JP5629643B2 - Silicone-modified epoxy resin composition, optical semiconductor encapsulating composition containing the resin composition, and optical semiconductor element adhesive - Google Patents

Description

  The present invention relates to a resin composition having a silicone-modified epoxy resin as an essential component and excellent in optical properties, heat resistance, UV resistance, curability and crack resistance, and particularly for sealing and adhesion of optical semiconductor elements such as LEDs. The present invention relates to a suitable resin composition.

Conventionally, transparent epoxy resin compositions have been widely used to seal optical semiconductor elements such as LEDs. These transparent epoxy resin compositions contain an alicyclic epoxy resin, a curing agent and a curing catalyst, and are used for sealing an optical semiconductor element by a molding method such as casting molding or transfer molding. In general, the epoxy resin composition has excellent handling properties because of the high hardness of the cured product. For example, in a low output white LED sealing application, the required durability can be obtained. Many are used.
However, as LEDs become increasingly brighter and have higher output in recent years, the cured products of conventional transparent epoxy resin compositions can be discolored by continuous use with short-wavelength blue light or ultraviolet light, resulting in a sufficient lifespan. It is difficult. In addition, there is a problem that cracks occur in the cured product due to repeated rapid temperature changes associated with turning on and off.

Recently, in order to solve these problems, an LED cured with a resin composition based on a silicone resin having excellent weather resistance has been used instead of an epoxy resin. There has been a report of an addition-curable silicone composition (Patent Document 1) for protective sealing of optical devices or semiconductor devices by addition reaction of hydrosilyl groups and olefins.
However, the silicone resin has high flexibility derived from the silicone skeleton, but has a disadvantage that the hardness of the cured product is low and the surface tends to be sticky, and the strength is low. In addition, although the resin having a high hardness silicone skeleton has improved handling properties, the problem of weather resistance and cracks due to repeated rapid temperature changes accompanying lighting and extinction have not been solved. Moreover, the silicone resin is very expensive and is not economically preferable.

Therefore, in recent years, there have been increasing reports of resin compositions (Patent Documents 2 to 8) obtained by curing a silicone resin having an epoxy group that is synthesized at a relatively low cost using a curing agent as compared with a silicone resin. Yes. For example, a resin composition obtained by curing a silicone resin having a glycidyl isocyanuryl group using a curing agent (Patent Document 9) has high flexibility derived from a silicone skeleton and relatively high heat resistance. It is known to have UV resistance. However, they are harder and more brittle than silicone resins, and have not improved crack resistance.
On the other hand, in the fields of electrical and electronic parts and IC encapsulants, as a technique for improving crack resistance, a technique in which a rubber component such as butadiene or organopolysiloxane is blended in an epoxy resin composition is known. However, although the stress of the cured product can be reduced, there is a problem that the heat resistance and other physical properties are deteriorated. Thus, there has been a report of imparting crack resistance while maintaining heat resistance by addition reaction of epoxidized polybutadiene and hydrogen polysiloxane (Patent Document 10). However, there has been no discussion regarding transparency and weather resistance, and it has been unclear whether satisfactory characteristics have been obtained for LED applications.
As described above, even if a silicone resin having excellent weather resistance is used as a base, it has not been obtained that satisfies both the economy and the characteristics required for the LED encapsulant, has sufficient hardness, and has weather resistance. There is a demand for materials that are excellent in performance and have the same handling and mass productivity as conventional epoxy resins.

JP 2000-198930 (Patent No. 3523098) Japanese Patent Laying-Open No. 2005-343998 (Patent No. 4198091) JP 2008-248170 A JP 2009-203258 A JP 2010-6156 A JP 2010-53204 A JP 2010-65161 A JP 2010-138380 A JP 2009-275206 A Japanese Patent Laid-Open No. 9-48837 (Patent No. 3497293)

  In order to solve these current problems, the present invention has good heat resistance and UV light transmittance of the cured product, no stickiness on the surface, sufficient hardness, good storage stability, crack resistance and handling. It is an object of the present invention to provide a silicone-modified epoxy resin composition having a good surface roughness, an optical semiconductor sealing composition containing the resin composition, and an optical semiconductor element adhesive.

As a result of intensive studies to achieve the above object, the present inventors have found that a silicone-modified epoxy resin composition containing a silicone-modified epoxy resin having a specific structure and a curing agent is an optical semiconductor sealing composition. In addition, the present inventors have found that a cured product suitable for an optical semiconductor element adhesive can be provided, and reached the present invention.
That is, the present invention provides the following curable resin composition, optical semiconductor sealing composition, and optical semiconductor element adhesive.

1. (A) A silicone-modified epoxy resin composition containing a silicone-modified epoxy resin having a structure represented by the following general formula (1) and (B) a curing agent.

[In the formula (1), R ¹ each independently represents a monovalent organic group, R ² each independently represents a chain aliphatic hydrocarbon group having 1 to 10 carbon atoms, or a cyclic group having 3 to 10 carbon atoms. Y represents a group selected from an aliphatic hydrocarbon group and a phenyl group, and Y represents an organic group containing a cyclic ether group. X may be the same or different. a and b are positive numbers, a + b = 1 and 0.3 ≦ a <1, and n is 1 to 25. ]
2. The hydrosilylation reaction of the (A) silicone-modified epoxy resin with (a1) liquid polybutadiene, (a2) a hydrogen polysiloxane compound, and (a3) a compound having an unsaturated bond and a cyclic ether group in one molecule. 2. The silicone-modified epoxy resin composition as described in 1 above, which is obtained by:
3. (A3) The silicone-modified epoxy resin composition according to 2, wherein the compound having an unsaturated bond and a cyclic ether group in one molecule is represented by the following formula (2).

(In the formula, R ³ represents an unsaturated hydrocarbon group, and each R ⁴ independently represents a cyclic ether group.)
4). 4. The silicone-modified epoxy resin composition according to any one of 1 to 3, wherein the (B) curing agent is an acid anhydride.
5. The optical semiconductor sealing composition containing the silicone modified epoxy resin composition in any one of said 1-4.
6). The optical-semiconductor element adhesive agent containing the silicone modified epoxy resin composition in any one of said 1-4.

  In the resin composition containing the silicone-modified epoxy resin of the present invention, the inorganic component and the organic component are uniformly mixed at the molecular level. Therefore, the cured product exhibits high optical properties and high stability, and is excellent in curability, heat resistance, UV transmittance, and crack resistance.

[(A) Silicone-modified epoxy resin]
The resin composition of the present invention contains a silicone-modified epoxy resin having a structure represented by the following general formula (1) as an essential component.

In formula (1), each R ¹ independently represents a monovalent organic group, each R ² independently represents a chain aliphatic hydrocarbon group having 1 to 10 carbon atoms, or a cyclic fatty acid having 3 to 10 carbon atoms. Y represents a group selected from a group hydrocarbon group and a phenyl group, and Y represents an organic group containing a cyclic ether group. X may be the same or different. a and b are positive numbers, a + b = 1 and 0.3 ≦ a <1, and n is 1 to 25.
Specific R ¹ , R ² , Y, a, b, and n are synonymous with those described later.

(A) The silicone-modified epoxy resin is obtained by a hydrosilylation reaction. (A) As a particularly preferable method for obtaining a silicone-modified epoxy resin, (a1) liquid polybudadiene, (a2) a hydrogenpolysiloxane compound, and (a3) an unsaturated bond and a cyclic ether group in one molecule This is a method based on a hydrosilylation reaction with a compound. More specifically, (a1) a hydrosilylation reaction between an unsaturated bond of liquid polybudadiene and (a2) a hydrosilyl group of a hydrogen polysiloxane compound, and (a3) an unsaturated bond and a cyclic ether group in one molecule. A carbon-silicon bond is formed by a hydrosilylation reaction between the unsaturated bond of the compound and the hydrosilyl group of the (a2) hydrogen polysiloxane compound, and (A) a silicone-modified epoxy resin can be obtained.
More specific components (a1) to (a3) are as follows.

((A1) Liquid polybudadiene)
(A1) Liquid polybudadiene is represented by the following formula (3).

The (a1) liquid polybudadiene represented by the above formula (3) is a low molecular weight polybutadiene having a number average molecular weight of about 500 to 5,000 obtained by polymerizing butadiene with a specific catalyst under predetermined polymerization conditions.
When the number average molecular weight is 500 or more, it becomes a resin having a normal skeleton of polybutadiene, and when the number average molecular weight is 5,000 or less, it is not rubbery and can maintain a liquid range. It does not become liquefied and handling properties do not deteriorate. Therefore, in the present invention, the number average molecular weight of (a1) liquid polybudadiene is preferably 500 to 5000, and more preferably 1000 to 4000.

(A1) As the liquid polybudadiene, those having different butadiene bonding modes are obtained depending on the catalyst used for production, and various products are commercially available. That is, there are a 1,2-bond type which is a repeat unit of a repeat number a and a 1,4-bond type which is a repeat unit of a repeat number b, and the 1,4-bond type further includes a trans type and a cis type. is there. As the R ¹ is a monovalent organic group at the end, those having -OH, -COOH, a functional group such as -CH = CH ₂ independently.
In the present invention, when the repeating unit a showing the proportion of 1,2-bond type and the repeating unit b showing the proportion of 1,4-bond type are set to a + b = 1, from the viewpoint of heat resistance and crack resistance. The ratio a of 1,2-bond type is 0.3 ≦ a <1, and preferably 0.5 ≦ a <1.
Further, the characteristics of the liquid polybutadiene resin other than those described above have different characteristics depending on the type of the liquid polybutadiene resin, but are not particularly limited in the present invention.

  In the present invention, commercially available (a1) liquid polybudadiene can be used, for example, Poly bd (trade name) which is a hydroxyl-terminated liquid polybutadiene manufactured by Idemitsu Kosan Co., Ltd., NISSO PB (Nippon Soda Co., Ltd.) Product name) G series and B series. Moreover, (a1) liquid polybudadiene can be used individually or in mixture of 2 or more types.

((A2) Hydrogen polysiloxane)
(A2) Hydrogen polysiloxane has a structure represented by the following formula (4) having at least two H—Si bonds in one molecule.

In the above formula (4), each R ² independently represents a group selected from a chain aliphatic hydrocarbon group having 1 to 10 carbon atoms, a cyclic aliphatic hydrocarbon group having 3 to 10 carbon atoms and a phenyl group. These may be the same or different. Moreover, the repeating unit n shows 1-25, and it is preferable that it is 1-20 from a viewpoint of a viscosity and handling.

  Examples of the chain aliphatic hydrocarbon group having 1 to 10 carbon atoms include chain alkyl groups such as methyl group, ethyl group, propyl group, and n-butyl group, and cyclic groups having 3 to 10 carbon atoms. Examples of the aliphatic hydrocarbon group include cycloalkyl groups such as a cyclopropyl group, a cyclobutyl group, a cyclopentyl group, and a cyclohexyl group.

  Commercially available products that can be used as the (a2) hydrogenpolysiloxane include TSL9586 (trade name) manufactured by Momentive Performance Materials, DMS series (trade name) manufactured by Gelest, Inc., and the like. (A2) Hydrogen polysiloxanes can be used alone or in admixture of two or more.

((A3) Compound having unsaturated bond and cyclic ether group in one molecule)
(A3) As a compound having an unsaturated bond and a cyclic ether group in one molecule, for example, an isocyanuric acid derivative represented by the following formula (2) can be used.

In the above formula (2), R ³ represents an unsaturated hydrocarbon group, and R ⁴ each independently represents a cyclic ether group.
The unsaturated hydrocarbon group for R ³ preferably has 2 to 6 carbon atoms, and examples thereof include a vinyl group, an allyl group, a propenyl group, and a butenyl group.
The cyclic ether group for R ⁴ preferably has, for example, 3 to 5 carbon atoms, and examples thereof include an epoxy group and a glycidyl group.
As a commercial item represented by the said Formula (2), MA-DGIC (brand name) etc. which are monoallyl diglycidyl isocyanuric acid by Shikoku Kasei Kogyo Co., Ltd. are mentioned, for example.

Moreover, as (a3) component, allyl glycidyl ether, 1,2-epoxy-4-vinylcyclohexane, etc. other than what is represented by said Formula (2) are mentioned, for example. Examples of commercially available products include Celoxide 2000 (trade name), which is 1,2-epoxy-4-vinylcyclohexane manufactured by Daicel Chemical Industries, Ltd.
(A3) A component can be used individually or in mixture of 2 or more types.

  Y, which is an organic group having a cyclic ether group in the general formula (1), is formed by a hydrosilylation reaction between the unsaturated bond of the component (a3) and the hydrosilyl group of the component (a2). It is preferably a residue derived from the component a3).

(Reaction conditions for hydrosilylation reaction)
A known method can be used for the hydrosilylation reaction of (a1) liquid polybutadiene, (a2) a hydrogen polysiloxane compound, and (a3) a compound having an unsaturated bond and a cyclic ether group in one molecule.
The hydrosilylation reaction can be performed without a solvent, but is preferably performed in a diluting solvent that does not affect the reaction from the viewpoint of reaction control. The diluent solvent is not particularly limited except that it does not have an unsaturated bond group and does not participate in the hydrosilylation reaction.
Examples of the dilution solvent include alcohols such as methanol, ethanol, 2-propanol, and butanol; aliphatic hydrocarbons such as hexane, heptane, cyclohexane, methylcyclohexane, and ethylcyclohexane; acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, and the like. Aliphatic ketones such as cyclopentanone; aromatics such as benzene, toluene, orthoxylene, metaxylene, paraxylene, chlorobenzene and dichlorobenzene; N, N-dimethylformamide, N, N-dimethylacetamide and N-methyl Aliphatic amides such as pyrrolidone; ethers such as tetrahydrofuran, dioxane, diethylene glycol dimethyl ether and triethylene glycol dimethyl ether. These can be used alone or in admixture of two or more.

  The reaction temperature for the condensation reaction is not particularly limited, but is usually 20 to 200 ° C, preferably 50 to 150 ° C. By setting the temperature to 20 ° C. or higher, the reaction proceeds satisfactorily and does not significantly slow down. Moreover, reaction can be easily controlled by setting it as 200 degrees C or less, and it can prevent gelatinizing and coloring.

As the catalyst used in the hydrosilylation reaction, a catalyst usually used for promoting a hydrosilylation reaction between a silicon atom to which a hydrogen atom is bonded and a hydrocarbon having a multiple bond can be used. The catalyst is not particularly limited as long as it is a known catalyst used in the above.
As said catalyst, the transition metal catalyst containing platinum, rhodium, palladium, ruthenium, iridium etc. can be used, for example, It is preferable to use platinum and a platinum compound especially. Examples of the platinum compound include hexachloroplatinic acid (IV) hexahydrate, platinum carbonyl vinylmethyl complex, platinum-divinyltetramethyldisiloxane complex, platinum-cyclovinylmethylsiloxane complex, and platinum-octylaldehyde / octanol complex. preferable. These can be used alone or in admixture of two or more.

  The amount of the catalyst used is usually preferably in the range of 0.01 to 500 ppm relative to the total mass of the components (a1), (a2) and (a3) as a platinum group metal. It is more preferable that If it is 0.01 ppm or more, the reaction can proceed favorably, and if it is 500 ppm or less, gelation or coloring during the reaction can be prevented.

[(B) Curing agent]
As the (B) curing agent contained in the resin composition of the present invention, since (A) the silicone-modified epoxy resin has an epoxy group, for example, in thermosetting, amine-based curing agents and acid anhydrides that are generally used A curing agent can be used, but an acid anhydride curing agent is desirable from the viewpoint of light transmittance and heat resistance.
Examples of the acid anhydride curing agent include succinic anhydride, phthalic anhydride, maleic anhydride, trimellitic anhydride, pyromellitic anhydride, hexahydrophthalic anhydride, 3-methyl-hexahydrophthalic anhydride, 4-methyl Hexahydrophthalic anhydride, tetrahydrophthalic anhydride, methyl-tetrahydrophthalic anhydride, nadic anhydride, methyl nadic anhydride, norbornane-2,3-dicarboxylic anhydride, methylnorbornane-2,3-dicarboxylic anhydride and And methylcyclohexene dicarboxylic acid anhydride. These can be used alone or in admixture of two or more.

Further, a curing accelerator and a curing catalyst effective for the reaction with the curing agent can be used in combination.
Examples of the curing accelerator include organic phosphorus compounds such as triphenylphosphine and tributylphosphine; ethyltriphenylphosphonium bromide, diethyl methyltriphenylphosphonium phosphate, tetra-n-butylphosphonium-O, O′-diethyl. Quaternary phosphonium salts such as phosphorodithionate; 1,8-diazabicyclo (5,4,0) undecan-7-ene, 1,8-diazabicyclo (5,4,0) undecan-7-ene and octylic acid And quaternary ammonium salts such as zinc octylate and tetrabutylammonium bromide. These can be used alone or in admixture of two or more.

  Examples of the curing catalyst include organic phosphine-based curing catalysts such as triphenylphosphine and diphenylphosphine; and three such as 1,8-diazabicyclo (5,4,0) undecene-7, triethanolamine and benzyldimethylamine. Secondary amine-based curing catalyst; imidazoles such as 2-methylimidazole and 2-phenyl-4-methylimidazole. These can be used alone or in admixture of two or more.

Moreover, it can be set as thermosetting and photocuring by adding a thermal cation curing catalyst or a photocationic curing catalyst.
Examples of the thermal cation curing catalyst include benzylsulfonium salt, thiophenium salt, thioranium salt, benzylammonium, pyridinium salt, hydrazinium salt, carboxylic acid ester, sulfonic acid ester, and amine imide. These can be used alone or in admixture of two or more.
Examples of the photocation curing catalyst include sulfonium salt and iodonium salt. Examples of the sulfonium salt system include, for example, triphenylsulfonium hexafluorophosphate and triphenylsulfonium hexafluoroantimonate. Examples of the iodonium salt system include, for example, diphenyliodonium tetrakis (pentafluorophenyl) borate and diphenyliodonium. Examples include hexafluorophosphate. These can be used alone or in admixture of two or more.

[Resin composition]
The silicone-modified epoxy resin composition of the present invention contains the above-described (A) silicone-modified epoxy resin and (B) a curing agent, and the content ratio thereof is 1 equivalent of the epoxy group of the component (A). Is preferably 0.8 to 1.5 equivalents of component (B). If it is 0.8 equivalent or more, an unreacted epoxy group does not remain, and if it is 1.5 equivalent or less, a functional group in the curing agent does not remain. From this, by making it in the said range, functions, such as hardness and heat resistance when it is set as hardened | cured material, can be made favorable.

  Moreover, when using (B) a hardening | curing agent, a hardening accelerator, and / or a hardening catalyst together, it is preferable that the usage-amount of a hardening catalyst is 0.05-5.0 mass% in a silicone modified epoxy resin composition. . If it is 0.05 mass% or more, the reaction progress of the (B) curing agent can be improved, and even if it exceeds 5.0 mass%, the effect according to the amount is not exhibited, and 5.0 mass% The following effects can be sufficiently exerted.

In the present invention, a compound having a cyclic ether group, preferably a monomer having an epoxy group, can be added as necessary in addition to the above components. By adding a monomer having an epoxy group, the density, free volume, adhesion to the substrate, refractive index and the like of the silicone-modified epoxy resin composition can be adjusted.
Examples of the monomer include novolac type epoxy resins, bisphenol alkyl type epoxy resins, biphenyl type epoxy resins, and those obtained by nuclear hydrogenation of these aromatic rings, glycidyl ester type epoxy resins, and olefin compounds containing a ring structure. Alicyclic epoxy resins, epoxy resins having an isocyanuric skeleton, and the like. These can be used alone or in admixture of two or more.
Although the addition amount of the said monomer is not specifically limited, 0.1-80 mass% is preferable with respect to a silicone modified epoxy resin composition, and 10-60 mass% is more preferable. If it exists in the range of 0.1-80 mass%, hardening by having added the said monomer can be exhibited favorably.

  Moreover, antioxidant can be added to the silicone-modified epoxy resin composition of the present invention. By adding an antioxidant, coloring of the cured product when exposed to a high temperature environment for a long time can be reduced. As the antioxidant, various known compounds such as hindered phenol antioxidants and thioether compound antioxidants can be applied.

  Examples of the hindered phenol-based antioxidant include 2,6-tert-butyl-p-cresol, butylated hydroxyanisole, 2,6-tert-butyl-p-ethylphenol, and stearyl-β- (3, Monophenols such as 5-di-tert-butyl-4--4-hydroxyphenyl) propionate; 2,2-methylenebis (4-methyl-6-tert-butylphenol), 2,2-methylenebis (4-ethyl-6) Bisphenols such as -tert-butylphenol) and 4,4'-thiobis (3-methyl-6-tert-butylphenol); 1,1,3-tris (2-methyl-4-hydroxy-5-tert-butylphenyl) ) Butane, 1,3,5-trimethyl-2,4,6-tris (3,5-di-tert-butyl) Le-4-hydroxybenzyl) benzene and tetrakis [methylene-3- (3,5-di -tert- butyl-4-hydroxyphenyl) propionate] methane, and the like.

  Examples of the thioether compound-based antioxidant include dilauryl 3,3′-dilauryl 3,3′-thiodipropionate, dimyristyl 3,3′-dilauryl 3,3′-thiodipropionate, distearyl 3, 3'-dilauryl 3,3'-thiodipropionate, pentaerythrityl tetrakis (3-lauryl thiopropionate), etc. are mentioned.

  Moreover, antioxidant containing a phosphorus atom can also be used together. For example, triphenyl phosphate, 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, 10- (3,5-di-tert-butyl 4-hydroxybenzyl) -9,10-dihydro Examples include -9-oxa-10-phosphaphenanthrene-10-oxide and 10-decyloxy-9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide. These antioxidants can be used alone or in admixture of two or more.

  The addition amount of the antioxidant is not particularly limited, but is preferably 0.001 to 20% by mass and more preferably 0.01 to 5% by mass with respect to the silicone-modified epoxy resin composition. When added in the range of 0.001 to 20% by mass, coloring can be reduced.

  The silicone-modified epoxy resin composition of the present invention may further contain additives such as dyes, pigments, surfactants, oxide nanoparticles, nitride nanoparticles, antifouling agents, metal fillers and heat-resistant agents. Can do. Moreover, if it is a grade which does not impair hardening, it is also possible to use a solvent, a reactive diluent, etc., and to adjust a viscosity and improve handling property.

[Optical Semiconductor Encapsulating Composition and Optical Semiconductor Element Adhesive]
Moreover, this invention provides the optical semiconductor sealing composition and optical semiconductor element adhesive agent containing a silicone modified epoxy resin composition. The LED that can use the optical semiconductor sealing composition and the optical semiconductor element adhesive is not only a recent LED with high luminous efficiency and a short wavelength, but also a compound semiconductor GaP, a compound semiconductor GaAs, and a compound semiconductor GaN. The red LED, the green LED, and the yellow LED that are manufactured in the above.
In addition, the above-mentioned silicone-modified epoxy resin composition can be used for sealing existing LEDs, and has been developed recently with a high-efficiency LED having a luminous efficiency of 80 lm / W or more at a wavelength in the blue or ultraviolet region. Ideal for.

  Hereinafter, embodiments of the present invention will be described. The present invention is not limited to the following examples as long as the gist thereof is not exceeded.

[Synthesis Example 1]
(A) Synthesis of silicone-modified epoxy resin (resin A) A 500 ml four-necked separable flask equipped with a thermometer, a cooling tube, a nitrogen introduction tube, and a stirring blade was charged with hydrogenpolydimethylsiloxane (trade name). : DMS-H03, Gelest, Inc. 85.0 parts by mass of n = 4, molecular weight 400-500 (catalog value)] and 100 parts by mass of toluene were added in the above formula (4), and stirred at room temperature. Platinum divinyltetramethyldisiloxane complex xylene solution [trade name: SIP6831.2, Gelest, Inc. 0.075 parts by mass] was added and heated to 60 ° C. using a mantle heater. Thereto, 53.1 parts by mass of (a3) monoallyl glycidyl isocyanuric acid [trade name: MA-DGIC, manufactured by Shikoku Kasei Kogyo Co., Ltd.] was added and dissolved. Then, it rose to 110 degreeC and stirred as it was for 4 hours.
Next, (a1) liquid polybutadiene dissolved in 50 parts by mass of toluene [trade name: NISSO PB G-1000, manufactured by Nippon Soda Co., Ltd., in formula (1), a> 0.85, R ¹ is —OH. 11.9 parts by weight of monovalent organic group having a number average molecular weight of 1250 to 1650 (catalog value)] was added dropwise to the reaction solution over 30 minutes, and the mixture was further stirred at 110 ° C. for 4 hours. The solvent of the obtained reaction mixture was distilled off under reduced pressure to obtain a silicone-modified epoxy resin (resin A).
The obtained silicone-modified epoxy resin was a colorless transparent liquid, and the epoxy equivalent was 395 g / eq.

[Synthesis Example 2]
Synthesis of Epoxy-Butadiene Resin Modified Silicone (Resin B) In a flask similar to that used in Synthesis Example 1, epoxidized polybutadiene [epoxy equivalent 203 g / eq, double bond equivalent 83 g / eq, number average molecular weight 1000] The epoxidized polybutadiene was dissolved by adding 123 parts by mass and 200 parts by mass of toluene. Platinum divinyltetramethyldisiloxane complex xylene solution [trade name: SIP6831.2, Gelest, Inc. 0.033 parts by mass] was added and heated to 60 ° C. using a mantle heater. Hydrogen polydimethylsiloxane dissolved in 70 parts by mass of toluene (trade name: DMS-H03, Gelest, Inc.). 6 parts by mass were added dropwise to the reaction solution over 30 minutes and further stirred at 110 ° C. for 4 hours. The solvent of the obtained reaction mixture was distilled off under reduced pressure to obtain a silicone-modified product (resin B) of an epoxidized butadiene resin.
The resulting silicone-modified product of the epoxidized butadiene resin was a colorless transparent liquid, and the epoxy equivalent was 213 g / eq.

[Synthesis Example 3]
Synthesis of diglycidyl isocyanuryl group-containing polydimethylsiloxane (resin C) In a flask similar to that used in Synthesis Example 1, hydrogen polydimethylsiloxane [trade name: DMS-H03, Gelest, Inc. 88.9 parts by mass and 111.1 parts by mass of monoallyl glycidyl isocyanuric acid [trade name: MA-DGIC, manufactured by Shikoku Kasei Kogyo Co., Ltd.] were added and stirred at room temperature. Platinum divinyltetramethyldisiloxane complex xylene solution [trade name: SIP6831.2, Gelest, Inc. 0.05 mass part] was added, and it heated at 110 degreeC using the mantle heater. Diglycidyl isocyanuryl group-containing polydimethylsiloxane (resin C) was obtained by stirring for 5 hours.
The obtained diglycidyl isocyanuryl group-containing polydimethylsiloxane was a colorless and transparent liquid, and the epoxy equivalent was 253 g / eq.

[Example 1, Comparative Examples 1-3]
Each component was mixed at the compounding ratio shown in Table 1 to obtain a resin composition.
The above resin composition is poured into a cell prepared by sandwiching a 2 mm thick silicone rubber sheet as a spacer between two glass plates, and cured by heating at 120 ° C. for 2 hours and at 150 ° C. for 5 hours. A plate-like cured product having a thickness of 2 mm was prepared.
The physical properties of the prepared plate-like cured product were evaluated by the following methods, and the results are shown in Table 1.

(1) Appearance The plate-like cured product was visually observed and evaluated for color and transparency.
(2) Transmittance (initial value)
The light transmittance at 400 nm of the plate-like cured product was measured using an ultraviolet-visible spectrophotometer (V-570) manufactured by JASCO Corporation. The evaluation criteria are as follows.
○: 80% or more, Δ: 70 to 79%, x: less than 70% (3) UV light transmittance The plate-shaped cured product is 100 using a cut filter that cuts light of a wavelength of 300 nm or less with a UV irradiation device. After irradiating with UV light for a time, the light transmittance at 400 nm was measured. The evaluation criteria are as follows.
(Circle): 80% or more, (triangle | delta): 70-79%, x: Less than 70% (4) Heat-resistant light transmittance The light transmittance of 400 nm after putting plate-shaped hardened | cured material into 150 degreeC oven for 200 hours was measured. The evaluation criteria are as follows.
○: 80% or more, Δ: 70 to 79%, x: less than 70% (5) Crack resistance Evaluation of whether cracks occur when a plate-like cured product having a size of 4 cm × 1 cm is bent at 90 °. did. The evaluation criteria are as follows.
○: No cracking occurred, ×: Cracking occurred (6) Surface stickiness When the plate-shaped cured product is put in a polyethylene bag at room temperature and brought into contact with the surface, it is determined whether the plate-shaped cured product sticks to the bag. evaluated. The evaluation criteria are as follows.
○: Not sticky, ×: Sticky

  The silicone-modified epoxy resin composition of the present invention is particularly suitable for a sealing composition and an adhesive for an optical semiconductor element such as an LED, and is extremely useful in such a field.

Claims (5)

(A) A silicone-modified epoxy resin composition containing a silicone-modified epoxy resin having a structure represented by the following general formula (1) and (B) an acid anhydride curing agent.

[In the formula (1), R ¹ each independently represents a monovalent organic group, R ² each independently represents a chain aliphatic hydrocarbon group having 1 to 10 carbon atoms, or a cyclic group having 3 to 10 carbon atoms. Y represents a group selected from an aliphatic hydrocarbon group and a phenyl group, and Y represents an organic group containing a cyclic ether group. X may be the same or different. a and b are positive numbers, a + b = 1 and 0.3 ≦ a <1, and n is 1 to 25. ]   The hydrosilylation reaction of (A) the silicone-modified epoxy resin is (a1) liquid polybutadiene, (a2) a hydrogenpolysiloxane compound, and (a3) a compound having an unsaturated bond and a cyclic ether group in one molecule. The silicone-modified epoxy resin composition according to claim 1, which is obtained by: The silicone-modified epoxy resin composition according to claim 2, wherein the compound (a3) having an unsaturated bond and a cyclic ether group in one molecule is represented by the following formula (2).

(In the formula, R ³ represents an unsaturated hydrocarbon group, and each R ⁴ independently represents a cyclic ether group.) The optical-semiconductor sealing composition containing the silicone modified epoxy resin composition in any one of Claims 1-3 . The optical-semiconductor element adhesive agent containing the silicone modified epoxy resin composition in any one of Claims 1-3 .