JP5095942B2 - 制御したラジカル重合用のS−(α,α’−二置換−α”−酢酸)置換ジチオカーボネート誘導体、方法およびそれから製造したポリマー - Google Patents

制御したラジカル重合用のS−(α,α’−二置換−α”−酢酸)置換ジチオカーボネート誘導体、方法およびそれから製造したポリマー Download PDF

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JP5095942B2
JP5095942B2 JP2005501651A JP2005501651A JP5095942B2 JP 5095942 B2 JP5095942 B2 JP 5095942B2 JP 2005501651 A JP2005501651 A JP 2005501651A JP 2005501651 A JP2005501651 A JP 2005501651A JP 5095942 B2 JP5095942 B2 JP 5095942B2
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carbon atoms
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JP2006503971A5 (enExample
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ジョン タ−ユアン ライ,
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ルブリゾル アドバンスド マテリアルズ, インコーポレイテッド
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D295/00Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/16Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms
    • C07D295/18Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms acylated on ring nitrogen atoms by radicals derived from carboxylic acids, or sulfur or nitrogen analogues thereof
    • C07D295/194Radicals derived from thio- or thiono carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C329/00Thiocarbonic acids; Halides, esters or anhydrides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C329/00Thiocarbonic acids; Halides, esters or anhydrides thereof
    • C07C329/12Dithiocarbonic acids; Derivatives thereof
    • C07C329/14Esters of dithiocarbonic acids
    • C07C329/16Esters of dithiocarbonic acids having sulfur atoms of dithiocarbonic groups bound to acyclic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C329/00Thiocarbonic acids; Halides, esters or anhydrides thereof
    • C07C329/12Dithiocarbonic acids; Derivatives thereof
    • C07C329/14Esters of dithiocarbonic acids
    • C07C329/18Esters of dithiocarbonic acids having sulfur atoms of dithiocarbonic groups bound to carbon atoms of rings other than six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C333/00Derivatives of thiocarbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C333/14Dithiocarbamic acids; Derivatives thereof
    • C07C333/18Esters of dithiocarbamic acids
    • C07C333/20Esters of dithiocarbamic acids having nitrogen atoms of dithiocarbamate groups bound to hydrogen atoms or to acyclic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C333/00Derivatives of thiocarbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
    • C07C333/14Dithiocarbamic acids; Derivatives thereof
    • C07C333/18Esters of dithiocarbamic acids
    • C07C333/24Esters of dithiocarbamic acids having nitrogen atoms of dithiocarbamate groups bound to carbon atoms of six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10Esters
    • C08F20/12Esters of monohydric alcohols or phenols
    • C08F20/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F20/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/28Polythiocarbonates

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2005501651A 2002-10-23 2003-10-21 制御したラジカル重合用のS−(α,α’−二置換−α”−酢酸)置換ジチオカーボネート誘導体、方法およびそれから製造したポリマー Expired - Fee Related JP5095942B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US10/278,335 2002-10-23
US10/278,335 US7205368B2 (en) 2000-02-16 2002-10-23 S-(α, α′-disubstituted-α′ ′-acetic acid) substituted dithiocarbonate derivatives for controlled radical polymerizations, process and polymers made therefrom
US10/681,679 US7335788B2 (en) 2000-02-16 2003-10-08 S-(α, α′-disubstituted-α″-acetic acid) substituted dithiocarbonate derivatives for controlled radical polymerizations, process and polymers made therefrom
US10/681,679 2003-10-08
PCT/US2003/033476 WO2004037780A1 (en) 2002-10-23 2003-10-21 S-(a, a’ -DISUBSTITUTED-a” -ACETIC ACID) SUBSTITUTED DITHIOCARBONATE DERIVATIVES FOR CONTROLLED RADICAL POLYMERIZATIONS, PROCESS AND POLYMERS MADE THEREFROM

Publications (3)

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JP2006503971A JP2006503971A (ja) 2006-02-02
JP2006503971A5 JP2006503971A5 (enExample) 2007-01-25
JP5095942B2 true JP5095942B2 (ja) 2012-12-12

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JP2005501651A Expired - Fee Related JP5095942B2 (ja) 2002-10-23 2003-10-21 制御したラジカル重合用のS−(α,α’−二置換−α”−酢酸)置換ジチオカーボネート誘導体、方法およびそれから製造したポリマー

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US (1) US7335788B2 (enExample)
EP (1) EP1554241B1 (enExample)
JP (1) JP5095942B2 (enExample)
AU (1) AU2003280005A1 (enExample)
WO (1) WO2004037780A1 (enExample)

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US7495050B2 (en) * 2000-02-16 2009-02-24 Lubrizol Advanced Materials, Inc. Associative thickeners for aqueous systems
US7557235B2 (en) 2000-02-16 2009-07-07 Lubrizol Advanced Materials, Inc. Hydroxyl-terminated thiocarbonate containing compounds, polymers, and copolymers, and polyurethanes and urethane acrylics made therefrom
FR2868072B1 (fr) * 2004-07-28 2006-06-30 Coatex Soc Par Actions Simplif Polymeres obtenus par l'utilisation de composes soufres comme agents de transfert pour la polymerisation radicalaire controlee de l'acide acrylique et leurs applications
US8137754B2 (en) * 2004-08-06 2012-03-20 Lubrizol Advanced Materials, Inc. Hydroxyl-terminated thiocarbonate containing compounds, polymers, and copolymers, and polyurethanes and urethane acrylics made therefrom
WO2006020281A1 (en) 2004-08-06 2006-02-23 Noveon, Inc. Polyurethanes and urethane acrylics made from hydroxyl-terminated thiocarbonate containing compounds
WO2006023790A1 (en) * 2004-08-20 2006-03-02 Noveon, Inc. Curable thiocarbonate compounds and compositions
US7671152B2 (en) * 2005-12-22 2010-03-02 The Goodyear Tire & Rubber Company Surfactantless synthesis of amphiphilic cationic block copolymers
US20080153982A1 (en) * 2006-12-20 2008-06-26 John Ta-Yuan Lai Vinyl-Thiocarbonate and Polyol Containing Block Copolymers
WO2009012202A1 (en) 2007-07-13 2009-01-22 Kemira Oyj Mineral dispersants and methods for preparing mineral slurries using the same
CN104059006A (zh) * 2007-08-09 2014-09-24 卢布里佐尔公司 制备取代的三硫代碳酸酯衍生物的方法
FR2931154B1 (fr) * 2008-05-14 2011-04-08 Univ Paris Curie Copolymere amphiphile a blocs, procede pour sa preparation
NZ594255A (en) * 2009-01-23 2013-09-27 Commw Scient Ind Res Org RAFT polymerisation
FR2962441A1 (fr) 2010-07-08 2012-01-13 Arkema France Agents raft a odeur amelioree et polymeres a odeur amelioree obtenus a l'aide de ces agents
CN103880995B (zh) * 2014-04-10 2016-09-28 苏州大学 一种活性可控自由基聚合的方法和乙烯基聚合物
CN106631882B (zh) * 2016-09-01 2020-02-07 吕梁学院 多氨类二硫代甲酸亚硫酸盐衍生物及其制备方法和应用
CN111378366B (zh) * 2018-12-27 2022-11-18 安集微电子(上海)有限公司 一种化学机械抛光液及其应用
CN119176890B (zh) * 2024-11-19 2025-03-21 湖南福尔程科技股份有限公司 乳液丁苯橡胶聚合体系的环保型终止剂、预制剂、制备及应用

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Publication number Publication date
US20040073056A1 (en) 2004-04-15
EP1554241B1 (en) 2015-03-18
AU2003280005A1 (en) 2004-05-13
WO2004037780A1 (en) 2004-05-06
EP1554241A1 (en) 2005-07-20
US7335788B2 (en) 2008-02-26
JP2006503971A (ja) 2006-02-02

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