JP5335451B2 - Humidity sensor - Google Patents

Humidity sensor Download PDF

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JP5335451B2
JP5335451B2 JP2009012447A JP2009012447A JP5335451B2 JP 5335451 B2 JP5335451 B2 JP 5335451B2 JP 2009012447 A JP2009012447 A JP 2009012447A JP 2009012447 A JP2009012447 A JP 2009012447A JP 5335451 B2 JP5335451 B2 JP 5335451B2
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moisture
humidity
porous fine
paper
fine particles
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JP2010169540A (en
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正義 志村
健 小田代
年博 野島
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アセイ工業株式会社
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この発明は湿度の検知を行う湿度センサーに関するものである。   The present invention relates to a humidity sensor that detects humidity.

湿度の管理は、商品の輸送、保管をはじめ、多くの産業分野において広く行われており、湿度を感知するための湿度センサーも数々のタイプのものが提案されている。   Humidity management is widely carried out in many industrial fields including transportation and storage of goods, and various types of humidity sensors for sensing humidity have been proposed.

特開2006−17599号公報JP 2006-17599 A

なしNone

シール状の基材上に感湿材を固定し、感湿材が吸湿した際の色相変化や滲みの広がりなどによって湿度の検知を行うシール状の湿度センサーは、設置、取扱いの容易さや感知精度の良さなどから、広く使用されている。   A moisture sensor is fixed on a seal-like substrate, and the humidity sensor detects the humidity by the hue change or spreading of the moisture when the moisture-sensitive material absorbs moisture. It is widely used because of its goodness.

しかしながら、従来から存在するこれらの湿度センサーの多くは、滲みの大きさや色相の変化という相対的変化によって湿度の変化を検知しようとするものであるので、分かりずらく、又、感湿材を基材上に固定する作業も手作業で行う必要があり、量産化がむずかしく、製造コストが高いといった問題が存在していた。   However, many of these existing humidity sensors are difficult to understand because they attempt to detect changes in humidity based on relative changes such as the size of bleeding and changes in hue, and are based on moisture sensitive materials. The work of fixing on the material also had to be done manually, and there were problems such as difficulty in mass production and high manufacturing costs.

本発明は、このシール状の湿度センサーの上記問題点を解決することを目的とするものであり、従来のものとは全く異なった表示メカニズムを採用することによって、湿度感知の事実を明瞭に表示出来る様にすると共に、量産化にも適した湿度センサーを提供せんとするものである。   The present invention aims to solve the above-mentioned problems of the seal-type humidity sensor. By adopting a display mechanism completely different from the conventional one, the fact of humidity sensing is clearly displayed. We intend to provide a humidity sensor suitable for mass production.

表面側に多孔質微粒子層6が形成された紙葉を適当な大きさに裁断した紙片1の裏面側に吸湿性を有する多孔質微粒子とデンプン糊と着色剤と水とを混練したインク状の吸湿材2をスポット状に塗布し乾燥させて感湿部3を形成することにより、上記課題を解決した。   An ink-like kneaded mixture of hygroscopic porous fine particles, starch paste, colorant, and water on the back side of a paper piece 1 obtained by cutting a paper sheet having a porous fine particle layer 6 formed on the front side into an appropriate size. The said subject was solved by apply | coating the moisture-absorbing material 2 to spot shape, and making it dry and forming the moisture-sensitive part 3. FIG.

図3に示す様に、感湿部3が形成されている側、つまり裏面側を設置箇所表面に接する様に貼り付け、使用に供する。この状態において、設置場所の雰囲気の水分は、紙片1の表面側から紙片1中に浸入し、感湿部3中の多孔質部粒子の細孔に取り込まれるが、雰囲気湿度が設定値を超えると、水分は着色剤を伴ってこれから溢れ出し、図4に矢印で示す様に、表面側に移動し、表面にスポット状の発色マーク4を現出される。なお、紙片1の表面側には多孔質微粒子がコーティングされ、多孔質微粒子層6が形成されているが、この多孔質微粒子の空隙は紙の繊維によって形成される空隙よりも狭く、水分吸収のドライビングフォースである毛細管力が大きい為、着色剤を伴った水分は毛細管現象によって紙片1の表面側に強力に吸い上げられ、紙片1の内部には拡散せずに、紙片1の表面に鮮明な発色マーク4を形成し、その周囲に不鮮明な滲みはほとんど形成しない。吸湿材2中のデンプン糊は多孔質微粒子及び着色剤を紙片1に固定させるバインダーの役を果すものであるが、デンプン糊はそれ自体水溶性であるので、水分が多孔質微粒子に浸入することを何ら阻げることはない。   As shown in FIG. 3, the side on which the moisture-sensitive part 3 is formed, that is, the back side is pasted so as to be in contact with the surface of the installation location and used. In this state, the moisture in the atmosphere at the installation location penetrates into the paper piece 1 from the surface side of the paper piece 1 and is taken into the pores of the porous part particles in the moisture sensitive part 3, but the atmospheric humidity exceeds the set value. Then, the water overflows with the colorant and moves to the surface side as shown by the arrow in FIG. 4 so that the spot-like coloring mark 4 appears on the surface. The surface side of the paper piece 1 is coated with porous fine particles to form a porous fine particle layer 6. The voids of the porous fine particles are narrower than the voids formed by the paper fibers, and absorb moisture. Since the capillary force that is the driving force is large, the water accompanying the colorant is strongly sucked up to the surface side of the paper piece 1 by the capillary phenomenon, and does not diffuse inside the paper piece 1 but vividly develops on the surface of the paper piece 1 The mark 4 is formed, and almost no blurred blur is formed around it. The starch paste in the hygroscopic material 2 serves as a binder for fixing the porous fine particles and the colorant to the paper piece 1, but the starch paste itself is water-soluble, so that moisture enters the porous fine particles. There is nothing to prevent.

この様に、それまで何もなかった紙片1の表面に設定湿度超過と共に、色彩を伴った発色マーク5が鮮やかに出現し、これにより設定湿度超過の事実が表示される。   In this way, the coloring mark 5 accompanied with the color appears vividly on the surface of the paper piece 1 that had nothing before, with the setting humidity being exceeded, thereby displaying the fact that the setting humidity has been exceeded.

従って、色相の変化や滲みの大きさにより、設定湿度超過の事実を知る従来の湿度センサーに比べはるかに分かりやすい。又、吸湿材2はインク状をしているので、これを紙片1の裏面側にスポット状に塗布するだけで簡単に湿度センサーを構成することが出来るので、生産性にすぐれ、製造コストも低廉である。更に、吸湿材2からなる感湿部3は紙片1の裏面側に形成され、設定湿度超過の際に紙片1内に広く拡散することもないので、粉末状の石油系ワックスの熱溶解作用を利用したワックスタイプ感湿センサーとの同一紙片上での併設も出来るので、湿度及び温度の同時管理も可能となる。   Therefore, it is much easier to understand than the conventional humidity sensor that knows the fact that the set humidity has been exceeded due to the change in hue and the size of bleeding. Further, since the moisture absorbent material 2 is in the form of ink, a humidity sensor can be configured simply by applying it to the back side of the paper piece 1 in a spot form, so that the productivity is excellent and the manufacturing cost is low. It is. Further, the moisture sensitive part 3 made of the moisture absorbent material 2 is formed on the back side of the paper piece 1 and does not diffuse widely into the paper piece 1 when the set humidity is exceeded. Since the wax type moisture sensor used can be installed on the same piece of paper, the humidity and temperature can be managed simultaneously.

この発明に係る湿度センサーの実施例1の拡大斜視図。1 is an enlarged perspective view of a humidity sensor according to Embodiment 1 of the present invention. FIG. 同じく、裏面側から見た斜視図。Similarly, the perspective view seen from the back side. 同じく、設置箇所表面に貼り付けた状況を示した拡大断面図。Similarly, the expanded sectional view which showed the condition affixed on the installation location surface. 同じく、設定湿度超過により、発色マークが形成されるメカニズムを模式的に描いた説明図。Similarly, an explanatory view schematically illustrating a mechanism for forming a color mark when the set humidity is exceeded. 同じく、設定湿度超過により、表面側に発色マークが形成された状況を示した表面側から見た斜視図。Similarly, the perspective view seen from the surface side which showed the condition where the color development mark was formed on the surface side by excess of setting humidity. 他の実施例の裏面側から見た斜視図。The perspective view seen from the back surface side of the other Example.

表面側に多孔質微粒子層6が形成された紙葉を適当な大きさに裁断した紙片1の裏面側に吸湿性を有する多孔質微粒子とデンプン糊と着色剤と水とを混練したインク状の吸湿材2をスポット状に塗布し、乾燥させて感湿部3を形成する。   An ink-like kneaded mixture of hygroscopic porous fine particles, starch paste, colorant, and water on the back side of a paper piece 1 obtained by cutting a paper sheet having a porous fine particle layer 6 formed on the front side into an appropriate size. The moisture absorbing material 2 is applied in a spot shape and dried to form the moisture sensitive portion 3.

図1はこの発明に係る湿度センサーの一実施例の断面図、図2はその裏面側から見た斜視図である。図中1は基材となる紙片であり、天然セルロースを水の存在化で薄葉状に形成した紙本体4の一方の面(表面側)にシリカゲルなどの多孔質微粒子をコーティングして、多孔質微粒子層6を形成した紙葉を適当な大きさに裁断したものである。この種の紙葉は、インクジェット紙と称され、インクジェットプリンタ用画像記録紙として広く市販されている。   FIG. 1 is a sectional view of an embodiment of a humidity sensor according to the present invention, and FIG. 2 is a perspective view seen from the back side thereof. In the figure, reference numeral 1 denotes a piece of paper serving as a base material. One side (surface side) of a paper body 4 in which natural cellulose is formed into a thin leaf shape in the presence of water, is coated with porous fine particles such as silica gel. The paper sheet on which the fine particle layer 6 is formed is cut into an appropriate size. This type of paper sheet is referred to as inkjet paper and is widely available as image recording paper for inkjet printers.

そして、この紙片1の裏面側には、吸湿材2がスポット状に塗付されて、感湿部3が形成されている。この吸湿材2は、本発明の最も重要な構成要件であり、シリカゲルなどの吸湿性に富む多孔質微粒子、デンプン糊、着色剤に水を加え、練り合わせたインク状物質である。多孔質微粒子としては、シリカゲルのほか、ゼオライトなども使用可能である。又、着色剤としては、顔料、染料どちらも使用可能である。   And the moisture absorption material 2 is apply | coated to the back surface side of this paper piece 1 in the spot shape, and the moisture sensitive part 3 is formed. The hygroscopic material 2 is the most important constituent element of the present invention, and is an ink-like substance obtained by adding water to porous fine particles having high hygroscopic properties such as silica gel, starch paste, and colorant and kneading them. In addition to silica gel, zeolite and the like can be used as the porous fine particles. As the colorant, both pigments and dyes can be used.

多孔質微粒子、デンプン糊、着色剤、水の配合割合は、使用条件によって左右される為、一概に規定出来ないが、多孔質微粒子は設定湿度に応じて増減されるものであり、一般的は、感知するべき設定湿度が高い程、多孔質微粒子の配合割合を多くする。
吸湿材2は紙片1に塗付された後、その中の水分が蒸発することにより、乾燥して固形状の感湿部3となる。
The mixing ratio of porous fine particles, starch paste, colorant, and water depends on the conditions of use, so it cannot be specified unconditionally, but the porous fine particles are increased or decreased according to the set humidity. As the set humidity to be sensed is higher, the blending ratio of the porous fine particles is increased.
After the moisture absorbent material 2 is applied to the paper piece 1, the moisture therein evaporates to dry and become a solid moisture-sensitive part 3.

なお、図1及び図2に示す感湿センサーは感湿部3が一個だけ形成されたものであるが、図6に示すものの様に、10%、20%、30%という様に設定湿度が異なる感湿部3を複数個形成しても良い。   The humidity sensor shown in FIG. 1 and FIG. 2 has only one humidity sensing part 3 formed. However, as shown in FIG. 6, the set humidity is 10%, 20%, and 30%. A plurality of different moisture sensitive portions 3 may be formed.

そして、この実施例に係る湿度センサーは、図3に示す様に、感湿部3が形成されている側、つまり裏面側を設置箇所表面に接する様に貼り付け、使用に供する。この状態において、設置場所の雰囲気中の水分は、紙片1の表面側から紙片1中に浸入し、感湿部3中の多孔質部粒子の細孔に取り込まれるが、雰囲気湿度が設定値を超えると、水分は着色剤を伴ってこれから溢れ出し、図4において矢印で示す様に表面側に移動し、図4及び図5に示す様に表面にスポット状の発色マーク4を現出される。なお、紙片1の表面側には多孔質微粒子がコーティングされ、多孔質微粒子層6が形成されているが、この多孔質微粒子の空隙は紙本体7の繊維によって形成される空隙よりも狭く、水分吸収のドライビングフォースである毛細管力が大きい為、着色剤を伴った水分は毛細管現象によって紙片1の表面側に強力に吸い上げられ、紙片1の紙本体7の内部には拡散せずに、紙片1の表面に鮮明な発色マーク4を形成し、その周囲に不鮮明な滲みはほとんど形成しない。吸湿材2中のデンプン糊は多孔質微粒子及び着色剤を紙片1に固定させるバインダーの役を果すものであるが、デンプン糊はそれ自体水溶性であるので、水分が多孔質微粒子に浸入することを何ら阻げることはない。   As shown in FIG. 3, the humidity sensor according to this embodiment is used by attaching the side where the moisture sensitive portion 3 is formed, that is, the back surface side so as to be in contact with the surface of the installation site. In this state, moisture in the atmosphere of the installation location enters the paper piece 1 from the surface side of the paper piece 1 and is taken into the pores of the porous part particles in the moisture-sensitive part 3, but the atmospheric humidity has a set value. If it exceeds, the moisture will overflow from this along with the colorant, move to the surface side as shown by the arrow in FIG. 4, and the spot-like colored mark 4 appears on the surface as shown in FIGS. . In addition, porous fine particles are coated on the surface side of the paper piece 1 to form a porous fine particle layer 6, but the voids of the porous fine particles are narrower than the voids formed by the fibers of the paper body 7, and moisture content is reduced. Since the capillary force, which is the driving force for absorption, is large, the water accompanying the colorant is strongly sucked up to the surface side of the paper piece 1 by capillary action, and does not diffuse into the paper body 7 of the paper piece 1, but the paper piece 1. A clear coloring mark 4 is formed on the surface of the film, and an unclear blur is hardly formed on the periphery thereof. The starch paste in the hygroscopic material 2 serves as a binder for fixing the porous fine particles and the colorant to the paper piece 1, but the starch paste itself is water-soluble, so that moisture enters the porous fine particles. There is nothing to prevent.

この様に、それまで何もなかった紙片1の表面に、設定湿度超過と共に、色彩を伴った発色マーク5が鮮やかに現出し、これにより、設定湿度超過の事実が表示される。   In this way, on the surface of the paper piece 1 that had nothing before, the colored mark 5 accompanied by the color appears vividly with the set humidity being exceeded, thereby displaying the fact that the set humidity has been exceeded.

従って、色相の変化や滲みの大きさにより設定湿度超過の事実を知る従来の湿度センサーに比べ、はるかに分かりやすい。又、吸湿材2はインク状をしているので、これを紙片1の裏面側にスポット状に塗付するだけで簡単に湿度センサーを構成することが出来るので、生産性にすぐれ、製造コストも低廉である。
更に、吸湿材2からなる感湿部3は紙片1の裏面側に形成され、設定湿度超過の際に紙片1内に広く拡散することもないので、粉末状の石油系ワックスの熱融解作用を利用したワックスタイプ感温センサーとの同一紙片上での併設も出来るので、湿度及び温度の同時管理も可能となる。
Therefore, it is much easier to understand than the conventional humidity sensor that knows the fact that the set humidity is exceeded by the change in hue and the size of the blur. In addition, since the moisture absorbent material 2 is in the form of ink, a humidity sensor can be configured simply by applying it to the back side of the piece of paper 1 in a spot shape, so it has excellent productivity and manufacturing cost. It is inexpensive.
Furthermore, the moisture sensitive part 3 made of the moisture absorbent 2 is formed on the back side of the paper piece 1 and does not diffuse widely into the paper piece 1 when the set humidity is exceeded. Since the wax-type temperature sensor used can be installed on the same piece of paper, the humidity and temperature can be managed simultaneously.

商品の輸送、管理をはじめ湿度管理を必要とするあらゆる産業分野において利用可能である。   It can be used in all industrial fields that require humidity control, including transportation and management of goods.

1 紙片
2 吸湿材
3 感湿部
4 発色マーク
6 多孔質微粒子層
7 紙本体
DESCRIPTION OF SYMBOLS 1 Paper piece 2 Hygroscopic material 3 Humidity sensing part 4 Color development mark 6 Porous fine particle layer 7 Paper body

Claims (2)

表面側に多孔質微粒子層(6)が形成された紙葉を適当な大きさに裁断した紙片(1)の裏面側に、吸湿性を有する多孔質微粒子とデンプン糊と着色剤と水とを混練したインク状の吸湿材(2)をスポット状に塗布し、乾燥させて感湿部(3)を形成したことを特徴とする湿度センサー。   On the back side of the paper piece (1) obtained by cutting the paper sheet on which the porous fine particle layer (6) is formed on the front surface side, hygroscopic porous fine particles, starch paste, colorant and water. A humidity sensor, wherein the kneaded ink-like moisture absorbent material (2) is applied in a spot shape and dried to form the moisture sensitive portion (3). 吸湿材(2)を構成している多孔質微粒子がシリカゲルであることを特徴とする請求項1記載の湿度センサー。   The humidity sensor according to claim 1, wherein the porous fine particles constituting the hygroscopic material (2) are silica gel.
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JP6990084B2 (en) 2017-10-02 2022-01-12 京セラ株式会社 Piezoelectric device

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JPS58216936A (en) * 1982-05-18 1983-12-16 Shin Nisso Kako Co Ltd Humidity indicator
JP3298217B2 (en) * 1993-03-31 2002-07-02 凸版印刷株式会社 Ink composition for moisture indicator and recording medium using the same
JP3081789B2 (en) * 1996-04-26 2000-08-28 鐘紡株式会社 Humidity sensor
JPH10253541A (en) * 1997-03-12 1998-09-25 Kyodo Printing Co Ltd Ink for indicator, manufacture thereof, and indicator using the ink
JP2008261681A (en) * 2007-04-11 2008-10-30 Kyodo Printing Co Ltd Humidity indicator

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JP6990084B2 (en) 2017-10-02 2022-01-12 京セラ株式会社 Piezoelectric device

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