JP5181154B2 - Multilayer solid electrolytic capacitor - Google Patents

Description

  The present invention relates to a multilayer solid electrolytic capacitor including a multilayer body in which a plurality of single plate capacitor elements are stacked.

  A solid electrolytic capacitor uses a valve action metal plate such as aluminum, tantalum, or niobium or a sintered body thereof as an anode portion, an oxide film layer formed on the surface of the anode portion as a dielectric, and a solid electrolyte on the surface of the oxide film layer. A cathode portion is formed by sequentially forming a layer, a carbon layer, and a silver layer. As this solid electrolyte layer, manganese dioxide, TCNQ complex, conductive polymer, etc. are generally known.

  In recent years, with the reduction in voltage and speed of CPUs used in computers and the like, when electric charges are supplied from a solid electrolytic capacitor to the CPU, the solid electrolytic capacitors are required to be charged / discharged at high speed, and low ESR, ESL It is an essential condition.

  As one method for realizing the low ESR and ESL, a multilayer solid electrolytic capacitor in which a plurality of single plate capacitor elements C as shown in FIG. 1 are stacked is widely used. This multilayer solid electrolytic capacitor has a plurality of single-plate capacitor elements C each having an anode part P, a cathode part N, a carbon layer K, and a masking layer M for insulating between the cathode part N and the anode part P. Each anode part P is joined to each other and connected to the anode terminal PL indicated by a dotted line, each cathode part N is joined to each other through the conductive paste R, and the lowermost surface thereof is joined to the cathode terminal NL, The entire laminate is molded with an exterior resin to obtain a finished product.

  Functionally, the entire valve action metal plate (or a sintered plate made of valve action metal powder) is the anode, but for the sake of convenience of explanation in this specification, the exposed portion of the valve action metal plate is the anode part. The portion of the solid electrolyte layer, the carbon layer, and the silver layer formed on the surface of the other valve action metal plate was indicated as a cathode portion N.

  In this multilayer solid electrolytic capacitor, as shown in FIG. 1, since the solid electrolyte layer, the carbon layer, and the silver layer are formed in the cathode portion N, the thickness is slightly larger than that of the anode portion P. For this reason, when the anode part P is pressure-welded by resistance welding or the like, the interlayer of the cathode part N slightly expands and the conductivity between the cathode parts N deteriorates. In order to solve this, usually in this type of multilayer solid electrolytic capacitor, the entire end face of the cathode part N of the laminate is additionally formed with a conductive paste such as silver, and each cathode part N The connection resistance between them is reduced (see, for example, Patent Document 1). In order to form an additional conductive coating layer using this conductive paste, in the laminate as shown in FIG. 1, after laminating each single plate capacitor element C, the anode part P and the cathode part N are respectively connected to the anode terminal PL. -Before joining to the cathode terminal NL, the anode part P of the laminate is suspended upward and only the cathode part N is immersed in a bath of conductive paste in which silver or the like is dissolved. A method of applying a conductive paste over the entire surface is employed.

  By this method, an additional conductive coating layer made of a conductive paste is formed on the cathode portion N, and the conductive paste penetrates between the cathode portions N at the same time. Greatly improved and lowers ESR. In this case, of course, since the anode part P needs to be completely insulated from the cathode part N, the anode part P is not immersed in the conductive paste bath so that the conductive paste does not adhere.

  Also, in this type of multilayer solid electrolytic capacitor, when laminating each single plate capacitor element in order to achieve lower ESR and ESL, lamination is made so that the protruding direction of the anode part is alternately opposite about the cathode part. However, a multi-terminal multilayer solid electrolytic capacitor in which the anode potential is taken out from both the left and right sides has been developed and put into practical use (for example, see Patent Document 2).

  In this multi-terminal structure solid electrolytic capacitor, in addition to the three-terminal structure in which the anode potential is taken out from the left and right sides and the cathode potential is taken out from the center as described above, the anode portion of the single plate capacitor element is centered on the cathode portion. Also known is a five-terminal structure in which the layers are laminated 90 ° apart from each other (the anode branches in the front, rear, left and right directions). By adopting such a multi-terminal structure, even if the number of stacked layers increases corresponding to the increase in capacity, the ESR / ESL value can be further improved by the magnetic field canceling effect.

  However, this multi-terminal structure solid electrolytic capacitor has anode portions on the left and right sides, so that the conductive coating layer on the peripheral surface of the multilayer body is immersed in the conductive paste tank as described above. Therefore, it is difficult to form only on the peripheral surface of the cathode portion. Therefore, the conductive coating layer in such a case is usually applied by spraying a conductive paste with a syringe having an air dispenser connected to the side surface of each cathode portion.

  2 and 3 show a laminate of a multilayer solid electrolytic capacitor having a three-terminal structure. FIG. 2 is a perspective view, and FIG. 3 is an enlarged sectional view taken along line YY ′ of FIG. In each single plate capacitor element C1 to C4 of FIG. 2, P1 to P4 are anode portions, N1 to N4 are cathode portions, K is a carbon layer, and M is a masking layer for insulating between the cathode portion and the anode portion. Indicates. In FIG. 3, 1 is a valve action metal plate, 2 is an oxide film layer, 3 is a solid electrolyte layer, 4 is a carbon layer, and 5 is a silver layer for extracting a cathode potential. Reference numeral 6 denotes a conductive paste for joining the cathode portions and ensuring electrical conduction, and these are formed on the single plate capacitor elements C1 to C4 in the process of manufacturing the single plate capacitor elements. . Reference numeral 7 denotes a conductive coating layer formed on the side surface of the laminated body after the single plate capacitor elements C1 to C4 are laminated, and is formed by spraying a conductive paste.

  However, according to the experiments by the present inventors, when a conductive paste is sprayed on the side surfaces of the laminated body on the cathode portions N1 to N4 side in order to form the conductive coating layer 7, between the cathode portions N1 to N4. Before the conductive paste permeates, it flows from the side surface of the laminate and falls, so that the amount of the conductive paste entering between the cathode portions N1 to N4 becomes insufficient, and the conductive property between the cathode portions N1 to N4 is not sufficient. It has been found that the improvement cannot be sufficiently achieved and an effective ESR reduction cannot be expected. That is, as can be seen from FIG. 3, it is desirable that the conductive paste enters as much as possible into the gap g between the respective cathode portions N1 to N4, but in most cases, only a small portion enters 7 '. Therefore, even if the conductive coating layer 7 is additionally formed by spending time and effort, the expected effect as described above cannot be obtained.

  As a result of further experiments, the present inventor has found that the lateral widths x1 to x4 of the cathode portions N1 to N4 of the single-plate capacitor elements C1 to C4 are narrower as the elements stacked on top thereof, as shown in FIGS. The side surface of the laminated body is formed in a stepped shape, and the conductive paste is made to enter a large amount into the gap g between the cathode portions N1 to N4 as in 8 'to realize ESR reduction. (For example, refer to Patent Document 3). However, this method has a problem in that the capacitance of the capacitor is reduced because the area of the cathode portion of the single-plate capacitor element is reduced.

JP 2004-281515 A JP 2007-1116064 A Japanese Patent Application No. 2008-017731

  The present invention has been conceived based on the above circumstances, and in a multilayer solid electrolytic capacitor, the conductivity between the cathode portions of the laminated single plate capacitor elements is further improved, and the capacitance is reduced. The main problem is to provide a multilayer solid electrolytic capacitor having a novel structure that enables further reduction of ESR without significant reduction.

  In order to solve the above problems, the present invention employs the following technical means.

  A multilayer solid electrolytic capacitor according to the present invention is a multilayer solid electrolytic capacitor provided with a laminate formed by laminating a plurality of single plate capacitor elements each having an anode portion on one side and a cathode portion on the other side. The concave portion formed on the side surface on the cathode portion side of the single plate capacitor element and penetrating in the stacking direction is different from the two or more single plate capacitor elements stacked in succession. By this, it is characterized by including the level | step-difference part formed in a part of side surface of the said laminated body, and the electroconductive coating layer formed between the said level | step-difference part and the said cathode part.

  According to this configuration, in the multilayer solid electrolytic capacitor according to the present invention, the step portion is formed on a part of the side surface of the multilayer body by making the sizes of the recesses different from each other, and thus the area of the cathode portion is reduced. In addition, the conductive paste for forming the conductive coating layer is prevented from flowing down and the conductive paste can easily enter between the cathode portions of the laminated single-plate capacitor elements. For this reason, the connection resistance between the cathode portions is reduced, and the ESR can be reduced without lowering the capacitance.

  Furthermore, in the above-described configuration, the present invention provides the single plate capacitor element, wherein a plurality of the single plate capacitor elements are stacked so that the protruding directions of the anode portions are alternately opposite, and the recess is the side surface on the cathode portion side. It is formed on a side surface parallel to the protruding direction of the anode part.

  According to this configuration, an additional conductive coating layer can be easily formed even in a multilayer solid electrolytic capacitor having a three-terminal structure in which it is difficult to form a conductive coating layer. For this reason, the connection resistance between the cathode portions is reduced, and the ESR can be reduced without lowering the capacitance.

  A multilayer solid electrolytic capacitor according to the present invention includes a multilayer solid body including a multilayer body in which a plurality of single plate capacitor elements each having an anode portion at both ends and a cathode portion formed between the anode portions at both ends are stacked. An electrolytic capacitor, wherein one side anode terminal and the other side anode terminal electrically connected to the anode part protruding from both ends of the laminated body, and the one side anode terminal and the other side anode terminal are electrically connected A connecting portion that is electrically connected, a cathode terminal that is electrically connected to a cathode body composed of the cathode portions of the plurality of capacitor elements, and is spaced apart from the connecting portion, and the connecting portion and the cathode terminal A laminate formed on a side surface of the single plate capacitor element on the cathode portion side, further including an insulator disposed over the layered body side surface of the connecting portion and the cathode terminal so as to cover the gap. Recessed through the direction A step portion formed on a part of a side surface of the multilayer body by making the sizes of the concave portions different from each other in two or more single-plate capacitor elements that are successively stacked; and And a conductive coating layer formed between the cathode portions.

  Furthermore, the present invention is such that, in the above configuration, the concave portion is formed so as to be positioned on the same straight line extending in the stacking direction when the single plate capacitor elements are stacked, and the upper layer is separated from the lower single plate capacitor element. The single plate capacitor element is gradually increased toward the single plate capacitor element.

  According to this configuration, the conductive coating layer can be easily formed without greatly changing the spraying direction of the conductive paste and the like.

  Furthermore, the present invention is characterized in that, in the above-mentioned configuration, at least one set of the concave portions is formed at positions facing each other on the side surface on the cathode portion side of the single plate capacitor element.

  According to this configuration, the conductive paste can easily enter between the cathode portions of the single plate capacitor element, and the conductivity between the cathode portions of the single plate capacitor element can be further improved.

  Furthermore, in the present invention, when the above configuration is viewed in plan, the ratio of the area of the recess is formed to be in a range of 0.6 to 11.0% with respect to the area of the single plate capacitor element. It is characterized by being.

  According to this configuration, since the lower limit of the ratio of the area of the recess to the area of the single-plate capacitor element is 0.6%, it becomes easy to discharge and apply the conductive paste in the recess. Since the conductive paste easily enters between the cathode terminals, the ESR can be reduced. On the other hand, since the upper limit of this ratio is 11.0%, it is possible to more surely suppress the decrease in capacitance due to the decrease in the area of the cathode portion.

  According to the multilayer solid electrolytic capacitor of the present invention, since the conductive paste easily enters between the cathode portions of the laminated single plate capacitor elements, the connection resistance between the cathode portions is reduced, and the capacitance is not lowered. , Low ESR can be realized.

It is a perspective view which shows the conventional multilayer solid electrolytic capacitor. It is a perspective view which shows the laminated body of the lamination type solid electrolytic capacitor of the conventional 3 terminal structure (comparative example). It is an expanded sectional view in the YY 'line of FIG. It is a perspective view which shows the laminated body of the multilayer solid electrolytic capacitor of the conventional (terminal example) 3 terminal structure. It is an expanded sectional view in the YY 'line of FIG. It is a top view which shows the single plate capacitor | condenser element which concerns on the Example of this invention. It is a perspective view which shows the laminated body which concerns on the Example of this invention. It is an expanded sectional view in the Y-Y 'line of FIG. 1 is a perspective view showing a multilayer solid electrolytic capacitor according to an embodiment of the present invention. It is a perspective view which shows the multilayer solid electrolytic capacitor which concerns on the modification 1 of this invention. It is a perspective view which shows the multilayer solid electrolytic capacitor which concerns on the modification 2 of this invention. It is a perspective view which shows the multilayer solid electrolytic capacitor which concerns on the modification 3 of this invention. It is an expanded sectional view which shows the multilayer solid electrolytic capacitor which concerns on the modification 4 of this invention. It is a top view which shows the terminal shape of the multilayer solid electrolytic capacitor which concerns on the modification 5 of this invention.

  Hereinafter, preferred embodiments of the present invention will be described with reference to the drawings.

[Example]
FIGS. 6 to 9 are explanatory views of a structure of a four-layered solid electrolytic capacitor having a three-terminal structure according to the present invention. FIG. 6 is a plan view showing a single plate capacitor element, and FIG. FIG. 8 is a perspective view, and FIG. 8 is a sectional view taken along line YY ′ of FIG. FIG. 9 is a perspective view showing a multilayer solid electrolytic capacitor in which each electrode of the multilayer body is bonded to a terminal plate (lead frame) and sheathed with an exterior resin. 6 to 9, the properties of the coating layer of each single-plate capacitor element are the same as those of the conventional multilayer solid electrolytic capacitor, so that each layer will be described with the same reference numeral.

  As shown in FIG. 6, a single plate capacitor element C according to the present invention is provided with an anode portion P provided on one side of a valve metal (an aluminum foil in this embodiment) subjected to an etching process, and on the other side. The cathode part N, the carbon layer K, the masking layer M for insulating the cathode part N and the anode part P, and the side face parallel to the protruding direction of the anode part P among the side faces on the cathode part N side It has the recessed part 10 provided so that it might oppose. In addition, the recessed part 10 is penetrated with respect to the lamination direction, and a magnitude | size changes with each single plate capacitor | condenser elements C1-C4.

  Then, as shown in FIG. 7, the single plate capacitor elements C1 to C4 are laminated so that the protruding directions of the anode portions P1 to P4 are alternately opposite to each other, and are formed on the single plate capacitor elements C1 to C4. The stacked body is manufactured by stacking so that the recessed portions 10 are positioned on the same straight line extending in the stacking direction. Further, in this embodiment, the single plate capacitor elements C1 to C4 are stacked so that the size of the recess 10 changes stepwise. Specifically, the single plate capacitor element C1 having the smallest concave portion 10 in the lowermost layer, the single plate capacitor element C2 having the concave portion 10 having a slightly larger size formed thereon, and then the larger size concave portion. The single-plate capacitor element C3 having 10 formed thereon is finally laminated with the single-plate capacitor element C4 having the concave portion 10 having the largest size.

  Explaining this on the basis of the enlarged sectional view shown in FIG. 8, each single plate capacitor element C <b> 1 to C <b> 4 includes an aluminum foil 1, an oxide film layer 2 formed on the surface of the aluminum foil 1, and an oxide film layer 2. The cathode part N which consists of the solid electrolyte layer 3, the carbon layer 4, and the silver layer 5 formed in the surface is comprised, and each cathode part N1-N4 is joined via the electrically conductive paste 6. FIG. In addition, the size of the recess 10 formed on the side surface of each single plate capacitor element C1 to C4 on the cathode part N1 to N4 side is as described above from the lowermost single plate capacitor element C1 to the uppermost single plate capacitor. Since the width is gradually increased toward the element C4, the widths w1 to w4 of each of the single-plate capacitor elements C1 to C4 in the portion where the recess 10 is formed are changed from the single-layer capacitor element C1 of the lowermost layer to the single-layer capacitor element C1 of the uppermost layer. It narrows stepwise toward the plate capacitor element C4.

  In this embodiment, each single-plate capacitor element C1 to C4 has a length l = 4.5 mm, a width x = 4.5 mm, a thickness d = 0.2 mm, and the recess 10 has a square shape. The length D of one side of the recess 10 is D1 = 0.25 mm, D2 = 0.50 mm, D3 = 0.75 mm, and D4 = 1.00 mm in order from the lowermost single-plate capacitor element C1. In addition, the width w of each single-plate capacitor element C1 to C4 in the portion where the recess 10 is formed is w1 = 4.0 mm, w2 = 3.5 mm, w3 = 3.0 mm, w4 = 2.5 mm. Yes.

  For this reason, by laminating the single plate capacitor elements C1 to C4 symmetrically with respect to the center line A, a part of the side surface of the multilayer body corresponding to the side surface on the cathode portion N1 to N4 side of each single plate capacitor element C1 to C4. In this case, a stepped step S is formed.

  An additional conductive coating layer 9 is formed in the recess 10 and on the stepped portion S of each single plate capacitor element C1 to C4. The conductive coating layer 9 is formed by discharging, applying and curing a silver conductive paste from the direction of the arrow with a syringe connected to an air dispenser.

  In this case, if the stepped portion S is provided on the side surface of the laminate, the discharged silver conductive paste temporarily stays at the stepped portion S, and each cathode portion N1 as indicated by 9 'therebetween. It penetrates deeply into the gap between N4. Therefore, the conductivity of the gap is greatly improved. In addition, the adhesiveness of the paste to the side surface of the laminate itself is further improved because there is no risk of flowing down as in the case of the conventional flush side surface.

  Also, in this type of multi-terminal laminate, the upper and lower anode parts protrude from the rear end face (the end face opposite to the anode part) of the cathode part, so that a conductive coating layer is directly applied to this rear end face. Although it is difficult to form, in the multilayer solid electrolytic capacitor according to the present invention, the conductive paste penetrates sufficiently deeply into the gaps between the cathode portions N1 to N4. As a result, this results after the cathode portions N1 to N4. As a result, the conductive coating layer 9 is formed more in this portion than in the conventional method. With the above synergistic effect, the multilayer solid electrolytic capacitor according to the present invention can achieve a significant reduction in ESR.

  As shown in FIG. 9, the multilayer solid electrolytic capacitor according to the present invention has left and right anode terminals (anode potential extraction terminal plates) PL, PL on anode portions P1, P3 and P2, P4 on both sides of the laminate. 'Is electrically connected by resistance welding or the like, and the cathode terminal (cathode potential extraction terminal plate) NL is connected to the lowermost cathode portion N1 via a conductive paste. ) 11 and exterior. The multilayer solid electrolytic capacitor according to the present invention has a rated voltage of 2.5 V and a rated capacity of 220 μF.

[Conventional example]
The conventional example is a four-layered solid electrolytic capacitor having a three-terminal structure shown in FIGS. 4 and 5, and each single-plate capacitor element C1 to C4 has a thickness d = 0.2 mm as in this embodiment. The length l = 4.5 mm. The width x of the single plate capacitor elements C1 to C4 was set to x1 = 4.5 mm, x2 = 4.0 mm, x3 = 3.5 mm, and x4 = 3.0 mm in order from the single-plate capacitor element C1 in the lowermost layer. Then, conductive silver paste is discharged and applied to the side surfaces of the laminated body of the single plate capacitor elements C1 to C4 in the same manner as in the present embodiment to form the conductive coating layer 8, and each of the anode portions P1 to P4, and After connecting each cathode part N1-N4 to each terminal, it is the finished product which was entirely packaged with the same exterior resin 11 as in this embodiment.

[Comparative example]
The comparative example is a four-layered solid electrolytic capacitor having a three-terminal structure shown in FIGS. 2 and 3, and each single-plate capacitor element C1 to C4 has a thickness d = 0.2 mm, as in this example. The length l was set to 4.5 mm, and the widths x were all set to x = 4.5 mm. After the anode parts P1 to P4 and the cathode parts N1 to N4 are connected to the respective terminals without forming an additional conductive coating layer on the side surface of the laminate, the entire exterior resin 11 is the same as that of the example. It is a finished product that is exteriorized with.

  Table 1 below shows 100 stacked solid electrolytic capacitors of the above-described examples, conventional examples, and comparative examples, and the ESR / capacitance performance of these capacitors was measured, and the average values of the respective data were compared. It is shown.

  As can be seen from Table 1, the multilayer solid electrolytic capacitor of the conventional example can greatly improve the ESR, but the capacitance is greatly reduced as compared with the multilayer solid electrolytic capacitor of the comparative example having the same rating. However, the multilayer solid electrolytic capacitor of the example can greatly improve the ESR without substantially reducing the capacitance. This reduction in ESR is achieved by forming the stepped step portion S on a part of both side surfaces of the laminate, thereby preventing the wasteful flow of the conductive paste when the conductive coating layer 9 is formed. This is because the conductive coating layer 9 can be effectively formed on the side surfaces and the conductive paste easily enters between the cathode portions N1 to N4, thereby reducing the connection resistance between the cathode portions N1 to N4. is there.

  In addition, the reduction in the electrostatic capacity is suppressed by forming the stepped portion S only in a part where the conductive coating layer 9 is formed, instead of making all the side surfaces of the laminated body stepped. This is because the reduction in the area of the cathode portions N1 to N4 of the elements C1 to C4 can be suppressed.

  Table 2 below shows a comparison of the areas in the plan view of the single plate capacitor elements C1 to C4 of the above example and the conventional example, and the plane of the recess 10 with respect to the area in the plan view of the single plate capacitor elements C1 to C4 of the above example. It shows the ratio of area in view.

  As can be seen from Table 2, in the conventional multilayer solid electrolytic capacitor, the area of the single plate capacitor element is greatly reduced from the lower layer (C1) to the upper layer (C4) as compared with the multilayer solid electrolytic capacitor of the example. However, in the multilayer solid electrolytic capacitor of the example, the area of the single plate capacitor element is hardly reduced. Thereby, the multilayer solid electrolytic capacitor of the embodiment can suppress a decrease in capacitance. Further, when the multilayer solid electrolytic capacitor of the example is viewed in plan, the ratio of the area of the recess to the area of the single plate capacitor element is 0.6% which is the lowest in the single plate capacitor element C1 of the lowermost layer, and the uppermost layer In the single plate capacitor element C4, the highest is 11.0%. When this ratio is low, it becomes difficult to discharge and apply the conductive paste into the recess 10 to form the conductive coating layer 8, and the conductive portion between the cathode portions N1 to N4 or between the cathode portion N1 and the cathode terminal NL. Since the paste becomes difficult to enter, the ESR becomes high. On the other hand, if this ratio is high, the capacitance decreases. However, in this embodiment, since the concave portion 10 is formed between 0.6 and 11.0%, it is possible to more reliably achieve both low ESR and securing of capacitance.

  Although the preferred embodiments of the present invention have been described above, the present invention is not limited to these configurations.

[Modification 1]
For example, in the above embodiment, the shape of the concave portion 10 is a square. However, the shape is not limited to this, and other shapes such as a semicircle and a triangle may be used, and the step portion S may be formed when stacked. The same effect can be obtained. FIG. 10 is a perspective view of a multilayer solid electrolytic capacitor in which the semicircular concave portions 12 are formed in the single plate capacitor elements C1 to C4. Except that the semicircular recess 12 is formed, it is the same as the multilayer solid electrolytic capacitor according to the present embodiment. Similar to the embodiment, the size of the semicircular recess 12 is increased stepwise from the lowermost single-plate capacitor element C1 toward the uppermost single-plate capacitor element C4, thereby forming a stepped portion. Has been.

[Modification 2]
In the above embodiment, the recesses 10 are present on both side surfaces of the single-plate capacitor element, but they may be provided on one side, and the position and number of the recesses are not limited to those in the embodiment and can be arbitrarily set. FIG. 11 is a perspective view of a multilayer solid electrolytic capacitor in which a plurality of concave portions 13 facing each other are formed on both side surfaces of each single plate capacitor element C1 to C4. Each of the single plate capacitor elements C1 to C4 is formed with a total of six recesses 13, and the size of each recess 13 is smaller than that of the recess 10 of the embodiment. In addition, the size of the concave portion 13 increases stepwise from the lowermost single-plate capacitor element C1 toward the uppermost single-plate capacitor element C4, thereby forming a stepped portion.

[Modification 3]
In the above-described embodiment, a three-terminal stacked solid electrolytic capacitor was produced, but the same effect can be obtained with a two-terminal stacked solid electrolytic capacitor. FIG. 12 is a perspective view of a multilayer solid electrolytic capacitor having a two-terminal structure in which concave portions 14 facing each other are formed on both side surfaces of each single-plate capacitor element. The size of each of the recesses 14 increases stepwise from the lowermost single-plate capacitor element toward the uppermost single-plate capacitor element, thereby forming a stepped portion. In the case of a multilayer solid electrolytic capacitor having a two-terminal structure, a concave portion may be formed on the end surface facing the anode portion P, or a concave portion may be formed in a corner portion on the cathode portion N side of the single plate capacitor. Also good.

[Modification 4]
In the above embodiment, the size of the concave portion 10 is increased stepwise from the lowermost single-plate capacitor element C1 toward the uppermost single-plate capacitor element C4. However, the present invention is not limited to this. May be alternately stacked in two types. FIG. 13 is a cross-sectional view of a stacked solid electrolytic capacitor that is stacked so that the size of the recesses is alternated in size. The size of each recess formed on the side surface of each single plate capacitor element C1 to C4 on the cathode part N1 to N4 side is small in the single plate capacitor elements C1 and C3, and large in the single plate capacitor elements C2 and C4. Yes. For this reason, by laminating the single plate capacitor elements C1 to C4, a stepped portion S on the staircase is generated in a part of the side surface of the multilayer body. In the stepped portion S formed in a step shape, an additional conductive coating layer 9 is formed by discharging, applying, and curing a silver conductive paste with a syringe connected to an air dispenser. In this case, similarly to the embodiment, the discharged silver conductive paste stays temporarily in the stepped portion S, and deeply in the gaps between the cathode portions N1 to N4 as indicated by 9 '. Will get in. Therefore, the conductivity of the gap is greatly improved, and the adhesion of the paste to the side surface of the laminate itself is improved.

[Modification 5]
In the above embodiment, a single plate capacitor element having an anode part P on one side and a cathode part N on the other side is used, and anode terminals PL and PL ′ are provided on both sides of the laminate, and a cathode terminal NL is provided in the center part. However, a single plate capacitor element in which an anode part is formed at both ends and a cathode part is formed between the anode parts at both ends is used. Further, the shape of the terminal is, for example, as shown in FIG. ', And anode terminals PL and PL' are arranged on both sides thereof, and the anode terminals PL and PL 'may be bridged by a connecting portion 15 made of a conductive material of the same material as the terminals. Good. In order to prevent the conductive paste from adhering to the side surface and the bottom surface of the connecting portion 15, the insulator 16 covers the connecting portion 15 and the cathode terminal NL so as to cover the gap between the connecting portion 15 and the cathode terminals NL and NL ′. , NL ′ are disposed across the surface of the laminate side.

  Moreover, in the said Example and the said modification, although aluminum (Al) was used for the valve action metal plate 1, the element which formed tantalum (Ta), niobium (Nb), titanium (Ti) etc. in the sheet form, The same effect can be obtained when an element obtained by compressing and sintering these metal powders into a sheet is used. The conductive coating layer 9 includes a conductive filler made of silver (Ag), gold (Au), copper (Cu), carbon, and the like, and a binder resin made of epoxy resin, acrylic resin, rubber resin, and the like. A combination of these can be used. Moreover, for the solid electrolyte layer 3 to be the cathode portion N, a conductive polymer such as polypyrrole or polyaniline may be used, and the same effect can be obtained with a manganese dioxide layer.

  Further, in the above example, the single plate capacitor element C having the anode part P on one side and the cathode part N on the other side was used, but the cathode part was formed between the anode part at both ends and the anode parts at both ends. Even when a single plate capacitor element was used, the same effect as in the above example could be obtained.

DESCRIPTION OF SYMBOLS 1 Valve action metal plate 2 Oxide film layer 3 Solid electrolyte layer 4 Carbon layer 5 Silver layer 6 Conductive paste 7, 8, 9 Conductive coating layer 10, 12, 13, 14 Recess 11 Exterior resin 15 Connection part 16 Insulator C , C1 to C4 Single plate capacitor element P, P1 to P4 Anode portion N, N1 to N4 Cathode portion K Carbon layer M Masking layer g Clearance between cathode portions S Stepped portion

Claims (6)

A multilayer solid electrolytic capacitor comprising a laminate formed by laminating a plurality of single plate capacitor elements each having an anode portion on one side and a cathode portion on the other side,
A concave portion penetrating in the stacking direction formed on the side surface of the single plate capacitor element on the cathode portion side;
A stepped portion formed on a part of the side surface of the multilayer body by making the size of the concave portion different from each other by two or more single-plate capacitor elements that are successively stacked, and
A conductive coating layer formed between the stepped portion and the cathode portion;
A multilayer solid electrolytic capacitor comprising: The single plate capacitor element is laminated in a plurality so that the protruding direction of the anode portion is alternately opposite,
2. The multilayer solid electrolytic capacitor according to claim 1, wherein the recess is formed on a side surface parallel to a protruding direction of the anode portion among side surfaces on the cathode portion side. A multilayer solid electrolytic capacitor comprising a laminate formed by laminating a plurality of single plate capacitor elements each having an anode portion at both ends and a cathode portion formed between the anode portions at both ends,
One-side anode terminal electrically connected to the anode portion protruding from both sides of the laminate,
The other side anode terminal;
A connecting portion for electrically connecting the one side anode terminal and the other side anode terminal;
A cathode terminal that is electrically connected to a cathode body composed of cathode portions of the plurality of capacitor elements and is spaced apart from the connecting portion;
An insulator disposed across a surface of the connection portion and the cathode terminal on the laminate side so as to cover a gap between the connection portion and the cathode terminal, and further, the cathode of the single plate capacitor element A concave portion penetrating in the stacking direction formed on the side surface of the portion side
A stepped portion formed on a part of the side surface of the multilayer body by making the size of the concave portion different from each other by two or more single-plate capacitor elements that are successively stacked, and
A conductive coating layer formed between the stepped portion and the cathode portion;
A multilayer solid electrolytic capacitor comprising:   The concave portions are formed so as to be positioned on the same straight line extending in the stacking direction when the single plate capacitor elements are stacked, from the lower single plate capacitor element toward the upper single plate capacitor element. The multilayer solid electrolytic capacitor according to claim 1, wherein the multilayer solid electrolytic capacitor increases in a stepwise manner.   5. The multilayer solid electrolytic capacitor according to claim 1, wherein at least one set of the concave portions is formed at positions facing each other on the side surface on the cathode portion side of the single plate capacitor element. .   The concave portion is formed such that a ratio of an area of the concave portion in plan view to an area of the single plate capacitor element in plan view is in a range of 0.6 to 11.0%. Item 6. The multilayer solid electrolytic capacitor according to any one of Items 1 to 5.

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