JP5590445B2 - Manufacturing method of sign board - Google Patents

Manufacturing method of sign board Download PDF

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JP5590445B2
JP5590445B2 JP2010089282A JP2010089282A JP5590445B2 JP 5590445 B2 JP5590445 B2 JP 5590445B2 JP 2010089282 A JP2010089282 A JP 2010089282A JP 2010089282 A JP2010089282 A JP 2010089282A JP 5590445 B2 JP5590445 B2 JP 5590445B2
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layer
phosphorescent
thermosetting resin
substrate
plate
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JP2011221219A (en
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隆志 神池
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Nok Corp
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Description

本発明は、避難誘導、室内及び屋外の案内などの標識に用いられる標識板の製造方法に関し、特に、屋外の光源の無い道路地点の標識として有用な標識板の製造方法に関する。 The present invention relates to a method of manufacturing a sign board used for signs such as evacuation guidance, indoor and outdoor guidance, and more particularly to a method of manufacturing a sign board useful as a sign for a road spot without an outdoor light source.

従来、屋外用途の蓄光標識板としては以下の内容のものが知られている。(特許文献1)
これまでの屋外用途の蓄光標識板は、蓄光材に水が触れると、蓄光材が酸化し、蓄光材の発光輝度が低下する問題を発生した。
そこで、残光性を有する蓄光材を含有した蓄光板を基板に設け、この蓄光板の前面側に保護板を設けると共に、蓄光板と保護板との間に介在させて蓄光板と保護板とを接着するとともに、蓄光板の周囲であり、かつ基板と保護板との間に介在させて基板と保護板とを接着する接着部を設ける態様としている。
Conventionally, the thing of the following content is known as a luminous sign board for outdoor use. (Patent Document 1)
Conventional phosphorescent sign boards for outdoor use have a problem that when the phosphorescent material is in contact with water, the phosphorescent material is oxidized and the luminous luminance of the phosphorescent material is lowered.
Therefore, a phosphorescent plate containing a phosphorescent material having afterglow is provided on the substrate, a protective plate is provided on the front side of the phosphorescent plate, and the phosphorescent plate and the protective plate are interposed between the phosphorescent plate and the protective plate. In addition, an adhesive portion is provided around the phosphorescent plate and provided between the substrate and the protective plate so as to bond the substrate and the protective plate.

そして、この接着部が、蓄光板の周囲であり、かつ基板と保護板との間に設けられ、蓄光板の周囲を囲うようにして基板と保護板とを接着しているので、蓄光板が基板と保護板との間から露出する部分がなくなる。
従って、蓄光板の厚みが厚く、基板と保護板との間が開いていても、基板と保護板とを接着して標示板としての形を保ちつつ、雨水などによる水分の浸入を蓄光板まで到達しないようにして、蓄光材の劣化を防ぐことにより屋外用途に使用可能とした蓄光式標示板及び製造法である。
And since this adhesion part is the circumference of the phosphorescent plate and is provided between the substrate and the protective plate, and the substrate and the protective plate are bonded so as to surround the phosphorescent plate, the phosphorescent plate is There is no portion exposed between the substrate and the protective plate.
Therefore, even if the phosphorescent plate is thick and the space between the substrate and the protective plate is open, the substrate and the protective plate are bonded together to maintain the shape as a sign plate, and moisture intrusion to the phosphorescent plate can be achieved. A phosphorescent marking plate and a manufacturing method that can be used for outdoor use by preventing the phosphorescent material from deteriorating without reaching.

しかし、この製造法は、減圧下での加工が必要である為、特殊な装置が必要となる欠点があった。
また、蓄光板は、樹脂、インク剤でシート状にしているが、蓄光材粒径100〜200μmを樹脂、インク剤で板状に加工することは困難であった。
更に、接着部が基板の全面を覆う形になっていない為、基板と蓄光板との界面に水分が滲入する余地が残されていると共に、蓄光標識板を支柱に取り付ける際に、緩みなく固定する事が困難であった。
However, since this manufacturing method requires processing under reduced pressure, there is a drawback that a special apparatus is required.
Moreover, although the phosphorescent plate is made into a sheet shape with a resin and an ink agent, it is difficult to process the phosphorescent material particle size of 100 to 200 μm into a plate shape with the resin and the ink agent.
In addition, since the adhesive part does not cover the entire surface of the substrate, there is room for moisture to penetrate into the interface between the substrate and the phosphorescent plate, and it is fixed without loosening when the phosphorescent marker plate is attached to the column. It was difficult to do.

更にまた、意匠を含む標示面の保護が不十分であるため、意匠を含む標示面が、早期に大気中の塵埃により汚れる問題を惹起した。   Furthermore, since the marking surface including the design is insufficiently protected, the marking surface including the design is apt to be contaminated with dust in the air at an early stage.

特開2006−162799号公報JP 2006-162799 A

本発明は上記したような事情に鑑みてなされたものであり、屋外の風雨に曝される環境下においても、蓄光層に水分が滲入することはなく、長期間に渡って夜間の視認性が良い蓄光標識機能を維持すると共に、取り付けが確実容易で、特別な製造設備を必要としないため、安価に製造出来る標識板の製造方法を提供することを目的とする。 The present invention has been made in view of the circumstances as described above, and even in an environment exposed to outdoor wind and rain, moisture does not penetrate into the phosphorescent layer, and nighttime visibility is maintained over a long period of time. An object of the present invention is to provide a method for manufacturing a sign plate that can be manufactured at low cost because it maintains a good phosphorescent sign function and is easily and reliably attached and does not require special manufacturing equipment.

上記目的を達成するために本発明に係る標識板の製造方法にあっては、熱盤上に、意匠を施した面を上にして透明層を配置する工程と、
前記透明層上に内型及び外型を配置する工程と、
前記内型内に、蓄光材が練り込まれた熱硬化性樹脂材料を流し込む工程と、
前記蓄光材が沈降して蓄光層と熱硬化性樹脂層とに分離した後、白色反射層を一方の面に形成した基板を、前記白色反射層が前記蓄光層側に配置される様に、前記蓄光層と前記熱硬化性樹脂層との間に配置する工程と、
前記内型を取り除き、前記内型が取り除かれた空所に前記熱硬化性樹脂層の一部を流し込むことにより被覆層を形成する工程と、
前記熱硬化性樹脂層が硬化した後、前記外型を取り外す工程と、
前記熱盤上から製品を取り出した後、不要な個所を裁断する仕上げ工程とを備えたことを特徴とする。
In the manufacturing method of the sign board according to the present invention to achieve the above object, a step of placing a transparent layer with the design on the hot platen,
Arranging an inner mold and an outer mold on the transparent layer;
Pouring a thermosetting resin material kneaded with a phosphorescent material into the inner mold;
After the phosphorescent material is settled and separated into a phosphorescent layer and a thermosetting resin layer, a substrate having a white reflective layer formed on one surface is arranged such that the white reflective layer is disposed on the phosphorescent layer side. A step of arranging between the phosphorescent layer and the thermosetting resin layer;
Removing the inner mold and forming a coating layer by pouring a part of the thermosetting resin layer into the void from which the inner mold has been removed;
Removing the outer mold after the thermosetting resin layer is cured;
And a finishing step of cutting unnecessary portions after taking out the product from the hot platen.

本発明は、以下に記載される効果を奏する。
請求項記載の発明の標識板によれば、長期間に渡って夜間の視認性が良い蓄光標識機能を発揮する標識板を、特別な製造設備を必要とせず、安価に製造出来る。
請求項記載の発明の標識板の製造方法によれば、基板を蓄光層と熱硬化性樹脂層の間に、容易に配置する事が出来る。
The present invention has the following effects.
According to the sign plate of the first aspect of the present invention, a sign plate that exhibits a phosphorescent sign function with good nighttime visibility over a long period of time can be produced at low cost without requiring special production equipment.
According to the manufacturing method of the sign board of the invention described in claim 2 , the substrate can be easily disposed between the phosphorescent layer and the thermosetting resin layer.

請求項記載の発明の標識板の製造方法によれば、耐久性の良好な標識板とする事が出来る。

According to the manufacturing method of the sign plate of the invention described in claim 3, it is possible to obtain a sign plate with good durability.

本発明に係る標識板の断面図。Sectional drawing of the sign board which concerns on this invention. 図1の標識板を地点標として使用した状態の部分断面図。The fragmentary sectional view of the state which used the marker board of FIG. 1 as a point marker. 熱盤上に配置した透明フィルム上に配置した金型内に材料を注入した状態を示す断面図。Sectional drawing which shows the state which inject | poured material into the metal mold | die arrange | positioned on the transparent film arrange | positioned on a heating board. 図3の材料が蓄光層と熱硬化性樹脂層に分離した状態を示す断面図。Sectional drawing which shows the state which the material of FIG. 3 isolate | separated into the luminous layer and the thermosetting resin layer. 白色塗装基板が蓄光層と熱硬化性樹脂層との間に配置された状態を示す断面図。Sectional drawing which shows the state by which the white coating substrate was arrange | positioned between the luminous layer and the thermosetting resin layer. 図5の内型を取り外した状態の断面図。Sectional drawing of the state which removed the inner mold | type of FIG. 図6の熱硬化性樹脂層の一部が、内型の取り除かれた空所に流れ込んだ状態を示す断面図。FIG. 7 is a cross-sectional view showing a state in which a part of the thermosetting resin layer of FIG. 図7の外型を取り除いた断面図。Sectional drawing which removed the outer mold | type of FIG. 図8の熱盤を取り除いた断面図。Sectional drawing which removed the heat disc of FIG.

以下、本発明を実施するための最良の形態について説明する。
まず、図1に基づき本発明の形態を説明する。
本発明に係る標識板10は、基板1の一方の面11に設けた白色反射層2と、この白色反射層2側に設けた熱硬化性樹脂中に蓄光材が存在する蓄光層3と、この蓄光層3の白色反射層2と反対側の面側に存在する意匠4と、この意匠4を含む蓄光層3表面を覆う透明層5とより構成されている。
Hereinafter, the best mode for carrying out the present invention will be described.
First, the form of this invention is demonstrated based on FIG.
The sign board 10 according to the present invention includes a white reflective layer 2 provided on one surface 11 of the substrate 1, a phosphorescent layer 3 in which a phosphorescent material is present in a thermosetting resin provided on the white reflective layer 2 side, The phosphorescent layer 3 is composed of a design 4 existing on the side opposite to the white reflective layer 2 and a transparent layer 5 covering the surface of the phosphorescent layer 3 including the design 4.

そして、基板1、白色反射層2及び蓄光層3の各側面及び基板1の他方の面12の全面は、熱硬化性樹脂の被覆層6により覆われている。
基板1は、本実施の形態では、アルミニウム板としたが、防錆加工を施した鉄板、アクリル板、ステンレス板とすることもできる。
この基板1には、複数の貫通孔13がその周囲に形成されている。
そして、この貫通孔13により、蓄光層3と被覆層6とが連通している。
このことにより、基板1、蓄光層3及び被覆層6の一体化が、より確実に行える。
また、この基板1の一方の面11には、白色塗料が塗布され、白色反射層2を形成している。
Each side surface of the substrate 1, the white reflective layer 2, and the phosphorescent layer 3 and the entire surface of the other surface 12 of the substrate 1 are covered with a thermosetting resin coating layer 6.
In the present embodiment, the substrate 1 is an aluminum plate, but may be an iron plate, an acrylic plate, or a stainless plate subjected to rust prevention.
The substrate 1 has a plurality of through holes 13 formed around it.
The luminous layer 3 and the covering layer 6 communicate with each other through the through hole 13.
Thereby, the integration of the substrate 1, the phosphorescent layer 3 and the coating layer 6 can be performed more reliably.
In addition, a white paint is applied to one surface 11 of the substrate 1 to form a white reflective layer 2.

また、熱硬化性樹脂としては、ポリウレタン樹脂、エポキシ樹脂、ポリエステル樹脂、アクリル樹脂等が使用可能であるが、ポリウレタン樹脂が好ましい。
本実施形態で使用するウレタン材は、注型ウレタン材であり、プレポリマーと言われる反応基(−NCO)を持つ主材と硬化剤(アミン系)とが反応してポリウレタンになるものである。この中でも、特に、透明無黄変熱硬化ウレタン材が好ましい。
Moreover, as a thermosetting resin, a polyurethane resin, an epoxy resin, a polyester resin, an acrylic resin, etc. can be used, but a polyurethane resin is preferable.
The urethane material used in the present embodiment is a cast urethane material, and a main material having a reactive group (—NCO) called a prepolymer and a curing agent (amine system) react to become polyurethane. . Among these, a transparent non-yellowing thermosetting urethane material is particularly preferable.

また、蓄光層3に使用される蓄光材としては、例えば、酸化ストロンチウム、酸化アルミニウム、酸化希土類等を使用することができるが、粒径100〜800μmのアルミン酸系蓄光材であることが好ましい。
そして、蓄光層3の表面には、蓄光材が、1,000g/平方メートル以上存在することが望ましい。
このことにより、夜間の間、十分な発光輝度を維持出来ると共に、日没後、12時間で15mcd/平方メートル以上を維持出来る。
Moreover, as a luminous material used for the luminous layer 3, although strontium oxide, an aluminum oxide, rare earth oxide etc. can be used, for example, it is preferable that it is an aluminate type luminous material with a particle size of 100-800 micrometers.
And it is desirable that the phosphorescent material is present on the surface of the phosphorescent layer 3 at 1,000 g / square meter or more.
This makes it possible to maintain sufficient emission luminance during the night and to maintain 15 mcd / square meter or more in 12 hours after sunset.

また、透明層5は、THV(テトラフルオロエチレン・ヘキサフルオロプロピレン・ビニリデンフロラィド共重合体)等のフツ素系透明フィルム、透明無黄変ウレタンフィルム(50〜300μm)の外側に光触媒層(酸化チタン0.1〜0.3μm)、下引き層(光触媒から耐候性透明フィルムの保護及び光触媒層と耐候性透明フィルムの接着剤で厚み1〜3μm)をコーティングし、内側に(蓄光層3側に)意匠4を印刷したもので、高透明性(UV領域の光も透過)、防水性、耐候性を有するフィルムである。   The transparent layer 5 is a photocatalytic layer (on the outside of a fluorine-based transparent film such as THV (tetrafluoroethylene / hexafluoropropylene / vinylidene fluoride copolymer)) or a transparent non-yellowing urethane film (50 to 300 μm). Titanium oxide 0.1 to 0.3 μm), undercoat layer (protection of weatherproof transparent film from photocatalyst and thickness of 1 to 3 μm with adhesive of photocatalyst layer and weatherable transparent film), coated inside (phosphorescent layer 3 It is a film having the design 4 printed on the side and having high transparency (also transmits light in the UV region), waterproofness, and weather resistance.

このため、透明層5表面は、大気中の塵埃により汚れる問題を効果的に回避出来る。
この様な構成を備えた標識板10は、例えば、図2に示す様な地点標として使用される。
そして、標識板10は、被覆層6が支柱8に接する形で、取り付け金具81により固定されるため、標識板10の支柱8への取り付けが確実容易に行える。
すなわち、標識板10が過大に締め付け固定されたとしても、被覆層6が緩衝材となる為、標識板10が損傷する事は無い。
For this reason, the problem that the surface of the transparent layer 5 is contaminated by dust in the atmosphere can be effectively avoided.
The sign board 10 having such a configuration is used as a point mark as shown in FIG. 2, for example.
And since the sign board 10 is fixed with the attachment bracket 81 in the form in which the coating layer 6 is in contact with the support pillar 8, the attachment of the sign board 10 to the support pillar 8 can be performed easily and reliably.
That is, even if the sign plate 10 is excessively tightened and fixed, the cover layer 6 serves as a cushioning material, so that the sign plate 10 is not damaged.

ついで、本発明に係る標識板10の製造方法を図3乃至図9に基づき説明する。
まず、図3に示す様に、90〜140℃に熱した熱盤9上に、意匠4を施した面を上にして耐候性透明フィルムの透明層5を配置する。
ついで、この透明層5上に内型91及び外型92を配置する。
この、内型91及び外型92は、矩形形状を呈している。
Next, a method for manufacturing the sign board 10 according to the present invention will be described with reference to FIGS.
First, as shown in FIG. 3, a transparent layer 5 of a weather-resistant transparent film is disposed on a hot platen 9 heated to 90 to 140 ° C. with the surface provided with the design 4 facing up.
Next, an inner mold 91 and an outer mold 92 are disposed on the transparent layer 5.
The inner mold 91 and the outer mold 92 have a rectangular shape.

ついで、この内型91内に、透明無黄変熱硬化ウレタンプレポリマー100部、アミン系硬化剤10部、蓄光材(アルミン酸系蓄光材で粒径100〜300μm)150部、反応促進剤0.02部を混合、撹拌した熱硬化性樹脂材料31を流し込む。
ついで、図4に示す様に、注入後2〜3分経過すると、熱硬化性樹脂材料31は、比重の大きい蓄光材が沈降して蓄光層3を形成し、蓄光材を殆ど含まない熱硬化性樹脂層61とに分離する。
Next, in this inner mold 91, 100 parts of a transparent non-yellowing thermosetting urethane prepolymer, 10 parts of an amine-based curing agent, 150 parts of a phosphorescent material (aluminic acid-based phosphorescent material having a particle size of 100 to 300 μm), a reaction accelerator 0 .02 parts of mixed and stirred thermosetting resin material 31 is poured.
Next, as shown in FIG. 4, when 2 to 3 minutes have elapsed after injection, the thermosetting resin material 31 settles the phosphorescent material having a large specific gravity to form the phosphorescent layer 3, and thermosets hardly contain the phosphorescent material. The resin layer 61 is separated.

この段階で、図5に示す様に、白色塗料が塗布された白色反射層2を一方の面11に形成したアルミ材製の基板1を、蓄光層3と熱硬化性樹脂層61との間に配置する。
この基板1には、透明無黄変熱硬化ウレタンプレポリマーである熱硬化性樹脂31が通過できる貫通孔13が形成されている為、熱硬化性樹脂材料31上に基板1を乗せ、荷重を掛けることにより、基板1は、蓄光層3と熱硬化性樹脂層61との間に留まる形で、配置される。
At this stage, as shown in FIG. 5, the aluminum substrate 1 having the white reflective layer 2 coated with the white paint formed on one surface 11 is placed between the phosphorescent layer 3 and the thermosetting resin layer 61. To place.
Since this substrate 1 has a through hole 13 through which a thermosetting resin 31 that is a transparent non-yellowing thermosetting urethane prepolymer can pass, the substrate 1 is placed on the thermosetting resin material 31 and a load is applied. By hanging, the substrate 1 is disposed so as to remain between the phosphorescent layer 3 and the thermosetting resin layer 61.

これは、熱盤9に近い蓄光層3の透明無黄変熱硬化ウレタンプレポリマーは、硬化が進むが、熱硬化性樹脂層61は、蓄光層3の蓄光材が断熱材の役割も果たし、熱盤9の熱が伝わり難いため、硬化が進まない為である。   This is because the transparent non-yellowing thermosetting urethane prepolymer of the phosphorescent layer 3 close to the hot platen 9 is cured, but the thermosetting resin layer 61 also serves as a heat insulating material. This is because the heat of the hot platen 9 is difficult to be transmitted and the curing does not proceed.

ついで、図6に示す様に、内型91を取り除くと、図7に示す様に、内型91が取り除かれた空所911に未硬化の熱硬化性樹脂層61の一部が流れ込み被覆層6を形成する。
この際、蓄光層3は硬化が進んでいる為、蓄光層3の一部が空所911に流れ込む事は無い。
Next, as shown in FIG. 6, when the inner mold 91 is removed, as shown in FIG. 7, a part of the uncured thermosetting resin layer 61 flows into the void 911 from which the inner mold 91 has been removed. 6 is formed.
At this time, since the phosphorescent layer 3 is hardened, a part of the phosphorescent layer 3 does not flow into the empty space 911.

ついで、図8に示す様に、熱硬化性樹脂層61が硬化した後、外型92を取り外す。   Next, as shown in FIG. 8, after the thermosetting resin layer 61 is cured, the outer mold 92 is removed.

最後に、図9に示す様に、20〜30分経過後に、熱盤9上から製品を取り出した後、不要な個所を裁断する仕上げを行うことにより、図1に示す標識板10が得られる。
尚、仕上げ工程の後、製品を80℃で12時間の熱処理を施すことにより、熱硬化性樹脂材料に十分な機械的強度を与える事が出来る。
Finally, as shown in FIG. 9, after 20 to 30 minutes have elapsed, the product is taken out from the hot platen 9 and then finished by cutting unnecessary portions, whereby the sign board 10 shown in FIG. 1 is obtained. .
In addition, sufficient mechanical strength can be given to a thermosetting resin material by heat-processing a product for 12 hours at 80 degreeC after a finishing process.

上述の発明は、視線誘導標、案内板や看板等に利用可能である。   The above-described invention can be used for a gaze guidance mark, a guide plate, a signboard, and the like.

1 基板
2 白色反射層
3 蓄光層
4 意匠
5 透明層
6 被覆層
7 防汚層
8 支柱
9 熱盤
10 標識板
11 一方の面
12 他方の面
13 貫通孔
31 熱硬化性樹脂材料
61 熱硬化性樹脂層
91 内型
92 外型
DESCRIPTION OF SYMBOLS 1 Board | substrate 2 White reflection layer 3 Phosphorescent layer 4 Design 5 Transparent layer 6 Covering layer 7 Antifouling layer 8 Support | pillar 9 Heating board 10 Marking board 11 One surface 12 The other surface 13 Through-hole 31 Thermosetting resin material 61 Thermosetting Resin layer 91 Inner mold 92 Outer mold

Claims (3)

熱盤(9)上に、意匠(4)を施した面を上にして透明層(5)を配置する工程と、前記透明層(5)上に内型(91)及び外型(92)を配置する工程と、前記内型(91)内に、蓄光剤(32)が練り込まれた熱硬化性樹脂材料(31)を流し込む工程と、  A step of disposing a transparent layer (5) on the hot platen (9) with the surface subjected to the design (4) facing upward, and an inner mold (91) and an outer mold (92) on the transparent layer (5) And a step of pouring a thermosetting resin material (31) in which a phosphorescent agent (32) is kneaded into the inner mold (91),
前記蓄光剤が沈降して蓄光層(3)と熱硬化性樹脂層(61)とに分離した後、白色反射層(2)を一方の面(11)に形成した基板(1)を、前記白色反射層(2)が前記蓄光層(3)側に配置される様に、前記蓄光層(3)と前記熱硬化性樹脂層(61)との間に配置する工程と、After the phosphorescent agent settles and separates into the phosphorescent layer (3) and the thermosetting resin layer (61), the substrate (1) on which the white reflective layer (2) is formed on one surface (11), A step of arranging between the phosphorescent layer (3) and the thermosetting resin layer (61) such that a white reflective layer (2) is arranged on the phosphorescent layer (3) side;
前記内型(91)を取り除き、前記内型(91)が取り除かれた空所(911)に前記熱硬化性樹脂層(61)の一部を流し込むことにより被覆層(6)を形成する工程と、Removing the inner mold (91) and forming a coating layer (6) by pouring a part of the thermosetting resin layer (61) into the void (911) from which the inner mold (91) has been removed. When,
前記熱硬化性樹脂層(61)が硬化した後、前記外型(92)を取り外す工程と、Removing the outer mold (92) after the thermosetting resin layer (61) is cured;
前記熱盤(9)上から製品を取り出した後、不要な個所を裁断する仕上げ工程とを備えた標識板の製造方法。A marking plate manufacturing method comprising: a finishing step of cutting an unnecessary portion after taking out a product from the hot platen (9).
前記基板(1)には、前記熱硬化性樹脂(31)が通過できる貫通孔(13)が形成されていることを特徴とする請求項1に記載の標識板の製造方法。The sign board manufacturing method according to claim 1, wherein a through hole (13) through which the thermosetting resin (31) can pass is formed in the substrate (1). 前記仕上げ工程の後、製品に熱処理を施すことを特徴とする請求項1まThe product is subjected to heat treatment after the finishing step.
たは2記載の標識板の製造方法。Or a method for producing a sign board according to 2.
JP2010089282A 2010-04-08 2010-04-08 Manufacturing method of sign board Expired - Fee Related JP5590445B2 (en)

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JP6849311B2 (en) * 2016-02-29 2021-03-24 デンカ株式会社 Fluorine-based resin sheet containing a phosphorescent phosphor, a laminate using this, a phosphorescent sheet, an outdoor phosphorescent label

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