JP5380744B2 - Post-harvest disease control agent - Google Patents

Post-harvest disease control agent Download PDF

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JP5380744B2
JP5380744B2 JP2008509903A JP2008509903A JP5380744B2 JP 5380744 B2 JP5380744 B2 JP 5380744B2 JP 2008509903 A JP2008509903 A JP 2008509903A JP 2008509903 A JP2008509903 A JP 2008509903A JP 5380744 B2 JP5380744 B2 JP 5380744B2
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裕 有本
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RIKEN Institute of Physical and Chemical Research
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/14Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
    • A23B7/153Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of liquids or solids
    • A23B7/154Organic compounds; Microorganisms; Enzymes
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/12Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group, wherein Cn means a carbon skeleton not containing a ring; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom

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  • Life Sciences & Earth Sciences (AREA)
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  • Wood Science & Technology (AREA)
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  • Chemical & Material Sciences (AREA)
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  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Medicines Containing Plant Substances (AREA)

Description

本発明は、ポストハーベスト病害防除剤に関する。   The present invention relates to a postharvest disease control agent.

収穫後の農産物、特に果実等の腐敗を防止するためのポストハーベスト病害防除剤としては、従来重曹などの塩基性塩類が効果を発揮することが知られている。しかし、その範囲はカンキツ緑かび病や青かび病など特定のポストハーベスト病害に限定されている(特許文献1〜4)。また、カラシ油成分やヒノキチオールなど揮発性殺菌成分もポストハーベスト病害防除剤として効果のあることが報告されている(非特許文献1〜2)。さらに、従来の農薬、たとえばベンレート水和剤、トップジン水和剤なども収穫後の果実腐敗防止に使われることがある。しかし、これらは農薬であり、収穫後の使用には本来望ましくない。
現在用いられているポストハーベスト病害防除剤として、収穫後の果実腐敗などに用いられている防かび剤としては、イマザリル、オルトフェニルフェノール、オルトフェニルフェノールナトリウム、ジフェニール、チアベンダザール等があるが、発ガン性、催奇形性などの危険性の疑いがあり好ましくないとされている(非特許文献3))。
しかし、果実等にこれらの農薬を付着させることは食品の安全上好ましくない。さらには収穫時に生じる傷口を熱で焼くこともポストハーベスト病害の防除につながるが、作業が繁雑になりコスト高となるという問題がある。
従って、多種のポストハーベスト病害に有効であり、食品の安全性の点からも問題がなく、かつ安価なポストハーベスト病害防除剤が要望されている。
Conventionally, basic salts such as baking soda are known to be effective as postharvest disease control agents for preventing decay of crops after harvesting, especially fruits. However, the range is limited to specific post-harvest diseases such as citrus green mold and blue mold (Patent Documents 1 to 4). In addition, volatile bactericidal components such as mustard oil components and hinokitiol have been reported to be effective as postharvest disease control agents (Non-Patent Documents 1 and 2). In addition, conventional pesticides such as benrate wettable powder and top gin wettable powder may be used to prevent fruit rot after harvesting. However, these are pesticides and are inherently undesirable for post-harvest use.
As fungicides used for post-harvest fruit rot, etc. as post-harvest disease control agents currently used, there are imazalil, orthophenylphenol, sodium orthophenylphenol, diphenyl, thiabendazal, etc. It is considered unfavorable because there is a suspicion of risks such as carcinogenicity and teratogenicity (Non-patent Document 3)).
However, it is not preferable for food safety to attach these pesticides to fruits or the like. Furthermore, burning the wounds that occur during harvesting with heat leads to the prevention of post-harvest diseases, but there is a problem that the work becomes complicated and the cost is high.
Therefore, there is a demand for a postharvest disease control agent that is effective for various postharvest diseases, has no problem in terms of food safety, and is inexpensive.

特開昭50−111230号公報Japanese Patent Laid-Open No. 50-111230 特開昭51−63932号公報JP 51-63932 A 特許第1168037号Japanese Patent No. 1168037 特許第1210679号Japanese Patent No. 1210679 www.mfc.co.jp/wasaouro/wasaouro/index.htmlwww.mfc.co.jp/wasaouro/wasaouro/index.html www.fukuoka.com/nid/www.fukuoka.com/nid/ www.pref.aichi.jp/shokuhinkensa/noyaku/boukabi.htmlwww.pref.aichi.jp/shokuhinkensa/noyaku/boukabi.html

本発明の目的は、ポストハーベスト病害防除剤を提供することであり、さらに詳細には、バナナクラウンロット病、マンゴー軸腐病、パパイヤ軸腐病などの収穫の際に生じる傷から感染が起こる病害の防除剤を提供することである。   An object of the present invention is to provide a post-harvest disease control agent, and more specifically, diseases in which infection is caused from wounds occurring at the time of harvest such as banana crown lot disease, mango shaft rot, papaya shaft rot, etc. It is to provide a control agent.

本発明は以下に示すポストハーベスト病害防除剤を提供するものである。
1.下記A群及びB群からなる群から選ばれる少なくとも1種の成分を含有するポストハーベスト病害防除剤。
(A)グリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、ソルビトール脂肪酸エステル、又は中鎖脂肪酸トリグリセライド、
(B)有機酸、又はリン酸。
2.A群の少なくとも1種の成分及びB群の少なくとも1種の成分を含有する上記1記載のポストハーベスト病害防除剤。
3.A群の成分5〜90質量部及びB群の成分10〜95質量部を含有する上記1又は2記載のポストハーベスト病害防除剤。
4.B群の成分が、アジピン酸、アスコルビン酸、アルギン酸、クエン酸、グルコン酸、コハク酸、酢酸、酒石酸、乳酸、フェルラ酸、フマル酸、プロピオン酸、リンゴ酸、又はリン酸である上記1〜3のいずれか1項記載のポストハーベスト病害防除剤。
5.上記1〜4のいずれか1項記載のポストハーベスト病害防除剤を水あるいは植物油で2〜100倍に希釈したポストハーベスト病害防除剤。
The present invention provides the following postharvest disease control agent.
1. A postharvest disease control agent comprising at least one component selected from the group consisting of Group A and Group B below.
(A) Glycerin fatty acid ester, sorbitan fatty acid ester, sorbitol fatty acid ester, or medium chain fatty acid triglyceride,
(B) Organic acid or phosphoric acid.
2. 2. The post-harvest disease control agent according to 1 above, which comprises at least one component of Group A and at least one component of Group B.
3. 3. The post-harvest disease control agent according to 1 or 2 above, which contains 5 to 90 parts by mass of the component of Group A and 10 to 95 parts by mass of the component of Group B.
4). 1 to 3 above, wherein the component of Group B is adipic acid, ascorbic acid, alginic acid, citric acid, gluconic acid, succinic acid, acetic acid, tartaric acid, lactic acid, ferulic acid, fumaric acid, propionic acid, malic acid, or phosphoric acid The postharvest disease control agent of any one of these.
5. The post-harvest disease control agent which diluted the post-harvest disease control agent of any one of said 1-4 with water or vegetable oil 2 to 100 times.

本発明のポストハーベスト病害防除剤は、人体に対して安全であり、自然環境に対して負荷を追わせることなく、収穫後の果実腐敗を、経済的にかつ有効に防止することができる。   The postharvest disease control agent of the present invention is safe for the human body and can economically and effectively prevent fruit rot after harvesting without causing a load on the natural environment.

本発明は食品添加物としても利用されているような人や動物に対して安全性の高い成分を必須成分として使用したことを特徴とするものである。
本発明のA群の成分は、グリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、ソルビトール脂肪酸エステル、又は中鎖脂肪酸トリグリセライドである。
A成分のグリセリン脂肪酸エステルとしては、モノ、ジ、トリエステルのいずれでも良く、成分脂肪酸の炭素原子数は好ましくは8〜20、さらに好ましくは12〜18である。グリセリン脂肪酸エステルの具体例としてはグリセリンモノオレート(OL−100)、グリセリンモノ・ジオレート(OL−200)、グリセリンジ・トリオレート(OL−95)、等が挙げられる。
A成分のソルビタン脂肪酸エステルとしては、モノ、ジ、トリ、テトラエステルのいずれでも良く、成分脂肪酸の炭素原子数は好ましくは8〜20、さらに好ましくは12〜18である。具体例としては、ソルビタンラウレート(L−250A、L−300)、ソルビタンオレート(O−80)、ソルビタントリオレート(OR−85)等が挙げられる。
The present invention is characterized by using, as an essential component, a component that is highly safe for humans and animals that are also used as food additives.
The component of Group A of the present invention is glycerin fatty acid ester, sorbitan fatty acid ester, sorbitol fatty acid ester, or medium chain fatty acid triglyceride.
The glycerin fatty acid ester of component A may be any of mono-, di-, and triesters, and the number of carbon atoms of the component fatty acid is preferably 8-20, more preferably 12-18. Specific examples of the glycerol fatty acid ester include glycerol monooleate (OL-100), glycerol monodiolate (OL-200), glycerol ditrioleate (OL-95), and the like.
The sorbitan fatty acid ester of component A may be any of mono-, di-, tri-, and tetra-esters, and the number of carbon atoms of the component fatty acid is preferably 8-20, more preferably 12-18. Specific examples include sorbitan laurate (L-250A, L-300), sorbitan oleate (O-80), sorbitan trioleate (OR-85), and the like.

A成分のソルビトール脂肪酸エステルとしては、モノ、ジ、トリ、テトラエステルのいずれでも良く、成分脂肪酸の炭素原子数は好ましくは8〜20、さらに好ましくは12〜18である。具体例としては、ソルビトールのモノ又はジラウリン酸エステル(L−300)、ソルビタンのモノ又はジラウリン酸エステル(L−250A)、ソルビタンのモノ又はジオレイン酸エステル(O−80)、ソルビタンのジ又はトリラウリン酸エステル、等が挙げられる。
A成分の中鎖脂肪酸トリグリセライドの成分中鎖脂肪酸の炭素原子数は好ましくは8〜12、さらに好ましくは8〜10である。具体例としては、C8単独(M−2)、C8とC10の混合物(例えば、60:40(M−1))、等が挙げられる。
The component A sorbitol fatty acid ester may be any of mono-, di-, tri-, and tetra-esters, and the number of carbon atoms of the component fatty acid is preferably 8 to 20, and more preferably 12 to 18. Specific examples include sorbitol mono- or dilaurate (L-300), sorbitan mono- or dilaurate (L-250A), sorbitan mono- or dioleate (O-80), sorbitan di- or trilaurate. And esters.
The number of carbon atoms in the component medium chain fatty acid of the component A medium chain fatty acid triglyceride is preferably 8 to 12, more preferably 8 to 10. Specific examples include C8 alone (M-2), a mixture of C8 and C10 (for example, 60:40 (M-1)), and the like.

本発明のB成分の有機酸は、人や動物に有害な影響のないものであれば特に制限されないが、好ましくは食品添加物として使用できる有機酸である。好ましい具体例としては、アジピン酸、アスコルビン酸、アルギン酸、クエン酸、グルコン酸、コハク酸、酢酸、酒石酸、乳酸、フェルラ酸、フマル酸、プロピオン酸、リンゴ酸等が挙げられる。
本発明のB成分として特に好ましいものは、クエン酸、コハク酸、酒石酸、乳酸、リンゴ酸、リン酸であり、もっとも好ましいものはクエン酸、コハク酸、リンゴ酸、リン酸である。
The organic acid of component B of the present invention is not particularly limited as long as it does not have harmful effects on humans and animals, but is preferably an organic acid that can be used as a food additive. Preferred examples include adipic acid, ascorbic acid, alginic acid, citric acid, gluconic acid, succinic acid, acetic acid, tartaric acid, lactic acid, ferulic acid, fumaric acid, propionic acid, malic acid and the like.
Particularly preferred as component B of the present invention are citric acid, succinic acid, tartaric acid, lactic acid, malic acid and phosphoric acid, and most preferred are citric acid, succinic acid, malic acid and phosphoric acid.

本発明のポストハーベスト病害防除剤はA成分とB成分の少なくとも1種を含むが、A成分の少なくとも1種とB成分の少なくとも1種を含むものが好ましい。
具体的なポストハーベスト病害防除剤の好ましい基本組成としては例えば、以下のものが挙げられる。
1.グリセリン脂肪酸エステル + 有機酸
2.ソルビタン脂肪酸エステル + 有機酸
3.中鎖脂肪酸トリグリセライド + 有機酸
4.グリセリン脂肪酸エステル + ソルビタン脂肪酸エステル + 有機酸
5.中鎖脂肪酸トリグリセライド + ソルビタン脂肪酸エステル + 有機酸
6.グリセリン脂肪酸エステル + 中鎖脂肪酸トリグリセライド + 有機酸
7.グリセリン脂肪酸エステル + ソルビタン脂肪酸エステル + 中鎖脂肪酸トリグリセライド + 有機酸
Although the postharvest disease control agent of this invention contains at least 1 sort (s) of A component and B component, what contains at least 1 sort (s) of A component and B component is preferable.
Specific examples of a preferable basic composition of the postharvest disease control agent include the following.
1. 1. Glycerin fatty acid ester + organic acid 2. Sorbitan fatty acid ester + organic acid 3. Medium chain fatty acid triglyceride + organic acid 4. Glycerin fatty acid ester + sorbitan fatty acid ester + organic acid Medium chain fatty acid triglyceride + sorbitan fatty acid ester + organic acid 6. Glycerin fatty acid ester + medium chain fatty acid triglyceride + organic acid Glycerin fatty acid ester + sorbitan fatty acid ester + medium chain fatty acid triglyceride + organic acid

本発明のポストハーベスト病害防除剤が成分Aと成分Bを含有する場合、成分Aと成分Bの合計を100質量部として、成分Aの含有量は、好ましくは5〜90質量部、さらに好ましくは10〜60質量部、もっとも好ましくは20〜40質量部であり、残部がB成分である。   When the post-harvest disease control agent of the present invention contains component A and component B, the total amount of component A and component B is 100 parts by mass, and the content of component A is preferably 5 to 90 parts by mass, more preferably It is 10-60 mass parts, Most preferably, it is 20-40 mass parts, and remainder is B component.

本発明のポストハーベスト病害防除剤は、成分A及び/又は成分Bの他に界面活性能を有する食品添加物(例えば、ポリグリセリン脂肪酸エステル等)等を含有してもよい。
本発明のポストハーベスト病害防除剤は、そのまま使用しても良いが、通常は、その100質量部に対して、水、植物油(例えば、ヤシ油、大豆油等)等を、好ましくは30〜10000質量部、さらに好ましくは100〜10000質量部加え、攪拌、混合して使用することが望ましい。
本発明のポストハーベスト病害防除剤の対象病害としては、バナナクラウンロット病、マンゴー軸腐病、パパイヤ軸腐病、などの収穫の際に生じる傷から感染が起こる病害が挙げられる。
本発明のポストハーベスト病害防除剤は上記の溶媒に希釈し、又は希釈することなく、対象植物の所望の部位に、適当な方法(例えば、刷毛塗り、スプレー塗布)により付着させればよい。その量は適宜決定されるが、通常はA成分及びB成分の合計量で、好ましくは0.1〜1000g/m2、さらに好ましくは1〜100g/m2程度が適当である。
The post-harvest disease control agent of this invention may contain the food additive (for example, polyglycerol fatty acid ester etc.) etc. which have surface active ability other than the component A and / or component B, etc.
The post-harvest disease control agent of the present invention may be used as it is, but usually 100 parts by weight of water, vegetable oil (for example, coconut oil, soybean oil, etc.), etc., preferably 30 to 10,000. It is desirable to add part by weight, more preferably 100 to 10,000 parts by weight, and stir and mix.
Examples of the target disease of the post-harvest disease control agent of the present invention include diseases in which infection is caused by wounds such as banana crown lot disease, mango shaft rot, papaya shaft rot, and the like that occur at the time of harvest.
The post-harvest disease control agent of the present invention may be diluted with the above-mentioned solvent or may be attached to a desired site of the target plant by an appropriate method (for example, brush coating or spray coating) without dilution. Although the amount is appropriately determined, usually in a total amount of components A and B, preferably 0.1~1000g / m 2, more preferably suitably about 1 to 100 g / m 2.

以下、実施例を示し本発明をさらに具体的に説明する。使用した成分(A)を以下に示す。
アクターM−1:トリカプリリン(70質量%)/トリカプリン(30質量%)
アクターM−2:トリカプリリン
リケマールL−250A:ソルビタンラウレート
リケマールL−300:ソルビタンラウレート
リケマールOL−100:グリセリンモノオレート
いずれも理研ビタミン株式会社製
Hereinafter, the present invention will be described more specifically with reference to examples. The component (A) used is shown below.
Actor M-1: Tricaprylin (70% by mass) / Tricaprin (30% by mass)
Actor M-2: Tricaprylin Riquemar L-250A: Sorbitan laurate Riquemar L-300: Sorbitan laurate Riquemar OL-100: Glycerol monooleate All manufactured by Riken Vitamin Co., Ltd.

実施例1
リケマールL−300とクエン酸を質量比1:3で混合した。使用時にこの1質量部を水1質量部で練る。
実施例2
アクターM−2とコハク酸を質量比2:3で混合した。使用時にこの1質量部を水2質量部で練る。
実施例3
アクターM−1とリンゴ酸を質量比3:3で混合した。使用時にこの1質量部を水3質量部で練る。
実施例4
リケマールL−300とリケマールOL−100とクエン酸を質量比1:1:3で混合した。使用時にこの1質量部を水1質量部で練る。
Example 1
Riquemar L-300 and citric acid were mixed at a mass ratio of 1: 3. During use, 1 part by mass is kneaded with 1 part by mass of water.
Example 2
Actor M-2 and succinic acid were mixed at a mass ratio of 2: 3. During use, 1 part by mass is kneaded with 2 parts by mass of water.
Example 3
Actor M-1 and malic acid were mixed at a mass ratio of 3: 3. During use, 1 part by mass is kneaded with 3 parts by mass of water.
Example 4
Riquemar L-300, Riquemar OL-100 and citric acid were mixed at a mass ratio of 1: 1: 3. During use, 1 part by mass is kneaded with 1 part by mass of water.

実施例5
リケマールL−300を単独で用いる。
実施例6
クエン酸を単独で用いる。使用時にクエン酸1質量部に対して水3質量部で練る。
実施例7
アクターM−1を単独で用いる。
実施例8
リケマールOL−100を単独で用いる。
実施例9
リンゴ酸を単独で用いる。
Example 5
Riquemar L-300 is used alone.
Example 6
Citric acid is used alone. At the time of use, it is kneaded with 3 parts by mass of water with respect to 1 part by mass of citric acid.
Example 7
Actor M-1 is used alone.
Example 8
Riquemar OL-100 is used alone.
Example 9
Malic acid is used alone.

試験例1 バナナクラウンロット病に対する防除効果
市販のバナナのクラウン部分を削り、新しい傷面を作った。そこに実施例1〜9のポストハーベスト病害防除剤をポストハーベスト病害防除剤の有効成分の量として10g/m2塗布した。無処理区を対照として設けた。その後、切り口にPDA培地で培養したLasiodiplodia theobromaeを培地ごと貼り付け、27℃の湿室に保ち、発病させた。7日後に発病程度を調査し、それから防除価を求めた。バナナ果梗部におけるLasiodiplodia theobromaeの生育と果梗部の黒変に対するポストハーベスト病害防除剤の効果を表1に示す。
Test Example 1 Control Effect against Banana Crown Lot's Disease A commercially available banana crown was shaved to create a new wound surface. The postharvest disease control agent of Examples 1-9 was apply | coated there as an amount of the active ingredient of a postharvest disease control agent 10g / m < 2 > there. An untreated section was provided as a control. Thereafter, Lasiodiplodia theobromae cultured in PDA medium was attached to the cut end together with the medium, and kept in a 27 ° C. wet chamber to cause disease. Seven days later, the severity of the disease was investigated, and then the control value was determined. Table 1 shows the effect of a post-harvest disease control agent on the growth of Lasiodiplodia theobromae in the banana prunus and the blackening of the prunus.

果実の変化
0:果梗の変色なし
1:果梗の一部が褐色
2:果梗の一部が黒色
3:果実の一部が黒色
Change in fruit 0: No change in the curd 1: Part of the curd is brown 2: Part of the curd is black 3: Part of the fruit is black

傷面での菌糸の生育
0:菌糸生育なし
1:わずかに生育が認められる
2:菌糸の生育が認められる
3:菌糸が盛んに生育している
Growth of hyphae on the wound surface 0: No hyphae growth 1: Slight growth is observed 2: Hyphae growth is observed 3: Hyphae is actively growing

発病程度 =(0×n0 + 1×n1 + 2×n2 + 3×n3)/3N
0:程度が0の果実数
1:程度が1の果実数
2:程度が2の果実数
3:程度が3の果実数
N:全果実数
防除価(%) = (1 − 処理区の発病程度/無処理区の発病程度)×100
Disease severity = (0 × n 0 + 1 × n 1 + 2 × n 2 + 3 × n 3 ) / 3N
n 0 : number of fruits with degree 0 n 1 : number of fruits with degree 1 n 2 : number of fruits with degree 2 n 3 : number of fruits with degree 3 N: total number of fruits Control value (%) = (1 − (Degree of disease in treated area / degree of disease in untreated area) x 100

Figure 0005380744
Figure 0005380744

試験例2 バナナクラウンロット病に対する防除効果
市販のバナナのクラウン部分を削り、新しい傷面を作った。そこに実施例1、5及び6の製剤をポストハーベスト病害防除剤の有効成分の量として10g/m2塗布した。無処理区を対照として設けた。その後、切り口にPDA培地で培養した表2及び表3に示した病原菌を培地ごと貼り付け、25℃の湿室に保ち、発病させた。7日後に発病程度を調査した。バナナ果梗部におけるクラウンロット病に関連する病原菌による果梗部の黒変に対する効果を表2に、バナナ果梗部におけるクラウンロット病に関連する病原菌の生育抑制効果を表3に示す。
Test Example 2 Control Effect against Banana Crown Lot Disease A commercially available banana crown was shaved to create a new scratched surface. Thereto, the preparations of Examples 1, 5 and 6 were applied at 10 g / m 2 as the amount of the active ingredient of the post-harvest disease control agent. An untreated section was provided as a control. Thereafter, the pathogens shown in Table 2 and Table 3 cultured in PDA medium were attached to the cut surface together with the medium, and kept in a 25 ° C. wet chamber to cause disease. Seven days later, the severity of the disease was investigated. Table 2 shows the effect of the pathogenic bacteria related to crown lot disease in the banana fruit infarction on the blackening of the fruit infarct, and Table 3 shows the growth inhibitory effect of the pathogenic bacteria related to crown lot in the banana fruit.

Figure 0005380744
Figure 0005380744

Figure 0005380744
Figure 0005380744

試験例3 パパイア軸腐病に対する効果
市販のパパイアの果梗部分を削り、新しい傷面を作った。そこに実施例1〜6の製剤をポストハーベスト病害防除剤の有効成分の量として15g/m2塗布した。無処理区を対照として設けた。その後、切り口にPDA培地で培養したLasiodiplodia theobromaeを培地ごと貼り付け、25℃の湿室に保ち、発病させた。7日後に発病程度(果実の腐敗)を調査した。
Test Example 3 Effect on Papaya Axis Rot A commercially available papaya was cut to produce a new wound surface. The formulation of Examples 1-6 was apply | coated there as a quantity of the active ingredient of a postharvest disease control agent 15g / m < 2 >. An untreated section was provided as a control. Thereafter, Lasiodiplodia theobromae cultured in PDA medium was attached to the cut end together with the medium and kept in a 25 ° C. wet chamber to cause disease. Seven days later, the disease severity (fruit rot) was investigated.

Figure 0005380744
Figure 0005380744

試験例4 マンゴー軸腐病に対する効果
市販のマンゴーの果梗部分を削り、新しい傷面を作った。そこに実施例1、4〜6の製剤をポストハーベスト病害防除剤の有効成分の量として15g/m2塗布した。無処理区を対照として設けた。
その後、切り口にPDA培地で培養したLasiodiplodia theobromaeを培地ごと貼り付け、25℃の湿室に保ち、発病させた。7日後に発病程度(果実の腐敗)を調査した。
Test Example 4 Effect on Mango Axial Decay A cut surface of a commercially available mango was shaved to create a new wound surface. Thereto, 15 g / m 2 of the preparations of Examples 1 and 4 to 6 were applied as the amount of the active ingredient of the post-harvest disease control agent. An untreated section was provided as a control.
Thereafter, Lasiodiplodia theobromae cultured in PDA medium was attached to the cut end together with the medium and kept in a 25 ° C. wet chamber to cause disease. Seven days later, the disease severity (fruit rot) was investigated.

Figure 0005380744
Figure 0005380744

Claims (4)

有効成分として、下記A群から選ばれる少なくとも1種の成分と、下記B群から選ばれる少なくとも1種の成分とを含み、且つ、1価のアルコール及び多価のアルコールを含まない、ポストハーベスト病害防除剤であって、
前記A群の成分とB群の成分の合計を100質量部として、A群の成分が5〜90質量部であり、且つB群の成分が10〜95質量部であ且つ
ポストハーベスト病害が、バナナクラウンロット病、マンゴー軸腐病、又はパパイヤ軸腐病である、前記ポストハーベスト病害防除剤:
(A)ソルビタン脂肪酸エステル;
(B)クエン酸、コハク酸及びリンゴ酸からなる群から選択される少なくとも1種の有機酸。
Post-harvest disease comprising , as an active ingredient, at least one component selected from the following group A and at least one component selected from the following group B , and not containing a monohydric alcohol or a polyhydric alcohol A control agent,
100 parts by weight total of the components of the component and the B group of the group A, a component of group A is 5 to 90 parts by weight, and component of Group B is Ri 10-95 parts by der, and
The post-harvest disease control agent , wherein the post-harvest disease is banana crown lot disease, mango shaft rot, or papaya shaft rot :
(A) sorbitan fatty acid ester;
(B) At least one organic acid selected from the group consisting of citric acid, succinic acid and malic acid.
有効成分が、下記A群から選ばれる少なくとも1種の成分と、下記B群から選ばれる少なくとも1種の成分とのみからなる、ポストハーベスト病害防除剤であって、  The active ingredient consists of at least one component selected from the following group A and at least one component selected from the following group B, a postharvest disease control agent,
前記A群の成分とB群の成分の合計を100質量部として、A群の成分が5〜90質量部であり、且つB群の成分が10〜95質量部であり、  The total of the components of Group A and Group B is 100 parts by mass, Group A components are 5-90 parts by mass, and Group B components are 10-95 parts by mass,
ポストハーベスト病害が、バナナクラウンロット病、マンゴー軸腐病、又はパパイヤ軸腐病である、前記ポストハーベスト病害防除剤:  The post-harvest disease control agent, wherein the post-harvest disease is banana crown lot disease, mango shaft rot, or papaya shaft rot:
(A)ソルビタン脂肪酸エステル;(A) sorbitan fatty acid ester;
(B)クエン酸、コハク酸及びリンゴ酸からなる群から選択される少なくとも1種の有機酸。(B) At least one organic acid selected from the group consisting of citric acid, succinic acid and malic acid.
請求項1又は2記載のポストハーベスト病害防除剤を水あるいは植物油で2〜100倍に希釈したポストハーベスト病害防除剤。   The postharvest disease control agent which diluted the postharvest disease control agent of Claim 1 or 2 2 to 100 times with water or vegetable oil. さらにポリグリセリン脂肪酸エステルを含有する、請求項1〜3のいずれか1項記載のポストハーベスト病害防除剤。   Furthermore, the postharvest disease control agent of any one of Claims 1-3 containing polyglyceryl fatty acid ester.
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JPH0953093A (en) * 1995-08-10 1997-02-25 Lion Corp Detergent composition suitable for vegetable, fruit and the like
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