JP5045898B2 - Hairdressing composition - Google Patents

Description

  The present invention relates to a hair styling composition that has excellent setability even under high-humidity conditions and is easy to wash away with a shampoo or the like.

  Conventionally, a hair cosmetic using a coating of a polymer compound with a set resin has been proposed in order to obtain hair styling properties such as hair unity and set retention (see Patent Document 1: JP-A-6-287116, Patent Document 2: Japanese Patent Application Laid-Open No. 9-20626). However, hair set with set resin bonds the hairs together, so it lacks a natural texture, and it is not good for combing and fingering. was there.

  In order to overcome such drawbacks, methods using oils and waxes as hair styling agents have been proposed (see Patent Document 3: Japanese Patent Laid-Open No. 10-45546, Patent Document 4: Japanese Patent Laid-Open No. 11-124316). ). However, hair styling agents using set resins, oils and fats, and waxy substances do not always have sufficient style retention under high humidity conditions. In addition, hair styling using these wax-like substances causes stickiness of the hair, and there has been a demand for improvement thereof. On the other hand, a method of improving slipperiness by using dimethylpolysiloxane in combination and reducing the stickiness of hair (see Patent Document 5: Japanese Patent Laid-Open No. 2002-370937) has been proposed. The style retention under high humidity conditions is not sufficient.

JP-A-6-287116 Japanese Patent Laid-Open No. 9-20626 JP-A-10-45546 JP 11-124316 A JP 2002-370937 A

  The present invention has been made in view of the above circumstances, and an object of the present invention is to provide a hair conditioner composition that has excellent setting properties even under high humidity conditions and can be easily washed away with a shampoo.

  As a result of intensive studies to achieve the above object, the present inventors have found that (A) solid waxes and / or solid waxes, (B) vegetable sterols and / or derivatives thereof, and (C) polyglycerin fatty acids. By using together with one or more nonionic surfactants selected from esters, sugar alcohol esters and alkylene oxide adducts thereof, the hair does not become sticky and has excellent setting properties even under high humidity conditions. In addition, it is possible to obtain a hair styling composition that can be easily washed away by shampoo, and further, by blending (D) alkylene glycol, a more remarkable effect can be obtained with respect to the effect of being easily washed away by shampoo. E) By blending solid powder, a more remarkable effect can be obtained with respect to setability under high humidity conditions. The combined use of the (D) and (E) component, and found that hair stickiness suppression effect is improved, in which the present invention has been accomplished.

Therefore, the present invention
[1]. (A) solid waxes and / or solid waxes, (B) polyoxyethylene (4-60) phytosterol , (C) polyoxyethylene (6-60) sorbit fatty acid ester , (D) alkylene glycol A hair styling composition containing,
[2]. Furthermore, (E) the hairdressing composition according to [1], which contains a solid powder,
[3]. The hair styling composition according to [1] or [2], wherein the component (A) is selected from microcrystalline wax, candelilla wax, and carnauba wax, and the content in the composition is 5 to 30% by mass. ,
[4]. The component (B) is selected from polyoxyethylene (10) phytosterol, polyoxyethylene (20) phytosterol, polyoxyethylene (30) phytosterol, and polyoxyethylene (60) phytosterol, and contained in the composition The hairdressing composition according to any one of [1] to [3], wherein the amount is 0.1 to 10% by mass;
[5]. (C) component is tetraoleic acid polyoxyethylene (6) sorbite, tetraoleic acid polyoxyethylene (30) sorbit, tetraoleic acid polyoxyethylene (40) sorbit, and tetraoleic acid polyoxyethylene (60) sorbit The hair conditioner composition according to any one of [1] to [4], wherein the content in the composition is 0.1 to 3% by mass,
[6]. (D) The hairdressing composition according to any one of [1] to [5], wherein the component is polyethylene glycol having an average molecular weight of 280 to 3800, and the content in the composition is 0.1 to 13% by mass. ,
[7]. The component (E) is selected from kaolin, talc, sericite, mica, aluminum magnesium silicate, hemp cellulose powder, wheat starch, silk powder, and corn starch, and the content in the composition is 5 to 30. The hair styling composition according to any one of [1] to [6],
[8]. The hair styling composition according to any one of [1] to [7], which is a hair wax .

  According to the present invention, it is possible to provide a hair styling composition that has excellent setability even under high humidity conditions and can be easily washed away with a shampoo.

  (A) component of this invention is solid waxes and / or solid waxes, and can be used individually by 1 type or in combination of 2 or more types. Solid waxes indicate hydrocarbons that are solid at room temperature (25 ° C.), and specific examples include paraffin wax, microcrystalline wax, ozokerite, and ceresin. Solid waxes are waxes that are solid at room temperature, which are mainly composed of esters of higher fatty acids and higher alcohols. Specifically, candelilla wax, carnauba wax, whale wax, sugarcane wax, palm wax, beeswax, montan wax, rice bran wax. , Hydrogenated rice bran wax, ibota wax, salmon montan wax, bayberry wax, ocully wax, esparto wax, hydrogenated jojoba wax, shellac wax, white beeswax, wood wax and the like. Among these solid waxes and solid waxes, microcrystalline wax, candelilla wax, and carnauba wax are preferable.

  (A) As for the compounding quantity of a component, 5-30 mass% is preferable in a hairdressing agent composition, More preferably, it is 10-20 mass%. Within this range, it has particularly excellent setting properties under high-humidity conditions, and if it exceeds 30% by mass, the elongation may deteriorate.

  The component (B) of the present invention is a plant sterol and / or a derivative thereof, which can be used alone or in combination of two or more. Examples of plant sterols or derivatives thereof include β-sitosterol, stigmasterol, campesterol, ergosterol, phytosterol which is a mixture thereof, and ester, ether, glycoside and alkylene oxide adducts thereof. It is done.

  Among these, an alkylene oxide adduct of phytosterol is preferable. Specifically, ethylene oxide, propylene oxide, and butylene oxide are preferably used as the alkylene oxide, and among these, ethylene oxide is particularly preferable. The average added mole number of ethylene oxide is not particularly limited, but is preferably 2 to 80 (polyoxyethylene (2 to 80) phytosterol, more preferably 3 to 70, and further preferably 4 to 60). If the number of added moles is too small, the aqueous preparation may not be uniformly mixed, and if it is too large, the desired effect may not be sufficiently exhibited.

  Although the compounding quantity of (B) component is not specifically limited, Usually, 0.01-20 mass% is preferable in a hairdressing composition, More preferably, it is 0.05-15 mass%, More preferably, it is 0.1-10 mass. %. Within this range, it is possible to further obtain excellent setability under high-humidity conditions and hair stickiness suppressing effect during use.

  The component (C) of the present invention is one or more nonionic surfactants selected from polyglycerin fatty acid esters, sugar alcohol esters, and alkylene oxide adducts thereof.

  Examples of polyglyceryl fatty acid esters include decaglyceryl monostearate, degaglyceryl monooleate, decaglyceryl distearate, triglyceryl distearate, pentaglyceryl distearate, hexaglyceryl tristearate, hexaglyceryl tetrabehenate, hexaglyceryl pentaoleate, Hexaglyceryl diricinoleate, hexaglyceryl triricinoleate, hexaglyceryl tetraricinoleate, hexaglyceryl pentaricinoleate, hexaglyceryl hexaricinoleate, hexaglyceryl pentaoleate, decaglyceryl tristearate, decaglyceryl trioleate, pentastearin Decaglyceryl acid, decaglyceryl pentahydroxystearate, pentaoleic acid Kaglyceryl, decaglyceryl heptastearate, decaglyceryl decastearate, decaglyceryl dekaoleate, decamacademia nut fatty acid And decaglyceryl hexaricinoleate.

  Examples of sugar alcohol esters and their alkylene oxide adducts include sorbite fatty acid esters, pentaerythritol fatty acid esters and sorbitan fatty acid esters, and their alkylene oxide adducts. Among these, from the viewpoint of solubility, polyoxyethylene is The added polyoxyethylene sorbit fatty acid ester, polyoxyethylene pentaerythritol fatty acid ester, and polyoxyethylene sorbitan fatty acid ester are preferable.

  Examples of polyoxyethylene sorbite fatty acid esters include tetraoleic acid polyoxyethylene (6) to (60) sorbit, dioleic acid polyoxyethylene (6) to (60) sorbit, trioleic acid polyoxyethylene (6) to (60 ) Sorbit, polyoxyethylene distearate (6)-(60) sorbit, polyoxyethylene tristearate (6)-(60) sorbit, polyoxyethylene tetrastearate (6)-(60) sorbit, polycapric dicaprylate Oxyethylene (6) to (60) sorbit, polyoxyethylene tricaprylate (6) to (60) sorbit, polyoxyethylene tetracaprylate (6) to (60) sorbit, polyoxyethylene dilaurate (6) to ( 60) Sorbit, Trilauri Acid polyoxyethylene (6) to (60) sorbitol, polyoxyethylene tetralaurate (6) to (60) sorbit, polymyethylene dimyristate (6) to (60) sorbitol, polyoxyethylene trimyristate ( 6) to (60) sorbitol, polymyethylene tetramyristate (6) to (60) sorbitol, polyoxyethylene dipalmitate (6) to (60) sorbitol, polyoxyethylene tripalmitate (6) to (60) ) Sorbite, polyoxyethylene tetrapalmitate (6) to (60) sorbite, polyoxyethylene diundecanoate (6) to (60) sorbitol, polyoxyethylene triundecanoate (6) to (60) sorbitol, tetraundecanoic acid Polyoxyethylene (6) to (60) Sorbit Etc. The.

  Examples of polyoxyethylene pentaerythritol fatty acid esters include polyoxyethylene distearate (6) to (60) pentaerythritol, polyoxyethylene dilaurate (6) to (60) pentaerythritol, and polyoxyethylene pentaerythritol dicaprylate. (6) to (60), polyoxyethylene pentaerythritol diundecanoate (6) to (60), polyoxyethylene pentaerythritol dimyristic acid (6) to (60), polyoxyethylene pentaerythritol dipalmitate (6) to (60), dioleic acid polyoxyethylene pentaerythritol (6) to (60), and the like.

  Examples of polyoxyethylene sorbitan fatty acid esters include polyoxyethylene (6) to (60) sorbitan dioleate, polyoxyethylene (6) to (60) sorbitan distearate, and polyoxyethylene (6) to (60) sorbitan dicaprylate. Polyoxyethylene diundecanoate (6) to (60) sorbitan, polyoxyethylene dilaurate (6) to (60) sorbitan, polyoxyethylene dimyristate (6) to (60) sorbitan, polyoxyethylene dipalmitate (6) to (60) sorbitan, polyoxyethylene distearate (6) to (60) sorbitan, polyoxyethylene dibehenate (6) to (60) sorbitan, polyoxyethylene sesquistearate (6) to (60) Sorbitan, polysesquioleate Xylethylene (6) to (60) sorbitan, polyoxyethylene monopalmitate (6) to (60) sorbitan, polyoxyethylene monostearate (6) to (60) sorbitan, polyoxyethylene monooleate (6) to (60) Sorbitan and the like can be mentioned.

  Among these, tetraoleic acid polyoxyethylene (4) sorbit, tetraoleic acid polyoxyethylene (6) sorbit, tetraoleic acid polyoxyethylene (30) sorbit, tetraoleic acid polyoxyethylene (40) sorbit, tetraoleic acid Polyoxyethylene (60) sorbit is particularly preferred.

  Although the compounding quantity of (C) component is not specifically limited, Usually, it is 0.01-10 mass% in a hairdressing composition, Preferably it is 0.1-5 mass%, More preferably, it is 0.1-3 mass%. It is. Within this range, it is possible to obtain more excellent setting properties under high-humidity conditions and hair stickiness suppressing effect during use.

  In the hairdressing composition of the present invention, by adding (D) alkylene glycol in addition to the above components, while maintaining excellent setability under high humidity conditions, the effect of being easily washed out with a shampoo, A more remarkable effect is obtained.

(D) Alkylene glycol is not specifically limited, It can use individually by 1 type or in combination of 2 or more types. Examples of the alkylene glycol include polyethylene glycol, polypropylene glycol, polyoxyethylene polyoxypropylene glycol, and the like, and polyethylene glycol is preferable. Among these, polyethylene glycol having an average molecular weight of 280 to 4000 is more preferable, and polyethylene glycol having an average molecular weight of 280 to 1000 is more preferable. If the average molecular weight is less than 280, it may be difficult to obtain the effect of reducing the stickiness of the hair, and if the average molecular weight exceeds 4,000, the stickiness of the hair may increase, and the hair may become sticky or stiff. In addition, average molecular weight shows the average molecular weight described in cosmetic raw material standards (2nd edition comment), polyethylene glycol 300 (average molecular weight 280-320), polyethylene glycol 400 (average molecular weight 380-420) and polyethylene glycol 1500 (of ethylene oxide). HOCH ₂ (CH ₂ OCH ₂ ) _n CH ₂ OH; an equivalent mixture of n = 5-6 and 28-36), polyethylene glycol 4000 (average molecular weight 2600-3800). Depending on the product, there may be a # between the polyethylene glycol and the numerical value, such as polyethylene glycol # 400.

  Although the compounding quantity of (D) component is not specifically limited, Usually, it is 0.01-20 mass% in a hairdressing composition, Preferably it is 0.1-15 mass%, More preferably, it is 0.1-13 mass%. It is. Within this range, it is possible to obtain a more effective setting property and ease of rinsing with a shampoo under high humidity conditions. When the amount exceeds 20% by mass, the hair feels sticky and heavy when used and dried. There is a case.

  In the hairdressing composition of the present invention, by further blending (E) solid powder, excellent setability under high humidity conditions is improved. In addition, the present invention is intended to further suppress the stickiness of hair during use, particularly when (D) and (E) components are used in combination, while maintaining excellent setability under high humidity conditions, Easily washed off with shampoo, improving the non-stickiness of hair.

  (E) Solid powder is not specifically limited, It can use individually by 1 type or in combination of 2 or more types. Examples of the solid powder include inorganic powders such as kaolin, talc, sericite, mica, and ground clay minerals such as magnesium aluminum silicate, synthetic ceramics such as boron nitride, hemp cellulose powder, wheat starch, and silk powder. , Organic powder such as corn starch, synthetic polymer compound powder such as powder or beads made of polyethylene, polystyrene, nylon, or methylsiloxane network polymer, aluminum stearate, zinc stearate, magnesium stearate, calcium stearate And metal soaps such as zinc palmitate, zinc myristate, and magnesium myristate.

  Among these powders, pulverized products of clay minerals such as kaolin, talc, sericite, mica, and aluminum magnesium silicate, and organic powders such as hemp cellulose powder, wheat starch, silk powder, and corn starch are preferable.

  Although the compounding quantity of (E) component is not specifically limited, Usually, it is 1-50 mass% in a hairdressing composition, More preferably, it is 5-30 mass%. If the blending amount is less than 1% by mass, the spread and feel during use may be poor, and if it exceeds 50% by mass, the composition may not be dispersed.

  Various additives may be appropriately added to the hairdressing composition of the present invention depending on the type and purpose of the hairdressing composition. Examples of such various additives include humectants such as polyols and oil classifications, ultraviolet absorbers, preservatives, pH adjusters, viscosity adjusters, antioxidants, dyes, fragrances and propellants, anionic interfaces. Nonionic surfactants other than the component (C), amphoteric surfactants, sequestering agents, emulsifying stabilizers, silicone, water and the like can be mentioned.

  Examples of the fragrances include fragrance components described in JP-A No. 2003-300811, [0021] to [0035], and further a fragrance solvent described in [0050]. The amount of the fragrance solvent used is 0.1 to 99% by mass, preferably 1 to 50% by mass in the fragrance composition. Examples of the fragrance stabilizer include dibutylhydroxytoluene, butylhydroxyanisole, vitamin E and its derivatives, catechin compounds, flavonoid compounds, polyphenol compounds and the like, and 0.0001 to 10% by mass in the fragrance composition. However, Preferably, 0.001 to 5 mass% is mix | blended. Among these, a preferable stabilizer is dibutylhydroxytoluene. A fragrance composition is a mixture comprising the fragrance component, a solvent, and a fragrance stabilizer. The hair fragrance composition of the present invention contains 0.005 to 40% by mass of the fragrance composition in the hair styling composition, but preferably 0.01 to 10% by mass.

  The pH at 25 ° C. of the hairdressing composition of the present invention is preferably 2 to 10, more preferably 3 to 8. The pH of the hairdressing composition is determined by the method defined in the general test method of the cosmetic raw material standard (second edition), and the pH value is read after the pH meter electrode is directly inserted into the composition. Can be measured by

  The hairdressing composition of the present invention can be prepared and used in various shapes such as liquid, cream, wax, gel, foam, mist, etc., for example, by mixing the above ingredients and water (remainder), It can be prepared according to conventional methods for pharmaceutical systems. Furthermore, the hairdressing composition according to the present invention can be used as hair water, hair oil, hair cream, hair wax, hair foam, hair spray, hair mist and the like. Of these, hair wax is most preferred. Moreover, when using as a foam production | generation aerosol type | mold, as a propellant to mix | blend, liquefied petroleum gas, nitrogen gas, carbon dioxide gas etc. can be used, for example.

  EXAMPLES Hereinafter, although an Example and a comparative example are shown and this invention is demonstrated concretely, this invention is not restrict | limited to the following Example. In the following examples, unless otherwise specified, “%” of the composition is mass%, and the amount of each component is an amount converted into a pure component.

[Examples 1-6 , Comparative Examples 1-3 , Reference Examples 1-10 ]
Compositions having the compositions shown in Tables 1 to 3 were prepared and evaluated by the following methods. The results are also shown in the table.

The set retention evaluation method under high humidity conditions (after 95% RH 8 hours) will be described with reference to FIG. 0.02 g of each composition was uniformly applied to a human hair bundle 1 (length 7 cm, 0.5 g) that had been treated once with a permanent and twice with a bleaching agent. A grid-like mounting plate 2 is set up vertically on the floor, and one end of the hair bundle 1 coated with the composition is attached to the mounting plate 2 with a clip so that the angle formed by the mounting plate 2 and the hair bundle 1 is 90 degrees. , Set with your fingers. Thereafter, the hair bundle 1 was left at 30 ° C. and 95% RH (relative humidity), and the angle formed by the attachment plate 2 and the hair bundle 1 after 8 hours was measured and evaluated based on the following criteria.
<Evaluation criteria>
A: 90 ° to 85 °
○: 84 ° to 75 °
Δ: 74 ° to 60 °
×: Less than 60 °

Non-sticky hair 20 female panelists used a suitable amount of hair wax filled in a jar according to the length of the hair, and evaluated the non-stickiness of the hair. The evaluation is based on the following criteria based on the number of people who answered “good”.
◎: 16 or more out of 20 responded as good ○: 10-15 out of 20 responded as good △: 4-9 out of 20 responded as good ×: Responded as good 3 or less of 20 people

Ease of washing with shampoo 20 female panelists (hair length semi-long) took an appropriate amount of hair wax filled in a jar (1 g) and used it (1 g), then shampooed and evaluated the ease of washing with shampoo. As the shampoo, an appropriate amount (about 6 g) of a plant story herb blend European blend (made by Lion) was used. The evaluation is based on the following criteria based on the number of people who answered “good”.
◎: 16 or more out of 20 responded as good ○: 10-15 out of 20 responded as good △: 4-9 out of 20 responded as good ×: Responded as good 3 or less of 20 people

[ Reference Example 11 ]
Dispenser Type Water Agent A water agent having the following formulation was prepared and filled into a PET pump dispenser container.
Composition%
Dimethyl silicone 2 0.5
Microcrystalline wax 2 5.0
Amino-modified silicone 1 0.5
Gallic acid-3,5-diglucoside 0.4
POE (30) Phytosterol 0.5
Decaglyceryl monooleate 0.5
Stearyltrimethylammonium chloride 1.0
POE (20) stearyl ether 3.0
N-methacryloyloxydiethyl N, N-dimethylaminoethyl-α-N-methylcarboxybetaine / methacrylic acid alkyl ester copolymer solution 0.05
Polyethylene glycol 400 3.0
Nylon powder 0.2
Methyl paraoxybenzoate 0.1
Anhydrous sodium pyrophosphate 0.05
Glycolic acid 0.2
Triethanolamine 1.0
Fragrance composition A 0.1
Ethanol 20.0
Purified water balance
Total 100.0

[Example 7 ]
Non-aerosol pump foam A foam agent having the following formulation was prepared and filled in a polypropylene pump foam container. The pH was adjusted to 4.5.
Composition%
Candelilla Row 5.0
Cationized starch 1.0
POE (30) Phytosterol 0.5
Tetraoleic acid POE (40) Sorbit 3.0
3-methyl-1,3-butanediol 10.0
Polyethylene glycol 400 3.0
Talc 0.5
Dimethyl silicone 2 1.0
Amino-modified silicone emulsion 2 1.0
POE (30) stearyl ether 0.9
Lauryldimethylamine oxide 0.5
Methyl paraoxybenzoate 0.1
Citric acid 0.5
Diethanolamine appropriate amount perfume composition C 0.1
Ethanol 20.0
Purified water balance
Total 100.0

[Example 8 ]
Gel A gel having the following formulation was prepared and filled in a pump type container made of PET. The pH was adjusted to 4.4, and the viscosity was adjusted to 1.5 to 3 Pa · s.
Composition%
Carnauba Arrow 5.0
Carboxyvinyl polymer 1 0.5
POE (40) hydrogenated castor oil 3.0
Amino-modified silicone 2 5.0
Tetraoleic acid POE (30) Sorbit 1.5
Polyethylene beads 0.5
POE (20) Phytosterol 0.5
Polyglyceryl diisostearate 5.0
Triethanolamine 0.5
Polyethylene glycol 400 5.0
Hydroxyethyl cellulose Appropriate amount Methyl paraoxybenzoate 0.1
Anhydrous sodium pyrophosphate 0.2
Glycolic acid appropriate amount ethanol 20.0
Fragrance composition D 0.05
Purified water balance
Total 100.0

[Example 9 ]
Aerosol foam An aerosol foam having the following formulation was produced. The container used was a pressure can made of aluminum.
Composition%
(Stock solution)
Dimethyl silicone 2 1.0
Isoparaffin wax 10.0
Amino-modified silicone 2 2.0
Tetraoleic acid POE (6) Sorbit 1.5
POE (30) Phytosterol 1.0
Polyethylene glycol 1500 10.0
Talc 5.0
Cationized cellulose 0.1
Dipropylene glycol 6.0
Stearyltrimethylammonium chloride 2.5
POE (60) hydrogenated castor oil 2.0
Triethanolamine 2.0
Fragrance composition C 0.1
Ethanol 20.0
Purified water balance
Total 92.0
(gas)
LPG gas 8.0
Total 100.0

[Example 10 ]
Hair wax A hair wax having the following formulation was prepared and filled in a jar-type container made of polypropylene into which an antistatic agent and an ultraviolet absorber were kneaded.
Composition%
Microcrystalline wax 1 10.0
Vaseline 20.0
POE (30) Phytosterol 1.0
Tetraoleic acid POE (40) Sorbit 1.0
Decaglyceryl diisostearate 5.0
Carboxyvinyl polymer 1 0.5
Polyethylene glycol 400 10.0
Polyorganosilsesquioxane 5.0
Talc 5.0
POE (60) hydrogenated castor oil 4.0
Glyceryl monostearate 1.0
Squalane 2.0
Candelilla Row 1.0
Polyoxypropylene (14) diglyceryl ether 4.0
Methyl paraoxybenzoate 0.1
Propyl paraoxybenzoate 0.3
Sodium benzoate 0.2
Glycerin 5.0
Diethanolamine 1.0
Fragrance composition B 0.05
Ethanol 5.0
Purified water balance
Total 100.0

[ Reference Example 12 ]
Gel A gel having the following formulation was prepared and filled into a polypropylene tube container.
Composition%
Dimethyl silicone 1 0.5
Tree wax 10.0
POE (30) Phytosterol 1.0
Monooleic acid POE (20) sorbitan 1.0
Talc 5.0
Polyethylene glycol 300 10.0
Carboxyvinyl polymer 1 0.5
Xanthan gum 0.25
POE (20) stearyl ether 8.0
Methyl paraoxybenzoate 0.1
Triethanolamine 1.5
Fragrance composition E 0.05
Ethanol 15.0
Purified water balance
Total 100.0

[Example 11 ]
Hair cream A oil phase part and B water phase part were each dissolved at 70 ° C., A was added to B, and the mixture was uniformly emulsified. The laminate tube was filled.
Composition%
Oil phase A Dimethyl silicone 1 1.0
Candelilla Row 6.0
Vaseline 5.0
Liquid paraffin 1.0
Polyethylene glycol 1500 9.0
Palm oil fatty acid sorbitan 2.0
Glycerol monostearate 1.0
Propyl paraoxybenzoate 0.1
B water phase POE (60) phytosterol 0.5
Tetraoleic acid POE (60) Sorbit 0.5
Stearyltrimethylammonium chloride 0.3
Dipropylene glycol 2.5
Methyl paraoxybenzoate 0.1
Purified water balance
Fragrance composition D 0.05
Total 100.0

[Example 12 ]
Aerosol foam An aerosol foam having the following formulation was prepared and filled in a pressure-resistant container made of PET.
Composition%
(Stock solution)
Amino-modified silicone 1 2.0
Microcrystalline wax 2 10.0
Vaseline 0.5
POE (30) Phytosterol 1.5
Tetraoleic acid POE (40) Sorbit 0.5
Polyethylene glycol 400 10.0
Talc 5.0
POE (30) stearyl ether 1.0
Triethanolamine 2.5
Benzoic acid 0.1
Fragrance composition B 0.2
Ethanol 20.0
Purified water balance 80.0
(gas)
LPG 10.0
DME 10.0
Total 100.0

In addition, the fragrance | flavor composition A, B, C, D, and E which were used by said each example are based on fragrance | flavor composition AE shown to Unexamined-Japanese-Patent No. 2003-267841 Table 2-16. For Examples 7 to 12 and Reference Examples 11 and 12 , as in Example 1, the set retention under high humidity conditions, the non-stickiness of hair, and the ease of washing with shampoo were evaluated. It was good.

  The raw materials used in the examples are shown below. POE represents polyoxyethylene.

It is explanatory drawing of the set holdability evaluation method under high-humidity conditions.

Explanation of symbols

1 Hair bundle 2 Mounting plate

Claims (8)

(A) solid waxes and / or solid waxes, (B) polyoxyethylene (4-60) phytosterol , (C) polyoxyethylene (6-60) sorbit fatty acid ester , (D) alkylene glycol A hair styling composition comprising: Additionally, (E) according to claim 1 Symbol placement of hair fixative compositions containing solid powder. The hair styling composition according to claim 1 or 2, wherein the component (A) is selected from microcrystalline wax, candelilla wax, and carnauba wax, and the content in the composition is 5 to 30% by mass. The component (B) is selected from polyoxyethylene (10) phytosterol, polyoxyethylene (20) phytosterol, polyoxyethylene (30) phytosterol, and polyoxyethylene (60) phytosterol, and contained in the composition The hair styling composition according to any one of claims 1 to 3, wherein the amount is 0.1 to 10% by mass. (C) component is tetraoleic acid polyoxyethylene (6) sorbite, tetraoleic acid polyoxyethylene (30) sorbit, tetraoleic acid polyoxyethylene (40) sorbit, and tetraoleic acid polyoxyethylene (60) sorbit The hair styling composition according to any one of claims 1 to 4, wherein the composition is selected from the group consisting of 0.1 to 3% by mass. The hairdressing composition according to any one of claims 1 to 5, wherein the component (D) is polyethylene glycol having an average molecular weight of 280 to 3800, and the content in the composition is 0.1 to 13% by mass. The component (E) is selected from kaolin, talc, sericite, mica, aluminum magnesium silicate, hemp cellulose powder, wheat starch, silk powder, and corn starch, and the content in the composition is 5 to 30. The hair styling composition according to any one of claims 1 to 6, wherein the hair styling composition is in mass%. The hair styling composition according to any one of claims 1 to 7, which is a hair wax.

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