JP5689216B2 - Animal shampoo composition - Google Patents
Animal shampoo composition Download PDFInfo
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- JP5689216B2 JP5689216B2 JP2007228650A JP2007228650A JP5689216B2 JP 5689216 B2 JP5689216 B2 JP 5689216B2 JP 2007228650 A JP2007228650 A JP 2007228650A JP 2007228650 A JP2007228650 A JP 2007228650A JP 5689216 B2 JP5689216 B2 JP 5689216B2
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- shampoo composition
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- animal shampoo
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- 241001465754 Metazoa Species 0.000 title claims description 51
- 239000000203 mixture Substances 0.000 title claims description 44
- 239000002453 shampoo Substances 0.000 title claims description 39
- -1 cationic polysaccharide Chemical class 0.000 claims description 38
- 244000078703 ectoparasite Species 0.000 claims description 13
- 229920001282 polysaccharide Polymers 0.000 claims description 10
- 239000005017 polysaccharide Substances 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 6
- 239000003945 anionic surfactant Substances 0.000 claims description 5
- 239000001913 cellulose Substances 0.000 claims description 5
- 229920002678 cellulose Polymers 0.000 claims description 5
- SBNFWQZLDJGRLK-RTWAWAEBSA-N (1R)-trans-phenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-RTWAWAEBSA-N 0.000 claims description 2
- 229960003536 phenothrin Drugs 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 description 16
- 230000000694 effects Effects 0.000 description 9
- 230000000749 insecticidal effect Effects 0.000 description 9
- 150000004676 glycans Chemical class 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 241000607479 Yersinia pestis Species 0.000 description 5
- 239000005871 repellent Substances 0.000 description 5
- 230000002940 repellent Effects 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 239000004480 active ingredient Substances 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 241000258924 Ctenocephalides felis Species 0.000 description 3
- 229920002907 Guar gum Polymers 0.000 description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 description 3
- 239000000665 guar gum Substances 0.000 description 3
- 235000010417 guar gum Nutrition 0.000 description 3
- 229960002154 guar gum Drugs 0.000 description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 241000272517 Anseriformes Species 0.000 description 2
- 241000282472 Canis lupus familiaris Species 0.000 description 2
- 229920002307 Dextran Polymers 0.000 description 2
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 241000282326 Felis catus Species 0.000 description 2
- PNVJTZOFSHSLTO-UHFFFAOYSA-N Fenthion Chemical compound COP(=S)(OC)OC1=CC=C(SC)C(C)=C1 PNVJTZOFSHSLTO-UHFFFAOYSA-N 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 241001674048 Phthiraptera Species 0.000 description 2
- 241000258242 Siphonaptera Species 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- FHIVAFMUCKRCQO-UHFFFAOYSA-N diazinon Chemical compound CCOP(=S)(OCC)OC1=CC(C)=NC(C(C)C)=N1 FHIVAFMUCKRCQO-UHFFFAOYSA-N 0.000 description 2
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 description 2
- 229950001327 dichlorvos Drugs 0.000 description 2
- ZNOLGFHPUIJIMJ-UHFFFAOYSA-N fenitrothion Chemical compound COP(=S)(OC)OC1=CC=C([N+]([O-])=O)C(C)=C1 ZNOLGFHPUIJIMJ-UHFFFAOYSA-N 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
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- SNMVRZFUUCLYTO-UHFFFAOYSA-N n-propyl chloride Chemical compound CCCCl SNMVRZFUUCLYTO-UHFFFAOYSA-N 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- CXBMCYHAMVGWJQ-CABCVRRESA-N (1,3-dioxo-4,5,6,7-tetrahydroisoindol-2-yl)methyl (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCN1C(=O)C(CCCC2)=C2C1=O CXBMCYHAMVGWJQ-CABCVRRESA-N 0.000 description 1
- VEMKTZHHVJILDY-PMACEKPBSA-N (5-benzylfuran-3-yl)methyl (1r,3s)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate Chemical compound CC1(C)[C@@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-PMACEKPBSA-N 0.000 description 1
- ZFHGXWPMULPQSE-SZGBIDFHSA-N (Z)-(1S)-cis-tefluthrin Chemical compound FC1=C(F)C(C)=C(F)C(F)=C1COC(=O)[C@@H]1C(C)(C)[C@@H]1\C=C(/Cl)C(F)(F)F ZFHGXWPMULPQSE-SZGBIDFHSA-N 0.000 description 1
- FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 description 1
- LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 241000238876 Acari Species 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000005874 Bifenthrin Substances 0.000 description 1
- 241000283690 Bos taurus Species 0.000 description 1
- 241000283707 Capra Species 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 239000005946 Cypermethrin Substances 0.000 description 1
- 239000005892 Deltamethrin Substances 0.000 description 1
- 206010012434 Dermatitis allergic Diseases 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 241000283086 Equidae Species 0.000 description 1
- 239000005895 Esfenvalerate Substances 0.000 description 1
- 239000005896 Etofenprox Substances 0.000 description 1
- 241000287828 Gallus gallus Species 0.000 description 1
- 229920002148 Gellan gum Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 229920000569 Gum karaya Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 241000283973 Oryctolagus cuniculus Species 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- VQXSOUPNOZTNAI-UHFFFAOYSA-N Pyrethrin I Natural products CC(=CC1CC1C(=O)OC2CC(=O)C(=C2C)CC=C/C=C)C VQXSOUPNOZTNAI-UHFFFAOYSA-N 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 241000934878 Sterculia Species 0.000 description 1
- 241000282887 Suidae Species 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- 239000005939 Tefluthrin Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 229940024113 allethrin Drugs 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 201000008937 atopic dermatitis Diseases 0.000 description 1
- 208000010668 atopic eczema Diseases 0.000 description 1
- OMFRMAHOUUJSGP-IRHGGOMRSA-N bifenthrin Chemical compound C1=CC=C(C=2C=CC=CC=2)C(C)=C1COC(=O)[C@@H]1[C@H](\C=C(/Cl)C(F)(F)F)C1(C)C OMFRMAHOUUJSGP-IRHGGOMRSA-N 0.000 description 1
- 229960005286 carbaryl Drugs 0.000 description 1
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 229920003090 carboxymethyl hydroxyethyl cellulose Polymers 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 150000001767 cationic compounds Chemical class 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229920006319 cationized starch Polymers 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000013330 chicken meat Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 229960001591 cyfluthrin Drugs 0.000 description 1
- QQODLKZGRKWIFG-QSFXBCCZSA-N cyfluthrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@@H](C#N)C1=CC=C(F)C(OC=2C=CC=CC=2)=C1 QQODLKZGRKWIFG-QSFXBCCZSA-N 0.000 description 1
- ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical compound CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 description 1
- 229960005424 cypermethrin Drugs 0.000 description 1
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 1
- 229960002483 decamethrin Drugs 0.000 description 1
- OWZREIFADZCYQD-NSHGMRRFSA-N deltamethrin Chemical compound CC1(C)[C@@H](C=C(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-NSHGMRRFSA-N 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 230000037213 diet Effects 0.000 description 1
- 235000005911 diet Nutrition 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 1
- 229960001826 dimethylphthalate Drugs 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- NYPJDWWKZLNGGM-RPWUZVMVSA-N esfenvalerate Chemical compound C=1C([C@@H](C#N)OC(=O)[C@@H](C(C)C)C=2C=CC(Cl)=CC=2)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-RPWUZVMVSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229950005085 etofenprox Drugs 0.000 description 1
- YREQHYQNNWYQCJ-UHFFFAOYSA-N etofenprox Chemical compound C1=CC(OCC)=CC=C1C(C)(C)COCC1=CC=CC(OC=2C=CC=CC=2)=C1 YREQHYQNNWYQCJ-UHFFFAOYSA-N 0.000 description 1
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- 229930195729 fatty acid Natural products 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 235000010492 gellan gum Nutrition 0.000 description 1
- 239000000216 gellan gum Substances 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
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- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000000077 insect repellent Chemical class 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 230000005722 itchiness Effects 0.000 description 1
- 235000010494 karaya gum Nutrition 0.000 description 1
- 239000000231 karaya gum Substances 0.000 description 1
- 229940039371 karaya gum Drugs 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 235000013594 poultry meat Nutrition 0.000 description 1
- FITIWKDOCAUBQD-UHFFFAOYSA-N prothiofos Chemical compound CCCSP(=S)(OCC)OC1=CC=C(Cl)C=C1Cl FITIWKDOCAUBQD-UHFFFAOYSA-N 0.000 description 1
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 description 1
- VJFUPGQZSXIULQ-XIGJTORUSA-N pyrethrin II Chemical compound CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VJFUPGQZSXIULQ-XIGJTORUSA-N 0.000 description 1
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- VEMKTZHHVJILDY-FIWHBWSRSA-N resmethrin Chemical compound CC1(C)[C@H](C=C(C)C)C1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-FIWHBWSRSA-N 0.000 description 1
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- YWSCPYYRJXKUDB-KAKFPZCNSA-N tralomethrin Chemical compound CC1(C)[C@@H](C(Br)C(Br)(Br)Br)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 YWSCPYYRJXKUDB-KAKFPZCNSA-N 0.000 description 1
- DDVNRFNDOPPVQJ-HQJQHLMTSA-N transfluthrin Chemical compound CC1(C)[C@H](C=C(Cl)Cl)[C@H]1C(=O)OCC1=C(F)C(F)=CC(F)=C1F DDVNRFNDOPPVQJ-HQJQHLMTSA-N 0.000 description 1
- PUVAFTRIIUSGLK-UHFFFAOYSA-M trimethyl(oxiran-2-ylmethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC1CO1 PUVAFTRIIUSGLK-UHFFFAOYSA-M 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
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- 229940082509 xanthan gum Drugs 0.000 description 1
- LTVDFSLWFKLJDQ-UHFFFAOYSA-N α-tocopherolquinone Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)(O)CCC1=C(C)C(=O)C(C)=C(C)C1=O LTVDFSLWFKLJDQ-UHFFFAOYSA-N 0.000 description 1
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- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Catching Or Destruction (AREA)
- Cosmetics (AREA)
Description
本発明は、殺虫性化合物及び害虫忌避化合物からなる群より選ばれる少なくとも1種を含有してなる動物用シャンプー組成物、および、該シャンプー組成物を使用する動物の外部寄生虫の防除方法に関する。 The present invention relates to an animal shampoo composition containing at least one selected from the group consisting of insecticidal compounds and insect repellent compounds, and a method for controlling ectoparasites in animals using the shampoo composition.
近年、犬や猫等の愛玩動物は家族の一員として飼育されるようになっており、飼い主は愛玩動物の健康状態に大きな注意を払うようになってきている。そのため、当該愛玩動物に寄生し、当該愛玩動物におけるかゆみやアレルギー性皮膚炎等の原因とされる外部寄生虫(例えばノミ類等)の駆除も盛んに行われている。
動物等に寄生する外部寄生虫を防除する方法としては、例えば、殺虫性化合物または害虫忌避化合物を含有するシャンプー組成物にて当該動物を洗浄する方法がある。このようなシャンプー組成物を使用する場合は、当該シャンプー組成物は、動物に対する毒性や刺激性が低く、動物の皮膚や被毛に対して優しい動物用シャンプー組成物が求められている。
しかしながら、このような動物用シャンプー組成物において、含有させる有効成分の量を減少させると、外部寄生虫に対する防除効力が不十分となる場合があり、有効成分の安定した防除効力が得られる動物用シャンプー組成物が求められている。
In recent years, pets such as dogs and cats have been bred as members of families, and owners are paying great attention to the health of pets. Therefore, extermination of ectoparasites (for example, fleas) that are parasitic on the pet animal and cause itchiness or allergic dermatitis in the pet animal has been actively performed.
As a method for controlling ectoparasites that parasitize animals, for example, there is a method of washing the animals with a shampoo composition containing an insecticidal compound or a pest repellent compound. When such a shampoo composition is used, the shampoo composition has low toxicity and irritation to animals, and an animal shampoo composition that is gentle to animal skin and hair is desired.
However, in such an animal shampoo composition, if the amount of the active ingredient to be contained is reduced, the control effect against the ectoparasites may be insufficient, and the stable control effect of the active ingredient can be obtained. There is a need for shampoo compositions.
本発明は、殺虫性化合物および害虫忌避化合物からなる群より選ばれる少なくとも1種を含有する動物用シャンプー組成物において、当該有効成分による外部寄生虫の防除効力が高められた動物用シャンプー組成物を提供することを課題とする。 The present invention relates to an animal shampoo composition containing at least one selected from the group consisting of an insecticidal compound and a pest repellent compound, the animal shampoo composition having an enhanced ectoparasite control effect by the active ingredient. The issue is to provide.
本発明者らは、上記課題を解決するために、鋭意検討を行った結果、本発明に至った。
即ち、本発明は、以下の発明を含む。
[発明1]
(A)殺虫性化合物および害虫忌避化合物からなる群より選ばれる少なくとも1種、
(B)陰イオン性界面活性剤、並びに
(C)陽イオン性ポリサッカライド
を含有してなる動物用シャンプー組成物。
[発明2]
前記(A)成分が、ピレスロイド系殺虫性化合物である発明1記載の動物用シャンプー組成物。
[発明3]
前記(B)成分が、ポリオキシエチレン構造を有する陰イオン性界面活性剤である発明1または2記載の動物用シャンプー組成物。
[発明4]
前記(C)成分が、カチオン化セルロースである発明1〜3のいずれか記載の動物用シャンプー組成物。
[発明5]
発明1〜4記載のいずれかの動物用シャンプー組成物を動物に処理することにより、該動物に寄生する外部寄生虫を防除する方法。
[発明6]
外部寄生虫がノミ類である請求項5記載の方法。
In order to solve the above-mentioned problems, the present inventors have intensively studied and, as a result, have reached the present invention.
That is, the present invention includes the following inventions.
[Invention 1]
(A) at least one selected from the group consisting of insecticidal compounds and pest repellent compounds;
(B) an anionic surfactant, and
(C) A shampoo composition for animals comprising a cationic polysaccharide.
[Invention 2]
The shampoo composition for animals according to invention 1, wherein the component (A) is a pyrethroid insecticidal compound.
[Invention 3]
The animal shampoo composition according to invention 1 or 2, wherein the component (B) is an anionic surfactant having a polyoxyethylene structure.
[Invention 4]
The animal shampoo composition according to any one of inventions 1 to 3, wherein the component (C) is cationized cellulose.
[Invention 5]
A method for controlling an ectoparasite that parasitizes the animal by treating the animal shampoo composition according to any one of inventions 1 to 4 with the animal.
[Invention 6]
6. The method of claim 5, wherein the ectoparasite is a flea.
本発明の動物用シャンプー組成物は、動物の外部寄生虫に対して優れた防除効力を有している。 The animal shampoo composition of the present invention has an excellent control effect against ectoparasites of animals.
本発明の動物用シャンプー組成物は、(A)殺虫性化合物および害虫忌避化合物からなる群より選ばれる少なくとも1種の有効成分、(B)陰イオン性界面活性剤、並びに(C)陽イオン性ポリサッカライドを含有してなる。 The animal shampoo composition of the present invention comprises (A) at least one active ingredient selected from the group consisting of an insecticidal compound and a pest repellent compound, (B) an anionic surfactant, and (C) a cationic compound. It contains a polysaccharide.
本発明の動物用シャンプー組成物に用いられる(A)成分としては、例えばアレスリン、エトフェンプロックス、シクロプロトリン、シハロトリン、シフルトリン、シペルメトリン、ピレトリン、トラロメトリン、フェンバレレート、エスフェンバレレート、フェンプロパトリン、フルシトリネート、ペルメトリン、ビフェントリン、シラフルオフェン、レスメトリン、テフルトリン、アクリナトリン、プラレトリン、シスメトリン、フェノトリン、デルタメトリン、テトラメトリン、フルバリネートおよびトランスフルトリン等のピレスロイド系殺虫性化合物;
フェニトロチオン、フェンチオン、ダイアジノン、ジクロルボス、フェニトロチオン、フェンチオン、ダイアジノン、ジクロルボス、トリキロルホン、プロチオホスおよびピダフォンチオン等の有機リン系殺虫性化合物;
カルバリル、フェノブカルブ、プロポクサー等のカーバメート系殺虫性化合物;
ディート、ジメチルフタレート、ジチルフタレートおよび2−エチル−1,3−ヘキサジオール等の害虫忌避化合物を例示することができる。尚、(A)成分は単独で用いてもよく、また、適宜組合わせて用いてもよい。
Examples of the component (A) used in the animal shampoo composition of the present invention include allethrin, etofenprox, cycloprotorin, cyhalothrin, cyfluthrin, cypermethrin, pyrethrin, tralomethrin, fenvalerate, esfenvalerate, fenpropatrin. , Pyrethroid insecticidal compounds such as flucitrinate, permethrin, bifenthrin, silafluophene, resmethrin, tefluthrin, acrinatrin, praretrin, cismethrin, phenothrin, deltamethrin, tetramethrin, fulvalinate and transfluthrin;
Organophosphorus insecticidal compounds such as fenitrothion, fenthion, diazinon, dichlorvos, fenitrothion, fenthion, diazinon, dichlorvos, trikilophone, prothiophos and pidafontione;
Carbamate insecticidal compounds such as carbaryl, fenocarb, propoxer;
Pest repellent compounds such as diet, dimethyl phthalate, dityl phthalate and 2-ethyl-1,3-hexadiol can be exemplified. The component (A) may be used alone or in appropriate combination.
本発明の動物用シャンプー組成物における(A)成分の含有量は、本発明の効果が発揮されれば特に限定されないが、安全性等の観点から、組成物全量に対して1重量%以下が好ましく、また駆除効力の観点から、組成物全量に対して0.01重量%以上が好ましい。 The content of the component (A) in the animal shampoo composition of the present invention is not particularly limited as long as the effect of the present invention is exhibited, but from the viewpoint of safety and the like, it is 1% by weight or less with respect to the total amount of the composition. From the viewpoint of controlling efficacy, 0.01% by weight or more is preferable with respect to the total amount of the composition.
本発明の動物用シャンプー組成物に用いられる(B)成分としては、例えば硫酸エステル塩、スルホン酸エステル塩およびカルボン酸エステル塩が挙げられ、より具体的には高級脂肪酸塩、高級アルコール硫酸エステル塩、高級アルキルスルホン酸塩、ポリオキシエチレンアルキルフェニルエーテル硫酸エステル塩、アルキルベンゼンスルホン酸塩、アルキルナフタレンスルホン酸塩、ポリオキシエチレンアルキルエーテル硫酸塩、ポリオキシエチレンアルキルエーテル酢酸塩、スルホコハク酸アルキル塩およびスルホコハク酸ポリオキシエチレンアルキル塩等を例示することができる。
本発明においては、洗浄・起泡力の観点および頭皮への刺激抑制の観点から、ポリオキシエチレンラウリルエーテル硫酸ナトリウム、ポリオキシエチレンラウリルエーテル硫酸アンモニウム、ポリオキシエチレンラウリルエーテル酢酸ナトリウム、スルホコハク酸ラウリルニナトリウム、スルホコハク酸ポリオキシエチレンラウリルニナトリウムが好ましく用いられる。尚、(B)成分は単独で用いてもよく、また、適宜組合わせて用いてもよい。
Examples of the component (B) used in the animal shampoo composition of the present invention include sulfate ester salts, sulfonate ester salts, and carboxylic acid ester salts, and more specifically, higher fatty acid salts, higher alcohol sulfate ester salts. , Higher alkyl sulfonates, polyoxyethylene alkylphenyl ether sulfates, alkylbenzene sulfonates, alkylnaphthalene sulfonates, polyoxyethylene alkyl ether sulfates, polyoxyethylene alkyl ether acetates, alkyl sulfosuccinates and sulfosuccinates An acid polyoxyethylene alkyl salt etc. can be illustrated.
In the present invention, polyoxyethylene lauryl ether sodium sulfate, polyoxyethylene lauryl ether ammonium sulfate, polyoxyethylene lauryl ether sodium acetate, lauryl disodium sulfosuccinate from the viewpoint of washing and foaming ability and suppression of irritation to the scalp Polyoxyethylene lauryl disodium sulfosuccinate is preferably used. The component (B) may be used alone or in appropriate combination.
本発明の動物用シャンプー組成物における(B)成分の含有量は、本発明の効果が発揮されれば特に限定されないが、洗浄・起泡力および泡持続力の観点から、組成物全量に対して3重量%以上が好ましく、また被毛や皮膚のべたつき感および皮膚刺激を抑制する観点から、組成物全量に対して20重量%以下が好ましい。 The content of the component (B) in the animal shampoo composition of the present invention is not particularly limited as long as the effects of the present invention are exhibited, but from the viewpoint of washing / foaming power and foam sustainability, the total amount of the composition 3% by weight or more is preferable, and from the viewpoint of suppressing the stickiness and skin irritation of hair and skin, 20% by weight or less is preferable with respect to the total amount of the composition.
本発明の動物用シャンプー組成物に用いられる(C)成分は、ポリサッカライド(多糖類)におけるヒドロキシル基末端に、例えば4級アンモニウム塩化合物等を反応させることにより、1箇所以上の陽イオン性の部位を持たせた陽イオン性ポリサッカライドである。
陽イオン性ポリサッカライドにおける主鎖となるポリサッカライドとしては、例えばカルボキシメチルセルロース、ヒドロキシエチルセルロース、ヒドロキシプロピルセルロース等のセルロース誘導体;キサンタンガム、ゲランガム、グァーガム、アラビアガムおよびカラヤガム等が挙げられる。
これらのポリサッカライドのヒドロキシル基末端に陽イオン性の部位を導入する陽イオン性部位を有する反応性化合物としては、例えば塩化グリシジルトリメチルアンモニウム、塩化3−クロロ−2−ヒドロキシプロピルトリメチルアンモニウム、塩化グリシジルトリエチルアンモニウム等が挙げられる。
(C)成分としては、例えば塩化O−[2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル]ヒドロキシエチルセルロース等のカチオン化セルロース;塩化O−[2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル]グァーガム等のカチオン化グァーガム;塩化O−[2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル]デンプン等のカチオン化デンプン;塩化O−[2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル]デキストラン等の陽イオン性デキストラン等を例示することができる。本発明においては、塩化O−[2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル]ヒドロキシエチルセルロース等のカチオン化セルロースが好ましく用いられる。
The component (C) used in the animal shampoo composition of the present invention is prepared by reacting, for example, a quaternary ammonium salt compound or the like with a hydroxyl group terminal in a polysaccharide (polysaccharide). It is a cationic polysaccharide with a site.
Examples of the polysaccharide serving as the main chain in the cationic polysaccharide include cellulose derivatives such as carboxymethyl cellulose, hydroxyethyl cellulose, and hydroxypropyl cellulose; xanthan gum, gellan gum, guar gum, gum arabic, and karaya gum.
Examples of the reactive compound having a cationic site for introducing a cationic site at the hydroxyl group terminal of these polysaccharides include glycidyl trimethyl ammonium chloride, 3-chloro-2-hydroxypropyl trimethyl ammonium chloride, and glycidyl triethyl chloride. Ammonium etc. are mentioned.
As the component (C), for example, cationized cellulose such as O- [2-hydroxy-3- (trimethylammonio) propyl chloride] hydroxyethylcellulose; O- [2-hydroxy-3- (trimethylammonio) propyl chloride] Cationized guar gum such as guar gum; Cationized starch such as O- [2-hydroxy-3- (trimethylammonio) propyl] chloride chloride; O- [2-hydroxy-3- (trimethylammonio) propyl] dextran chloride and the like And cationic dextran. In the present invention, cationized cellulose such as O- [2-hydroxy-3- (trimethylammonio) propyl] hydroxyethylcellulose chloride is preferably used.
本発明の動物用シャンプー組成物における(C)成分の含有量は、本発明の効果を発揮されれば特に限定されないが、組成物全量に対して0.01重量%以上が好ましく、1重量%以下が好ましい。 The content of the component (C) in the animal shampoo composition of the present invention is not particularly limited as long as the effect of the present invention is exhibited, but is preferably 0.01% by weight or more based on the total amount of the composition, and is 1% by weight. The following is preferred.
本発明の動物用シャンプー組成物には、本発明の効果を損なわない範囲内であれば、(A)〜(C)成分以外に、例えば非イオン性界面活性剤、両性界面活性剤、陽イオン性ポリサッカライド以外の陽イオン性界面活性剤、シリコーン類、増粘剤、保湿剤、パール化剤、溶剤、キレート剤、酸化防止剤、防腐・殺菌剤、pH調整剤、抗酸化剤、着色剤、香料などを目的に応じて適宜含有させることができる。 In the animal shampoo composition of the present invention, in the range not impairing the effects of the present invention, in addition to the components (A) to (C), for example, nonionic surfactants, amphoteric surfactants, cations Cationic surfactants other than water-soluble polysaccharides, silicones, thickeners, moisturizers, pearlizing agents, solvents, chelating agents, antioxidants, antiseptic / disinfectants, pH adjusters, antioxidants, colorants A fragrance or the like can be appropriately contained depending on the purpose.
尚、本発明の動物用シャンプー組成物には、(A)〜(C)成分および必要に応じて適宜含有させられる上記の成分の残部に液体溶剤を含有する。液体溶剤としては、例えば精製水、イオン交換水等の水、エタノール等の低級アルコール類、軽質流動イソパラフィン等の炭化水素類、エーテル類などが挙げられる。これらの溶剤は単独で用いてもよく、また適宜組合せて用いてもよい。本発明においては、精製水が好ましく用いられる。 In addition, the animal shampoo composition of the present invention contains components (A) to (C) and a liquid solvent in the remainder of the above components that are appropriately contained as necessary. Examples of the liquid solvent include water such as purified water and ion exchange water, lower alcohols such as ethanol, hydrocarbons such as light liquid isoparaffin, ethers, and the like. These solvents may be used alone or in appropriate combination. In the present invention, purified water is preferably used.
本発明の動物用シャンプー組成物の剤型としては、適宜、液状、ジェル状、クリーム状等の目的に応じた剤型にすることができ、充填される容器としては、ボトル、ポンプ付き容器、チューブ、ポンプフォーマーなどが挙げられる。 As the dosage form of the animal shampoo composition of the present invention, it can be appropriately formulated according to the purpose such as liquid, gel, cream, etc., and as a container to be filled, a bottle, a container with a pump, A tube, a pump former, etc. are mentioned.
本発明の動物用シャンプー組成物を適用できる動物としては、例えばネコ、イヌ、ウサギ等の愛玩動物類、ウシ、ウマ、ブタ、ヒツジ、ヤギ等の家畜類、アヒル、ニワトリ、ガチョウ等の家禽類が挙げらる。
本発明の動物用シャンプー組成物は、上記の動物に寄生する、例えばノミ類、ダニ類、シラミ類、ハエ類、アブ類、ヌカカ類、ハジラミ類等の外部寄生虫に対して、優れた防除効力を有する。
Examples of animals to which the shampoo composition for animals of the present invention can be applied include pets such as cats, dogs and rabbits, livestock such as cattle, horses, pigs, sheep and goats, and poultry such as ducks, chickens and geese. Is mentioned.
The animal shampoo composition of the present invention provides excellent control against ectoparasites such as fleas, ticks, lices, flies, abs, nukaka and lice that parasitize the above animals. Has efficacy.
本発明の動物用シャンプー組成物を使用して、上記の動物に寄生する外部寄生虫を防除するには、通常、処理する動物の体毛を水で湿らせた後、該動物用シャンプー組成物をそのまま又は水で適宜希釈して、ブラシ等を用い均一に処理して、使用する。処理後は、必要により適宜水で洗い流す。使用対象動物の種類や体毛の量にもよるが、通常本発明の動物用シャンプー組成物は、予め水で希釈して使用することが好ましい。 In order to control the ectoparasites that parasitize the above animals using the animal shampoo composition of the present invention, the animal hair to be treated is usually moistened with water, and then the animal shampoo composition is used. Use as is or diluted appropriately with water and uniformly treated with a brush or the like. After treatment, rinse with water as needed. Although depending on the type of animal to be used and the amount of body hair, it is usually preferable to dilute the animal shampoo composition of the present invention with water in advance.
実施例1〜8および比較例1〜2
表1、表2および表3に記載した個々の成分を、記載の比率で適宜混合して、動物用シャンプー組成物を調製した。
Examples 1-8 and Comparative Examples 1-2
Animal shampoo compositions were prepared by appropriately mixing the individual components described in Tables 1, 2 and 3 in the ratios described.
試験例1
実施例1〜8および比較例1〜2の動物用シャンプー組成物を、各々水で100倍に希釈して試験溶液を調整した。それぞれの試験溶液中に、ネコノミ成虫15匹を漬けた。その後、該ネコノミ成虫を取り出し、清潔な濾紙を敷いたガラスシャーレに移し、ガラスシャーレを通気性を有するフィルムにて覆った。これらのガラスシャーレを26℃、相対湿度60%の条件下に、24時間保管し、その後、ガラスシャーレ中のネコノミの死虫数を観察した。結果を表4および表5に記す。
Test example 1
The animal solution shampoo compositions of Examples 1-8 and Comparative Examples 1-2 were each diluted 100 times with water to prepare test solutions. Fifteen cat flea adults were soaked in each test solution. Thereafter, the adult cat flea was taken out, transferred to a glass petri dish with clean filter paper, and the glass petri dish was covered with a breathable film. These glass petri dishes were stored for 24 hours under the conditions of 26 ° C. and relative humidity 60%, and then the number of dead cat fleas in the glass petri dishes was observed. The results are shown in Tables 4 and 5.
本発明のシャンプー組成物は、動物の外部寄生虫に対して優れた防除活性を有しており、有用である。 The shampoo composition of the present invention has an excellent control activity against animal ectoparasites and is useful.
Claims (5)
(B)陰イオン性界面活性剤、
(C)陽イオン性ポリサッカライド、並びに
(D)溶剤を含有してなり、
かつ、上記溶剤が水のみからなることを特徴とする動物用シャンプー組成物。 (A) phenothrin ,
(B) an anionic surfactant ,
( C) a cationic polysaccharide , and
(D) contains a solvent,
The animal shampoo composition is characterized in that the solvent consists only of water .
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