JP5748833B2 - Laminated polyester film - Google Patents

Description

  The present invention relates to a laminated polyester film. For example, in a backlight unit of a liquid crystal display, the present invention is suitably used as various optical members that require good adhesion to a light diffusion layer, a sticking prevention layer, and the like. The present invention relates to a laminated polyester film.

  In recent years, liquid crystal displays have been widely used as display devices for televisions, personal computers, digital cameras, mobile phones and the like. Since these liquid crystal displays do not have a light emitting function by a liquid crystal display unit alone, a method of displaying by irradiating light using a backlight from the back side is widespread.

  The backlight system has a structure called an edge light type or a direct type. Recently, there is a tendency to reduce the thickness of liquid crystal displays, and an edge light type is increasingly used. The edge light type is generally configured in the order of a reflection sheet, a light guide plate, a light diffusion sheet, and a prism sheet. As the flow of light, the light incident on the light guide plate from the backlight is reflected by the reflection sheet and emitted from the surface of the light guide plate. The light beam emitted from the light guide plate enters the light diffusion sheet, is diffused and emitted by the light diffusion sheet, and then enters the next existing prism sheet. The light beam is condensed in the normal direction by the prism sheet and emitted toward the liquid crystal layer.

  The light diffusion sheet used in this configuration is used for uniformly diffusing transmitted light in multiple directions, and needs to have high light diffusibility and high light transmission. As the light diffusing sheet, the surface of the sheet is roughened by heating and pressing during finishing, so-called embossing, or a light diffusing layer made of a transparent resin containing particles on a transparent base film The one made by coating is known. In the light diffusion sheet, a binder and a small amount of beads are used to prevent sticking (partial adhesion) between the light diffusion sheet and the light guide plate on the surface of the transparent base film opposite to the light diffusion layer. It has also been proposed to form a sticking-preventing layer containing Pt.

  A polyester film is generally used as the transparent base film for forming the light diffusion sheet in consideration of transparency and mechanical properties, and improves the adhesion between the base polyester film and the light diffusion layer or anti-sticking layer. In order to make this happen, an easily adhesive coating layer is generally provided as the intermediate layer. As an easily adhesive coating layer, for example, polyester resin, acrylic resin, urethane resin and the like are known (Patent Documents 4 and 5).

  In recent years, in the field of liquid crystal displays, there has been a demand for larger screens and higher image quality. In addition, due to a drastic price reduction of the liquid crystal display, a significant cost reduction is required in processing steps such as a light diffusion layer and an anti-sticking layer. For these reasons, the structure of the light diffusion layer, the anti-sticking layer, etc. is drastically changed, and there is a demand for a polyester film having easy adhesion performance that has good adhesion to various layers.

JP 2000-89007 A JP 2004-4598 A JP 2007-286166 A JP-A-8-281890 JP 2000-229395 A

  The present invention has been made in view of the above circumstances, and its solution is to have good adhesion to various light diffusion layers, anti-sticking layers, etc., for example, in backlight units of liquid crystal displays, etc. It is providing the laminated polyester film which can be utilized suitably.

  As a result of intensive studies in view of the above circumstances, the present inventors have found that the use of a laminated polyester film having a specific configuration can easily solve the above-described problems, and have completed the present invention.

That is, the gist of the present invention is to have a coating layer formed by coating a coating liquid containing an acrylic resin, an epoxy compound and an oxazoline compound on at least one surface of a polyester film. It exists in the laminated polyester film characterized by having a resin layer containing a resin particle or an acrylic urethane resin particle, and a hardening | curing agent .

  According to the laminated polyester film of the present invention, when a light diffusing layer or an anti-sticking layer is formed, a laminated polyester film having excellent adhesion can be provided, and its industrial value is high.

Hereinafter, the present invention will be described in more detail.
The polyester film constituting the laminated polyester film in the present invention may have a single layer structure or a multilayer structure, and may have four or more layers as long as it does not exceed the gist of the present invention other than a two-layer or three-layer structure. It may be a multilayer, and is not particularly limited.

  The polyester used in the present invention may be a homopolyester or a copolyester. In the case of a homopolyester, those obtained by polycondensation of an aromatic dicarboxylic acid and an aliphatic glycol are preferred. Examples of the aromatic dicarboxylic acid include terephthalic acid and 2,6-naphthalenedicarboxylic acid, and examples of the aliphatic glycol include ethylene glycol, diethylene glycol, and 1,4-cyclohexanedimethanol. Typical polyester includes polyethylene terephthalate and the like. On the other hand, examples of the dicarboxylic acid component of the copolyester include isophthalic acid, phthalic acid, terephthalic acid, 2,6-naphthalenedicarboxylic acid, adipic acid, sebacic acid, and oxycarboxylic acid (for example, p-oxybenzoic acid). 1 type or 2 types or more are mentioned, As a glycol component, 1 type or 2 types or more, such as ethylene glycol, diethylene glycol, propylene glycol, butanediol, 4-cyclohexane dimethanol, neopentyl glycol, is mentioned.

  The polyester film of the present invention may contain an ultraviolet absorber in order to prevent the liquid crystal of the liquid crystal display from being deteriorated by ultraviolet rays. The ultraviolet absorber is not particularly limited as long as it is a compound having ultraviolet absorbing ability and can withstand the heat applied in the production process of the polyester film.

  As the ultraviolet absorber, there are an organic ultraviolet absorber and an inorganic ultraviolet absorber. From the viewpoint of transparency, an organic ultraviolet absorber is preferable. Although it does not specifically limit as an organic type ultraviolet absorber, For example, a cyclic imino ester type, a benzotriazole type, a benzophenone type etc. are mentioned. From the viewpoint of durability, a cyclic imino ester type and a benzotriazole type are more preferable. It is also possible to use two or more ultraviolet absorbers in combination.

  In the polyester layer of the film of the present invention, it is preferable to blend particles mainly for the purpose of imparting slipperiness and preventing scratches in each step. The kind of the particle to be blended is not particularly limited as long as it is a particle capable of imparting slipperiness. Specific examples thereof include silica, calcium carbonate, magnesium carbonate, barium carbonate, calcium sulfate, calcium phosphate, and phosphoric acid. Examples of the particles include magnesium, kaolin, aluminum oxide, and titanium oxide. Further, the heat-resistant organic particles described in JP-B-59-5216, JP-A-59-217755 and the like may be used. Examples of other heat-resistant organic particles include thermosetting urea resins, thermosetting phenol resins, thermosetting epoxy resins, benzoguanamine resins, and the like. Furthermore, precipitated particles obtained by precipitating and finely dispersing a part of a metal compound such as a catalyst during the polyester production process can also be used.

  On the other hand, the shape of the particles to be used is not particularly limited, and any of a spherical shape, a block shape, a rod shape, a flat shape, and the like may be used. Moreover, there is no restriction | limiting in particular also about the hardness, specific gravity, a color, etc. These series of particles may be used in combination of two or more as required.

  Moreover, the average particle diameter of the particle | grains to be used is 0.01-3 micrometers normally, Preferably it is the range of 0.1-2 micrometers. If the average particle size is less than 0.01 μm, the slipperiness may not be sufficiently imparted, or the particles may be aggregated to make the dispersibility insufficient, thereby reducing the transparency of the film. On the other hand, when the thickness exceeds 3 μm, the surface roughness of the film becomes too rough, and a problem may occur when a light diffusion layer, a sticking prevention layer, or the like is formed in a subsequent process.

  Further, the content of particles in the polyester layer is usually in the range of 0.001 to 5% by weight, preferably 0.005 to 3% by weight. When the particle content is less than 0.001% by weight, the slipperiness of the film may be insufficient. On the other hand, when the content exceeds 5% by weight, the transparency of the film is insufficient. There is.

  The method for adding particles to the polyester layer is not particularly limited, and a conventionally known method can be adopted. For example, it can be added at any stage for producing the polyester constituting each layer, but it is preferably added after completion of esterification or transesterification.

  Also, a method of blending a slurry of particles dispersed in ethylene glycol or water with a vented kneading extruder and a polyester raw material, or a blending of dried particles and a polyester raw material using a kneading extruder. It is done by methods.

  In addition to the above-mentioned particles, conventionally known antioxidants, antistatic agents, thermal stabilizers, lubricants, dyes, pigments, and the like can be added to the polyester film in the present invention as necessary.

  Although the thickness of the polyester film in this invention will not be specifically limited if it can be formed into a film as a film, Usually, 10-350 micrometers, Preferably it is the range of 50-250 micrometers.

  Next, although the manufacture example of the polyester film in this invention is demonstrated concretely, it is not limited to the following manufacture examples at all. That is, a method of using the polyester raw material described above and cooling and solidifying a molten sheet extruded from a die with a cooling roll to obtain an unstretched sheet is preferable. In this case, in order to improve the flatness of the sheet, it is preferable to improve the adhesion between the sheet and the rotary cooling drum, and an electrostatic application adhesion method and / or a liquid application adhesion method is preferably employed. Next, the obtained unstretched sheet is stretched in the biaxial direction. In that case, first, the unstretched sheet is stretched in one direction by a roll or a tenter type stretching machine. The stretching temperature is usually 70 to 120 ° C., preferably 80 to 110 ° C., and the stretching ratio is usually 2.5 to 7 times, preferably 3.0 to 6 times. Next, the film is stretched in the direction perpendicular to the first stretching direction. In that case, the stretching temperature is usually 70 to 170 ° C., and the stretching ratio is usually 3.0 to 7 times, preferably 3.5 to 6 times. is there. Subsequently, heat treatment is performed at a temperature of 180 to 270 ° C. under tension or under relaxation within 30% to obtain a biaxially oriented film. In the above-described stretching, a method in which stretching in one direction is performed in two or more stages can be employed. In that case, it is preferable to carry out so that the draw ratios in the two directions finally fall within the above ranges.

  In the present invention, the simultaneous biaxial stretching method can be adopted for the production of the polyester film constituting the laminated polyester film. The simultaneous biaxial stretching method is a method in which the above-mentioned unstretched sheet is usually stretched and oriented in the machine direction and the width direction at a temperature controlled normally at 70 to 120 ° C., preferably 80 to 110 ° C. Is 4 to 50 times, preferably 7 to 35 times, and more preferably 10 to 25 times in terms of area magnification. Subsequently, heat treatment is performed at a temperature of 170 to 250 ° C. under tension or under relaxation within 30% to obtain a stretched oriented film. With respect to the simultaneous biaxial stretching apparatus that employs the above-described stretching method, a conventionally known stretching method such as a screw method, a pantograph method, or a linear driving method can be employed.

  Next, formation of the coating layer which comprises the laminated polyester film in this invention is demonstrated. As for the coating layer, it may be provided by in-line coating, which treats the film surface during the stretching process of the polyester film, or may be applied off-system on the film once manufactured, and may employ both offline coating. You may use together. In-line coating is preferably used in that it can be applied at the same time as film formation, and thus can be manufactured at low cost, and the thickness of the coating layer can be changed by the draw ratio.

  The in-line coating is not limited to the following, but for example, in the sequential biaxial stretching, the coating treatment can be performed particularly before the lateral stretching after the longitudinal stretching is finished. When a coating layer is provided on a polyester film by in-line coating, coating can be performed simultaneously with film formation, and the coating layer can be processed at a high temperature, and a film suitable as a polyester film can be produced.

  In the present invention, it is an essential requirement to have a coating layer formed by coating a coating liquid containing an acrylic resin, an epoxy compound and an oxazoline compound on at least one side of a polyester film.

  The coating layer in the present invention can improve adhesion to various thermosetting layers and active energy ray-curable layers such as a light diffusion layer and an anti-sticking layer.

  As a result of various studies, it is possible to improve the adhesion with a light diffusion layer, an anti-sticking layer, etc. by forming a coating layer that uses one kind of a crosslinking agent such as an acrylic resin and an epoxy compound or an oxazoline compound. found. As a result of further investigation, it was found that the coating layer made of an acrylic resin, an epoxy compound, and an oxazoline compound exhibits very good adhesion.

  The acrylic resin used in the present invention is a polymer comprising a polymerizable monomer having a carbon-carbon double bond, as typified by acrylic and methacrylic monomers. These may be either a homopolymer or a copolymer. Moreover, the copolymer of these polymers and other polymers (for example, polyester, polyurethane, etc.) is also included. For example, a block copolymer or a graft copolymer. Alternatively, a polymer (possibly a mixture of polymers) obtained by polymerizing a polymerizable monomer having a carbon-carbon double bond in a polyester solution or a polyester dispersion is also included. Similarly, a polymer (in some cases, a mixture of polymers) obtained by polymerizing a polymerizable monomer having a carbon-carbon double bond in a polyurethane solution or polyurethane dispersion is also included. Similarly, a polymer obtained by polymerizing a polymerizable monomer having a carbon-carbon double bond in another polymer solution or dispersion (in some cases, a polymer mixture) is also included.

  The polymerizable monomer having a carbon-carbon double bond is not particularly limited, but particularly representative compounds include, for example, acrylic acid, methacrylic acid, crotonic acid, itaconic acid, fumaric acid, maleic acid, citracone. Various carboxyl group-containing monomers such as acids, and salts thereof; 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 4-hydroxybutyl (meth) acrylate, monobutyl hydroxyl fumarate, Various hydroxyl group-containing monomers such as monobutylhydroxy itaconate; various monomers such as methyl (meth) acrylate, ethyl (meth) acrylate, propyl (meth) acrylate, butyl (meth) acrylate, lauryl (meth) acrylate ( (Meth) acrylic acid esters; Various nitrogen-containing vinyl monomers such as (meth) acrylimide, diacetone acrylamide, N-methylol acrylamide or (meth) acrylonitrile; various styrene derivatives such as styrene, α-methylstyrene, divinylbenzene, vinyltoluene, Various vinyl esters such as vinyl acetate and vinyl propionate; γ-methacryloxypropyltrimethoxysilane, vinyltrimethoxysilane, “Silaplane FM-07” (methacryloyl silicon macromer) manufactured by Chisso Corporation Various silicon-containing polymerizable monomers; phosphorus-containing vinyl monomers; vinyl chloride, biliden chloride, vinyl fluoride, vinylidene fluoride, trifluorochloroethylene, tetrafluoroethylene, chlorotrifluoroethylene, hexafur Various vinyl halides such as Russia propylene; various conjugated dienes such as butadiene and the like.

  An acrylic resin containing a functional group such as a hydroxyl group, an amino group, or an amide group can be used in order to improve the adhesion to the light diffusion layer or the anti-sticking layer.

  In the formation of the coating layer in the film of the present invention, the coating film of the coating layer is strengthened and has sufficient adhesion with various light diffusion layers or anti-sticking layers, etc., and heat and heat resistance after these layers are formed. In order to improve, epoxy compounds and oxazoline compounds are used as crosslinking agents.

  As an epoxy compound, the compound containing an epoxy group in a molecule | numerator, its prepolymer, and hardened | cured material are mentioned, for example. Examples include condensates of epichlorohydrin with hydroxyl groups and amino groups such as ethylene glycol, polyethylene glycol, glycerin, polyglycerin, and bisphenol A, and polyepoxy compounds, diepoxy compounds, monoepoxy compounds, glycidylamine compounds, and the like. is there. Examples of the polyepoxy compound include sorbitol, polyglycidyl ether, polyglycerol polyglycidyl ether, pentaerythritol polyglycidyl ether, diglycerol polyglycidyl ether, triglycidyl tris (2-hydroxyethyl) isocyanate, glycerol polyglycidyl ether, trimethylol. Examples of the propane polyglycidyl ether and diepoxy compound include neopentyl glycol diglycidyl ether, 1,6-hexanediol diglycidyl ether, resorcin diglycidyl ether, ethylene glycol diglycidyl ether, polyethylene glycol diglycidyl ether, propylene glycol diglycidyl ether. Ether, polypropylene glycol diglycidyl ether, Ritetramethylene glycol diglycidyl ether and monoepoxy compounds include, for example, allyl glycidyl ether, 2-ethylhexyl glycidyl ether, phenyl glycidyl ether, and glycidyl amine compounds such as N, N, N ′, N ′,-tetraglycidyl-m. -Xylylenediamine, 1,3-bis (N, N-diglycidylamino) cyclohexane and the like.

  An oxazoline compound is a compound having an oxazoline group in the molecule. In particular, a polymer containing an oxazoline group is preferable, and it can be prepared by polymerization of an addition polymerizable oxazoline group-containing monomer alone or with another monomer. Addition polymerizable oxazoline group-containing monomers include 2-vinyl-2-oxazoline, 2-vinyl-4-methyl-2-oxazoline, 2-vinyl-5-methyl-2-oxazoline, 2-isopropenyl-2-oxazoline, 2-isopropenyl-4-methyl-2-oxazoline, 2-isopropenyl-5-ethyl-2-oxazoline, and the like can be mentioned, and one or a mixture of two or more thereof can be used. Among these, 2-isopropenyl-2-oxazoline is preferred because it is easily available industrially. The other monomer is not limited as long as it is a monomer copolymerizable with an addition polymerizable oxazoline group-containing monomer. For example, alkyl (meth) acrylate (the alkyl group includes a methyl group, an ethyl group, an n-propyl group, an isopropyl group, (meth) acrylic acid esters such as n-butyl group, isobutyl group, t-butyl group, 2-ethylhexyl group, cyclohexyl group); acrylic acid, methacrylic acid, itaconic acid, maleic acid, fumaric acid, crotonic acid, styrene Unsaturated carboxylic acids such as sulfonic acid and its salts (sodium salt, potassium salt, ammonium salt, tertiary amine salt, etc.); Unsaturated nitriles such as acrylonitrile, methacrylonitrile; (meth) acrylamide, N-alkyl ( (Meth) acrylamide, N, N-dialkyl (meth) acrylamide, As the alkyl group, unsaturated amides such as methyl group, ethyl group, n-propyl group, isopropyl group, n-butyl group, isobutyl group, t-butyl group, 2-ethylhexyl group and cyclohexyl group); vinyl acetate Vinyl esters such as vinyl propionate; vinyl ethers such as methyl vinyl ether and ethyl vinyl ether; α-olefins such as ethylene and propylene; halogen-containing α, β-unsaturated monomers such as vinyl chloride, vinylidene chloride and vinyl fluoride And α, β-unsaturated aromatic monomers such as styrene and α-methylstyrene, and the like, and one or more of these monomers can be used.

  In the laminated polyester film of the present invention, a binder other than an acrylic resin is used for improving the coated surface, improving visibility when various light diffusion layers and anti-sticking layers are formed on the coated surface, and improving transparency. It is also possible to use a polymer in combination.

  The “binder polymer” used in the present invention is a number average molecular weight (Mn) measured by gel permeation chromatography (GPC) according to a polymer compound safety evaluation flow scheme (sponsored by the Chemical Substance Council in November 1985). ) Is a polymer compound having a molecular weight of 1000 or more and having a film-forming property.

  Specific examples of the binder polymer include polyester resin, urethane resin, polyvinyl (polyvinyl alcohol, polyvinyl chloride, vinyl chloride vinyl acetate copolymer, etc.), polyalkylene glycol, polyalkyleneimine, methylcellulose, hydroxycellulose, starches, and the like. Can be mentioned. Among these, it is preferable to use a polyester resin in combination from the viewpoint of improving the coated surface and adhesion.

  Moreover, it is also possible to contain particle | grains for the improvement of the slipperiness of a coating layer, or a blocking improvement. Examples of the particles used include inorganic particles such as silica, alumina, and metal oxide, or organic particles such as crosslinked polymer particles.

  Furthermore, as long as it does not impair the gist of the present invention, the coating layer has an antifoaming agent, a coating property improving agent, a thickener, an organic lubricant, an antistatic agent, an ultraviolet absorber, an antioxidant, foaming as necessary. Agents, dyes and the like may be contained.

  In the present invention, the content of the acrylic resin in the coating layer is usually 20 to 90% by weight, preferably 25 to 85% by weight, and more preferably 30 to 80% by weight. When the amount is less than 20% by weight, the adhesion may not be sufficient due to the small amount of the acrylic resin component, and when it exceeds 90% by weight, the coating layer becomes brittle due to the small amount of the crosslinking agent component, and the adhesion is not sufficient. In some cases, the heat and humidity resistance may not be sufficient.

  In this invention, the quantity of the compound derived from the epoxy compound and oxazoline compound which occupies in a coating layer is 10-80 weight% normally, Preferably it is 15-75 weight%, More preferably, it is 20-70 weight%. When the amount is less than 10% by weight, the coating layer becomes brittle and may not sufficiently withstand moisture and heat. When the amount exceeds 80% by weight, the adhesion may not be sufficient. Moreover, it is preferable that at least one of an epoxy compound and an oxazoline compound exceeds 5 weight%. In the case of 5% by weight or less in all cases, when exposed to high temperature and high humidity conditions for a long time, the adhesion with the light diffusion layer, the anti-sticking layer or the like may not be stable.

  In the polyester film of the present invention, a coating layer can also be provided on the surface opposite to the surface on which the coating layer is provided. For example, when a functional layer such as an anti-sticking layer, a prism layer, a microlens layer, or a hard coat layer is formed on the opposite side where the light diffusion layer is formed, it is possible to improve adhesion with the functional layer. . A conventionally well-known thing can be used as a component of the coating layer formed in the surface on the opposite side. For example, a binder polymer such as a polyester resin, an acrylic resin, and a urethane resin, a crosslinking agent such as an epoxy compound, an oxazoline compound, a melamine compound, an isocyanate compound, and the like may be used. You may use together. Further, it may be a coating layer (a coating layer having the same surface on both sides of a polyester film) formed from an acrylic resin, an epoxy compound, or an oxazoline compound as described above. Considering the convenience of production and film processing, the coating layers are preferably the same.

  Analysis of the components in the coating layer can be performed by surface analysis such as TOF-SIMS.

  When providing a coating layer by in-line coating, the above-mentioned series of compounds is applied as an aqueous solution or dispersion, and the coating solution adjusted to a solid content concentration of about 0.1 to 50% by weight as a guide is applied onto the polyester film. It is preferable to produce a laminated polyester film. Moreover, in the range which does not impair the main point of this invention, a small amount of organic solvents may be contained in the coating liquid for the purpose of improving dispersibility in water, improving film-forming properties, and the like. Only one type of organic solvent may be used, or two or more types may be used as appropriate.

Respect laminated polyester film of the present invention, the thickness of the coating layer provided on the polyester film is usually 0.002~1.0g / ^{m 2,} more preferably 0.01 to 0.5 g / ^{m 2,} more preferably The range is 0.02 to 0.2 g / m ² . If the film thickness is less than 0.002 g / m ^2, sufficient adhesion may not be obtained, and if it exceeds 1.0 g / m ² , the appearance, transparency, and film blocking properties may be deteriorated. There is sex.

  In the present invention, as a method for providing the coating layer, a conventionally known coating method such as reverse gravure coating, direct gravure coating, roll coating, die coating, bar coating, curtain coating or the like can be used.

  In the present invention, the drying and curing conditions for forming the coating layer on the polyester film are not particularly limited. For example, when the coating layer is provided by off-line coating, it is usually 3 to 40 at 80 to 200 ° C. The heat treatment may be performed for 2 seconds, preferably 100 to 180 ° C. for 3 to 40 seconds.

  On the other hand, when the coating layer is provided by in-line coating, heat treatment is usually performed at 70 to 280 ° C. for 3 to 200 seconds as a guide.

  Further, irrespective of off-line coating or in-line coating, heat treatment and active energy ray irradiation such as ultraviolet irradiation may be used in combination as required. The polyester film constituting the laminated polyester film in the present invention may be subjected to surface treatment such as corona treatment or plasma treatment in advance.

  In the laminated polyester film of the present invention, a resin layer such as a light diffusion layer or a sticking prevention layer is provided on the coating layer. The resin layer contains particles and a binder.

  The particles to be included in the resin layer may be any particles having a property of diffusing light, such as organic particles such as acrylic resin, acrylic urethane resin, urethane resin, polyester resin, and polyvinyl resin, silica, and metal oxide. Inorganic particles such as barium sulfate can be used. Of these, acrylic resins and acrylic urethane resins having good transparency are preferably used. Moreover, the particle size of these particles is not particularly limited, but the average particle size is 1 to 50 μm, more preferably 5 to 15 μm.

  The binder contained in the resin layer is used to fix particles and develop light diffusibility. For example, polyester resin, acrylic resin, polyurethane resin, fluororesin, silicone resin, epoxy resin, UV curable resin Etc. In consideration of processability, a polyol compound is preferably used, and examples thereof include acrylic polyol and polyester polyol.

  When a polyol compound is used as a binder, it is preferable to contain isocyanate as a curing agent. By containing isocyanate, a stronger cross-linked structure can be formed, and physical properties as a light diffusion layer are improved. Further, when an ultraviolet curable resin is used as the binder, an acrylate resin is preferable, which can be used for improving the hardness of the resin layer.

  The resin layer may contain a surfactant, a fine inorganic filler, a plasticizer, a curing agent, an antioxidant, an ultraviolet absorber, a rust preventive agent and the like as long as the light diffusion performance is not impaired.

  The mixing ratio of the binder and particles in the resin layer can be appropriately set depending on the light diffusibility to be obtained, and is not particularly limited. For example, the weight ratio of the binder / particles is in the range of 0.1 to 50. Preferably it is the range of 0.5-20.

  Examples of the method for forming the resin layer include a method in which a coating liquid containing a binder and particles is prepared, applied and dried. As a coating method, a conventionally known coating method such as reverse gravure coating, direct gravure coating, roll coating, die coating, bar coating, curtain coating, spray coating, spin coating or the like can be used. The thickness of the resin layer is not particularly limited, but it is in the range of 1 to 100 μm, more preferably in the range of 3 to 30 μm, considering light diffusibility, film strength, and the like.

  It is also possible to form an anti-sticking layer on the surface opposite to the resin layer. The anti-sticking layer contains the same binder and particles as the resin layer, and the content of the particles is not intended to be light diffusive. Therefore, a method of containing a smaller amount with a smaller particle size is common. is there. The forming method can also be formed by coating similarly to the resin layer, and the thickness is not particularly limited, but is preferably in the range of 1 to 10 μm.

  EXAMPLES Hereinafter, although an Example demonstrates this invention further in detail, this invention is not limited to a following example, unless the summary is exceeded. The measurement method and evaluation method used in the present invention are as follows.

(1) Measurement of intrinsic viscosity of polyester 1 g of polyester from which other polymer components and pigments incompatible with polyester have been removed are precisely weighed, and 100 ml of a mixed solvent of phenol / tetrachloroethane = 50/50 (weight ratio) is added. It was dissolved and measured at 30 ° C.

(2) Measurement of average particle diameter (d ₅₀ : μm) Integration (weight basis) 50% in equivalent spherical distribution measured using centrifugal sedimentation type particle size distribution measuring device (SA-CP3 type manufactured by Shimadzu Corporation) Was the average particle size.

(3) Evaluation method of adhesion 1 As a coating solution for the light diffusion layer, 100 parts by mass of resin (Halus Hybrid UV-G301 made by Nippon Shokubai), 10 parts by mass of isocyanate (manufactured by Sumika Bayer Urethane, Death Module N-3200), By preparing 30 parts by mass of acrylic resin particles having an average particle size of 15 μm (MBX-15, manufactured by Sekisui Plastics Industry Co., Ltd.), 100 parts by mass of toluene, and 100 parts by mass of methyl ethyl ketone, coating and heat curing, the thickness of 15 g / m ² A light diffusion layer was formed. Further, acrylic resin particles having an average particle diameter of 15 μm used in the coating solution for the light diffusion layer as an anti-sticking layer on the side opposite to the light diffusion layer were replaced with acrylic resin particles having an average particle diameter of 5 μm (manufactured by Sekisui Plastics MBX-5) A double-sided product was prepared in the same manner except that a layer having a thickness of 3 g / m ² was formed instead of 7 parts by mass. Then, 10 × 10 cross cut is applied to each of the light diffusion layer and the anti-sticking layer, and an 18 mm wide tape (Cello Tape (registered trademark) CT-18 manufactured by Nichiban Co., Ltd.) is applied thereon. After peeling off sharply at a peeling angle of 180 degrees, the peeled surface is observed, and for the larger peeled area, if the peeled area is 5% or less, ○, if it exceeds 5% and 30% or less, Δ, 30 When it exceeded%, it was set as x. In general, the anti-sticking layer has less surface irregularities, and therefore has better adhesion to the tape to be peeled, and therefore the peel area tends to be larger than the light diffusion layer.

(4) Adhesion 2 Evaluation Method As a coating solution for the light diffusion layer, 60 parts by mass of dipentaerythritol hexaacrylate, 6 parts by mass of 2-hydroxy-3-phenoxypropyl acrylate, a photopolymerization initiator (Irgacure 184 manufactured by Ciba Specialty Chemicals) ) 4 parts by mass, acrylic resin particles having an average particle size of 12 μm (MBX-12 manufactured by Sekisui Plastics Industry Co., Ltd.), 30 parts by mass, and 200 parts by mass of methyl ethyl ketone were prepared, applied, cured by irradiation with ultraviolet rays, and a thickness of 10 g / A light diffusion layer of m ² was formed. Further, acrylic resin particles having an average particle diameter of 12 μm used in the coating solution for the light diffusion layer as an anti-sticking layer on the side opposite to the light diffusion layer, acrylic resin particles having an average particle diameter of 5 μm (manufactured by Sekisui Plastics Co., Ltd.) MBX-5) A double-sided processed product was prepared in the same manner except that a layer having a thickness of 3 g / m ² was formed instead of 5 parts by mass. Immediately thereafter (initial), after 150 hours in an environment of 80 ° C./90% RH (wet heat test), a 10 × 10 cross-cut was made on each of the light diffusion layer and the anti-sticking layer, and 18 mm was formed thereon. After affixing a width tape (cello tape (registered trademark) CT-18 manufactured by Nichiban Co., Ltd.) and peeling off sharply at a peel angle of 180 degrees, the peeled surface was observed, and the peel area was larger, When the peeled area was 5% or less, it was evaluated as ◯ when it exceeded 5% and 30% or less, and when it exceeded 30%, it was rated as x. In general, the anti-sticking layer has less surface irregularities, and therefore has better adhesion to the tape to be peeled, and therefore the peel area tends to be larger than the light diffusion layer.

The polyester used in the examples and comparative examples was prepared as follows.
<Method for producing polyester (A)>
Using 100 parts by weight of dimethyl terephthalate and 60 parts by weight of ethylene glycol as starting materials, adding tetrabutoxy titanate as a catalyst to the reactor, setting the reaction start temperature to 150 ° C., and gradually increasing the reaction temperature as methanol is distilled off. It was 230 degreeC after 3 hours. After 4 hours, the transesterification reaction was substantially completed, and then a polycondensation reaction was performed for 4 hours.
That is, the temperature was gradually raised from 230 ° C. to 280 ° C. On the other hand, the pressure was gradually reduced from normal pressure, and finally 0.3 mmHg. After the start of the reaction, the reaction was stopped at a time corresponding to an intrinsic viscosity of 0.63 due to a change in stirring power of the reaction vessel, and the polymer was discharged under nitrogen pressure to obtain a polyester (A) having an intrinsic viscosity of 0.63.

<Method for producing polyester (B)>
Starting from 100 parts by weight of dimethyl terephthalate and 60 parts by weight of ethylene glycol, magnesium acetate / tetrahydrate is added as a catalyst to the reactor, the reaction start temperature is set to 150 ° C., and the reaction temperature is gradually increased as methanol is distilled off. Was raised to 230 ° C. after 3 hours. After 4 hours, the transesterification reaction was substantially terminated. This reaction mixture was transferred to a polycondensation tank, orthophosphoric acid was added, and germanium dioxide was added to carry out a polycondensation reaction for 4 hours. That is, the temperature was gradually raised from 230 ° C. to 280 ° C. On the other hand, the pressure was gradually reduced from normal pressure, and finally 0.3 mmHg. After the start of the reaction, the reaction was stopped at a time corresponding to an intrinsic viscosity of 0.65 due to a change in stirring power in the reaction vessel, and the polymer was discharged under nitrogen pressure to obtain a polyester (B) having an intrinsic viscosity of 0.65.

<Method for producing polyester (C)>
In the production method of polyester (A), 0.2 part of silica particles having an average particle diameter of 2.0 μm dispersed in ethylene glycol was added, and the polycondensation reaction was stopped at a time corresponding to an intrinsic viscosity of 0.66. A polyester (C) having an intrinsic viscosity of 0.66 was obtained using a method similar to the method for producing polyester (A).

Examples of compounds constituting the coating layer are as follows.
(Example compounds)
Acrylic resin: (IA) Aqueous dispersion of acrylic resin polymerized with the following composition: ethyl acrylate / n-butyl acrylate / methyl methacrylate / N-methylol acrylamide / acrylic acid = 65/21/10/2/2 (% by weight) Emulsion polymer (emulsifier: anionic surfactant)
Acrylic resin: (IB) Aqueous dispersion of acrylic resin polymerized with the following composition: ethyl acrylate / methyl methacrylate / 2-hydroxyethyl methacrylate / N-methylol acrylamide / acrylic acid = 65/28/3/2/2 (% by weight ) Emulsion polymer (emulsifier: anionic surfactant)

Polyester resin: (II) A water dispersion of a polyester resin copolymerized with the following composition: Monomer composition: (acid component) terephthalic acid / isophthalic acid / 5-sodium sulfoisophthalic acid // (diol component) ethylene glycol / 1 4-butanediol / diethylene glycol = 56/40/4 // 70/20/10 (mol%)

Epoxy compound: (III) Denacol EX-521 (manufactured by Nagase ChemteX), which is polyglycerol polyglycidyl ether

・ Oxazoline compounds: (IVA)
Acrylic polymer Epocross WS-500 having an oxazoline group and a polyalkylene oxide chain (manufactured by Nippon Shokubai, containing about 38% by weight of 1-methoxy-2-propanol solvent)
・ Oxazoline compounds: (IVB)
Oxazoline group-containing acrylic polymer Epocros WS-300 (manufactured by Nippon Shokubai)

-Particles: (V) Silica sol with an average particle size of 65 nm

Example 1:
A mixed raw material obtained by mixing polyesters (A), (B), and (C) at a ratio of 85%, 5%, and 10%, respectively, is used as a raw material of the outermost layer (surface layer), and polyesters (A) and (B) are each 95 %, 5% mixed raw materials were used as intermediate layer raw materials, each was supplied to two extruders, melted at 290 ° C, and then on a cooling roll set at 40 ° C. Coextruded with a layer structure of layers (surface layer / intermediate layer / surface layer = 1: 18: 1 discharge amount) and cooled and solidified to obtain an unstretched sheet. Next, the film was stretched 3.2 times in the machine direction at a film temperature of 85 ° C. using the difference in peripheral speed of the roll, and then the coating solution 1 shown in Table 1 below was applied to both sides of the longitudinally stretched film, leading to a tenter. Stretched 3.8 times at 120 ° C in the transverse direction, heat-treated at 225 ° C, relaxed by 2% in the transverse direction, and a coating amount (after drying) having a coating layer as shown in Table 2 has a thickness of 188 µm A polyester film was obtained.

  When various adhesiveness was evaluated regarding the obtained polyester film, in any evaluation, it was favorable. The properties of this film are shown in Table 2 below.

Examples 2-7:
In Example 1, it manufactured similarly to Example 1 except having changed the coating agent composition into the coating agent composition shown in Table 1, and obtained the polyester film. The finished polyester film was as shown in Table 2 and had good adhesion.

Comparative Examples 1-3:
In Example 1, it manufactured similarly to Example 1 except having changed the coating agent composition into the coating agent composition shown in Table 1, and obtained the polyester film. When the completed laminated polyester film was evaluated, it was as shown in Table 2 and had poor adhesion.

  The film of the present invention can be suitably used for applications that require good adhesion to a light diffusion layer, an anti-sticking layer, etc., such as a backlight unit of a liquid crystal display.

Claims (4)

On at least one surface of a polyester film having an acrylic resin, an epoxy compound and coating layer formed by coating a coating solution containing an oxazoline compound, and a binder to the coating layer, an acrylic resin particle or an acrylic urethane resin particles And a laminated polyester film comprising a resin layer containing a curing agent . The laminated polyester film according to claim 1, wherein the coating liquid contains a polyester resin. The laminated polyester film according to claim 1 or 2, wherein the content of the epoxy resin and the oxazoline compound in the coating solution is 10 to 20% by weight, respectively. The laminated polyester film according to any one of claims 1 to 3, wherein the binder in the resin layer is a polyol compound .