JP5469368B2 - Fitting female material for surface fastener and method for manufacturing the same - Google Patents

Fitting female material for surface fastener and method for manufacturing the same Download PDF

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JP5469368B2
JP5469368B2 JP2009109532A JP2009109532A JP5469368B2 JP 5469368 B2 JP5469368 B2 JP 5469368B2 JP 2009109532 A JP2009109532 A JP 2009109532A JP 2009109532 A JP2009109532 A JP 2009109532A JP 5469368 B2 JP5469368 B2 JP 5469368B2
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fabric
adhesive
engaging
adhesive layer
yarn
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JP2010253183A (en
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健一郎 森下
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3M Innovative Properties Co
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3M Innovative Properties Co
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Priority to JP2009109532A priority Critical patent/JP5469368B2/en
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Priority to PCT/US2010/032494 priority patent/WO2010129244A2/en
Priority to BRPI1007734A priority patent/BRPI1007734A2/en
Priority to EP10772495.7A priority patent/EP2424400A4/en
Priority to KR20117027969A priority patent/KR20120023011A/en
Priority to TW99113374A priority patent/TW201102465A/en
Priority to CN201080018325.2A priority patent/CN102413727B/en
Publication of JP2010253183A publication Critical patent/JP2010253183A/en
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Classifications

    • AHUMAN NECESSITIES
    • A44HABERDASHERY; JEWELLERY
    • A44BBUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
    • A44B18/00Fasteners of the touch-and-close type; Making such fasteners
    • AHUMAN NECESSITIES
    • A44HABERDASHERY; JEWELLERY
    • A44BBUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
    • A44B18/00Fasteners of the touch-and-close type; Making such fasteners
    • A44B18/0023Woven or knitted fasteners
    • AHUMAN NECESSITIES
    • A44HABERDASHERY; JEWELLERY
    • A44BBUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
    • A44B18/00Fasteners of the touch-and-close type; Making such fasteners
    • A44B18/0069Details
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04BKNITTING
    • D04B21/00Warp knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
    • D04B21/02Pile fabrics or articles having similar surface features
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/56Supporting or fastening means
    • A61F13/62Mechanical fastening means, ; Fabric strip fastener elements, e.g. hook and loop
    • A61F13/622Fabric strip fastener elements, e.g. hook and loop
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/10Physical properties porous
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2403/00Details of fabric structure established in the fabric forming process
    • D10B2403/01Surface features
    • D10B2403/011Dissimilar front and back faces
    • D10B2403/0112One smooth surface, e.g. laminated or coated
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel
    • D10B2501/06Details of garments
    • D10B2501/063Fasteners
    • D10B2501/0632Fasteners of the touch-and-close type

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Slide Fasteners, Snap Fasteners, And Hook Fasteners (AREA)
  • Adhesive Tapes (AREA)
  • Laminated Bodies (AREA)
  • Woven Fabrics (AREA)

Description

本発明は、面ファスナ用係合雌材及びその製造方法に関する。   The present invention relates to an engaging female member for a hook-and-loop fastener and a method for manufacturing the same.

係合雌材は、布帛と基材との間に接着剤層を配置してラミネートすることにより作製される。布帛は、間隔をおいて配置された経糸及び緯糸、並びに、ループ糸を有している。ループ糸は、例えば、布帛における接着剤層が配置された面と反対側の面から突出している。係合雌材は、ループ糸が係合雄材のフックと絡み合うことにより、係合システムとして機能している。   The engaging female member is produced by placing an adhesive layer between a fabric and a substrate and laminating. The fabric has warps and wefts arranged at intervals, and loop yarns. For example, the loop yarn protrudes from the surface of the fabric opposite to the surface on which the adhesive layer is disposed. The engaging female member functions as an engaging system when the loop yarn is entangled with the hook of the engaging male member.

欧州特許出願公開第0848938号明細書には、再係合可能な係合デバイスに適用可能な係合雌材が開示されている。米国特許出願公開第2006/0182927号明細書には、ベルクロファスナの複合材要素が開示されている。米国特許第5876532号明細書には、積層組立体の製造方法が開示されている。米国特許出願公開第2005/0208260号明細書には、面ファスナ、特にオムツファスナ用の結合材料が開示されている。   European Patent Application No. 0848938 discloses an engaging female member applicable to a re-engageable engaging device. US 2006/0182927 discloses a velcro fastener composite element. U.S. Pat. No. 5,876,532 discloses a method for manufacturing a laminated assembly. US 2005/0208260 discloses a binding material for hook and loop fasteners, in particular diaper fasteners.

欧州特許出願公開第0848938号明細書European Patent Application No. 08488938 米国特許出願公開第2006/0182927号明細書US Patent Application Publication No. 2006/0182927 米国特許第5876532号明細書US Pat. No. 5,876,532 米国特許出願公開第2005/0208260号明細書US Patent Application Publication No. 2005/0208260

ところで、近年、紙おむつ、フローリング床材、衣類等の多岐に渡る製品の信頼性に優れ、低目付の布帛であっても使用可能であると共に、安定した製造が可能な係合雌材が求められている。そのため、係合雌材における基材と布帛との層間剥離を起こさず、かつ、係合雄材との係合力を良好に保つことができると共に、ロール状態としたときにおける基材同士のブロッキングの発生を抑制することが重要となる。   By the way, in recent years, there has been a demand for an engaging female material that is excellent in the reliability of a wide variety of products such as disposable diapers, flooring flooring materials, clothing, etc., and can be used even with low-weight fabrics and can be stably manufactured. ing. Therefore, the delamination between the base material and the fabric in the engaging female material does not occur, the engaging force with the engaging male material can be kept good, and the occurrence of blocking between the base materials when in the roll state It is important to suppress this.

そこで、本発明は、基材と布帛との層間剥離を起こさず、かつ、係合雄材との係合力を良好に保つことができると共に、ロール状態としたときにおける基材同士のブロッキングの発生を抑制することができる面ファスナ用係合雌材及びその製造方法を提供する。   Therefore, the present invention does not cause delamination between the base material and the fabric, and can keep the engaging force with the engaging male material good, and the occurrence of blocking between the base materials when in the roll state. An engagement female material for a hook-and-loop fastener that can be suppressed and a method for manufacturing the same are provided.

本発明は、間隔をおいて配置された経糸(warp yarn)及び緯糸(weft yarn)、並びに少なくとも一方面から突出するループ糸(loop yarn)を有する、開口が形成された布帛と、平面状の基材と、布帛の一方面の糸(yarn)上に位置し、布帛及び基材を接合する接着剤層と、を備える面ファスナ用係合雌材であって、(接着剤層の開口率)/(布帛の開口率)の値が、0.1以上、1.0以下である、面ファスナ用係合雌材を提供する。   The present invention relates to a fabric having openings, having spaced warp and weft yarns, and loop yarns protruding from at least one side, An engaging female member for a hook-and-loop fastener, comprising: a base material; and an adhesive layer that joins the fabric and the base material and is located on a yarn on one side of the fabric, wherein the aperture ratio of the adhesive layer ) / (Fabric opening ratio) has a value of 0.1 or more and 1.0 or less.

「布帛の一方面の糸」には、布帛の一方面側に位置する経糸、緯糸及びループ糸の少なくとも1つ(好ましくは、経糸及び緯糸)が含まれる。なお、「布帛の開口」とは、向かい合う経糸及び向かい合う緯糸で囲まれる部分に形成される空間をいい、「布帛の開口率」とは、布帛の主面の面積(経糸、緯糸及びループ糸の存在する部分と全ての布帛の開口部分との合計面積)に対する、全ての布帛の開口部分の面積をいう。「接着剤層の開口」とは、向かい合う経糸上に位置する接着剤及び向かい合う緯糸上に位置する接着剤で囲まれる部分に形成される空間をいい、「接着剤層の開口率」は、接着剤層の主面の面積(接着剤の存在する部分と全ての接着剤層の開口部分との合計面積)に対する、全ての接着剤層の開口部分の面積をいう。   The “yarn on one side of the fabric” includes at least one of warp, weft and loop yarns (preferably warp and weft) located on one side of the fabric. The “fabric opening” means a space formed in a portion surrounded by facing warps and facing wefts, and “fabric opening ratio” means the area of the main surface of the fabric (warp, weft and loop yarns). The total area of all fabric openings relative to the existing area and the total area of all fabric openings). “Opening of the adhesive layer” means a space formed in a portion surrounded by the adhesive located on the opposite warp and the adhesive located on the opposite weft, and the “opening ratio of the adhesive layer” The area of the opening part of all the adhesive layers with respect to the area of the main surface of an adhesive layer (the total area of the part in which an adhesive exists, and the opening part of all the adhesive layers) is said.

また、本発明は、間隔をおいて配置された経糸及び緯糸、並びに少なくとも一方面から突出するループ糸を有する、開口が形成された布帛の、一方面の糸上に接着剤を塗布して、上記開口に対応した開口を有する接着剤層を形成するステップと、接着剤層上に平面状の基材を積層して、布帛及び基材を接合させ、(接着剤層の開口率)/(布帛の開口率)の値を、0.1以上、1.0以下とするステップと、を備える、面ファスナ用係合雌材の製造方法を提供する。   In the present invention, an adhesive is applied onto the yarn on one side of the fabric having openings, the warp and the weft arranged at intervals, and the loop yarn protruding from at least one side, A step of forming an adhesive layer having an opening corresponding to the opening, a planar base material is laminated on the adhesive layer, and the fabric and the base material are joined, and (opening ratio of the adhesive layer) / ( And a step of setting the value of the opening ratio of the fabric to 0.1 or more and 1.0 or less.

本発明によれば、基材と布帛との層間剥離を起こさず、かつ、係合雄材との係合力を良好に保つことができると共に、ロール状態としたときにおける基材同士のブロッキングを抑制することができる面ファスナ用係合雌材及びその製造方法を提供する。   According to the present invention, delamination between the base material and the fabric does not occur, the engaging force with the engaging male material can be kept good, and blocking between the base materials when in a roll state is suppressed. An engaging female member for a hook-and-loop fastener and a method for manufacturing the same are provided.

本発明の係合雌材及びそれを用いた面ファスナの一例を模式的に示す断面図である。It is sectional drawing which shows typically an example of the engaging female material of this invention, and a surface fastener using the same. 接着剤が塗布される前の布帛の概略平面図である。It is a schematic plan view of the fabric before an adhesive is applied. 接着剤を塗布した後に基材と接合した布帛の概略平面図である。It is a schematic top view of the fabric joined with the base material after apply | coating an adhesive agent. 接着剤をロールコーティングにより塗布する方法を示す模式図である。It is a schematic diagram which shows the method of apply | coating an adhesive agent by roll coating. 接着剤をロールコーティングにより塗布する方法を示す模式図である。It is a schematic diagram which shows the method of apply | coating an adhesive agent by roll coating. 市松模様のパターンの例を示す模式図である。It is a schematic diagram which shows the example of a checkered pattern. (a)比較例2及び(b)実施例3の係合雌材の光学顕微鏡写真である。It is an optical microscope photograph of the engaging female material of (a) Comparative example 2 and (b) Example 3.

以下、必要に応じて図面を参照しつつ、本発明の好適な実施形態について詳細に説明する。なお、図面中、同一要素には同一符号を付すこととし、重複する説明は省略する。また、上下左右等の位置関係は、特に断らない限り、図面に示す位置関係に基づくものとする。更に、図面の寸法比率は図示の比率に限られるものではない。   Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the drawings as necessary. In the drawings, the same elements are denoted by the same reference numerals, and redundant description is omitted. Further, the positional relationship such as up, down, left and right is based on the positional relationship shown in the drawings unless otherwise specified. Further, the dimensional ratios in the drawings are not limited to the illustrated ratios.

図1〜図3を参照して、本実施形態に係る係合雌材について説明する。図1は、本実施形態に係る係合雌材及びそれを用いた面ファスナの一例を模式的に示す断面図である。図2は、接着剤が塗布される前の布帛の概略平面図である。図3は、接着剤を塗布した後に基材と接合した布帛の概略平面図である。但し、図2では、ループ糸の図示が省略されており、図3では、ループ糸及び基材の図示が省略されている。   The engaging female member according to the present embodiment will be described with reference to FIGS. FIG. 1 is a cross-sectional view schematically showing an example of an engaging female member according to the present embodiment and a hook-and-loop fastener using the same. FIG. 2 is a schematic plan view of the fabric before the adhesive is applied. FIG. 3 is a schematic plan view of a fabric bonded to a substrate after applying an adhesive. However, in FIG. 2, the illustration of the loop yarn is omitted, and in FIG. 3, the illustration of the loop yarn and the base material is omitted.

本実施形態に係る係合雌材(面ファスナ用係合雌材)1は、布帛3と、接着剤層9と、基材21とを備える。布帛3は、間隔をおいて配置された経糸3a及び緯糸3b、並びに表面(一方面)5aから突出する複数のループ糸3cを有する。経糸3a及び緯糸3bは、例えば編組により互いに交差している。布帛3には、間隔をおいて経糸3a及び緯糸3bが配置されることにより複数の開口(布帛の開口)7が形成されている。接着剤層9は、表面5aと反対側の裏面5bの糸上に位置し、布帛3及び基材21を接合している。接着剤層9には、開口7に対応した複数の開口(接着剤層の開口)11が形成されている。開口11は、係合雌材1を厚み方向に見て開口7と重なるように形成されている。   An engaging female member (engaging female member for surface fastener) 1 according to the present embodiment includes a fabric 3, an adhesive layer 9, and a base material 21. The fabric 3 has warp yarns 3a and weft yarns 3b arranged at intervals, and a plurality of loop yarns 3c protruding from the surface (one surface) 5a. The warp 3a and the weft 3b cross each other, for example, by braiding. A plurality of openings (fabric openings) 7 are formed in the fabric 3 by arranging warps 3a and wefts 3b at intervals. The adhesive layer 9 is located on the yarn on the back surface 5b opposite to the front surface 5a, and joins the fabric 3 and the base material 21. A plurality of openings (openings of the adhesive layer) 11 corresponding to the openings 7 are formed in the adhesive layer 9. The opening 11 is formed to overlap the opening 7 when the engaging female member 1 is viewed in the thickness direction.

係合雌材1は、ループ糸3cが係合雄材31のフック33と絡み合うことにより、係合雄材31と係合する。係合雄材31としては、ループ糸3cと絡み合うことが可能なフック33を有する汎用のものを用いることができる。以下では、係合雌材1の布帛3、接着剤層9及び基材21について、更に説明する。   The engaging female member 1 is engaged with the engaging male member 31 by the loop yarn 3 c entangled with the hook 33 of the engaging male member 31. As the engaging male member 31, a general-purpose member having a hook 33 capable of being intertwined with the loop yarn 3c can be used. Below, the cloth 3, the adhesive bond layer 9, and the base material 21 of the engaging female material 1 are further demonstrated.

布帛3について説明する。経糸3a、緯糸3b及びループ糸3cのそれぞれは、1本のフィラメントであっても、複数のフィラメントの束であってもよい。布帛3は、経糸3a、緯糸3b及びループ糸3c以外の糸を含んでいてもよく、例えば経糸3a及び緯糸3bと交差する糸を含んでいてもよい。ループ糸3cは、少なくとも表面5aから突出していればよく、表面5a及び裏面5bから突出していてもよい。ループ糸3cは、経糸3a,緯糸3bのいずれかに編みこまれていればよく、経糸3a及び緯糸3bの両方に編みこまれていてもよい。   The fabric 3 will be described. Each of the warp 3a, the weft 3b, and the loop yarn 3c may be a single filament or a bundle of a plurality of filaments. The fabric 3 may include yarns other than the warp yarn 3a, the weft yarn 3b, and the loop yarn 3c. For example, the fabric 3 may include a yarn that intersects with the warp yarn 3a and the weft yarn 3b. The loop yarn 3c only needs to protrude from at least the front surface 5a, and may protrude from the front surface 5a and the back surface 5b. The loop yarn 3c only needs to be knitted into either the warp yarn 3a or the weft yarn 3b, and may be knitted into both the warp yarn 3a and the weft yarn 3b.

布帛3としては、例えばループ糸を有する3枚筬編物、2枚筬の編物、緯糸挿入編物、ラッセル編物その他の編物、ジャガード織その他の織物が用いられる。布帛3の素材としては、例えば、ナイロン、ポリエステル、ポリプロピレン、ポリウレタン、EVA(エチレン・ビニルアセテート)、ポリエチレン、ポリ乳酸が挙げられる。布帛3の素材は、1種を単独で又は2種以上組み合わせて使用することもできる。また、布帛3では、経糸3a、緯糸3b及びループ糸3cの素材がそれぞれ同じであっても、異なっていてもよい。   As the fabric 3, for example, a three-ply knitted fabric having a loop yarn, a two-ply knitted fabric, a weft insertion knitted fabric, a raschel knitted fabric and other knitted fabrics, a jacquard woven fabric and other woven fabrics are used. Examples of the material of the fabric 3 include nylon, polyester, polypropylene, polyurethane, EVA (ethylene / vinyl acetate), polyethylene, and polylactic acid. The raw material of the fabric 3 can also be used individually by 1 type or in combination of 2 or more types. Further, in the fabric 3, the materials of the warp 3a, the weft 3b, and the loop yarn 3c may be the same or different.

布帛3の秤量は、係合雄材31のフック33との係合力の維持、及び製造コストの観点から決めることができる。ある態様においては、10〜29g/mとすることができ、15〜24g/mであることがより好ましく、17〜22g/mであることが特に好ましい。 The weight of the fabric 3 can be determined from the viewpoint of maintaining the engagement force of the engagement male member 31 with the hook 33 and the manufacturing cost. In some embodiments, it can be a 10~29g / m 2, more preferably from 15~24g / m 2, and particularly preferably 17~22g / m 2.

次に、接着剤層9について説明する。接着剤層9は、裏面5bの経糸3a及び緯糸3b上に形成されている。また、ループ糸3cが裏面5bから突出している場合には、裏面5b側のループ糸3c上にも接着剤層9が形成される。接着剤層9は、係合雌材1を厚さ方向に見たときに経糸3a及び緯糸3bを完全に覆っていなくてもよく、接着剤層9に覆われていない経糸3a及び緯糸3bが存在していてもよい。   Next, the adhesive layer 9 will be described. The adhesive layer 9 is formed on the warp 3a and the weft 3b on the back surface 5b. When the loop yarn 3c protrudes from the back surface 5b, the adhesive layer 9 is also formed on the loop yarn 3c on the back surface 5b side. The adhesive layer 9 may not completely cover the warp 3a and the weft 3b when the engaging female member 1 is viewed in the thickness direction, and the warp 3a and the weft 3b not covered by the adhesive layer 9 May be present.

(接着剤層9の開口率)/(布帛3の開口率)は0.1以上である。この値が、0.1を下回ると、基材同士のブロッキングが起こりやすくなる傾向がある。(接着剤層9の開口率)/(布帛3の開口率)は、0.2以上であることが好ましく、0.3以上であることがより好ましい。一方、(接着剤層9の開口率)/(布帛3の開口率)は1.0以下であり、(接着剤層9の開口率)/(布帛3の開口率)が1.0の場合、接着剤が糸幅に沿って存在する状態となる。「基材と布帛との層間剥離防止(層間強度向上)」及び「基材同士のブロッキング発生抑制」という2つの特性のバランスという観点から、(接着剤層9の開口率)/(布帛3の開口率)は0.9以下であることが好ましく、0.8以下であることがより好ましい。   (Opening ratio of adhesive layer 9) / (opening ratio of fabric 3) is 0.1 or more. When this value is less than 0.1, blocking between the substrates tends to occur. (Opening ratio of adhesive layer 9) / (opening ratio of fabric 3) is preferably 0.2 or more, and more preferably 0.3 or more. On the other hand, (opening ratio of adhesive layer 9) / (opening ratio of fabric 3) is 1.0 or less, and (opening ratio of adhesive layer 9) / (opening ratio of fabric 3) is 1.0. The adhesive is present along the yarn width. From the viewpoint of the balance between the two characteristics of “preventing delamination between substrate and fabric (improving interlayer strength)” and “suppressing blocking between substrates”, (opening ratio of adhesive layer 9) / (of fabric 3) (Aperture ratio) is preferably 0.9 or less, and more preferably 0.8 or less.

「接着剤層9の開口率」は、以下のように測定できる。折れ曲がりやしわ等がない状態で、表面5aが平板に接するように係合雌材1を平板上に置く。係合雌材1に対して係合雌材1の厚さ方向に光を照射して平板に投影像を形成する。顕微鏡を用いて、少なくとも10個の開口11が含まれる視野を観察する。上記視野において平板上に形成される接着剤層9の投影像の面積から、かかる投影像面積における接着剤層9の開口率を測定し、この測定された値を面ファスナ用係合雌剤における「接着剤層9の開口率」とする。なお、面ファスナ用係合雌剤における「布帛3の開口率」も、接着剤層9の開口率と同様の手順により測定することができる。

The “opening ratio of the adhesive layer 9” can be measured as follows. The engaging female member 1 is placed on the flat plate so that the surface 5a is in contact with the flat plate without any bending or wrinkling. Light is irradiated to the engaging female member 1 in the thickness direction of the engaging female member 1 to form a projected image on the flat plate. A field of view including at least 10 apertures 11 is observed using a microscope. From the area of the projected image of the adhesive layer 9 formed on the flat plate in the field of view, the aperture ratio of the adhesive layer 9 in the projected image area is measured, and this measured value is used in the engaging female agent for the surface fastener. It is assumed that “the opening ratio of the adhesive layer 9”. The “opening ratio of the fabric 3” in the engaging female agent for surface fastener can also be measured by the same procedure as the opening ratio of the adhesive layer 9.

接着剤層9は、布帛3の裏面5bの糸上に、接着剤を後述するロールコーティングして形成されたものであることが好ましい。接着剤層9に用いられる接着剤は、係合雌材1の用途や使用環境に応じて任意に選択される接着剤であり、反応型ホットメルト接着剤が好ましい。反応型ホットメルト接着剤としては、例えば、ウレタン系、EVA系、アクリル系、酢酸ビニル系が挙げられ、中でも、良好な接着力及び高温下での安定性と柔軟性の観点から反応型ポリウレタンが好ましい。なお、反応型ホットメルト接着剤を使用することにより、溶剤の排出量を低減することができる。   The adhesive layer 9 is preferably formed by roll-coating an adhesive, which will be described later, on the yarn of the back surface 5b of the fabric 3. The adhesive used for the adhesive layer 9 is an adhesive that is arbitrarily selected according to the application and use environment of the engaging female member 1, and is preferably a reactive hot-melt adhesive. Examples of the reactive hot melt adhesive include urethane, EVA, acrylic, and vinyl acetate. Among them, reactive polyurethane is preferable from the viewpoint of good adhesive strength, stability at high temperature, and flexibility. preferable. In addition, the discharge amount of a solvent can be reduced by using a reactive hot melt adhesive.

接着剤には、必要に応じて添加剤を添加してもよい。添加剤としては、例えば、ブロッキング防止剤、顔料、染料、老化防止剤が挙げられる。添加剤は、1種を単独で又は2種以上組み合わせて使用することもできる。   You may add an additive to an adhesive agent as needed. Examples of the additive include an antiblocking agent, a pigment, a dye, and an antiaging agent. An additive can also be used individually by 1 type or in combination of 2 or more types.

次に、基材21について説明する。基材21は平面状であり、例えばフィルム、不織布が挙げられる。なお、基材21には接着剤層9との密着性を上げるための前処理を施すことができる。適当な前処理として、例えば、接着剤層9の側にコロナ放電処理を施すことや、一般的なプライマー処理(例えば、エチレンイミド、TBT(トリブチレンテレフタレート))を施すことが挙げられる。   Next, the base material 21 will be described. The base material 21 is planar, for example, a film and a nonwoven fabric are mentioned. The base material 21 can be subjected to a pretreatment for improving the adhesion with the adhesive layer 9. Appropriate pretreatments include, for example, performing a corona discharge treatment on the adhesive layer 9 side, and applying a general primer treatment (for example, ethyleneimide, TBT (tributylene terephthalate)).

基材21に用いるフィルムの素材としては、例えばナイロン、ポリエステル、ポリプロピレン、ポリウレタン、EVA、ポリエチレン、ポリ乳酸が挙げられ、中でも、形状安定性の観点から、2軸延伸ポリプロピレンフィルムが好ましい。フィルムの素材は、1種を単独で又は2種以上組み合わせて使用することもできる。   Examples of the film material used for the substrate 21 include nylon, polyester, polypropylene, polyurethane, EVA, polyethylene, and polylactic acid. Among them, a biaxially stretched polypropylene film is preferable from the viewpoint of shape stability. The film material can be used alone or in combination of two or more.

基材21に不織布を用いた場合には、通気性を持たせることができる。不織布は、例えば、SB(スパンボンド)、MB(メルトブロー)、SMS(スパンボンド・メルトブロー・スパンボンド)、スパンレース等の周知の製法により形成された合成繊維や天然繊維が挙げられる。不織布の素材として、ナイロン、ポリエステル、ポリプロピレン、ポリウレタン、EVA、ポリエチレン、ポリ乳酸が挙げられる。不織布の素材は、1種を単独で又は2種以上組み合わせて使用することもできる。   When a non-woven fabric is used for the substrate 21, air permeability can be imparted. Examples of the nonwoven fabric include synthetic fibers and natural fibers formed by a well-known manufacturing method such as SB (spunbond), MB (melt blow), SMS (spunbond / meltblown / spunbond), and spunlace. Examples of the nonwoven material include nylon, polyester, polypropylene, polyurethane, EVA, polyethylene, and polylactic acid. The raw material of a nonwoven fabric can also be used individually by 1 type or in combination of 2 or more types.

次に、本実施形態に係る係合雌材1の製造方法について説明する。本実施形態に係る係合雌材1の製造方法は、間隔をおいて配置された経糸3a及び緯糸3b、並びに表面5aから突出するループ糸3cを有する、開口7が形成された布帛3の、裏面5bの糸上に接着剤を塗布して、開口7に対応した開口11を有する接着剤層9を形成するステップと、接着剤層9上に平面状の基材21を積層して、布帛3及び基材21を接合させるステップとを備える。布帛3及び基材21を接合させるステップでは、(接着剤層9の開口率)/(布帛3の開口率)の値は、0.1以上、1.0以下とされる。上述の通り、(接着剤層9の開口率)/(布帛3の開口率)は、0.2以上であることが好ましく、0.3以上であることがより好ましい。一方、(接着剤層9の開口率)/(布帛3の開口率)は0.9以下であることが好ましく、0.8以下であることがより好ましい。本実施形態では、裏面5bの糸上への接着剤の塗布、並びに、布帛3と基材21との接合は、接着剤が開口7及び開口11を完全に覆うことなく実施される。   Next, the manufacturing method of the engaging female material 1 which concerns on this embodiment is demonstrated. The method of manufacturing the engaging female member 1 according to the present embodiment includes a warp 3a and a weft 3b arranged at intervals, and a loop 3 3c protruding from the surface 5a. A step of forming an adhesive layer 9 having an opening 11 corresponding to the opening 7 by applying an adhesive on the yarn of the back surface 5b, and laminating a planar substrate 21 on the adhesive layer 9, 3 and the base material 21 are joined. In the step of bonding the fabric 3 and the substrate 21, the value of (opening ratio of the adhesive layer 9) / (opening ratio of the fabric 3) is set to 0.1 or more and 1.0 or less. As described above, (opening ratio of adhesive layer 9) / (opening ratio of fabric 3) is preferably 0.2 or more, and more preferably 0.3 or more. On the other hand, (opening ratio of adhesive layer 9) / (opening ratio of fabric 3) is preferably 0.9 or less, and more preferably 0.8 or less. In the present embodiment, the application of the adhesive onto the yarn on the back surface 5 b and the joining of the fabric 3 and the base material 21 are performed without the adhesive completely covering the openings 7 and 11.

接着剤の塗布は、ロールコーティングにより実施されることが好ましい。図4及び図5を用いてロールコーティングについて説明する。ロールコーティングでは、布帛3の上に2本の加熱ロール15を配置し、2本の加熱ロール15間において接着剤13を溶融させる。加熱ロール15が回転することにより、溶融した接着剤13が加熱ロール15の外周全体を覆って付着すると共に、布帛3が搬送される。接着剤13は、裏面5bの経糸3a及び緯糸3bに接することにより、経糸3a及び緯糸3b上に転写塗布される。接着剤13の塗布量は、2本の加熱ロール15の間隔により制御される。経糸3a及び緯糸3bに転写塗布されない接着剤は、加熱ロール15の外周に付着したまま、加熱ロール15の回転により2本の加熱ロール15間に戻される。これにより、経糸3a及び緯糸3bに転写塗布されない接着剤が布帛3の開口7を覆うことを抑制することができる。したがって、上記(接着剤層9の開口率)/(布帛3の開口率)の値を容易に上記数値に制御することができる。   The adhesive is preferably applied by roll coating. Roll coating will be described with reference to FIGS. In roll coating, two heating rolls 15 are disposed on the fabric 3 and the adhesive 13 is melted between the two heating rolls 15. As the heating roll 15 rotates, the melted adhesive 13 covers and adheres to the entire outer periphery of the heating roll 15, and the fabric 3 is conveyed. The adhesive 13 is transferred and applied onto the warp 3a and the weft 3b by contacting the warp 3a and the weft 3b on the back surface 5b. The application amount of the adhesive 13 is controlled by the interval between the two heating rolls 15. The adhesive that is not transferred and applied to the warp 3 a and the weft 3 b is returned to the two heating rolls 15 by the rotation of the heating roll 15 while adhering to the outer periphery of the heating roll 15. Thereby, it can suppress that the adhesive agent which is not transfer-applied to the warp 3a and the weft 3b covers the opening 7 of the fabric 3. FIG. Therefore, the value of (opening ratio of adhesive layer 9) / (opening ratio of fabric 3) can be easily controlled to the above numerical value.

ロールコーティングによる接着剤13の塗布は、接着剤の塗布を容易に行うことができることから、粘度1500〜12000mPa・sの接着剤を用いて行われることが好ましい。接着剤13の塗布量、加熱温度、布帛3の搬送速度は、接着剤13・布帛3の種類やロールコーターの設備により適宜選択される。接着剤13の塗布は、加熱ロール15の回転速度及び布帛3の搬送速度を等しくすることが好ましい。この場合、接着剤13の供給と消費(塗布)のバランスがとれるため、接着剤の塊が布帛3に付着することを抑制することができる。   The application of the adhesive 13 by roll coating is preferably performed using an adhesive having a viscosity of 1500 to 12000 mPa · s because the adhesive can be easily applied. The application amount of the adhesive 13, the heating temperature, and the conveyance speed of the fabric 3 are appropriately selected depending on the type of the adhesive 13 and the fabric 3 and the equipment of the roll coater. It is preferable to apply the adhesive 13 so that the rotation speed of the heating roll 15 and the conveyance speed of the fabric 3 are equal. In this case, since supply and consumption (application) of the adhesive 13 can be balanced, it is possible to prevent the adhesive lump from adhering to the fabric 3.

ところで、フィルム状の基材に接着剤を全面塗布又はパターン塗布した後、基材と布帛とをドライラミネートする場合、基材における布帛の開口に対向する部分には接着剤が存在する。これにより、ラミネートの際に布帛の開口を接着剤が通過し、表面側のループ糸に接着剤が付着してしまう。そのため、ループ糸が布帛の表面に向かって倒れてしまい、ループ糸が係合雄材のフックと絡み合いづらくなる。   By the way, when the base material and the fabric are dry-laminated after the adhesive is applied to the entire surface of the film-like base material or the pattern is applied, the adhesive is present in the portion of the base material facing the opening of the fabric. As a result, the adhesive passes through the opening of the fabric during lamination, and the adhesive adheres to the loop yarn on the surface side. Therefore, the loop yarn falls toward the surface of the fabric, and the loop yarn is difficult to be entangled with the hook of the engaging male material.

また、Tダイノズルを用いて接着剤を塗布する場合には、Tダイリップにおける布帛のMD方向(長手方向)に沿った糸に接する部分では、Tダイリップから糸へ接着剤が連続して塗布され続けることとなる。そのため、Tダイリップの接着剤の供給量と消費量(塗布量)のバランスがとれている。一方、布帛の開口上を通過するTダイリップの部分は、開口部分では接着剤が消費されないことから、Tダイリップへの接着剤の供給量が消費量を上回ることとなる。そのため、Tダイリップに接着剤の塊が生じてしまう。そして、接着剤の供給に伴い接着剤の塊は大きくなり、ある程度の大きさになると布帛に付着してしまうこととなる。布帛に付着した接着剤の塊は、ラミネートした基材を巻き取る際にブロッキングの要因となり、係合雌材の生産性が低下する。更に、係合雌材と係合雄材との係合力や布帛と基材との間の層間強度等の諸特性が不安定となる。   Further, when the adhesive is applied using the T die nozzle, the adhesive is continuously applied from the T die lip to the yarn at the portion of the T die lip that contacts the yarn along the MD direction (longitudinal direction) of the fabric. It will be. Therefore, the supply amount and consumption amount (application amount) of the adhesive for the T die lip are balanced. On the other hand, in the portion of the T die lip that passes over the opening of the fabric, the adhesive is not consumed in the opening, and therefore the amount of adhesive supplied to the T die lip exceeds the consumption. Therefore, an adhesive lump is generated on the T die lip. As the adhesive is supplied, the lump of the adhesive grows, and when it reaches a certain size, it adheres to the fabric. The lump of adhesive adhering to the fabric becomes a blocking factor when the laminated base material is wound, and the productivity of the engaging female member is lowered. Furthermore, various characteristics such as the engaging force between the engaging female member and the engaging male member and the interlaminar strength between the fabric and the substrate become unstable.

一方、ロールコーティングにより得られた係合雌材1は、上述の通り経糸3a及び緯糸3bに転写塗布されない接着剤が開口7を覆うことが抑制されている。これにより、係合雄材31のフック33と絡み合う表面5a側のループ糸3cに接着剤が付着することや、接着剤の塊が布帛3に付着することが抑制されている。そのため、ロールコーティングにより得られた係合雌材1は、ドライラミネート等により得られる係合雌材と比較して、乾燥後の接着剤量が少ないにも関わらず、布帛3と基材21との間の層間強度が高く、係合雌材1と係合雄材31との係合力も高くなる。また、安定して接着剤を塗布することができるため、布帛3と基材21との間の層間強度や、係合雌材1と係合雄材31との係合力を安定させることができる。また、ロールコーティングを用いることにより、低目付の布帛を利用することが可能となる。   On the other hand, in the engaging female member 1 obtained by roll coating, the adhesive that is not transferred and applied to the warp 3a and the weft 3b is prevented from covering the opening 7 as described above. Thereby, it is suppressed that an adhesive adheres to the loop yarn 3c on the surface 5a side intertwined with the hook 33 of the engaging male member 31, and an adhesive lump adheres to the fabric 3. Therefore, although the engagement female material 1 obtained by roll coating has a smaller amount of adhesive after drying than the engagement female material obtained by dry lamination or the like, the fabric 3 and the base material 21 And the engaging force between the engaging female member 1 and the engaging male member 31 is also high. Further, since the adhesive can be stably applied, the interlayer strength between the fabric 3 and the base material 21 and the engaging force between the engaging female member 1 and the engaging male member 31 can be stabilized. Moreover, it becomes possible to utilize a fabric with a low basis weight by using roll coating.

更に、ロールコーティングの場合、基材21に近接した経糸3a及び緯糸3bだけでなく、基材21と離れて位置する経糸3a及び緯糸3bに対しても接着剤13が塗布される。そのため、布帛3と基材21との接合に多くの経糸3a及び緯糸3bが寄与することができるため、布帛3と基材21との間の層間強度を高めることができる。このように、ロールコーティングを用いることにより、係合雌材1の信頼性を向上させると共に、係合雌材1の安定した製造が可能となる。   Further, in the case of roll coating, the adhesive 13 is applied not only to the warp 3a and the weft 3b close to the base material 21, but also to the warp 3a and the weft 3b located away from the base material 21. Therefore, since many warps 3a and wefts 3b can contribute to the joining of the fabric 3 and the base material 21, the interlayer strength between the fabric 3 and the base material 21 can be increased. Thus, by using roll coating, the reliability of the engaging female member 1 can be improved and the engaging female member 1 can be stably manufactured.

以下に、本発明を実施例に基づいて具体的に説明するが、本発明はこれに限定されるものではない。   Hereinafter, the present invention will be specifically described based on examples, but the present invention is not limited thereto.

(実施例1〜6)
ロールコーティングを用いて、以下のように係合雌材を作製した。ロールコーター(松下工業(株)社製)を用いて、布帛としてのポリアミドトリコット22g/mに、表1に示す接着剤を塗布した。そして、接着剤を塗布した布帛と、表1に示す基材とをラミネートした。なお、接着剤の塗布量は、約2.5g/mとし、加熱ロールの温度は120℃程度とした。その後、ラミネートにより数十mの係合雌材を作製し、ロール状にして常温常湿で2〜3日間保管し、接着剤を硬化させた。
(Examples 1-6)
Using roll coating, an engaging female member was produced as follows. Using a roll coater (manufactured by Matsushita Kogyo Co., Ltd.), the adhesive shown in Table 1 was applied to 22 g / m 2 of polyamide tricot as a fabric. And the fabric which apply | coated the adhesive agent and the base material shown in Table 1 were laminated. The application amount of the adhesive was about 2.5 g / m 2 and the temperature of the heating roll was about 120 ° C. Thereafter, an engaging female material having a thickness of several tens of meters was produced by laminating, and was rolled and stored at room temperature and normal humidity for 2 to 3 days to cure the adhesive.

(比較例1〜5)
Tダイを用いて、以下のように係合雌材を作製した。Tダイ(ITWダイナテック社製)を用いて、布帛としてのポリアミドトリコット22g/mに、表1に示す接着剤を塗布した。そして、接着剤を塗布した布帛と、表1に示す基材とをラミネートした。なお、接着剤の塗布量は、約2.5g/mとし、Tダイの温度は120℃程度とした。その後、ラミネートにより数十mの係合雌材を作製し、ロール状にして常温常湿で2〜3日間保管し、接着剤を硬化させた。
(Comparative Examples 1-5)
Using the T-die, an engaging female member was produced as follows. The adhesive shown in Table 1 was applied to polyamide tricot 22 g / m 2 as a fabric using a T die (manufactured by ITW Dynatech). And the fabric which apply | coated the adhesive agent and the base material shown in Table 1 were laminated. The amount of adhesive applied was about 2.5 g / m 2 and the temperature of the T die was about 120 ° C. Thereafter, an engaging female material having a thickness of several tens of meters was produced by laminating, and was rolled and stored at room temperature and normal humidity for 2 to 3 days to cure the adhesive.

(比較例6〜9)
紐状に接着剤を塗布して、係合雌材を作製した。オメガコートノズルダイ(ITWダイナテック社製)を用いて、布帛としてのポリアミドトリコット22g/mに、表1に示す接着剤を塗布した。そして、オーブンで乾燥した後、接着剤を塗布した布帛と、表1に示す基材とをラミネートした。なお、接着剤の塗布量は、約2.5g/mとし、塗布における温度は120℃程度とした。その後、ラミネートにより数十mの係合雌材を作製し、ロール状にして常温常湿で2〜3日間保管し、接着剤を硬化させた。
(Comparative Examples 6-9)
An engaging female member was produced by applying an adhesive in a string shape. The adhesive shown in Table 1 was applied to a polyamide tricot 22 g / m 2 as a fabric using an omega coat nozzle die (ITW Dynatech). And after drying in oven, the fabric which apply | coated the adhesive agent and the base material shown in Table 1 were laminated. The application amount of the adhesive was about 2.5 g / m 2, and the temperature in application was about 120 ° C. Thereafter, an engaging female material having a thickness of several tens of meters was produced by laminating, and was rolled and stored at room temperature and normal humidity for 2 to 3 days to cure the adhesive.

(比較例10)
ドライラミネートを用いて、係合雌材を作製した。主剤(三井化学ポリウレタン社製、商品名:A969V)18質量部と、硬化剤(三井化学ポリウレタン社製、商品名:A5)6質量部と、シリカ(トクシールUSA:トクヤマ社製)1.5質量部とを混合して接着剤を調製した。この接着剤を表1に示す基材に全面塗布した。そして、オーブンで乾燥した後、接着剤を塗布した接着剤と、布帛としてのポリアミドトリコット22g/mとをラミネートした。なお、接着剤の塗布量は、約2.5g/mとした。その後、約35℃で2日ほど保管し、接着剤硬化を行った。
(Comparative Example 10)
An engaging female member was produced using a dry laminate. 18 parts by mass of main agent (Mitsui Chemicals Polyurethanes, trade name: A969V), 6 parts by weight of curing agent (Mitsui Chemicals Polyurethanes, trade name: A5), and 1.5 parts by mass of silica (Tokushia USA: Tokuyama) An adhesive was prepared by mixing the parts. This adhesive was applied to the entire surface of the substrate shown in Table 1. And after drying in oven, the adhesive agent which apply | coated the adhesive agent and the polyamide tricot 22g / m < 2 > as a fabric were laminated | stacked. The application amount of the adhesive was about 2.5 g / m 2 . Then, it stored at about 35 degreeC for about 2 days, and adhesive agent hardening was performed.

(比較例11)
図6に示す塗布領域2mm×2mmの市松模様のパターン塗布をドライラミネートにより行ったことを除き、比較例10と同様に係合雌材を作製した。図6中、符号17は接着剤が塗布されている領域を、符号19は接着剤が塗布されていない領域を示す。パターン塗布には、ドライラミネート用グラビアに2mm×2mmの市松模様をエッチング加工したものを用いた。
(Comparative Example 11)
An engaging female member was produced in the same manner as in Comparative Example 10, except that the checkered pattern application with a coating area of 2 mm × 2 mm shown in FIG. In FIG. 6, the code | symbol 17 shows the area | region where the adhesive agent is apply | coated, and the code | symbol 19 shows the area | region where the adhesive agent is not apply | coated. For pattern coating, a dry laminate gravure obtained by etching a checkered pattern of 2 mm × 2 mm was used.

作製した係合雌材について、以下の各評価を行った。各実施例及び比較例で用いた塗布方法、基材、接着剤及び各評価結果を表1に示す。なお、表1中の各材料の詳細は以下の通りである。
(基材)
BOPP:両面コロナ処理フィルム(フタムラ化学社製、商品名:FOR−2、厚さ:12μm)
NW1:不織布(三井化学社製、13g/m、ポリプロピレン、SMS)
(接着剤)
MA−3380S:湿気硬化型ポリウレタン接着剤(三井化学ポリウレタン社製、120℃における粘度1800mPa・s)
MA−3002T:湿気硬化型ポリウレタン接着剤(三井化学ポリウレタン社製、120℃における粘度3800mPa・s)
YR−346−1:湿気硬化型ポリウレタン接着剤(日立化成ポリマー社製、120℃における粘度12000mPa・s)
MA−6311:湿気硬化型ポリウレタン接着剤(三井化学ポリウレタン社製、130℃における12000mPa・s)
DH−792:ポリオレフィン熱可塑性接着剤(ノガワケミカル社製、130℃における7000mPa・s)
The following evaluation was performed about the produced engaging female material. Table 1 shows the coating method, base material, adhesive, and evaluation results used in each example and comparative example. The details of each material in Table 1 are as follows.
(Base material)
BOPP: Double-sided corona-treated film (Futamura Chemical Co., Ltd., trade name: FOR-2, thickness: 12 μm)
NW1: Non-woven fabric (Mitsui Chemicals, 13 g / m 2 , polypropylene, SMS)
(adhesive)
MA-3380S: Moisture curable polyurethane adhesive (manufactured by Mitsui Chemicals Polyurethanes, viscosity 1800 mPa · s at 120 ° C.)
MA-3002T: Moisture curable polyurethane adhesive (manufactured by Mitsui Chemicals Polyurethanes, viscosity 3800 mPa · s at 120 ° C.)
YR-346-1: Moisture curable polyurethane adhesive (manufactured by Hitachi Chemical Polymer Co., Ltd., viscosity 12000 mPa · s at 120 ° C.)
MA-6611: Moisture curable polyurethane adhesive (Mitsui Chemical Polyurethanes, 12000 mPa · s at 130 ° C.)
DH-792: polyolefin thermoplastic adhesive (manufactured by Nogawa Chemical Co., Ltd., 7000 mPa · s at 130 ° C.)

((接着剤層の開口率)/(布帛の開口率)の値の測定)
まず、ループ糸が突出する面が平板に接するように、実施例3で作製した係合雌材を折れ曲がりやしわ等がない状態で平板上に置いた。次に、係合雌材に対して係合雌材の厚さ方向に光を照射して平板に投影像を形成した。顕微鏡(キーエンス社製、商品名:VH−6200)を用いて、10個の接着剤層の開口が存在する視野を観察した(倍率:25倍)。上記視野において平板上に形成される接着剤層の投影像の面積から、接着剤層の開口率を測定した。また、平板上に置いた布帛を用いて、同様の手順により布帛3の開口率を算出した。算出した接着剤層の開口率及び布帛の開口率の値から、(接着剤層の開口率)/(布帛の開口率)の値を算出した。この測定を、別の視野を観察して、もう1回繰り返し、同様の方法で再度(接着剤層の開口率)/(布帛の開口率)の値を算出した。
(Measurement of (opening ratio of adhesive layer) / (opening ratio of fabric))
First, the engaging female member produced in Example 3 was placed on a flat plate without bending or wrinkles so that the surface from which the loop yarn protruded was in contact with the flat plate. Next, the engagement female member was irradiated with light in the thickness direction of the engagement female member to form a projected image on the flat plate. Using a microscope (manufactured by Keyence Corporation, trade name: VH-6200), a visual field where openings of 10 adhesive layers were present was observed (magnification: 25 times). From the area of the projected image of the adhesive layer formed on the flat plate in the field of view, the aperture ratio of the adhesive layer was measured. Moreover, the opening ratio of the fabric 3 was calculated in the same procedure using the fabric placed on a flat plate. The value of (opening ratio of the adhesive layer) / (opening ratio of the fabric) was calculated from the calculated opening ratio of the adhesive layer and the opening ratio of the fabric. This measurement was repeated once more while observing another visual field, and the value of (opening ratio of adhesive layer) / (opening ratio of fabric) was calculated again in the same manner.

上記同様の手順により、比較例2で作製した係合雌材についても(接着剤層の開口率)/(布帛の開口率)の値を算出した。実施例3及び比較例2についての(接着剤層の開口率)/(布帛の開口率)の値の算出結果を表2に示す。   By the same procedure as described above, the value of (opening ratio of adhesive layer) / (opening ratio of fabric) was also calculated for the engaging female member produced in Comparative Example 2. Table 2 shows the calculation results of the value of (opening ratio of adhesive layer) / (opening ratio of fabric) for Example 3 and Comparative Example 2.

(係合雌材と係合雄材との係合力の測定方法)
各実施例及び比較例により作製された係合雌材について測定を行った。50mm×100mmの鋼板に、両面接着テープを用いて鋼板とほぼ同サイズの係合雌材を固定した。25mm幅×20mm長の係合雄材を用意し、接着テープを用いて、25mm幅×200mm長、25μm厚みのPETフィルムの一端部を係合雄材の裏面に接合した。係合雄材の全面が係合雌材上となるように乗せて、2kgのローラーで1往復加重をかけて圧着し、係合雄材と係合雌材とを係合させた。次いで、係合雄材と接合されていないPETフィルムの他端部を水平方向に荷重1kgの錘で引っ張り、係合状態を安定化させた。なお、係合雄材のフックは、CS−600(住友スリーエム社製、ピン密度:1600ppi、先端形状:茸状)を用いた。
(Measuring method of engaging force between engaging female member and engaging male member)
Measurement was performed on the engaging female member produced in each example and comparative example. An engaging female member of approximately the same size as the steel plate was fixed to a 50 mm × 100 mm steel plate using a double-sided adhesive tape. An engagement male material having a width of 25 mm × 20 mm was prepared, and one end of a PET film having a width of 25 mm × 200 mm and a thickness of 25 μm was bonded to the back surface of the engagement male material using an adhesive tape. The entire surface of the engaging male member was placed on the engaging female member, and the reciprocating load was applied by a 2 kg roller, and the male male member was engaged with the engaging female member. Next, the other end of the PET film not joined to the engaging male member was pulled horizontally with a weight of 1 kg to stabilize the engaging state. Note that CS-600 (manufactured by Sumitomo 3M, pin density: 1600 ppi, tip shape: bowl-shaped) was used as the hook of the engaging male member.

そして、係合雌材と係合雄材との剥離力を、テンシロン引張試験機(島津製作所社製、商品名:AGS−100B)を用い、チャック間距離25mm、90度方向の引張りスピード300mm/分で測定し、係合雌材と係合雄材との係合力を求めた。なお、各実施例及び比較例により作製された係合雌材をそれぞれ6つ用意し、それぞれの測定値の平均値を係合力の値とした。   Then, using a Tensilon tensile tester (manufactured by Shimadzu Corporation, trade name: AGS-100B), the separation force between the engaging female member and the engaging male member is 25 mm between chucks and a pulling speed of 300 mm / min in the 90-degree direction. The engaging force between the engaging female member and the engaging male member was determined. Note that six engaging female members prepared according to the respective examples and comparative examples were prepared, and the average value of the respective measured values was used as the value of the engaging force.

(布帛と基材との間の層間強度の測定方法)
各実施例及び比較例により作製された係合雌材について測定を行った。接着剤で接着された布帛と基材とを25mm幅×100mm長の短冊状にカットし、基材裏面に補強材としてSTA−373接着テープ(住友スリーエム社製)を積層したものを試料とした。チャック間距離25mm、300mm/分のスピードで、布帛と基材とを180度方向に引っ張って剥離するときの接着力をテンシロン引張試験機(島津製作所社製、商品名:AGS−100B)を用いて測定し、布帛と基材との間の層間強度を求めた。なお、各実施例及び比較例により作製された係合雌材をそれぞれ6つ用意し、それぞれのサンプルにより得られた測定値の平均値を層間強度の値とした。
(Measurement method of interlayer strength between fabric and substrate)
Measurement was performed on the engaging female member produced in each example and comparative example. A sample obtained by cutting a fabric and a substrate bonded with an adhesive into a strip of 25 mm width × 100 mm length and laminating a STA-373 adhesive tape (manufactured by Sumitomo 3M) as a reinforcing material on the back surface of the substrate was used as a sample. . Using a Tensilon tensile tester (manufactured by Shimadzu Corporation, trade name: AGS-100B) for the adhesive force when the fabric and the substrate are pulled and peeled in the direction of 180 degrees at a distance between chucks of 25 mm and a speed of 300 mm / min. The interlayer strength between the fabric and the substrate was determined. Note that six engaging female members prepared in each example and comparative example were prepared, and the average value of the measured values obtained from each sample was used as the value of the interlayer strength.

(層間剥離の評価方法)
上述した係合力測定時に、布帛と基材との層間剥離が発生した場合を「あり」とし、発生しない場合を「なし」とした。
(Evaluation method of delamination)
When the above-described engagement force measurement, delamination between the fabric and the substrate occurred as “Yes”, and when it did not occur as “None”.

(ブロッキングの評価方法)
ロール状態の各実施例及び比較例の係合雌材について、ロール状を解いた際にラミネート基材同士が接着されている場合には、ブロッキング「あり」とし、ラミネート基材同士の接着がない場合には、ブロッキング「なし」とした。
(Blocking evaluation method)
When the laminated base materials are bonded to each other in the rolled state of each of the working examples and comparative examples when the roll shape is unwound, blocking is “present” and there is no adhesion between the laminated base materials. In this case, the blocking was “none”.

(布帛への接着剤塗布の安定性評価)
各実施例及び比較例により作製された係合雌材について、光学顕微鏡観察により布帛への接着剤塗布の安定性を評価した。評価は光学顕微鏡を用いて観察(倍率:25倍)することにより行った。図7に、(a)比較例2及び(b)実施例3の係合雌材の光学顕微鏡写真を示す。
(Stability evaluation of adhesive application to fabric)
About the engaging female material produced by each Example and the comparative example, stability of application | coating of the adhesive agent to a fabric was evaluated by optical microscope observation. Evaluation was performed by observing using an optical microscope (magnification: 25 times). In FIG. 7, the optical microscope photograph of the engaging female material of (a) Comparative example 2 and (b) Example 3 is shown.

(総合評価)
係合雌材では、係合雄材との係合により布帛と基材との層間剥離を起こさないように、布帛と基材との間の層間強度を保持している必要がある。一般的に、係合雌材と係合雄材との係合力が1.5〜4.5N/25mmであり、布帛と基材との間の層間強度が3N/25mm以上であれば、布帛と基材との層間剥離は起きにくい。
(Comprehensive evaluation)
In the engaging female member, it is necessary to maintain the interlayer strength between the fabric and the substrate so that the interlayer separation between the fabric and the substrate does not occur due to the engagement with the engaging male member. Generally, if the engaging force between the engaging female member and the engaging male member is 1.5 to 4.5 N / 25 mm and the interlayer strength between the fabric and the substrate is 3 N / 25 mm or more, Delamination with the substrate is unlikely to occur.

上記知見と生産性とを考慮し、以下の要件(1),(2)により、各実施例及び比較例により作製された係合雌材の総合評価を行った。具体的には、(1)及び(2)の条件を満たす場合を「A」、(1)又は(2)を満たす場合を「B」、(1)及び(2)を満たさない場合を「C」と評価した。
(1)接着剤の塊が布帛に付着せず、接着剤の付着によりループ糸が倒れず、ラミネート後のロール状態とした際にブロッキングが起きないこと。
(2)布帛と基材との間の層間強度が3N/25mm以上であり、かつ、係合雄材との係合により布帛と基材との層間剥離が起きないこと。
In consideration of the above knowledge and productivity, comprehensive evaluation of the engaging female material produced by each example and comparative example was performed according to the following requirements (1) and (2). Specifically, “A” is satisfied when the conditions of (1) and (2) are satisfied, “B” is satisfied when (1) or (2) is satisfied, and “1” is not satisfied when (1) and (2) are not satisfied. C ".
(1) The adhesive lump does not adhere to the fabric, the loop yarn does not fall down due to adhesion of the adhesive, and blocking does not occur when the roll state after lamination is obtained.
(2) The interlayer strength between the fabric and the substrate is 3 N / 25 mm or more, and the interlayer separation between the fabric and the substrate does not occur due to the engagement with the engaging male material.

(通気性の評価方法)
各実施例及び比較例により作製された係合雌材について、通気性評価装置(TOYOSEIKI社製、商品名:DENSOMETER)を用いて、ガーレ法により通気性を評価した。通気性「あり」とは、10秒/100CC以下であり、この値を越えるものは通気性「なし」とした。
(Breathability evaluation method)
About the engaging female material produced by each Example and the comparative example, air permeability was evaluated by the Gurley method using the air permeability evaluation apparatus (The product name: DENSOMETER, the product made by TOYOSEIKI). The air permeability “present” is 10 seconds / 100 CC or less, and those exceeding this value were regarded as “no air permeability”.

本発明の係合雌材は、紙おむつ、フローリング床材、衣類等の係合システムに好適に用いられる。   The engaging female material of this invention is used suitably for engaging systems, such as a paper diaper, a flooring floor material, and clothing.

1…係合雌材(面ファスナ用係合雌材)、3…布帛、3a…経糸、3b…緯糸、3c…ループ糸、5a…布帛の表面、5b…布帛の裏面、7…布帛の開口、9…接着剤層、11…接着剤層の開口、21…基材。   DESCRIPTION OF SYMBOLS 1 ... Engagement female material (engagement female material for surface fastener), 3 ... Fabric, 3a ... Warp, 3b ... Weft, 3c ... Loop yarn, 5a ... Fabric surface, 5b ... Fabric back surface, 7 ... Fabric opening , 9 ... Adhesive layer, 11 ... Opening of adhesive layer, 21 ... Base material.

Claims (5)

間隔をおいて配置された経糸及び緯糸、並びに少なくとも一方面から突出するループ糸を有する、開口が形成された布帛と、平面状の基材と、前記布帛の一方面の糸上に位置し、前記布帛及び前記基材を接合する接着剤層と、を備える面ファスナ用係合雌材であって、
(前記接着剤層の開口率)/(前記布帛の開口率)の値が、0.1以上、1.0以下である、面ファスナ用係合雌材。
Located on the yarn on one side of the fabric, a fabric having an opening, having warps and wefts arranged at intervals, and a loop yarn protruding from at least one side, a planar substrate, An engagement female material for a hook-and-loop fastener comprising the fabric and an adhesive layer that joins the base material,
An engaging female member for hook-and-loop fasteners having a value of (opening ratio of the adhesive layer) / (opening ratio of the fabric) of 0.1 or more and 1.0 or less.
前記基材は、不織布である、請求項1に記載の面ファスナ用係合雌材。   The engaging female member for a hook-and-loop fastener according to claim 1, wherein the base material is a non-woven fabric. 前記接着剤層は、前記布帛の一方面の糸上に接着剤をロールコーティングして形成されたものである、請求項1に記載の面ファスナ用係合雌材。   The engagement female material for a hook-and-loop fastener according to claim 1, wherein the adhesive layer is formed by roll-coating an adhesive on the yarn on one surface of the fabric. 間隔をおいて配置された経糸及び緯糸、並びに少なくとも一方面から突出するループ糸を有する、開口が形成された布帛の、一方面の糸上に接着剤を塗布して、前記開口に対応した開口を有する接着剤層を形成するステップと、
前記接着剤層上に平面状の基材を積層して、前記布帛及び前記基材を接合させ、(前記接着剤層の開口率)/(前記布帛の開口率)の値を、0.1以上、1.0以下とするステップと、を備える、面ファスナ用係合雌材の製造方法。
An opening corresponding to the opening is formed by applying an adhesive on the yarn on one side of a fabric having an opening formed having warps and wefts arranged at intervals and a loop yarn protruding from at least one side. Forming an adhesive layer having:
A flat base material is laminated on the adhesive layer, the fabric and the base material are joined, and the value of (opening ratio of the adhesive layer) / (opening ratio of the fabric) is 0.1. The manufacturing method of the engaging female material for hook-and-loop fasteners provided with the step made into 1.0 or less above.
前記接着剤の塗布は、ロールコーティングにより実施される、請求項4に記載の面ファスナ用係合雌材の製造方法。   The method for producing an engaging female material for a hook-and-loop fastener according to claim 4, wherein the adhesive is applied by roll coating.
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JP2009109532A JP5469368B2 (en) 2009-04-28 2009-04-28 Fitting female material for surface fastener and method for manufacturing the same
BRPI1007734A BRPI1007734A2 (en) 2009-04-28 2010-04-27 female coupling element for a hook and loop fastener and a method of preparing it
EP10772495.7A EP2424400A4 (en) 2009-04-28 2010-04-27 Engaging female member for a hook-and-loop fastener and a method for preparing the same
KR20117027969A KR20120023011A (en) 2009-04-28 2010-04-27 Engaging female member for a hook-and-loop fastener and a method for preparing the same
PCT/US2010/032494 WO2010129244A2 (en) 2009-04-28 2010-04-27 Engaging female member for a hook-and-loop fastener and a method for preparing the same
TW99113374A TW201102465A (en) 2009-04-28 2010-04-27 Engaging female member for a hook-and-loop fastener and a method for preparing the same
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WO2010129244A3 (en) 2011-02-24
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EP2424400A2 (en) 2012-03-07
JP2010253183A (en) 2010-11-11

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