JP5251402B2 - Interior decorative material - Google Patents

Interior decorative material Download PDF

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JP5251402B2
JP5251402B2 JP2008251381A JP2008251381A JP5251402B2 JP 5251402 B2 JP5251402 B2 JP 5251402B2 JP 2008251381 A JP2008251381 A JP 2008251381A JP 2008251381 A JP2008251381 A JP 2008251381A JP 5251402 B2 JP5251402 B2 JP 5251402B2
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density
decorative material
interior decorative
density wood
fiberboard
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JP2010006042A (en
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浩久 吉川
康夫 中井
功 吉村
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Dai Nippon Printing Co Ltd
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Description

本発明は内装化粧材に関する。   The present invention relates to an interior decorative material.

従来、住宅や商業施設、病院、介護施設等の壁面には、石膏ボード等の不燃性を有するボードの上に、壁紙、ポリエステル化粧板、木粉配合塩ビ、あるいは合板、パーティクルボード、中密度繊維板(MDF)等の木質系基材に化粧シートを貼着した化粧材を施工したものが用いられている。近年、消費者の要求がより厳しくなり、かつ多様化している中、施工性、耐擦傷性等の従来要求されていた特性に加えて、耐衝撃性が求められている。例えば自宅介護をする住宅、病院や介護施設では、車椅子、患者搬送のためのストレッチャーや、食事配膳用のキャリアー等が用いられるが、これらが壁面に衝突することによる壁面表面の化粧材及びその下層にある石膏ボード等の下地材の破損が問題となっていた。施工性、耐擦傷性等に優れた化粧材はこれまで多く開発されてきているが(例えば、特許文献1参照)、耐衝撃性にも優れた壁面等の内装に用いられる化粧材は開発が十分になされていないのが現状であり、耐衝撃性に優れた内装化粧材の開発が望まれている。   Conventionally, on walls of houses, commercial facilities, hospitals, nursing homes, etc., on non-flammable boards such as plasterboard, wallpaper, polyester decorative board, wood powder blended PVC, or plywood, particle board, medium density fiber What applied the decorative material which stuck the decorative sheet on the woody base materials, such as a board (MDF), is used. In recent years, as consumer demands have become more severe and diversified, in addition to conventionally required characteristics such as workability and scratch resistance, impact resistance has been demanded. For example, wheelchairs, stretchers for transporting patients, carriers for meals, etc. are used in homes, hospitals, and nursing homes where home care is provided. Damage to the base material such as gypsum board in the lower layer was a problem. Many cosmetic materials excellent in workability, scratch resistance, etc. have been developed so far (see, for example, Patent Document 1), but cosmetic materials used for interiors such as wall surfaces with excellent impact resistance have been developed. The current situation is not enough, and the development of interior decoration materials with excellent impact resistance is desired.

ところで、上記したような用途における需要が増加するに伴い、その使用条件が多様化することで、これまで以上に厳しい環境化での使用が見込まれている。特に高温多湿の環境下においては、内装化粧材の反りが生じやすく、この反りによる下地材と内装化粧材との剥離、剥離による見栄えの悪さが問題となることがある。   By the way, with the increase in the demand in the above-mentioned uses, the use conditions are diversified, so that it is expected to be used in a severer environment than before. In particular, in an environment of high temperature and humidity, warping of the interior decorative material is likely to occur, and peeling of the base material and the interior decorative material due to the warpage may cause a problem of poor appearance due to the peeling.

特開2001−260109号公報JP 2001-260109 A

本発明は、このような状況の下で、耐衝撃性に優れ、かつ高温多湿の状況下でも反りの発生が抑えられる内装化粧材を提供することを目的とする。   An object of the present invention is to provide an interior decorative material that is excellent in impact resistance under such circumstances and can suppress the occurrence of warpage even under high-temperature and high-humidity conditions.

本発明者らは、前記目的を達成するために鋭意研究を重ねた結果、密度の異なる木質繊維板を積層することで、耐衝撃性に優れ、かつ高温多湿の状況下でも反りの発生が抑えられる内装化粧材を得ることができた。   As a result of intensive research to achieve the above object, the present inventors have laminated wood fiberboards having different densities, which are excellent in impact resistance and suppress the occurrence of warpage even under high temperature and high humidity conditions. Interior decoration material that can be obtained.

すなわち、本発明は、
(1)密度が0.40g/cm2未満の範囲である低密度木質系繊維板の上に、密度が0.70g/cm2以上の範囲である高密度木質系繊維板を積層してなる内装化粧材、
(2)前記低密度木質系繊維板の前記高密度木質系繊維板を設けた裏面に、さらに高密度木質系繊維板を積層してなる前記(1)に記載の内装化粧材、
(3)前記高密度木質系繊維板に、化粧シートを積層してなる前記(1)又は(2)に記載の内装化粧材、
(4)前記高密度木質系繊維板が、MDF(中密度繊維板)である前記(1)又は(3)に記載の内装化粧材、
(5)前記高密度木質系繊維板の少なくとも一方が、MDF(中密度繊維板)である前記(2)又は(3)に記載の内装化粧材、
(6)前記低密度木質系繊維板が、インシュレーションボードである前記(1)〜(5)のいずれかに記載の内装化粧材、及び
(7)腰壁に用いられる前記(1)〜(6)のいずれかに記載の内装化粧材、
を提供するものである。
That is, the present invention
(1) On a low density wood fiberboard having a density of less than 0.40 g / cm 2 , a high density wood fiberboard having a density of 0.70 g / cm 2 or more is laminated. Interior cosmetics,
(2) The interior decorative material according to (1), wherein a high-density wood fiberboard is further laminated on the back surface of the low-density wood fiberboard provided with the high-density wood fiberboard.
(3) The interior decorative material according to (1) or (2), wherein a decorative sheet is laminated on the high-density wooden fiberboard,
(4) The interior decorative material according to (1) or (3), wherein the high-density wood fiberboard is MDF (medium density fiberboard),
(5) The interior decorative material according to (2) or (3), wherein at least one of the high-density wood fiberboard is MDF (medium density fiberboard).
(6) The interior decorative material according to any one of (1) to (5), wherein the low-density wood fiberboard is an insulation board, and (7) the (1) to ( 6) the interior decorative material according to any one of
Is to provide.

本発明によれば、耐衝撃性に優れ、かつ高温多湿の状況下でも反りの発生が抑えられ、特に腰壁に好適に用いられる内装化粧材を提供することができる。   ADVANTAGE OF THE INVENTION According to this invention, it is excellent in impact resistance, generation | occurrence | production of curvature is suppressed also in the condition of high temperature and humidity, and it can provide the interior decoration material used suitably especially for a waist wall.

本発明の内装化粧材の典型的な構造の一例を、図1及び図2を用いて説明する。図1は本発明の内装化粧材1の好ましい一例の断面を示す模式図である。図1に示す例では、本発明の内装化粧材1は、低密度木質系繊維板4と高密度木質系繊維板2と化粧シート5とが接着剤層を介して順次積層されたものである。また、本発明の内装化粧材1の好ましい一例の断面を示す模式図である図2に示される例では、本発明の内装化粧材1は、高密度木質系繊維板21と低密度木質系繊維板4と高密度木質系繊維板22と化粧シート5とが接着剤層を介して順次積層されたものである。また、図3は本発明の内装化粧材1の使用例の断面を示す模式図であり、本発明の内装化粧材1は、下地材6となる石膏ボード等に貼着して用いられる。   An example of a typical structure of the interior decorative material of the present invention will be described with reference to FIGS. FIG. 1 is a schematic view showing a cross section of a preferred example of the interior decorative material 1 of the present invention. In the example shown in FIG. 1, the interior decorative material 1 of the present invention is one in which a low-density wood fiberboard 4, a high-density wood fiberboard 2, and a decorative sheet 5 are sequentially laminated via an adhesive layer. . Moreover, in the example shown by FIG. 2 which is a schematic diagram which shows the cross section of a preferable example of the interior decorative material 1 of the present invention, the interior decorative material 1 of the present invention includes a high-density wood fiber board 21 and a low-density wood fiber. The board 4, the high density wood fiber board 22, and the decorative sheet 5 are sequentially laminated through an adhesive layer. FIG. 3 is a schematic view showing a cross section of an example of use of the interior decorative material 1 of the present invention. The interior decorative material 1 of the present invention is used by being attached to a gypsum board or the like serving as a base material 6.

[高密度木質系繊維板]
本発明にかかる高密度木質系繊維板は、JIS A5905−2003に規定される繊維板のうち、密度0.70g/m2以上の木質系繊維板のことをいう。前記JISで規定される木質系繊維板は、主に木材等の植物繊維を成型したボードであり、一般に表面の硬度が高く、適切な密度のものを選択すれば、物体が衝突した際の凹みに対して強い、有用な材料である。また、材料のコストも、プラスチックと比較して安価に入手可能である。
このような高密度木質系繊維板としては、MDF(中密度繊維板)、ハードボードなどが好ましく挙げられる。これらの高密度木質系繊維板は、比較的安価で表面性が良好であり、化粧シートを平滑にラミネートすることができ、定寸に切断して施工を行う際の切削性も良好であることから、好ましい。複数の高密度木質系繊維板を用いる場合には、これらの高密度木質系繊維板は同じであっても、異なっていてもよいが、反りを低減させる観点から同じであることが好ましい。
[High-density wood fiberboard]
The high-density wood fiberboard according to the present invention refers to a wood fiberboard having a density of 0.70 g / m 2 or more among fiberboards defined in JIS A5905-2003. The wood fiberboard specified by the above JIS is a board formed mainly from wood and other plant fibers. Generally, the surface hardness is high, and if an appropriate density is selected, a dent when an object collides with it is selected. It is a strong and useful material. In addition, the cost of the material can be obtained at a lower cost than plastic.
Preferred examples of such a high density wood fiberboard include MDF (medium density fiberboard) and hard board. These high-density wood fiberboards are relatively inexpensive, have good surface properties, can be laminated smoothly on decorative sheets, and have good machinability when cut into fixed sizes for construction. Therefore, it is preferable. When using a plurality of high density wood fiberboards, these high density wood fiberboards may be the same or different, but are preferably the same from the viewpoint of reducing warpage.

高密度木質系繊維板の厚さは、特に制限はないが、木質系繊維板の製造上の制限、及び重量の観点から、1〜5mmが好ましく、1.5〜5mmがより好ましく、1.5〜3mmがさらに好ましい。内装化粧材として、高密度木質系繊維板のみを用いた場合、十分な耐衝撃性を得るには10mm以上の厚みを要するため、重量物となり、材料のコストも高価となってしまう。しかし、高密度木質系繊維板に、低密度木質系繊維板を組み合わせることにより、高密度木質系繊維板が上記の厚みであっても、十分な耐衝撃性を確保することができ、材料のコストも抑えることが可能となる。本発明の内装化粧材に2枚の高密度木質系繊維板を用いる場合、2枚の高密度木質系繊維板の厚さは同じでも異なっていてもよいが、反りを低減させる観点から同じであることが好ましい。   The thickness of the high-density wood fiberboard is not particularly limited, but is preferably 1 to 5 mm, more preferably 1.5 to 5 mm, from the viewpoint of manufacturing restrictions and weight of the wood fiberboard. 5 to 3 mm is more preferable. When only a high-density wood fiberboard is used as the interior decorative material, a thickness of 10 mm or more is required to obtain sufficient impact resistance, which results in a heavy article and an expensive material. However, by combining a low-density wood fiberboard with a high-density wood fiberboard, even if the high-density wood fiberboard has the above-mentioned thickness, sufficient impact resistance can be ensured. Costs can be reduced. When two high-density wood fiberboards are used for the interior decorative material of the present invention, the thicknesses of the two high-density wood fiberboards may be the same or different, but are the same from the viewpoint of reducing warpage. Preferably there is.

[低密度木質系繊維板]
本発明にかかる低密度木質系繊維板は、JIS A5905−2003に規定される繊維板のうち、密度0.40g/m2未満の木質系繊維板のことをいう。このような低密度木質系繊維板としては、インシュレーションボード、タタミボード、シージングボードなどが挙げられ、反りを低減させる観点からインシュレーションボードが好ましい。
低密度木質系繊維板の厚さは、特に制限はないが、木質系繊維板の製造上の制限、及び重量の観点から、1〜5mmが好ましく、2〜5mmがより好ましく、3〜5mmがさらに好ましい。
[Low density wood fiberboard]
The low-density wood fiberboard according to the present invention refers to a wood fiberboard having a density of less than 0.40 g / m 2 among fiberboards defined in JIS A5905-2003. Examples of such a low-density wood fiberboard include an insulation board, a tatami board, and a sizing board, and the insulation board is preferable from the viewpoint of reducing warpage.
The thickness of the low-density wood fiberboard is not particularly limited, but is preferably 1 to 5 mm, more preferably 2 to 5 mm, and more preferably 3 to 5 mm from the viewpoints of production restrictions and weight of the wood fiberboard. Further preferred.

[接着剤層]
本発明の内装化粧材において、高密度木質系繊維板と低密度木質系繊維板との間、及び高密度木質系繊維板と化粧シートとの間には、各々接着剤層が設けられる。
接着剤層に用いられる接着剤としては、(メタ)アクリル系樹脂、ポリウレタン系樹脂、エポキシ系樹脂、ポリエステル系樹脂、ポリアミド系樹脂、(メタ)アクリル酸エステル−オレフィン系共重合体樹脂、塩化ビニル−酢酸ビニル系共重合体樹脂、エチレン−酢酸ビニル系共重合体樹脂、アイオノマー系樹脂、オレフィン−αオレフィン系共重合体樹脂等の易接着樹脂単体等が挙げられ、これらを単独で又は複数を組み合わせて用いることができる。なかでも、初期及び長期の密着性が良好であることから、ポリウレタン系樹脂が好ましい。ここで、「(メタ)アクリレート」とは、「アクリレート又はメタクリレート」を意味する。
[Adhesive layer]
In the interior decorative material of the present invention, an adhesive layer is provided between the high-density wood fiberboard and the low-density wood fiberboard, and between the high-density wood fiberboard and the decorative sheet.
Adhesives used in the adhesive layer include (meth) acrylic resins, polyurethane resins, epoxy resins, polyester resins, polyamide resins, (meth) acrylic ester-olefin copolymer resins, vinyl chloride. -Easy adhesive resins such as vinyl acetate copolymer resins, ethylene-vinyl acetate copolymer resins, ionomer resins, olefin-α olefin copolymer resins, etc. They can be used in combination. Of these, polyurethane resins are preferred because of good initial and long-term adhesion. Here, “(meth) acrylate” means “acrylate or methacrylate”.

接着剤層の厚みは要求物性等に応じて適当な厚さとすればよいが、通常1〜100μm程度である。また、接着剤層の形成方法は特に限定は無いが、通常は、上記樹脂を希釈溶剤で希釈した樹脂液からなるインキ又は塗液として、グラビア印刷、ロールコート等の公知の印刷又は塗工手段により形成する。また、接着剤層中には、更に、インキ(又は塗工液)の印刷(又は塗工)適性等の諸物性を調整、向上させる目的で、必要に応じて、その他の副材料、例えば、体質顔料等の各種添加剤を添加してもよい。   The thickness of the adhesive layer may be an appropriate thickness depending on the required physical properties and the like, but is usually about 1 to 100 μm. The method for forming the adhesive layer is not particularly limited, but usually, known printing or coating means such as gravure printing, roll coating, etc. as an ink or coating liquid comprising a resin liquid obtained by diluting the above resin with a diluent solvent. To form. Further, in the adhesive layer, for the purpose of adjusting and improving various physical properties such as printing (or coating) suitability of the ink (or coating liquid), other auxiliary materials, for example, Various additives such as extender pigments may be added.

本発明の内装化粧材において、層間接着力を向上させるために、プライマー層を施すことができる。プライマー層は、通常1〜10μmの厚みを有し、これをなす樹脂としては、(メタ)アクリル系樹脂、ポリウレタン系樹脂、ウレタン−アクリル系樹脂などを好ましく挙げることができる。   In the interior decorative material of the present invention, a primer layer can be applied in order to improve interlayer adhesion. The primer layer usually has a thickness of 1 to 10 μm, and preferred examples of the resin forming the primer layer include (meth) acrylic resins, polyurethane resins, and urethane-acrylic resins.

[化粧シート]
本発明の内装化粧材は、意匠性を付与する目的で、高密度木質系繊維板に、該高密度木質系繊維板が2枚ある場合には、その少なくとも一方に、化粧シートをさらに積層することができる。化粧シートとしては、意匠性を付与できれば特に制限なく使用することができるが、本発明の内装化粧材にさらに耐摩耗性、耐傷付性や耐汚染性等を付与するために、オーバーコート層を有する化粧シートを用いることが好ましい。このような化粧シートとしては、例えばウレタン系樹脂やアクリル系樹脂等によるコート紙や、電離放射線硬化性樹脂組成物が架橋硬化してなる表面保護層を設けた化粧シート等を好ましく挙げることができるが、なかでも電離放射線硬化性樹脂組成物が架橋硬化してなる表面保護層を有する化粧シートが特に好ましい。このような電離放射線硬化性樹脂組成物が架橋硬化してなる表面保護層を有する化粧シートとしては、例えば「WSサフマーレ」(商品名、大日本印刷株式会社製)を挙げることができる。
[Decorative sheet]
When the interior decorative material of the present invention has two high-density wood fiberboards on the high-density wood fiberboard, a decorative sheet is further laminated on at least one of them for the purpose of imparting design properties. be able to. As a decorative sheet, it can be used without any limitation as long as it can provide design properties, but in order to further impart wear resistance, scratch resistance, stain resistance, etc. to the interior decorative material of the present invention, an overcoat layer is provided. It is preferable to use a decorative sheet. As such a decorative sheet, for example, a coated sheet made of urethane resin or acrylic resin, a decorative sheet provided with a surface protective layer formed by crosslinking and curing an ionizing radiation curable resin composition, and the like can be preferably exemplified. However, a decorative sheet having a surface protective layer formed by crosslinking and curing the ionizing radiation curable resin composition is particularly preferable. As a decorative sheet having a surface protective layer formed by crosslinking and curing such an ionizing radiation curable resin composition, for example, “WS Safmare” (trade name, manufactured by Dai Nippon Printing Co., Ltd.) can be exemplified.

化粧シートは、内装化粧材の側面の美観を得て、湿度による反りを防止する目的から、化粧シートを高密度木質系繊維板及び低密度木質系繊維板からなる積層基材の側面及び裏面に巻き込んで貼着することが好ましい。例えば、内装化粧材が高密度木質系繊維板と低密度木質系繊維板と高密度木質系繊維板とが積層する3層構造の積層基材を有する場合、化粧シートは、いずれかの高密度木質系繊維板のみの側面及び裏面を巻き込んで貼着してもよいし、高密度木質系繊維板及び低密度木質系繊維板の側面及び裏面を巻き込んで貼着してもよいし、高密度木質系繊維板、低密度木質系繊維板及びもう一方の高密度木質系繊維板の側面及び裏面を巻き込んで貼着してもよい。また、本発明の内装化粧材がその裏面に防湿シートを設ける場合、化粧シートは、特に制限はないが積層基材に該防湿シートを設けたうえで、貼着すればよい。上記のように、化粧シートを積層基材の側面及び裏面に巻き込んで貼着するには、二方巻きや四方巻きなどの方法から用途に応じて適宜選択すればよい。
また、化粧シートを貼着させる積層基材の表面には、密着性を向上させる目的で、プライマー層を設けることができる。該プライマー層は、通常1〜15μmの厚みを有し、(メタ)アクリル系樹脂、ポリウレタン系樹脂、ウレタン−アクリル系樹脂などの樹脂により形成することが好ましい。
For the purpose of obtaining the beauty of the side of the interior decorative material and preventing warping due to humidity, the decorative sheet is applied to the side surface and the back surface of the laminated base material composed of the high-density wood fiberboard and the low-density wood fiberboard. It is preferable to enclose and stick. For example, when the interior decorative material has a laminated base material having a three-layer structure in which a high-density wood fiberboard, a low-density wood fiberboard, and a high-density wood fiberboard are laminated, The side and back of only the wood fiberboard may be wrapped and pasted, or the side and the back of the high density wood fiberboard and low density wood fiberboard may be wrapped and pasted, or high density The side and back surfaces of the wood fiberboard, the low-density wood fiberboard, and the other high-density wood fiberboard may be rolled in and stuck. Further, when the interior decorative material of the present invention is provided with a moisture-proof sheet on the back surface, the decorative sheet is not particularly limited, but may be attached after the moisture-proof sheet is provided on the laminated base material. As described above, the decorative sheet may be appropriately selected from methods such as two-way winding and four-way winding in order to wrap the decorative sheet around the side surface and the back surface of the laminated base material.
In addition, a primer layer can be provided on the surface of the laminated base material on which the decorative sheet is pasted for the purpose of improving adhesion. The primer layer usually has a thickness of 1 to 15 μm and is preferably formed of a resin such as a (meth) acrylic resin, a polyurethane resin, or a urethane-acrylic resin.

[防湿シート]
本発明の内装化粧材は、積層基材への水分の浸入による内装化粧材の反りを防止する目的で、高密度木質系繊維板に、該高密度木質系繊維板が2枚ある場合には、その少なくとも一方に、防湿シートを好ましく設けることができる。また、化粧シートが設けられる場合には、化粧シートとは反対の面に設けることができる。
防湿シートとしては、高密度ポリエチレン樹脂の押出コート層の両面に紙層を貼着した3層構造のものが好ましく挙げられる(以下、防湿シートAという。)。ここで、高密度ポリエチレン樹脂とは密度0.941g/m3以上のポリエチレン樹脂のことをいい、低密度ポリエチレン樹脂とは密度0.910〜0.925g/m3のポリエチレン樹脂のことをいう。防湿シートAに用いられる紙層としては、秤量20〜50g/m2の建材用プリント用紙、純白紙などにラテックスや合成樹脂を含浸したもの、あるいは、合成樹脂を混抄させて層間強度を強化した薄葉紙(いわゆる紙間強化紙)などが好ましく使用される。秤量が20〜50g/m2であれば、柔軟すぎないので、貼合せ加工時に皺が起こりにくく、紙層からの剥がれ及び湿気が浸透しにくいので不具合が生じにくくなる。また、難燃性基材2側の紙層には、レーヨン不織布などの化繊紙と一般に呼ばれる化学繊維紙を用いることにより、その層間、あるいは高密度ポリエチレンとの界面の強度を強くすることも可能である。
[Dampproof sheet]
The interior decorative material of the present invention is for the purpose of preventing warpage of the interior decorative material due to the ingress of moisture into the laminated base material, and when there are two high-density wood fiber boards in the high-density wood fiber board A moisture-proof sheet can be preferably provided on at least one of them. Moreover, when a decorative sheet is provided, it can be provided on the surface opposite to the decorative sheet.
As the moisture-proof sheet, a sheet having a three-layer structure in which a paper layer is stuck on both sides of a high-density polyethylene resin extrusion coating layer is preferably mentioned (hereinafter referred to as moisture-proof sheet A). Here, the high density polyethylene resin means a polyethylene resin having a density of 0.941 g / m 3 or more, and the low density polyethylene resin means a polyethylene resin having a density of 0.910 to 0.925 g / m 3 . As the paper layer used for the moisture-proof sheet A, the weight of 20 to 50 g / m 2 of building paper, pure white paper impregnated with latex or synthetic resin, or synthetic resin is mixed to enhance interlayer strength. Thin paper (so-called inter-paper reinforcing paper) is preferably used. If the weight is 20 to 50 g / m 2 , it is not too flexible, so that wrinkles are unlikely to occur during the laminating process, and peeling from the paper layer and moisture do not easily permeate. In addition, it is possible to increase the strength of the interlayer or the interface with high-density polyethylene by using chemical fiber paper, which is commonly called synthetic fiber paper such as rayon nonwoven fabric, for the paper layer on the flame-retardant substrate 2 side. It is.

また、防湿性を有する高密度ポリエチレン樹脂の押出コート層は、防湿性として、透湿度30g/m2・24hr以下、好ましくは透湿度15g/m2・24hr以下の性能を有することが望ましく、その厚みとしては、防湿シートとしての剛性、及び紙層との貼着作業性、材料コストの点から15〜30μm程度が好ましい。ここで、ポリエチレン樹脂を同一厚みで貼着した場合に、高密度ポリエチレン樹脂(密度0.942g/m3)と低密度ポリエチレン樹脂(密度0.924g/m3)とを対比すると、その透湿度は、例えば、15μmの時、それぞれ20g/m2・24hr、35g/m2・24hrであり、また30μmの時には10g/m2・24hr、20g/m2・24hrである。すなわち、高密度ポリエチレン樹脂の高防湿性能が発揮されるか、または低密度ポリエチレン樹脂と同等の防湿性能でよい場合には、薄膜化できるので、安価な防湿シートが作製可能となる。 The moisture-proof high-density polyethylene resin extrusion coating layer desirably has a moisture permeability of 30 g / m 2 · 24 hr or less, preferably a moisture permeability of 15 g / m 2 · 24 hr or less. As thickness, about 15-30 micrometers is preferable from the point of the rigidity as a moisture-proof sheet, sticking workability | operativity with a paper layer, and material cost. Here, when the polyethylene resin is pasted with the same thickness, when the high density polyethylene resin (density 0.942 g / m 3 ) and the low density polyethylene resin (density 0.924 g / m 3 ) are compared, the moisture permeability is For example, at 15 μm, they are 20 g / m 2 · 24 hr and 35 g / m 2 · 24 hr, respectively, and at 30 μm, they are 10 g / m 2 · 24 hr and 20 g / m 2 · 24 hr, respectively. That is, when the high moisture-proof performance of the high-density polyethylene resin is exhibited, or when the moisture-proof performance equivalent to that of the low-density polyethylene resin is sufficient, the film can be made thin, and an inexpensive moisture-proof sheet can be produced.

防湿シートAの作製方法としては、紙層と高密度ポリエチレン樹脂のフイルムとを接着剤を使うか、あるいは熱などで貼合せる方法、2枚の紙層にエクストルージョンラミネート法により高密度ポリエチレン樹脂の層を溶融押出しと同時にラミネートする方法などが挙げられるが、紙層/高密度ポリエチレン樹脂/紙層といった3層構造にするときには、エクストルージョンラミネート法により一度に3つの層を貼合せる方法が、工程が少なくて済むので最適な方法である。   The moisture-proof sheet A can be produced by using a method in which a paper layer and a high-density polyethylene resin film are bonded using an adhesive or heat, and the high-density polyethylene resin is formed on two paper layers by an extrusion laminating method. A method of laminating layers at the same time as melt extrusion is mentioned, but when a three-layer structure such as a paper layer / high-density polyethylene resin / paper layer is formed, a method of laminating three layers at a time by the extrusion laminating method is a process. This is the best method because it requires less.

また、防湿シートとしては、合成樹脂製基材と蒸着層とからなるもの(以下、防湿シートBという。)も好ましく用いられる。防湿シートBに用いられる合成樹脂製基材としては、上記した化粧シート5の樹脂シートを形成する樹脂が用いられるシートなどが挙げられる。当該シートの厚さは、5〜50μmが好ましく、9〜30μmがより好ましく、9〜25μmがさらに好ましい。
蒸着層としては、アルミニウムに代表される金属薄膜からなる無機物の蒸着層、あるいは酸化珪素、酸化マグネシウム、酸化アルミニウムに代表される無機酸化物の薄膜からなる無機酸化物蒸着層が好ましく挙げられる。この蒸着層は、真空蒸着法、プラズマ活性化化学反応蒸着法などの周知の蒸着法で、上記した合成樹脂製基材層の少なくとも一方の面に薄膜形成される。また、蒸着層の上には、防湿シートの防湿性を向上させる目的で、ポリビニルアルコールあるいはポリビニルアルコールに酸化珪素、酸化マグネシウム、酸化アルミニウムに代表される無機酸化物を添加した組成物をロールコート法、グラビアコート法などの周知の塗布方法でポリビニルアルコール層あるいは当該組成物層を塗布形成することができる。
Moreover, as a moisture-proof sheet, what consists of a synthetic resin base material and a vapor deposition layer (henceforth a moisture-proof sheet B) is also used preferably. Examples of the synthetic resin substrate used for the moisture-proof sheet B include a sheet using a resin that forms the resin sheet of the decorative sheet 5 described above. The thickness of the sheet is preferably 5 to 50 μm, more preferably 9 to 30 μm, and still more preferably 9 to 25 μm.
Preferred examples of the vapor deposition layer include an inorganic vapor deposition layer composed of a metal thin film typified by aluminum, or an inorganic oxide vapor deposition layer composed of an inorganic oxide thin film typified by silicon oxide, magnesium oxide, and aluminum oxide. This vapor deposition layer is formed into a thin film on at least one surface of the above-mentioned synthetic resin base material layer by a known vapor deposition method such as a vacuum vapor deposition method or a plasma activated chemical reaction vapor deposition method. In addition, on the vapor deposition layer, a roll coating method is applied to polyvinyl alcohol or a composition in which an inorganic oxide typified by silicon oxide, magnesium oxide or aluminum oxide is added to polyvinyl alcohol or polyvinyl alcohol for the purpose of improving moisture resistance of the moisture-proof sheet. The polyvinyl alcohol layer or the composition layer can be applied and formed by a known coating method such as a gravure coating method.

防湿シートBは、積層基材との接着性を向上させる目的で、接着用プライマー層を有することができる。プライマー層を形成する樹脂としては、エステル系樹脂、ウレタン系樹脂、アクリル系樹脂、ポリカーボネート系樹脂、塩化ビニル−酢酸ビニル共重合体、ポリビニルブチラール系樹脂、ニトロセルロース系樹脂などが挙げられ、これらの樹脂は単独で又は複数を混合して用いることができる。接着用プライマー層は、上記した樹脂をロールコート法やグラビア印刷法などの塗布方法により塗布することで、形成される。   The moisture-proof sheet B can have an adhesion primer layer for the purpose of improving the adhesion to the laminated substrate. Examples of the resin forming the primer layer include ester resins, urethane resins, acrylic resins, polycarbonate resins, vinyl chloride-vinyl acetate copolymers, polyvinyl butyral resins, nitrocellulose resins, and the like. The resins can be used alone or in combination. The adhesion primer layer is formed by applying the above-described resin by a coating method such as a roll coating method or a gravure printing method.

上記した以外の接着用プライマー層に用いられる樹脂としては、アクリル樹脂とウレタン樹脂との共重合体(I)と、イソシアネート(II)とからなる樹脂が特に好ましく挙げられる。上記共重合体(I)のアクリル樹脂とウレタン樹脂との共重合体は、末端に水酸基を有するアクリル重合体成分(A)、両末端に水酸基を有するポリエステルポリオール成分(B)、及びジイソシアネート成分(C)を配合して反応させてプレポリマーとし、該プレポリマーにジアミンなどの鎖延長剤(D)を添加して鎖延長することにより得られる。この反応により、得られるアクリル樹脂とウレタン樹脂との共重合体(I)は、ポリエステルウレタンが形成されるとともに、アクリル重合体成分が分子中に導入されて、末端に水酸基を有するアクリル−ポリエステルウレタン共重合体である。このようにして得られるアクリル樹脂とウレタン樹脂との共重合体(I)の末端の水酸基が、イソシアネート(II)と反応して硬化することで、接着用プライマー層が形成する。   As the resin used for the adhesion primer layer other than those described above, a resin comprising a copolymer (I) of an acrylic resin and a urethane resin and isocyanate (II) is particularly preferable. The copolymer of the copolymer (I) of an acrylic resin and a urethane resin includes an acrylic polymer component (A) having a hydroxyl group at a terminal, a polyester polyol component (B) having a hydroxyl group at both terminals, and a diisocyanate component ( It is obtained by blending and reacting C) to obtain a prepolymer, and adding a chain extender (D) such as diamine to the prepolymer to extend the chain. As a result of this reaction, the copolymer (I) of the resulting acrylic resin and urethane resin forms a polyester urethane, an acrylic polymer component is introduced into the molecule, and an acrylic-polyester urethane having a hydroxyl group at the end. It is a copolymer. The terminal hydroxyl group of the copolymer (I) of the acrylic resin and the urethane resin thus obtained reacts with the isocyanate (II) and cures to form an adhesion primer layer.

本発明の内装化粧材は、特に制限は無いが、その特徴をいかせる点で、耐衝撃性が要求される用途に用いられることが好ましい。好ましい用途としては、例えば、扉、壁板、床板、腰壁、回縁、棚、戸袋等の内装建材用途、机、箪笥等の家具用途等が挙げられる。なかでも、本発明の内装化粧材は、住宅や商業施設、病院、介護施設等の壁面に用いられる腰壁用途として有用である。腰壁用途の内装化粧材の厚みとしては、壁面からのドア枠の突き出し幅以下であることが好ましい。突き出し幅以下であると、耐衝撃性や反りの発生が生じにくいことの他に内装化粧材の壁面の収まりがよく、綺麗な壁面に仕上げることができる。一般に壁面からのドア枠の突き出し幅としては、10mm程度であることから、具体的な腰壁用途の内装化粧材の厚みとしては、10mm以下が好ましく、より好ましくは7mm以下である。また、本発明の内装化粧材は、通常の環境下ではもちろんのこと、高温多湿な厳しい環境下においても、反りの発生が生じにくいため、高温多湿な環境においても反りの発生を気にすることなく用いることができる。
腰壁として用いられる場合、本発明の内装化粧材は、図3に示されるように、石膏板、石膏スラグ板等の石膏系板、珪酸カルシウム板、石綿スレート板、軽量発泡コンクリート板、中空押出セメント板等のセメント板、パルプセメント板、石綿セメント板、木片セメント板等の繊維セメント板等の下地材の上に接着剤層を介して貼着して用いられる。接着剤層に用いられる接着剤は、通常用いられるものを制限なく使用することができる。
The interior decorative material of the present invention is not particularly limited, but is preferably used for applications that require impact resistance in terms of its characteristics. Preferable uses include, for example, interior building materials such as doors, wall boards, floor boards, waist walls, curbs, shelves, door pockets, and furniture uses such as desks and bags. Especially, the interior decoration material of this invention is useful as a waist wall use used for wall surfaces, such as a house, a commercial facility, a hospital, and a nursing care facility. The thickness of the interior decorative material for the waist wall is preferably equal to or less than the protruding width of the door frame from the wall surface. When the width is not more than the protrusion width, impact resistance and warpage are less likely to occur, and the interior decorative material has a good fit and can be finished into a beautiful wall. Generally, the width of the door frame protruding from the wall surface is about 10 mm, and therefore the thickness of the interior decorative material for specific waist wall use is preferably 10 mm or less, more preferably 7 mm or less. In addition, the interior decorative material of the present invention is less likely to be warped in a hot and humid environment as well as in a normal environment. Can be used.
When used as a waist wall, as shown in FIG. 3, the interior decorative material of the present invention includes a plaster board such as a gypsum board and a gypsum slag board, a calcium silicate board, an asbestos slate board, a lightweight foamed concrete board, and a hollow extruded board. It is used by adhering to a base material such as a cement board such as a cement board, a fiber cement board such as a pulp cement board, an asbestos cement board, and a wood chip cement board via an adhesive layer. As the adhesive used for the adhesive layer, a commonly used adhesive can be used without limitation.

次に、本発明を実施例により、さらに詳細に説明するが、本発明は、この例によってなんら限定されるものではない。
(評価及び測定方法)
各実施例で得られた化粧内装材、及び各実施例で用いた材料について、以下の方法で評価及び測定した。
(1)破断伸び特性の測定
各実施例で用いた熱可塑性樹脂発泡板の破断伸び特性を、JIS K7127−1999に準じて測定した。
(2)反りの評価
各実施例及び比較例で製造した内装化粧材を30cm×90cmにカットして、60℃10%の環境下で1週間放置し、次いで50℃90%の環境下で1週間放置した。この内装化粧材の90cmの辺の反りを計測した。
◎ 0以上2mm未満
○ 2mm以上4mm未満
△ 4mm以上10mm未満
× 10mm以上
(3)耐衝撃性の評価(内装化粧材表面)
各実施例及び比較例で製造した内装化粧材を下地材の石膏ボードに貼着して得られた試験片を、JIS K7211−1976に準じて落錘衝撃試験を行った。なす型重錘(なす1型)を、高さ75cm及び1m上から内装化粧材に落下させ、該内装化粧材の表面の様子を目視し、下記の基準で評価した。
○ 表面の変化は全くなかった
△ 表面に若干の凹みが生じたが、実用上問題ない
× 表面に著しい凹みが生じた
(4)耐衝撃性の評価(下地材)
上記の落錘衝撃試験を行い、内装化粧材の下地材である石膏ボードの様子を目視し、下記の基準で評価した。
○ 割れは全くなかった
△ 割れが若干生じたが、実用上問題ない
× 割れが著しく生じた
EXAMPLES Next, although an Example demonstrates this invention further in detail, this invention is not limited at all by this example.
(Evaluation and measurement method)
The decorative interior materials obtained in each Example and the materials used in each Example were evaluated and measured by the following methods.
(1) Measurement of elongation at break The elongation at break of the thermoplastic resin foam plate used in each example was measured according to JIS K7127-1999.
(2) Evaluation of warpage The interior decorative material produced in each example and comparative example was cut into 30 cm × 90 cm, left in a 60 ° C. and 10% environment for one week, and then in a 50 ° C. and 90% environment. Left for a week. The warpage of the 90 cm side of this interior decorative material was measured.
◎ 0 or more and less than 2mm ○ 2mm or more and less than 4mm △ 4mm or more and less than 10mm × 10mm or more (3) Impact resistance evaluation (interior cosmetic material surface)
A test piece impact test was carried out on the test pieces obtained by sticking the interior decorative material produced in each Example and Comparative Example to a gypsum board as a base material according to JIS K7211-1976. An eggplant type weight (an eggplant type 1) was dropped onto an interior decorative material from a height of 75 cm and 1 m, and the surface of the interior decorative material was visually observed and evaluated according to the following criteria.
○ There was no change in the surface. △ Some dents were formed on the surface, but there was no problem in practical use. × Remarkable dents were generated on the surface. (4) Impact resistance evaluation (base material)
The falling weight impact test was performed, and the appearance of the gypsum board as the base material of the interior decorative material was visually observed and evaluated according to the following criteria.
○ There were no cracks. △ Some cracks occurred, but there was no problem in practical use.

実施例1
低密度木質系繊維板として、インシュレーションボード(大建工業(株)製、厚み:4.0mm,密度:0.27g/cm2)を、高密度木質系繊維板として、中密度繊維板(商品名:NPウッド、住友林業(株)製、厚み:2.5mm,密度:0.76g/cm2、以下、MDFと称する。)を、化粧シート5としてオレフィンシート(商品名:WSサフマーレ、大日本印刷株式会社製、厚み:0.14mm)を用意した。まず、MDFにポリウレタン系樹脂を主成分とする接着剤を厚さ10μm/dryで塗布し、オレフィンシートを貼着させた。次いで、低密度木質系繊維板に、上記と同様の接着剤を厚さ10μm/dryで塗布し、MDFを貼着して、本発明の内装化粧材を得た。得られた内装化粧材を、石膏ボード(商品名:タイガーボード、吉野石膏株式会社、厚み:12.5mm)に貼着して試験片を得た。
Example 1
As a low-density wood fiberboard, an insulation board (Daiken Kogyo Co., Ltd., thickness: 4.0 mm, density: 0.27 g / cm 2 ) is used as a high-density wood fiberboard. Product name: NP Wood, manufactured by Sumitomo Forestry Co., Ltd., thickness: 2.5 mm, density: 0.76 g / cm 2 , hereinafter referred to as MDF), and olefin sheet (trade name: WS Safmare, Dai Nippon Printing Co., Ltd., thickness: 0.14 mm) was prepared. First, an adhesive mainly composed of a polyurethane resin was applied to MDF at a thickness of 10 μm / dry, and an olefin sheet was adhered. Next, the same adhesive as described above was applied to the low-density wood fiberboard at a thickness of 10 μm / dry, and MDF was stuck to obtain the interior decorative material of the present invention. The obtained interior decorative material was stuck on a gypsum board (trade name: Tiger Board, Yoshino Gypsum Co., Ltd., thickness: 12.5 mm) to obtain a test piece.

実施例2
低密度木質系繊維板として、インシュレーションボード(大建工業(株)製、厚み:4.0mm,密度:0.27g/cm2)を、高密度木質系繊維板として、ハードボード(大建工業(株)製、厚み:2mm,密度:1.01g/cm2)2枚を、化粧シート5としてオレフィンシート(商品名:WSサフマーレ、大日本印刷株式会社製、厚み:0.14mm)を用意した。まず、1枚のハードボードにポリウレタン系樹脂を主成分とする接着剤を厚さ10μm/dryで塗布し、オレフィンシートを貼着させた。次いで、低密度木質系繊維板に、上記と同様の接着剤を厚さ10μm/dryで塗布し、オレフィンシートを貼着させたハードボードのオレフィンシートが最外面となるように貼着して、さらに、もう1枚のハードボードに上記と同様の接着剤を厚さ10μm/dryで塗布し、低密度木質系繊維板を貼着させて、本発明の内装化粧材を得た。得られた内装化粧材を、石膏ボード(商品名:タイガーボード、吉野石膏株式会社、厚み:12.5mm)に貼着して試験片を得た。
Example 2
Insulation board (Daiken Kogyo Co., Ltd., thickness: 4.0 mm, density: 0.27 g / cm 2 ) is used as the low-density wood fiberboard, and hardboard (Daiken) as the high-density wood fiberboard. Two olefin sheets (trade name: WS Safmare, manufactured by Dai Nippon Printing Co., Ltd., thickness: 0.14 mm) were used as decorative sheets 5 with two sheets manufactured by Kogyo Co., Ltd., thickness: 2 mm, density: 1.01 g / cm 2. Prepared. First, an adhesive mainly composed of a polyurethane resin was applied to one hard board at a thickness of 10 μm / dry, and an olefin sheet was adhered. Next, the same adhesive as described above was applied to the low-density wood fiberboard at a thickness of 10 μm / dry, and the olefin sheet of the hardboard on which the olefin sheet was adhered was adhered to the outermost surface, Furthermore, an adhesive similar to the above was applied to another hard board at a thickness of 10 μm / dry, and a low-density wood fiberboard was adhered to obtain the interior decorative material of the present invention. The obtained interior decorative material was stuck on a gypsum board (trade name: Tiger Board, Yoshino Gypsum Co., Ltd., thickness: 12.5 mm) to obtain a test piece.

製造例1(防湿シートAの作製)
秤量20g/m2の紙間強化紙(「FIX−30(商品名)」:三興製紙(株)製)にTダイ押出機から40μmの厚さに密度0.94g/cm3の高密度ポリエチレン樹脂を押出コーティングし、同時にもう一枚の秤量20g/m2の紙間強化紙(三興製紙(株)製、FIX−30)をラミネートして、チルロールで冷却して紙層が2層構造となる防湿シートAを作製した。
Production Example 1 (Preparation of moisture-proof sheet A)
High density of 0.94 g / cm 3 with a thickness of 40 μm from T-die extruder on paper-reinforced paper (“FIX-30 (trade name)” manufactured by Sanko Paper Co., Ltd.) weighing 20 g / m 2 Polyethylene resin is extrusion coated, and at the same time, another sheet of paper-reinforced paper with a weight of 20 g / m 2 (manufactured by Sanko Paper Co., Ltd., FIX-30) is laminated and cooled with a chill roll to form two paper layers. A moisture-proof sheet A having a structure was produced.

製造例2(防湿シートB1の作製)
一方の面にシリカ蒸着層を設けた二軸延伸PETフィルム(「ルミラー(商品名)」:東レ株式会社製,厚さ:12μm)の蒸着層面に、2液硬化型ウレタン系接着剤を3g/m2(固形分基準)で塗布・乾燥し、該塗布面にTダイ押出機でポリエチレンを15μm厚さに加熱溶融押出しして積層体(PET/蒸着層/ポリエチレン)を作製した。この積層体の両表出面にコロナ放電処理を施した後、主剤としてウレタン樹脂/硝化綿系樹脂に硬化剤としてイソシアネートを添加した2液硬化型樹脂をグラビア印刷で、各々5g/m2(固形物基準)で塗布して、接着用プライマー層を両面に形成した防湿シートB1を作製した。
Production Example 2 (Preparation of moisture-proof sheet B1)
On the surface of the biaxially stretched PET film (“Lumirror (trade name)” manufactured by Toray Industries, Inc., thickness: 12 μm) having a silica vapor deposition layer on one surface, 3 g / two-component curable urethane adhesive is used. It was coated and dried at m 2 (based on solid content), and polyethylene was heated and extruded to a thickness of 15 μm with a T-die extruder on the coated surface to produce a laminate (PET / deposition layer / polyethylene). After the corona discharge treatment is applied to both exposed surfaces of this laminate, a two-part curable resin in which isocyanate is added as a curing agent to a urethane resin / nitrified cotton-based resin as a main agent is obtained by gravure printing at 5 g / m 2 (solid The moisture-proof sheet B1 was produced by applying the adhesive primer layer on both sides.

製造例3(防湿シートB2の作製)
一方の面にシリカ蒸着層を設けた二軸延伸PETフィルム(「ルミラー(商品名)」:東レ株式会社製,厚さ:12μm)の蒸着層面に、ポリビニルアルコール溶液を乾燥後に0.2g/m2となるようにグラビア印刷で塗布した後、他方の面にコロナ放電処理を施して、ポリビニルアルコール溶液の塗布面とコロナ放電処理面とに、主剤としてウレタン樹脂//硝化綿系樹脂に硬化剤としてイソシアネートを添加した2液硬化型樹脂をグラビア印刷で、各々2g/m2(固形物基準)で塗布して、接着用プライマー層を両面に形成した防湿シートB2を作製した。
Production Example 3 (Preparation of moisture-proof sheet B2)
On the surface of the biaxially stretched PET film (“Lumirror (trade name)” manufactured by Toray Industries, Inc., thickness: 12 μm) provided with a silica vapor deposition layer on one surface, 0.2 g / m after drying the polyvinyl alcohol solution. After applying by gravure printing so that it becomes 2 , the other surface is subjected to corona discharge treatment, and the hardened agent is urethane resin // nitrified cotton-based resin as the main agent on the coated surface of the polyvinyl alcohol solution and the corona discharge treated surface. As a moisture-proof sheet B2 having a primer layer for adhesion formed on both sides was applied by gravure printing with a two-component curable resin added with isocyanate as 2 g / m 2 (based on solids).

実施例3
低密度木質系繊維板として、インシュレーションボード(大建工業(株)製、厚み:4.0mm,密度:0.27g/cm2)を、高密度木質系繊維板として、ハードボード(大建工業(株)製、厚み:2mm,密度:1.01g/cm2)2枚を、化粧シート5としてオレフィンシート(商品名:WSサフマーレ、大日本印刷株式会社製、厚み:0.14mm)を用意した。まず、低密度木質系繊維板に、ポリウレタン系樹脂を主成分とする接着剤を厚さ10μm/dryで塗布し、オレフィンシートを貼着させたハードボードのオレフィンシートが最外面となるように貼着して、さらに、もう1枚のハードボードに上記と同様の接着剤を厚さ10μm/dryで塗布し、低密度木質系繊維板を貼着させて、3層の積層基材を得た。次いで、得られた積層基材の一方の高密度木質系繊維板の表面に、ポリウレタン系樹脂を主成分とする接着剤を厚さ10μm/dryで塗布して、製造例1で得られた防湿シートAを貼着し、もう一方の高密度木質系繊維板の表面に、樹脂組成物(ウレタン系樹脂(EX−9)とアクリル系樹脂(SA−95)との混合物で、その質量比は100:10である。EX−9及びSA−95は、いずれも中央理化工業株式会社製である。)を11μmの厚さとなるように塗布し、乾燥させた後、オレフィンシートにウレタン系樹脂を主成分とする接着剤を厚さ10μm/dryで塗布して、積層基材に貼着して、本発明の内装化粧材を得た。得られた内装化粧材を、石膏ボード(商品名:タイガーボード、吉野石膏株式会社、厚み:12.5mm)に貼着して試験片を得た。
Example 3
Insulation board (Daiken Kogyo Co., Ltd., thickness: 4.0 mm, density: 0.27 g / cm 2 ) is used as the low-density wood fiberboard, and hardboard (Daiken) as the high-density wood fiberboard. Two olefin sheets (trade name: WS Safmare, manufactured by Dai Nippon Printing Co., Ltd., thickness: 0.14 mm) were used as decorative sheets 5 with two sheets manufactured by Kogyo Co., Ltd., thickness: 2 mm, density: 1.01 g / cm 2. Prepared. First, an adhesive mainly composed of a polyurethane resin is applied to a low-density wood fiberboard at a thickness of 10 μm / dry, and the hardboard olefin sheet is pasted so that the olefin sheet is the outermost surface. Further, the same adhesive as described above was applied to another hard board at a thickness of 10 μm / dry, and a low-density wood fiberboard was adhered to obtain a three-layer laminated substrate. . Next, an adhesive mainly composed of a polyurethane resin was applied at a thickness of 10 μm / dry on the surface of one of the high-density wood fiberboards of the obtained laminated substrate, and the moisture-proof obtained in Production Example 1 The sheet A is attached, and the other high-density wood fiberboard is coated with a resin composition (a mixture of a urethane resin (EX-9) and an acrylic resin (SA-95). 100: 10 EX-9 and SA-95 are both manufactured by Chuo Rika Kogyo Co., Ltd.) to a thickness of 11 μm and dried, and then urethane resin is applied to the olefin sheet. The adhesive as a main component was applied at a thickness of 10 μm / dry and adhered to the laminated base material to obtain the interior decorative material of the present invention. The obtained interior decorative material was stuck on a gypsum board (trade name: Tiger Board, Yoshino Gypsum Co., Ltd., thickness: 12.5 mm) to obtain a test piece.

実施例4
実施例3において、オレフィンシートを積層基材の対向する二辺の裏面まで巻き込む二方巻きで貼着した以外は、実施例3と同様にして内装化粧材と試験片を得た。
Example 4
In Example 3, an interior decorative material and a test piece were obtained in the same manner as in Example 3 except that the olefin sheet was attached by two-way winding to wind up to the opposite two back surfaces of the laminated base material.

実施例5及び6
実施例3において、防湿シートAを各々製造例2で得られた防湿シートB1及び製造例3で得られた防湿シートB2にした以外は、実施例3と同様にして、実施例5及び実施例6の内装化粧材と試験片を得た。
Examples 5 and 6
In Example 3, Example 5 and Example are the same as Example 3 except that the moisture-proof sheet A is the moisture-proof sheet B1 obtained in Production Example 2 and the moisture-proof sheet B2 obtained in Production Example 3, respectively. 6 interior decorative materials and test pieces were obtained.

比較例1
実施例1において、インシュレーションボードを使用せず、MDFの厚みを9mmとした以外は実施例1と同様にして内装化粧材及び試験片を得た。
Comparative Example 1
In Example 1, an interior decorative material and a test piece were obtained in the same manner as in Example 1 except that the insulation board was not used and the thickness of the MDF was 9 mm.

比較例2
壁紙(東リ株式会社製、厚み:1mm)を石膏ボード(商品名:タイガーボード、吉野石膏株式会社、厚み:12.5mm)に貼着して試験片を得た。なお、反りの評価は壁紙で行った。
Comparative Example 2
Wallpaper (made by Toli Co., Ltd., thickness: 1 mm) was stuck on a gypsum board (trade name: Tiger Board, Yoshino Gypsum Co., Ltd., thickness: 12.5 mm) to obtain a test piece. The warpage was evaluated using wallpaper.

比較例3
ポリエステル化粧板(アイカ工業株式会社製、厚み:2.5mm)を石膏ボード(商品名:タイガーボード、吉野石膏株式会社、厚み:12.5mm)に貼着して試験片を得た。なお、反りの評価はポリエステル化粧板で行った。
Comparative Example 3
A polyester decorative board (manufactured by Aika Kogyo Co., Ltd., thickness: 2.5 mm) was attached to a gypsum board (trade name: Tiger Board, Yoshino Gypsum Co., Ltd., thickness: 12.5 mm) to obtain a test piece. The warpage was evaluated using a polyester decorative board.

比較例4
木粉配合塩ビシート(厚み:2.5mm)を石膏ボード(商品名:タイガーボード、吉野石膏株式会社、厚み:12.5mm)に貼着して試験片を得た。なお、反りの評価は木粉配合塩ビシートで行った。
Comparative Example 4
A wood powder blended PVC sheet (thickness: 2.5 mm) was adhered to a gypsum board (trade name: Tiger Board, Yoshino Gypsum Co., Ltd., thickness: 12.5 mm) to obtain a test piece. In addition, evaluation of curvature was performed with the wood powder combination PVC sheet.

参考例1
実施例1において、インシュレーションボードを使用せず、MDFの厚みを12mmとした以外は実施例1と同様にして内装化粧材及び試験片を得た。
Reference example 1
In Example 1, an interior decorative material and a test piece were obtained in the same manner as in Example 1 except that the insulation board was not used and the thickness of the MDF was set to 12 mm.

実施例1〜6、比較例1〜4、ならびに参考例1について上記評価を行った結果を第1表に示す。
実施例1で得られた内装化粧材は、全ての点で高い性能が示され、実施例2で得られた内装化粧材は、実施例1と比べて反りの評価がさらに向上した。防湿シートを設けた実施例3、5及び6で得られた内装化粧材は、さらに反りの評価が優れたものとなり、化粧シートを二方巻きで貼着した実施例4で得られた内装化粧材は、反りの評価に加えて側面の美観に優れた化粧材が得られた。また、比較例1〜4では、反りの評価は良好であったが、表面の凹み、石膏ボードの割れの点で不十分であった。また、参考例1は、熱可塑性樹脂発泡板を用いず、木質系繊維板を厚くして、耐衝撃性の評価が十分となる例であるが、木質系繊維板の厚みとして12mmが必要であり、重量物となり実用とするには十分ではなかった。
Table 1 shows the results of the above evaluations on Examples 1 to 6, Comparative Examples 1 to 4, and Reference Example 1.
The interior decorative material obtained in Example 1 showed high performance in all respects, and the interior decorative material obtained in Example 2 was further improved in warpage evaluation as compared to Example 1. The interior decorative material obtained in Examples 3, 5 and 6 provided with the moisture-proof sheet is further excellent in warpage evaluation, and the interior cosmetic obtained in Example 4 in which the decorative sheet is stuck in two-way winding. In addition to the evaluation of warpage, the material was a decorative material with excellent side aesthetics. Moreover, in Comparative Examples 1-4, although evaluation of curvature was favorable, it was inadequate at the point of the surface dent and the crack of a gypsum board. Reference Example 1 is an example in which the thermoplastic fiber foam board is not used and the wood fiber board is thickened, and the impact resistance is sufficiently evaluated. However, the thickness of the wood fiber board is required to be 12 mm. It was heavy and was not sufficient for practical use.

Figure 0005251402
Figure 0005251402

本発明によれば、耐衝撃性に優れ、かつ高温多湿の状況下でも反りの発生が抑えられ、特に腰壁に好適に用いられる内装化粧材を得ることができる。   ADVANTAGE OF THE INVENTION According to this invention, it is excellent in impact resistance, generation | occurrence | production of curvature is suppressed also in the conditions of high temperature and humidity, and the interior decoration material used suitably especially for a waist wall can be obtained.

本発明の内装化粧材の断面を示す模式図である。It is a schematic diagram which shows the cross section of the interior decorative material of this invention. 本発明の内装化粧材の断面を示す模式図である。It is a schematic diagram which shows the cross section of the interior decorative material of this invention. 本発明の内装化粧材の使用例の断面を示す模式図である。It is a schematic diagram which shows the cross section of the usage example of the interior decorative material of this invention.

符号の説明Explanation of symbols

1.内装化粧材
2.高密度木質系繊維板
21.高密度木質系繊維板
22.高密度木質系繊維板
31.接着剤層
32.接着剤層
33.接着剤層
34.接着剤層
4.低密度木質系繊維板
5.化粧シート
6.下地材
1. Interior decorative material 2. High density wood fiberboard 21. High density wood fiberboard 22. High density wood fiberboard 31. Adhesive layer 32. Adhesive layer 33. Adhesive layer 34. Adhesive layer 4. 4. Low density wood fiberboard Decorative sheet Base material

Claims (8)

密度が0.40g/cm 3 未満の範囲である低密度木質系繊維板の上に、密度が0.70g/cm 3 以上の範囲である高密度木質系繊維板を積層し、該低密度木質系繊維板の該高密度木質系繊維板を設けた裏面に、さらに高密度木質系繊維板を積層してなり、かつ該高密度木質系繊維板の少なくとも一方に防湿シートが設けられる内装化粧材。 On the low density wood fiber board having a density of less than 0.40 g / cm 3 , a high density wood fiber board having a density of 0.70 g / cm 3 or more is laminated , the rear surface having a high-density wood fiber board density wood fiberboard, made by further laminating a high density wood fiber board, and that at least moisture-proof sheet on one of the high density wood fiber board is provided Interior decorative material. 前記防湿シートが、高密度ポリエチレン樹脂の押出コート層の両面に紙層を有する防湿シート、又は合成樹脂基材と蒸着層とからなる防湿シートである請求項1に記載の内装化粧材。The interior decorative material according to claim 1, wherein the moisture-proof sheet is a moisture-proof sheet having paper layers on both sides of an extrusion coating layer of a high-density polyethylene resin, or a moisture-proof sheet comprising a synthetic resin substrate and a vapor deposition layer. 前記高密度木質系繊維板に、化粧シートを積層してなる請求項1又は2に記載の内装化粧材。   The interior decorative material according to claim 1 or 2, wherein a decorative sheet is laminated on the high-density wood fiberboard. 前記2枚の高密度木質系繊維板が同じである請求項1〜3のいずれかに記載の内装化粧材。The interior decorative material according to any one of claims 1 to 3, wherein the two high-density wood fiberboards are the same. 前記高密度木質系繊維板が、MDF(中密度繊維板)である請求項1〜4のいずれかに記載の内装化粧材。 The interior decorative material according to any one of claims 1 to 4, wherein the high-density wood fiberboard is MDF (medium density fiberboard). 前記高密度木質系繊維板の少なくとも一方が、MDF(中密度繊維板)である請求項1〜3のいずれかに記載の内装化粧材。 The interior decorative material according to any one of claims 1 to 3, wherein at least one of the high-density wood fiberboard is MDF (medium density fiberboard). 前記低密度木質系繊維板が、インシュレーションボードである請求項1〜6のいずれかに記載の内装化粧材。 The interior decorative material according to any one of claims 1 to 6 , wherein the low-density wood fiberboard is an insulation board. 腰壁に用いられる請求項1〜7のいずれかに記載の内装化粧材。 The interior decorative material according to any one of claims 1 to 7 , which is used for a waist wall.
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JPS59111833A (en) * 1982-12-18 1984-06-28 Hokusan Riaruutsudo Kk Decorative board with carved pattern
JPH0616743Y2 (en) * 1989-02-18 1994-05-02 株式会社ノダ Laminate
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