JP5244399B2 - 遷移金属を触媒とする炭素−窒素結合および炭素−炭素結合形成反応 - Google Patents

遷移金属を触媒とする炭素−窒素結合および炭素−炭素結合形成反応 Download PDF

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JP5244399B2
JP5244399B2 JP2007550475A JP2007550475A JP5244399B2 JP 5244399 B2 JP5244399 B2 JP 5244399B2 JP 2007550475 A JP2007550475 A JP 2007550475A JP 2007550475 A JP2007550475 A JP 2007550475A JP 5244399 B2 JP5244399 B2 JP 5244399B2
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hydrogen
alkyl
group
aryl
cycloalkyl
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エル バッチウォルド，ステファン
ダブリュ アンダーソン，ケヴィン
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/367—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by introduction of functional groups containing oxygen only in singly bound form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
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    • C07B37/04—Substitution
    • C—CHEMISTRY; METALLURGY
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    • C07B43/04—Formation or introduction of functional groups containing nitrogen of amino groups
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
    • C07C303/22—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof from sulfonic acids, by reactions not involving the formation of sulfo or halosulfonyl groups; from sulfonic halides by reactions not involving the formation of halosulfonyl groups
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    • C07C303/40—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of amides of sulfonic acids by reactions not involving the formation of sulfonamide groups
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    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
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    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
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    • C07D409/06—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
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    • B01J2231/4211—Suzuki-type, i.e. RY + R'B(OR)2, in which R, R' are optionally substituted alkyl, alkenyl, aryl, acyl and Y is the leaving group
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    • B01J2231/4211—Suzuki-type, i.e. RY + R'B(OR)2, in which R, R' are optionally substituted alkyl, alkenyl, aryl, acyl and Y is the leaving group
    • B01J2231/4227—Suzuki-type, i.e. RY + R'B(OR)2, in which R, R' are optionally substituted alkyl, alkenyl, aryl, acyl and Y is the leaving group with Y= Cl
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    • B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
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    • B01J2231/4266—Sonogashira-type, i.e. RY + HC-CR' triple bonds, in which R=aryl, alkenyl, alkyl and R'=H, alkyl or aryl
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    • B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
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JP2007550475A 2005-01-10 2006-01-09 遷移金属を触媒とする炭素−窒素結合および炭素−炭素結合形成反応 Expired - Lifetime JP5244399B2 (ja)

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US64277405P 2005-01-10 2005-01-10
US60/642,774 2005-01-10
PCT/US2006/000365 WO2006074315A2 (en) 2005-01-10 2006-01-09 Transition-metal-catalyzed carbon-nitrogen and carbon-carbon bond-forming reactions

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JP2008526872A JP2008526872A (ja) 2008-07-24
JP2008526872A5 JP2008526872A5 (https=) 2009-03-05
JP5244399B2 true JP5244399B2 (ja) 2013-07-24

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US (3) US7560596B2 (https=)
EP (1) EP1833605B1 (https=)
JP (1) JP5244399B2 (https=)
CA (1) CA2594307C (https=)
WO (1) WO2006074315A2 (https=)

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DE102005030400A1 (de) * 2005-06-27 2006-12-28 Archimica Gmbh Verfahren zur Herstellung von Arylaminen, Arylethern und Arylthioethern
DE102006037399A1 (de) * 2006-08-10 2008-02-14 Archimica Gmbh Verfahren zur Herstellung von Arylaminen
EP2170914A1 (en) * 2007-06-20 2010-04-07 Agency for Science, Technology and Research N-heterocyclic carbene metallacycle catalysts and methods
BRPI0812829A2 (pt) * 2007-07-03 2014-12-09 Sanofi Aventis Processo para o acoplamento catalisado por paládio de alcinas terminais com tosilatos de arila
JP4275186B2 (ja) * 2007-07-30 2009-06-10 新日本石油株式会社 ノルボルネン誘導体の製造方法
US7858784B2 (en) * 2007-12-12 2010-12-28 Massachusetts Institute Of Technology Ligands for transition-metal-catalyzed cross-couplings, and methods of use thereof
JP5225716B2 (ja) * 2008-03-11 2013-07-03 新日鉄住金化学株式会社 インドール誘導体の製造方法
JP5222632B2 (ja) * 2008-06-13 2013-06-26 白鳥製薬株式会社 ビアリール化合物の製造方法
BR112013001138A2 (pt) 2010-07-16 2016-07-05 Abbvie Inc ligantes de fosfina para reações catalíticas
US8895737B2 (en) 2010-07-16 2014-11-25 Shashank Shekhar Process for preparing antiviral compounds
US8975443B2 (en) 2010-07-16 2015-03-10 Abbvie Inc. Phosphine ligands for catalytic reactions
US9255074B2 (en) 2010-07-16 2016-02-09 Abbvie Inc. Process for preparing antiviral compounds
DE102011017027A1 (de) 2011-04-14 2012-10-18 Studiengesellschaft Kohle Mbh Verfahren zur Herstellung von aromatischen und heteroaromatischen Aminen
EP2559484A1 (en) * 2011-08-18 2013-02-20 Universiteit van Amsterdam Coordination complex system comprising a second bulding block without donor moiety
EP2776386B1 (de) 2011-11-11 2019-11-20 Merck Patent GmbH Verfahren zur herstellung von arylaminen
WO2013159229A1 (en) * 2012-04-24 2013-10-31 Dalhousie University Silanyloxyaryl phosphine ligand and uses thereof in c-n cross-coupling
US11104653B2 (en) 2018-05-08 2021-08-31 Colorado State University Research Foundation Methods for forming aryl carbon-nitrogen bond using light
KR102785431B1 (ko) 2018-07-04 2025-03-21 메르크 파텐트 게엠베하 아릴아민의 제조 방법
JP7041092B2 (ja) 2019-04-05 2022-03-23 日本化学工業株式会社 ビアリールホスフィンの製造方法
CN114606520B (zh) * 2022-03-28 2024-01-19 重庆化工职业学院 一种芳基磷酸酯的合成方法
EP4665495A1 (en) * 2023-02-15 2025-12-24 Indian Institute of Technology Bombay Development of ligands for metals and metal-catalyzed reactions

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US6307087B1 (en) * 1998-07-10 2001-10-23 Massachusetts Institute Of Technology Ligands for metals and improved metal-catalyzed processes based thereon
EP1097158B1 (en) * 1998-07-10 2006-01-25 Massachusetts Institute Of Technology Ligands for metals and metal-catalyzed processes
WO2003006420A1 (en) 2001-07-12 2003-01-23 Yale University Catalytic method to convert aryl compounds to aryl amines
CA2509522C (en) * 2002-12-09 2013-05-07 Massachusetts Institute Of Technology Ligands for metals and improved metal-catalyzed processes based thereon

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WO2006074315A3 (en) 2006-08-31
US20130178632A1 (en) 2013-07-11
EP1833605A2 (en) 2007-09-19
US8735630B2 (en) 2014-05-27
JP2008526872A (ja) 2008-07-24
EP1833605B1 (en) 2018-08-15
US8378145B2 (en) 2013-02-19
WO2006074315A2 (en) 2006-07-13
US7560596B2 (en) 2009-07-14
US20060173186A1 (en) 2006-08-03
US20090287016A1 (en) 2009-11-19
CA2594307A1 (en) 2006-07-13
CA2594307C (en) 2013-07-30

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