JP5615838B2 - フィッシャートロプシュ法における高速停止 - Google Patents
フィッシャートロプシュ法における高速停止 Download PDFInfo
- Publication number
- JP5615838B2 JP5615838B2 JP2011541380A JP2011541380A JP5615838B2 JP 5615838 B2 JP5615838 B2 JP 5615838B2 JP 2011541380 A JP2011541380 A JP 2011541380A JP 2011541380 A JP2011541380 A JP 2011541380A JP 5615838 B2 JP5615838 B2 JP 5615838B2
- Authority
- JP
- Japan
- Prior art keywords
- reactor
- catalyst
- gaseous
- fischer
- inlet section
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims description 43
- 239000003054 catalyst Substances 0.000 claims description 54
- 238000006243 chemical reaction Methods 0.000 claims description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 10
- 239000007789 gas Substances 0.000 description 17
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 14
- 239000011261 inert gas Substances 0.000 description 12
- 229910052751 metal Inorganic materials 0.000 description 11
- 239000002184 metal Substances 0.000 description 11
- 229930195733 hydrocarbon Natural products 0.000 description 8
- 150000002430 hydrocarbons Chemical class 0.000 description 8
- 229910017052 cobalt Inorganic materials 0.000 description 7
- 239000010941 cobalt Substances 0.000 description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 7
- 238000009792 diffusion process Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 230000009849 deactivation Effects 0.000 description 5
- 230000000737 periodic effect Effects 0.000 description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 4
- 230000000903 blocking effect Effects 0.000 description 4
- 239000012263 liquid product Substances 0.000 description 4
- 229910052748 manganese Inorganic materials 0.000 description 4
- 239000011572 manganese Substances 0.000 description 4
- 229910052720 vanadium Inorganic materials 0.000 description 4
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000012876 carrier material Substances 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 239000003345 natural gas Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000012438 extruded product Nutrition 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910000310 actinide oxide Inorganic materials 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
- C10G2/34—Apparatus, reactors
- C10G2/341—Apparatus, reactors with stationary catalyst bed
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08171752 | 2008-12-16 | ||
| EP08171752.2 | 2008-12-16 | ||
| PCT/EP2009/067091 WO2010069927A1 (en) | 2008-12-16 | 2009-12-14 | High-speed stop in a fischer-tropsch process |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012512228A JP2012512228A (ja) | 2012-05-31 |
| JP2012512228A5 JP2012512228A5 (enExample) | 2014-06-05 |
| JP5615838B2 true JP5615838B2 (ja) | 2014-10-29 |
Family
ID=40651417
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011541380A Expired - Fee Related JP5615838B2 (ja) | 2008-12-16 | 2009-12-14 | フィッシャートロプシュ法における高速停止 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20100184874A1 (enExample) |
| EP (1) | EP2366001A1 (enExample) |
| JP (1) | JP5615838B2 (enExample) |
| AU (1) | AU2009327203B2 (enExample) |
| MY (1) | MY169287A (enExample) |
| WO (1) | WO2010069927A1 (enExample) |
| ZA (1) | ZA201103313B (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8980194B2 (en) | 2009-12-28 | 2015-03-17 | Shell Oil Company | Stacked catalyst bed for Fischer-Tropsch |
| MY165436A (en) | 2011-06-28 | 2018-03-22 | Shell Int Research | Stacked catalyst bed for fischer-tropsch |
| RU2014102606A (ru) | 2011-06-28 | 2015-08-10 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Составной слой катализатора для процесса фишера-тропша |
| AU2014363104B2 (en) * | 2013-12-11 | 2017-12-07 | Sasol Technology Proprietary Limited | A method of shutting down an operating three-phase slurry bubble column reactor |
| AU2015233471B2 (en) | 2014-03-21 | 2018-03-15 | Shell Internationale Research Maatschappij B.V. | Catalyst |
| WO2016201218A2 (en) * | 2015-06-12 | 2016-12-15 | Velocys, Inc. | Synthesis gas conversion process |
| AU2022324146A1 (en) * | 2021-08-05 | 2024-02-08 | Infinium Technology, Llc | Production and use of liquid fuel as a hydrogen and/or syngas carrier |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2177318B (en) * | 1985-07-02 | 1989-01-18 | Shell Int Research | Catalytic conversion of gas or liquid in a multitube reactor |
| GB2204055B (en) * | 1987-04-29 | 1992-01-02 | Shell Int Research | Process for the preparation of hydrocarbons |
| GB2223237B (en) * | 1988-07-21 | 1992-09-16 | Shell Int Research | Shut-down process for a fischer-tropsch reactor, and said reactor |
| GB9014417D0 (en) * | 1990-06-28 | 1990-08-22 | Shell Int Research | A process for the preparation of hydrocarbons,a process for the shutdown of a reactor for carrying out said process and a reactor to be used therefor |
| GB2246576A (en) | 1990-06-28 | 1992-02-05 | Shell Int Research | A process for the preparation of hydrocarbons, a process for the shutdown of a reactor for carrying out said process and a reactor to be used therefor |
| US6512017B1 (en) * | 1999-10-14 | 2003-01-28 | Sasol Technology (Proprietary) Limited | Handling of a catalyst |
| US6869978B2 (en) * | 1999-11-17 | 2005-03-22 | Conocophillips Company | Pressure swing catalyst regeneration procedure for Fischer-Tropsch catalyst |
| ATE271418T1 (de) * | 2000-09-26 | 2004-08-15 | Shell Int Research | Stabförmiger einsatz für reaktionsrohre |
| JP2003292972A (ja) * | 2002-03-29 | 2003-10-15 | Nippon Steel Corp | 合成ガスから炭化水素を製造する装置の停止方法 |
| ITMI20031776A1 (it) * | 2003-09-18 | 2005-03-19 | Enitecnologie Spa | Procedimento per il caricamento di un catalizzatore in un reattore adatto a reazioni in fase eterogenea |
| JP2007505669A (ja) * | 2003-09-19 | 2007-03-15 | エレメント シックス リミテッド | 人工関節 |
| US6974842B1 (en) * | 2004-11-22 | 2005-12-13 | Conocophillips Company | Process for catalyst recovery from a slurry containing residual hydrocarbons |
| FR2878845B1 (fr) * | 2004-12-03 | 2007-01-12 | Inst Francais Du Petrole | Procede d'interruption provisoire d'une reaction de type fischer-tropsch dans un reacteur a lit triphasique |
| US7935734B2 (en) * | 2005-07-08 | 2011-05-03 | Anna Lee Tonkovich | Catalytic reaction process using microchannel technology |
| DE102005050526A1 (de) * | 2005-10-21 | 2007-04-26 | Choren Industries Gmbh | Verfahren zum Haltebetrieb einer Fischer-Tropsch-Synthese |
-
2009
- 2009-12-14 JP JP2011541380A patent/JP5615838B2/ja not_active Expired - Fee Related
- 2009-12-14 MY MYPI2011002227A patent/MY169287A/en unknown
- 2009-12-14 AU AU2009327203A patent/AU2009327203B2/en not_active Ceased
- 2009-12-14 WO PCT/EP2009/067091 patent/WO2010069927A1/en not_active Ceased
- 2009-12-14 EP EP09768095A patent/EP2366001A1/en not_active Withdrawn
- 2009-12-15 US US12/638,625 patent/US20100184874A1/en not_active Abandoned
-
2011
- 2011-05-06 ZA ZA2011/03313A patent/ZA201103313B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ZA201103313B (en) | 2012-01-25 |
| WO2010069927A1 (en) | 2010-06-24 |
| AU2009327203A1 (en) | 2010-06-24 |
| EP2366001A1 (en) | 2011-09-21 |
| AU2009327203B2 (en) | 2012-08-23 |
| JP2012512228A (ja) | 2012-05-31 |
| MY169287A (en) | 2019-03-21 |
| US20100184874A1 (en) | 2010-07-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5602760B2 (ja) | フィッシャー・トロプシュ法における高速停止 | |
| JP5615838B2 (ja) | フィッシャートロプシュ法における高速停止 | |
| JP4181876B2 (ja) | 分割フィード水素化分解／水素化処理を用いるフィッシャー−トロプシュワックスの改質法 | |
| US20100160462A1 (en) | High-speed stop in a fischer-tropsch process | |
| AU2012277855A1 (en) | Stacked catalyst bed for Fischer-Tropsch | |
| US20100184873A1 (en) | Multi stage process for producing hydrocarbons from syngas | |
| AU2010338293B2 (en) | Stacked catalyst bed for Fischer-Tropsch | |
| US7855234B2 (en) | Fischer-tropsch process and reactor assembly | |
| AU2009331536B2 (en) | Integrated process and parallel reactor arrangement for hydrocarbon synthesis | |
| AU2008328910B2 (en) | Catalyst support | |
| AU2003246557B2 (en) | Reactor system for several reactor units in parallel | |
| AU2012277857A1 (en) | Stacked catalyst bed for Fischer-Tropsch |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20121207 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20131225 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140121 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140418 |
|
| A524 | Written submission of copy of amendment under article 19 pct |
Free format text: JAPANESE INTERMEDIATE CODE: A524 Effective date: 20140418 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20140812 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20140910 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5615838 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| LAPS | Cancellation because of no payment of annual fees |