JP5315928B2 - Cold rolled steel sheet for drums and method for producing the same - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a cold-rolled steel sheet for a drum can which has particularly proper bake hardenability, has a casting yield, is inexpensive, also has excellent low temperature toughness, has sufficient strength even in retreatment, and is hard to be deformed, and to provide a method of producing the same. <P>SOLUTION: The cold-rolled steel sheet for a drum can has a composition comprising, by mass, 0.0015 to 0.060% C, 0.0015 to 0.060% Si, 0.15 to 0.60% Mn, 0.0015 to 0.060% P, 0.0015 to 0.060% S, 0.015 to 0.060% Al and 0.0015 to &lt;0.0050% N, and the balance Fe with inevitable impurities, and in the C and N, the total of solid solution N and C is 0.0005 to 0.0020%. <P>COPYRIGHT: (C)2010,JPO&amp;INPIT

Description

  The present invention relates to a steel high-strength drum, and more particularly to a cold-rolled steel sheet suitable as a steel drum can material and a method for manufacturing the same. Specifically, the present invention relates to a cold rolled steel sheet for a drum can made of a bake hard type high strength low cost good low temperature toughness steel and a manufacturing method thereof.

  The drums targeted by the present invention include two types of steel open drums defined in JIS Z 1600 and sealed drums defined in JIS Z 1601 as liquid steel drums. The drum is composed of a top plate, a ground plate, and a body plate. In a sealed drum, it is composed of a body plate that is bent into a cylindrical shape and joined by seam welding. In an open drum, only the body plate and the ground plate are tightened. The top plate is detachable. Further, the outer surface and the inner surface are subjected to chemical conversion treatment or coating treatment as necessary.

  Drum cans require precision of the cans and soundness of welded parts, joints, and tightened parts. JIS standards stipulate that confidential tests (water pressure tests), drop tests, stack tests, etc. should be performed. Yes. In addition, when deformed when subjected to an external force during transportation or the like, the stacking or the like is hindered and the appearance is also impaired, so that strength is required.

  Further, since the drum can is subjected to the shot blasting immediately after the post-recovery heat treatment (around 800 ° C.) as the regeneration treatment, it is essential that the heat treatment is not softened and the shot blast treatment is not deformed. Furthermore, in recent years, it is necessary to have low temperature toughness assuming that it is used even in cold regions.

  The steel plate that can be used as the drum material is a hot rolled mild steel plate and steel strip specified in JIS G 3131, or a cold rolled steel plate or steel strip specified in JIS G 3141. The thickness of the steel sheet used is regulated in the range of 1.6 mm to 0.5 mm depending on the kind and class of the drum. For example, in the case of a Class 1 H class with a sealed drum capacity of 200 liters, it is decided to use steel plates with a plate thickness of 1.6 mm for the body plate, top plate, and ground plate.

Conventionally, low carbon aluminum killed box annealed materials have been used as steel plates for drums with emphasis on workability. Its typical steel composition ranges from 0.05 to 0.10% C-0.2 to 0.5% Mn- to 0.05% Si-0.04 to 0.10% Al-0.0015 to 0.005. 0030% N. However, since then, the manufacturing process of steel sheets has been aimed at continuation, and continuous annealing materials with continuous annealing equipment, which is equipment with higher production efficiency, have been widely applied. The steel composition of the continuously annealed material has been almost the same as that of the low carbon aluminum killed box annealed material. At present, this low-carbon aluminum killed steel continuous annealing material has become mainstream in Japan, Europe and America. As an example of the tensile characteristics of the material manufactured for drums, the plate thickness is 1.0 to 1.2 mm, the yield stress (YS) is 23 kgf / mm ² , the tensile strength (TS) is 35 kgf / mm ² , and the elongation ( EL): about 42%. In addition, hot-rolled material is also applied to some thick drums, but the ratio is low.

  Recently, attempts have been made to reduce the thickness of the drum can material in order to reduce can manufacturing costs. However, it is necessary to increase the strength of the material in order to compensate for the decrease in the strength of the can that accompanies a decrease in the thickness of the material. In addition, drums are not used only once, but are generally used after the contents are put in once and the inside is washed again or again, and on average, 4 to 5 times repeatedly. is there. In re-use, shot blasting is usually performed to remove deposits on the inner surface and paint on the outer surface. When the amount of deformation generated in the can body by this shot blasting process is large, the drum cans cannot be stacked and become unsuitable for recycling. Therefore, the amount of deformation of the can body by this shot blasting is one factor that determines the recycling.

  It has been newly found that the deformation of the can body due to the shot blasting process cannot be prevented by merely increasing the room temperature strength of the steel sheet used. That is, before the shot blasting process, an incineration process in which the can body is heated to about 800 ° C. may be performed, and then the shot blast process is often performed before the can body is completely cooled. In addition to the small amount of deformation of the can body due to the above-described shot blasting treatment, the present inventors determine that the amount of deformation during high-temperature heating and the deformation due to the shot blasting treatment at 200 to 500 ° C. is small. It is an important factor. For this reason, it is also required that the can body has high high-temperature strength at 200 ° C. or higher.

As a drum can to which a high-strength steel plate is applied, for example, Japanese Patent Application Laid-Open No. 56-77039 (the following Patent Document 1) discloses an unannealed 0.4 to 0.4 with a yield point of 70 to 100 kg / mm ² by cold rolling. Proposing a drum can manufacturing method that uses 0.9mm thick cold-rolled steel sheet as the material for the can body plate, heat-treats only the processed part used to connect the can body part to the top plate, and the base plate, and softens it to ensure formability. Has been. However, in this technique, the can body is annealed during the incineration process at 800 ° C., and the recycling is remarkably controlled. Further, distortion occurs due to unannealing, and in addition to the generation of the surface oxide film by the heat treatment, Since only the part is heat-treated, the process becomes complicated and there is a problem that it is not suitable for mass production, and has not yet been put into practical use.

  As countermeasures, techniques described in JP-A-11-080886 (the following Patent Document 2), JP-A-11-080888 (the following Patent Document 3), and JP-A-11-302782 (the following Patent Document 4) are disclosed. However, none of them has achieved the object of the present invention.

  In other words, Patent Document 2 and Patent Document 3 disclose that the combination of N addition (0.0050 to 0.0200%) is preferable because the reduction in ductility becomes large when only solid solution C is strengthened. Yes. However, in this case, since N is high, surface cracking or the like is likely to occur during continuous casting, resulting in an increase in cost due to a decrease in yield, and low temperature toughness characteristics when used in a cold region. .

Patent Document 4 discloses that it is indispensable for ensuring the quality at the time of forming the welded portion by welding by adding Nb, but in order to obtain a recrystallized grain structure when Nb is added. However, it is necessary to raise the annealing temperature excessively, and there is a problem that C and N are excessively melted to deteriorate the ductility and increase the cost as well as the manufacturability.
JP 56-77039 A Japanese Patent Laid-Open No. 11-080886 Japanese Patent Laid-Open No. 11-080889 Japanese Patent Laid-Open No. 11-302782

  The present invention solves the problems of the prior art as described above, has a particularly appropriate bake hardening property, excellent casting yield, low cost, low temperature toughness, and sufficient strength even in reprocessing. An object of the present invention is to provide a cold-rolled steel sheet for drums that is difficult to deform and a method for producing the same.

As a result of various studies on the steel plate composition and manufacturing method in order to solve the above-mentioned problems, the inventors have controlled the appropriate amount of C and N, and the heating temperature and finishing temperature under the conditions during hot rolling, the winding temperature The present invention was accomplished by finding an excellent cold-rolled steel sheet for drums and a method for producing the same that can solve the above problems by optimizing the cutting and optimal combination of the ultimate temperature of the continuous annealing process and the overaging conditions of the cooling rate. The gist thereof is as follows, as described in the claims.
(1) By mass%, C: 0.0015 to 0.060%, Si: 0.0015 to 0.060%, Mn: 0.15 to 0.60%, P: 0.0015 to 0.060% , S: 0.0015 to 0.060%, Al: 0.015 to 0.060%, N: 0.0015% or more to less than 0.0050%, with the balance being Fe and inevitable impurities and the C, of N, the sum of solute N and C measured by internal friction method, Ri .0005 to .0020% der, obtained from the further deposition analysis by dissolution with bromine ester A cold-rolled steel sheet for drums , wherein the solid solution N is 0.0001 to 0.0002% .
(2) By mass%, C: 0.0015 to 0.060%, Si: 0.0015 to 0.060%, Mn: 0.15 to 0.60%, P: 0.0015 to 0.060% , S: 0.0015 to 0.060%, Al: 0.015 to 0.060%, N: 0.0015% to less than 0.0050%, with the balance being Fe and inevitable impurities A steel material is heated to a temperature of 1000 to 1200 ° C., hot-rolled at a temperature of 820 to 920 ° C., pickled at a temperature of 600 to 700 ° C., pickled and descaled, and a reduction rate of 40 to 85%. Cold-rolled at a temperature of 660 to 720 ° C. for 30 to 300 seconds, then cooled to 300 to 450 ° C. at a cooling rate of 5 ° C./second or more, and in a temperature range of 300 to 450 ° C. Perform overaging treatment for 10 to 300 seconds, and perform temper rolling at a rolling reduction of 1 to 5%. The sum of solute N and C measured by internal friction method is 0.0005 to 0.0020%, solute N is further obtained from the precipitation analysis by dissolution with bromine ester 0.0001 to 0. A method for producing a cold-rolled steel sheet for drums, comprising producing a steel sheet of 0002% .

  According to the present invention, while controlling an appropriate amount of C and N, the heating temperature and finishing temperature in the conditions during hot rolling, optimization of winding, and the overaging of the ultimate temperature and cooling rate in the continuous annealing process It is possible to provide an excellent cold-rolled steel sheet for drums that can solve the above problems by an optimal combination of conditions, and a method for producing the same, as well as being able to achieve thinning of the steel sheet and contributing to a reduction in can manufacturing costs. Useful and significant effect.

  The present invention is configured based on the above findings. That is, the present invention for achieving this object is the mass% of the composition of the steel plate, C: 0.0015 to 0.060%, Si: 0.0015 to 0.060%, Mn: 0.15 to 0. .60%, P: 0.0015 to 0.060%, S: 0.0015 to 0.060%, Al: 0.015 to 0.060%, N: 0.0015% to less than 0.0050% The balance is made of Fe and unavoidable impurities, and the total amount of solute N and C out of C and N is 0.0005 to 0.000020%. A high-strength cold-rolled steel sheet and a method for producing the same.

First, the reasons for limiting the chemical composition of the steel sheet of the present invention will be described. In the following description, the content of each component indicates mass%.
"C: 0.0015 to 0.060%"
C is a harmful element that lowers ductility and deteriorates workability, but if its amount is limited, it becomes an extremely effective element for drum regeneration, and is the most important chemical component for the present invention. In particular, if the upper limit exceeds 0.060%, harmful aspects become conspicuous, so 0.060% or less, preferably 0.040% or less. However, in order to obtain effective BH reinforcement, it is desirable to make it contain 0.0015% or more, and it shall increase according to the required BH effect. Further, the amount of solute C in the steel is desirably in the range of 5 ppm or more and less than 10 ppm. This solid solution C amount is analyzed by the internal friction method. If this value is less than 5 ppm, a sufficient BH effect cannot be expected. On the other hand, if it exceeds 10 ppm, the BH effect appears even at room temperature storage, and a perfect circle required for can strength cannot be obtained during bending of the drum can. Therefore, it is necessary to ensure this solute C range in a steel sheet that has undergone temper rolling.
"Si: 0.0015 to 0.060%"
Si is useful as a strengthening element, but if it is contained in a large amount, cold rolling property, surface treatment property, and corrosion resistance deteriorate. For this reason, the Si content is preferably 0.0015 to 0.060%.
“Mn: 0.15 to 0.60%”
Mn has the effect of refining crystal grains, and the addition of Mn is preferably 0.15% or more in terms of material. However, if added in a large amount, the corrosion resistance tends to deteriorate, and the steel sheet is hardened and the cold rolling property is deteriorated, so Mn: 0.15 to 0.60 is a preferable range.
"P: 0.0015-0.060%"
P makes the steel remarkably hard, deteriorates flange workability and neck workability at the time of manufacturing the drum can, and remarkably deteriorates corrosion resistance. Moreover, P has a strong tendency to segregate in steel and causes embrittlement of the weld. For this reason, the P content is preferably 0.0015 to 0.060%.
"S: 0.0015-0.060%"
Since S exists mainly as an inclusion in steel, it is preferable to reduce it as much as possible in order to reduce the elongation of the steel sheet and further reduce the corrosion resistance. Since it becomes an obstruction factor, it is made into 0.060% or less.

On the other hand, considering the cost of reducing S, it is made 0.0015% or more, and therefore S: 0.0015 to 0.060%.
“Al: 0.015 to 0.060%”
Al is a useful element that is added as a deoxidizing element and improves the cleanliness of the steel, and also has an effect of refining the structure, and is positively added. However, if the Al content is large, the surface properties of the steel sheet deteriorate and the amount of solute N is significantly reduced. For this reason, the Al content is preferably 0.060% or less. Moreover, since it has the pinning effect which suppresses a crystal grain growth by precipitation of AlN, the range of 0.015 to 0.060 %% is preferable.
“N: 0.0015% or more and less than 0.0050%”
N is an element that increases the BH effect as solute N, but the BH effect is more likely to appear at room temperature storage than C, and it is difficult to obtain a perfect circle when the drum can is bent. Therefore, it is desirable to use as little as possible. However, since steel is an element that is inevitably mixed in the atmosphere, N is fixed as AlN by adding Al. Here, if the N content exceeds 0.0050%, stable N fixation with Al becomes difficult, so the N content is 0.0050% or less, preferably 0.0025% or less. In the present invention, the aim is to obtain the BH effect only by C regardless of N. However, if the amount of N is less than 5 ppm, an auxiliary strengthening action on the BH effect can be expected, so the lower limit is made 0.0015%. .
“The total amount of solute N and C in the C and N contents is 0.0005 to 0.000020%”
In order to stably increase the strength of the can after making the can, the total content of the solid solution N and C in the C and N content is set to 0.0005 to 0.0020%. preferable. The adjustment of the solid solution N amount can be performed by a combination of the total N amount and C amount of the steel material and hot rolling (cold rolling) annealing conditions.

  The solute N and solute C amounts referred to in the present invention are the amounts of N and C obtained by subtracting the precipitation amount obtained by precipitation analysis by bromine ester from the total N amount and C amount in steel. Say total.

  The balance of the steel material components other than the above consists of Fe and inevitable impurities, and the following components may be added.

  Further, Cu: 0.2% or less, Ni: 0.2% or less, Cr: 0.2% or less, Mo: 0.2% or less, Nb: 0.02% or less, Ti: 0.02% or less, B: It is preferable to limit to the range of 0.0010% or less. By containing these elements, the strength of the steel sheet is increased, but the weldability, the workability of the welded portion, and the chemical conversion property are remarkably deteriorated, so that the application to the drum can becomes extremely difficult, and is limited to the above range.

  Next, the reasons for limiting the manufacturing conditions of the steel sheet will be described.

  The molten steel having the above composition is melted by a generally known melting method such as a converter or an electric furnace, and solidified into a slab by a known method such as a continuous casting method, an ingot-making method, or a thin slab casting method to obtain a steel material. preferable. Among these known casting methods, the continuous casting method is preferable in order to prevent macro segregation.

Also, the heating temperature at the time of hot rolling is in the range of 1000-1200 ° C, the finishing temperature is controlled at 900-920 ° C, winding is performed, and it is necessary at the time of paint baking at the customer in the annealing process at the time of material production In the heat treatment at the time of reuse at the customer, the amount of C and N is dissolved and precipitated, and the cementite produced at the time of paint baking is properly dissolved at the time of cooling after annealing in the production of the material. High tenacity can be achieved.
"Heating in the range of 1000-1200 ° C"
The steel material is heated and hot rolled. The slab heating temperature is preferably set to a range of 1200 ° C. or lower in order to prevent the precipitated AlN from re-dissolving and to suppress the amount of dissolved N in the stage before hot rolling. Moreover, if it is less than 1000 degreeC, a deformation resistance becomes high and a rolling load will increase and hot rolling will become difficult.
"Hot rolling in the range of 820-920 ° C"
A uniform structure is obtained by hot-rolling in the temperature range above the A3 transformation point, the material of the final product is homogeneous, and solid solution N can be secured stably at the hot-rolled plate stage. The hot rolling temperature is set to 820 ° C. or higher in order to stabilize the mechanical characteristics. On the other hand, when the hot rolling temperature exceeds 920 ° C., the rough surface of the hot-rolled work roll progresses and the surface quality is remarkably deteriorated.
"Cut in the range of 600-700 ° C"
Scattering at 600 ° C. or higher and scraping above 700 ° C. in order to obtain a scraping temperature range in which N dissolved in AlN dissolution in the heating stage reprecipitates as AlN results in large material variations.

  N in the hot-rolled steel sheet is precipitated as AlN by the combination of the above slab heating and hot rolling temperature, and the solid solution N becomes 10 ppm or less.

The hot-rolled sheet is pickled and then cold-rolled to form a cold-rolled sheet. The pickling conditions for the hot-rolled sheet need not be specified in particular, and it is sufficient if the surface scale can be removed, and the surface scale is usually removed by a known method, for example, an acid such as hydrochloric acid or sulfuric acid. Cold rolling is performed to make the hot-rolled sheet into a cold-rolled sheet having a predetermined thickness.
"Cold rolling in the range of 40-85%"
In order to refine the uniform structure obtained by hot rolling and keep the steel plate shape flat during annealing and keep the final product shape good, the rolling reduction of cold rolling is in the range of 40 to 85%. Is preferred.
“Recrystallization treatment at an annealing temperature of 660 to 720 ° C. for 30 to 300 seconds”
The cold-rolled sheet is annealed for 30 to 300 seconds in a temperature range of 660 to 720 ° C. above the recrystallization temperature. Here, the recrystallization temperature means the recrystallization end temperature. When annealing is performed below the recrystallization end temperature, the structure becomes an unrecrystallized structure. The non-recrystallized structure has high strength but low ductility, and shows a tendency to rapidly soften when exposed to high temperatures, so that it is not suitable for applications exposed to high temperatures, for example, drum cans for welding assembly. It becomes inappropriate. Furthermore, the material variation increases in the width direction and the longitudinal direction of the steel plate.

  In addition, it is preferable to hold | maintain for 30 to 300 second in the range of 660-720 degreeC in order to ensure solid solution N amount.

Annealing is performed by continuous annealing with an overaging furnace without using BAF. The annealing cycle is a temperature range and time range in which carbides dissolve and solid solution C increases and AlN precipitates and solid solution N decreases, and steel sheets that have solid solution N ≦ 10 ppm at the hot rolling stage are recrystallized. Sometimes further precipitation of AlN proceeds, and the amount of dissolved N becomes 1 to 2 ppm.
“Cooling rate of 5 ℃ / second or more”
By cooling from the recrystallization temperature to the overaging temperature range at 5 ° C./second or more, precipitation of carbides in the crystal grains is induced.
“Overaging treatment for 10 to 300 seconds at an overaging temperature of 300 to 450 ° C.”
In order to obtain a temperature and time range within which excessive solid solution C can be precipitated at the carbide precipitation sites in the grains and at the grain boundaries, the overaging treatment is performed by maintaining the temperature in the range of 300 to 450 ° C. for 10 to 300 seconds. The over-aging treatment takes a long time for solid solution C precipitation at low temperatures, so the lower limit is set to 300 ° C. On the other hand, the upper limit of the high temperature range where the amount of C dissolved in equilibrium increases is 450 ° C. The amount of C dissolved in equilibrium in this temperature range is 10 ppm or less. The longer the holding time, the more solid solution C precipitates, but the effect gradually weakens in 10 to 300 seconds, and holding for longer than the upper limit time hinders productivity.

  By hot rolling and continuous annealing + overaging treatment, the solid solution N becomes 1 to 2 ppm, and the solid solution C becomes less than 10 ppm. In the measurement by the internal friction method, the total amount of solid solution C + N is 5 to 20 ppm.

  The annealed cold-rolled steel sheet is further subjected to temper rolling. The temper rolling is performed to eliminate or reduce the yield point elongation, and to adjust the surface roughness of the steel sheet and improve the shape of the original sheet. The rolling reduction of temper rolling is preferably 8% or less. If the rolling reduction exceeds 8%, the ductility of the steel sheet deteriorates, and the rolling reaction force becomes too large, which may exceed the allowable load of the rolling mill. In order to adjust the surface roughness, it is preferably 1% or more and 5% or less.

  The temper-rolled steel sheet may be subjected to a surface treatment such as galvanizing, chrome plating, tin plating, or tin-zinc alloy plating, if necessary. Moreover, in order to give rust prevention and lubricity with or without surface treatment, chromate treatment or lubrication coating may be performed. A film may be laminated.

The drum can is composed of a trunk, a top plate, and a main plate. Using the cold-rolled steel sheet of the present invention as a raw material, the top plate and the ground plate are pressed, a cylinder is formed by bending, and both ends are joined by seam welding or butt welding to form a can body, and both ends of the can body A base plate (and top plate) is attached to the drum by tightening to form a drum. There are open type that only tightens the main plate and close type that also tightens the top plate. After forming into a drum, chemical conversion treatment and painting-baking process are performed. In the drum can using the cold-rolled steel sheet of the present invention, the strength is greatly increased in the baking process after coating, and a high strength of the can that is not found in the prior art is exhibited. By applying the cold-rolled steel sheet of the present invention to at least one of the drum plate body plate, top plate, and ground plate, an effect of increasing the strength of the can body can be obtained. In addition, since the strength is not easily reduced even when the drum can is heated for recycling, it can withstand 15 times of recycling. In the past, only 4 to 5 recycles were possible. Even if only solid solution N is used as disclosed in Patent Document 2, since the solid solution N is precipitated as AlN by heating during recycling, the strength is relatively reduced. On the other hand, in the present application, Fe ₃ C precipitated by the overaging treatment at the time of continuous annealing is dissolved at around 700 ° C. to increase the solid solution C, so that the strength is hardly lowered even if the recycling is performed many times. However, since the crystal grains suddenly increase and the strength decreases when recycled for 15 times or more, the upper limit of recycling is set to 15 times. This is thought to be because the pinning effect is lost due to dissolution of the precipitate. The cold-rolled steel sheet of the present invention can achieve strength improvement by drying the paint at the time of manufacturing the drum can mainly by the BH effect due to solute N and ensure the strength by recycling mainly due to the BH effect due to solute C. it can.

  An example of the material of the steel plate for the drum can is a plate thickness of 1.0 to 1.2 mm, yield point (hereinafter referred to as YP) = 225 MPa, and tensile strength (hereinafter referred to as TS) = 343 MPa. The material for the exploration test was a low-carbon aluminum killed steel slab used for drum materials. The steel components are as shown in Table 1. This was heated with a target of 1235 ° C., hot-rolled with a target of 900 ° C., and scraped off with a target of 670 ° C. Further, YP, TS of cold rolled steel sheet that has been descaled, cold rolled, subjected to recrystallization annealing by continuous annealing and overaging (OA) treatment at 400 ° C. for 120 seconds, and subjected to temper rolling aimed at 1% Measurement and solid solution (C + N) amount measurement by the internal friction method were performed. After pressure regulation, YP is 376 MPa, TS is 396 MPa, and the amount of solid solution (C + N) is 9 ppm%. This steel plate is charged into an electric furnace, heated to 700 ° C., held at that temperature for 60 seconds, then taken out of the electric furnace and subjected to a rapid cooling process by air cooling, and measured by YP and TS at room temperature and by a solid friction method. The amount of dissolved (C + N) was investigated. The YP and TS values are steel plate strengths without shot blasting. Table 2 and FIG. 1 show the results of repeating this heat incineration treatment and material measurement up to 25 times. Table 3 shows the C and N states in the cold rolled steel sheet manufacturing process, and Table 4 shows the C and N states in the drum can manufacturing process and recycling.

This result proved the following.
(1) The YP and TS values of the temper rolled steel sheet and the steel sheet that has been incinerated 1 to 15 times are equal.
(2) The solid solution (C + N) amount of the steel plate incinerated 15 times is 25 ppm%, which is higher than the raw steel plate 9 ppm, and the BH effect by shot blasting is strengthened.

  Further, steel having chemical components shown in Table 5 was melted in an actual converter, continuously cast, and then subjected to hot rolling and cold rolling shown in Table 2 to a plate thickness of 1.22 mm. Continuous annealing of the material of the present invention was performed by recrystallization annealing in a furnace capable of overaging, and then temper rolling was performed at 2% to a finished sheet thickness of 1.2 mm. The comparative material was subjected to recrystallization annealing with an overaging furnace plate temperature of 300 ° C. or lower so that no overaging treatment occurred. The rolling reduction of temper rolling was 2% for both the inventive material and the comparative material. From the obtained cold-rolled steel sheet, a test piece for examining the solid solution C, N amount and the tensile strength was cut out, and the YP and TS values, which are indicators of the solid solution C, N amount, and the can body strength, were examined. Next, the processing performance when these cold-rolled steel sheets were actually formed into drums was investigated. These results are shown in Table 7.

  A drum can is made by seaming or butt-welding both ends of a body plate bent into a cylindrical shape, and then tightening the top plate and the main plate. After it becomes a drum can body, it is chemically treated and painted and baked. Unlike the conventional BAF annealed material, the continuous annealed material of the present invention has solid solution C and a small amount of solid solution N. BH strengthening due to strain aging occurs by baking, and a can body with increased strength before coating is obtained. It is done.

It can be seen from Table 7 that Examples 1 to 6 of the present invention have good can body forming performance. On the other hand, in Comparative Examples 7, 8, and 12, the amounts of dissolved C and N exceeded the upper limit of the range of the present invention, and the bending workability was poor. In Comparative Examples 9 and 11, the number of reproduction uses is as small as four. In Comparative Example 9, the amount of Al is outside the lower limit of the present invention range, and in Comparative Example 11, the amount of N is outside the lower limit of the present invention range. In any condition, the precipitation amount of AlN is insufficient and the pinning effect of suppressing crystal grain growth is weak, and it is assumed that softening of grain growth was promoted by annealing at 800 ° C. during regeneration. In Comparative Example 10, the number of times of recycling is as small as 3, which is presumably due to the fact that the Al amount is outside the upper limit of the present invention, and the AlN precipitate is coarsened and loses the pinning effect.

It is a figure which shows the result of having repeated the heat incineration process and the material measurement to the cold-rolled steel plate for drums of this invention up to 25 times.

Claims (2)

% By mass
C: 0.0015 to 0.060%,
Si: 0.0015 to 0.060%,
Mn: 0.15 to 0.60%,
P: 0.0015 to 0.060%,
S: 0.0015 to 0.060%,
Al: 0.015 to 0.060%,
N: 0.0015% or more to less than 0.0050%, the balance being Fe and unavoidable impurities, and the total of solid solution N and C measured by the internal friction method among C and N in, cold rolled for drums, wherein Ri 0.0005 to 0.0020% der, solid solution N further obtained from precipitation analysis by dissolution with bromine ester is 0.0002% 0.0001 steel sheet. % By mass
C: 0.0015 to 0.060%,
Si: 0.0015 to 0.060%,
Mn: 0.15 to 0.60%,
P: 0.0015 to 0.060%,
S: 0.0015 to 0.060%,
Al: 0.015 to 0.060%,
N: A steel material containing 0.0015% or more and less than 0.0050%, with the balance being Fe and inevitable impurities, is heated to a temperature of 1000 to 1200 ° C., and hot at a temperature of 820 to 920 ° C. Rolled, pickled at a temperature of 600 to 700 ° C., pickled and descaled, cold rolled at a rolling reduction of 40 to 85%, and recrystallized at a temperature of 660 to 720 ° C. for 30 to 300 seconds. After that, it is cooled to 300 to 450 ° C. at a cooling rate of 5 ° C./second or more, subjected to an overaging treatment held at a temperature range of 300 to 450 ° C. for 10 to 300 seconds, and temper rolled at a reduction rate of 1 to 5%. The total of solid solution N and C measured by the internal friction method is 0.0005 to 0.000020% , and the solid solution N obtained from precipitation analysis by dissolution with bromine ester is 0.0001. production of steel plate is ～0.0002% Method of manufacturing a drum for a cold rolled steel sheet according to claim Rukoto.

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