JP5082662B2 - Easy-open blister container - Google Patents

Easy-open blister container Download PDF

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JP5082662B2
JP5082662B2 JP2007206062A JP2007206062A JP5082662B2 JP 5082662 B2 JP5082662 B2 JP 5082662B2 JP 2007206062 A JP2007206062 A JP 2007206062A JP 2007206062 A JP2007206062 A JP 2007206062A JP 5082662 B2 JP5082662 B2 JP 5082662B2
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opening
lid
container
thermal bonding
container body
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JP2008179411A (en
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京谷  均
敦子 高萩
新 山田
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Dai Nippon Printing Co Ltd
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Dai Nippon Printing Co Ltd
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Description

本発明は、蓋体を容器本体から剥離させて容易に開封できる易開封性ブリスター容器に関し、特に一つの辺側に設けた開封用摘み部より、開封用切れ目線に沿って開封する易開封性ブリスター容器に関する。   The present invention relates to an easily openable blister container that can be easily opened by peeling the lid from the container body, and in particular, easily opened from the opening knob provided on one side along the opening cut line. Related to blister containers.

従来より、ハム、ベーコン等の食品あるいは医薬品、化粧品等の種々の内容物を封入する包装容器として、熱成形され内容物を収納する凹部とフランジ部を有する容器本体と蓋体からなり、内容物を凹部に収納し、内容物とフランジ部を蓋体で被覆して周縁を熱接着させたブリスター容器が知られている。密封に際して、含気包装以外に内容物により、その保存性の向上を図るために、窒素ガス、炭酸ガスを封入するガス充填包装や脱酸素剤封入包装や真空包装などの包装技法が一般的に用いられている。   Conventionally, as a packaging container for enclosing various contents such as foods such as ham and bacon or pharmaceuticals, cosmetics, etc., it is composed of a container body having a recess and a flange part for containing the contents and a lid, and the contents. A blister container is known in which the contents and the flange portion are covered with a lid and the periphery is thermally bonded. When sealing, in order to improve the storage stability of the contents, in addition to the aerated packaging, packaging techniques such as gas-filled packaging in which nitrogen gas or carbon dioxide gas is sealed, oxygen scavenger packaging, or vacuum packaging are generally used. It is used.

これらのブリスター容器は開封を容易とするために、概ね平面形状が矩形で、一つの角部に蓋体と容器本体との未接着部を形成して開封用摘み部を設けて、ここから蓋体を剥離する構成となっている。更に蓋体及び/又は容器本体の熱接着される面に易剥離性処理が施され、例えば、蓋体に易剥離性処理を施す場合には、容器本体と熱接着される蓋体の内層に易剥離性熱接着樹脂層を積層した構造を有し、開封用摘み部を一方の手指で摘み、他方の手指で容器本体を摘み、相反する方向に引張ると蓋体と容器本体が剥離し、容易に開封できるようになっている。   In order to facilitate the opening of these blister containers, the planar shape is generally rectangular, and an unbonded portion between the lid and the container body is formed at one corner to provide an opening knob, from which the lid is opened. It is configured to peel off the body. Furthermore, the surface of the lid and / or the container body that is thermally bonded is subjected to an easy-release treatment. For example, when the lid is subjected to an easy-release treatment, the inner layer of the lid that is thermally bonded to the container body is used. It has a structure in which an easily peelable thermal adhesive resin layer is laminated, picking the opening knob with one finger, picking the container body with the other finger, pulling in the opposite direction, the lid body and the container body peel, It can be opened easily.

しかしながら、蓋体と容器本体は密着して容易に開封用摘み部を容器本体から分離して摘みにくいという問題がある。特に、これらのブリスター容器の製造は、容器本体と蓋体とを熱接着した後に矩形状に打抜いてトリミングされる方法が多く、熱接着の余熱が残存した状態でトリミングされるために蓋体と容器本体のトリミング部分が仮着を起こし、開封用摘み部の分離をより一層、困難にすることがある。   However, there is a problem that the lid and the container main body are in close contact with each other and the opening knob is easily separated from the container main body and is difficult to pick. In particular, in the manufacture of these blister containers, there are many methods in which the container main body and the lid are thermally bonded and then punched into a rectangular shape and trimmed, and the lid is trimmed with the residual heat remaining after thermal bonding. And the trimming part of the container body may cause temporary attachment, making separation of the opening knob more difficult.

上記の問題を改善するため、例えば、ミルクポーションパックのようにタブ部が設けられ、タブ部の容器本体側に蓋体と容器本体との周縁シール部の外縁近傍に薄肉線を設けて折り曲げて切取り、タブ部を摘みやすい構成が用いられている。これらは、容器本体が小さい場合や、容器本体が折り曲げて切り取りやすい剛性のある構成には、有効であるが、スライスハムやベーコン等のブリスター容器のように大きくなると、手で容器が摘みにくいあるいは、容器本体の材質がフレキシブルな構成のものには、剛性がなく、このような切取り方式は不適当である。   In order to improve the above problem, for example, a tab portion is provided like a milk portion pack, and a thin wire is provided near the outer edge of the peripheral seal portion between the lid and the container body on the container body side of the tab portion and bent. The structure which is easy to cut and tab tabs is used. These are effective when the container body is small, or when the container body is bent and rigid enough to be cut off, but when the container body becomes large like a blister container such as sliced ham or bacon, the container is difficult to pick by hand or A material having a flexible container main body has no rigidity, and such a cutting method is inappropriate.

また、未接着部の、容器本体又は蓋材の少なくとも一方に凸部を設けて開封性を向上させる包装容器が提案されている(例えば特許文献1参照)。しかしながら、トリミングのエッジにおいて蓋材と容器本体との密着防止には十分なものではなく、特に真空包装においては、未接着部も真空にされて、容器本体と蓋材間に大気圧に準ずる圧力が印加され、且つ接着部に近接するためにある程度の熱も加わり、一旦形成した凹凸部が押しつぶされて、所望の易開封性向上効果を十分に得られないという問題がある。
特開2002−302158号公報
In addition, a packaging container has been proposed in which a convex portion is provided on at least one of the container main body or the lid member of the non-adhered portion to improve openability (see, for example, Patent Document 1). However, it is not sufficient to prevent the lid and container body from sticking together at the trimming edge. Especially in vacuum packaging, the non-bonded part is also evacuated, and the pressure corresponding to the atmospheric pressure between the container body and the lid material. Is applied, and a certain amount of heat is applied to approach the bonded portion, and the uneven portion once formed is crushed, and the desired easy-opening improvement effect cannot be sufficiently obtained.
JP 2002-302158 A

そこで本発明は、上記問題を解決すべくなされたものであり、蓋体を容易に摘むことができ、蓋体を容器本体から剥離させることにより簡単に開封して内容物を取り出せることのできる易開封性ブリスター容器を提供することである。   Accordingly, the present invention has been made to solve the above-described problems, and can easily pick the lid and easily remove the lid from the container body so that the contents can be taken out. It is to provide an openable blister container.

本発明は、上記課題を達成するために、請求項1記載の本発明は、一方に開口部を有し内容物を収納する凹部と該凹部の周縁にフランジ部を備えた容器本体と、該容器本体の前記開口部と前記フランジ部を覆い前記フランジ部の外縁と略同じ大きさの蓋体とが、前記フランジ部の周縁部に設けられた第一熱接着部で熱接着された四角形状のブリスター容器において、一つの辺の前記第一熱接着部の内周縁と前記開口部の周縁との間に頂部を有し、該頂部より前記開口部側に向かい拡開し一つの辺に隣接して対向する他の二辺の第一熱接着部に接続する斜めシール部を備えた第二熱接着部が前記フランジ部に設けられ、該第二熱接着部で前記蓋体と前記容器本体が剥離可能に熱接着され、前記第二熱接着部の前記頂部と対向する一つの辺の前記第一熱接着部に未シール部を設けて、前記頂部を跨ぎ前記第二熱接着部若しくはその近傍から前記未シール部の外縁に達しそれぞれ前記蓋体を貫通する切れ目線が形成されて前記頂部をそれぞれの前記切れ目線及び前記未シール部の外縁で囲まれる開封用摘み部が設けられ、前記開封用摘み部のそれぞれの前記切れ目線の第二熱接着部側の端部又はその近傍から前記斜めシール部若しくはその外縁周辺の未シール部分に前記斜めシール部に沿って二方向に延伸しそれぞれが交わることなく終端する開封用切れ目線が前記蓋体に設けられ、前記開封用摘み部より前記開封用切れ目線に沿って開封することを特徴とする易開封性ブリスター容器である。   In order to achieve the above object, the present invention is characterized in that the present invention according to claim 1 includes a recess having an opening on one side and containing contents, a container body having a flange on the periphery of the recess, A quadrangular shape that covers the opening of the container body and the flange portion and is thermally bonded by a first heat bonding portion provided on the peripheral edge of the flange portion, and a lid body having the same size as the outer edge of the flange portion. The blister container has a top portion between the inner peripheral edge of the first thermal bonding portion on one side and the peripheral edge of the opening portion, and is expanded from the top portion toward the opening portion side and adjacent to one side. A second thermal bonding portion having an oblique seal portion connected to the first thermal bonding portions on the other two sides facing each other is provided on the flange portion, and the lid body and the container body are provided at the second thermal bonding portion. Is heat-bonded so as to be peelable, and the one side of the second heat-bonding portion that faces the top portion of the second heat-bonding portion An unsealed portion is provided in one heat-bonded portion, straddling the top portion, reaching the outer edge of the unsealed portion from the second heat-bonded portion or its vicinity, and forming a cut line that penetrates the lid body, respectively. Opening knobs surrounded by the respective cut lines and the outer edges of the unsealed parts are provided, and the diagonal lines are formed from the end of the cut line of each of the opening knobs on the second heat bonding part side or in the vicinity thereof. An opening cut line extending in two directions along the oblique seal portion and ending without crossing the seal portion or an unsealed portion around the outer edge of the seal portion is provided on the lid, and the opening is opened from the opening knob. It is an easy-open blister container characterized by being opened along the cut line.

本発明のブリスター容器は、蓋体を貫通する切れ目線が形成されて開封用摘み部が設けられており、容器本体と密着することがなく、蓋体と容器本体が容易に分離でき、開封用摘み部を手指で摘むことができる。開封用切れ目線が第二熱接着部の斜めシール部若しくはその外縁周辺の未シール部分に斜めシール部に沿って蓋体に設けられ、第二熱接着部で蓋体と容器本体が剥離可能に熱接着されており、開封用摘み部より開封用切れ目線に沿って容易に、しかも容器を持ち替えることなく開封することができる。   The blister container of the present invention has a cut line that penetrates the lid and is provided with an opening knob, so that the lid and the container main body can be easily separated without being in close contact with the container main body. The picking part can be picked with fingers. An opening cut line is provided on the lid body along the oblique seal portion at the oblique seal portion of the second thermal bonding portion or the unsealed portion around the outer edge thereof, and the lid body and the container body can be peeled off at the second thermal bonding portion. It is thermally bonded and can be easily opened from the opening knob along the opening cut line without changing the container.

上記の本発明について、図面等を用いて以下に説明する。
図1は本発明にかかる易開封性ブリスター容器の第一実施形態を示す平面図、図2は図1のX−X線断面図、図3は図1の円内の切れ目線及び切れ目を示す拡大図、図4は易開封性ブリスター容器の開封途中の状態を示す斜視図であり、図中の符号1は易開封性ブリスター容器、2は蓋体、3は容器本体、4は開口部、5は凹部、6はフランジ部、7は第一熱接着部、8は第二熱接着部、8aは頂部、8bは斜めシール部、8aaは直線シール部、8abは山型シール部、9は切れ目線、10は開封用摘み部、11は開封用切れ目線、12は切れ目、12aは直線部、12bは斜線部、12hは切れ目の先端、12tは切れ目の後端、13、16は基材層、14、17は中間層、15、18は熱接着性樹脂層、19は引裂き片、121は一番目の切れ目、122は次(二番目)の切れ目、L1は一つの辺、L2は一つの辺と対向する辺、M1、M2は対向する他の二辺、Nは未シール部をそれぞれ示す。
The above-described present invention will be described below with reference to the drawings.
1 is a plan view showing a first embodiment of an easily openable blister container according to the present invention, FIG. 2 is a sectional view taken along line XX of FIG. 1, and FIG. 3 is a broken line and a cut in the circle of FIG. FIG. 4 is an enlarged view, and FIG. 4 is a perspective view showing a state in the middle of opening of the easily openable blister container. Reference numeral 1 in the figure denotes an easily openable blister container, 2 denotes a lid, 3 denotes a container body, 4 denotes an opening, 5 is a concave portion, 6 is a flange portion, 7 is a first thermal bonding portion, 8 is a second thermal bonding portion, 8 a is a top portion, 8 b is an oblique sealing portion, 8 aa is a linear sealing portion, 8 ab is a mountain-shaped sealing portion , 9 cut lines 10 opening knob portion 11 is opening for cut line, 12 is cut, 12a linear portion, 12b are shaded area, 12h is the cut tip, 12t rear end of the cut, 13, 16 group Material layer, 14 and 17 are intermediate layers, 15 and 18 are heat-adhesive resin layers, 19 is a tear piece, 121 is one The second cut , 122 is the next (second) cut , L1 is one side, L2 is the side facing one side, M1 and M2 are the other two sides facing each other, and N is the unsealed part .

本発明の易開封性ブリスター容器の第一実施形態は図1、図2に示すとおりである。一方に開口部4を有し内容物を収納する略円筒形の凹部5と凹部5の周縁にフランジ部6を備えた容器本体3と、容器本体3の開口部4とフランジ部6を覆いフランジ部6の外縁と略同じ大きさの蓋体2とが、フランジ部6の周縁部に設けられた第一熱接着部7で熱接着された四角形状の易開封性ブリスター容器1である。一つの辺L1の第一熱接着部7の内周縁と開口部4の周縁との間に頂部8aを有し、該頂部8aより開口部4側に向かい拡開し一つの辺L1に隣接して対向する他の二辺M1、M2の第一熱接着部7に接続する斜めシール部8bとで構成され、一つの辺L1の第一熱接着部7側に凸形状の第二熱接着部8がフランジ部6に設けられ、第二熱接着部8で蓋体2と容器本体3が剥離可能に熱接着されている。さらに第二熱接着部8の頂部8aと対向する一つの辺L1の第一熱接着部7に未シール部Nが設けられ、頂部8aを跨ぎ第二熱接着部8若しくはその近傍から未シール部Nの外縁に達しそれぞれ蓋体2を貫通する切れ目線9、9が形成されて頂部8aをそれぞれの切れ目線9、9及び未シール部Nの外縁で囲まれる開封用摘み部10が設けられている。切れ目線9には蓋体2を貫通しない歯止めを部分的に適宜、設けてもよい。さらに開封用摘み部10のそれぞれの切れ目線9、9の第二熱接着部8側の端部から斜めシール部8b若しくはその外縁周辺の未シール部分に斜めシール部8bに沿って開封用切れ目線11、11が蓋体2に設けられている。開封用切れ目線11は、斜めシール部8bに設けてもよいが、開封性等から斜めシール部8bの外縁周辺の未シール部分に設けるほうが好ましい。容器本体3の凹部5の形状は、上記の形状に限定されるものでなく、角型、楕円型等の種々の形状にできる。   The first embodiment of the easy-open blister container of the present invention is as shown in FIGS. A substantially cylindrical recess 5 having an opening 4 on one side and a container body 3 provided with a flange 6 on the periphery of the recess 5, and a flange covering the opening 4 and the flange 6 of the container body 3 The lid 2 having the same size as the outer edge of the portion 6 is a quadrangular easy-open blister container 1 thermally bonded by a first thermal bonding portion 7 provided on the peripheral edge of the flange portion 6. There is a top 8a between the inner peripheral edge of the first thermal bonding portion 7 on one side L1 and the peripheral edge of the opening 4, and it expands from the top 8a toward the opening 4 and is adjacent to one side L1. And an oblique seal portion 8b connected to the first thermal bonding portion 7 of the other two sides M1 and M2 facing each other, and a convex second thermal bonding portion on the first thermal bonding portion 7 side of one side L1 8 is provided on the flange portion 6, and the lid body 2 and the container main body 3 are thermally bonded by the second thermal bonding portion 8 so as to be peelable. Furthermore, the unsealed part N is provided in the 1st heat bonding part 7 of 1 side L1 facing the top part 8a of the 2nd heat bonding part 8, and it straddles the top part 8a and the unsealed part from the 2nd heat bonding part 8 or its vicinity. There are provided opening knobs 10 that are formed with cut lines 9 and 9 that reach the outer edge of N and pass through the lid 2 respectively, and the top portion 8a is surrounded by the cut lines 9 and 9 and the outer edge of the unsealed part N. Yes. The break line 9 may be appropriately provided with a pawl that does not penetrate the lid 2. Furthermore, the opening cut line along the oblique seal portion 8b extends from the end of each of the cut line portions 9 and 9 of the opening knob 10 to the oblique seal portion 8b or the unsealed portion around the outer edge thereof. 11 and 11 are provided on the lid 2. The opening cut line 11 may be provided in the oblique seal portion 8b, but it is preferable to provide it in an unsealed portion around the outer edge of the oblique seal portion 8b in view of the unsealing property. The shape of the concave portion 5 of the container body 3 is not limited to the above shape, and can be various shapes such as a square shape and an elliptical shape.

第二熱接着部8の頂部8aは、一つの辺L1に平行な所定長さの直線シール部8aaを有し、該直線シール部8aaには、一つの辺L1側に突出した1ケないしは複数の山型シール部8abが設けられている。このような構成にすることにより、開封用摘み部10を摘み、蓋体2を容器本体3より開封する際に、開封初期に必要な引張り力を少なくすることができ、開封用摘み部10を引張って容易に剥離することができ、スムーズに開封開始ができる効果を奏するものである。山型シール部8abの突出した山の数は開封用摘み部10の一つの辺L1と平行する側の長さにより1ケないし複数設けることができ、該長さが長くなれば複数の山の数を設けるのが好ましい。なお、山型シール部8abを設けなくても開封できるが、設けたほうがスムーズな開封開始ができるので好ましい。また、頂部8aに直線シール部8aaを設けずに、例えば、山型、丸型、突起状等の形状でもよく、記載の形状に限定されるものではない。   The top portion 8a of the second thermal bonding portion 8 has a linear seal portion 8aa having a predetermined length parallel to one side L1, and the linear seal portion 8aa includes one or a plurality of protrusions projecting toward one side L1. The chevron-shaped seal portion 8ab is provided. By adopting such a configuration, when the opening knob 10 is picked and the lid 2 is opened from the container body 3, the tensile force required at the initial stage of opening can be reduced. It can be easily peeled off by pulling, and has the effect of opening smoothly. The number of protruding peaks of the chevron-shaped seal portion 8ab may be one or more depending on the length of the opening knob 10 parallel to one side L1, and if the length becomes longer, It is preferable to provide a number. In addition, although it can open even if it does not provide the mountain-shaped seal | sticker part 8ab, since the opening start can be performed smoothly, providing is preferable. Moreover, without providing the linear seal | sticker part 8aa in the top part 8a, shapes, such as a mountain shape, a round shape, a protrusion shape, may be sufficient, for example, and it is not limited to the shape of description.

次に、蓋体2と容器本体3とが熱接着された第一熱接着部7及び第二熱接着部8を剥離可能とする蓋体2及び容器本体3の積層構成について説明する。蓋体2の構成としては図2に示すように、収納される内容物に対して要求される化学的保護機能(ガスバリア性、透湿度等)や物理的保護機能(引張強度、衝撃強度等)により、基材層13/印刷層(図示しない)/中間層14/熱接着性樹脂層15又は基材層13/印刷層(図示しない)/熱接着性樹脂層15を基本構成として適宜設計することができる。基材層13にはナイロン、ポリエチレンテレフタレート、ポリプロピレン等の二軸延伸されたプラスチックフィルム並びにこれらのフィルムにポリビニルアルコール、塩化ビニリデン等のバリア材がコートされたフィルム及び酸化珪素、酸化アルミ等の無機物が蒸着されたフィルムが使用される。図示しないが、印刷層は、例えば基材層13の中間層14と対向した面にグラビア印刷され設けられる。中間層14にはエチレンビニルアルコール等のバリアフィルム、アルミ箔、アルミ等の金属が蒸着されたフィルム及び上記基材層13に使用されるフィルムが使用される。熱接着性樹脂層15には、ポリエチレン、エチレン・酢酸ビニル共重合体、アイオノマー、ポリプロピレンないしは易剥離性熱接着性樹脂(EPR)等をフィルム又はエクストルージョンラミネーションして使用される。なお、EPRの易剥離性を付与する方法として表面に接着力の弱い薄層を設けた多層構成とする方法や、相溶性の少ない樹脂をブレンドするなどの構成により易剥離性を発現させる方法などの公知のものが適宜採用される。上記の各層はドライラミネーション法やエクストルージョンラミネーション法等の公知の技法により積層され積層材が構成される。例えば、蓋体2の具体的積層構成例として、以下のような構成が挙げられる。
(1)OPP/DL/PET/DL/PEF又はEVA又はアイオノマー
(2)PET/DL/EPR
(3)PET/DL/ON/DL/PEF
(4)OPP/DL/PEF又はCPP
(5)ON/DL/PEF
尚、前記構成例の記載に用いた略記号は次の通りである。OPP:二軸延伸ポリプロピレンフィルム、PET:二軸延伸ポリエステルフィルム、PEF:ポリエチレンフィルム、EVA:エチレン・酢酸ビニル共重合体、CPP:未延伸ポリプロピレンフィルム、DL:ドライラミネート接着剤を示す。
Next, the laminated structure of the lid body 2 and the container body 3 that can peel the first thermal bonding portion 7 and the second thermal bonding portion 8 to which the lid body 2 and the container body 3 are thermally bonded will be described. As shown in FIG. 2, the structure of the lid 2 is a chemical protection function (gas barrier property, moisture permeability, etc.) and a physical protection function (tensile strength, impact strength, etc.) required for the contents to be stored. Thus, the base material layer 13 / printing layer (not shown) / intermediate layer 14 / thermoadhesive resin layer 15 or the base material layer 13 / printing layer (not shown) / thermoadhesive resin layer 15 is appropriately designed as a basic configuration. be able to. The base layer 13 is made of a biaxially stretched plastic film such as nylon, polyethylene terephthalate, or polypropylene, a film in which a barrier material such as polyvinyl alcohol or vinylidene chloride is coated on these films, or an inorganic material such as silicon oxide or aluminum oxide. A vapor deposited film is used. Although not shown, the printing layer is provided by gravure printing on the surface of the base material layer 13 facing the intermediate layer 14, for example. For the intermediate layer 14, a barrier film such as ethylene vinyl alcohol, a film on which a metal such as aluminum foil or aluminum is deposited, and a film used for the base material layer 13 are used. For the heat-adhesive resin layer 15, polyethylene, ethylene / vinyl acetate copolymer, ionomer, polypropylene or easily peelable heat-adhesive resin (EPR) or the like is used after film or extrusion lamination. In addition, as a method for imparting easy peelability of EPR, a method of forming a multilayer structure in which a thin layer having a weak adhesive force is provided on the surface, a method of expressing easy peelability by a configuration such as blending a resin having low compatibility, etc. These known ones are appropriately employed. Each of the above layers is laminated by a known technique such as a dry lamination method or an extrusion lamination method to form a laminated material. For example, the following structure is mentioned as a specific laminated structure example of the cover body 2.
(1) OPP / DL / PET / DL / PEF or EVA or ionomer (2) PET / DL / EPR
(3) PET / DL / ON / DL / PEF
(4) OPP / DL / PEF or CPP
(5) ON / DL / PEF
The abbreviations used in the description of the configuration examples are as follows. OPP: biaxially stretched polypropylene film, PET: biaxially stretched polyester film, PEF: polyethylene film, EVA: ethylene / vinyl acetate copolymer, CPP: unstretched polypropylene film, DL: dry laminate adhesive.

容器本体3の構成としては図2に示すように、収納される内容物に対して要求される化学的保護機能(ガスバリア性、透湿度等)や物理的保護機能(引張強度、衝撃強度等)及び成型性により、基材層16/中間層17/熱接着性樹脂層18又は基材層16/熱接着性樹脂層18を基本構成として適宜設計することができる。基材層16にはナイロン、ポリエチレンテレフタレート、ポリプロピレン、ポリアクリロニトリル、塩化ビニル等の未延伸のプラスチックフィルム並びにこれらのフィルムにポリビニルアルコール、塩化ビニリデン等のバリア材がコートされたフィルム等が使用される。中間層17にはエチレンビニルアルコール共重合体、塩化ビニリデン等のバリアフィルム等のフィルムが使用される。熱接着性樹脂層15には、ポリエチレン、エチレン・酢酸ビニル共重合体、アイオノマー、ポリプロピレンないしは易剥離性熱接着性樹脂(EPR)等をフィルム又はエクストルージョンラミネーションして使用される。上記の各層はドライラミネーション法やエクストルージョンラミネーション法等の公知の技法により積層され容器本体3を構成する容器材となる。また、容器本体3は、基材層16/中間層17/熱接着性樹脂層18、基材層16/熱接着性樹脂層18が共押出しフィルムでもよく、基材層16単層でもよい。蓋体2及び容器本体3の熱接着性樹脂層15、18にはEPRを用いる方が易開封性がより向上し、好ましい。また、この場合、EPRは蓋体2及び容器本体3の熱接着性樹脂層15、18の両層に使用してもよいし、いずれか一方でも良い。   As shown in FIG. 2, the configuration of the container body 3 includes chemical protection functions (gas barrier properties, moisture permeability, etc.) and physical protection functions (tensile strength, impact strength, etc.) required for the contents to be stored. Depending on the moldability, the base layer 16 / intermediate layer 17 / thermoadhesive resin layer 18 or the substrate layer 16 / thermoadhesive resin layer 18 can be appropriately designed as a basic configuration. For the base material layer 16, unstretched plastic films such as nylon, polyethylene terephthalate, polypropylene, polyacrylonitrile, vinyl chloride, and films obtained by coating these films with a barrier material such as polyvinyl alcohol and vinylidene chloride are used. For the intermediate layer 17, a film such as a barrier film such as an ethylene vinyl alcohol copolymer or vinylidene chloride is used. For the heat-adhesive resin layer 15, polyethylene, ethylene / vinyl acetate copolymer, ionomer, polypropylene or easily peelable heat-adhesive resin (EPR) or the like is used after film or extrusion lamination. Each of the above layers is a container material constituting the container body 3 by being laminated by a known technique such as a dry lamination method or an extrusion lamination method. In the container body 3, the base material layer 16 / intermediate layer 17 / thermoadhesive resin layer 18 and the base material layer 16 / thermoadhesive resin layer 18 may be coextruded films, or the base material layer 16 may be a single layer. It is preferable to use EPR for the thermoadhesive resin layers 15 and 18 of the lid 2 and the container body 3 because the easy-opening property is further improved. In this case, the EPR may be used for both the heat-adhesive resin layers 15 and 18 of the lid body 2 and the container body 3, or any one of them may be used.

図1、図3を用いて本発明の易開封性ブリスター容器の開封部分の構成について詳しく説明する。図3は図1の円内の拡大図であって、開封部分の構成を示す。蓋体2に設けられた開封用切れ目線11は、間欠した切れ目12からなり、該切れ目12が、斜めシール部8bと平行方向の直線部12aと、該直線部12aの開封用摘み部方向に対して後端側より一つの辺L1に隣接して対向する他の二辺M1、M2に向かい直線部12aに対して鈍角で斜めに延びた斜線部12bとからなり、一番目の切れ目121の先端12hが開封用摘み部10の切れ目線9の第二熱接着部8側の端部と連接して形成され、開封用摘み部10より開封用切れ目線11に沿って開封する構成となっている。開封用切れ目線11の切れ目121の後端12tと、二番目の切れ目122の直線部12aの先端12hとが、開封方向に対して一致するか若しくは少なくとも重なって形成されていることが好ましい。そうすることにより、開封用摘み部10を引張って蓋体2を開封すると、一番目の切れ目121の後端12tから蓋体2が引裂かれて、二番目の切れ目122に連結し、二番目の切れ目122により、引裂き方向が、次の三番目の切れ目に案内され、順次、同様に繰り返され開封用切れ目線11から外れて開封不能になることを防ぐことができ、開封用切れ目線11に沿って開封できる。また、切れ目12の形状は、直線や例えば、くの字やへの字等の屈曲線、U字等の曲線、若しくはこれらの組合せなどを用いることができるが、直線や屈曲線がシンプルで好ましい。尚、一番目の切れ目121、二番目の切れ目122の符号は説明上、付したものであり、切れ目12と形状、機能とも同一のものである。   The structure of the opening part of the easily openable blister container of this invention is demonstrated in detail using FIG. 1, FIG. FIG. 3 is an enlarged view in the circle of FIG. 1 and shows the structure of the opening portion. The opening cut line 11 provided on the lid body 2 includes intermittent cuts 12, and the cuts 12 extend in a direction parallel to the oblique seal portion 8b and a straight portion 12a in the direction of the opening knob of the straight portion 12a. On the other hand, it consists of a slanted line portion 12b extending obliquely at an obtuse angle with respect to the straight line portion 12a toward the other two sides M1 and M2 facing each other adjacent to one side L1 from the rear end side. The front end 12h is formed so as to be connected to the end portion on the second thermal bonding portion 8 side of the cut line 9 of the opening knob 10 and is opened along the opening cut line 11 from the opening knob 10. Yes. It is preferable that the rear end 12t of the cut 121 of the opening cut line 11 and the tip 12h of the straight portion 12a of the second cut 122 coincide with each other or at least overlap with each other. By doing so, when the opening knob 10 is pulled to open the lid 2, the lid 2 is torn from the rear end 12 t of the first cut 121 and is connected to the second cut 122. The tear 122 guides the tearing direction to the next third break, and can be repeated in the same manner to prevent the tearing line 11 from coming off from the opening break line 11 and becoming unopenable, along the opening break line 11. Can be opened. In addition, as the shape of the cut line 12, a straight line, for example, a bent line such as a character or a hem, a curved line such as a U-character, or a combination of these can be used, but a straight line or a bent line is simple and preferable. . In addition, the code | symbol of the 1st cut | interruption 121 and the 2nd cut | interruption 122 is attached | subjected on description, and the cut | disconnection 12 and a shape and a function are the same.

次に、蓋体2の製造方法について説明する。まず最初に基材層13の中間層14に対向する面にグラビア印刷方式で印刷絵柄を裏刷する。その後、中間層14、熱接着性樹脂層15を順次、ドライラミネーション法又はエクストルージョンラミネーション法で積層し、蓋材の巻取が製造される。次に抜き工程で得られた蓋材の巻取を巻き戻しながら、印刷見当に合せて所定位置に切れ目線9及び切れ目12を基材層13、中間層14、熱接着性樹脂層15まで貫通するように例えば、ロータリーダイカッターを用いて形成され、開封用摘み部10及び開封用切れ目線11が設けられ、蓋体2が製造される。なお、印刷絵柄は中間層14の基材層13に対向する面又は熱接着性樹脂層15に対向する面に設けてもよい。   Next, a method for manufacturing the lid 2 will be described. First, a printed pattern is back printed on the surface of the base material layer 13 facing the intermediate layer 14 by a gravure printing method. Thereafter, the intermediate layer 14 and the heat-adhesive resin layer 15 are sequentially laminated by the dry lamination method or the extrusion lamination method, and the winding of the lid material is manufactured. Next, while rewinding the winding of the cover material obtained in the punching process, the cut line 9 and the cut line 12 are penetrated to the base material layer 13, the intermediate layer 14, and the thermoadhesive resin layer 15 at predetermined positions according to the printing register. For example, the lid 2 is manufactured by using a rotary die cutter, provided with the opening knob 10 and the opening cut line 11. The printed pattern may be provided on the surface of the intermediate layer 14 facing the base material layer 13 or the surface facing the thermoadhesive resin layer 15.

次に、本発明の易開封性ブリスター容器1の製造方法について説明する。上記で製造された蓋体2と、上記で説明した方法で作製された容器材をそれぞれ所定の幅に切断して巻取とした後に、成型インライン充填機械で製造される。まず、容器材が巻き戻され熱成型され凹部5とフランジ部6を有する容器本体3が製造される。その後、凹部5に内容物が収納された後、蓋体2が巻き戻され容器本体3と蓋体2とが所定位置になるように見当合せしながら容器本体3のフランジ部6、開口部4及び内容物を覆い第一熱接着部7、第二熱接着部8で蓋体2と容器本体3とを剥離可能に熱接着し、内容物が封入され、易開封性ブリスター容器1が製造される。成型方法は真空成型、圧空成型、真空圧空成型などの熱成型方法が使用できる。また、内容物に要求される保存性により、真空包装、窒素ガスや炭酸ガスあるいはその混合ガスなどを封入するガス充填包装、脱酸素剤封入包装、含気包装などの包装技法を併用することができる。なお、容器本体3は一旦、別工程で熱成型してトリミングしたものを使用してもよい。この場合には、容器本体3には、熱可塑性樹脂をインジェクション成型して用いることもできる。   Next, the manufacturing method of the easily openable blister container 1 of this invention is demonstrated. The lid body 2 manufactured above and the container material manufactured by the method described above are each cut into a predetermined width and wound, and then manufactured by a molding inline filling machine. First, the container body 3 having the recess 5 and the flange 6 is manufactured by being rewound and thermoformed. Thereafter, after the contents are stored in the recess 5, the lid 2 is rewound and the container body 3 and the lid 2 are aligned so that the container body 3 and the lid 2 are in a predetermined position, and the flange portion 6 and the opening 4 of the container body 3. And the cover 2 and the container body 3 are heat-bonded to be peelable by the first heat bonding part 7 and the second heat bonding part 8 so as to cover the contents, the contents are enclosed, and the easily openable blister container 1 is manufactured. The As the molding method, a thermoforming method such as vacuum molding, pressure molding, vacuum pressure molding or the like can be used. In addition, depending on the preservability required for the contents, packaging techniques such as vacuum packaging, gas-filled packaging in which nitrogen gas, carbon dioxide gas or a mixed gas thereof is enclosed, oxygen scavenger packaging, and aeration packaging may be used in combination. it can. In addition, you may use the container body 3 which was once thermoformed and trimmed in another process. In this case, the container body 3 can be used by injection molding a thermoplastic resin.

次に、図4を用いて本発明の易開封性ブリスター容器1の開封方法について説明する。該易開封性ブリスター容器1の蓋体2に設けられた開封用摘み部10を手指で摘み、上に引張りながら一つの辺L1と対向する辺L2の方向に開封すると切れ目線9に連接した一番目の切れ目121の後端12tから開口部4の方向に蓋体2が引裂かれ二番目の切れ目122に達すると二番目の切れ目122に沿って開封方向が案内され、順次、同じことが繰返され、開封用切れ目線11に沿って、蓋体2が引裂かれて引裂き片19が形成されると共に、開口部4と内容物(図示しない)が現れる。開封用切れ目線11が第一熱接着部7に達し、さらに引裂き片19を引張ると第一熱接着部7に沿って、蓋体2と容器本体3との間で剥離して引裂き片19が取除かれて開口部4が開口され、内容物を容易に取出すことが可能となる。このように、開封用摘み部10を一つの辺L1の中央に予め蓋体2を貫通する切れ目線9、9と未シール部Nの外縁で囲まれるように設けることにより、従来の角部に設けた開封用摘み部が容器本体と密着して容易に開封用摘み部を容器本体から分離して摘みにくいという問題を解決し、開封用摘み部10を容易に摘み開封することができるものである。   Next, the opening method of the easily openable blister container 1 of this invention is demonstrated using FIG. When the opening knob 10 provided on the lid 2 of the easy-open blister container 1 is picked with fingers and opened upward in the direction of the side L2 opposite to the side L1, one connected to the cut line 9 is connected. When the lid 2 is torn from the rear end 12t of the second cut 121 in the direction of the opening 4 and reaches the second cut 122, the opening direction is guided along the second cut 122, and the same is repeated sequentially. The lid 2 is torn along the opening cut line 11 to form a tear piece 19, and the opening 4 and contents (not shown) appear. When the opening cut line 11 reaches the first thermal bonding portion 7 and the tear piece 19 is further pulled, the tear piece 19 is peeled along the first thermal bonding portion 7 between the lid body 2 and the container body 3. It is removed and the opening 4 is opened, and the contents can be easily taken out. In this way, by providing the opening knob 10 at the center of one side L1 so as to be surrounded by the cut lines 9, 9 penetrating the lid 2 in advance and the outer edge of the unsealed portion N, the conventional corner portion is provided. The provided opening knob is in close contact with the container body, and the opening knob is easily separated from the container body and is difficult to pick. The opening knob 10 can be easily picked and opened. is there.

次に、本発明について、以下に実施例を挙げてさらに詳しく説明する。   Next, the present invention will be described in more detail with reference to the following examples.

実施例1
厚さ12μmの二軸延伸ポリエチレンテレフタレートフィルム(PET)の片面にグラビア印刷法によりポリウレタン系インキで所定の印刷を行い、印刷面に、ポリエステルポリオール−イソシアネート系接着剤を介して厚さ30μmの片面コロナ処理されたEPRフィルム(東セロ化学株式会社製、CMPS013C)のコロナ処理面とをドライラミネーション法で積層し、40℃、2日間養生して蓋体に使用する蓋材を作製した。
[ Example 1 ]
One side of a 12 μm thick biaxially stretched polyethylene terephthalate film (PET) is subjected to predetermined printing with a polyurethane ink by a gravure printing method, and a single side corona with a thickness of 30 μm is applied to the printed surface via a polyester polyol-isocyanate adhesive. A corona-treated surface of the treated EPR film (CMPS013C, manufactured by Tosero Chemical Co., Ltd.) was laminated by a dry lamination method, and cured at 40 ° C. for 2 days to produce a lid material used for the lid.

厚さ40μの未延伸ナイロンフィルム(CN)と厚さ50μmの片面コロナ処理された未延伸ポリプロピレンフィルムのコロナ処理面とをポリエステルポリオール−イソシアネート系接着剤を介してドライラミネーション法で積層し、40℃、2日間養生して容器本体に使用する容器材を作製した。   An unstretched nylon film (CN) having a thickness of 40 μm and a corona-treated surface of a single-sided corona-treated polypropylene film having a thickness of 50 μm were laminated by a dry lamination method through a polyester polyol-isocyanate adhesive, and 40 ° C. The container material used for a container main body was produced after curing for two days.

上記の容器材を用いて、真空深絞り成型し深さ15mm×直径100mmの凹部を有する170mm×135mmの角形の容器本体を作製した。上記の蓋材の所定位置に長さ(図1におけるM1からM2方向)40mm×幅(図1におけるL1からL2方向)20mmの開封用摘み部を設けて、直線部5mm、斜線部2.5mm、直線部と斜線部で形成する角度135°の切り目を切り目の後端と次の切り目の先端が開封方向に対して一致する位置に形成し、開封用切れ目線を設けて蓋体を作製した。その後、容器本体の開口部とフランジ部を覆い、一つの辺の中央に開封用摘み部が位置するようにして、第一熱接着部、第二熱接着部で蓋体と容器本体とを剥離可能に熱接着して柔軟性のあるソフトタイプの易開封性ブリスター容器1を作製した。なお、第二熱接着部8の頂部8aは約15mmの直線シール部8aaとし、該部に一つの辺L1側に2.5mm突出した5ケの山型シール部とした。   Using the container material described above, a 170 mm × 135 mm rectangular container body having a concave portion having a depth of 15 mm × diameter of 100 mm was formed by vacuum deep drawing. An opening knob having a length (M1 to M2 direction in FIG. 1) of 40 mm × width (L1 to L2 direction in FIG. 1) 20 mm is provided at a predetermined position of the lid member, and a straight portion is 5 mm and a hatched portion is 2.5 mm. In addition, a 135 ° angled cut formed by the straight line portion and the hatched portion is formed at a position where the rear end of the cut and the front end of the next cut coincide with the opening direction, and a lid is prepared by providing the opening cut line. . Then, cover the opening and flange of the container body, and the lid and container body are peeled off by the first and second thermal bonding sections so that the opening knob is located at the center of one side. A flexible soft type easy-open blister container 1 was prepared by heat bonding. In addition, the top part 8a of the 2nd heat bonding part 8 was made into the linear seal part 8aa of about 15 mm, and was made into the 5 mountain-shaped seal part which protruded 2.5 mm in the one side L1 side in this part.

実施例2
厚さ250μの片面コロナ処理された未延伸ポリプロピレンシートのコロナ処理面と片面コロナ処理されたEPRフィルム(住友ベークライト株式会社製、CEL4541)のコロナ処理面とをポリエステルポリオール−イソシアネート系接着剤を介してドライラミネーション法で積層し、40℃、2日間養生して容器本体に使用する容器材を作製した。蓋材は実施例1と同じ蓋材を用いて、剛性のあるハードタイプの実施例1と同じ易開封性ブリスター容器1を作製した。
[ Example 2 ]
Through a polyester polyol-isocyanate adhesive, a corona-treated surface of a single-sided corona-treated unstretched polypropylene sheet having a thickness of 250 μm and a corona-treated surface of a single-sided corona-treated EPR film (manufactured by Sumitomo Bakelite Co., Ltd., CEL4541). The container material used for a container main body was produced by laminating by a dry lamination method and curing at 40 ° C. for 2 days. The same lid material as in Example 1 was used as the lid material, and the same easy-open blister container 1 as in Hard Type Example 1 was produced.

[比較例1]
実施例1と同じ容器本体と、実施例1と同じ蓋材を用いて、蓋材に開封用切れ目線及び開封用摘み部を形成する切れ目線を設けない蓋体とを用いて、フランジ部を剥離可能に熱接着した、実施例1と同様の大きさの柔軟性のあるソフトタイプの易開封性ブリスター容器を作成した。尚、一つの角部に蓋体と容器本体との未接着部を形成して開封用摘み部を設けた。
[Comparative Example 1]
Using the same container main body as in Example 1 and the same lid material as in Example 1, using the lid body that does not provide the cut line for opening and the cut line for opening on the lid material, the flange portion is A soft type easy-open blister container having the same size as that of Example 1 and thermally bonded so as to be peeled was prepared. In addition, an unbonded portion between the lid and the container main body was formed at one corner portion to provide an opening knob.

実施例1〜の易開封性ブリスター容器は、開封用摘み部を辺の中央に設けているために、一方の手指で容器の一端を摘み、他方の手で開封用摘み部を容易に摘むことができ、開封用切れ目線に沿って、第二熱接着部及び第一熱接着部で容器本体と蓋体とが剥離され、容器を持ち替えることなく開封することができ、内容物を容易に取出せた。比較例1は、蓋体と容器本体は密着して容易に角部に設けた開封用摘み部を容器本体から分離して摘みにくく、しかも、開封摘み部が角部のために、蓋体を剥離し、内容物を取り出すまでに何度も容器を持ち替える必要があり、煩わしいものであった。このように、本願発明の易開封性ブリスター容器の開封用摘み部は、辺の中央に設けられているために、開封時に、一方の手指で容器の中央が摘めると共に、開封用摘み部は蓋体を貫通する切れ目線で形成されているために、容器本体と蓋体が密着することもなく他方の手で開封用摘み部を容易に摘むことができ、容器を持ち替えることなくスムーズに開封できるという効果を奏するものである。 Since the easy-open blister containers of Examples 1 and 2 have the opening knob at the center of the side, one end of the container is picked with one finger, and the opening knob is easily picked with the other hand. The container body and the lid body are peeled off at the second heat bonding portion and the first heat bonding portion along the opening cut line, and can be opened without changing the container, and the contents can be easily I was able to take it out. In Comparative Example 1, the lid and the container main body are in close contact with each other, and the opening knob provided at the corner is easily separated from the container main body. It was annoying because it was necessary to change the container many times before peeling and taking out the contents. In this way, since the opening knob of the easily openable blister container of the present invention is provided at the center of the side, at the time of opening, the center of the container can be gripped with one finger, and the opening knob is Since it is formed with a cut line that penetrates the lid, the container can be easily picked with the other hand without the container body and the lid closely contacting each other, and it can be opened smoothly without changing the container. It has the effect of being able to do it.

本発明にかかる易開封性ブリスター容器の第一実施形態を示す平面図である。It is a top view which shows 1st embodiment of the easily openable blister container concerning this invention. 図1のX−X線断面図である。It is the XX sectional view taken on the line of FIG. 図1の円内の切れ目線及び切れ目を示す拡大図である。It is an enlarged view which shows the cut line and cut in the circle | round | yen of FIG. 易開封性ブリスター容器の開封途中の状態を示す斜視図である。It is a perspective view which shows the state in the middle of opening of an easily openable blister container.

易開封性ブリスター容器
2 蓋体
3 容器本体
4 開口部
5 凹部
6 フランジ部
7 第一熱接着部
7a 突出シール部
第二熱接着部
8a 頂部
8b 斜めシール部
8aa 直線シール部
8ab 山型シール部
9 切れ目線
10 開封用摘み部
11 開封用切れ目線
12 切れ目
12a 直線部
12b 斜線部
12h 切れ目の先端
12t 切れ目の後端
13、16 基材層
14、17 中間層
15、18 熱接着性樹脂層
19 引裂き片
121 一番目の切れ目
122 次の切れ目
L1 一つの辺
L2 一つの辺と対向する辺
M1、M2 対向する他の二辺
N 未シール部
1 Easy-openable blister container 2 Lid 3 Container body 4 Opening part 5 Recessed part 6 Flange part 7 First heat bonding part 7a Protruding seal part
8 Second heat bonding part
8a top part 8b slant seal part 8aa linear seal part 8ab chevron seal part 9 cut line 10 picking part for opening
11 Opening line 12 Cutting line 12a Straight line part 12b Diagonal line part 12h Cutting edge 12t Cutting edge rear edge 13, 16 Base material layer 14, 17 Intermediate layer 15, 18 Thermal adhesive resin layer 19 Tear piece
121 First cut 122 Next cut L1 One side L2 One side facing one side M1, M2 Two other sides facing each other N Unsealed part

Claims (1)

一方に開口部を有し内容物を収納する凹部と該凹部の周縁にフランジ部を備えた容器本体と、該容器本体の前記開口部と前記フランジ部を覆い前記フランジ部の外縁と略同じ大きさの蓋体とが、前記フランジ部の周縁部に設けられた第一熱接着部で熱接着された四角形状のブリスター容器において、一つの辺の前記第一熱接着部の内周縁と前記開口部の周縁との間に頂部を有し、該頂部より前記開口部側に向かい拡開し一つの辺に隣接して対向する他の二辺の第一熱接着部に接続する斜めシール部を備えた第二熱接着部が前記フランジ部に設けられ、該第二熱接着部で前記蓋体と前記容器本体が剥離可能に熱接着され、前記第二熱接着部の前記頂部と対向する一つの辺の前記第一熱接着部に未シール部を設けて、前記頂部を跨ぎ前記第二熱接着部若しくはその近傍から前記未シール部の外縁に達しそれぞれ前記蓋体を貫通する切れ目線が形成されて前記頂部をそれぞれの前記切れ目線及び前記未シール部の外縁で囲まれる開封用摘み部が設けられ、前記開封用摘み部のそれぞれの前記切れ目線の第二熱接着部側の端部又はその近傍から前記斜めシール部若しくはその外縁周辺の未シール部分に前記斜めシール部に沿って二方向に延伸しそれぞれが交わることなく終端する開封用切れ目線が前記蓋体に設けられ、前記開封用摘み部より前記開封用切れ目線に沿って開封することを特徴とする易開封性ブリスター容器。 A recess having an opening on one side and containing the contents; a container body provided with a flange on the periphery of the recess; and covering the opening and flange of the container body and substantially the same size as the outer edge of the flange In the rectangular blister container thermally bonded by the first thermal bonding portion provided on the peripheral edge of the flange portion, the inner peripheral edge of the first thermal bonding portion on one side and the opening A slant seal part having a top part between the peripheral edge of the part and expanding to the opening part side from the top part and connected to the first two heat-bonding parts opposite to each other adjacent to one side A second thermal bonding portion provided on the flange portion, wherein the lid and the container body are thermally bonded in a peelable manner at the second thermal bonding portion, and are opposed to the top portion of the second thermal bonding portion. An unsealed portion is provided in the first thermal bonding portion on one side, and the second thermal welding is straddled across the top portion. An opening knob is provided in which a cut line that reaches the outer edge of the unsealed portion from the portion or the vicinity thereof and penetrates the lid is formed, and the top portion is surrounded by the cut line and the outer edge of the unsealed portion. From the end on the second thermal bonding part side of each of the cut lines of the opening knob or the vicinity thereof to the oblique seal part or the unsealed part around the outer edge thereof in two directions along the oblique seal part. An easy-open blister container, characterized in that an opening cut line that extends and terminates without crossing each other is provided on the lid, and is opened along the opening cut line from the opening knob.
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JP4422285B2 (en) * 1999-03-19 2010-02-24 パナソニック株式会社 Sealed package
JP2001002130A (en) * 1999-06-18 2001-01-09 Toppan Printing Co Ltd Easy full-openable cup
JP2001335065A (en) * 2000-05-30 2001-12-04 Tashichiro Harada Packaging bag
JP4549574B2 (en) * 2001-05-30 2010-09-22 大日本印刷株式会社 Packaging container
JP3084370U (en) * 2001-08-29 2002-03-22 株式会社カナオカ Packaging bag with easy-open means
JP4385685B2 (en) * 2003-09-02 2009-12-16 東洋製罐株式会社 Packaging bag

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