification part 9 ......... Base material 11 ...... Sacrificial layer 13 ......... Alkali-soluble metal layer 15 ...... Photosensitive resin layer 17 ...... Exposure light 18 ......... Mask 19 ......... Transparent substrate 20 ......... Light shielding film 21 ......... Uneven shape 23 ......... Base material 25 ......... Sacrificial layer 27 ......... Metal uneven surface 29 ......... Second metal layer 31 ......... Regist layer 41 ......... Marketable securities 43 ......... Particle-containing part 51 ……… Card 53 ……… Particle-containing part

Claims (12)

A base material preparation step for preparing a base material in which a sacrificial layer, an alkali-soluble metal layer, and a photosensitive resin layer are laminated in this order;
An exposure step of exposing the photosensitive resin layer on the substrate to a pattern having a shape that can be identified by magnifying and observing,
Developing with an alkaline developer, and patterning the photosensitive resin layer and the alkali-soluble metal layer; and
A photosensitive resin layer peeling step for peeling the photosensitive resin layer from the alkali-soluble metal layer;
A second metal layer forming step of forming a second metal layer on the alkali-soluble metal layer;
A peeling step of dissolving the sacrificial layer and peeling the particles having the alkali-soluble metal layer and the second metal layer from the substrate;
A method for producing anti-counterfeit particles, comprising:   The method for producing anti-counterfeit particles according to claim 1, wherein the second metal layer is formed by electroplating. The shape of the anti-counterfeit particles is a flat plate shape,
The anti-counterfeit particle according to claim 1 or 2, wherein the forgery-preventing particle has a contour and / or a shape of a penetrating portion of one or more of letters, numbers, symbols, and figures. Manufacturing method. The surface of the alkali-soluble metal layer has an uneven shape,
The method for producing anti-counterfeit particles according to claim 1, wherein the uneven shape is identifiable by observing the enlarged shape.   5. The anti-counterfeit particle according to claim 4, wherein the anti-counterfeit particle is formed with one or more three-dimensional shapes of letters, numbers, symbols, and figures due to the uneven shape. Production method. The uneven shape is a diffraction grating or a hologram,
5. The anti-counterfeit particle according to claim 4, wherein any one or more of letters, numbers, symbols, and figures are displayed on the surface of the anti-counterfeit particle by the diffraction grating or the hologram. Production method.   7. The anti-counterfeit particle according to claim 4, wherein a shape of the contour of the anti-counterfeit particle is one or more of letters, numbers, symbols, and figures. Manufacturing method.   The method for producing anti-counterfeit particles according to any one of claims 1 to 7, wherein the size is 10 to 300 µm and the thickness is 1 to 25 µm.   A method for producing an anti-counterfeit ink, wherein the anti-counterfeit particles according to claim 1 are dispersed in a dispersion medium.   A method for producing a forgery-preventing sheet, wherein the anti-counterfeit particles according to any one of claims 1 to 8 are dispersed in a resin.   A method for producing a security, wherein the anti-counterfeit particles according to any one of claims 1 to 8 are applied to a surface.   A card manufacturing method, wherein the anti-counterfeit particles according to any one of claims 1 to 8 are applied to a surface.

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