JP5670605B2 - Semiconductor device - Google Patents

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JP5670605B2
JP5670605B2 JP2014527412A JP2014527412A JP5670605B2 JP 5670605 B2 JP5670605 B2 JP 5670605B2 JP 2014527412 A JP2014527412 A JP 2014527412A JP 2014527412 A JP2014527412 A JP 2014527412A JP 5670605 B2 JP5670605 B2 JP 5670605B2
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舛岡 富士雄
富士雄 舛岡
広記 中村
広記 中村
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    • HELECTRICITY
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    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
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    • H01L29/49Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
    • H01L29/495Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET the conductor material next to the insulator being a simple metal, e.g. W, Mo
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    • H01L29/40Electrodes ; Multistep manufacturing processes therefor
    • H01L29/43Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
    • H01L29/49Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
    • H01L29/4966Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET the conductor material next to the insulator being a composite material, e.g. organic material, TiN, MoSi2

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Description

本発明は半導体装置の製造方法、及び、半導体装置に関する。   The present invention relates to a method for manufacturing a semiconductor device and a semiconductor device.

半導体集積回路、特にMOSトランジスタを用いた集積回路は、高集積化の一途を辿っている。この高集積化に伴って、その中で用いられているMOSトランジスタはナノ領域まで微細化が進んでいる。このようなMOSトランジスタの微細化が進むと、リーク電流の抑制が困難であり、必要な電流量確保の要請から回路の占有面積をなかなか小さくできない、といった問題があった。このような問題を解決するために、基板に対してソース、ゲート、ドレインが垂直方向に配置され、ゲート電極が柱状半導体層を取り囲む構造のSurrounding Gate Transistor(以下、「SGT」という。)が提案されている(例えば、特許文献1、特許文献2、特許文献3を参照)。   Semiconductor integrated circuits, in particular integrated circuits using MOS transistors, are becoming increasingly highly integrated. Along with this high integration, the MOS transistors used therein have been miniaturized to the nano region. When the miniaturization of such a MOS transistor progresses, it is difficult to suppress the leakage current, and there is a problem that the occupied area of the circuit cannot be easily reduced due to a request for securing a necessary amount of current. In order to solve such a problem, a Surrounding Gate Transistor (hereinafter referred to as “SGT”) having a structure in which a source, a gate, and a drain are arranged in a vertical direction with respect to a substrate and a gate electrode surrounds a columnar semiconductor layer is proposed. (For example, see Patent Document 1, Patent Document 2, and Patent Document 3).

シリコン柱が細くなると、シリコンの密度は5×1022個/cm3であるから、シリコン柱内に不純物を存在させることが難しくなってくる。When the silicon pillar is thinned, the density of silicon is 5 × 10 22 pieces / cm 3 , so that it becomes difficult for impurities to exist in the silicon pillar.

従来のSGTでは、チャネル濃度を1017cm-3以下と低不純物濃度とし、ゲート材料の仕事関数を変えることによってしきい値電圧を決定することが提案されている(例えば、特許文献4を参照)。In the conventional SGT, it is proposed to determine the threshold voltage by changing the work function of the gate material by setting the channel concentration to a low impurity concentration of 10 17 cm −3 or less (see, for example, Patent Document 4). ).

平面型MOSトランジスタにおいて、LDD領域のサイドウォールが低濃度層と同一の導電型を有する多結晶シリコンにより形成され、LDD領域の表面キャリアがその仕事関数差によって誘起され、酸化膜サイドウォールLDD型MOSトランジスタに比してLDD領域のインピーダンスが低減できることが示されている(例えば、特許文献5を参照)。その多結晶シリコンサイドウォールは電気的にゲート電極と絶縁されていることが示されている。また図中には多結晶シリコンサイドウォールとソース・ドレインとは層間絶縁膜により絶縁していることが示されている。   In the planar MOS transistor, the sidewall of the LDD region is formed of polycrystalline silicon having the same conductivity type as that of the low concentration layer, and the surface carrier of the LDD region is induced by the work function difference, so that the oxide film sidewall LDD type MOS It has been shown that the impedance of the LDD region can be reduced as compared with a transistor (see, for example, Patent Document 5). The polycrystalline silicon sidewall is shown to be electrically insulated from the gate electrode. In the figure, it is shown that the polysilicon side wall and the source / drain are insulated by an interlayer insulating film.

特開平2−71556号公報JP-A-2-71556 特開平2−188966号公報Japanese Patent Laid-Open No. 2-188966 特開平3−145761号公報Japanese Patent Laid-Open No. 3-145761 特開2004−356314号公報JP 2004-356314 A 特開平11−297984号公報JP 11-297984 A

そこで、本発明は、トランジスタを金属と半導体との仕事関数差によって形成する構造を持つSGTを提供することを目的とする。   Therefore, an object of the present invention is to provide an SGT having a structure in which a transistor is formed by a work function difference between a metal and a semiconductor.

本発明の半導体装置は、1017cm-3以下の不純物濃度の柱状半導体と、前記柱状半導体を囲む第1の絶縁物と、前記柱状半導体の一端の前記第1の絶縁物を取り囲む第1の金属と、前記柱状半導体の他方の一端の前記第1の絶縁物を取り囲む第2の金属と、前記第1の金属と前記第2の金属とに挟まれた領域で前記第1の絶縁物を取り囲む第3の金属と、前記第1の金属と前記第3の金属との間に形成された第2の絶縁物と、前記第2の金属と前記第3の金属との間に形成された第3の絶縁物と、前記第1の金属と前記柱状半導体の一端とを接続する第4の金属と、前記第2の金属と前記柱状半導体の他方の一端とを接続する第5の金属を有し、前記第3の金属の仕事関数は4.2eVから5.0eVの間であることを特徴とする。The semiconductor device of the present invention includes a columnar semiconductor having an impurity concentration of 10 17 cm −3 or less, a first insulator surrounding the columnar semiconductor, and a first insulator surrounding the first insulator at one end of the columnar semiconductor. The first insulator in a region sandwiched between the metal, the second metal surrounding the first insulator at the other end of the columnar semiconductor, and the first metal and the second metal. An enclosing third metal; a second insulator formed between the first metal and the third metal; and formed between the second metal and the third metal. A third metal, a fourth metal that connects the first metal and one end of the columnar semiconductor, and a fifth metal that connects the second metal and the other end of the columnar semiconductor. And the work function of the third metal is between 4.2 eV and 5.0 eV.

また、前記半導体は、シリコンであることを特徴とする。   Further, the semiconductor is silicon.

また、前記第1の金属と前記第2の金属の仕事関数は4.0eVから4.2eVの間であることを特徴とする。   The work function of the first metal and the second metal is between 4.0 eV and 4.2 eV.

また、前記第1の金属と前記第2の金属の仕事関数は5.0eVから5.2eVの間であることを特徴とする。   The work function of the first metal and the second metal is between 5.0 eV and 5.2 eV.

本発明によれば、トランジスタを金属とシリコンとの仕事関数差によって形成する構造を持つSGTを提供することができる。   According to the present invention, an SGT having a structure in which a transistor is formed by a work function difference between metal and silicon can be provided.

前記柱状シリコンの一端の前記第1の絶縁物を取り囲む第1の金属と、前記柱状シリコンの他方の一端の前記第1の絶縁物を取り囲む第2の金属と、によって、金属とシリコンとの仕事関数差によってキャリアが誘起されるため、第1の金属と前記第2の金属の仕事関数が4.0eVから4.2eVの間であればn型トランジスタとなり、前記第1の金属と前記第2の金属の仕事関数が5.0eVから5.2eVの間であればp型トランジスタとなる。不純物が柱状シリコン内に存在しない状態でトランジスタ動作が可能となる。従って、拡散層を形成するための不純物注入が不要となる。   Work of metal and silicon by a first metal surrounding the first insulator at one end of the columnar silicon and a second metal surrounding the first insulator at the other end of the columnar silicon. Since carriers are induced by the functional difference, an n-type transistor is formed if the work function of the first metal and the second metal is between 4.0 eV and 4.2 eV, and the first metal and the second metal If the work function of the metal is between 5.0 eV and 5.2 eV, a p-type transistor is obtained. Transistor operation can be performed in a state where impurities are not present in the columnar silicon. Therefore, impurity implantation for forming the diffusion layer is not necessary.

(a)は本発明に係る半導体装置の鳥瞰図である。(b)は(a)のX−X’面での断面図である。(A) is a bird's-eye view of the semiconductor device concerning the present invention. (B) is sectional drawing in the X-X 'surface of (a).

以下、本発明の実施形態に係る、SGTの構造を有する半導体装置を、図1を参照しながら説明する。   Hereinafter, a semiconductor device having an SGT structure according to an embodiment of the present invention will be described with reference to FIG.

基板110上に、1017cm-3以下の不純物濃度の柱状シリコン101と、前記柱状シリコン101を囲む第1の絶縁物102と、前記柱状シリコン101の一端の前記第1の絶縁物102を取り囲む第1の金属104と、前記柱状シリコン101の他方の一端の前記第1の絶縁物102を取り囲む第2の金属105と、前記第1の金属104と前記第2の金属105とに挟まれた領域で前記第1の絶縁物102を取り囲む第3の金属103と、前記第1の金属104と前記第3の金属103との間に形成された第2の絶縁物107と、前記第2の金属105と前記第3の金属103との間に形成された第3の絶縁物106と、前記第1の金属104と前記柱状シリコン101の一端とを接続する第4の金属108と、前記第2の金属105と前記柱状シリコン101の他方の一端とを接続する第5の金属109を有し、前記第3の金属103の仕事関数は4.2eVから5.0eVの間であることを特徴とする。A columnar silicon 101 having an impurity concentration of 10 17 cm −3 or less, a first insulator 102 surrounding the columnar silicon 101, and the first insulator 102 at one end of the columnar silicon 101 are surrounded on a substrate 110. Sandwiched between the first metal 104, the second metal 105 surrounding the first insulator 102 at the other end of the columnar silicon 101, and the first metal 104 and the second metal 105 A third metal 103 surrounding the first insulator 102 in a region; a second insulator 107 formed between the first metal 104 and the third metal 103; A third insulator 106 formed between the metal 105 and the third metal 103; a fourth metal 108 connecting the first metal 104 and one end of the columnar silicon 101; Two metals 105 And the other end of the columnar silicon 101, and the work function of the third metal 103 is between 4.2 eV and 5.0 eV.

第4の金属108により、前記第1の金属104と前記柱状シリコン101の一端とは同電位が印加される。   The same potential is applied to the first metal 104 and one end of the columnar silicon 101 by the fourth metal 108.

第5の金属109により、前記第2の金属105と前記柱状シリコン101の他方の一端とは同電位が印加される。   The same potential is applied to the second metal 105 and the other end of the columnar silicon 101 by the fifth metal 109.

従って、柱状シリコン101の一端と他方の一端は、金属とシリコンとの仕事関数差によってキャリアが誘起されることとなる。   Therefore, at one end of the columnar silicon 101 and the other end, carriers are induced by the work function difference between the metal and silicon.

前記第1の金属104と前記第2の金属105の仕事関数が4.0eVから4.2eVの間であるとき、n型シリコンの仕事関数4.05eVの近傍であるため、柱状シリコン101の一端と他方の一端は、n型シリコンとして機能する。前記第1の金属104と前記第2の金属105は、例えば、タンタルとチタンの化合物(TaTi)や窒化タンタル(TaN)が好ましい。   When the work functions of the first metal 104 and the second metal 105 are between 4.0 eV and 4.2 eV, the work function of the n-type silicon is in the vicinity of 4.05 eV. The other end functions as n-type silicon. For example, the first metal 104 and the second metal 105 are preferably a compound of tantalum and titanium (TaTi) or tantalum nitride (TaN).

前記第1の金属104と前記第2の金属105の仕事関数が5.0eVから5.2eVの間であるとき、p型シリコンの仕事関数5.15eVの近傍であるため、柱状シリコン101の一端と他方の一端は、p型シリコンとして機能する。前記第1の金属104と前記第2の金属105は、例えば、ルテニウム(Ru)や窒化チタン(TiN)が好ましい。   When the work functions of the first metal 104 and the second metal 105 are between 5.0 eV and 5.2 eV, the work function of the p-type silicon is in the vicinity of 5.15 eV. The other end functions as p-type silicon. The first metal 104 and the second metal 105 are preferably, for example, ruthenium (Ru) or titanium nitride (TiN).

このとき、前記第3の金属103の仕事関数は4.2eVから5.0eVの間であると、エンハンスメント型として動作することができる。   At this time, when the work function of the third metal 103 is between 4.2 eV and 5.0 eV, the third metal 103 can operate as an enhancement type.

上記により、前記第1の金属104と前記第2の金属105の仕事関数が4.0eVから4.2eVの間であるとき、n型シリコンの仕事関数4.05eVの近傍であるため、柱状シリコン101の一端と他方の一端は、n型シリコンのソースドレインとして機能し、柱状シリコン101の第3の金属103に取り囲まれる部分は、i型シリコン、もしくは薄い濃度のn型シリコン、もしくは薄い濃度のp型シリコンとして機能する。従って、n型トランジスタとして機能する。   As described above, when the work functions of the first metal 104 and the second metal 105 are between 4.0 eV and 4.2 eV, the work function of the n-type silicon is in the vicinity of 4.05 eV. One end and the other end of 101 function as a source / drain of n-type silicon, and a portion surrounded by the third metal 103 of the columnar silicon 101 is i-type silicon, or light n-type silicon, or lightly-concentrated Functions as p-type silicon. Therefore, it functions as an n-type transistor.

また、前記第1の金属104と前記第2の金属105の仕事関数が5.0eVから5.2eVの間であるとき、p型シリコンの仕事関数5.15eVの近傍であるため、柱状シリコン101の一端と他方の一端は、p型シリコンのソースドレインとして機能し、柱状シリコン101の第3の金属103に取り囲まれる部分は、i型シリコン、もしくは薄い濃度のn型シリコン、もしくは薄い濃度のp型シリコンとして機能する。従って、p型トランジスタとして機能する。   Further, when the work functions of the first metal 104 and the second metal 105 are between 5.0 eV and 5.2 eV, the work function of the p-type silicon is in the vicinity of 5.15 eV. One end and the other end of p-type silicon function as a source / drain of p-type silicon, and a portion surrounded by the third metal 103 of the columnar silicon 101 is i-type silicon, or light n-type silicon, or light p Functions as mold silicon. Therefore, it functions as a p-type transistor.

以上により、不純物が柱状シリコン内に存在しない状態でトランジスタ動作が可能となる。従って、拡散層を形成するための不純物注入が不要となる。   As described above, transistor operation can be performed in a state where impurities are not present in columnar silicon. Therefore, impurity implantation for forming the diffusion layer is not necessary.

なお、本発明は、本発明の広義の精神と範囲を逸脱することなく、様々な実施形態及び変形が可能とされるものである。また、上述した実施形態は、本発明の一実施例を説明するためのものであり、本発明の範囲を限定するものではない。   It should be noted that the present invention can be variously modified and modified without departing from the broad spirit and scope of the present invention. Further, the above-described embodiment is for explaining an example of the present invention, and does not limit the scope of the present invention.

101.柱状シリコン
102.第1の絶縁物
103.第3の金属
104.第1の金属
105.第2の金属
106.第3の絶縁物
107.第2の絶縁物
108.第4の金属
109.第5の金属
110.基板
101. Columnar silicon 102. First insulator 103. Third metal 104. First metal 105. Second metal 106. Third insulator 107. Second insulator 108. Fourth metal 109. Fifth metal 110. substrate

Claims (4)

1017cm-3以下の不純物濃度である柱状半導体と、
前記柱状半導体を取り囲む第1の絶縁物と、
前記柱状半導体の一端の前記第1絶縁物を取り囲む第1の金属と、
前記柱状半導体の他方の一端の前記第1の絶縁物を取り囲む第2の金属と、
前記第1の金属と前記第2の金属とに挟まれた領域で前記第1の絶縁物を取り囲む第3の金属と、
前記第1の金属と前記第3の金属との間に形成された第2の絶縁物と、
前記第2の金属と前記第3の金属との間に形成された第3の絶縁物と、
前記第1の金属と前記柱状半導体の一端とを接続する第4の金属と、
前記第2の金属と前記柱状半導体の他方の一端を接続する第5の金属を有し、
前記第3の金属の仕事関数は4.2eVから5.0eVの間であることを特徴とする半導体装置。
A columnar semiconductor having an impurity concentration of 10 17 cm −3 or less;
A first insulator surrounding the columnar semiconductor;
A first metal surrounding the first insulator at one end of the columnar semiconductor;
A second metal surrounding the first insulator at the other end of the columnar semiconductor;
A third metal surrounding the first insulator in a region sandwiched between the first metal and the second metal;
A second insulator formed between the first metal and the third metal;
A third insulator formed between the second metal and the third metal;
A fourth metal connecting the first metal and one end of the columnar semiconductor;
A fifth metal connecting the second metal and the other end of the columnar semiconductor;
The semiconductor device according to claim 3, wherein the work function of the third metal is between 4.2 eV and 5.0 eV.
前記半導体は、シリコンであることを特徴とする請求項1に記載の半導体装置。   The semiconductor device according to claim 1, wherein the semiconductor is silicon. 前記第1の金属と前記第2の金属の仕事関数は4.0eVから4.2eVの間であることを特徴とする請求項2に記載の半導体装置。   The semiconductor device according to claim 2, wherein a work function of the first metal and the second metal is between 4.0 eV and 4.2 eV. 前記第1の金属と前記第2の金属の仕事関数は5.0eVから5.2eVの間であることを特徴とする請求項2に記載の半導体装置。   The semiconductor device according to claim 2, wherein a work function of the first metal and the second metal is between 5.0 eV and 5.2 eV.
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