JP5087427B2 - Hard coating for cutting tools - Google Patents

Hard coating for cutting tools Download PDF

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JP5087427B2
JP5087427B2 JP2008048318A JP2008048318A JP5087427B2 JP 5087427 B2 JP5087427 B2 JP 5087427B2 JP 2008048318 A JP2008048318 A JP 2008048318A JP 2008048318 A JP2008048318 A JP 2008048318A JP 5087427 B2 JP5087427 B2 JP 5087427B2
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JP2009202300A (en
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彰 佐藤
和浩 川村
喬紀 山谷
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UNION TOOL Co
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本発明は、高硬度鋼の切削加工等に使用する工具に被覆する切削工具用硬質皮膜に関するものである。   TECHNICAL FIELD The present invention relates to a hard film for a cutting tool that covers a tool used for cutting of hard steel and the like.

従来、金属切削用工具に被覆する硬質耐摩耗皮膜としてTiN,TiCN若しくはTiAlNが使用されてきた。特に、特許文献1及び特許文献2に代表されるTiAlN系皮膜はTiNにAlを添加することで硬度と耐熱性を改良させたもので、耐摩耗性の良さから焼入れ鋼を含む鉄鋼材料を加工するための切削工具用硬質皮膜として広く用いられている。   Conventionally, TiN, TiCN, or TiAlN has been used as a hard wear-resistant coating for coating metal cutting tools. In particular, TiAlN-based coatings represented by Patent Document 1 and Patent Document 2 are improved in hardness and heat resistance by adding Al to TiN, and work on steel materials including hardened steel because of their good wear resistance. It is widely used as a hard coating for cutting tools.

しかしながら、近年ではさらに高硬度な材料の切削を実現するための工具が求められてきており、TiAlN系皮膜とTiSiN系皮膜とを積層させた特許文献3や特許文献4に開示されるような切削工具用硬質皮膜が提案されている。   However, in recent years, a tool for realizing cutting of a material with higher hardness has been demanded, and cutting as disclosed in Patent Document 3 and Patent Document 4 in which a TiAlN-based film and a TiSiN-based film are laminated. Hard coatings for tools have been proposed.

特開昭62−56565号公報JP-A 62-56565 特開平2−194159号公報Japanese Patent Laid-Open No. 2-194159 特許第3248897号公報Japanese Patent No. 3248897 特許第3248898号公報Japanese Patent No. 3248898

しかしながら、高速度鋼などに代表される高硬度焼入鋼の切削では、上記従来技術のSi含有多層皮膜でも耐摩耗性が充分とはいえず、さらに耐摩耗性能を上げた切削工具用硬質皮膜の開発が求められている。   However, in the cutting of high hardness hardened steel represented by high-speed steel, the hard coating for cutting tools with higher wear resistance is not sufficient even with the above-mentioned conventional Si-containing multilayer coating. Development is required.

本発明は、上述のような現状に鑑み、本発明者等が切削工具用硬質皮膜における皮膜組織、皮膜層構成及び皮膜組成について研究した結果、この皮膜組織、皮膜層構成及び皮膜組成を工夫することで上記課題を解決できるとの知見を得て完成したもので、従来の切削工具用硬質皮膜に比し高速度鋼などに代表される高硬度焼入鋼の切削における耐摩耗性が向上する極めて実用性に秀れた切削工具用硬質皮膜を提供するものである。   In view of the present situation as described above, the present inventors have studied the film structure, the film layer structure and the film composition in the hard film for cutting tools, and as a result, devised the film structure, the film layer structure and the film composition. As a result of the knowledge that the above-mentioned problems can be solved, the wear resistance in cutting of hardened steel represented by high-speed steel is improved compared to conventional hard coatings for cutting tools. The present invention provides a hard coating for a cutting tool that is extremely practical.

本発明の要旨を説明する。   The gist of the present invention will be described.

基材上に形成される切削工具用硬質皮膜であって、この硬質皮膜は第一皮膜層と第二皮膜層とが交互に各2層以上積層して成る多層皮膜層を含み、前記第一皮膜層は金属成分として少なくともAlとCrとを含み非金属成分としてNを含み不可避不純物を含む皮膜層であり、前記第二皮膜層は金属及び半金属成分として少なくともTiとSiとを含み非金属成分としてNを含み不可避不純物を含む皮膜層であり、前記第一皮膜層及び前記第二皮膜層の夫々一層当りの膜厚は1nm以上20nm以下に設定され、前記多層皮膜層を断面TEM法で観察したとき、前記第一皮膜層の成分と前記第二皮膜層の成分とが混在した組織を有する混在組織部が存在し、この混在組織部の面積が前記多層皮膜層の断面積の5%以上80%以下であることを特徴とする切削工具用硬質皮膜に係るものである。 A hard film for a cutting tool formed on a substrate, the hard film including a multilayer film layer in which two or more first film layers and second film layers are alternately laminated, coating layer is a coating layer contain inevitable impurities include N as a non-metal component and at least Al and Cr as metal components, non-metallic and at least Ti and Si the second coating layer is a metal and metalloid components A film layer containing N as an ingredient and containing inevitable impurities, the film thickness of each of the first film layer and the second film layer is set to 1 nm or more and 20 nm or less, and the multilayer film layer is formed by a cross-sectional TEM method. when viewed, the a component of the first coating layer and the component of the second coating layer is present mixed tissue section having a tissue mixed with 5% of the cross-sectional area of the area of the mixed tissue section the multilayer coating layer More than 80% Those of the hard film for a cutting tool to.

また、請求項1記載の切削工具用硬質皮膜において、前記第一皮膜層は金属及び半金属成分が原子%で、
Al(100−x−y−z)Cr(x)V(y)B(z)
ただし、20≦x≦40,2≦y≦15,2≦z≦15
と表され、前記第二皮膜層は金属及び半金属成分が原子%で、
Ti(100−v−w)Cr(v)Si(w)
ただし、5≦v≦30,5≦w≦30
と表されることを特徴とする切削工具用硬質皮膜に係るものである。
Further, in the hard film for a cutting tool according to claim 1, the first film layer has an atomic% metal and metalloid component,
Al (100-xyz) Cr (x) V (y) B (z)
However, 20 ≦ x ≦ 40, 2 ≦ y ≦ 15, 2 ≦ z ≦ 15
And the second coating layer is an atomic% metal and metalloid component,
Ti (100-vw) Cr (v) Si (w)
However, 5 ≦ v ≦ 30, 5 ≦ w ≦ 30
It is based on the hard film | membrane for cutting tools characterized by these.

また、請求項1,2いずれか1項に記載の切削工具用硬質皮膜において、前記基材と前記多層皮膜層との間には第三皮膜層が設けられ、この第三皮膜層の金属成分または金属成分及び半金属成分は前記第一皮膜層の金属成分または金属成分及び半金属成分と同一であることを特徴とする切削工具用硬質皮膜に係るものである。   The hard coating for a cutting tool according to any one of claims 1 and 2, wherein a third coating layer is provided between the base material and the multilayer coating layer, and the metal component of the third coating layer Alternatively, the metal component and the metalloid component are the same as the metal component or the metal component and the metalloid component of the first coating layer, and the hard coating for a cutting tool is characterized.

また、請求項1〜3いずれか1項に記載の切削工具用硬質皮膜において、前記基材直上には第四皮膜層が設けられ、この第四皮膜層はTiを主成分とする窒化物若しくは炭窒化物から成り、この第四皮膜層の膜厚は0.01μm〜0.5μmに設定されていることを特徴とする切削工具用硬質皮膜に係るものである。   Further, in the hard coating for a cutting tool according to any one of claims 1 to 3, a fourth coating layer is provided immediately above the base material, and the fourth coating layer is a nitride mainly composed of Ti or It is made of carbonitride, and the film thickness of the fourth coating layer is related to a hard coating for a cutting tool, which is set to 0.01 μm to 0.5 μm.

また、請求項1〜3いずれか1項に記載の切削工具用硬質皮膜において、前記基材直上には第四皮膜層が設けられ、この第四皮膜層はCrを主成分とする窒化物若しくは炭窒化物から成り、この第四皮膜層の膜厚は0.01μm〜0.5μmに設定されていることを特徴とする切削工具用硬質皮膜に係るものである。   Further, in the hard coating for a cutting tool according to any one of claims 1 to 3, a fourth coating layer is provided immediately above the base material, and the fourth coating layer is a nitride containing Cr as a main component or It is made of carbonitride, and the film thickness of the fourth coating layer is related to a hard coating for a cutting tool, which is set to 0.01 μm to 0.5 μm.

また、請求項1〜5いずれか1項に記載の切削工具用硬質皮膜において、前記多層皮膜層の表層側には第五皮膜層が設けられ、この第五皮膜層の金属成分及び半金属成分は前記第二皮膜層の金属成分及び半金属成分と同一であることを特徴とする切削工具用硬質皮膜に係るものである。   Further, in the hard film for a cutting tool according to any one of claims 1 to 5, a fifth film layer is provided on a surface layer side of the multilayer film layer, and a metal component and a semimetal component of the fifth film layer. Is the same as the metal component and the semi-metal component of the second coating layer, and relates to a hard coating for a cutting tool.

また、請求項1〜5いずれか1項に記載の切削工具用硬質皮膜において、前記多層皮膜層の表層側には第五皮膜層が設けられ、この第五皮膜層の金属成分または金属成分及び半金属成分は前記第一皮膜層の金属成分または金属成分及び半金属成分と同一であることを特徴とする切削工具用硬質皮膜に係るものである。   Further, in the hard film for a cutting tool according to any one of claims 1 to 5, a fifth film layer is provided on a surface layer side of the multilayer film layer, and the metal component or metal component of the fifth film layer and The metalloid component is the same as the metal component of the first coating layer or the metal component and the metalloid component.

また、請求項1〜7いずれか1項に記載の切削工具用硬質皮膜において、前記基材はWCを主成分とする硬質粒子とCoを主成分とする結合材からなる超硬合金であって、前記WC粒子の平均粒径が0.1μm〜2μmに設定され、前記Coの含有量が重量%で5〜15%に設定されたものであることを特徴とする切削工具用硬質皮膜に係るものである。   The hard film for a cutting tool according to any one of claims 1 to 7, wherein the base material is a cemented carbide composed of hard particles mainly containing WC and a binder mainly containing Co. According to the hard coating for a cutting tool, the average particle diameter of the WC particles is set to 0.1 μm to 2 μm, and the Co content is set to 5 to 15% by weight%. Is.

本発明は上述のように構成したから、第一皮膜層と第二皮膜層との層間密着性が高まり、それだけ従来の切削工具用硬質皮膜に比し高速度鋼などに代表される高硬度焼入鋼の切削における耐摩耗性が向上する極めて実用性に秀れた切削工具用硬質皮膜となる。   Since the present invention is configured as described above, the interlaminar adhesion between the first coating layer and the second coating layer is enhanced, and the high hardness firing typified by high-speed steel as compared with the conventional hard coating for cutting tools. It becomes a hard coating for cutting tools with excellent practicality that improves wear resistance in cutting of steel.

好適と考える本発明の実施形態を本発明の作用を示して簡単に説明する。   The preferred embodiment of the present invention will be briefly described by showing the operation of the present invention.

多層皮膜層にして第一皮膜層と第二皮膜層との層間部分に第一皮膜層と第二皮膜層とが混在する混在組織部(図1,2に図示したように第一皮膜層と第二皮膜層とが明確に区別されず、第一皮膜層の成分と第二皮膜層の成分とが混在する部分)が存在するから、第一皮膜層と第二皮膜層との結合が強固となって層間密着性が高まり、それだけ高速度鋼などに代表される高硬度焼入鋼に対する耐摩耗性が向上する。   A multi-layer coating layer in which the first coating layer and the second coating layer are mixed in the interlayer portion between the first coating layer and the second coating layer (the first coating layer and the first coating layer as shown in FIGS. The second coating layer is not clearly distinguished, and there is a portion where the components of the first coating layer and the second coating layer are mixed), so the bond between the first coating layer and the second coating layer is strong. As a result, the interlayer adhesion is enhanced, and the abrasion resistance to high hardness hardened steel represented by high speed steel is improved.

本発明の具体的な実施例について図面に基づいて説明する。   Specific embodiments of the present invention will be described with reference to the drawings.

本実施例は、基材上に形成される切削工具用硬質皮膜であって、この硬質皮膜は第一皮膜層と第二皮膜層とが交互に各2層以上積層して成る多層皮膜層を含み、前記第一皮膜層は金属成分として少なくともAlとCrとを含み非金属成分としてNを含み不可避不純物を含む皮膜層であり、第二皮膜層は金属及び半金属成分として少なくともTiとSiとを含み非金属成分としてNを含み不可避不純物を含む皮膜層であり、前記第一皮膜層及び前記第二皮膜層の夫々一層当りの膜厚は1nm以上20nm以下に設定され、前記多層皮膜層を断面TEM法で観察したとき、前記第一皮膜層と前記第二皮膜層とが混在した混在組織部が存在し、この混在組織部の面積が前記多層皮膜層の断面積の5%以上80%以下のものである。   The present example is a hard coating for a cutting tool formed on a substrate, and this hard coating is a multilayer coating layer in which two or more first coating layers and second coating layers are alternately laminated. The first coating layer is a coating layer containing at least Al and Cr as metal components, N as a non-metallic component and unavoidable impurities, and the second coating layer includes at least Ti and Si as metal and metalloid components. Is a coating layer containing N as a non-metallic component and containing inevitable impurities, and the thickness of each of the first coating layer and the second coating layer is set to 1 nm or more and 20 nm or less, and the multilayer coating layer is When observed by a cross-sectional TEM method, there is a mixed structure part in which the first film layer and the second film layer are mixed, and the area of the mixed structure part is 5% or more and 80% of the cross-sectional area of the multilayer film layer. It is as follows.

各部を具体的に説明する。   Each part will be specifically described.

基材は、WC(タングステンカーバイド)を主成分とする硬質粒子とCo(コバルト)を主成分とする結合材とから成る超硬合金製のものが採用されている。具体的には、前記WC粒子の平均粒径が0.1μm〜2μmに設定され、前記Coの含有量が重量%で5〜15%に設定されたものが採用されている。   As the base material, a cemented carbide alloy composed of hard particles mainly composed of WC (tungsten carbide) and a binder mainly composed of Co (cobalt) is employed. Specifically, the average particle diameter of the WC particles is set to 0.1 μm to 2 μm, and the Co content is set to 5 to 15% by weight.

この基材の直上には、Ti(チタン)を主成分とする窒化物若しくは炭窒化物から成る第四皮膜層が設けられている。この第四皮膜層の膜厚は0.01μm〜0.5μmに設定されている。尚、第四皮膜層として、Cr(クロム)を主成分とする窒化物若しくは炭窒化物を採用しても良い。この場合も膜厚は0.01μm〜0.5μmに設定すると良い。   A fourth coating layer made of a nitride or carbonitride containing Ti (titanium) as a main component is provided immediately above the base material. The film thickness of the fourth coating layer is set to 0.01 μm to 0.5 μm. Note that a nitride or carbonitride containing Cr (chromium) as a main component may be employed as the fourth coating layer. In this case, the film thickness is preferably set to 0.01 μm to 0.5 μm.

この第四皮膜層の上には、第三皮膜層が設けられている。この第三皮膜層の金属成分または金属成分及び半金属成分は前記第一皮膜層の金属成分または金属成分及び半金属成分と同一に設定されている。本実施例においては、後述するように第一皮膜層が金属成分と半金属成分を含む構成であり、第三皮膜層の金属成分及び半金属成分を第一皮膜層の金属成分及び半金属成分と同一に設定している。   A third coating layer is provided on the fourth coating layer. The metal component or metal component and metalloid component of the third coating layer are set to be the same as the metal component or metal component and metalloid component of the first coating layer. In the present embodiment, as will be described later, the first coating layer includes a metal component and a metalloid component, and the metal component and the metalloid component of the third coating layer are combined with the metal component and the metalloid component of the first coating layer. Is set to be the same.

本実施例においては、この第三皮膜層の上に前記第一皮膜層と第二皮膜層とを交互に積層して成る多層皮膜層が設けられている。   In this embodiment, a multilayer coating layer formed by alternately laminating the first coating layer and the second coating layer is provided on the third coating layer.

第一皮膜層は金属及び半金属成分が原子%で、
Al(100−x−y−z)Cr(x)(y)(z)
ただし、20≦x≦40,2≦y≦15,2≦z≦15
と表され、非金属成分としてNを含むと共に、不可避不純物を含む構成としている。
The first film layer is atomic% of metal and metalloid components,
Al (100-xyz) Cr (x) V (y) B (z)
However, 20 ≦ x ≦ 40, 2 ≦ y ≦ 15, 2 ≦ z ≦ 15
And includes N as a non-metallic component and unavoidable impurities.

また、第二皮膜層は金属及び半金属成分が原子%で、
Ti(100−v−w)Cr(v)Si(w)
ただし、5≦v≦30,5≦w≦30
と表され、非金属成分としてNを含むと共に、不可避不純物を含む構成としている。
In addition, the second coating layer is atomic% of metal and metalloid components,
Ti (100-vw) Cr (v) Si (w)
However, 5 ≦ v ≦ 30, 5 ≦ w ≦ 30
And includes N as a non-metallic component and unavoidable impurities.

この多層皮膜層の表層側には、第五皮膜層が設けられ、この第五皮膜層の金属成分,半金属成分及び非金属成分は前記第二皮膜層の金属成分,半金属成分及び非金属成分と同一に設定されている。尚、第五皮膜層の金属成分,半金属成分及び非金属成分は前記第一皮膜層の金属成分,半金属成分及び非金属成分と同一に設定しても良い。   On the surface side of the multilayer coating layer, a fifth coating layer is provided, and the metal component, semi-metal component and non-metal component of the fifth coating layer are the metal component, semi-metal component and non-metal of the second coating layer. It is set the same as the component. The metal component, metalloid component, and nonmetal component of the fifth coating layer may be set the same as the metal component, metalloid component, and nonmetal component of the first coating layer.

上記構成を採用した理由及び上記構成による作用効果を以下に説明する。   The reason why the above configuration is adopted and the operation and effect of the above configuration will be described below.

はじめに、Al−Cr−N系皮膜及びTi−Si−N系皮膜の特徴と課題について述べる。特許第3039381号公報などで提案されているAl−Cr−N皮膜は、切削工具用硬質皮膜として従来広く使われてきたTi−Al−N皮膜に対し、TiNの代わりにCrNをベースとすることで耐熱性を向上させたものであり、耐熱性が高く、また、靭性も比較的高いものの、硬度がやや低く、高速度鋼などに代表される高硬度焼入鋼の切削には耐摩耗性が十分とは言えない。一方、Veprekら(S.Christiansen,M.Albrecht,H.P.Strunk,and S.Veprek,J.Vac.Sci.Technol.B16(1),Jan/Feb1998.)によれば、Ti−Si−N皮膜は粒状のTiN微細結晶とSi−N非晶質部が混在した組織となり、非常に高い硬度が得られ、また、耐熱性も高い皮膜であると言われている。しかし、硬度と耐熱性は高いものの靭性がやや低く、高硬度被削材を切削した際、切れ刃に微小チッピングが生じる場合がある。本発明者等は、Al−Cr−N系皮膜の薄い層とTi−Si−N系皮膜の薄い層を積層することで両者の欠点を補い、高硬度被削材に対する耐摩耗性を高めることができると考え、研究を行った。   First, the characteristics and problems of the Al—Cr—N based coating and the Ti—Si—N based coating will be described. The Al—Cr—N coating proposed in Japanese Patent No. 3039381 is based on CrN instead of TiN, compared to the Ti—Al—N coating that has been widely used as a hard coating for cutting tools. It has improved heat resistance, and has high heat resistance and relatively high toughness, but it has a slightly low hardness and wear resistance when cutting high-hardness hardened steel such as high-speed steel. Is not enough. On the other hand, according to Veprek et al. (S. Christiansen, M. Albrecht, HP Strunk, and S. Veprek, J. Vac. Sci. Technol. B16 (1), Jan / Feb 1998.), the Ti-Si-N coating is It is said that it has a structure in which granular TiN fine crystals and Si—N amorphous parts coexist, resulting in a very high hardness and a high heat resistance. However, although the hardness and heat resistance are high, the toughness is slightly low, and when cutting a high-hardness work material, there is a case where minute chipping occurs on the cutting edge. The inventors of the present invention have made a thin layer of an Al—Cr—N film and a thin layer of a Ti—Si—N film to make up for the disadvantages of both, and to improve the wear resistance against high-hardness work materials. I thought I could do it and I did research.

本発明者等は、Al−Cr−N系皮膜層とTi−Si−N系皮膜層の積層皮膜について、種々の成膜条件で皮膜を作成して研究を行ったところ、皮膜積層部内の層間密着性の良し悪しが被覆工具の耐摩耗性に大きく影響することがわかった。即ち、皮膜積層部内の層間密着性が良いと高硬度被削材に対して良好な耐摩耗性が得られるが、層間密着性が悪いと微小チッピングを伴う工具摩耗形態となり十分な耐摩耗性が得られない。後者の被覆工具は積層部内で微小破壊が生じ、それが起点となって工具摩耗が進行したものと思われる。断面TEM法にて積層部を観察したところ、耐摩耗性が良好な皮膜では、Ti−Si−N系皮膜層とAl−Cr−N系皮膜層が混在した組織の部分が存在することがわかった。多層皮膜層の一部が第一皮膜層と第二皮膜層との混在組織になることで皮膜積層部内の層間密着性が高くなり、その結果、被覆工具の耐摩耗性が良好になったものと考える。本実施例は、この結果をもとに、皮膜積層部の一部が混在組織になるように皮膜組織をコントロールすることで皮膜積層部内の層間密着性を高くし、耐摩耗性に優れた切削工具用多層型硬質皮膜を提供するものである。皮膜積層部断面に閉める混在組織の割合が少なすぎると層間密着性を向上させる効果が低くなり、一方、混在組織の割合が多すぎると耐熱性がやや低下するので、混在組織の割合を5%以上80%以下にすることが望ましい。混在組織の生成メカニズムについては今後の研究が待たれるところであるが、ドロップレットと呼ばれる微小金属粒子の皮膜への取り込みが影響しているように思われる。ドロップレットの密度を適切にコントロールすることで、ある程度、混在組織の割合を制御することができるようである。また、明確には判明していないが、混在組織部はAl−Cr−Ti−Si−N系物質のマトリックスにTiNを主成分とする微細結晶が分散した組織になっているものと推定される。混在組織部は第一皮膜層と第二皮膜層の境界が不明瞭となっているところに特徴がある。   The inventors of the present invention conducted research on a multilayered film of an Al—Cr—N-based film layer and a Ti—Si—N-based film layer under various film formation conditions. It was found that good or bad adhesion greatly affects the wear resistance of the coated tool. In other words, good interlaminar adhesion within the film stack provides good wear resistance for high-hardness workpieces, but poor interlaminar adhesion results in a tool wear form with microchipping and sufficient wear resistance. I can't get it. In the latter coated tool, microfracture occurs in the laminated portion, and it is considered that the tool wear has progressed from that. When the laminated part was observed by a cross-sectional TEM method, it was found that a film with good wear resistance had a portion of a structure in which a Ti—Si—N film layer and an Al—Cr—N film layer were mixed. It was. A part of the multilayer coating layer becomes a mixed structure of the first coating layer and the second coating layer, so that the interlaminar adhesion within the coating layer is increased, and as a result, the wear resistance of the coated tool is improved. I think. This example is based on this result, by controlling the film structure so that a part of the film lamination part becomes a mixed structure, the interlaminar adhesion in the film lamination part is increased, and cutting with excellent wear resistance is achieved. A multilayer hard coating for a tool is provided. If the ratio of the mixed structure that closes to the cross section of the film stack is too small, the effect of improving the interlaminar adhesion will be low. On the other hand, if the ratio of the mixed structure is too large, the heat resistance will be slightly reduced. It is desirable to make it 80% or less. Future research is awaiting the mechanism of formation of the mixed tissue, but it seems that the incorporation of fine metal particles called droplets into the film has an effect. It seems that the proportion of mixed tissue can be controlled to some extent by appropriately controlling the density of droplets. Although not clearly understood, the mixed structure portion is estimated to have a structure in which fine crystals mainly composed of TiN are dispersed in a matrix of an Al-Cr-Ti-Si-N-based material. . The mixed tissue part is characterized in that the boundary between the first film layer and the second film layer is unclear.

次に、第一皮膜層及び第二皮膜層の夫々一層当りの膜厚について述べる。一層当りの膜厚を1nm未満とすると、第一皮膜層と第二皮膜層とが混在しやすくなり、前記ドロップレットの密度に関わらず第一皮膜層と第二皮膜層との混在組織の割合が80%を超える傾向となり、耐熱性が低下してしまう。一方、一層当りの膜厚を20nmより厚くすると、第二皮膜層が厚くなり過ぎて積層皮膜全体の靭性を十分に高くすることが出来ない。また、第一皮膜層についても、薄くし過ぎると積層皮膜全体の靭性が高くならず、厚くし過ぎると積層皮膜全体の硬度が低くなる。以上のことから、第一皮膜層及び第二皮膜層の夫々一層当りの膜厚を1nm以上20nm以下とすることが望ましい。   Next, the film thickness per layer of the first coating layer and the second coating layer will be described. When the film thickness per layer is less than 1 nm, the first film layer and the second film layer are likely to be mixed, and the ratio of the mixed structure of the first film layer and the second film layer regardless of the density of the droplets. Tends to exceed 80%, resulting in a decrease in heat resistance. On the other hand, if the film thickness per layer is greater than 20 nm, the second film layer becomes too thick and the toughness of the entire laminated film cannot be sufficiently increased. Also, if the first film layer is too thin, the toughness of the entire laminated film will not be high, and if it is too thick, the hardness of the entire laminated film will be low. From the above, it is desirable that the thickness of each of the first coating layer and the second coating layer be 1 nm or more and 20 nm or less.

次に、第一皮膜層の組成について述べる。本実施例は金属及び半金属成分として少なくともAlとCrを含み非金属成分としてNを含む組成を発明の範囲としており、AlCrNをベースとしている。本発明者等は、AlCrN皮膜に種々の第3元素を入れた皮膜について研究し、V及びBを所定量含有させることで鉄鋼材料に対する耐摩耗性を向上できることを発見した。皮膜の硬度と潤滑性が改善されたためと考える。金属及び半金属のみの原子%でB量が2%に満たない場合その効果は小さいが、2%以上で硬度の向上効果が現れる。そして、B含有量が15%を超えると硬度の値はあまり変化しなくなる。BはAlやCrに比べて高価な元素であるので、皮膜硬度と経済性を考慮すると、金属及び半金属のみの原子%で2%以上、15%以下の組成範囲でBを含有させることが望ましい。また、Vの含有については、その含有量を多くすると皮膜の潤滑性が向上する。金属及び半金属のみの原子%でV量が2%に満たない場合その効果は小さいが、2%以上で潤滑性の向上効果が現れ、その皮膜を被覆した工具の鉄鋼材料に対する耐摩耗性が向上する。一方、V含有量を多くしすぎると皮膜の硬度が低下し、鉄鋼材料に対する耐摩耗性が低下してくる。また、VはAlやCrに比べて極めて高価な元素であるので、皮膜の潤滑性及び硬度と経済性とを考慮すると、金属及び半金属のみの原子%で2%以上、15%以下の組成範囲でVを含有させることが望ましい。   Next, the composition of the first coating layer will be described. In this example, a composition containing at least Al and Cr as the metal and metalloid components and N as the nonmetal component is within the scope of the invention, and is based on AlCrN. The inventors of the present invention have studied a film in which various third elements are added to an AlCrN film, and have found that the wear resistance against a steel material can be improved by containing a predetermined amount of V and B. This is thought to be due to the improved hardness and lubricity of the film. The effect is small when the amount of B is less than 2% with only atomic% of metal and metalloid, but the effect of improving hardness appears at 2% or more. When the B content exceeds 15%, the hardness value does not change much. Since B is an expensive element compared to Al and Cr, in consideration of film hardness and economy, B may be contained in a composition range of 2% or more and 15% or less in terms of atomic% of only metal and metalloid. desirable. Moreover, about the content of V, if the content is increased, the lubricity of the film is improved. The effect is small when the amount of V is less than 2% with atomic% of metal and metalloid only, but the effect of improving lubricity appears at 2% or more, and the wear resistance of the tool coated with the coating on the steel material improves. On the other hand, when the V content is excessively increased, the hardness of the coating is lowered and the wear resistance against the steel material is lowered. Further, since V is an extremely expensive element compared to Al and Cr, the composition of 2% or more and 15% or less in terms of atomic% of only metal and metalloid in consideration of the lubricity, hardness and economics of the film. It is desirable to contain V in the range.

次に、第二皮膜層の組成について述べる。本実施例は、金属成分及び半金属成分として少なくともTiとSiを含み非金属成分としてNを含むものとしているが、そのベースとなるのはTiSiNである。本発明者等はTiSiNをベースに、皮膜の耐摩耗性をさらに向上すべく、様々な種類の第3元素の添加を試みた。その結果、Crを所定量含有させることで潤滑性が向上し、皮膜の耐摩耗性が向上することを確認した。即ち、金属及び半金属のみの原子%でCr量が5%に満たない場合、その効果は小さいが、5%以上で潤滑性の向上効果が現れ、その皮膜を被覆した超硬合金基材切削工具の高硬度被削材に対する耐摩耗性が向上することが確認された。また、Cr含有量を多くしすぎると皮膜の硬度が低下し、その皮膜を被覆した超硬合金基材切削工具の高硬度被削材に対する耐摩耗性が低下してくることも確認された。これらのことから、Crの含有量は金属及び半金属のみの原子%で5%以上30%以下が望ましい。一方、Siの含有については、その含有量を多くすると、皮膜の耐酸化性と硬度が向上する。すなわち、金属及び半金属のみの原子%でSi量が5%に満たない場合、その効果は小さいが、5%以上で耐酸化性と硬度の向上効果が現れ、その皮膜を被覆した超硬合金基材切削工具の高硬度被削材に対する耐摩耗性が向上することが確認された。また、Si含有量を多くしすぎると、その皮膜を被覆した超硬合金基材切削工具の高硬度被削材に対する耐摩耗性が低下してくることも確認された。これは、Si量が多すぎると、皮膜の内部応力が大きくなりすぎることで、皮膜内に微小亀裂が生じやすくなるためと考える。これらのことから、Siの含有量は金属及び半金属のみの原子%で5%以上30%以下が望ましい。   Next, the composition of the second coating layer will be described. In the present embodiment, at least Ti and Si are included as the metal component and the semimetal component, and N is included as the nonmetal component, but the base is TiSiN. The present inventors tried to add various kinds of third elements based on TiSiN in order to further improve the wear resistance of the coating. As a result, it was confirmed that inclusion of a predetermined amount of Cr improves lubricity and improves the wear resistance of the film. That is, when the atomic percentage of only metal and metalloid is less than 5%, the effect is small, but the effect of improving lubricity appears at 5% or more, and the cemented carbide base material coated with the coating is cut. It was confirmed that the wear resistance of the tool against a high-hardness work material is improved. It was also confirmed that if the Cr content is excessively increased, the hardness of the coating is lowered, and the wear resistance of the cemented carbide base cutting tool coated with the coating on the high-hardness work material is reduced. For these reasons, the Cr content is desirably 5% or more and 30% or less in terms of atomic% of only metals and metalloids. On the other hand, regarding the content of Si, if the content is increased, the oxidation resistance and hardness of the film are improved. That is, when the atomic percentage of only metal and metalloid is less than 5%, the effect is small, but the effect of improving oxidation resistance and hardness appears at 5% or more, and the cemented carbide coated with the coating. It was confirmed that the wear resistance of the base material cutting tool against the high-hardness work material is improved. It was also confirmed that if the Si content is excessively increased, the wear resistance of the cemented carbide substrate cutting tool coated with the coating on the high-hardness work material is reduced. This is considered to be because if the amount of Si is too large, the internal stress of the film becomes too large, and microcracks are likely to occur in the film. For these reasons, the Si content is preferably 5% or more and 30% or less in terms of atomic% of only metals and metalloids.

次に、第三皮膜層について述べる。本発明者等は超硬合金製切削工具に多層皮膜層を被覆して切削試験を試みたが、切削時に皮膜剥離が生じてしまう場合があることを確認した。超硬合金基材と皮膜との密着性が十分でないためと考えられる。そこで、超硬合金基材と多層皮膜層との間に第三皮膜層を形成し、第三皮膜層の金属成分及び半金属成分を第一皮膜層の金属成分及び半金属成分と同一の組成としたところ、切削時の皮膜剥離が格段に低減した。第三皮膜層を形成したことで、超硬合金基材と皮膜との密着性が大幅に向上したものと考えられる。第三皮膜層の膜厚については特に限定するものではないが、薄すぎると密着性向上の効果が現れにくいので、膜厚を0.1μm以上とすることが望ましい。   Next, the third coating layer will be described. The inventors of the present invention tried a cutting test by coating a cemented carbide cutting tool with a multilayer coating layer, and confirmed that peeling of the coating may occur during cutting. This is probably because the adhesion between the cemented carbide substrate and the coating is not sufficient. Therefore, a third coating layer is formed between the cemented carbide substrate and the multilayer coating layer, and the metal component and the semimetal component of the third coating layer have the same composition as the metal component and the semimetal component of the first coating layer. As a result, film peeling during cutting was significantly reduced. It is considered that the adhesion between the cemented carbide base material and the film is greatly improved by forming the third film layer. The film thickness of the third coating layer is not particularly limited, but if it is too thin, the effect of improving the adhesion is difficult to appear, so it is desirable that the film thickness be 0.1 μm or more.

皮膜剥離を低減するための別の方策として、基材との密着性に優れたTi系あるいはCr系の窒化物若しくは炭窒化物(第四皮膜層)を基材直上に形成させても良い。基材の直上に第四皮膜層を形成しその上に多層皮膜層を形成しても、膜剥離が大幅に低減する。より好ましい皮膜構成は、基材の直上に第四皮膜層を形成し、その上に第三皮膜層を形成し、さらにその上に多層皮膜層を形成した構成である。第四皮膜層の膜厚は、その上に第三皮膜層を形成する場合には比較的膜厚が薄くても基材との密着性向上の効果が現れるが、その場合でも0.01μm以上の厚さがあることが望ましい。また、第四皮膜層の目的は基材との密着性向上効果にあるので、膜厚を厚くしすぎる必要もなく、膜厚を0.5μm以下にすることが望ましい。   As another measure for reducing film peeling, a Ti-based or Cr-based nitride or carbonitride (fourth coating layer) having excellent adhesion to the substrate may be formed directly on the substrate. Even if the fourth coating layer is formed directly on the substrate and the multilayer coating layer is formed thereon, film peeling is greatly reduced. A more preferable coating configuration is a configuration in which a fourth coating layer is formed directly on the substrate, a third coating layer is formed thereon, and a multilayer coating layer is further formed thereon. The film thickness of the fourth film layer is such that when the third film layer is formed thereon, the effect of improving the adhesion with the substrate appears even if the film thickness is relatively thin. It is desirable to have a thickness of In addition, since the purpose of the fourth coating layer is to improve the adhesion to the substrate, it is not necessary to make the film thickness too thick, and it is desirable to make the film thickness 0.5 μm or less.

次に、第五皮膜層について述べる。本発明者等は、最表層部にAl−Cr−N系皮膜(金属成分及び半金属成分が第一皮膜層と同一の組成)またはTi−Si−N系皮膜(金属成分及び半金属成分が第二皮膜層と同一の組成)を形成することで、被削材の種類によっては、被覆工具の耐摩耗性をさらに少し高められる場合があることを確認した。65HRCに熱処理されたSKH51材(高速度鋼)に対しては、Ti−Si−N系皮膜を最表部に形成することで被覆工具の耐摩耗性がやや向上した。一方、53HRCに熱処理されたSTAVAX材に対してはAl−Cr−N系皮膜を最表部に形成することで被覆工具の耐摩耗性が少し向上した。前述した通り、Al−Cr−N系皮膜は靭性が比較的高いものの硬度がやや低く、Ti−Si−N系皮膜は硬度が高いものの靭性がやや低い特徴がある。詳細なメカニズムは不明であるものの、最表部に第五皮膜層を設けることで、これらの特徴が被覆工具の耐摩耗性に良い効果をもたらしたものと思われる。第五皮膜層の膜厚については特に限定するものではないが、薄くしすぎるとその効果が現れにくく、また、厚くしすぎると硬度の低さ(Al−Cr−N系皮膜)や靭性の低さ(Ti−Si−N系皮膜)が現れてくるので、0.1μm以上1μm以下にすることが望ましい。   Next, the fifth coating layer will be described. The inventors of the present invention applied an Al—Cr—N-based film (metal component and semi-metal component are the same composition as the first film layer) or a Ti—Si—N-based film (metal component and semi-metal component are present on the outermost layer). It was confirmed that the wear resistance of the coated tool may be further enhanced by forming the same composition as the second coating layer) depending on the type of work material. For the SKH51 material (high speed steel) heat-treated to 65HRC, the wear resistance of the coated tool was slightly improved by forming a Ti—Si—N-based film on the outermost surface. On the other hand, for the STAVAX material heat-treated to 53HRC, the wear resistance of the coated tool was slightly improved by forming an Al—Cr—N-based film on the outermost surface. As described above, the Al—Cr—N-based film has a relatively high toughness, but the hardness is slightly low, and the Ti—Si—N-based film has a high hardness, but has a slightly low toughness. Although the detailed mechanism is unknown, it is considered that these characteristics have had a good effect on the wear resistance of the coated tool by providing the fifth coating layer on the outermost surface. The film thickness of the fifth film layer is not particularly limited, but if it is too thin, the effect is difficult to appear, and if it is too thick, the hardness is low (Al-Cr-N-based film) and the toughness is low. (Ti-Si-N-based film) appears, so it is desirable that the thickness be 0.1 μm or more and 1 μm or less.

本実施例の硬質皮膜は鉄鋼材料用切削工具向けに発明されたものであるが、その基材としては、WCを主成分とする硬質粒子とCoを主成分とする結合材からなる超硬合金が、鉄鋼材料用切削工具として硬度と靭性のバランスが取れた材料であることから望ましい。WC粒子の平均粒径を小さくしすぎると、結合材中にWC粒子を均一に分散させることが難しくなり、超硬合金の抗折力低下を引き起こしやすい。一方、WC粒子を大きくしすぎると超硬合金の硬度が低下する。また、Co含有量を少なくしすぎると超硬合金の抗折力が低下し、逆にCo含有量を多くしすぎると超硬合金の硬度が低下する。そのため、WC粒子の平均粒径が0.1μm〜2μmであり、Co含有量が重量%で5〜15%の超硬合金を基材とすることが望ましい。   The hard coating of this example was invented for a cutting tool for steel materials, and the base material thereof is a cemented carbide alloy composed of hard particles mainly composed of WC and a binder mainly composed of Co. However, it is desirable because it is a material having a balance between hardness and toughness as a cutting tool for steel materials. If the average particle size of the WC particles is too small, it will be difficult to uniformly disperse the WC particles in the binder, which tends to cause a reduction in the bending strength of the cemented carbide. On the other hand, if the WC particles are too large, the hardness of the cemented carbide decreases. Further, if the Co content is too small, the bending strength of the cemented carbide decreases, and conversely if the Co content is excessively increased, the hardness of the cemented carbide decreases. Therefore, it is desirable to use a cemented carbide having a mean particle size of WC particles of 0.1 μm to 2 μm and a Co content of 5 to 15% by weight as a base material.

本実施例は上述のように構成したから、多層皮膜層に第一皮膜層と第二皮膜層が混在する混在組織部が所定量存在することにより、第一皮膜層と第二皮膜層との層間密着性が高まり、それだけ高速度鋼などに代表される高硬度焼入鋼に対する耐摩耗性が向上する。   Since the present embodiment is configured as described above, when there is a predetermined amount of mixed tissue portion in which the first coating layer and the second coating layer are mixed in the multilayer coating layer, the first coating layer and the second coating layer Interlayer adhesion is enhanced, and the wear resistance against high hardness hardened steel represented by high speed steel is improved accordingly.

特に、本実施例は、基材上に、第四皮膜層、第三皮膜層、多層皮膜層、第五皮膜層を順次積層し、多層皮膜層の基材側及び表層側に夫々更に所定の特性を有する皮膜層を設けている。即ち、膜応力が大きくなる皮膜の基材側に靱性に秀れた皮膜層を配すると共に、被切削物と接触する表層側に硬度に秀れた皮膜層を配することで、皮膜が基材から剥離し難く且つ表層が摩耗し難くなり、極めてチッピングが生じ難いものとなる。   In particular, in this example, a fourth coating layer, a third coating layer, a multilayer coating layer, and a fifth coating layer are sequentially laminated on the base material, and each of the multilayer coating layers is further provided on the base material side and the surface layer side, respectively. A film layer having characteristics is provided. In other words, a coating layer having excellent toughness is disposed on the base material side of the coating film where the film stress is increased, and a coating layer having excellent hardness is disposed on the surface layer side in contact with the work to be cut. It is difficult to peel off from the material and the surface layer is difficult to wear, and chipping is extremely difficult to occur.

従って、本実施例は、第一皮膜層と第二皮膜層との層間密着性が高まり、それだけ従来の切削工具用硬質皮膜に比し高速度鋼などに代表される高硬度焼入鋼の切削における耐摩耗性が向上する極めて実用性に秀れた切削工具用硬質皮膜となる。   Therefore, in this example, the interlaminar adhesion between the first coating layer and the second coating layer is enhanced, and the cutting of high hardness hardened steel represented by high-speed steel and the like compared with the conventional hard coating for cutting tools. It becomes a hard coating for a cutting tool with extremely high practicality, which improves the wear resistance at.

以下、本実施例の効果を裏付ける実験例について説明する。   Hereinafter, experimental examples supporting the effects of the present embodiment will be described.

[実験例1]
実験例1では、成膜装置としてアーク放電式イオンプレーティング装置を用い、金属及び半金属成分の蒸発源としてAl60Cr27及びTi62Cr15Si23ターゲットを成膜装置内に取り付け、また、反応ガスとしてNガスを成膜装置内に導入し、ガス圧を6Pa、バイアス電圧を−100V、基材温度600℃として、成膜基材としての超硬合金板に成膜した。成膜装置内に2種類のターゲットを互いに向かい合うように配置し、その中央部に成膜基材をセットして回転速度3min−1で回転させた(回転軸はターゲット面と平行)。成膜初期はTi62Cr15Si23ターゲットの放電をOFFにして、超硬基板直上に(Al60Cr27)N(第三皮膜層)を形成し、次に、Ti62Cr15Si23ターゲットの放電もONにして(Al60Cr27ターゲットとTi62Cr15Si23ターゲットの同時放電)、(Al60Cr27)N(第一皮膜層)と(Ti62Cr15Si23)N(第二皮膜層)とを基材の回転に伴って交互に積層し多層皮膜層を形成した。図1,図2の積層部で相対的に黒くみえる層が第二皮膜層、相対的に白くみえる層が第一皮膜層である。TEM像から、積層部の一部に第一皮膜層と第二皮膜層とが混在した組織が存在することが確認できる。この混在組織を積層部に導入することで、多層皮膜層の層間密着性を大幅に改良することができ、それにより被覆工具の耐摩耗性の向上を実現している。
[Experimental Example 1]
In Experimental Example 1, an arc discharge ion plating apparatus is used as a film forming apparatus, and Al 60 Cr 27 V 5 B 8 and Ti 62 Cr 15 Si 23 targets are used as evaporation sources of metal and metalloid components in the film forming apparatus. At the same time, N 2 gas is introduced into the film forming apparatus as a reaction gas, the gas pressure is set to 6 Pa, the bias voltage is set to −100 V, and the base material temperature is 600 ° C. to form a film on the cemented carbide plate as the film forming base. did. Two types of targets were arranged in the film forming apparatus so as to face each other, and a film forming substrate was set at the center and rotated at a rotation speed of 3 min −1 (the rotation axis was parallel to the target surface). In the initial stage of film formation, the discharge of the Ti 62 Cr 15 Si 23 target is turned off to form (Al 60 Cr 27 V 5 B 8 ) N (third coating layer) directly on the carbide substrate, and then Ti 62 Cr 15 Si 23 target is also turned on (simultaneous discharge of Al 60 Cr 27 V 5 B 8 target and Ti 62 Cr 15 Si 23 target), (Al 60 Cr 27 V 5 B 8 ) N (first coating layer) And (Ti 62 Cr 15 Si 23 ) N (second coating layer) were alternately laminated with the rotation of the substrate to form a multilayer coating layer. The layer that appears relatively black in the laminated portion of FIGS. 1 and 2 is the second coating layer, and the layer that appears relatively white is the first coating layer. From the TEM image, it can be confirmed that a structure in which the first coating layer and the second coating layer are mixed exists in a part of the laminated portion. By introducing this mixed structure into the laminated portion, the interlaminar adhesion of the multilayer coating layer can be greatly improved, thereby improving the wear resistance of the coated tool.

[実験例2]
実験例2では、成膜装置としてアーク放電式イオンプレーティング装置を用い、金属及び半金属成分の蒸発源として各種組成のターゲットを成膜装置内に取り付け、また、反応ガスとしてNガス、CHガスのうち、1種類もしくは2種類のガスを成膜装置内に導入して、成膜基材としての超硬合金製2枚刃ボールエンドミル(外径3mm)に所定の皮膜を成膜した。3種類のターゲットが取り付けられる成膜装置を使用し、2種類または3種類のターゲットを取り付けて成膜を行った。成膜に当たっては、ガス圧6Pa、バイアス電圧−30V〜−200V、基材温度500℃〜600℃の条件とし、全皮膜の膜厚が3.0〜4.0μmになるように基材エンドミルに成膜した。所定の皮膜を被覆したエンドミルを用いて、次の切削条件で切削試験を行い、エンドミル逃げ面の摩耗幅を測定した。即ち、被削材をSKH51焼入材(65HRC)とし、外径3mmのエンドミルを19000min−1の回転速度で回転させ、送り速度1440mm/min、切り込み量Ad=0.15mm、Pf=0.45mmとし、エアーブローをクーラントとして試験を行った。切削試験の結果を表1に示す。
[Experiment 2]
In Experimental Example 2, an arc discharge ion plating apparatus is used as a film forming apparatus, targets of various compositions are attached in the film forming apparatus as evaporation sources of metal and metalloid components, and N 2 gas, CH are used as reaction gases. One or two of the four gases were introduced into the film forming apparatus, and a predetermined film was formed on a cemented carbide two-blade ball end mill (outer diameter: 3 mm) as a film forming substrate. . Using a film forming apparatus to which three types of targets were attached, two or three types of targets were attached to form a film. In forming the film, the conditions are such that the gas pressure is 6 Pa, the bias voltage is −30 V to −200 V, the substrate temperature is 500 ° C. to 600 ° C., and the film thickness of the entire film is 3.0 to 4.0 μm. A film was formed. Using an end mill coated with a predetermined film, a cutting test was performed under the following cutting conditions, and the wear width of the end mill flank was measured. That is, the work material is SKH51 hardened material (65HRC), an end mill with an outer diameter of 3 mm is rotated at a rotation speed of 19000 min −1 , a feed speed is 1440 mm / min, a cutting amount Ad = 0.15 mm, Pf = 0.45 mm. The test was conducted using air blow as a coolant. The results of the cutting test are shown in Table 1.

尚、No.8,11,12の第四皮膜層(TiCN)は、基材直上部のC量を0、即ちTiNとし、表層部に向けて徐々にC量を増やしながら成膜した。また、No.9の第四皮膜層(CrCN)は、基材直上部のC量を0、即ちCrNとし、表層部に向けて徐々にC量を増やしながら成膜した。   No. The fourth coating layers (TiCN) of 8, 11 and 12 were formed while the C amount immediately above the base material was 0, that is, TiN, and the C amount was gradually increased toward the surface layer portion. No. The fourth coating layer (CrCN) No. 9 was formed while the C amount immediately above the base material was 0, that is, CrN, and the C amount was gradually increased toward the surface layer portion.

また、No.1〜9の実施例では、多層皮膜層の断面TEM像に第一皮膜層と第二皮膜層とが混在した組織の部分が存在し、その混在組織部の面積が多層皮膜層の断面積の5%以上80%以下であった。尚、No.10の比較例では、多層皮膜層の断面TEM像に第一皮膜層と第二皮膜層とが混在した組織を確認することができなかった。   No. In the examples of 1 to 9, the cross-sectional TEM image of the multilayer coating layer includes a portion of the structure in which the first coating layer and the second coating layer are mixed, and the area of the mixed tissue portion is the cross-sectional area of the multilayer coating layer. It was 5% or more and 80% or less. No. In the comparative example of 10, the structure in which the first coating layer and the second coating layer were mixed could not be confirmed in the cross-sectional TEM image of the multilayer coating layer.

表1では実施例とともに、従来の硬質皮膜や実施例の範囲外の硬質皮膜を実施例と同様な手段で被覆したエンドミルで切削試験を行った結果を比較例として記載している。   Table 1 shows, as a comparative example, the results of a cutting test performed with an end mill in which a conventional hard coating and a hard coating out of the range of the embodiment are coated by the same means as in the embodiment.

表1から、本実施例は比較例に比べてエンドミル逃げ面摩耗幅の低減、すなわち、高硬度焼入鋼に対する耐摩耗性の向上が認められる。   From Table 1, it can be seen that this example has a reduction in end mill flank wear width, that is, an improvement in wear resistance with respect to hardened hardened steel, as compared with the comparative example.

本実施例の要部の説明断面図である。It is explanatory sectional drawing of the principal part of a present Example. 本実施例の要部の拡大説明断面図である。It is expansion explanatory sectional drawing of the principal part of a present Example.

Claims (8)

基材上に形成される切削工具用硬質皮膜であって、この硬質皮膜は第一皮膜層と第二皮膜層とが交互に各2層以上積層して成る多層皮膜層を含み、前記第一皮膜層は金属成分として少なくともAlとCrとを含み非金属成分としてNを含み不可避不純物を含む皮膜層であり、前記第二皮膜層は金属及び半金属成分として少なくともTiとSiとを含み非金属成分としてNを含み不可避不純物を含む皮膜層であり、前記第一皮膜層及び前記第二皮膜層の夫々一層当りの膜厚は1nm以上20nm以下に設定され、前記多層皮膜層を断面TEM法で観察したとき、前記第一皮膜層の成分と前記第二皮膜層の成分とが混在した組織を有する混在組織部が存在し、この混在組織部の面積が前記多層皮膜層の断面積の5%以上80%以下であることを特徴とする切削工具用硬質皮膜。 A hard film for a cutting tool formed on a substrate, the hard film including a multilayer film layer in which two or more first film layers and second film layers are alternately laminated, coating layer is a coating layer contain inevitable impurities include N as a non-metal component and at least Al and Cr as metal components, non-metallic and at least Ti and Si the second coating layer is a metal and metalloid components A film layer containing N as an ingredient and containing inevitable impurities, the film thickness of each of the first film layer and the second film layer is set to 1 nm or more and 20 nm or less, and the multilayer film layer is formed by a cross-sectional TEM method. when viewed, the a component of the first coating layer and the component of the second coating layer is present mixed tissue section having a tissue mixed with 5% of the cross-sectional area of the area of the mixed tissue section the multilayer coating layer More than 80% The hard film for a cutting tool to be with. 請求項1記載の切削工具用硬質皮膜において、前記第一皮膜層は金属及び半金属成分が原子%で、
Al(100−x−y−z)Cr(x)V(y)B(z)
ただし、20≦x≦40,2≦y≦15,2≦z≦15
と表され、前記第二皮膜層は金属及び半金属成分が原子%で、
Ti(100−v−w)Cr(v)Si(w)
ただし、5≦v≦30,5≦w≦30
と表されることを特徴とする切削工具用硬質皮膜。
The hard film for a cutting tool according to claim 1, wherein the first film layer is composed of metal and a metalloid component in atomic%.
Al (100-xyz) Cr (x) V (y) B (z)
However, 20 ≦ x ≦ 40, 2 ≦ y ≦ 15, 2 ≦ z ≦ 15
And the second coating layer is an atomic% metal and metalloid component,
Ti (100-vw) Cr (v) Si (w)
However, 5 ≦ v ≦ 30, 5 ≦ w ≦ 30
A hard coating for a cutting tool, characterized by:
請求項1,2いずれか1項に記載の切削工具用硬質皮膜において、前記基材と前記多層皮膜層との間には第三皮膜層が設けられ、この第三皮膜層の金属成分または金属成分及び半金属成分は前記第一皮膜層の金属成分または金属成分及び半金属成分と同一であることを特徴とする切削工具用硬質皮膜。   The hard film for a cutting tool according to any one of claims 1 and 2, wherein a third film layer is provided between the base material and the multilayer film layer, and a metal component or metal of the third film layer is provided. The hard coating for a cutting tool, wherein the component and the metalloid component are the same as the metal component or the metal component and the metalloid component of the first coating layer. 請求項1〜3いずれか1項に記載の切削工具用硬質皮膜において、前記基材直上には第四皮膜層が設けられ、この第四皮膜層はTiを主成分とする窒化物若しくは炭窒化物から成り、この第四皮膜層の膜厚は0.01μm〜0.5μmに設定されていることを特徴とする切削工具用硬質皮膜。   The hard film for a cutting tool according to any one of claims 1 to 3, wherein a fourth film layer is provided immediately above the base material, and the fourth film layer is a nitride or carbonitride containing Ti as a main component. A hard film for a cutting tool, characterized in that the film thickness of the fourth film layer is set to 0.01 μm to 0.5 μm. 請求項1〜3いずれか1項に記載の切削工具用硬質皮膜において、前記基材直上には第四皮膜層が設けられ、この第四皮膜層はCrを主成分とする窒化物若しくは炭窒化物から成り、この第四皮膜層の膜厚は0.01μm〜0.5μmに設定されていることを特徴とする切削工具用硬質皮膜。   The hard film for a cutting tool according to any one of claims 1 to 3, wherein a fourth film layer is provided immediately above the base material, and the fourth film layer is a nitride or carbonitride containing Cr as a main component. A hard film for a cutting tool, characterized in that the film thickness of the fourth film layer is set to 0.01 μm to 0.5 μm. 請求項1〜5いずれか1項に記載の切削工具用硬質皮膜において、前記多層皮膜層の表層側には第五皮膜層が設けられ、この第五皮膜層の金属成分及び半金属成分は前記第二皮膜層の金属成分及び半金属成分と同一であることを特徴とする切削工具用硬質皮膜。   The hard film for a cutting tool according to any one of claims 1 to 5, wherein a fifth film layer is provided on a surface layer side of the multilayer film layer, and the metal component and the semimetal component of the fifth film layer are A hard coating for a cutting tool, characterized by being the same as the metal component and the semi-metal component of the second coating layer. 請求項1〜5いずれか1項に記載の切削工具用硬質皮膜において、前記多層皮膜層の表層側には第五皮膜層が設けられ、この第五皮膜層の金属成分または金属成分及び半金属成分は前記第一皮膜層の金属成分または金属成分及び半金属成分と同一であることを特徴とする切削工具用硬質皮膜。   The hard film for a cutting tool according to any one of claims 1 to 5, wherein a fifth film layer is provided on a surface layer side of the multilayer film layer, and a metal component or a metal component and a semimetal of the fifth film layer are provided. The hard coating for a cutting tool, wherein the component is the same as the metal component or the metal component and the metalloid component of the first coating layer. 請求項1〜7いずれか1項に記載の切削工具用硬質皮膜において、前記基材はWCを主成分とする硬質粒子とCoを主成分とする結合材からなる超硬合金であって、前記WC粒子の平均粒径が0.1μm〜2μmに設定され、前記Coの含有量が重量%で5〜15%に設定されたものであることを特徴とする切削工具用硬質皮膜。   The hard film for a cutting tool according to any one of claims 1 to 7, wherein the substrate is a cemented carbide composed of hard particles mainly composed of WC and a binder mainly composed of Co, and A hard film for a cutting tool, wherein an average particle diameter of WC particles is set to 0.1 μm to 2 μm, and the Co content is set to 5 to 15% by weight.
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WO2021200042A1 (en) 2020-03-30 2021-10-07 三菱マテリアル株式会社 Surface-coated cutting tool
WO2022138375A1 (en) 2020-12-22 2022-06-30 三菱マテリアル株式会社 Surface-coated cutting tool

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JP5010707B2 (en) * 2010-04-13 2012-08-29 ユニオンツール株式会社 Hard coating for cutting tools
CN113403578A (en) * 2021-06-22 2021-09-17 南京工业职业技术大学 Preparation method of superhard multilayer nano composite coating

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EP1842610B1 (en) * 2004-12-28 2017-05-03 Sumitomo Electric Hardmetal Corp. Surface-coated cutting tool and process for producing the same
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WO2021200042A1 (en) 2020-03-30 2021-10-07 三菱マテリアル株式会社 Surface-coated cutting tool
WO2022138375A1 (en) 2020-12-22 2022-06-30 三菱マテリアル株式会社 Surface-coated cutting tool

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