JP5483464B2 - Power generation electrode body - Google Patents

Description

  The present invention relates to a generator and a fuel cell method characterized in that no fuel is required for power generation and operation throughout the day, 24 hours a day, and there is no problem of large fuel costs.

  Photovoltaic solar cells are a kind of renewable energy that generates electricity only in the daytime, and are a power generation method that directly converts solar energy into electric power, and have environmental and economic advantages.

  Wind power generation has low greenhouse gas emissions, requires no operating fuel, can be used continuously, and has excellent economic effects.

  It has been disclosed that a power source for lighting a light emitting diode can be obtained using only water and an electrode without using an electrolyte, and a self-charging secondary battery is made.

  Japanese Patent Laid-Open No. 2005-19367

  However, in the technique of Patent Literature 1, carbon fiber or C is used as the positive electrode of the electrode, Zn alloy or Fe is used as the negative electrode, and an electromotive force is obtained simply by immersing in water, but an ore receiver is used to obtain a high electromotive force. In need of.

  However, solar power generation is possible only during the day, not during the night, and the output varies depending on the weather. In order to generate electricity, a large number of solar cell panels are installed, so that a large area is required. Further, a large amount of energy is required for manufacturing the solar cell panel, and a large amount of oil is consumed.

  In addition, wind power generators of wind power generation have output voltage and power factor that fluctuate regardless of demand as the wind condition and wind speed fluctuate. Therefore, the supplied power is unstable and there is a risk of causing noise damage to the surroundings.

  The present invention has been made in view of the problems of the prior art, and even if the sunlight is not illuminated at night or the wind does not blow, there is no need for fuel for operation. An object of the present invention is to provide an electrode body capable of generating power for 24 hours in the presence of water vapor, in water, hot water, seawater, and sunlight, and for 24 hours regardless of daytime or nighttime.

  The electrode body for power generation according to the present invention has at least two kinds of metals having different electromotive force levels in the electrochemical potential row, arranged in contact with each other in the presence of water vapor (in the air), underwater (seawater, water, hot water). The electrode potential difference is a driving force for causing an electrochemical reaction when immersed in snow, ice, seawater with floating ice, or frozen ice), and continues to exert antibacterial or antifungal effects, as long as there is water or water vapor. It has the following generator function and fuel cell function.

  On the other hand, in the power generation electrode body of the present invention, at least two kinds of metal electrodes having different electromotive force levels in the electrochemical potential sequence are arranged apart from each other, contacted in the presence of water vapor (in the air), solar It has been discovered that power generation can be achieved by immersion in light, wind, or seawater, water, hot water, seawater with floating ice, or frozen ice. Different types of metals in the electrochemical potential series (electrochemical forces) with an electromotive force level are classified into an anodic material (positive side from the electrochemical potential series) and a cathodic material (under the electrochemical potential series). The negative electrode potential difference is the combination of the negative electrode potential difference, and as a driving force for the electrochemical reaction, the flow of electrons constantly occurs from the negative (cathode) electrode to the positive (anode) electrode. Generate and generate electricity.

  In the electrode body of the present invention, the potential is constantly maintained, static electricity flows, electric field formation, the cathode sucks metal ions and microorganisms to the electrode surface, sterilization by crevice corrosion and electric discharge sterilization, electrochemical sterilization, In addition, fine metals and metal ions floating in the electrolyte solution in the air are transported or collected in chemical parts.

  Different types of metals with different electrochemical potential sequences are listed in Table 1, but when metals with different electromotive force levels are contacted or immersed in water in the presence of water vapor, these One direction is an anode and the other is a cathode (anode, cathode), and a potential difference is generated between the two, and this electrochemical reaction exerts a power generation effect. The larger the difference in electromotive force level, the more the electrochemical reaction of the reaction in which the electric field formation, the generation of static electricity, the voltage, the current, etc. produce larger values.

  The metal is potassium, sodium, magnesium, magnesium alloy, titanium oxide, sulfur, aluminum, aluminum / manganese alloy, cadmium plated steel, 80 tin / 20 tin plated steel, galvanized iron / steel, tin, zinc, zinc alloy, Chrome, iron, soft iron or steel, soft iron or steel, tin, brass, duralumin, lead, chrome plated steel, soft solder, nickel base chrome plated steel, tin plated steel, high chrome stainless steel, 12% chromium stainless steel, copper, It is preferable that they are different kinds of metals among copper alloy, silver solder, copper alloy, nickel-plated steel, silver, rhodium-undercoated copper, silver / gold alloy, charcoal, activated carbon, palladium, platinum, and gold.

  The following experiment was carried out by rearranging the above metals for 3 years, rearranging different types of metals, fixing at least two different types of metals on the surface of cloth, resin or charcoal cloth, and fixing them in parallel. Separate a different kind of metal, insert a cloth, resin or charcoal cloth between the metals, stack the metal on the laminate, adhere to a larger cloth, resin or charcoal cloth, and immerse in water to make a water battery. As long as there is water, it has a power generation function that repeats discharging and charging, and generates static electricity and keeps current flowing, confirming that it is an electric field formation, generator, and fuel cell.

  The voltage, current, and resistance generated in the above experiment always change. When the metal has a small electrode potential difference between at least two different metals, the generated voltage and current are small, and when the electrode potential difference is large, the voltage is large. It is confirmed that the current value is generated and the static electricity is generated at the same time, and is used for microbial control of microbial growth inhibition, sterilization, and growth and proliferation.

  The area of one of the metals having a low electromotive force with a different electrochemical potential sequence is preferably larger than the other area of the metal.

  One of the metals is preferably disposed on one surface of a cloth, resin or charcoal cloth, and the other of the metals is preferably disposed on the other surface of the cloth, resin or charcoal cloth.

  It is preferable that at least one of the metals is formed in a lattice shape, a net shape, or a spiral shape on the surface of the cloth, resin, or charcoal cloth.

  It is preferable that one side of the metal is arranged so as to be surrounded by the other side of the metal on one side of the cloth, resin or charcoal cloth.

  On one side of the cloth, resin or charcoal cloth, one of the metals is preferably arranged side by side on the other side of the metal.

  It is preferable that the cloth, resin or charcoal cloth on which the metal is formed are laminated or parallel.

  The cloth, resin or charcoal cloth on which the metal is formed is preferably formed in a cylindrical shape.

  The metal may be formed on both surfaces of paint, silicon resin, resin or ceramic.

  Here, “cloth, resin” is a concept that widely includes a plate-like body made of cloth, paper, synthetic fiber, non-woven fabric, rubber, silicone resin, resin, synthetic resin, etc., and has an insulating function in a dry state. When cloth, paper, non-woven fabric, rubber, silicone resin, resin, synthetic resin are in contact with water vapor, or with electrolyte (water, seawater, hot water), cloth, resin, paper, non-woven fabric In addition, the material of rubber, silicon resin, resin, and synthetic resin is used in a wet state, and a material having electrical resistance between the ends of the resin is used.

  "Charcoal cloth" is a charcoal cloth with both sides of charcoal sandwiched between cloth and resin. Charcoal with sardine (Japanese paper) charcoal, bamboo charcoal, charcoal, activated carbon, fine activated carbon, carbon black, carbon nanotubes sandwiched from both sides with cloth. When cloth is in contact in the presence of water vapor, or when wet with electrolytic solution (water, seawater, hot water), Japanese (washi) charcoal, bamboo charcoal, charcoal, activated carbon, fine activated carbon, carbon black, carbon nanotube material Wet materials are used that cause electrical resistance between the edges of the material.

  Charcoal cloth with one side of charcoal fixed to cloth or resin is charcoal cloth with sardine (Japanese paper) charcoal, bamboo charcoal, charcoal, activated carbon, fine activated carbon, carbon black, carbon nanotubes fixed to one side of cloth. When in contact or when wet with electrolytic solution, sushi (Japanese paper) charcoal, bamboo charcoal, activated carbon, fine particle activated carbon, carbon black, carbon nanotube material gets wet, and there is an electric resistance between the ends of the material Is used.

  For the use of charcoal and activated carbon, a metal (electrode) with a different electrochemical potential sequence is combined with an electrode having an electromotive force level, and the electrochemical reaction (oxidation reduction reaction, Electrochemical energy generated by the electrochemical corrosion reaction, both positive and negative ions of the electrolyte are absorbed by the electrode surface by charging, paired with positive and negative charges in the electrode, store electricity, and the electric double layer disappears The electric double capacitor that charges and discharges the electric energy is used to store sardine (Japanese paper) charcoal, bamboo charcoal, charcoal, activated carbon, particulate activated carbon, carbon black, carbon nanotube charcoal.

  The present invention relates to electrosterilization for sterilizing organisms and microorganisms (bacteria, molds, yeasts, viruses), as well as electrochemical sterilization, and power generation using different types of metals (electrodes) in the electrochemical potential sequence, and the electromotive force level. Electrodes with electrode potential difference (electromotive force) are attached and fixed to the cloth or charcoal cloth. In the system where the electrode and electrolyte are connected, the wet electrode, cloth, resin or charcoal cloth is in contact with each other. The reactivity of the electrochemical reaction of the electric double layer in which electrons are exchanged at the interface between the electrons and the electrolyte is a driving force for causing an electrochemical reaction due to an electrode potential difference.

  A large number of electrodes with an electrode potential difference are separated and assembled, and fixed to cloth, resin (cloth, non-woven fabric, rubber, silicon resin, resin, synthetic resin), or charcoal cloth (Japanese paper charcoal, activated carbon fixed to cloth), electrode Is in contact with the presence of water vapor, and when in contact with the presence of the electrolyte solution, an electrical resistance is generated between the electrode and electrode, electrode and cloth, resin and electrode, or electrode and charcoal cloth, and the electrode is in contact. The electric corrosion action and electrolytic corrosion action that occurs when the current flows from one metal to another metal, so there is an electrical resistance between the electrodes, and the electrodes are also fixed to a conductive cloth, resin or charcoal cloth. It is characterized by that.

  Metal ions adhere to the surface of microbial cytoplasmic membranes and cell walls, and are affected by the cytoplasmic electron transport system and ion conduction. In the electrochemical reaction of the electric double layer at the interface of the liquid, the reaction energy that causes electrolysis of water by discharge, battery reaction, and electroplating is converted into electric energy, which is characterized by the generation of metal ions.

  Ion production by electrochemical reaction is because the substance with unpaired electrons becomes free radicals, steals electrons from other molecules, and the fat layer of the microbial membrane causes cell membrane destruction and kills cells and tissues by reducing their functions In the electrode and the electrolyte, the electrolyte repeats the descending order (reduction) in which the redox potential (ORP) decreases to negative, and the increasing order (oxidation) in which the redox potential (ORP) decreases to the minus by the electron emission and exchange of electrons in the electrochemical reaction. It is characterized by oxidation, reduction and free radical action.

  Microbial cell membranes and cell walls cause electric field formation, generation of static electricity, discharge current destruction, voltage destruction, corona discharge destruction and sterilization reactivity. A resin or charcoal cloth is inserted and fixed in parallel to form a parallel capacitor.Electrons are exchanged at the interface between the conductive electrode in contact with the electrolyte and the electrolyte. The charcoal cloth activated carbon electrode has a storage battery function of storing electrical energy, and the battery is characterized by a battery in which positive and negative ions of the electrode and the solution are repeatedly charged and discharged by physical adsorption and desorption on the negative electrode and the positive electrode, respectively.

  At least two types of electrode plates with different conductive properties have a large area. The electrode plates are spaced apart, and a cloth, charcoal, or activated carbon dielectric is inserted between the spaced electrode plates, and the electrode plates are placed in parallel. Electric double layer capacitor that can be fixed on cloth, resin or charcoal cloth, electrodes become parallel plates, electric charges are concentrated inside the metal plate and a strong electric field is created, and an electrochemical reaction occurs due to electrode potential difference to charge and discharge electric energy. A parallel capacitor with the power storage function.

  The reactivity of the electrochemical reaction reduces the area of the anode material electrode (on the positive side of the electrochemical potential sequence) and increases the amount of electrons supplied to the anode due to corrosion (electrochemical potential sequence) Increase the area of the negative side from the bottom), separate the anode material and cathode material (asode, cathode), fix the cloth, resin or charcoal cloth, and provide the space, and also the working electrode, reference electrode, and auxiliary An electrode having a large electrode potential difference by separating and combining a large number of electrodes from 1 is characterized in that a large number of electrodes are separated and incorporated.

  The electrode shape is flat, round, spherical, spiral, linear, lattice, mesh, hexagonal, chevron, corrugated, metal solid, activated carbon is processed into fine particles, carbon black, nanotubes are used, To increase the charge and sterilize by electrochemical reaction of electrostatic discharge, ion generation, corona discharge, and free radical action, the electrostatically charged electrode increases the total surface area, and the metal solid is processed into fine particles. Are characterized by being stacked or arranged in parallel.

  The power generation effect is enhanced by adding titanium oxide, fine powder of sulfur, or fine particles to electrodes having electromotive force levels of different types of metals having different electrochemical potential sequences.

In the plan view of the battery case, the anode plate and the cathode plate are arranged in parallel in the battery case, but the electrode plate separates and combines the electrode A6, electrode B7, electrode C8, electrode D9, electrode E10, etc. FIG. 2 is a plan view of a power generation electrode body or a fuel cell electrode body in which a cloth, resin or charcoal cloth 5 is inserted and fixed, and a conductive wire 3 is connected to end faces of an anode plate and a cathode plate. In the plan view of the battery case, the inner end of many electrode plates in the battery case is an anode plate, the other end is a cathode plate, the current flows sequentially through the electrode plate in the middle of the anode toward the cathode, Connected in series, the intermediate plate is a cathode on one side, the other side is an anode and the electrode plate on one side is different (double pole) on both sides. The electrode plates are electrodes A6, B7, C8, D9, and electrodes. FIG. 3 is a plan view of a power generation electrode body or a fuel cell electrode body in which E10 and the like are separated and combined, cloth, resin or charcoal cloth 5 is inserted and fixed between electrodes, and lead wires 3 are connected to end faces of an anode plate and a cathode plate. Metal electrodes with different electromotive force levels are formed in a spherical shape, and three layers are laminated, and cloth, resin, or charcoal cloth is inserted between the electrodes and fixed. The electrode plates are electrode A6, electrode B7, electrode C8, electrode D9, electrode E10, etc. , A cloth, resin or charcoal cloth 5 is inserted between the electrodes and fixed, and on the outer periphery, an antenna 4 for adsorbing negative electrons falling from space is attached, and a spherical power generation electrode body for generating power by continuously sending negative electrons to the electrode body a12 is a cross-sectional view of the fuel cell electrode body; It is a structure | tissue image of the zinc electrode expanded 150 times. It is a structure | tissue image of the zinc electrode expanded 150 times. It is a graph which shows the time-dependent change of ORP of a test liquid. It is a perspective image of the zinc electrode of the three laminated electrodes which inserted the charcoal cloth between zinc (tongue board), copper, and silver, and was fixed to the big charcoal cloth. It is a perspective image which shows the silver electrode of the 3 laminated electrode which inserted the charcoal cloth between silver, zinc (totone), and copper, and was fixed to the big charcoal cloth. It is the perspective image which image | photographed the discharge phenomenon of the power generation electrode body of the experimental result which this inventor performed. It is a perspective image which shows the electrode purification body of the shape of the three laminated electrodes of zinc (tongue board), a copper plate, and a silver plate (T10004). It is a perspective image which shows the shape of four laminated electrodes of a zinc material, stainless steel, aluminum, and a silver plate (T10005). A metal electrode A6, a metal electrode B7, a metal electrode C8, a metal electrode D9, a metal electrode E10, and the like of different kinds of electrochemical potential columns are spaced apart and fixed to the surface of a plate-like cloth, resin or charcoal cloth 5, and the electrodes are in a lattice shape. Use a wire in the form of a net, form an electric double layer capacitor, and supply electrodes by corrosive action at the anode by laminating metal with different electromotive force levels in a grid, net, wire or wire. Because it is a cathode material, the cathode area is increased, and when the electrode is immersed in the electrolytic solution 2, an electrochemical reaction occurs due to the electrode potential difference, and organisms and microorganisms are sterilized by electrical sterilization and electrochemical sterilization. It is a top view which shows the electric power generation electrode body b13 utilized for a fuel cell. On the surface of a plate-like cloth, resin or charcoal cloth 5, linear or wire-like electrodes A6, metal electrodes B7, metal electrodes C8, metal electrodes 9, or metal electrodes 10 having different electrochemical potential columns are separated. Side by side, parallel arrangement, fixation, lamination of metals with different electromotive force levels and immersion of the electrode in the electrolytic solution 2 causes an electrochemical reaction due to the electrode potential difference, sterilizing organisms and microorganisms, and storing electrical energy It is a top view which shows the electric power generation electrode body c14 utilized as a fuel cell to perform or a generator to generate electric power. On the surface of the plate-like cloth, resin or charcoal cloth 5, plate-like electrode A6, electrode B7, electrode C8, electrode 9, or electrode 10 of different types having different electrochemical potential rows are arranged apart from each other and arranged in parallel. When the electrodes are fixed and laminated with different electromotive force levels and the electrode is immersed in the electrolytic solution 2, an electrochemical reaction is caused by the electrode potential difference to sterilize organisms and microorganisms, and a fuel cell that stores electrical energy, or power generation that generates electricity It is a top view which shows the electric power generation electrode body d15 utilized as a machine. Plate-like cloth, resin or charcoal cloth 5 on the surface of plate-like electrode A6, electrode B7, electrode C8, electrode D9, electrode E10, etc. of different types having different electrochemical potential rows are arranged apart and vertically fixed. When electrodes with different electromotive force levels are laminated and the electrode is immersed in the electrolytic solution 2, an electrochemical reaction occurs due to the electrode potential difference, and organisms and microorganisms are sterilized by electrical sterilization and electrochemical sterilization. It is a top view which shows the electric power generation electrode body e16 utilized as a machine. On the surface of the cloth, resin or charcoal cloth 5, different kinds of metals having different electrochemical potential rows are arranged in a pyramid shape with the electrode A6, the electrode B7, the electrode C8, the electrode 9 and the electrode 10 being spaced apart and fixed. Also, it is a front view showing a power generation electrode body f17 used as a fuel cell and a generator that are fixed in parallel to control the reactivity of the electrochemical reaction, sterilize by causing an electrochemical reaction with an electrode potential difference, and store electric energy. The electrodes A6 and B7 are spaced and fixed clockwise around the circles of different types of electrodes C8, D9 and E10 of different electrochemical potential rows on the surface of the cloth, resin or charcoal cloth 5, and the generated electric energy is swirled. FIG. 5 is a plan view showing a power generation electrode body g18 that is shaped like an electrode and causes an electrochemical reaction with an electrode potential difference, and sterilizes organisms and microorganisms with electrical sterilization and sterilization with electrochemical sterilization. The electrodes A6 and B7 are spaced and fixed counterclockwise around the circles of the different types of electrodes C8, D9 and E10 having different electrochemical potential rows on the surface of the cloth, resin or charcoal cloth 5, and the generated electric energy is swirled. This shows an electrochemical reaction caused by an electrode potential difference, electrosterilization of organisms and microorganisms, sterilization by electrochemical sterilization, a generator used as a generator, a fuel cell, and an electrode body h19 used as a fuel cell. It is a top view. On the surface of the cloth or charcoal cloth 5, electrodes A6, B7, C8, D8, and E9 of different types having different electrochemical potential rows are arranged in parallel and spaced apart, and a spacer cloth, resin or charcoal cloth 5 is placed between the electrodes. In order to store electric energy by inserting and separating the electrode plate into a parallel capacitor, static electricity is generated through the electrolytic solution, sunlight, wind, water, water vapor, hot water, seawater, and an electrochemical reaction is caused by the electrode potential difference to generate electric energy. It is a perspective view which shows the power generation electrode body i20 utilized in order to sterilize the fuel cell, generator, and living organisms and microorganisms which store electricity. On the surface of cloth or charcoal cloth 5, electrodes A6 of different types having a net-like electrochemical potential sequence, electrode B7 and 18-hole electrode C8 having an area, electrode D9 and electrode E10 are separated and electrode plates are arranged in parallel. , Spacer cloth, resin or charcoal cloth 5 is inserted between the electrodes and fixed to a large cloth, resin or charcoal cloth 5, the electrode is a parallel capacitor, the flow of metal ions is improved, and an electrochemical reaction is caused by the electrode potential difference. It is a perspective view showing a power generation electrode body j21 that stores electric energy and uses it as a battery, sterilizes an air cleaner, sterilizes living organisms and microorganisms by electrical sterilization, sterilizes by electrochemical sterilization, a fuel cell, and a generator. . Inside the sphere of activated carbon, round electrodes A6, round electrodes B7, round electrodes C8, and round electrodes D9 of different kinds of metals having different electrochemical potential rows are arranged apart from each other, and electrolytic solution, seawater, water, hot water , Water vapor, air, compressed air passing through, rotating the electrode, and storing the electric energy of the electric double layer of the electrochemical reaction by the electrode potential difference, fuel cell, power generator, air, compressed air, seawater, water, hot water It is sectional drawing which shows the electric power generation electrode body k22 utilized as sterilizing. Three cylinders are stacked to form a three-layer electrode cylinder, and a spacer cloth, resin or charcoal cloth 5 is placed between the cylinders and arranged in parallel, spaced apart, and the cloth, resin or charcoal cloth 5 is fixed to the outer periphery, and the electrochemical potential sequence is different. Electrodes A, B6, C7, and D8 are separated from each other and electrode cylinders are arranged in parallel, and hot water, wind, gas, air, compressed air, water, and seawater pass through the electrodes as parallel capacitors. It can be used as a battery that generates an electrochemical reaction due to generation or electrode potential difference and takes out electric energy of the electric double layer, discharge of static electricity generated by hot water, water, gas, wind, air, compressed air passing through the tube, or electricity It is sectional drawing which shows the electric power generation electrode body L23 which is sterilized by sterilization and electrochemical sterilization, and is used as a generator and a fuel cell. The square is stacked in three layers, and a three-layer electrode square is used. Spacer cloth, resin or charcoal cloth 5 is placed between the squares, spaced apart and arranged in parallel, and the cloth, resin or charcoal cloth 5 is fixed to the outer periphery. Different types of metal electrodes A6, B7, C8, and D9 are spaced apart and the electrode cylinders are arranged in parallel, and the electrodes are parallel capacitors. Hot water, wind, gas, air, air, compressed air, water, hot water, seawater Passes through and generates static electricity, causes an electrochemical reaction due to the electrode potential difference, takes out the electric energy of the electric double layer, is used as a fuel cell, generator, hot water, water, gas, wind, air, compressed air passing through the pipe 3 is a tilted surface showing a power generation electrode body m24 sterilized by discharge of static electricity generated by the electric field, electric sterilization, or electrochemical sterilization. The electrodes A6, B7, C8, and D9 are provided to increase the area of contact between the surfaces of the cloth, resin, or charcoal cloth 5 and the electrodes of different types of electrochemical potential columns in a mountain shape to increase the static electricity. Spaced in layers, arranged in parallel, spacer cloth, resin or charcoal cloth 5 inserted, electrodes as parallel capacitors, static electricity generated by passing through wind, sunlight, water, seawater, and electrochemical reaction with electrode potential difference It is a perspective view showing a power generation electrode body n25 that is used as a raising fuel cell and a generator, and sterilizes water by electrostatic discharge, electrical sterilization, and electrochemical sterilization. Hexagonal electrochemical potential trains of different metals with different areas Electrodes A6, B7, C8, D9 of different types of metal are separated from each other in a stack, electrode plates are arranged in parallel, and a hole is formed in the center. The electrode is a parallel capacitor, and an electrochemical reaction is caused by the electrode potential difference from the parallel plane and the hexagonal cross section, and it is used as a fuel cell and a generator. In addition, the discharge of static electricity generated by water, air and electrolytic solution passing through the electrode, It is a top view which shows the electric power generation electrode body o26 sterilized by static sterilization and electrochemical sterilization. FIG. 26 is a right side view of the three-layered electrode in FIG. 25. Different types of electrodes A6, B7, C8, and D9 of different types of rectangular electrochemical potential arrays with different areas are separated from each other in a stack, electrode plates are arranged in parallel, a hole is formed in the center, Parallel capacitor, electrochemical reaction caused by electrode potential difference from parallel plane and square cross section, used as fuel cell, generator, electrostatic discharge generated by electrolytic solution, water, air passing through electrode, electric sterilization, It is a top view which shows the electric power generation electrode body p27 sterilized by electrochemical sterilization. It is a right view of the 3 laminated electrode of FIG. The fine particle electrode A30 and the fine particle electrode B31 having different electrochemical potential rows are fixed to the surface of the cloth, resin or charcoal cloth 5, and both surfaces of the fine particle electrode are covered with the paint 11, or the fine particle electrode A30, the fine particle electrode B31, or the fine particle Electrode C32, fine particle electrode D33, fine particle electrode E34, etc. are laminated or arranged in parallel and coated, and the fine particle electrode is used as a parallel capacitor to form an electric double layer capacitor, thereby improving the flow of metal ions and forming an electric double capacitor. When immersed in an electrolytic solution, seawater, water, hot water, or air, an electrochemical reaction occurs due to the electrode potential difference, and the electrical energy is stored and used as a fuel cell or generator. Biological organisms and microorganisms are sterilized by electrical sterilization and electrochemical sterilization. It is sectional drawing which shows the fine particle electrode body q28 utilized. On the surface of the cloth, resin or charcoal cloth 5, fine-particle power generation electrode bodies 30 and fine-particle electrodes B31 having different electrochemical potential rows are laminated or fixed in parallel, and both surfaces are covered with the paint 11, and further the fine-particle electrode C32 or fine-particle electrode D33, the fine particle electrode E34 is fixed and the surface is covered with coating, the fine particle electrode A30, the fine particle electrode B31, and the fine particle electrode C32 are fixed, and the fine particle electrode D33 and the fine particle electrode E34 are fixed, stacked or arranged in parallel. , Forming an electric double layer capacitor, improving the flow of metal ions, soaking in an electrolytic solution, seawater, water, hot water, air causes an electrochemical reaction due to an electrode potential difference and stores electric energy to be used as a fuel cell, generator, Electrode sterilization of organisms and microorganisms, sterilization by electrochemical sterilization, and particulate power generation electrode used for batteries that store electrical energy R29 is a sectional view showing a. It is a figure which shows that a purification | cleaning body is killed rather than growth inhibition in the culture experiment of coliform bacteria. It is a figure which shows growth and proliferation by the culture | cultivation experiment of coliform bacteria.

  The following experiment was carried out after recombination of the above metals for 3 years. At least two kinds of different metals were fixed on the surface of the cloth, resin or charcoal cloth, and at least two kinds of metals were fixed in parallel. Separate the above different metals, insert cloth or charcoal cloth between the metals, stack the metal on the laminate and fix it on a large cloth or charcoal cloth, soak in water to become a water battery, discharge and charge as long as there is water Confirm that the fuel cell has a power generation function and continues to generate static electricity.

  The present inventor inserted charcoal cloth between the electrodes of different kinds of metals, tin materials, copper materials, silver materials, and (T-7101) in the electrochemical potential sequence in order to confirm the voltage, current, and resistance through experiments. The laminate was fixed on a large charcoal cloth, and three laminated electrodes and a solution (50 ml of hot water remaining in the bath) were placed in a plastic container, and the voltage, current, and resistance were measured for three days. The voltage, current, and resistance values are generated between different electrodes, and the voltage and current gradually increase and then decrease again. As long as water is present, the battery becomes a water battery, and the measured values are shown in Table 2. The electrode shape is as shown in FIG.

  Furthermore, a cloth is inserted between the electrodes of the tin plate, copper plate, and silver plate to form a three-layer electrode (T-7102). When measured for 3 days, it becomes a water battery and discharge and charge are repeated, and the measured values are shown in Table 3. It is.

The details of the above experimental results are shown in Table 4. Table 4 is a test report (No. 21-0353, (1) Measurement of current, voltage and resistance) issued by Niigata Prefectural Industrial Technology Research Institute.

  Analysis of the electrolyte solution tested revealed C, O, Si, Ca, Fe, Cu, and Zn. Zinc on the tin plate elutes in the form of threads, turns black when oxidized, and undergoes an electrochemical reaction of water electrolysis (see Table 5).

The details of the above experimental results are shown in Table 6 1-2. Tables 6-1 and 2-2 are test results issued by Niigata Prefectural Industrial Technology Research Institute (No. 21-0367, (1) X-ray microanalyzer analysis (qualitative analysis)).

  On the surface of the above zinc electrode (tin plate), zinc is eluted in a thread form in an amount of 100 μm × 11 mm by an electrochemical reaction (redox reaction). (See FIGS. 4 and 5),

  In the above-mentioned metal ion measurement experiment, the hexagonal zinc plate (tin plate), the copper plate, and the silver plate, which are the electrodes T-7102, were separated, the cloth was inserted, and the three laminated electrodes were fixed to the large cloth, and the electrode and the electrolyte 50 ml ( The remaining hot water of the bath was placed in a plastic container, and the ions after 10 days were measured. Zinc ions were significantly increased to 3.99 ppm, copper ions were significantly increased to 0.11 ppm, and silver ions were confirmed to increase slightly, and an electrochemical reaction occurred (see Table 7).

  Furthermore, a silver wire is fixed to the front side of the charcoal cloth, and a copper wire is fixed to the back side (hereinafter referred to as “purified body”). The bath is immersed in a bathtub to boil, and then the purified body is removed and the bath is used. Table 7 shows the result of measuring the metal ions of the remaining hot water and comparing the measured values.

The details of the above experimental results are shown in Table 8. Table 8 is a test report issued by Niigata Prefectural Industrial Technology Research Institute (No. 21-0367-2, (1) Quantitative Analysis).

  50ml of the above electrode, zinc material (tin plate), copper material, silver material and 50ml of electrolyte (residual hot water in a bath) are placed in a plastic container and the electrostatic capacity is measured. Charge high static electricity of -0.5 kv (measurement over 1 hour). The measuring device is a static locator, model: Z-201, manufactured by Hozan Co., Ltd.

  A single-layer electrode in which one zinc material (tin plate) is fixed to a charcoal cloth and a three-layer electrode in which silver, zinc (copper plate) and copper are separated and a charcoal cloth is inserted are fixed to a large charcoal cloth, and each electrode is Compared with the amount of metal ions generated in the electrolyte solution, metal ions are eluted more in the three-layer electrode than in the one-layer electrode, and the electrode potential difference at different electromotive force levels is different for the three-layer electrode. Ions are strong and accelerate the reactivity of electrochemical reactions.

  When the metal electrode solid is divided and processed into fine powders and fine particles, the total surface area increases dramatically, and a large amount of static electricity is charged on the surface and many metal ions are generated.

  Furthermore, in the experiment, an aluminum wire 1.0 mm and a silver wire 0.3 mm are placed apart from each other on a charcoal cloth, a culture solution (100 ml) is put in to produce a purified body, and general bacteria (E. coli) are put in and observed. Bacteria are attracted to the silver side by the reaction, and a single battery, 1.5V is connected, current flows and an electrochemical reaction (redox action) sterilizes E. coli 12 hours after energization, shortening the sterilization time of microorganisms, The sterilization effect is improved.

  The solution does not penetrate the cloth or charcoal cloth immediately, but the electrode A (silver material) and the electrode D (aluminum material) are fixed to the cloth or charcoal cloth. Due to the ionic action, the solution permeates the cloth or charcoal cloth in a short time.

  Furthermore, it was confirmed by experiments that the silver, zinc, copper (T-8001) and silver, aluminum, copper (T-8003) electrodes have excellent antibacterial effects, and the electrode shape is as shown in FIG. is there.

  The sterilization experiment of E. coli is made of three kinds of metals with different electrochemical potential sequences. Three layers of metal, silver material, zinc material (tin plate), copper material (T-8001) with electromotive force level and charcoal cloth inserted. The electrode is fixed to a large charcoal cloth, 100 ml of culture solution is added, E. coli is cultured, incubated at 35 ° C., the E. coli specimen is doubled to 1,000 cells / ml in 24 hours, and biological contamination is measured by 3M Petri film, Chisso It was confirmed by Sani-ta-kun made by Co., Ltd. Bacterial death could be confirmed, colonies of coliform bacteria did not change from blue to light green, no bacteria were detected, and the antibacterial effect could be completely verified. The killing of the coliform group after the test is shown in FIG.

  As a control, Escherichia coli is placed in a 100 ml culture solution of ionized water from which the purified body has been removed, incubated at 35 ° C. and cultured for 24 hours, and the Escherichia coli is diluted to 1,000 specimens / ml. I confirmed it thick. The bacteria did not die, and colonies of the coliform group developed from blue to green, confirming the detection of the bacteria. FIG. 32 shows the growth and proliferation of the coliform group after the test.

  As a sterilization experiment of Escherichia coli, the metal electrodes with different electromotive potential sequences have electromotive force levels of silver, zinc (tongue), copper (T-8001) and silver, aluminum, copper Insert the charcoal cloth into the space of (T-8003), place the three laminated electrodes on the large charcoal cloth, and the redox potential of the test solution containing 100 ml of the culture solution and the control (ion water 390 mV) is 3, 6, 24, 72 hours After 72 hours from the measurement, the test solution T-8001 was 275 mV, the T-8003 was 283 mV, and it was found that the redox potential was negative and the reduction in descending order and the ascending order of oxidation were repeated (see FIG. 6). It is thought that unpaired electrons are generated between the electrode and the test solution and become free radicals. Table 9 shows the experimental results.

  A pack test was conducted to examine the generation of metal ions in the test solution 72 hours after the start of the experiment. Measured by Kyoritsu Riken Co., Ltd., zinc ion 5 mg / L (ppm) at T-8001, copper ion 0.5 mg / L (ppm), copper ion 1.0 mg / L (ppm) at T-8003, It was confirmed that trace amounts of aluminum ions 0.5 mg Al / L (ppm) and silver ions ≈ 0 were generated. An electrochemical reaction (redox reaction) occurs, and metal ions having the same tendency as in Table 7 are generated.

  Inserting a charcoal cloth between the silver material, aluminum material and copper material on the electrode, fixing the three-layered electrode to the charcoal cloth, and putting it in the electrolyte (ionic water), after 24 to 72 hours, the aluminum ion is 0.5 mg Al / L (ppm) elutes. (See Table 10)

The details of the above experimental results are shown in Tables 11-1 to 11-6 .

  In an experiment conducted by the present inventor, a camera was installed with the shooting place completely dark, a charcoal cloth was inserted between three laminated electrodes of a zinc plate, a copper plate, and a silver plate, and the three laminated electrodes were fixed to a slightly larger charcoal cloth. Laminated electrodes are placed in a glass container (7 l) with tap water (3.5 l) and placed on a transparent circle of 30 x 50 mm. When the electrodes are immersed, electric field formation, static electricity, voltage and current are generated, and the voltage and current are Photoelectric emission is stored in the double-layer capacitor, and the discharge occurs when the allowable voltage is exceeded. The shape of the electrode is as shown in FIG. The camera is Canon EOS1, the lens is Canon Macro 100mm, F2.8, with bulb (long exposure) function, the film is FUJIFILM Natural 1600, and the sensitivity at the time of development is 3200. The results of the above photography are shown in FIG.

In this experiment, a charcoal cloth is inserted between the electrodes of different types of metals, zinc materials, silver materials, copper materials, and (T-10011) electrodes having different electrochemical potential sequences, and is fixed to a large charcoal cloth in three layers. The laminated electrode and the electrolytic solution (pure water 50 ml) were placed in a plastic container, and the voltage, current, and resistance were measured for 3 days. Voltage between different electrode, current, voltage resistance is generated, the current gradually increases with decreasing thereafter also "charging, discharging" the will zinc battery repeated over a long period of time as long as the pure water is present, the measured value Table 12 The electrode shape is as shown in FIG.

Furthermore, a cloth is inserted between the electrodes of the zinc plate, silver plate, and copper plate to form a three-layer electrode (T-1202). When three days are measured, a zinc battery is formed and discharging and charging are repeated, and the measured values are as shown in Table 13. It is.

Tables 14-1 to 3-3 are test results issued by Niigata Prefectural Industrial Technology Research Institute (test results 22-0016, (1) measurement of current, voltage and resistance, (2) far-infrared radiation amount. Measurement). Furthermore, in the experiment, a charcoal cloth was inserted between the electrodes of different kinds of metals, zinc materials, silver materials, copper materials, and (T-10003) of electrochemical potential trains, and three layers were stacked and fixed to a large charcoal cloth. Infrared was measured, the measurement wavelength was 1.3 μm to 14.5 μm, the effective wavelength was 3.0 μm to 14.5 μm, and the far infrared rays were confirmed to be emitted from the zinc plate. The measured values are as shown in Tables 14 to 1-3 The electrode shape is as shown in FIG. The details of the above experimental results are shown in Tables 14-3 .

In the experiment, zinc plates, stainless steel, aluminum plates, and silver plates were made into 4 layers, and a cloth or charcoal cloth was inserted between them, and the 4 layers electrode fixed to a slightly larger cloth or charcoal cloth had an electric field in the presence of water vapor (in the air). Formation, generation of static electricity, voltage, current, and the application of sunlight to the electrode surface as acceleration of electrochemical corrosion reaction from the outside, the temperature rises and the electrochemical reaction is accelerated, and the electrolytic solution, hot water under high temperature conditions , seawater, low temperature When immersed in seawater with floating ice conditions or confined in frozen ice conditions, the electrochemical reaction (electrochemical corrosion reaction) becomes more active, forming an electric field, and increasing the static electricity, voltage, and current values. The electrode shape is as shown in FIG. Details of the above experimental results are shown in Table 15 .

  In the experiment, when a purifier consisting of two or more sets of metal electrodes with different electromotive forces is immersed in an electrolytic solution, an electrochemical reaction (electrochemical corrosion) occurs using the electrode potential difference as the driving force, and the generated voltage and current are changed between the cloth and charcoal cloth. Accumulated in the electric double layer capacitor, the voltage causing electrolysis of water reaches around 1.5V, causing electrolysis of water by discharge, generating hydrogen gas bubbles on the metal surface of the cathode, and oxygen gas on the metal surface of the anode Confirm that it oxidizes.

  In the experiment, the silver wire and the aluminum wire of the metal electrodes with different electromotive forces were separated and fixed to the charcoal cloth, and when immersed in the electrolytic solution, an electrochemical reaction occurred due to a potential difference, static electricity was generated, electric field formation, and E. coli dispersed in the electrolytic solution The group collects bacteria on the silver wire of the cathode, and when applied to the silver wire and aluminum wire with a single battery (1.5V), the bacteria collect on the surface of the silver wire electrode and the E. coli group that has passed for 12 hours accumulates and dies and is sterilized by inspection. Is not detected.

The electrical effect which acts on the morphology and proliferation of a cell when applying a -0.2V- + 1.2V constant potential about the HeLa cell cultured on the electrode is shown. Since the surface of the cell membrane is negatively charged, cells are observed to change in shape from an original spindle shape to a spherical shape depending on the potential at −0.2 V to +0.4 V, but do not die. At + 0.7V, gradually die and at + 1.2V all cells die within 1 hour.
(Non-Patent Document) The Electrochemical Society of Japan, “Electrochemical Handbook” published by Maruzen Co., Ltd., published on June 30, 2000, Cell Control Technology, P339

“Electrolysis of water produced at a voltage lower than the electrolysis pressure” Even when no electric field is applied, water molecules are in an equilibrium state represented by H ₂ O → H ⁺ + OH ⁻ , and even when no electric field is applied to water , Each ion moves toward the opposite electrode surface, and a current flows between the electrodes. The electrolysis in this case corresponds to the left portion of D in FIG. 31 (voltage below the electrolysis pressure), and even if hydrogen gas is generated on the negative electrode surface, oxygen gas is not generated on the positive electrode surface. Hydrogen ions H ⁺ and hydroxide ions OH ⁻ are hydrated with water molecules, respectively, to become H ₃ O ⁺ (hydronium ions) and H ₃ O ₂ ⁻ (hydroxyl ions). The movement of these ions in water is due to the so-called “hopping model”, in which only H ⁺ or OH ⁻ is passed to the adjacent water molecules, resulting in the movement of the ions. And the fast about twice as compared with the moving speed of the H ⁺ ions, low discharge potential of H ⁺ ions, become gases will readily discharge electrode surface in H ₂ lost from the water, one of OH ^- Since ions have a higher discharge potential on the electrode surface, they are diffused into the water stream as charged ions.
Water electrolysis H ₂ O → ← H ⁺ + OH ⁻
Water Hydrogen ion Hydroxide ion H ⁺ + H ₂ O → H ₃ O ⁺ [Part of the hydrogen ion becomes H ₂ gas (hydrogen gas)]
Hydrogen ion Water Hydronium ion OH ⁻ + H ₂ O → H ₃ O ₂ ⁺
Hydroxyl ion Water Hydroxyl ion (Non-patent literature) Kunihiko Watabuchi, supervised by Shoji Kubota, “New water science and utilization technology”, published by Scien Forum Co., Ltd., November 10, 1992, P304

  The electrode A and the fine particle electrode A use gold, platinum, vanadium, rhodium base copper, silver / gold alloy, silver material, charcoal, activated carbon.

  Electrode B and fine particle electrode B use nickel-plated steel, silver solder, copper alloy, copper, high chromium stainless steel, and 12% chromium stainless steel.

  Electrode C and fine particle electrode C use nickel base chromium-plated steel, chromium-plated steel, soft solder, lead, duralumin, brass and tin.

  Electrode D and fine particle electrode D use iron, soft iron or steel, chromium, zinc, zinc alloy, 80 tin / 20 tin plated steel, galvanized iron / steel (totan), cadmium plated steel, aluminum / manganese alloy, aluminum .

  The electrode E and the fine particle electrode E use titanium oxide, sulfur, magnesium, magnesium alloy, sodium, and potassium.

  The paint 11 uses paint and silicon resin.

  The cloth, resin, or charcoal cloth 5 uses cloth (cloth, non-woven fabric, rubber, resin, synthetic resin) or charcoal cloth (Wat charcoal, bamboo charcoal, activated carbon is fixed to the cloth).

  The fine particle activated carbon uses fine particle activated carbon, carbon black, and carbon nanotube.

Hereinafter, preferred embodiments of the power generation electrode body and the fuel cell of the present invention will be described with reference to the drawings.
FIG. 1 is a plan view of a parallel-type battery case. In the battery case, the anode plate and the cathode plate are arranged in parallel with each other. The electrode plates are electrodes A6, B7, C8, D9, and E10. FIG. 4 is a parallel plan view in which the conductors 3 are inserted and fixed by inserting cloth, resin or charcoal cloth 5 between electrodes, and the conductors 3 are connected to the end faces of the anode plate and the cathode plate.

  Fig. 2 is a plan view of a series-type battery case. Inside the battery case, the inner end of many electrode plates is an anode plate, the other end is a cathode plate, and the current flows sequentially through the electrode plate in the middle of the anode. To the cathode, the electrode plates are connected in series, the intermediate plate or the like is a cathode on one side, the other side is an anode and the electrode plate on one side is different (double pole), and the electrode plates are electrodes A6, B7, A series plan view in which electrode C8, electrode D9, electrode E10, etc. are combined and spaced apart, and cloth, resin or charcoal cloth 5 is inserted between the electrodes and fixed, and lead wire 3 is connected to the end faces of the anode and cathode plates. It is.

  FIG. 3 shows that electrons (negative ions) are constantly falling from the universe, collected by the antenna 4, attracted to the positive electrode of the electrode body, and then carried to the negative electrode, and then negative electrons from the negative electrode side. Is formed in such a way that it is ejected, and the positive electrode flies along the lines of electric force, an electric field is formed, the static electricity is continuously generated, and the spherical power generation electrode body a12 is laminated. Show.

  FIG. 12 shows a cross section of a modified example of the power generation electrode body b13 of the electrode A6 fixed to the surface of the cloth, resin or charcoal cloth 5, here fixed to a grid or net, and further to the electrode B7, electrode C8, electrode D9, electrode E10, etc. are fixed to the surface of cloth, resin or charcoal cloth 5, and different electrodes are laminated.

  FIG. 13 shows a cross section of a modified example of the power generating electrode body c14 of the electrode A6 fixed to the surface of the cloth, resin or charcoal cloth 5, where it is spiral, and the electrode is fixed by winding left or right. Further, the electrode B7, the electrode C8, the electrode D9, the electrode E10 and the like are fixed to the surface of the cloth, resin or charcoal cloth 5, and different electrodes are laminated.

  FIG. 14 shows a cross section of a modified example of the power generation electrode body d15 of the electrode A6, the electrode B7, the electrode D9, and the electrode E10 fixed to the surface of the cloth, resin, or charcoal cloth 5, and here, strip-shaped electrodes are arranged side by side. The electrodes A6, B7, C8, D9, and E10 are fixed on the surface of the cloth, resin or charcoal cloth 5, and different electrodes are laminated.

  FIG. 15 shows a cross section of a modified example of the power generation electrode body e16 of the electrode A6, the electrode B7, the electrode C8, the electrode D9, and the electrode E10 that is fixed to the surface of the cloth, resin, or charcoal cloth 5, and here, the belt-like electrode is shown. The electrodes A6, B7, C8, D9, E10, etc. are arranged and fixed on the surface of the cloth, resin or charcoal cloth 5, and different electrodes are laminated.

  FIG. 16 shows a modification of the power generating electrode body f17 in which a cloth, resin or charcoal cloth 5 is formed in a pyramid shape, and the electrodes A6, B7, C8, D9, and E10 are separated and fixed on the surface thereof. The rectangular plate-like electrodes are spaced apart from each other.

  FIG. 17 shows power generation in which circular electrodes C8, D9, and E10 are arranged on the surface of cloth, resin, or charcoal cloth 5, and electrodes A6 and B7 are fixed in a clockwise spiral around the electrodes. The modification of the electrode body g18 is shown.

  FIG. 18 shows a power generation electrode in which circular electrodes C8, D9 and E10 are arranged on the surface of cloth, resin or charcoal cloth 5, and electrodes A6 and B7 are fixed in a counterclockwise spiral around the electrodes. The modification of the body h19 is shown.

  FIG. 19 shows a modified example of the power generation electrode body i20 in which rectangular plate-like electrodes A6, B7, C8, and D9 are spaced apart and arranged in parallel so as to stand on the surface of cloth, resin or charcoal cloth 5. FIG. A parallel capacitor can be configured by inserting cloth, resin or charcoal cloth 5 as a spacer between the electrodes.

  FIG. 20 shows a perforated electrode having an area having any one of the mesh-like and grid-like electrodes of the electrode A6 and the electrode B7 and the electrode C8, the electrode D9, and the electrode E10. A modified example of the power generation electrode body j21 arranged in parallel and spaced apart with the carbon cloth 5 interposed is shown, and a cloth, resin or charcoal cloth 5 is inserted as a spacer between the mesh electrode and the perforated electrode to constitute a parallel capacitor. be able to.

  FIG. 21 shows a modified example of the power generation electrode body k22 in which the round electrode A6, the round electrode B7, the round electrode C8, and the round electrode D9 are arranged apart from each other inside the activated carbon 5 having a cylindrical cross section. These electrodes can be rotated by an external motor or the like.

  FIG. 22 shows a cross section of a modified example of the power generation electrode body L23 of a cylindrical three-layer electrode in which cylindrical electrodes are coaxially stacked, and cloth, resin or charcoal cloth 5 is inserted as a spacer between a plurality of cylinders. The cylindrical electrodes A6, B7, C8, and D9 are spaced apart and arranged in parallel to form a parallel capacitor.

  FIG. 23 shows a modified example of the power generation electrode body m24 of a square three-layer electrode in which square electrodes are arranged in three layers, and cloth, resin or charcoal cloth 5 is inserted as a spacer between the plurality of squares. It is a perspective view which can arrange | position the square-shaped electrode A6, the electrode B7, the electrode C8, and the electrode D9 spaced apart in parallel, and can comprise a parallel capacitor.

  FIG. 24 is a perspective view showing a modified example of a power generation electrode body n25 in which a mountain-shaped electrode A6, electrode C8, electrode B7, and electrode D9 are separated and cloth, resin or charcoal cloth 5 is inserted as a spacer and laminated in parallel. FIG.

  FIG. 25 shows a modification of the power generation electrode body p26 in which hexagonal electrodes A6, B7, D8, and E9 having different areas are separated and cloth, resin or charcoal cloth 5 is inserted as spacers and laminated in parallel. FIG. 26 is a side view of the same modification. A parallel capacitor can be formed by inserting cloth, resin or charcoal cloth 5 as a spacer between the three electrodes. A hole is formed in the center of each electrode.

  FIG. 27 shows an upper surface of a modified example of the power generation electrode body q27 in which square electrodes A6, B7, D8, and E9 having different areas are spaced apart and cloth, resin or charcoal cloth 5 is stacked in parallel as spacers. FIG. 28 is a side view of the modification. A parallel capacitor can be formed by inserting and separating cloth, resin, or charcoal cloth 5 as a spacer between the three electrodes. A hole is formed in the center of each electrode.

  FIG. 29 shows a cross-sectional view of a modified example of the power generation electrode body R28 in which the fine particle electrode A30 and the fine particle electrode B31 are separated and cloth, resin, or charcoal cloth 5 is placed in parallel as spacers, and both surfaces of the fine particle electrode are shown. An electric double layer capacitor can be formed by covering with the coating material 11 or coating the fine particle electrode C32, the fine particle electrode D33, the fine particle electrode E34, etc. in a stacked or parallel arrangement, and using the fine particle electrode as a parallel capacitor.

  FIG. 30 shows a cross-sectional view of a modified example of the power generation electrode body s29 in which the fine particle power generation electrode body 30 and the fine particle electrode B31 are spaced apart and cloth, resin or charcoal cloth 5 are stacked in parallel as spacers, and the upper surface is painted. 11, and further, the fine particle electrode C32, the fine particle electrode D33, the fine particle electrode E34, and the like are laminated or arranged in parallel and coated, and the fine particle electrode is used as a parallel capacitor to constitute an electric double layer capacitor.

DESCRIPTION OF SYMBOLS 1 Battery case 2 Electrolyte solution, water, hot water, seawater, floating seawater, frozen seawater 3 Conductor 4 Antenna 5 Cloth, Resin, Charcoal cloth 6 Electrode A (gold, platinum, vanadium, rhodium-plated copper, silver / gold Alloy, silver, charcoal, activated carbon)
7 Electrode B (Nickel plated steel, silver solder, copper alloy, copper, high chromium stainless steel, 12% chromium stainless steel)
8 Electrode C (nickel-undercoated chrome-plated steel, chrome-plated steel, soft solder, lead, duralumin, brass, tin)
9 Electrode D (Iron, soft iron or steel, chromium, zinc, zinc alloy, 80 tin / 20 tin-plated steel, galvanized iron / steel (titan), cadmium-plated steel, aluminum / mangan alloy, aluminum)
10 Electrode E (Titanium oxide, sulfur, magnesium, magnesium alloy, sodium, potassium)
11 Paint (paint, silicone resin)
12 Spherical power generation electrode body a
13 Power generation electrode body b
14 Power generation electrode body c
15 Power generation electrode body d
16 Power generation electrode body e
17 Power generation electrode body f
18 Power generation electrode body g
19 Power generation electrode body h
20 Power generation electrode body i
21 Power generation electrode body j
22 Power generation electrode body k
23 Power generation electrode body L
24 Power generation electrode body m
25 Power generation electrode body n
26 Power generation electrode body o
27 Power generation electrode body p
28 Fine Particle Power Generation Electrode Body q
29 Fine Particle Power Generation Electrode Body R
30 Particle electrode A
(Gold, platinum, vanadium, rhodium-plated copper, silver / gold alloy, silver, charcoal, activated carbon)
31 Fine particle electrode B
(Nickel plated steel, silver solder, copper alloy, copper, high chromium stainless steel, 12% chromium stainless steel)
32 Fine Particle Electrode C
(Nickel-underlying chrome-plated steel, chrome-plated steel, soft solder, lead, duralumin, brass, tin)
33 Fine particle electrode D
(Iron, soft iron or steel, chromium, zinc, zinc alloy, 80 tin / 20 tin-plated steel, galvanized iron / steel (totan), cadmium-plated steel, aluminum / manganese alloy, aluminum)
34 Fine Particle Electrode E
(Titanium oxide, sulfur, magnesium, magnesium alloy, sodium, potassium)

Claims (3)

Electrochemical potential Ri is Do different, as electrodes three or more types of areas mutually different metal plates having different electromotive force levels, cloth, while interposing the resin or charcoal cloth, so as not to contact with the edges to each other when viewed in the stacking direction In the back of the metal plate having the largest area, a cloth, resin, or charcoal cloth having a larger area is provided opposite to the back surface of the metal plate. A power generating electrode body characterized by generating electricity through a connected conductive wire and exhibiting antibacterial or antifungal effects. The metal is potassium, sodium, magnesium, magnesium alloy, titanium oxide, sulfur, zinc, zinc alloy, 80 tin / 20 galvanized steel, galvanized iron / steel (totan), aluminum, cadmium plated steel, aluminum / manganese alloy, Soft iron, duralumin, tin, lead, brass, chrome-plated steel, soft solder, nickel-undercoated chrome-plated steel, tin-plated steel, 12% chrome stainless steel, high chrome stainless steel, copper, copper alloy, silver solder, austenitic stainless steel 2. The power generating electrode body according to claim 1 , which is a different kind of metal among nickel, plated copper, silver, rhodium-based gold-plated copper, silver / gold alloy, carbon, activated carbon, vanadium, platinum, and gold. . Generating electrode member according to claim 1 or 2 characterized by forming an electric double layer capacitor between the electrodes.