JP5067924B2 - Endless belt and image forming apparatus - Google Patents

Description

  The present invention relates to an endless belt and an image forming apparatus, and more particularly to an endless belt capable of forming a high-quality image over a long period of time and an image forming apparatus including the endless belt.

  In an electrophotographic image forming apparatus, an endless belt formed of a thermoplastic resin or the like is used instead of or in addition to a metal drum body or an elastic roller. Examples of such endless belts include a transfer belt, an intermediate transfer belt, a transfer conveyance belt, a conveyance belt, a fixing belt, and a development belt. These endless belts are usually stretched around a plurality of support rollers, and always run at a high speed while being repeatedly applied and stopped on an endless track in a tensioned state.

Such an endless belt is usually formed of a resin composition containing various resins. Resins contained in the resin composition forming the endless belt are, for example, polyamide imide resin, polyimide based on properties such as strength, flexibility, dimensional stability and heat resistance and properties required for the endless belt. Resin, polyamide resin, aramid resin, polyester (PET, PBT, etc.), polysulfone resin, epoxy resin, melamine resin, etc. are appropriately selected. As an endless belt formed from a resin composition, for example, “in a fixing / pressurizing belt for fixing an electrostatic image transferred to a transfer object, a belt body made of polyamide-imide resin and silicone on the surface of the belt body “Fixing / pressurizing belt characterized by forming a rubber coating layer” (see Patent Document 1), “Resin composition containing thermoplastic polyimide resin and conductive filler having specific surface area of 5 to 500 m ² / g” (Refer to Patent Document 2), and “in a single-layer endless belt made of synthetic resin, the glossiness with respect to the axial direction and the circumferential direction is anisotropic, and the axial direction thereof” And a single-layer endless belt characterized in that the glossiness of the toner is larger than that in the circumferential direction (see Patent Document 3).

  In general, in order to form a high-quality image in an image forming apparatus using an endless belt, the endless belt needs to have characteristics that allow the endless belt to transport a conveyed object such as a recording medium or developer as desired. In addition, it is required that the developer or the components contained in the developer are not fixed to the endless belt, and that the developer or the like carried on another member or the recording medium can be easily transferred. In addition, strength characteristics and the like that do not damage the endless belt are also required.

  Incidentally, in recent years, image forming apparatuses have been improved in lifespan, high definition, and high speed (that is, high speed of the endless belt). Accordingly, the endless belt has characteristics superior to those of conventional endless belts and can form high-quality images over a long period of time while realizing a long life, high definition and high speed of the image forming apparatus. Is required.

No. 6-397 JP-A-11-170389 JP 2005-10182 A

  An object of the present invention is to provide an endless belt capable of forming a high-quality image over a long period of time and an image forming apparatus including the endless belt.

As means for solving the problems,
In claim 1, trimellitic anhydride and diphenylmethane-4,4′-diisocyanate are 10 parts by mass with respect to 100 parts by mass in total of trimellitic anhydride and diphenylmethane-4,4′-diisocyanate. the following, an amino group, in the presence of polydimethylsiloxane terminated with at least one of the carboxy group and hydroxy group, with modified polyamideimide resin obtained by polymerizing formed in a single-layer structure, ISO folding number 6500 It is an endless belt characterized in that the loop stiffness is 150 to 450 mN after the rotation,
Claim 2 is the endless belt according to claim 1, characterized in that the water absorption is 1.8% or less,
Claim 3 is the endless belt according to claim 1 or 2, wherein the polydimethylsiloxane has a carboxy group at a terminal.
A fourth aspect of the present invention is an image forming apparatus provided with the endless belt according to any one of the first to third aspects .

  Since the endless belt according to the present invention is formed in a single-layer structure, the mechanical strength of each layer constituting the endless belt, the difference in Young's modulus, and the like, and damage to the multi-layer structure are compared to the multi-layer structure. As a result, the mechanical strength of the endless belt is not greatly reduced, and there is no occurrence of problems such as peeling between layers when the endless belt is mounted on the image forming apparatus and travels infinitely. In addition, since the endless belt according to the present invention has an ISO folding endurance of 6500 times or more, it has improved weather resistance, that is, durability against repeated bending fatigue. As a result, the endless belt according to the present invention is mounted on a conventional image forming apparatus and travels endlessly, or is mounted on an image forming apparatus that has a long life, high definition, and speed, and travels infinitely. However, the initial characteristics of the endless belt itself can be exhibited over a long period of time without greatly deteriorating. Therefore, according to the present invention, it is possible to provide an endless belt capable of forming a high-quality image over a long period of time and an image forming apparatus capable of forming a high-quality image over a long period of time.

  Hereinafter, an endless belt as an example of the present invention will be described with reference to the drawings. As shown in FIG. 1, the endless belt 1 is formed in an annular shape by a modified polyamideimide resin described later. The thickness of the endless belt 1 is not particularly limited, but usually, for example, preferably 0.03 to 1 mm, more preferably 0.05 to 0.2 mm, and about 0.07 to 0.14 mm. Is particularly preferred. If the thickness of the endless belt 1 is less than 0.03 mm, the mechanical strength of the endless belt 1 may decrease. On the other hand, if the thickness exceeds 1 mm, the flexibility of the endless belt 1 decreases and durability increases. May be inferior. The width and inner diameter of the endless belt 1 are set to a desired width according to the use of the endless belt 1, that is, the position (component) disposed in the image forming apparatus, the interval between a plurality of stretched rollers, and the like. And it is arbitrarily set so that it may become an inner peripheral diameter. For example, the endless belt 1 has a width of 200 to 350 mm and an inner peripheral diameter of 200 to 2,500 mm.

  As shown in FIG. 1, the endless belt 1 has a single layer structure. When the endless belt 1 is formed in a single layer structure, it may be attached to an image forming apparatus for a long period of time, or it may be attached to an image forming apparatus with a long life, high definition and high speed. It is possible to effectively prevent a decrease in mechanical strength due to a difference in mechanical strength, Young's modulus, etc. of each layer constituting the endless belt formed in the structure and damage of a multilayer structure, and endlessness. The layers constituting the belt 1 cannot be peeled off. As a result, the endless belt 1 having a single layer structure can form a high-quality image over a long period of time.

  The endless belt 1 has an ISO folding endurance of 6,500 times or more. If this ISO folding endurance is 6,500 times or more, the weather resistance, that is, the durability against repeated bending fatigue is improved. Even if the endless belt 1 is mounted on an image forming apparatus having a long life, high definition, and high speed and travels infinitely, the endless belt 1 can be prevented from being damaged such as cracks and cracks. As a result, the endless belt 1 can form a high-quality image over a long period of time. The ISO folding endurance number is preferably 6,800 times or more and particularly preferably 7,500 times or more in that a high-quality image can be formed for a longer period of time. On the other hand, the upper limit value of the ISO folding endurance number is not particularly limited. Actually, it may be, for example, about 12,000 times, but about 10,000 times depending on the use of the endless belt 1 or the like. It may be.

  The ISO folding endurance number can be obtained as follows. First, an MIT testing machine (for example, trade name “MIT-DA” manufactured by Toyo Seiki Seisakusho Co., Ltd.) is prepared, and the endless belt 1 or the endless belt 1 having dimensions of 15 mm in width, 150 mm in length and 100 μm in thickness. The test piece cut out in the above dimensions is clamped and fixed by a bending clamp (tip radius 0.38 mmR) equipped in the MIT testing machine. Next, the endless belt 1 fixed to the bending clamp or the free end of the test piece (width 15 mm × length about 100 mm) is clamped by a spring load clamp provided at a distance of 50 mm from the bending clamp of the MIT testing machine. To do. While pulling the endless belt 1 or the test piece with a load of 4.9 N, the bending clamp is rotated so that the bending angle becomes 90 degrees, and the endless belt 1 or the test piece is repeatedly bent. The number of reciprocal bendings until the endless belt 1 or the test piece breaks is defined as the number of folding times. This test is performed a plurality of times, for example, three times, the arithmetic average value of the common logarithm of the folding endurance number is obtained, and the true number of the obtained arithmetic average value is set as the ISO folding endurance number of the endless belt 1. Other than the above conditions, basically, the measurement conditions defined in JIS P8115 are followed.

  The ISO folding endurance number of the endless belt 1 can be adjusted according to the type of the modified polyamideimide resin, the conditions of the secondary solvent removing step described later, and the like.

  The endless belt 1 preferably has a water absorption rate of 1.8% or less. When the water absorption is 1.8% or less, the dimensional stability of the endless belt 1 is high, and the endless belt 1 is mounted on the image forming apparatus for a long period of time and / or mounted on the image forming apparatus at a high speed. Further, the endless belt 1 stretched around the support roller does not run idle, and the object to be conveyed such as the recording medium and the developer can be conveyed as desired. If the water absorption is 1.8% or less, the endless belt 1 can absorb moisture even if the endless belt 1 is used as an intermediate transfer belt and an amorphous silicon photosensitive drum or the like is used as an image carrier to be described later. It is possible to prevent the occurrence of the image flow phenomenon and to form a high quality image. Here, the image flow phenomenon refers to a phenomenon in which a-SiO generated from an amorphous silicon photosensitive drum and water are combined to reduce the electric resistance value on the surface of the amorphous silicon photosensitive drum, and the potential flows laterally. -SiO is generated when the surface of the amorphous silicon photosensitive drum is oxidized due to the effects of ozone, nitrogen oxides, etc. generated when the amorphous silicon photosensitive drum is charged. It is hydrophilic and binds to the water contained in the atmosphere or intermediate transfer belt. It has the characteristic of being easy. The water absorption is more preferably 1.65% or less, and particularly preferably 1.6% or less from the viewpoint that these characteristics are more excellent. The lower limit value of the water absorption rate is ideally 0%, but can be practically set to about 0.5%, for example. The lower limit value of the water absorption rate is not limited to about 0.5%, and may be, for example, about 0.3% in consideration of the characteristics of the endless belt 1, workability when adjusting the water absorption rate, and the like.

  The water absorption rate was measured in water adjusted to 25 ° C. after a test piece obtained by cutting the endless belt 1 into a size of 10 mm × 150 mm × 100 μm (thickness) was dried at 23 ° C. and 50% RH for 24 hours. For 24 hours, and the mass change before and after immersion is divided by the mass before immersion. This measurement is performed a plurality of times, for example, three times, and the arithmetic average value is defined as the water absorption rate of the endless belt 1.

  The water absorption rate of the endless belt 1 can be adjusted by the type of the modified polyamideimide resin and the conditions of the secondary solvent removing step described later.

  The endless belt 1 preferably has a Young's modulus of 1,500 to 4,000 MPa, more preferably 2,000 to 4,000 MPa, and particularly preferably 2,000 to 3,000 MPa. When the Young's modulus of the endless belt 1 is in the above range, the endless belt 1 is highly flexible and is not easily damaged or damaged even when stretched on a plurality of rollers, drive rollers, etc. in a state where a predetermined tension is applied. In addition, the amount of deformation of the endless belt 1 with respect to the stress during driving is reduced, and high quality image quality can be stably formed. If the Young's modulus of the endless belt 1 is in the above range, even if a magnetic two-component developer containing toner particles and carrier particles is used as the developer, the carrier particles are attached to the endless belt 1. The carrier particle pulling phenomenon is less likely to occur, and a high-quality image can be formed. Here, the carrier particle pulling phenomenon is a phenomenon in which, when carrier particles such as iron powder adhere to the surface of the endless belt 1, the nip interval between the endless belt 1 and the image carrier is locally increased. .

  The Young's modulus can be measured according to the method described in “Plastic Tensile Test Method” defined in JIS K7113. That is, the force ΔS applied to the unit cross-sectional area and the elongation Δa in the unit length in the endless belt 1 can be measured and can be obtained by the equation E = ΔS / Δa. Here, in the above expression, ΔS is expressed by the expression ΔS = F / (w × t) from the load F, the thickness t and the width w of the endless belt 1, and Δa is the reference length L of the endless belt 1. From the elongation ΔL of the endless belt 1 when a load is applied, Δa = ΔL / L. The Young's modulus of the endless belt 1 can also be measured using a tensile tester, for example, a trade name “MODEL-1605N” (manufactured by Aiko Engineering Co., Ltd.). The calculation or the measurement is performed a plurality of times, for example, three times, and the arithmetic average value is set as the Young's modulus of the endless belt 1.

  The Young's modulus of the endless belt 1 can be adjusted according to the type of the modified polyamideimide resin and the conditions for the secondary solvent removal step described later.

  The endless belt 1 preferably has a tensile elongation of 10% or more, and more preferably 12% or more. The upper limit of the tensile elongation is ideally not particularly limited, but in reality it should be 100%, preferably 80%, and particularly preferably 50%. When the tensile elongation of the endless belt 1 is in the above range, even if the end of the endless belt 1 is damaged, the endless belt 1 can be prevented from breaking due to the damaged portion.

  The tensile elongation can be measured in accordance with a method described in “Plastic Tensile Test Method” defined in JIS K7113. The tensile elongation of the endless belt 1 is measured a plurality of times, for example, three times, and the arithmetic average value is obtained. The tensile elongation of the endless belt 1 can be adjusted according to the type of the modified polyamideimide resin and the conditions for the secondary solvent removal step described later.

The endless belt 1 preferably has a contact charge amount of −7 × 10 ^{−3 to} 7 × 10 ⁻³ μC (excluding 0 μC), and −5 × 10 ^{−3 to} 5 × 10 ⁻³ μC (excluding 0 μC). ), More preferably −3 × 10 ^{−3 to} 3 × 10 ⁻³ μC (excluding 0 μC). When the contact charge amount of the endless belt 1 is in the above range, the endless belt 1 can be used as a transfer conveyance belt or a conveyance belt, and the recording medium can be conveyed over a long period of time as desired. When 1 is used as an intermediate transfer belt, a transfer belt, a development belt, etc., it is possible to carry a developer as desired and transfer it to a recording medium or an image carrier. Can be formed.

  The contact charge amount can be measured, for example, as follows. First, a cascade type contact charge measuring device (for example, product name “TS-100AT” manufactured by Toshiba Chemical Co., Ltd.) and spherical ferrite powder (product name “MF-60” manufactured by Powder Tech Co., Ltd.) as a reference contact powder. And a test piece cut out from the endless belt 1 to a size of 75 mm × 100 mm. Next, the prepared test piece is set in a cascade type contact charge measuring device. Then, under an atmosphere of 25 ° C. and 60% RH, measurement is performed three times with a flow time of the reference contact powder of 5 seconds, and the arithmetic average value of the three times is obtained. This average value is defined as the contact charge amount of the endless belt 1. The contact charge amount of the endless belt 1 can be adjusted by the type of the modified polyamideimide resin, the type or blending amount of the conductivity-imparting agent, the conditions for the secondary solvent removal step described later, and the like.

  The endless belt 1 preferably has a wetting index of 34 mN / m or less, more preferably 32 mN / m or less, and particularly preferably 25 mN / m or less. If the wetting index of the endless belt 1 is in the above range, the silica particles contained in the developer can be prevented from adhering to the endless belt 1 and a high quality image can be formed.

  The wetting index can be measured using a mixed liquid for wet tension test manufactured by Wako Pure Chemical Industries, Ltd. This measurement is performed a plurality of times, for example, three times, and the arithmetic average value is used as the wetting index of the endless belt 1. The wetting index of the endless belt 1 can be adjusted according to the type of the modified polyamideimide resin and the conditions of the secondary solvent removing step described later.

  The endless belt 1 preferably has a loop stiffness of 150 to 450 mN, more preferably 200 to 400 mN, and particularly preferably 250 to 350 mN. When the loop stiffness of the endless belt 1 is within the above range, the flexibility and durability of the endless belt 1 are expressed in a balanced manner.

  The loop stiffness can be measured as follows. First, a loop stiffness measuring device (for example, “Loop Stiffness Tester DA Model”, manufactured by Toyo Seiki Seisakusho Co., Ltd.) is prepared, and the dimensions of a width of 20 mm and a circumference of 175 mm are obtained in the same manner as the endless belt 1. A looped test piece is prepared. Subsequently, this loop-shaped test piece is chucked and fixed to the clamp of the measuring device at intervals of 80 mm. And in the region of the loop-shaped test piece that is between the parts chucked by the clamp and is not chucked (from the direction not affected by gravity), until the pushing amount reaches 20 mm at a pushing speed of 100 mm / min. Then, a disk-shaped indenter having a diameter of 20 mm is pressed. At this time, the unchucked loop-shaped test piece is deformed, and the maximum pressing load applied to the disk-shaped indenter is read with a load measuring instrument connected to the disk-shaped indenter, for example, a digital force gauge, and the load value is calculated. taking measurement. This measurement is performed a plurality of times, for example, three times, and the arithmetic average value is set as the loop stiffness of the endless belt 1.

  The loop stiffness of the endless belt 1 can be adjusted by the type of the modified polyamideimide resin, the type or amount of polydimethylsiloxane described later, the conditions of the secondary solvent removal step described later, and the like.

The endless belt 1 usually preferably has a volume resistivity of 1 × 10 ⁹ to 1 × 10 ¹³ Ω · cm when conductivity is required, and is preferably 1 × 10 ¹⁰ to 1 × 10 ¹² Ω · cm. Particularly preferred is cm. When the volume resistivity is within the above range, a high-quality image can be formed when the endless belt 1 is used in an image forming apparatus. The volume resistivity can be measured by a volume resistance measuring device (manufactured by Mitsubishi Chemical Corporation, trade name: Hiresta-UP, probe used: URS).

  The endless belt 1 is formed of a modified polyamideimide resin described later. This modified polyamide-imide resin is a modified aromatic polyamide-imide resin obtained by modifying an aromatic polyamide-imide resin with polydimethylsiloxane, which will be described later, and has excellent mechanical properties such as strength, flexibility, dimensional stability and heat resistance. Is particularly preferable.

  The modified aromatic polyamideimide resin can be produced by a diisocyanate method in which a tricarboxylic acid anhydride and a diisocyanate compound are reacted in the presence of polydimethylsiloxane, which will be described later. It is excellent in that there are few. In addition to the modified aromatic polyamideimide resin produced by the diisocyanate method, a diamine compound can be used in place of the diisocyanate compound in the presence of polydimethylsiloxane described later if the polycondensation reaction can be suitably carried out. A modified aromatic polyamideimide resin produced by the method is also preferable. A modified aromatic polyamideimide resin obtained using a diamine compound has a high Young's modulus and is suitable as a resin for forming the endless belt 1. Moreover, the modified aromatic polyamide-imide resin in which a part of the tricarboxylic acid anhydride is replaced with tetracarboxylic dianhydride to increase the imide bond is excellent in moisture resistance.

  The modified aromatic polyamide-imide resin is obtained by reacting a tricarboxylic acid anhydride with a diisocyanate compound in an appropriate solvent in the presence of polydimethylsiloxane, which will be described later, at normal pressure, and at normal temperature or under heating. It can be easily synthesized.

  The amount of polydimethylsiloxane present when polymerizing the tricarboxylic acid anhydride and the diisocyanate compound is preferably 10 parts by mass or less with respect to a total of 100 parts by mass of the tricarboxylic acid anhydride and the diisocyanate compound. It is particularly preferred that the amount is not more than parts. When the amount of polydimethylsiloxane exceeds 10 parts by mass, if endless belt 1 is formed from the resulting modified aromatic polyamideimide resin, bubbles may be generated on the surface and inside of endless belt 1. On the other hand, the abundance of polydimethylsiloxane is preferably 2 parts by mass or more, and more preferably 3 parts by mass or more. When the abundance of polydimethylsiloxane is less than 2 parts by mass, the desired effect may not be obtained even if the endless belt 1 is formed from the obtained modified aromatic polyamideimide resin.

The polydimethylsiloxane has a polydimethylsiloxane structure — (Si (CH ₃ ) ₂ —O) _n — composed of repeating units — (Si (CH ₃ ) ₂ —O) —, and has an amino group at its end, It is a polydimethylsiloxane having at least one kind of carboxy group and hydroxy group. Here, n in the polydimethylsiloxane structure is an integer, specifically, for example, an integer of 40 to 60. When the polydimethylsiloxane has at least one group of an amino group, a carboxy group, and a hydroxy group at the terminal, these groups react with the isocyanate group of the isocyanate compound to form a tricarboxylic acid anhydride and a diisocyanate compound. Polydimethylsiloxane can be uniformly incorporated into the resulting polyamideimide resin, and a modified polyamideimide resin of a block copolymer or a graft copolymer can be obtained.

  The polydimethylsiloxane preferably has at least one group of an amino group, a carboxy group and a hydroxy group at both ends of the polydimethylsiloxane structure, and the group at the end of the polydimethylsiloxane structure is preferably a carboxy group. .

  The polydimethylsiloxane preferably has a number average molecular weight of 3,200 to 4,600. When the number average molecular weight of the polydimethylsiloxane is within the above range, the weather resistance of the endless belt 1 and the releasability of the developer are improved. The number average molecular weight is a molecular weight in terms of standard polystyrene by gel permeation chromatography.

  The polydimethylsiloxane may be appropriately prepared, or a commercially available product may be used. Examples of commercially available products include the trade name “X22-162C” (both ends of the polydimethylsiloxane structure are carboxy groups, number average molecular weight 4,600, manufactured by Shin-Etsu Chemical Co., Ltd.), trade name “X22-176DX” (polydimethyl). Both ends of the siloxane structure are hydroxy groups, number average molecular weight 3,200, manufactured by Shin-Etsu Chemical Co., Ltd.), trade name “KF8012” (both ends of polydimethylsiloxane structure are amino groups, number average molecular weight about 4,000, Shin-Etsu Chemical) Etc.).

  The tricarboxylic acid anhydride is preferably an aromatic tricarboxylic acid anhydride, such as trimellitic acid anhydride, 3,4,4′-diphenyl ether tricarboxylic acid anhydride, 3,4,4′-benzophenone tricarboxylic acid anhydride. 2,3,5-pyridinetricarboxylic acid anhydride, naphthalenetricarboxylic acid anhydride, and derivatives thereof. These acid anhydrides can be used singly or in combination of two or more.

  Examples of the tetracarboxylic dianhydride used in place of a part of the tricarboxylic acid anhydride include pyromellitic dianhydride, 3,3 ′, 4,4′-benzophenone tetracarboxylic dianhydride, 3, 3 ′, 4,4′-biphenyltetracarboxylic dianhydride, 2,3,6,7-naphthalenetetracarboxylic dianhydride, 1,4,5,8-naphthalenetetracarboxylic dianhydride, 2, 2'-bis (3,4-dicarboxyphenyl) propane dianhydride, bis (3,4-dicarboxyphenyl) sulfonic dianhydride, perylene-3,4,9,10-tetracarboxylic dianhydride Bis (3,4-dicarboxyphenyl) ether dianhydride, ethylenetetracarboxylic dianhydride, and derivatives thereof. These tetracarboxylic dianhydrides can be used alone or in combination of two or more.

  Preferred examples of the diisocyanate compound include aromatic diisocyanate compounds. In addition, as the diisocyanate compound, an aliphatic diisocyanate compound and / or an alicyclic diisocyanate compound, or amines that are derivatives thereof can be used together with or in place of the aromatic diisocyanate compound.

  Examples of the aromatic diisocyanate compound include m-phenylene diisocyanate, p-phenylene diisocyanate, diphenylmethane-4,4′-diisocyanate, 4,4′-diisocyanate diphenyl ether, 4,4′-diisocyanate diphenyl sulfone, and 4,4′-diisocyanate. Biphenyl, 3,3′-dimethyl-4,4′-diisocyanate biphenyl, 2,4-toluene diisocyanate, xylylene diisocyanate and the like can be mentioned. Diamines that are derivatives of these aromatic diisocyanate compounds can also be used as raw materials. Examples of the aliphatic diisocyanate compound include ethylene diisocyanate, propylene diisocyanate, and hexamethylene diisocyanate. Examples of the alicyclic diisocyanate compound include 1,4-cyclohexane diisocyanate, 1,3-cyclohexane diisocyanate, isophorone diisocyanate, 4,4'-dicyclohexylmethane diisocyanate, and the like. Among these diisocyanate compounds, considering the heat resistance, mechanical properties, solubility, and the like of the endless belt 1, 60% by mass or more, preferably 70% by mass or more of all the diisocyanate compounds used is diphenylmethane-4,4. It is preferable to use diamines that are '-diisocyanate, 2,4-toluene diisocyanate, 3,3'-dimethyl-4,4'-diisocyanate biphenyl, isophorone diisocyanate, or derivatives thereof. Further, considering the dimensional stability of the endless belt 1, 70% by mass or more of all diisocyanate compounds used may be diphenylmethane-4,4′-diisocyanate or its derivative 4,4′-diaminodiphenylmethane. preferable.

  As a solvent used in the reaction for synthesizing the modified aromatic polyamideimide resin, a polar solvent is preferable in terms of solubility, and an aprotic polar solvent is particularly preferable in consideration of reactivity. Examples of aprotic polar solvents include N, N-dialkylamides, and examples of N, N-dialkylamides include N, N-dimethylformamide, N, N-dimethylacetamide, N, N- Examples include diethylformamide, N, N-diethylacetamide, and N, N-dimethylmethoxyacetamide. Further, as a polar solvent, N-methyl-2-pyrrolidone, pyridine, dimethyl sulfoxide, tetramethylene sulfone, dimethyltetramethylene sulfone, and the like are also preferable. These solvent can be used individually by 1 type or in mixture of 2 or more types.

  The modified aromatic polyamide-imide resin thus polymerized is a block copolymer or graft copolymer in which the polydimethylsiloxane structure is incorporated or grafted into the aromatic polyamide-imide resin.

  The modified aromatic polyamideimide resin preferably has a number average molecular weight of 10,000 to 50,000. When the number average molecular weight of the modified aromatic polyamideimide resin is in the above range, the tensile elongation of the molded film is improved. The number average molecular weight is a molecular weight in terms of standard polystyrene by gel permeation chromatography.

  The endless belt 1 is formed of a modified polyamideimide resin, but may be formed of a resin composition containing a modified polyamideimide resin and various additives, if necessary.

For example, when a certain degree of conductivity is required for the endless belt 1 such as a transfer conveyance belt or an intermediate transfer belt, the endless belt is made of a resin composition containing a modified polyamideimide resin and a conductivity imparting agent. 1 may be formed. Examples of the conductivity imparting agent contained in the resin composition include various carbon blacks such as furnace black, acetylene black, and ketjen black, graphite powder such as natural graphite, artificial graphite, and expanded graphite, and needles made of a metal or an alloy. , Spherical, plate-like, and irregular shaped powders, ceramic powders, and various particles whose surfaces are metal-plated. Among these, carbon black is preferable in that the particle size, conductivity, affinity with the modified polyamideimide resin, and the like are excellent in a balanced manner. Carbon black is more preferably oxidized carbon black to which a carboxy group, a hydroxy group, etc. are added by oxidation treatment in terms of improving affinity with the modified polyamideimide resin, and oxidation treatment carbon black having a pH of 6 or less is also preferred. . A preferable shape of the conductivity-imparting agent is spherical or irregular. The size of the particles of the conductivity-imparting agent having a spherical or irregular shape is preferably about 0.01 to 10 μm as the primary particle diameter. If conductive agent is carbon black, the BET specific surface area, strong correlation between the primary particle diameter is preferably ^{50~300m 2 / g, 100~200m 2 /} g is more preferable.

  The addition amount of the conductivity-imparting agent may be appropriately adjusted depending on the conductivity and particle size of the conductivity-imparting agent, the conductivity required for the endless belt 1, and the like. It is preferable that it is 1-25 mass% with respect to a total of 100 mass% with an imparting agent, and it is more preferable that it is 5-20 mass%. When the addition amount of the conductivity imparting agent is less than 1% by mass, the developed conductivity may be small. On the other hand, when the addition amount of the conductivity imparting agent exceeds 25% by mass, the mechanical strength of the endless belt 1 is increased. May decrease. In order to disperse the conductivity-imparting agent in the modified polyamideimide resin, a known method can be appropriately selected. Examples of known methods include mixing rolls, pressure kneaders, extruders, three rolls, homogenizers, and ball mills. And a mixing method using a pot mill, a bead mill and the like.

  Examples of additives other than the conductivity-imparting agent include, for example, fluorine organic compounds, coupling agents, lubricants, antioxidants, plasticizers, colorants, antistatic agents, anti-aging agents, reinforcing fillers, reaction Various additives such as auxiliaries and reaction inhibitors, other resins, solvents and the like can be mentioned.

  Next, a method for manufacturing the endless belt 1 according to the present invention will be described. In order to manufacture the endless belt 1, first, the modified polyamideimide resin is prepared. That is, as described above, for example, in the presence of polydimethylsiloxane having at least one group of amino group, carboxy group and hydroxy group at both ends of the polydimethylsiloxane structure, in an appropriate solvent, under normal pressure, and The modified polyamidoimide resin is produced by polymerizing the tricarboxylic acid anhydride and the diisocyanate compound at room temperature or under heating. If necessary, a resin composition containing a modified polyamideimide resin and various additives is prepared by the above method.

  Next, a modified polyamideimide resin or a resin composition (hereinafter referred to as a modified polyamideimide resin or the like) is molded into a ring shape by a known molding method. For example, the endless belt 1 can be formed by centrifugal molding, extrusion molding, injection molding, RIM molding, or the like. Among these molding methods, centrifugal molding is preferable in terms of excellent thickness accuracy.

  When the endless belt 1 is molded by centrifugal molding, the modified polyamideimide resin or the like that forms the endless belt 1 is preferably adjusted to have a viscosity at molding of 50,000 mPa · s or less. When the viscosity exceeds 50,000 mPa · s, it may be difficult to produce the endless belt 1 having a uniform thickness. The lower limit of the viscosity is not particularly limited, but is preferably 10 mPa · s or more. When the viscosity of the modified polyamideimide resin or the like at the time of molding is out of the above range, the viscosity of the modified polyamideimide resin or the like can be adjusted within the above range by adjusting the addition amount of the solvent or the like. Examples of the solvent include the solvents used when synthesizing the modified aromatic polyamideimide resin.

  According to centrifugal molding, a modified polyamideimide resin or the like that has developed fluidity by containing a solvent is poured into a cylindrical mold, and the mold is rotated and the modified polyamideimide is rotated on the inner peripheral surface of the mold by centrifugal force. A layer of resin or the like is uniformly developed, and the solvent is dried and removed from the layer of modified polyamideimide resin or the like to produce an endless belt base. Various metal pipes can be used for the mold. As a suitable mold, the inner peripheral surface of the mold is mirror-polished, and the inner peripheral surface that becomes the mirror surface is subjected to a release treatment with a release agent such as a fluororesin or a silicone resin, and the formed endless belt base is formed. Examples thereof include a metal tube that can be easily removed from the inner peripheral surface.

  In addition to the above-described centrifugal molding, the tricarboxylic acid anhydride and the diisocyanate compound are partially polymerized in the presence of polydimethylsiloxane having at least one of an amino group, a carboxy group, and a hydroxy group at the terminal. The modified polyamic acid solution is coated on the inner and outer peripheral surfaces of the mold by a dipping method, a centrifugal method, a coating method, or the like, or an appropriate method such as filling the casting mold with the modified polyamic acid solution. A known method for developing into a cylindrical shape, drying the formed layer into a belt shape, heat-treating the molded product to convert the modified polyamic acid into a modified imide and recovering it from the mold The endless belt 1 can also be manufactured according to Japanese Patent Application Laid-Open No. 61-95361, Japanese Patent Application Laid-Open No. 64-22514, Japanese Patent Application Laid-Open No. 3-180309, and the like. In this method, the amount of the polydimethylsiloxane when the tricarboxylic acid anhydride and the diisocyanate compound are partially polymerized is as described above.

  The solvent removed from the layer of modified polyamideimide resin or the like developed on the inner peripheral surface of the mold is a solvent contained in the layer of modified polyamideimide resin or the like developed on the inner peripheral surface of the mold. In addition to the solvent used when adjusting the viscosity of the polyamide-imide resin or the like, a solvent used when synthesizing the modified aromatic polyamide-imide resin may be used. Examples of the treatment for removing the solvent from the layer such as the modified polyamideimide resin developed on the inner peripheral surface of the mold include a heat treatment, but the solvent removal treatment comprising the following primary solvent removal step and secondary solvent removal step. Is preferably performed.

  In the primary solvent removal step, the mold is formed while removing the solvent from the layer of the modified polyamideimide resin or the like developed on the inner peripheral surface of the mold by rotating the mold, and the layer of the modified polyamideimide resin or the like is formed into a film Let it be the body. In the primary solvent removal step, the solvent is removed by passing hot air of 40 to 150 ° C. through the mold for 5 to 60 minutes while rotating the mold. When the hot air temperature exceeds 150 ° C. and / or when the heating time exceeds 60 minutes, the molded film-like molded body may be oxidized.

  In the secondary solvent removing step, the film-like molded body molded in the primary solvent removing step is taken out from the centrifugal molding machine together with the mold, heated together with the mold to remove the solvent from the film-like molded body, To do. For example, when using a heater such as a hot air dryer or oven, the film-like molded body may be heated together with the mold at 200 to 300 ° C. for 1 to 3 hours, and when a superheated steam furnace is used. What is necessary is just to heat a film-form molded object for 30 to 150 minutes with 110-350 degreeC superheated steam with a metal mold | die.

  In this way, after the film-shaped molded body is uniformly formed, the film-shaped molded body is taken out together with the mold, or after removing the solvent from the film-shaped molded body, the film-shaped molded body is taken out from the mold and released. Cool down. In addition, when the film-shaped molded body is allowed to cool together with the mold, the film-shaped molded body formed of the resin composition can be removed due to the difference in thermal expansion coefficient between the mold and the film-shaped molded body. The endless belt 1 can be manufactured by removing both end portions of the removed cylindrical film-shaped molded body and cutting each predetermined width.

  The endless belt in the present invention is not limited to the endless belt 1 described above, and various modifications can be made within a range in which the object of the present invention can be achieved. For example, the endless belt 1 does not include a meander-preventing member, but in the present invention, in the vicinity of at least one end of the endless belt, the endless belt 1 extends in the circumferential direction of the endless belt. A meandering prevention member having a shape may be provided.

  Next, an example of an image forming apparatus provided with the endless belt 1 according to the present invention (hereinafter sometimes referred to as an image forming apparatus according to the present invention) will be described with reference to FIG. The image forming apparatus shown in FIG. 2 is a direct transfer tandem color image forming apparatus that directly transfers a developer image developed on an image carrier to a recording medium. As shown in FIG. The endless belt 1 is stretched around two support rollers 42 as a transfer conveyance belt, and is stretched around a fixing roller 31 and an endless belt support roller 33 of the fixing device 30 as a fixing belt.

  As shown in FIG. 2, the image forming apparatus 10 is a tandem color image forming apparatus in which image carriers 11B, 11C, 11M, and 11Y equipped in four types of developing units are arranged in series on the transfer conveyance belt 1. Therefore, the developing units B, C, M, and Y are arranged in series on the transfer conveyance belt 1.

  As shown in FIG. 2, the developing unit B is provided with a rotatable image carrier 11B on which an electrostatic latent image is formed, in contact with or in pressure contact with the image carrier 11B, or at a predetermined interval. The charging means 12B for charging the image carrier 11B, the exposure means 13B provided above the image carrier 11B and forming an electrostatic latent image on the image carrier 11B, and the image carrier 11B are in contact with or pressed against each other. Or developing means 20B for supplying the developer 22B with a constant layer thickness to the image carrier 11B and developing the electrostatic latent image, and a transfer conveyance belt below the image carrier 11B. A transfer unit 14B, which is provided so as to be in contact with or pressed through 1 and transfers the developed electrostatic latent image from the image carrier 11B onto the recording medium 16 conveyed by the transfer conveyance belt 1; Is not transferred to the image carrier 11B and remains on the image carrier 11B. And a cleaning unit 15B for removing the developer 22B, and the like. As shown in FIG. 2, the image carrier 11 </ b> B and the transfer unit 14 </ b> B in the developing unit B are in contact or pressure contact with each other via the transfer conveyance belt 1 stretched around the two support rollers 5. The recording body 16 is transported by the transfer transport belt 1 so as to pass through the contact portion between the image carrier 11B and the transfer unit 14B. The transfer conveyance belt 1 conveys the recording medium 16 and transfers the developed electrostatic latent image on the image carrier 11B in cooperation with the transfer means 14B. As the image carrier 11B, the charging unit 12B, the exposure unit 13B, the transfer unit 14B, and the cleaning unit 15B, conventionally known ones can be appropriately selected and used.

  As shown in FIG. 2, the developing means 20B has an opening at a position facing the image carrier 11B, and a housing 21B for storing the developer 22B and an image carrier at the opening of the housing 21B. A rotatable developer carrier 23B which is provided in contact with or pressed against the body 11B or at a predetermined interval and supplies the developer 22B to the image carrier 11B with a constant layer thickness; and a developer carrier 23B And a developer regulating member 24B that regulates the layer thickness of the developer 22B by contacting or press-contacting the developer carrier 23B and charging the developer 22B by frictional charging. As the developer carrier 23B and the developer regulating member 24B, conventionally known ones can be appropriately selected and used. The developer 22B may be a dry developer or a wet developer, and may be a non-magnetic developer or a magnetic developer as long as it can be charged by friction and can be fixed to the recording medium 16. One-component developer or two-component developer may be used. The developing unit B stores a black developer in the housing 21B.

  The developing units C, M and Y are configured in the same manner as the developing unit B as shown in FIG. The developing units C, M, and Y accommodate a cyan developer 22C, a magenta developer 22M, and a yellow developer 22Y in housings 21C, 21M, and 21Y, respectively.

  As shown in FIG. 2, at the bottom of the image forming apparatus 10, a cassette 41 for storing a plurality of recording bodies as a recording body 16 is installed. One recording body in the cassette 41 is fed by a paper feed roller or the like. It is sent out one by one and conveyed onto the transfer conveyance belt 1.

  As shown in FIG. 2, a fixing unit 30 that fixes various developers (electrostatic latent images) transferred to the recording body 16 is disposed downstream in the conveyance direction of the recording body 16 in the image forming apparatus 10. . As the fixing unit 30, for example, a heat roller fixing device including a fixing roller capable of generating heat, a heat fixing device such as an oven fixing device, a pressure fixing device including a pressurizing fixing roller, or the like can be used. As shown in FIG. 2, the image forming apparatus 10 includes a fixing device 30 including an endless belt 1. As shown in FIG. 2, the fixing device 30 includes a fixing roller 31 and an endless belt supported in the vicinity of the fixing roller 31 in a housing 34 having an opening 35 through which the recording medium 16 passes. A roller 33, a fixing belt wound around the fixing roller 31 and the endless belt support roller 33, that is, the endless belt 1, and a pressure roller 32 disposed to face the fixing roller 31; This is a pressure and heat fixing device in which the fixing roller 31 and the pressure roller 32 are rotatably supported so as to contact or press against each other. The endless belt support roller 33 may be a roller that is normally used in an image forming apparatus. For example, an elastic roller or the like is used. Each of the fixing roller 31, the endless belt support roller 33, and the pressure roller 32 includes a heating body (not shown). The pressure roller 32 causes the endless belt 1 to be moved by a biasing means (not shown) such as a spring. Via the fixing roller 31. By passing the recording medium 16 between the endless belt 1 and the pressure roller 32, the recording medium 16 is heated simultaneously with the pressurization, and the developer 42 (electrostatic latent image) transferred to the recording medium 16 is fixed. be able to.

  The image forming apparatus 10 operates as follows. First, the image carrier 11B of the developing unit B is uniformly charged by the charging unit 12B, the image is exposed by the exposure unit 13B, and an electrostatic latent image is formed on the surface of the image carrier 11B. On the other hand, in the developing means 20B, the black developer 22B is regulated to a desired layer thickness and charged as desired by the developer carrier 23B and the developer regulating member 24B. Then, the black developer 22B is supplied from the developer carrier 23B to the image carrier 11B, and the electrostatic latent image formed on the image carrier 11B is developed and visualized as a developer image. Next, the developer image is transferred onto the recording medium 16 conveyed by the transfer conveyance belt 1 between the image carrier 11B and the transfer unit 14B. In this way, the developer image is visualized as a black image on the recording medium 16.

  Next, in the same manner as the developing unit B, the cyan image, the magenta image, and the yellow image are superimposed on the recording medium 16 in which the developer image is visualized as a black image by the developing units C, M, and Y, respectively. The image is visualized.

  Next, the recording body 16 in which the color image is visualized is conveyed to the fixing unit 30 by the conveying unit, and passes through a contact portion or a pressure contact portion between the fixing roller 31 and the pressure roller 32 via the endless belt 1. Occasionally heated and / or pressurized to fix the transferred color image as a permanent image. In this way, a color image can be formed on the recording medium 16.

  According to the image forming apparatus 10, since the endless belt 1 is used as a transfer conveyance belt, even if the image forming apparatus 10 is a conventional image forming apparatus, the life, the definition, and the speed are increased. Even if the image forming apparatus is attached to the image forming apparatus for a long time and / or runs endlessly for a long time, the endless belt 1 can be prevented from idling and the endless belt 1 can be cracked or cracked. The occurrence of damage can be suppressed. Therefore, the initial characteristics of the endless belt 1 are exhibited over a long period of time, and the recording body 16 can be conveyed as desired over the long term by the endless belt 1. As a result, a cyan image, a magenta image, and a yellow image can be superimposed on accurate positions on the black image visualized on the recording medium 16 to effectively prevent image misalignment and uneven image density. . Further, since the endless belt 1 is used as the fixing belt, the developer of each color transferred onto the recording paper 16 can be fixed as desired. Therefore, according to the image forming apparatus 10, a high quality image can be formed over a long period of time.

  The endless belt 1 according to the present invention is a transfer belt (also referred to as a photosensitive belt) that plays the same role as the image carrier 11, and an intermediate transfer belt used as a primary transfer body in the intermediate transfer system. Even when incorporated in the image forming apparatus 10 as a developing belt having the same role as the developer carrier, the endless belt 1 exhibits the initial characteristics over a long period of time as described above. 10 can form a high-quality image.

  The image forming apparatus 10 is an electrophotographic image forming apparatus. However, in the present invention, the image forming apparatus 10 is not limited to the electrophotographic system, and is, for example, an electrostatic image forming apparatus. Also good. Further, the image forming apparatus 10 is a tandem type color image forming apparatus in which a plurality of image carriers each having a developing unit for each color are arranged in series on a transfer conveyance belt. Even a monochrome image forming apparatus provided with a developing unit may be a four-cycle color image forming apparatus that sequentially repeats primary transfer of a developer image carried on an image carrier onto an endless belt. The image forming apparatus 10 is an image forming apparatus such as a copying machine, a facsimile machine, or a printer.

Example 1
In a reaction vessel, an appropriate amount of N-methyl-2-pyrrolidone, 1 mol of trimellitic anhydride, 1 mol of diphenylmethane-4,4′-diisocyanate, trimellitic anhydride and diphenylmethane-4,4′-diisocyanate 10 parts by mass of polydimethylsiloxane (trade name “X22-162C”, both ends are carboxy groups, manufactured by Shin-Etsu Chemical Co., Ltd.) and 0.02 mol of potassium fluoride (catalyst) with respect to the total mass, and nitrogen gas After raising the temperature from room temperature to 150 ° C. over 1 hour with stirring in an atmosphere, the same temperature is maintained for 4 hours, and the concentration of reactants (substantially fully ring-modified modified polyamideimide resin, number average molecular weight of modified polyamideimide resin) 20,000) 20% by mass of a modified polyamideimide resin solution was obtained. N-methyl-2-pyrrolidone was further added to this solution to prepare a modified polyamideimide resin solution having a reactant concentration of 15% by mass. To the resulting modified polyamideimide resin solution, an oxidized carbon black (trade name “Special Black 4”, manufactured by Degussa, pH 3.0, volatile content 14.0%) was added to the modified polyamideimide resin and oxidized carbon black. It added in the ratio of 15 mass% with respect to a total of 100 mass%, and it mixed and dispersed with the bead mill for 1 hour, and prepared the resin composition.

  A mold used for centrifugal molding has an inner diameter of 200 mm, an outer diameter of 220 mm, and a length of 400 mm, and the inner surface of the mold is mirror-polished by polishing. Next, ring-shaped lids (inner diameter: 170 mm, outer diameter: 250 mm) are fitted into the openings at both ends of the mold, the mold is closed, and the resin composition is rotated at a speed of 1,000 rpm. 215 g was injected around the circumference. Next, the mold was rotated at the same speed for 30 minutes to uniformly spread the resin composition layer on the inner peripheral surface of the mold. Next, while the mold was rotated at the same speed, the temperature around the mold was maintained at 150 ° C. with a hot air dryer, and this state was maintained for 30 minutes to form a film-like molded body. Thereafter, the rotation of the mold is stopped, the film-like molded body is taken out from the centrifugal molding machine together with the mold, heated in a superheated steam furnace adjusted to 250 ° C. for 150 minutes, then allowed to cool at room temperature, and endless A belt substrate was obtained. When the endless belt substrate was cooled together with the mold, the endless belt substrate was peeled off due to the difference in thermal expansion coefficient between the mold and the endless belt substrate.

  Both ends of the belt substrate thus prepared were cut and cut into a size having a circumferential length of about 200 mm and a width of 240 mm to produce an endless belt 1A having a thickness of 100 μm.

(Example 2)
Example 1 except that the amount of polydimethylsiloxane (trade name “X22-162C”) was changed to 5 parts by mass with respect to the total mass of trimellitic anhydride and diphenylmethane-4,4′-diisocyanate. In the same manner, an endless belt 1B was produced.

(Comparative Example 1)
An endless belt 1C was produced in the same manner as in Example 1 except that the polydimethylsiloxane was not used (that is, the amount of polydimethylsiloxane was changed to 0 part by mass).

(Comparative Example 2)
Oxidized carbon black (trade name “Special Black 4”, manufactured by Degussa, pH 3.0, volatile content 14.0%) on a polyimide resin solution (trade name “U-Varnish-S”, manufactured by Ube Industries, Ltd.) A resin composition was prepared by adding 15% by mass with respect to a total of 100% by mass of the polyimide resin and the oxidized carbon black in the polyimide resin solution, and mixing and dispersing in a bead mill for 1 hour.

  Next, as in Example 1, 215 g of the resin composition was injected into the inner periphery of the mold while rotating a mold having an inner diameter of 200 mm, an outer diameter of 220 mm, and a length of 400 mm at a speed of 1,000 rpm. Next, the mold was rotated at the same speed for 30 minutes to uniformly spread the resin composition layer on the inner peripheral surface of the mold. Next, while the mold was rotated at the same speed, the temperature around the mold was maintained at 150 ° C. with a hot air dryer, and this state was maintained for 30 minutes to form a film-like molded body. Thereafter, the rotation of the mold was stopped, the film-shaped molded body was taken out from the centrifugal molding machine together with the mold, heated with superheated steam in a superheated steam furnace adjusted to 350 ° C. for 150 minutes, allowed to cool at room temperature, and endless. A belt substrate was obtained. When the endless belt substrate was cooled together with the mold, the endless belt substrate was peeled off due to the difference in thermal expansion coefficient between the mold and the endless belt substrate. Both end portions of the endless belt substrate thus prepared were cut and cut into a size having a circumference of about 200 mm and a width of 240 mm to prepare an endless belt 1D having a thickness of 100 μm.

(Comparative Example 3)
After the silicone graft acrylic resin (trade name “X22-8004”, manufactured by Shin-Etsu Chemical Co., Ltd.) is uniformly applied to the surface of the endless belt base produced in Comparative Example 1 to a thickness of 5 μm by a spray coating method, It dried at 150 degreeC for 2 hours, and produced the endless belt 1E of 2 layer structure.

(Comparative Example 4)
Silicone graft acrylic resin (trade name “X22-8004”, manufactured by Shin-Etsu Chemical Co., Ltd.) and N-methyl-2-pyrrolidone are mixed to form a silicone graft acrylic resin solution having a silicone graft acrylic resin concentration of 15% by mass. Was prepared. To the obtained silicone graft acrylic resin solution, oxidized carbon black (trade name “Special Black 4”, manufactured by Degussa, pH 3.0, volatile content 14.0%) was added with silicone graft acrylic resin and oxidized carbon black. It added in the ratio of 15 mass% with respect to a total of 100 mass%, and it mixed and dispersed with the bead mill for 1 hour, and prepared the resin composition.

  Next, in the same manner as in Example 1, a layer of the resin composition was uniformly developed on the inner peripheral surface of the mold. Next, while rotating the mold at the same speed, the temperature around the mold was maintained at 80 ° C. with a hot air dryer, and this state was maintained for 30 minutes to form a film-shaped molded body. Thereafter, the rotation of the mold is stopped, the film-shaped molded body is taken out from the centrifugal molding machine together with the mold, heated in a hot air dryer adjusted to 100 ° C. for 150 minutes, allowed to cool at room temperature, and an endless belt substrate. It was. Both ends of the belt substrate thus prepared were cut and cut into a size having a circumferential length of about 200 mm and a width of 240 mm to produce an endless belt 1F having a thickness of 100 μm.

  In accordance with the above measurement methods, the ISO folding endurance number, water absorption rate, Young's modulus, tensile elongation, contact charge amount, wetting index, and loop stiffness of endless belts 1A to 1F were measured. The results are shown in Table 1.

  Moreover, the silica adhesion test of the endless belts 1A to 1F was performed. Specifically, after applying silica powder (trade name “X24-9163A”, manufactured by Shin-Etsu Chemical Co., Ltd.) to the surface of the endless belts 1A to 1F with a waste cloth, the applied silica powder was wiped with a clean waste cloth. . The amount of silica powder remaining on the surface of each endless belt was visually evaluated. The evaluation was made in three stages of “」 ”,“ ◯ ”, and“ × ”in order from the smallest remaining amount of silica powder. The results are shown in Table 2.

  Further, image flow of endless belts 1A to 1F, developer transferability, and white spot test were performed. Specifically, each of the produced endless belts 1A to 1F is mounted on a belt intermediate transfer type color image forming apparatus (trade name “DocuPrint C830”, manufactured by Fuji Xerox Co., Ltd.) equipped with an amorphous silicon photosensitive drum, and developed. A printing test was performed using a magnetic two-component toner as an agent, and the printed sample was judged by observing with a 10 × optical microscope. The image flow is “◎” when the outline of the printed character in the print sample is not blurred around, and “○” when the outline of the printed character is slightly blurred but is practically no problem. , “×” indicates that the outline of the printed character was intensely blurred. The transferability of the developer is “◎” when the halftone dots in the print sample are clearly transferred onto the paper, “○” when the halftone dots are somewhat missing, and the halftone dots The case where there was a large defect was designated as “x”. Blank areas are indicated by “◎” when the untransferred portion (white portion) of the developer is not observed in the solid print image in the print sample, and the untransferred portion (white portion) of the developer in the solid print image. Is marked with “◯”, and when a large number of untransferred portions (white portions) of the developer are found in the solid printed image, “x” is marked. The results are shown in Table 2.

  Further, the produced endless belts 1A to 1F are respectively attached to the image forming apparatus (tandem type color printer (trade name “MicroLine 9055c”, manufactured by Oki Data Co., Ltd.)) shown in FIG. 2 (tension 100 to 3,000 gf). The endless belt stretched on the endless belt support roller 33 was rotated on an endless track at a speed of printing 21 sheets of A4 paper / min. After running 300,000 revolutions, the endless belt was checked for cracks and / or breakage. The case where cracks and breakage did not occur even when the endless belt was run for 300,000 revolutions was marked with “◎”, and the case where cracks and breakage did not occur even when the endless belt was run for 100,000 revolutions was marked with “◯”. The case where cracks and / or breakage occurred before the endless belt traveled 50,000 times was evaluated as “x”. The results are shown in Table 2.

FIG. 1 is a schematic perspective view showing an endless belt according to an embodiment of the present invention. FIG. 2 is a schematic view of a tandem color image forming apparatus according to an embodiment of the present invention.

Explanation of symbols

1 Endless belt 10 Image forming apparatus 11B, 11C, 11M, 11Y Image carrier 12B, 12C, 12M, 12Y Charging means 13B, 13C, 13M, 13Y Exposure means 14B, 14C, 14M, 14Y Transfer means 15B, 15C, 15M, 15Y cleaning means 16 recording medium 20 developing means 21B, 21C, 21M, 21Y, 34 housings 22B, 22C, 22M, 22Y developer 23B, 23C, 23M, 23Y developer carrier 24B, 24C, 24M, 24Y developer regulation Member 30 Fixing device 31 Fixing roller 32 Pressure roller 33 Endless belt support roller 35 Opening 41 Cassette 42 Support rollers B, C, M, Y Development unit

Claims (4)

Trimellitic anhydride and diphenylmethane-4,4′-diisocyanate are 10 parts by mass or less of amino groups with respect to a total of 100 parts by mass of trimellitic anhydride and diphenylmethane-4,4′-diisocyanate. , Rupusutefu in the presence of polydimethylsiloxane terminated with at least one of the carboxy group and hydroxy group, with modified polyamideimide resin obtained by polymerizing formed in a single-layer structure, ISO folding number above 6500 times An endless belt having a ness of 150 to 450 mN.   The endless belt according to claim 1, wherein the water absorption is 1.8% or less.   The endless belt according to claim 1, wherein the polydimethylsiloxane has a carboxy group at a terminal. An image forming apparatus comprising the endless belt according to claim 1 .

Images