JP5400525B2 - Surface treatment apparatus for cylinder barrel inner surface and surface treatment method thereof - Google Patents

Surface treatment apparatus for cylinder barrel inner surface and surface treatment method thereof Download PDF

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JP5400525B2
JP5400525B2 JP2009184933A JP2009184933A JP5400525B2 JP 5400525 B2 JP5400525 B2 JP 5400525B2 JP 2009184933 A JP2009184933 A JP 2009184933A JP 2009184933 A JP2009184933 A JP 2009184933A JP 5400525 B2 JP5400525 B2 JP 5400525B2
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cylinder barrel
processing liquid
cylinder
treatment
recess
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JP2011038137A (en
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裕行 成瀬
均 唐澤
亮太郎 高田
義光 小川
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Honda Motor Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/02Tanks; Installations therefor
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F1/00Etching metallic material by chemical means
    • C23F1/08Apparatus, e.g. for photomechanical printing surfaces
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/34Pretreatment of metallic surfaces to be electroplated
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • C25D7/04Tubes; Rings; Hollow bodies

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Electroplating Methods And Accessories (AREA)
  • Cylinder Crankcases Of Internal Combustion Engines (AREA)

Description

本発明は、シリンダブロックに設けられているシリンダバレルの内面へ処理液を接触させて内面を処理する、シリンダバレル内面の表面処理技術に関する。   The present invention relates to a surface treatment technique for an inner surface of a cylinder barrel in which a treatment liquid is brought into contact with an inner surface of a cylinder barrel provided in a cylinder block to treat the inner surface.

エンジンのシリンダバレル内面は、ピストンリングによる摩擦や燃料の燃焼による高熱に晒されるため、表面の強度が求められる。表面の強度を高めるには表面処理が有効である。表面処理の一つであるめっき処理を施す場合、めっき処理前に表面の汚れ等をあらかじめ除去することが望まれる。このように表面処理前に汚れ等を除去する処理は、前処理と呼ばれる。
めっき処理の前処理の一例を次図で説明する。
Since the inner surface of the cylinder barrel of the engine is exposed to high heat due to friction caused by piston rings and combustion of fuel, surface strength is required. Surface treatment is effective for increasing the strength of the surface. When performing a plating process which is one of the surface treatments, it is desired to remove surface stains and the like before the plating process. Such a process of removing dirt and the like before the surface treatment is called pretreatment.
An example of the pretreatment of the plating process will be described with reference to the following diagram.

図8に示されるように、前処理では、エッチング処理、酸活性処理、第1亜鉛置換処理、溶解活性処理及び第2亜鉛置換処理が実施される。エッチング処理だけでも、処理液による化学処理、洗浄のための1次水洗、2次水洗及び乾燥を防ぐアイドラー等複数の工程で構成される。これらの工程のうち、化学処理工程の具体例が提案されている(例えば、特許文献1(図3(b))参照。)。   As shown in FIG. 8, in the pretreatment, an etching treatment, an acid activation treatment, a first zinc substitution treatment, a dissolution activation treatment, and a second zinc substitution treatment are performed. The etching process alone is composed of a plurality of processes such as chemical treatment with a treatment liquid, primary water washing for washing, secondary water washing and an idler for preventing drying. Among these processes, a specific example of a chemical treatment process has been proposed (see, for example, Patent Document 1 (FIG. 3B)).

この特許文献1の技術を図面に基づいて以下に説明する。
図9に示されるように、シリンダブロック101を、下部開口閉塞部材103が備えられたパレット104に載置し、シリンダブロック101の下部開口を塞ぐ。そして、パレット104をパン105の上に配置し、ノズル106が備えられた蓋体107を、矢印(1)のように移動させ、シリンダブロック101の上部開口を塞ぐ。
The technique of this patent document 1 is demonstrated below based on drawing.
As shown in FIG. 9, the cylinder block 101 is placed on the pallet 104 provided with the lower opening closing member 103 to close the lower opening of the cylinder block 101. Then, the pallet 104 is placed on the pan 105, and the lid 107 provided with the nozzle 106 is moved as indicated by the arrow (1) to close the upper opening of the cylinder block 101.

処理液を、矢印(2)のように、処理液供給路108からノズル106に供給する。
供給された処理液は、矢印(3)のように、処理液噴射孔109からシリンダバレル110の下部に噴射され、矢印(4)のように、シリンダバレル110の内面に接触しながら上昇する。
シリンダバレル110内の処理液は、矢印(5)のように、主にパレット104に設けられた第1の排液通路111から排出され、処理液の残部は、矢印(6)のように蓋体107に設けられた第2の排液通路112から排出される。
The processing liquid is supplied from the processing liquid supply path 108 to the nozzle 106 as indicated by the arrow (2).
The supplied processing liquid is injected from the processing liquid injection hole 109 to the lower part of the cylinder barrel 110 as indicated by an arrow (3), and ascends while contacting the inner surface of the cylinder barrel 110 as indicated by an arrow (4).
The processing liquid in the cylinder barrel 110 is discharged mainly from the first drainage passage 111 provided in the pallet 104 as indicated by an arrow (5), and the remaining portion of the processing liquid is covered by a lid as indicated by an arrow (6). The liquid is discharged from the second drainage passage 112 provided in the body 107.

ところで、シリンダブロックには様々な形態がある。そこで、発明者らは、クランクケース部102がない形態のシリンダブロックに対して同様のエッチング処理を行った。   By the way, there are various forms of cylinder blocks. Therefore, the inventors performed the same etching process on a cylinder block having no crankcase portion 102.

図10に示されるように、ガスケット面113が上になるようにして、シリンダブロック114をパレット115に載置する。シール部材116で段部117がシールされる。また、シリンダバレル118の上部開口119に繋がる凹部120を有するカバー部材121でシリンダバレル118の上部開口119を覆う。カバー部材121には、シリンダバレル118の内面へ処理液を供給するノズル122が設けられ、このノズル122の下部に処理液を噴射する処理液噴射孔123が備えられている。   As shown in FIG. 10, the cylinder block 114 is placed on the pallet 115 with the gasket surface 113 facing upward. The step portion 117 is sealed by the seal member 116. Further, the upper opening 119 of the cylinder barrel 118 is covered with a cover member 121 having a recess 120 connected to the upper opening 119 of the cylinder barrel 118. The cover member 121 is provided with a nozzle 122 for supplying a processing liquid to the inner surface of the cylinder barrel 118, and a processing liquid injection hole 123 for injecting the processing liquid is provided below the nozzle 122.

このシリンダブロック114に、図9と同様にして処理液を供給したところ、次のような結果を得た。なお、図10の符号A、B、Cはシリンダバレル118内面の上部、中間部、下部における測定点を示す。
高温の処理液を処理液噴射孔123、123から噴射すると、処理液は、パレット115に溜まり、シリンダバレル118内を上昇し、凹部120に達する。結果、C点が最初に昇温し、B点がこれにつづき、A点が最後に昇温する。加えて、処理液はA点に達するまでに保有熱がシリンダバレル118に吸収されるために、温度が下がる。
この結果、図11に示すように、A点の昇温曲線とC点の昇温曲線との間に最大T1=25℃もの温度差が発生する。
When the processing liquid was supplied to the cylinder block 114 in the same manner as in FIG. 9, the following results were obtained. Note that reference symbols A, B, and C in FIG. 10 indicate measurement points at the upper, middle, and lower portions of the inner surface of the cylinder barrel 118.
When the high-temperature processing liquid is injected from the processing liquid injection holes 123 and 123, the processing liquid accumulates in the pallet 115, rises in the cylinder barrel 118, and reaches the recess 120. As a result, the temperature rises at point C first, point B continues, and point A heats up last. In addition, since the retained heat is absorbed by the cylinder barrel 118 until the processing liquid reaches the point A, the temperature of the processing liquid decreases.
As a result, as shown in FIG. 11, a temperature difference of maximum T1 = 25 ° C. occurs between the temperature rising curve at point A and the temperature rising curve at point C.

処理液によって、シリンダバレル表面をエッチング(腐食)処理するが、エッチング処理の大小は温度によって変化する。最大T1=25℃もの温度差は、エッチング処理に影響することが予想される。そこで、A点、B点、C点毎のエッチング量を調べた。   The cylinder barrel surface is etched (corroded) by the treatment liquid, and the magnitude of the etching treatment varies depending on the temperature. A temperature difference as high as T1 = 25 ° C. is expected to affect the etching process. Therefore, the etching amount for each of the points A, B, and C was examined.

図12(a)に示すように、B、C点では、エッチング量x1が充分であったが、A点では、エッチング量x1は少なかった。   As shown in FIG. 12A, the etching amount x1 was sufficient at the points B and C, but the etching amount x1 was small at the point A.

エッチング量が少ない、すなわち不十分であると、めっきの密着性が低下することが予想される。そこで、A点、B点、C点毎に、めっきの密着性を調べた。   When the etching amount is small, that is, when the etching amount is insufficient, it is expected that the adhesion of the plating is lowered. Therefore, the adhesion of plating was examined for each of points A, B, and C.

図12(b)示すように、この前処理を施したシリンダバレルに対してめっきすると、めっきの剥離幅y1は、B、C点では少なく、A点では大きくなることが判明した。これはシリンダバレル内面に温度差が生じたことにより、処理が不均一になることによるものである。すなわち、表面処理を均一化することができるシリンダバレル内面の表面処理技術が求められている。   As shown in FIG. 12B, when the cylinder barrel subjected to this pretreatment is plated, it has been found that the peeling width y1 of the plating is small at the points B and C and large at the point A. This is due to non-uniform processing due to the temperature difference on the inner surface of the cylinder barrel. That is, there is a need for a surface treatment technique for the inner surface of a cylinder barrel that can make the surface treatment uniform.

特開2008−214730公報JP 2008-214730 A

本発明は、表面処理を均一化することができるシリンダバレル内面の表面処理技術を提供することを課題とする。   An object of the present invention is to provide a surface treatment technique for the inner surface of a cylinder barrel that can make the surface treatment uniform.

請求項1に係る発明は、内燃機関のシリンダブロックに設けられているシリンダバレルの内面へ処理液を接触させて前記内面を処理する、シリンダバレル内面の表面処理装置であって、前記シリンダブロックのガスケット面が上になるようにして、前記シリンダブロックを支えると共にシリンダバレルの下部開口を塞ぐパレットと、このパレットに設けられ前記シリンダバレル内に溜められた前記処理液の一部を排出する第1の排液通路と、上方に窪むと共に前記シリンダバレルの上部開口に繋がる凹部を有し、前記ガスケット面に載せられ前記シリンダバレルの上部開口を覆うカバー部材と、このカバー部材から下へ延ばされ、前記処理液を前記凹部の壁に向かって噴射する処理液噴射孔を有し、前記凹部の壁を介して前記シリンダバレルの内面へ前記処理液を供給するノズルと、前記カバー部材に設けられ前記シリンダバレル内に溜められた前記処理液の残部を排出する第2の排液通路と、からなることを特徴とする。
An invention according to claim 1 is a surface treatment device for an inner surface of a cylinder barrel, wherein the inner surface of the cylinder barrel provided in the cylinder block of the internal combustion engine is brought into contact with a treatment liquid to treat the inner surface. A pallet that supports the cylinder block and closes the lower opening of the cylinder barrel with the gasket surface facing upward, and a first part that is provided on the pallet and discharges a part of the processing liquid stored in the cylinder barrel. a drainage passage, have a recess leading to the upper opening of the cylinder barrel with recessed upward, and a cover member for covering an upper opening of the cylinder barrel mounted on the gasket face, it extends down from the cover member is, includes a processing fluid spray nozzles for jetting towards said processing liquid on the wall of the recess, the cylinder barrel through a wall of said recess A nozzle for supplying a treatment fluid to the inner surface, and wherein the second drain passage, in that it consists of discharging a remaining portion of said processing liquid pooled in the cylinder barrel provided in the cover member.

請求項2に係る発明では、内燃機関のシリンダブロックに設けられているシリンダバレルの内面へ処理液を接触させて前記内面を処理する、シリンダバレル内面の表面処理方法であって、前記シリンダブロックのガスケット面が上になるようにして、シリンダバレルの下部開口を塞ぐパレットに前記シリンダブロックを載置する工程と、前記シリンダバレルの上部開口に前記処理液を供給するノズルを挿入しつつ、前記シリンダバレルの上部開口に繋がる凹部を下部に有するカバー部材で、前記シリンダバレルの上部開口を覆う工程と、前記ノズルに設けられた処理液噴射孔から前記処理液を前記凹部の壁に向かって噴射して、前記凹部の壁を介して前記シリンダバレルの内面へ前記処理液を供給する工程と、前記シリンダバレル内に溜められた前記処理液の一部を、前記パレットに設けられた第1の排液通路から排出すると共に、前記シリンダバレル内に溜められた前記処理液の残部を、前記カバー部材に設けられた第2の排液通路から排出する工程と、からなることを特徴とする。   The invention according to claim 2 is a surface treatment method for an inner surface of a cylinder barrel, wherein a treatment liquid is brought into contact with an inner surface of a cylinder barrel provided in a cylinder block of an internal combustion engine to treat the inner surface. Placing the cylinder block on a pallet that closes the lower opening of the cylinder barrel with the gasket surface facing upward, and inserting the nozzle for supplying the processing liquid into the upper opening of the cylinder barrel, A cover member having a concave portion connected to the upper opening of the barrel at the lower portion, covering the upper opening of the cylinder barrel, and injecting the processing liquid from the processing liquid injection hole provided in the nozzle toward the wall of the concave portion. Supplying the treatment liquid to the inner surface of the cylinder barrel through the wall of the recess, and collecting the treatment liquid in the cylinder barrel. A part of the processing liquid is discharged from a first drainage passage provided in the pallet, and a remaining part of the processing liquid stored in the cylinder barrel is provided in a second member provided in the cover member. And a step of discharging from the drainage passage.

請求項1に係る発明は、シリンダバレルの上部開口に繋がる凹部を下部に有し、ガスケット面に載せられシリンダバレルの上部開口を覆うカバー部材と、このカバー部材に取付けられ、処理液を凹部の壁に向かって噴射する処理液噴射孔を有し、凹部の壁を介してシリンダバレルの内面へ処理液を供給するノズルとを備えている。シリンダバレル内面に直接処理液を噴射するのではなく、凹部に処理液を噴射するので、処理液が直接あたる部分への優先的な反応を防止し、反応を均一にすることができる。結果、シリンダバレル内面のエッチング処理が均一になるので、めっきの密着性の向上を図ることができる。   The invention according to claim 1 has a concave portion connected to the upper opening of the cylinder barrel at the lower portion, a cover member that is placed on the gasket surface and covers the upper opening of the cylinder barrel, and is attached to the cover member. A nozzle for supplying a processing liquid to the inner surface of the cylinder barrel through the wall of the recess; Since the processing liquid is not sprayed directly onto the inner surface of the cylinder barrel, but the processing liquid is sprayed into the concave portion, it is possible to prevent a preferential reaction to the portion directly hit with the processing liquid and make the reaction uniform. As a result, since the etching process on the inner surface of the cylinder barrel becomes uniform, the adhesion of the plating can be improved.

請求項2に係る発明では、ノズルに設けられた処理液噴射孔から処理液を凹部の壁に向かって噴射して、凹部の壁を介してシリンダバレルの内面へ処理液を供給する工程と、シリンダバレル内に溜められた処理液の一部を、パレットに設けられた第1の排液通路から排出すると共に、シリンダバレル内に溜められた処理液の残部を、カバー部材に設けられた第2の排液通路から排出する工程とからなる。肉厚の厚いシリンダバレル上方から処理液を投入し、再び下方から液面を上昇させて処理液を循環させることで、シリンダバレル内面の上部と下部との温度差を低減させることができ、表面処理を均一にすることができる。結果、シリンダバレル内面のエッチング処理が均一になるので、めっきの密着性の向上を図ることができる。   In the invention according to claim 2, the step of injecting the processing liquid from the processing liquid injection hole provided in the nozzle toward the wall of the recess and supplying the processing liquid to the inner surface of the cylinder barrel through the wall of the recess; A part of the processing liquid stored in the cylinder barrel is discharged from the first drain passage provided in the pallet, and the remaining part of the processing liquid stored in the cylinder barrel is provided in the cover member. And a step of discharging from the two drainage passages. By introducing the treatment liquid from above the thick cylinder barrel and increasing the liquid level from below again to circulate the treatment liquid, the temperature difference between the upper and lower parts of the cylinder barrel inner surface can be reduced. Processing can be made uniform. As a result, since the etching process on the inner surface of the cylinder barrel becomes uniform, the adhesion of the plating can be improved.

本発明に係るシリンダバレル内面の表面処理装置の側面図である。It is a side view of the surface treatment apparatus of the cylinder barrel inner surface which concerns on this invention. 本発明の要部の断面図である。It is sectional drawing of the principal part of this invention. シリンダブロックをセットする工程の説明図である。It is explanatory drawing of the process of setting a cylinder block. シリンダブロックに表面処理を施す工程の説明図である。It is explanatory drawing of the process of surface-treating to a cylinder block. 本発明におけるシリンダバレル内面の温度変化を示す図である。It is a figure which shows the temperature change of the cylinder barrel inner surface in this invention. 本発明と従来の技術における温度差の比較図である。It is a comparison figure of the temperature difference in this invention and a prior art. 本発明におけるエッチング量及びめっきの密着性を示す図である。It is a figure which shows the etching amount in this invention, and the adhesiveness of plating. めっきの前処理工程を説明する図である。It is a figure explaining the pretreatment process of plating. 従来の技術の基本原理を説明する図である。It is a figure explaining the basic principle of the prior art. 従来の技術をクランクケース部がないシリンダブロックに使用した例を説明する図である。It is a figure explaining the example which used the prior art for the cylinder block without a crankcase part. 従来の技術におけるシリンダバレル内面の温度変化を示す図である。It is a figure which shows the temperature change of the cylinder barrel inner surface in a prior art. 従来の技術におけるエッチング量及びめっきの密着性を示す図である。It is a figure which shows the etching amount and the adhesiveness of plating in a prior art.

本発明の実施の形態を添付図に基づいて以下に説明する。なお、図面は符号の向きに見るものとする。   Embodiments of the present invention will be described below with reference to the accompanying drawings. The drawings are viewed in the direction of the reference numerals.

本発明の実施例を図面に基づいて説明する。
図1に示されるように、シリンダバレル内面の表面処理装置10は、アジャスタ11を有するベース12と、このベース12から立ち上げられている下部柱13と、下部柱13の上端に設けられている中部支持部材15と、この中部支持部材15に支持され処理液を集めるパン16と、このパン16に集められた処理液を外部に出す処理液排出管14と、パン16の上に設けられている囲い部材17と、この囲い部材17に囲われるように中部支持部材15に設けられている表面処理部20と、この表面処理部20に設けられ表面処理部20の上部からの排液を誘導する排液管21と、この排液管21の排液を監視する処理液検知部22と、中部支持部材15から立ち上げられている中部柱23と、この中部柱23の上端に設けられている上部支持部材24と、この上部支持部材24から立ち上げられている上部柱25と、この上部柱25の上端に設けられている天板26とを備える。
Embodiments of the present invention will be described with reference to the drawings.
As shown in FIG. 1, the surface treatment apparatus 10 on the inner surface of the cylinder barrel is provided on a base 12 having an adjuster 11, a lower column 13 rising from the base 12, and an upper end of the lower column 13. An intermediate support member 15, a pan 16 that is supported by the intermediate support member 15 and collects the processing liquid, a processing liquid discharge pipe 14 that discharges the processing liquid collected in the pan 16, and a pan 16 are provided. The surrounding member 17, the surface treatment unit 20 provided in the middle support member 15 so as to be surrounded by the enclosure member 17, and the drainage from the upper part of the surface treatment unit 20 provided in the surface treatment unit 20 A drainage pipe 21, a treatment liquid detection unit 22 that monitors the drainage of the drainage pipe 21, a middle column 23 raised from the middle support member 15, and an upper end of the middle column 23. On Comprises a support member 24, the upper column 25 has been raised from the upper support member 24, a top plate 26 provided at the upper end of the upper column 25.

表面処理部20は、詳細は後述するが、表面処理が施されるシリンダブロック27を支えるパレット31と、シリンダブロック27の上部を覆うカバー部材32と、このカバー部材32に設けられ処理液の一部を排出する第2の排液通路33とを備える。   The surface treatment unit 20, which will be described in detail later, includes a pallet 31 that supports the cylinder block 27 on which the surface treatment is performed, a cover member 32 that covers the top of the cylinder block 27, and one of the treatment liquids provided on the cover member 32. And a second drainage passage 33 for discharging the part.

また、シリンダバレル内面の表面処理処置10は、天板26に設けられ昇降ロッド34を介してカバー部材32を昇降させる昇降シリンダ35と、昇降ロッド34の下端に回転軸36を中心に揺動自在に設けられている揺動部37と、昇降ロッド34の下部に設けられ進退ロッド38を介して揺動部37を揺動させる揺動シリンダ41とを備える。   Further, the surface treatment 10 on the inner surface of the cylinder barrel is swingable about a rotary shaft 36 at the lower end of the lifting rod 34 and the lifting cylinder 35 provided on the top plate 26 for lifting the cover member 32 via the lifting rod 34. And an oscillating cylinder 41 which is provided below the elevating rod 34 and oscillates the oscillating portion 37 via an advancing / retreating rod 38.

次にシリンダバレル内面の表面処理装置10の要部について説明する。
図2に示されるように、シリンダバレル内面の表面処理装置10の要部としての表面処理部20は、シリンダブロック27のガスケット面42が上になるようにして、シリンダブロック27を支えると共にシリンダバレル43の下部開口44を塞ぐパレット31と、このパレット31に設けられシリンダバレル43内に溜められた処理液の一部を排出する第1の排液通路45と、パレット31に設けられシリンダブロック27の段部46をシールする段部シール部材47と、パレット31に設けられシリンダブロック27の穴48の位置決めをする位置決めピン51と、シリンダバレル43の上部開口52に繋がる凹部53を有し、ガスケット面42に載せられシリンダバレル43の上部開口52を覆うカバー部材32と、このカバー部材32の下端に設けられガスケット面42をシールするガスケット面シール部材54と、カバー部材32に上から下向きに挿入されるようにしてカバー部材32に取付けられ、処理液を凹部53の壁55に向かって噴射する処理液噴射孔56を有し、凹部53の壁55を介してシリンダバレル43の内面へ処理液を供給するノズル57と、このノズル57に処理液を供給する処理液供給路58と、カバー部材32に設けられシリンダバレル43内に溜められた処理液の残部を排出する第2の排液通路33と、からなる。
Next, the main part of the surface treatment apparatus 10 on the cylinder barrel inner surface will be described.
As shown in FIG. 2, the surface treatment unit 20 as a main part of the surface treatment device 10 on the cylinder barrel inner surface supports the cylinder block 27 so that the gasket surface 42 of the cylinder block 27 faces upward and supports the cylinder barrel. A pallet 31 that closes the lower opening 44 of the cylinder 43, a first drainage passage 45 that is provided on the pallet 31 and discharges a part of the processing liquid stored in the cylinder barrel 43, and a cylinder block 27 that is provided on the pallet 31. A step seal member 47 for sealing the step portion 46 of the cylinder block 27, a positioning pin 51 for positioning the hole 48 of the cylinder block 27 provided on the pallet 31, and a recess 53 connected to the upper opening 52 of the cylinder barrel 43. A cover member 32 placed on the surface 42 and covering the upper opening 52 of the cylinder barrel 43, and the cover member 3 A gasket surface sealing member 54 that seals the gasket surface 42 and is attached to the cover member 32 so as to be inserted downward into the cover member 32, and the processing liquid is directed toward the wall 55 of the recess 53. A nozzle 57 for supplying the processing liquid to the inner surface of the cylinder barrel 43 through the wall 55 of the recess 53, a processing liquid supply path 58 for supplying the processing liquid to the nozzle 57, The second drainage passage 33 is provided in the cover member 32 and discharges the remaining portion of the processing liquid stored in the cylinder barrel 43.

以上の述べたシリンダバレル内面の表面処理装置10の作用を図3〜図4に述べる。先ず、図3ではシリンダブロック27を表面処理装置10にセットするまでの工程を示す。
図3(a)は、シリンダブロック27を載置する工程を示す。シリンダブロック27を、矢印(7)のように、シリンダブロック27のガスケット面42が上になるようにして、シリンダバレル47の下部開口44を塞ぐパレット31に載置する。位置決めピン51が穴48に入れることで、シリンダブロック27が位置決めされる。
The operation of the surface treatment apparatus 10 on the inner surface of the cylinder barrel described above will be described with reference to FIGS. First, FIG. 3 shows steps until the cylinder block 27 is set in the surface treatment apparatus 10.
FIG. 3A shows a process of placing the cylinder block 27. The cylinder block 27 is placed on the pallet 31 that closes the lower opening 44 of the cylinder barrel 47 so that the gasket surface 42 of the cylinder block 27 faces upward as indicated by an arrow (7). The cylinder block 27 is positioned by inserting the positioning pin 51 into the hole 48.

図3(b)は、上部開口52を覆う工程を示す。カバー部材32を、矢印(8)のように移動させ、シリンダバレル43の上部開口52にノズル57を挿入しつつ、シリンダバレル43の上部開口52を覆う。   FIG. 3B shows a process of covering the upper opening 52. The cover member 32 is moved as indicated by an arrow (8), and the nozzle 57 is inserted into the upper opening 52 of the cylinder barrel 43, and the upper opening 52 of the cylinder barrel 43 is covered.

図4(a)は、処理液を供給する工程を示す。処理液を、矢印(9)のように供給し、処理液噴射孔56から凹部53の壁55に向かって噴射する。処理液は、矢印(10)のように、凹部53の壁55を介してシリンダバレル43の内面へ供給される。   FIG. 4A shows a process of supplying the treatment liquid. The processing liquid is supplied as indicated by an arrow (9), and sprayed from the processing liquid spray hole 56 toward the wall 55 of the recess 53. The processing liquid is supplied to the inner surface of the cylinder barrel 43 through the wall 55 of the recess 53 as indicated by an arrow (10).

図4(b)は、処理液を第1の排液通路から排出する工程を示す。シリンダバレル43内に溜められた処理液の一部は、矢印(11)のように、第1の排液通路45から排出される。処理液の供給量は、第1の排液通路45から排出される量よりも多い。そのため、処理液は矢印(12)のように、シリンダバレル43内を上昇する。ノズル57がシリンダバレル43の下方まで延びていることで、シリンダバレル43内面とノズル57外面で形成される空間の体積が小さくなるので、処理液の上昇が速くなり、処理に掛かる工数を短縮することができる。   FIG. 4B shows a step of discharging the processing liquid from the first drainage passage. A part of the processing liquid stored in the cylinder barrel 43 is discharged from the first drainage passage 45 as indicated by an arrow (11). The supply amount of the processing liquid is larger than the amount discharged from the first drainage passage 45. Therefore, the processing liquid ascends in the cylinder barrel 43 as indicated by an arrow (12). Since the volume of the space formed by the inner surface of the cylinder barrel 43 and the outer surface of the nozzle 57 is reduced by the nozzle 57 extending to the lower side of the cylinder barrel 43, the processing liquid rises faster and the number of processes is shortened. be able to.

図4(c)は、処理液を第2の排液通路から排出する工程を示す。シリンダバレル43内に溜められた処理液の残部は、矢印(13)のように、第2の排液通路33から排出される。なお、処理液検知部(図1、符号22)により排液を監視することで、表面処理を確実に実施することができる。   FIG. 4C shows a step of discharging the processing liquid from the second drainage passage. The remainder of the processing liquid stored in the cylinder barrel 43 is discharged from the second drainage passage 33 as shown by an arrow (13). In addition, surface treatment can be reliably implemented by monitoring a drainage liquid by a process liquid detection part (FIG. 1, code | symbol 22).

次に、本発明者らは、図2に示す点A、点B、点Cにおける温度変化を調べた。この結果を、次図で説明する。
図5に示すように、シリンダバレル43の下部と中間部にあるB、C点では、高温の処理液を供給すると直ぐに、温度が上昇した。上部にあるA点においても、図11の従来例に比較して温度上昇が速い結果を得た。これは、高温の処理液をシリンダバレル43内面の上方から供給したことで、先ず、A点に処理液の保有熱が渡されて最初に昇温したことによる。なお、T2は、最大温度差を示す。
Next, the inventors examined temperature changes at points A, B, and C shown in FIG. The result will be described with reference to the next figure.
As shown in FIG. 5, at the points B and C at the lower part and the middle part of the cylinder barrel 43, the temperature immediately increased when the high-temperature treatment liquid was supplied. Also at the point A at the upper part, a result that the temperature rise was faster than the conventional example of FIG. 11 was obtained. This is because the high-temperature processing liquid was supplied from above the inner surface of the cylinder barrel 43, and first, the retained heat of the processing liquid was transferred to point A and the temperature was first raised. T2 represents the maximum temperature difference.

次に、図2の実施例における温度差と図10の従来例における温度差を比較した。この結果を、次図で説明する。
図6に示されるように、従来例の最大温度差T1=25℃であるのに対し、実施例の最大温度差T2=12℃である。処理液の供給開始後直ぐの時点において、実施例はシリンダバレル内面の位置の違いによる温度差が15℃以下であり小さい。実施例は従来例に比較して、シリンダバレル内面の温度が均一であることが分かる。
Next, the temperature difference in the example of FIG. 2 was compared with the temperature difference in the conventional example of FIG. The result will be described with reference to the next figure.
As shown in FIG. 6, the maximum temperature difference T1 = 25 ° C. in the conventional example, whereas the maximum temperature difference T2 = 12 ° C. in the example. Immediately after the start of the supply of the treatment liquid, the embodiment has a small temperature difference of 15 ° C. or less due to the difference in position of the cylinder barrel inner surface. It can be seen that the temperature of the inner surface of the cylinder barrel is more uniform in the example than in the conventional example.

温度差を15℃以下に低減させたことは、エッチング処理への影響も低減することが予想される。そこで、A点、B点、C点毎のエッチング量を調べた。この結果を、次図で説明する。   Reducing the temperature difference to 15 ° C. or less is expected to reduce the influence on the etching process. Therefore, the etching amount for each of the points A, B, and C was examined. The result will be described with reference to the next figure.

図7(a)に示されるように、A、B、C点共に、エッチング量x2が2.5μm以上あり、エッチング量は充分である。
エッチング量が充分であると、めっきの密着性が向上することが予想される。そこで、A点、B点、C点毎に、めっきの密着性を調べた。この結果を、次図で説明する。
As shown in FIG. 7A, the etching amount x2 is 2.5 μm or more at points A, B, and C, and the etching amount is sufficient.
If the etching amount is sufficient, it is expected that the adhesion of plating is improved. Therefore, the adhesion of plating was examined for each of points A, B, and C. The result will be described with reference to the next figure.

図7(b)示すように、この前処理を施したシリンダバレルに対してめっきすると、めっきの剥離幅y2が、A、B、C点共に少ない。これはシリンダバレル内面の温度差が小さいことにより、処理が均一化されたことを示す。   As shown in FIG. 7B, when the cylinder barrel subjected to this pretreatment is plated, the peeling width y2 of the plating is small at all points A, B, and C. This indicates that the processing is made uniform because of the small temperature difference on the inner surface of the cylinder barrel.

尚、本発明に係るシリンダバレルの表面処理技術は、実施の形態ではめっきの前処理に適用したが、めっきの前処理に限定されず、シリンダバレルの内面の表面処理であれば、他の表面処理工程に適用することは差し支えない。   The surface treatment technology for the cylinder barrel according to the present invention is applied to the pretreatment for plating in the embodiment, but is not limited to the pretreatment for plating. It can be applied to processing steps.

本発明のシリンダバレル内面の表面処理技術は、シリンダバレル内面のめっきの前処理に好適である。   The surface treatment technology for the cylinder barrel inner surface of the present invention is suitable for pretreatment of plating on the cylinder barrel inner surface.

10…シリンダバレル内面の表面処理装置、20…表面処理部、27…シリンダブロック、31…パレット、32…カバー部材、33…第2の排液通路、42…ガスケット面、43…シリンダバレル、44…下部開口、45…第1の排液通路、52…上部開口、53…凹部、55…壁、56…処理液噴射孔、57…ノズル。   DESCRIPTION OF SYMBOLS 10 ... Surface treatment apparatus of cylinder barrel inner surface, 20 ... Surface treatment part, 27 ... Cylinder block, 31 ... Pallet, 32 ... Cover member, 33 ... 2nd drainage passage, 42 ... Gasket surface, 43 ... Cylinder barrel, 44 ... lower opening, 45 ... first drainage passage, 52 ... upper opening, 53 ... recess, 55 ... wall, 56 ... treatment liquid injection hole, 57 ... nozzle.

Claims (2)

内燃機関のシリンダブロックに設けられているシリンダバレルの内面へ処理液を接触させて前記内面を処理する、シリンダバレル内面の表面処理装置であって、
前記シリンダブロックのガスケット面が上になるようにして、前記シリンダブロックを支えると共にシリンダバレルの下部開口を塞ぐパレットと、
このパレットに設けられ前記シリンダバレル内に溜められた前記処理液の一部を排出する第1の排液通路と、
上方に窪むと共に前記シリンダバレルの上部開口に繋がる凹部を有し、前記ガスケット面に載せられ前記シリンダバレルの上部開口を覆うカバー部材と、
このカバー部材から下へ延ばされ、前記処理液を前記凹部の壁に向かって噴射する処理液噴射孔を有し、前記凹部の壁を介して前記シリンダバレルの内面へ前記処理液を供給するノズルと、
前記カバー部材に設けられ前記シリンダバレル内に溜められた前記処理液の残部を排出する第2の排液通路と、
からなることを特徴とするシリンダバレル内面の表面処理装置。
A surface treatment device for an inner surface of a cylinder barrel for treating the inner surface by bringing a treatment liquid into contact with an inner surface of a cylinder barrel provided in a cylinder block of an internal combustion engine,
A pallet that supports the cylinder block and closes the lower opening of the cylinder barrel, with the gasket surface of the cylinder block facing up,
A first drainage passage for discharging a part of the processing liquid provided in the pallet and stored in the cylinder barrel;
A cover member have a recess leading to the upper opening of the cylinder barrel with recessed upward, is placed on the gasket surface to cover the upper opening of the cylinder barrel,
A treatment liquid injection hole that extends downward from the cover member and injects the treatment liquid toward the wall of the recess, and supplies the treatment liquid to the inner surface of the cylinder barrel through the wall of the recess. A nozzle,
A second drainage passage that is provided in the cover member and discharges the remaining portion of the processing liquid stored in the cylinder barrel;
A surface treatment apparatus for an inner surface of a cylinder barrel, comprising:
内燃機関のシリンダブロックに設けられているシリンダバレルの内面へ処理液を接触させて前記内面を処理する、シリンダバレル内面の表面処理方法であって、
前記シリンダブロックのガスケット面が上になるようにして、シリンダバレルの下部開口を塞ぐパレットに前記シリンダブロックを載置する工程と、
前記シリンダバレルの上部開口に前記処理液を供給するノズルを挿入しつつ、前記シリンダバレルの上部開口に繋がる凹部を下部に有するカバー部材で、前記シリンダバレルの上部開口を覆う工程と、
前記ノズルに設けられた処理液噴射孔から前記処理液を前記凹部の壁に向かって噴射して、前記凹部の壁を介して前記シリンダバレルの内面へ前記処理液を供給する工程と、
前記シリンダバレル内に溜められた前記処理液の一部を、前記パレットに設けられた第1の排液通路から排出すると共に、前記シリンダバレル内に溜められた前記処理液の残部を、前記カバー部材に設けられた第2の排液通路から排出する工程と、
からなることを特徴とするシリンダバレル内面の表面処理方法。
A surface treatment method for an inner surface of a cylinder barrel, wherein a treatment liquid is brought into contact with an inner surface of a cylinder barrel provided in a cylinder block of an internal combustion engine to treat the inner surface,
Placing the cylinder block on a pallet that closes the lower opening of the cylinder barrel so that the gasket surface of the cylinder block is on top;
A step of covering the upper opening of the cylinder barrel with a cover member having a recess connected to the upper opening of the cylinder barrel at the lower part while inserting a nozzle for supplying the processing liquid to the upper opening of the cylinder barrel;
Injecting the processing liquid from the processing liquid injection hole provided in the nozzle toward the wall of the recess, and supplying the processing liquid to the inner surface of the cylinder barrel through the wall of the recess;
A part of the processing liquid stored in the cylinder barrel is discharged from a first drain passage provided in the pallet, and a remaining part of the processing liquid stored in the cylinder barrel is discharged to the cover. Discharging from a second drainage passage provided in the member;
A surface treatment method for an inner surface of a cylinder barrel, comprising:
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