JP5371195B2 - Matte wood finish - Google Patents
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- JP5371195B2 JP5371195B2 JP2007043972A JP2007043972A JP5371195B2 JP 5371195 B2 JP5371195 B2 JP 5371195B2 JP 2007043972 A JP2007043972 A JP 2007043972A JP 2007043972 A JP2007043972 A JP 2007043972A JP 5371195 B2 JP5371195 B2 JP 5371195B2
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- 239000011342 resin composition Substances 0.000 claims abstract description 23
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Abstract
Description
本発明は、家具や扉、棚板などの木口部に接着される艶消し木質調木口材に関し、更に詳しくは、耐候性に優れ、木口部分の大きさに合わせて端部を切削した場合でも切削面に木目が現れて木質感があり、シボがつけやすく深さのコントロールが容易な艶消し木質調木口材に関する。 The present invention, furniture and doors, related to matte wood tone butt end member which is adhered to the butt portion of such a shelf plate, more particularly, excellent weather resistance, when cutting the edge portion in accordance with the size of the cut end portion But there is a woody feeling of grain appears on the cutting surface, control of grain is put easy depth is about the easy matte wood tone butt end material.
従来、家具や弱電製品、扉、棚板等の木口部分に張り付けてその外観を改善する木口材としては、塩化ビニル樹脂製木口材やジアリルフタレート樹脂製木口材がよく用いられている。特に、塩化ビニル樹脂製木口材は、着色性、二次加工性、印刷適性などの自由度が高く意匠性のある木口材として広く使用されてきた。しかし近年では、塩化ビニル樹脂製木口材は燃焼時に塩化水素ガスが発生するため、環境保全の観点から非塩化ビニル樹脂製の木口材も使用されている。 Conventionally, a vinyl chloride resin mouthpiece or a diallyl phthalate resin mouthpiece is often used as a mouthpiece material to improve the appearance by sticking to the mouth portion of furniture, light electrical appliances, doors, shelves and the like. In particular, a vinyl chloride resin-made mouthpiece has been widely used as a mouthpiece with a high degree of freedom in terms of colorability, secondary processability, printability, and the like. In recent years, however, a vinyl chloride resin wood chip generates hydrogen chloride gas during combustion, and therefore a non-vinyl chloride resin wood mouth is also used from the viewpoint of environmental conservation.
非塩化ビニル樹脂製の木口材としては、例えば、ABS樹脂系フイルムを基材とし、該基材の表面側には、酸化チタン顔料が配合された印刷インクのベタ印刷層と、該ベタ印刷層上に着色印刷層と、該着色印刷層上に透明保護層が形成され、かつ、該透明保護層にはエンボス模様が形成されているABS樹脂系化粧シートからなる木口材が提案されている(特許文献1参照)。これはABS樹脂を折り曲げるとその部分で白化し外観を損ねてしまうため、表面に印刷層を設けて白化した部分を隠すものである。 The non-vinyl chloride resin end piece is made of, for example, an ABS resin film as a base material, and a solid printing layer of a printing ink in which a titanium oxide pigment is blended on the surface side of the base material, and the solid printing layer There has been proposed a colored print layer, and a mouthpiece made of an ABS resin-based decorative sheet in which a transparent protective layer is formed on the colored print layer, and an embossed pattern is formed on the transparent protective layer ( Patent Document 1). This is because when the ABS resin is bent, the portion is whitened and the appearance is deteriorated. Therefore, a printed layer is provided on the surface to hide the whitened portion.
また、別の例としては、テレフタル酸からなるジカルボン酸成分と、20〜35モル%の1,4−シクロヘキサンジメタノールと65〜80モル%のエチレングリコールからなるジオール成分とから構成された非晶質ポリエステル樹脂を主成分とする樹脂成分100重量部に対して、アクリルゴム系改質剤、アクリルシリコンゴム系改質剤、ジエンゴム系改質剤、オレフィンゴム系改質剤から選ばれた少なくとも1種の改質剤を1〜25重量部を配合した着色ポリエステル樹脂系シートの表面側に、2液硬化型ウレタン樹脂塗料を塗布してなるポリエステル樹脂系木口材が提案されている(特許文献2参照)。これは、基材として使用する非晶質ポリエステルは低温条件下で割れや欠けが発生しやすいため、この欠点を解消するため改質剤を配合し、さらに物性改善や光沢調製のため、表面に2液硬化型ウレタン樹脂塗料を塗布したものである。 As another example, an amorphous material composed of a dicarboxylic acid component composed of terephthalic acid and a diol component composed of 20 to 35 mol% 1,4-cyclohexanedimethanol and 65 to 80 mol% ethylene glycol. At least one selected from an acrylic rubber modifier, an acrylic silicon rubber modifier, a diene rubber modifier, and an olefin rubber modifier with respect to 100 parts by weight of a resin component mainly composed of a high-quality polyester resin There has been proposed a polyester resin-based wood end material obtained by applying a two-component curable urethane resin paint to the surface side of a colored polyester resin-based sheet containing 1 to 25 parts by weight of various modifiers (Patent Document 2). reference). This is because the amorphous polyester used as a base material is likely to crack or chip under low temperature conditions. Therefore, a modifier is blended in order to eliminate this defect. A two-component curable urethane resin paint is applied.
しかしながら、上記のような木口材の化粧性、意匠性はいずれも樹脂基材の表面に施された印刷層、塗膜層などにより保持されているので、風雨に曝されて印刷層等が劣化剥離すると樹脂基材が剥き出しになり、その化粧性や意匠性が極めて悪くなる。さらにABS樹脂やポリエステル樹脂は耐候性の点で劣っており、特に屋外ではその耐久性は極めて短くなる。
また、この種の木口材は木口部分に張り付ける際には木口部分の大きさに合わせて端部を切削する場合があるが、現場で切削面に印刷層等を施すことはできないため、その結果、切削面では樹脂基材が剥き出しになる。この樹脂基材の切削面の色、光沢は、当然のことながら印刷層や塗膜層とは非常に異なるため、著しく外観を損なうとともに安っぽい印象を与えてしまう。
さらに、この種の木口材はソリッド(非発泡)品であるため、艶消し感に乏しく、またエンボスロール等で凹凸(シボ)を付けるのが困難で、仮にシボを付けたとしても十分な深さのシボを付けることは不可能であり、従って、例えシボにより木質感を付与したとしても非常に平板的で単調であり、満足できる木質感を得ることはできなかった。
In addition, when this kind of kerf material is attached to the kerf part, the end part may be cut according to the size of the kerf part. As a result, the resin base material is exposed on the cut surface. Naturally, the color and gloss of the cut surface of the resin base material are very different from those of the printed layer and the coating layer, so that the appearance is remarkably impaired and a cheap impression is given.
In addition, this kind of wood is a solid (non-foamed) product, so it has a dull feeling and it is difficult to make irregularities (textures) with embossing rolls. Therefore, it is impossible to attach a grain texture. Therefore, even if a texture is given by grain, it is very flat and monotonous, and a satisfactory texture can not be obtained.
本発明はかかる実情に鑑み、上記のような従来技術の問題点を解消し、耐候性に優れており、木口部分の大きさに合わせて端部を切削した場合でも切削面にも木目が現れて木質感があり、シボがつけやすく深さのコントロールもし易い艶消し木質調木口材及びその製造方法を提供することを目的とするものである。
本発明者らは上記問題点を解消するべく鋭意研究の結果、特定の樹脂を基材樹脂とし、これに木質充填剤、発泡剤、種剤樹脂、及び顔料を配合した木質系樹脂組成物の発泡成形体により木口材を作成することにより、上記課題を解決できることを見出し、本発明を完成するに至った。
In view of such circumstances, the present invention solves the above-mentioned problems of the prior art, has excellent weather resistance, and even when the end portion is cut according to the size of the end portion, grain appears on the cutting surface. It is an object of the present invention to provide a matte wood-like wood mouthpiece that has a wood texture, is easy to be wrinkled, and is easy to control the depth, and a method for producing the same.
As a result of diligent research to solve the above problems, the present inventors have developed a wood-based resin composition in which a specific resin is used as a base resin, and a wood filler, a foaming agent, a seed resin, and a pigment are blended therein. It has been found that the above-mentioned problems can be solved by creating a mouthpiece material from a foamed molded product, and the present invention has been completed.
上記目的を達成するための本発明の請求項1は、アクリロニトリル−エチレンプロピレンゴム−スチレン樹脂又はアクリルゴム−スチレン−アクリロニトリル樹脂からなる基材樹脂、木質充填剤、発泡剤、種剤樹脂、及び顔料を含む木質系樹脂組成物のシボ付けと艶消しされた発泡倍率が1.05〜1.8倍の発泡成形体からなることを特徴とする艶消し木質調木口材を内容とする。 In order to achieve the above object, claim 1 of the present invention provides a base resin, a wood filler, a foaming agent, a seed resin, and a pigment made of acrylonitrile-ethylenepropylene rubber-styrene resin or acrylic rubber-styrene-acrylonitrile resin. A matt wood-like wood mouthpiece characterized in that it comprises a foamed molded article having a texture expansion ratio of 1.05 to 1.8 times and a textured wood resin composition comprising
本発明の請求項2は、木質系樹脂組成物が、基材樹脂100重量部当り、木質充填剤4〜25重量部、発泡剤0.1〜1.0重量部、種剤樹脂3〜15重量部及び顔料0.5〜5.0重量部を含有することを特徴とする請求項1記載の艶消し木質調木口材を内容とする。 According to claim 2 of the present invention, the wood-based resin composition has a wood filler of 4 to 25 parts by weight, a foaming agent of 0.1 to 1.0 parts by weight, and a seed resin of 3 to 15 per 100 parts by weight of the base resin. The matte wood-cut mouthpiece according to claim 1, comprising 0.5 parts by weight and 0.5 parts by weight of pigment.
本発明の請求項3は、木質系樹脂組成物が、更に、無機充填剤及び/又は滑剤を含有することを特徴とする請求項1又は請求項2記載の艶消し木質調木口材を内容とする。 According to a third aspect of the present invention, the wood-based resin composition further comprises an inorganic filler and / or a lubricant, and the matted wood-like mouthpiece according to claim 1 or 2, To do.
本発明の請求項4は、無機充填剤が5〜20重量部、滑剤が0.1〜2.0重量部であることを特徴とする請求項3記載の艶消し木質調木口材を内容とする。 Claim 4 of the present invention, the inorganic filler is 5 to 20 parts by weight, and the content of the matte wood tone butt material according to claim 3, characterized in that the lubricant is 0.1 to 2.0 parts by weight To do.
本発明の請求項5は、発泡倍率が1.2〜1.5倍であることを特徴とする請求項1乃至請求項4のいずれかに記載の艶消し木質調木口材を内容とする。 A fifth aspect of the present invention includes the matted wood-like wood mouthpiece according to any one of the first to fourth aspects, wherein the expansion ratio is 1.2 to 1.5 times.
本発明の請求項6は、表面側の光沢が5〜20cdであることを特徴とする請求項1乃至請求項5のいずれかに記載の艶消し木質調木口材を内容とする。 According to a sixth aspect of the present invention, the matte wood-cut mouthpiece according to any one of the first to fifth aspects is characterized in that the surface side gloss is 5 to 20 cd.
本発明の請求項7は、裏面側にプライマー層が形成されていることを特徴とする請求項1乃至請求項6のいずれかに記載の艶消し木質調木口材を内容とする。 Claim 7 of the present invention is directed to the content of the matte wood tone butt material according to any one of claims 1 to 6, characterized in that the primer layer is formed on the back side.
本発明の艶消し木質調木口材は、耐候性に優れた基材樹脂の中に種剤樹脂を配合するため、種剤樹脂は押出発泡成形工程では基材樹脂と均一に混合せず、発泡成形体に鮮明な木目模様が形成される。また、発泡体であるからシボが付け易く、その深さも調節しやすく、木に近い質感が得られる。従って、本発明の艶消し木質調木口材は、長期に亘って表面の木目模様が劣化することがなく、また、木口部分のサイズに合わせて端部を切削してもその切削面に木目模様が消えることなく保持される。 The matted wood-like wood mouthpiece of the present invention blends a seed resin with a base resin excellent in weather resistance, so the seed resin does not mix uniformly with the base resin in the extrusion foam molding process, and foam A clear wood grain pattern is formed on the molded body. Moreover, since it is a foam, it is easy to attach a texture, the depth is easy to adjust, and a texture close to wood is obtained. Accordingly, the matted wood-like wood cut end material of the present invention does not deteriorate the surface grain pattern over a long period of time, and even if the end is cut according to the size of the end part, the grain pattern on the cut surface Is kept without disappearing.
木質系樹脂組成物の好ましい組成は、基材樹脂100重量部当り、木質充填剤4〜25重量部、発泡剤0.1〜1.0重量部、種剤樹脂3〜15重量部及び顔料0.5〜5.0重量部であり、これによりシボがつけ易く木質感の高い、艶消し木質調木口材が得られる。 The preferred composition of the wood-based resin composition is 4 to 25 parts by weight of a wood filler, 0.1 to 1.0 part by weight of a foaming agent, 3 to 15 parts by weight of a seed resin, and 0 pigment per 100 parts by weight of the base resin. It is .5 to 5.0 parts by weight, and this makes it possible to obtain a matted wood-finished mouthpiece that is easy to be wrinkled and has a high wood texture.
更に、樹脂組成物に無機充填剤を配合すると、線膨張率が低くなるため、張り付けられた木口材が綺麗な木質調外観を維持することができる。無機充填材の好ましい含有量は樹脂100重量部当り5〜20重量部である。
また、更に、樹脂組成物に滑剤を配合すると、基材樹脂と種剤樹脂とが更に混ざりにくくなり、一層鮮明な木目模様が形成され、より木質感が増す。滑剤の好ましい含有量は樹脂100重量部当り0.1〜2.0重量部である。
Furthermore, when an inorganic filler is blended in the resin composition, the linear expansion coefficient is lowered, so that the pasted wood end material can maintain a beautiful woody appearance. A preferable content of the inorganic filler is 5 to 20 parts by weight per 100 parts by weight of the resin.
Furthermore, when a lubricant is blended in the resin composition, the base resin and the seed resin are more difficult to mix, and a clearer wood grain pattern is formed and the wood texture is further increased. A preferable content of the lubricant is 0.1 to 2.0 parts by weight per 100 parts by weight of the resin.
木質系樹脂組成物の好ましい発泡倍率は1.05〜1.8倍であり、この範囲とすることにより、シボがつけ易く木質感が高いばかりでなく、強度にも優れた艶消し木質調木口材が得られる。 The preferred foaming ratio of the wood-based resin composition is 1.05 to 1.8 times, and by setting it within this range, not only is it easy to apply a texture, but the wood texture is high, and the matte wood-like wood finish excellent in strength A material is obtained.
木口材表面側の光沢度が5〜20cdであると、本来の木により近い質感を持つ艶消し木質調木口材が得られる。 If the glossiness on the surface side of the wood mouthpiece is 5 to 20 cd, a matte wood-like wood mouthpiece having a texture closer to that of the original wood can be obtained.
本発明の艶消し木質調木口材の製造方法は、基材樹脂の中に、木質充填剤、発泡剤、種剤樹脂、及び顔料を含む木質系樹脂組成物を大気中に押し出し、押し出された発泡成形体に180℃〜220℃のエンボスロールによりシボ付けと艶消しとを行う方法であり、これにより、上記した優れた特徴を有する艶消し木質調木口材を製造することができる。 In the method for producing a matted wood-like headpiece according to the present invention, a wood-based resin composition containing a wood filler, a foaming agent, a seed resin, and a pigment is extruded into the base material and extruded. This is a method of embossing and matting a foamed molded product with an embossing roll at 180 ° C. to 220 ° C., and thereby a matted wood-like wood cutting material having the above-described excellent characteristics can be produced.
また、発泡成形体にエンボスロールによりシボ付けと艶消しとを行った後、更に、シリコンロールで押圧し反りの修正を行えば、木口部分に張り付けた時もこの艶消し木質調木口材の浮き上がりがなく、より商品価値の高い艶消し木質調木口材を得ることができる。 In addition, after embossing and embossing the foamed molded body, and further correcting the warp by pressing it with a silicon roll, the matte wood finish lumber will be lifted even when it is attached to the end of the wood. Therefore, it is possible to obtain a matted wood-like mouthpiece having a higher commercial value.
本発明の艶消し木質調木口材は、アクリロニトリル−エチレンプロピレンゴム−スチレン樹脂又はアクリルゴム−スチレン−アクリロニトリル樹脂からなる基材樹脂、木質充填剤、発泡剤、種剤樹脂、及び顔料を含む木質系樹脂組成物の発泡成形体からなることを特徴とする。 The matte wood-like wood timber of the present invention is a wood-based material comprising a base resin composed of acrylonitrile-ethylenepropylene rubber-styrene resin or acrylic rubber-styrene-acrylonitrile resin, a wood filler, a foaming agent, a seed resin, and a pigment. It consists of the foaming molding of a resin composition, It is characterized by the above-mentioned.
本発明において基材樹脂として使用される樹脂は、アクリロニトリル−エチレンプロピレンゴム−スチレン樹脂(AES)、又はアクリルゴム−スチレン−アクリロニトリル樹脂(ASA)であり、かかる樹脂として市販されている製品はいずれも好適に使用できる。前者の市販樹脂としては、例えば、「W220(テクノポリマー株式会社製)」等が挙げられ、また、後者の市販樹脂としては、例えば、「S710(三菱レイヨン株式会社製)」等が挙げられる。これらの樹脂は耐候性に優れたおり、長期に亘って優れた艶消し木質調の外観を保持することができる。 The resin used as the base resin in the present invention is acrylonitrile-ethylenepropylene rubber-styrene resin (AES), or acrylic rubber-styrene-acrylonitrile resin (ASA), and any product marketed as such a resin is used. It can be used suitably. Examples of the former commercially available resin include “W220 (manufactured by Techno Polymer Co., Ltd.)” and the like, and examples of the latter commercially available resin include “S710 (manufactured by Mitsubishi Rayon Co., Ltd.)”. These resins are excellent in weather resistance and can maintain an excellent matte wood-like appearance over a long period of time.
本発明において用いられる木質充填剤は、本発明の艶消し木質調木口材に木質感を付与する目的で配合される。このような木質充填剤はセルロースを主成分とする物質の粉粒体で、例えば木材、竹、籾殻、ケナフ、パルプ、紙、落綿、セルロース繊維等の粉粒体が挙げられ、これらは単独又は2種以上組み合わせて用いられるが、特に木粉が好適である。木質充填剤は平均粒径が150μm(100メッシュパス)〜375μm(40メッシュパス)ものが好ましい。細かすぎると木質感が発現しがたく、一方、粗すぎると得られる発泡成形体の表面が不均一となり、外観、物性ともに低下する The wood filler used in the present invention is blended for the purpose of imparting a wood texture to the matted wood finish mouthpiece of the present invention. Such a wood filler is a granular material of a substance mainly composed of cellulose, and examples thereof include granular materials such as wood, bamboo, rice husk, kenaf, pulp, paper, cotton wool, and cellulose fibers. Or, two or more types are used in combination, and wood flour is particularly preferred. The wood filler preferably has an average particle size of 150 μm (100 mesh pass) to 375 μm (40 mesh pass). If it is too fine, it will be difficult to express the wood texture. On the other hand, if it is too rough, the surface of the foamed molded product will be uneven and both the appearance and physical properties will be reduced.
木質充填剤の配合量は本発明の目的が達成できる限り特に限定されないが、上記した基材樹脂100重量部に対し4〜25重量部程度が好ましい。4重量部よりも少ないと木質感を十分に付与できない傾向があり、一方、25重量部を超えると艶消し木質調木口材の強度が低下する傾向がある。 Although the compounding quantity of a wood filler is not specifically limited as long as the objective of this invention can be achieved, About 4-25 weight part is preferable with respect to 100 weight part of above-described base resin. If the amount is less than 4 parts by weight, the wood texture tends not to be sufficiently imparted, whereas if the amount exceeds 25 parts by weight, the strength of the matte wood finish mouthpiece tends to decrease.
本発明において用いられる発泡剤としては、加熱によって分解、或いは物理的変化によりガスを発生するタイプの、従来から発泡プラスチックスの発泡剤として使用されてきたものがいずれも使用できる。発泡剤をより具体的に示すと、無機系発泡剤としては、重炭酸ナトリウム、重炭酸アンモニウム、炭酸アンモニウム、水素化ホウ素ナトリウム、アジド化合物などが例示できる。有機系発泡剤としては、アゾジカルボンアミドやアゾビスイソブチロニトリルに代表されるアゾ化合物、オキシスベンゼンスルホニルヒドラジドに代表されるスルホニルヒドラジド化合物、ジニトロソペンタメチレンテトラミンに代表されるニトロソ化合物等が例示でき、また、発泡剤や高圧ガスを内部に含むマイクロカプセルの様な自己膨張型発泡剤を用いても良いが、これに限定されるものではない。これらの発泡剤は単独又は2種以上を組み合わせて用いられるが、アゾ化合物系の発泡剤を使用すると、セルが緻密な艶消し木質調木口材を製造することができる。 As the foaming agent used in the present invention, any of the types that have been used as foaming agents for foamed plastics of the type that decomposes by heating or generates gas by physical change can be used. More specifically, the inorganic foaming agent includes sodium bicarbonate, ammonium bicarbonate, ammonium carbonate, sodium borohydride, an azide compound, and the like. Examples of organic foaming agents include azo compounds represented by azodicarbonamide and azobisisobutyronitrile, sulfonyl hydrazide compounds represented by oxysbenzenesulfonyl hydrazide, and nitroso compounds represented by dinitrosopentamethylenetetramine. A self-expanding foaming agent such as a microcapsule containing a foaming agent or a high-pressure gas may be used, but is not limited thereto. These foaming agents are used singly or in combination of two or more. When an azo compound-based foaming agent is used, a matte wood-like wood finish with dense cells can be produced.
発泡剤の配合量は使用する発泡剤のガス発生量によっても異なり一概には規定し難いが、シボが付けやすくなり、端部を切削した時にその切削面に艶が発生しない程度であれば特に限定されない。通常、上記基材樹脂100重量部に対し、0. 1〜1.0重量部程度配合するのが好ましい。この配合量により発泡倍率が1.05〜1.8倍程度の発泡成形体になり、シボが付けやすく、また深さもコントロールしやすく、端部を切削したとしても切断面に艶が発生せず、十分に木質感が現れ、また強度も十分である。なお、発泡倍率が1.05倍未満では、ソリッド品に近くなり、シボが付けにくいばかりでなく気泡が少なすぎて木質感が出にくくなり、一方、1.8倍を超えると発泡成形体の表面硬度が軟らかくなり傷が付きやすく、また端部を切削した時に発泡層のセルが粗くなり表面の質感とに差が発生しやすくなる。より好ましくは、1.2〜1.5倍程度である。 The blending amount of the foaming agent varies depending on the amount of gas generated by the foaming agent used, and it is difficult to specify it.However, it is easy to apply a wrinkle, especially if it does not cause gloss on the cut surface when cutting the edge It is not limited. Usually, it is preferable to mix about 0.1 to 1.0 part by weight with respect to 100 parts by weight of the base resin. With this blending amount, it becomes a foamed molded product with a foaming ratio of about 1.05 to 1.8 times, it is easy to attach a texture, the depth is easy to control, and even if the edge is cut, no gloss is generated on the cut surface The wood texture is sufficient, and the strength is sufficient. If the expansion ratio is less than 1.05, it is close to a solid product, and not only is it difficult to apply a texture, but there are too few bubbles to make the wood texture difficult to produce. The surface hardness is soft and easily scratched, and the cell of the foam layer becomes rough when the end portion is cut, and a difference in the surface texture tends to occur. More preferably, it is about 1.2 to 1.5 times.
本発明において用いられる種剤樹脂は、基材樹脂よりもMFR値が低い樹脂を用いることが好ましい。種剤樹脂は基材樹脂よりも流動性が低いため押出成形の混練工程では基材樹脂と均一に混合せず、このような種剤樹脂を混合することにより発泡成形体中に不規則な且つ境界のはっきりしない筋模様を形成して木目調に酷似した外観を与えることができる。種剤樹脂として用いる樹脂の種類は、基材樹脂と同じまたは基材樹脂と相溶性のある樹脂が好ましい。
種剤樹脂の配合量は、適当な木目模様が形成される限り特に限定されないが、基材樹脂100重量部に対して好ましくは3〜15重量部である。3重量部未満では十分に木目模様が発現せず、一方、15重量部を超えると顔料の含有量が多くなり木目模様が目立たなくなる傾向がある。
The seed resin used in the present invention is preferably a resin having an MFR value lower than that of the base resin. Since the seed resin has lower fluidity than the base resin, it is not uniformly mixed with the base resin in the kneading process of extrusion molding. A streak pattern with an unclear boundary can be formed to give an appearance very similar to a wood grain. The kind of resin used as the seed resin is preferably the same as the base resin or a resin compatible with the base resin.
The blending amount of the seed resin is not particularly limited as long as an appropriate wood grain pattern is formed, but is preferably 3 to 15 parts by weight with respect to 100 parts by weight of the base resin. If the amount is less than 3 parts by weight, the wood grain pattern does not sufficiently develop. On the other hand, if the amount exceeds 15 parts by weight, the pigment content increases and the wood grain pattern tends to be inconspicuous.
本発明において用いられる顔料としては特に限定されず、従来公知の顔料が全て好適に使用でき、所望の木目模様に応じて、イエロー、オレンジ、ブラウン、レッド等の色の顔料が、単独又は2種以上組み合わせて用いられる。
顔料の配合量は、所望の木目模様や木質感により適宜決定されるが、基材樹脂100重量部に対し0.5〜5.0重量部が好ましい。0.5重量部未満では深みのある木目模様や木質感が発現せず、一方、5.0重量部を超えると、顔料の含有量が多くなり、木目模様が目立たなくなる傾向がある。
The pigment used in the present invention is not particularly limited, and all conventionally known pigments can be suitably used. Depending on the desired wood grain pattern, pigments of colors such as yellow, orange, brown, and red may be used alone or in combination of two kinds. Used in combination.
The blending amount of the pigment is appropriately determined depending on the desired wood grain pattern and texture, but is preferably 0.5 to 5.0 parts by weight with respect to 100 parts by weight of the base resin. If the amount is less than 0.5 parts by weight, a deep wood pattern or wood texture does not appear. On the other hand, if the amount exceeds 5.0 parts by weight, the pigment content increases and the wood pattern tends to be inconspicuous.
本発明における木質な樹脂組成物には、更に無機充填剤を配合することもできる。この無機充填剤を配合することにより、艶消し木質調木口材の線膨張を抑え、綺麗な外観を維持することができる。本発明で用いられる無機充填剤としては特に限定されず、通常、アクリロニトリル−エチレンプロピレンゴム−スチレン樹脂、アクリルゴム−スチレン−アクリロニトリル樹脂に配合される無機充填剤が全て好適に使用できるが、例えば、炭酸カルシウム、珪酸カルシウム、タルク、アルミナ、雲母、石英又はシリカ、ガラス等が挙げられ、これらは単独又は2種以上組み合わせて用いられる。無機充填剤の粒径は2μm〜10μm程度が好ましい。
無機充填剤の配合量は、通常、基材樹脂100重量部に対し5〜20重量部が好ましい。5重量部未満では線膨脹率が大きくなり、一方、20重量部を超えると強度の低下が生じやすくなる。
The woody resin composition in the present invention can further contain an inorganic filler. By blending this inorganic filler, it is possible to suppress the linear expansion of the matted wood-finished mouthpiece and maintain a clean appearance. The inorganic filler used in the present invention is not particularly limited, and usually all inorganic fillers blended in acrylonitrile-ethylenepropylene rubber-styrene resin and acrylic rubber-styrene-acrylonitrile resin can be suitably used. Examples thereof include calcium carbonate, calcium silicate, talc, alumina, mica, quartz or silica, glass, and the like, and these are used alone or in combination of two or more. The particle size of the inorganic filler is preferably about 2 μm to 10 μm.
The amount of the inorganic filler is usually preferably 5 to 20 parts by weight with respect to 100 parts by weight of the base resin. If the amount is less than 5 parts by weight, the linear expansion coefficient increases.
本発明における木質系樹脂組成物には、更に滑剤を配合することもできる。滑剤としては、汎用合成樹脂の押出成形で通常使用されるものがいずれも使用でき、例えば、ステアリン酸カルシウム、ステアリン酸マグネシウム、ステアリン酸亜鉛等の金属石鹸類;ステアリン酸モノグリセライド、ステアリルステアリレート等の脂肪酸エステル類;ステアリン酸アミド、メチレンビスステアリン酸アミド等の脂肪酸アマイド類;ポリエチレンワックス、パラフィン等の炭化水素類;ステアリルアルコール等の高級アルコール、ステアリン酸等の高級脂肪酸等が挙げられる。これらは単独で又は2種以上組み合わせて用いられる。 A lubricant may be further added to the woody resin composition in the present invention. As the lubricant, any of those commonly used in extrusion molding of general-purpose synthetic resins can be used, for example, metal soaps such as calcium stearate, magnesium stearate, and zinc stearate; fatty acids such as stearic acid monoglyceride and stearyl stearate. Esters; fatty acid amides such as stearic acid amide and methylenebis stearic acid amide; hydrocarbons such as polyethylene wax and paraffin; higher alcohols such as stearyl alcohol; higher fatty acids such as stearic acid and the like. These may be used alone or in combination of two or more.
滑剤は、通常の場合、樹脂の加熱成形時にその流動性を高くして成形を容易にするため、樹脂組成物に対し1〜10重量部程度添加されるが、本発明においては基材樹脂の流動性のみを高くして、流動性の低い種剤樹脂との流動性の差をより大きして木目模様をより鮮明にするために、基材樹脂100重量部に対し0.1〜2.0重量部配合するのが好ましい。配合量が0.1重量部より少ないと上記添加効果が十分でなく、一方、2.0重量部を超えると基材樹脂のみならず種剤樹脂の流動性までも大きくなり、その結果、両者の流動性の差が大きくならず、木目模様をより鮮明にする効果は得られ難い。 In general, the lubricant is added to the resin composition in an amount of about 1 to 10 parts by weight in order to increase the fluidity at the time of resin heat molding and facilitate molding. In order to increase only the fluidity and increase the difference in fluidity from the seed resin having low fluidity to make the grain pattern clearer, 0.1 to 2. It is preferable to add 0 part by weight. When the blending amount is less than 0.1 parts by weight, the above-described effect of addition is not sufficient, while when it exceeds 2.0 parts by weight, not only the base resin but also the fluidity of the seed resin is increased. The difference in fluidity does not increase, and the effect of making the wood grain pattern clearer is difficult to obtain.
本発明における木質系樹脂組成物には、更に、発泡性を向上させるために、発泡核剤としてタルク、炭酸カルシウム、ワラストナイト、クレイ、珪酸カルシウム等を添加してもよい。これらは単独で又は2種以上組み合わせて用いられる。 In the woody resin composition of the present invention, talc, calcium carbonate, wollastonite, clay, calcium silicate, and the like may be added as a foam nucleating agent in order to improve foamability. These may be used alone or in combination of two or more.
本発明における木質系樹脂組成物には、必要に応じて、更に、酸化防止剤、ゲル化促進剤、メヤニ防止剤、帯電防止剤等のその他の添加剤を配合してもよい。 If necessary, the wood-based resin composition in the present invention may further contain other additives such as an antioxidant, a gelation accelerator, an anti-scratch agent, and an antistatic agent.
本発明で使用する木質系樹脂組成物の調製には、従来公知の混合機、押出機が使用される。まず、基材樹脂、木質充填剤、発泡剤、種剤樹脂、顔料等を配合し、混合機で混合する。混合機としては、例えば、スーパーミキサー、バンバリーミキサー等が挙げられる。混合機で混合された粉体状の混合物は、そのまま押出成形機に供給してもよく、また、発泡剤を除く原料を混練押出機でペレットとし、このペレットと発泡剤との混合物を押出成形機に供給してもよい。 Conventionally known mixers and extruders are used for the preparation of the woody resin composition used in the present invention. First, a base resin, a woody filler, a foaming agent, a seed resin, a pigment, and the like are blended and mixed with a mixer. Examples of the mixer include a super mixer and a Banbury mixer. The powdery mixture mixed in the mixer may be supplied to the extruder as it is, or the raw material excluding the foaming agent is formed into pellets with the kneading extruder, and the mixture of the pellets and the foaming agent is extruded. You may supply to a machine.
以下、粉体状の木質系樹脂組成物から艶消し木質調木口材を製造する好ましい方法を、図1に基づいて説明する。
まず、上記の如く調整した木質系樹脂組成物を押出成形機1のホッパー1aから投入し、金型のダイ1bから溶融した樹脂を大気中に押し出す。
Hereinafter, a preferred method for producing a matted wood-like cut end from a powdery wood-based resin composition will be described with reference to FIG.
First, the woody resin composition prepared as described above is charged from the
押し出された発泡成形体は、平滑性、寸法安定性がないため、サイジング2を用いて平滑性、寸法安定性を付与することが好ましい。 Since the extruded foamed article does not have smoothness and dimensional stability, it is preferable to use sizing 2 to impart smoothness and dimensional stability.
次に、発泡成形体は冷却固化される。冷却方法は特に限定されず、図示したように、水槽3内を通過させて水冷してもよいし、また、冷却ロールにて押圧しながら冷却してもよく、これらを組み合わせて使用してもよい。 Next, the foamed molded product is cooled and solidified. The cooling method is not particularly limited, and as shown in the figure, it may be cooled by passing through the water tank 3, may be cooled while being pressed with a cooling roll, or may be used in combination. Good.
次に、発泡成形体は加熱したエンボスロール4にて押圧することにより、表面にシボ付け及び艶消しが行われる。
エンボスロール4の温度は好ましくは180℃〜220℃である。この温度が180℃未満であるとシボが入りにくく、艶も消えず、一方、220℃を超えると発泡成形体の表面がおかされ粗悪となる。
Next, the foamed molded product is pressed and matted on the surface by pressing with a heated embossing roll 4.
The temperature of the embossing roll 4 is preferably 180 ° C to 220 ° C. If this temperature is less than 180 ° C., the embossing is difficult to enter, and the gloss does not disappear. On the other hand, if it exceeds 220 ° C., the surface of the foamed molded product is damaged and becomes poor.
加熱したエンボスロール4でシボ付け及び、艶消しを行うことにより、発泡成形体に幅方向の反りが発生することがある。この反りを修正するため、シリコンロール5で該発泡成形体の表面側及び裏面側を押圧することが好ましい。これにより、木口部分に張り付けた木口材が浮き上がって剥がれるようなことが防止され、より商品価値の高い艶消し木質調木口材を得ることができる。尚、この場合、シリコンロール5の温度を上記したエンボスロール4と同程度の温度に加熱することにより、反り防止と同時に更に艶消し効果も得ることができる。 By performing embossing and matting with the heated embossing roll 4, warpage in the width direction may occur in the foamed molded product. In order to correct this warp, it is preferable to press the surface side and the back side of the foamed molded body with the silicon roll 5. Thereby, it is prevented that the lip material stuck to the lip portion is lifted and peeled off, and a matte wood-like timber with a higher commercial value can be obtained. In this case, by heating the silicon roll 5 to a temperature comparable to that of the embossing roll 4 described above, it is possible to obtain a matte effect while preventing warpage.
シボ付け及び艶消しされた発泡成形体は、引取機6を経て該成形体の裏面に、木口部分との接着性を高めるためのプライマーを塗布してプライマー層を形成してもよい。
プライマーの塗布方法としては、公知の種々の方法を用いることができる。例えば、ロールコート法、グラビアロールコート法、ロールブラッシュ法、スプレーコート法、エアーナイフコート法、バーコート法及びカーテンコート法等を単独でもしくは組み合わせて使用することができる。
塗布するプライマーとしては、アロンエバーグリップリミテッド製PR−135NT、P−71等が例示できる。
この場合、図2に示すように、発泡成形体の裏面に、プライマー塗布用の溝11を設け、プライマー層12を形成しておくのが好ましい。
The foamed molded product that has been textured and matted may be subjected to a take-up machine 6 to apply a primer for improving the adhesiveness to the end of the molded product to form a primer layer.
Various known methods can be used as a method for applying the primer. For example, a roll coating method, a gravure roll coating method, a roll brush method, a spray coating method, an air knife coating method, a bar coating method, a curtain coating method and the like can be used alone or in combination.
Examples of the primer to be applied include PR-135NT and P-71 manufactured by Aron Evergrip Limited.
In this case, as shown in FIG. 2, it is preferable that a
プライマー塗布された発泡成形体は乾燥機8にて乾燥され、艶消し木質調木口材9とされ、巻き取り機10により巻き取られる。
The foam-molded article coated with the primer is dried by a dryer 8 to form a matted wood-like wood mouthpiece 9 and wound by a
以下、実施例及び比較例を挙げて本発明を更に詳細に説明するが、本発明はこれらにより何ら制限されるものではない。 EXAMPLES Hereinafter, although an Example and a comparative example are given and this invention is demonstrated further in detail, this invention is not restrict | limited at all by these.
実施例1
アクリロニトリル−エチレンプロピレンゴム−スチレン樹脂(テクノポリマー株式会社製、W220)100重量部、木粉(木質充填剤)[有限会社大林工業製、S80(80メッシュ)]15重量部、発泡剤(永和化成工業株式会社製、ビニホールAC#1)0.4重量部、タルク(無機充填剤)(富士タルク株式会社製、PKP−53)5重量部、滑剤[コグニスジャパン株式会社製、LOXAMID EBS(エチレンビスステアリン酸アマイド)]0.5重量部、種材樹脂6重量部(日本ピグメント株式会社製、WX01MB LD0220を3重量、日本ピグメント株式会社製、WX01MB LD0362を3重量部)、顔料(レジノカラー株式会社、SBHP−8366)2重量部からなる混合物をホッパー1aから押出成形機1(IKG株式会社製50粍、L/D比=24)内に投入した。シリンダーの温度条件は、C1/130℃、C2/170℃、C3/170℃であり、ダイスの温度条件は170℃とした。
なお、押出成形機1には、2mm×39mmの板状で裏面に幅5mm深さ0.3mmの溝が6mm間隔に3本設けられた発泡成形体を押出すダイ1bが設けられた金型を取り付けた。
Example 1
Acrylonitrile-ethylenepropylene rubber-styrene resin (Technopolymer Co., Ltd., W220) 100 parts by weight, wood powder (wood filler) [manufactured by Obayashi Kogyo Co., Ltd., S80 (80 mesh)], 15 parts by weight, foaming agent (Yewa Kasei) Industrial Co., Ltd., VINYHALL AC # 1) 0.4 parts by weight, talc (inorganic filler) (Fuji Talc Co., Ltd., PKP-53) 5 parts by weight, lubricant [Cognis Japan Co., Ltd., LOXAMID EBS (ethylene bis Stearic acid amide)] 0.5 parts by weight, seed resin 6 parts by weight (manufactured by Nippon Pigment Co., Ltd., 3 parts by weight of WX01MB LD0220, manufactured by Nippon Pigment Co., Ltd., 3 parts by weight of WX01MB LD0362), pigment (Resino Color Co., Ltd., SBHP-8366) Mixing 2 parts by weight from
The extrusion molding machine 1 is provided with a die 1b for extruding a foam molded body having a plate shape of 2 mm × 39 mm and having three grooves with a width of 5 mm and a depth of 0.3 mm on the back surface at intervals of 6 mm. Attached.
押出された発泡成形体にサイジング2で波取り処理を施し、水槽3により水冷した。なお、水冷直後の成形品の温度は約20℃であった。
この発泡成形体の表面に200℃に熱したエンボスロール4(宮森金属製版所製、B1072)を押圧して、その表面にシボ付け及び艶消しを行った。
次いで、発泡成形体の表面にシリコンロール5(明和ゴム株式会社製)で押圧して、幅方向の反りを修正するとともに、再度補充的に、表面の艶消しを行った。
The extruded foamed product was subjected to a chamfering process with sizing 2 and cooled with water in a water tank 3. The temperature of the molded product immediately after water cooling was about 20 ° C.
An embossing roll 4 (B1072 manufactured by Miyamori Metal Works, Ltd.) heated to 200 ° C. was pressed on the surface of the foamed molded product, and the surface was subjected to embossing and matting.
Next, the surface of the foam molded body was pressed with a silicon roll 5 (manufactured by Meiwa Rubber Co., Ltd. ) to correct the warp in the width direction, and the surface was matted again.
次に、発泡成形体の裏面にプライマー(アロンエバーグリップリミテッド株式会社製、PR−135NT)を塗布し、厚さ70μmのプライマー層を形成した。なお、このプライマー塗布に使用した塗布機7はハッポー化学工業株式会社製である。
得られたプライマー層付きの発泡成形体を乾燥機8で乾燥した後、巻き取り機10(直径500mm)に巻き取り、ロール状の艶消し木質調木口材(発泡倍率1.2)9を得た。
Next, a primer (PR-135NT, manufactured by Aron Evergrip Limited, Inc.) was applied to the back surface of the foamed molded product to form a primer layer having a thickness of 70 μm. The applicator 7 used for the primer application is manufactured by Happo Chemical Industries, Ltd.
The foamed molded body with the primer layer thus obtained is dried with a dryer 8 and then wound around a winder 10 (diameter 500 mm) to obtain a roll-like matte wood finish mouthpiece (foaming ratio 1.2) 9. It was.
得られた艶消し木質調木口材について、光沢度(艶消し)及び耐候性を下記の方法により評価した。結果を表1に示す。
(光沢度)
タコスジャパン株式会社製ハンディー光沢計(TMS724)を使用した。
測定条件:光源角度60° 受光角度60°
(耐候性)
サンシャインウエザロメーター(スガ試験機社製)を用い、下記の条件で試験した。色差ΔEが5以下を耐候性良好と評価した。
試験条件:
促進試験時間:2000時間
色差計:CM3600D(ミノルタ社製)
光源:サンシャインカーボンアーク
ブラックパネル温度:63℃
試験サイクル:照射102分、降雨18分の繰り返し
About the obtained matte wood-like wood cutting material, glossiness (matte) and weather resistance were evaluated by the following methods. The results are shown in Table 1.
(Glossiness)
A handy gloss meter (TMS724) manufactured by Taco Japan Co., Ltd. was used.
Measurement conditions: Light source angle 60 ° Light receiving angle 60 °
(Weatherability)
A sunshine weatherometer (manufactured by Suga Test Instruments Co., Ltd.) was used for testing under the following conditions. A color difference ΔE of 5 or less was evaluated as good weather resistance.
Test conditions:
Acceleration test time: 2000 hours Color difference meter: CM3600D (Minolta)
Light source: Sunshine carbon arc Black panel temperature: 63 ° C
Test cycle: Irradiation 102 minutes, rainfall 18 minutes repetition
実施例2
シリコンロール5を用いなかった他は実施例1と同様にしてロール状の艶消し木質調木口材を得、実施例1と同様にして光沢度及び耐候性を評価した。結果を表1に示す。
Example 2
Except that the silicon roll 5 was not used, a roll-like matte wood finish was obtained in the same manner as in Example 1, and the glossiness and weather resistance were evaluated in the same manner as in Example 1. The results are shown in Table 1.
比較例1
基材樹脂をABS樹脂(テクノポリマー株式会社製ABS150)に置き換えた他は実施例1と同様にしてロール状の艶消し木質調木口材を得、実施例1と同様にして光沢度及び耐候性を評価した。結果を表1に示す。
Comparative Example 1
Except that the base resin was replaced with ABS resin (ABS150 manufactured by Techno Polymer Co., Ltd.), a roll-like matte wood finish was obtained in the same manner as in Example 1, and the glossiness and weather resistance were obtained in the same manner as in Example 1. Evaluated. The results are shown in Table 1.
比較例2
発泡剤を含有させなかった他は、比較例1と同様にしてソリッド(非発泡)の木質調木口材を得、実施例1と同様にして光沢度及び耐候性を評価した。結果を表1に示す。
Comparative Example 2
A solid (non-foamed) wood-like wood mouthpiece was obtained in the same manner as in Comparative Example 1 except that no foaming agent was contained, and the glossiness and weather resistance were evaluated in the same manner as in Example 1. The results are shown in Table 1.
叙上のとおり、本発明の艶消し木質調木口材は、木質感に富むとともに、艶消し性に優れ高級感があり、また耐候性が良好であるので、特に屋外で使用される木口材としても有用である。 As described above, the matted wood-like wood mouthpiece of the present invention is rich in wood texture, excellent in matteness and high-quality, and has good weather resistance, so that it is particularly useful as a mouthpiece used outdoors. Is also useful.
1 押出成形機
1a ホッパー
1b ダイ
2 サイジング
3 水槽
4 エンボスロール
5 シリコンロール
6 引取機
7 プライマー塗布機
8 乾燥機
9 艶消し木質調木口材
10 巻き取り機
11 プライマー塗布用の溝
12 プライマー層
DESCRIPTION OF SYMBOLS 1
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