JP4994731B2 - Fuel cell power generation system - Google Patents

Description

  The present invention relates to a fuel cell power generation system, and in particular, achieves effective use of stack heat generation in a medium temperature fuel cell stack having a stack operating temperature of 100 [° C.] or higher.

  FIG. 9 shows the structure of a conventional fuel cell stack 1. A conventional fuel cell stack 1 includes a sheet-like solid polymer electrolyte membrane 2, a fuel electrode 3 and an oxidizer electrode 4 joined to each of the main surfaces of the second solid polymer electrolyte membrane 2, and further, both of the outer surfaces of the fuel electrode stack 1. A plurality of fuel battery cells 9 each composed of a fuel gas separator 6 having a fuel gas flow path 5 and an oxidant gas separator 8 having an oxidant gas flow path 7 are laminated, or for each number of laminated fuel cells. 9 and a cooling plate 11 having cooling medium flow paths 10 are arranged alternately.

  Here, the cooling plate 11 generates heat when a fuel gas mainly containing hydrogen and an oxidant gas such as air or oxygen react electrochemically with the solid polymer electrolyte membrane 2 interposed therebetween. It arrange | positions in order to exhaust heat and to keep the temperature of the fuel cell 9 constant. Further, water is mainly used as the cooling medium supplied to the cooling plate 11.

  FIG. 10 shows a configuration of a conventional stationary fuel cell power generation system 20 in which the fuel cell stack 1 is mounted. The cooling medium supplied to the cooling plate 11 in the fuel cell stack 1 is configured to circulate between the cooling plate 11 and the pure water tank 22 by the power of the circulation pump 21 or the like. The pure water tank 22 is heat-exchanged with an external heat utilization device, for example, a hot water storage tank 23, so that the cooling water discharged from the cooling plate 11 and having a high temperature is cooled to a predetermined temperature, The system configuration is such that the cooling plate 11 is supplied again and circulated.

  Specifically, the raw material gas is supplied from the outside, the reformer 24 reforms the raw material gas into a hydrogen-rich reformed gas, and carbon monoxide in the reformed gas is reduced to become a fuel gas. The shift reactor 25 and the CO selective oxidation unit 26, the fuel cell stack 1 that receives the supply of fuel gas and air and generates power by an electrochemical reaction, the cooling water of the fuel cell stack 1, and the low-temperature water of the hot water storage tank 23 A heat exchanger 27 that performs heat exchange, a DC / DC converter 28 that adjusts the voltage and current of the DC power from the fuel cell stack 1 to convert it to desired DC power, and the converted DC power to a commercial power source (system) ) And an inverter 29 for supplying power to a commercial power supply (system).

The pure water stored in the pure water tank 22 is supplied to the steam generator 31 via the pure water supply pump 30 and supplied to the inlet of the reformer 24 via the steam control valve 32. Are arranged in series. In the reformer 24 and the shift reactor 25, the raw material gas supplied from the raw material gas line via the booster pump 33, the desulfurizer 34 that removes sulfur and the control valve 35, and the pure water tank 22 to the steam generator 31. Then, the hydrogen-rich reformed gas is generated by the steam reforming reaction and the shift reaction of the following formulas (1) and (2) with the steam whose flow rate is adjusted by the control valve 32.
CH ₄ + H ₂ O → CO + 3H ₂ (1)
CO + H ₂ O → CO ₂ + H ₂ (2)

  The reformer 24 is provided with a combustion section 36 that supplies heat necessary for such a reaction and, in addition, heat necessary for generating steam in the steam generator 31. The exhaust gas on the anode side of the fuel cell stack 1 is supplied so that unreacted hydrogen in the anode off-gas can be used as fuel.

  Therefore, in the power generation system 20 using a conventional low-temperature solid polymer fuel cell (operating temperature is 100 [° C.] or less), the amount of hydrogen required in the fuel cell stack 1 and the combustion part 36 are set to 700 [ It was necessary to supply a raw material gas corresponding to the sum of the amount of hydrogen necessary to maintain a predetermined temperature of about [° C.] to the power generation system.

給したメタンのうち、改質された割合）、Ｕｆは燃料利用率（発電に必要な理論水素量と実際に燃料電池スタック５０に供給する水素量との比）、Ｖは定格負荷運転時の電圧、Ｖ_０は理論電圧、ηｉｎｖはインバーター効率を表す。Here, the following formula (3) shows the power generation efficiency of the stationary fuel cell power generation system.

Of the supplied methane, the reformed ratio), Uf is the fuel utilization rate (ratio between the theoretical hydrogen amount necessary for power generation and the hydrogen amount actually supplied to the fuel cell stack 50), and V is the rated load operation Voltage, V ₀ is the theoretical voltage, and ηinv represents the inverter efficiency.

  The power generation efficiency of the low-temperature polymer electrolyte fuel cell power generation system currently being leased and sold in Japan is about 32 [%] (HHV), which is lower than the average power generation efficiency of system power about 37 [%]. Although it is a value, since the heat recovery efficiency used for hot water supply exceeds 40%, the overall efficiency exceeds 70% (HHV).

  Therefore, the advantage can be exhibited in the cogeneration operation of the heat mains, but, for example, in summer, the demand for hot water supply is reduced, so the advantage in overall efficiency cannot be established, and the low temperature solid polymer Since the operating time of the fuel cell power generation system is reduced, there is a problem that the merit of reducing the annual running cost is reduced. For this reason, for the commercialization of the polymer electrolyte fuel cell power generation system, it is desired to increase the power generation efficiency to be equal to or higher than the system power.

  In response to these demands, in recent years, in order to effectively use heat in the system, a medium temperature type operating temperature of 100 ° C. or higher (in this case, a low temperature type operating fuel cell having an operating temperature of 100 ° C. or lower). Research and development of a polymer electrolyte fuel cell (which defines a temperature of 100 to 250 [° C.] as a medium temperature type) is underway. In this intermediate temperature type polymer electrolyte fuel cell, the temperature of water that is a cooling medium of the fuel cell stack also becomes 100 [° C.] or higher, so that with the increase of the saturated vapor pressure, the pressure resistance specification is essential for the refrigerant piping system.

  In particular, the pressure-resistant specification of the cooling water circulation pump 21 (FIG. 10) is currently selected from industrial pumps with a large capacity, which inevitably leads to an increase in power consumption and size, and is targeted at household use. In designing a small-capacity (for example, 5 kW or less) fuel cell power generation system, there is a problem that the system design cannot be established in terms of system efficiency and system size, and commercialization becomes difficult.

  In this case, in order to avoid the pressure resistance specification of the cooling system, a counter plan using a high-boiling point refrigerant, such as silicon oil, can be considered, but these high-boiling point refrigerants have a considerably lower thermal conductivity than water, which increases the flow rate of the cooling medium. Not only does this increase the power of the circulating pump, but also reduces the heat efficiency from the standpoint of heat recovery of stationary fuel cell power generation systems for cogeneration purposes. The problem remained.

As a solution to the above-mentioned cooling system pressure resistance specification, Patent Document 1 discloses that a plate-type heat pipe is used by using a plate-type heat pipe having a structure that is larger than the area of the stack end face of the fuel cell and protrudes from the stack end face. Realizing a heat dissipation structure using pipes enables air cooling of the fuel cell stack, eliminates the need for equipment such as a circulation pump and cooling circulation water piping for cooling the fuel cells, and circulates the cooling medium. A method of providing a fuel cell that does not require management of the pump power of water and water as a cooling medium, achieves downsizing and cost reduction of the device, improves efficiency during power generation, and facilitates maintenance management. Disclosure.
Japanese Patent Laid-Open No. 11-214017

  However, the method described in Patent Document 1 is specialized in cooling of the fuel cell stack, and is an effective means for applications such as portable fuel cells, but aims at cogeneration that effectively uses the heat generated by the fuel cell stack. However, in the stationary fuel cell power generation system, no measures have been taken to improve the system efficiency.

  The present invention has been made in consideration of the above points, and intends to propose a fuel cell system capable of improving the electrical efficiency of the system and at the same time simplifying the configuration of the entire apparatus and reducing the power of auxiliary equipment. Is.

  In order to solve such a problem, in the present invention, a cell composed of an electrolyte and a pair of electrodes composed of an anode and a cathode sandwiching the electrolyte, a fuel gas containing hydrogen is supplied to and discharged from the anode of the electrode, and oxygen is supplied to the cathode. A fuel cell stack in which a plurality of pairs of separators having gas flow paths for supplying and discharging the contained oxidant gas are alternately stacked; a fuel reforming processing system for generating a fuel gas to be supplied from the raw material gas to the fuel cell body; A fuel cell power generation having a pure water system for supplying pure water to a first steam generator for supplying water vapor necessary for causing a reforming reaction in the fuel reforming treatment system and at the same time making effective use of exhaust heat In the system, the heat transfer medium is engaged with all or a part of the plurality of cells stacked in the fuel cell stack with heat conductivity, and the fuel cell is connected to the heat transfer medium in a heat conductive connection. Disposed adjacent to the stack, characterized in that it comprises a second steam generator for generating steam based on the heat supplied through the heat transfer medium.

  In the present invention, the first steam generator and the second steam generator are connected in series by being connected via the first shut-off valve, and the second steam generator is connected to the steam control valve. A line connected to the inlet of the fuel reforming treatment system via a line and a line returning to the pure water system via the second shut-off valve, and during the system startup, the first shut-off valve is opened, By supplying the steam generated by the first steam generator to the second steam generator, the heat of the steam staying in the second steam generator is transferred to the fuel cell stack via each heat transfer medium. Then, after the temperature rise of the fuel cell stack is completed, when the system load is turned on, the steam control valve is opened, and the steam generated by the first steam generator is passed through the second steam generator. To the fuel reforming system, the system shifts to system load operation. After the setting, the first shut-off valve disposed between the first steam generator and the second steam generator is closed, and the second shut-off valve is opened so that the second steam generation It is characterized by switching to single operation of the vessel.

  Furthermore, in the present invention, the heat transfer medium is characterized in that a plurality of cells stacked in the fuel cell stack are inserted every predetermined number of stacked sheets or alternately with each cell. Furthermore, the heat transfer medium is characterized in that it has a meandering capillary heat pipe structure in which meandering narrow tubes are arranged or formed in a plate, and a working fluid as a heat transport medium is enclosed in the narrow tubes.

  Further, the heat transfer medium is characterized in that an electrical insulating inclusion is disposed on at least one of the stacked end faces of the plurality of cells.

  As described above, according to the fuel cell power generation system of the present invention, the heat generation of the intermediate temperature fuel cell stack having an operation temperature of 100 [° C.] or more is transferred to the adjacent second steam generator to perform the reforming reaction. Can be used for steam generation necessary for the conventional fuel reforming treatment system provided in the conventional low temperature type (operating temperature 70 to 80 [° C.]) polymer electrolyte fuel cell power generation system. It is no longer necessary to apply heat equivalent to the generation of reformed steam to one steam generator, and the raw material gas to be input to the fuel cell power generation system can be reduced. As a result, since operation with a higher fuel utilization rate is possible, higher electric efficiency of the fuel cell power generation system can be achieved.

  Further, since the heat transfer medium that moves the heat generated by the fuel cell stack to the second steam generator is a plate heat pipe having excellent heat conductivity, it is required when water is conventionally used as the heat transfer medium. The equipment such as the pressure-resistant circulation pump and the cooling circulation water piping can be eliminated, so that the apparatus can be reduced in size and cost, and the auxiliary power can be reduced.

  Furthermore, according to the method for starting the fuel cell power generation system according to the present invention, during the system startup, a part of the combustion heat generated in the combustion part of the reformer is obtained and generated by the first steam generator. Using steam, heat is transferred through a heat transfer medium arranged in the second steam generator to increase the temperature of the fuel cell stack. Further, during the transient state of load application and rated load transition However, since the amount of heat transfer from the fuel cell stack to the second steam generator is still insufficient, the supply of reformed steam by the second steam generator alone cannot be realized, so that the first steam generator Is controlled so that the steam continuously generated from the fuel can be supplied to the reformer as reformed steam, so that water is conventionally used as a heat transfer medium even in an intermediate temperature fuel cell stack with an operating temperature of 100 ° C or higher. In case that the Flop, circulating cooling water pipe without requiring a sounding equipment, such as, quickly and efficiently, to complete the heating operation of the fuel cell stack, it may also complete a transient state until rated operation smoothly.

  From the above, we have improved the electrical efficiency of the fuel cell power generation system by using the heat generated by the intermediate temperature fuel cell stack and generating reformed steam, and at the same time, deleted the conventional fuel cell stack cooling water circulation line. It is possible to provide a fuel cell power generation system that can reduce the cost of the apparatus and reduce the power of auxiliary equipment.

  In the present invention, particularly in an intermediate temperature fuel cell power generation system, a fuel cell stack and a first steam generator are disposed adjacent to each other via a heat transfer medium for cooling or heating the fuel cell stack. The heat generated by the fuel cell stack is directly used as a heat source for generating steam for the reformer, while the heat obtained by the first steam generator is used for heating the fuel cell stack during system startup. And

Embodiments of the present invention will be described below in detail with reference to the drawings.
(1) First Embodiment (1-1) Configuration of Fuel Cell Stack FIG. 1 shows the structure of a fuel cell stack 50 showing an embodiment of the present invention. A structure arranged adjacent to the vessel 51 is shown in FIG. Hereinafter, an embodiment of the present invention will be described with reference to FIGS.

  The fuel cell stack 50 of the present invention includes a sheet-like solid polymer electrolyte membrane 52, a fuel electrode 53 and an oxidizer electrode 54 joined to each of the main surfaces of the solid polymer electrolyte membrane 52, and both outer surfaces of the fuel electrode stack 50. A plurality of fuel battery cells 59 each composed of a fuel gas separator 56 having a fuel gas flow channel 55 and an oxidant gas separator 58 having an oxidant gas flow channel 57 are stacked. The heat transfer medium 60 having a structure protruding from at least one side of the laminated end face is interposed. Each of these heat transfer media 60 is covered with an insulating sheet 61 on the projecting portion so as to prevent a short circuit when connected to the second steam generator 51.

  The connection between the heat transfer medium 60 and the second steam generator 51 via the insulating sheet 61 facilitates heat transfer, so that the heat transfer medium 60 is finned in the second steam generator 51. Arranged to obtain structure. The connection between the heat transfer medium 60 and the second steam generator 51 is not limited to the fin structure, and a configuration in which heat exchange between the two is effectively performed is desirable. Further, a heat insulating material 62 for preventing heat dissipation is attached around the fuel cell stack 50, the heat transfer medium 60, and the second steam generator 51 so as to cover the whole.

Here, a rough calculation regarding the heat generation amount of the fuel cell stack 50 during the rated load operation and the heat balance necessary for generating the reformed steam required for performing the reforming reaction during the rated operation is shown below. .
・ Assumption conditions (1) System capacity: 1kW class power generation system for home use (Gloss output 1.3 [kW])
( ² ) Rated performance of fuel cell: 0.3 [A / cm ² ] load current, cell voltage 0.75 [V / cell], cell effective area 100 [cm ² ], number of cells 45 [cell]
(3) Reformer performance: reformer conversion efficiency 90 [%], fuel utilization rate Uf = 80 [%], steam / carbon ratio = 3
(4) Heat dissipation = 0 (ideal condition)

The heat balance when calculated under the above assumptions (1) to (4) is as shown in Table 1 below.

  As described above, from the results shown in Table 1, even when heat dissipation and transient response are taken into account, the amount of heat generated by the reformed steam can be sufficiently covered by the amount of heat generated by the stack.

  As described above, according to the rated operation of the fuel cell power generation system of the embodiment described above, the heat generated by the intermediate temperature type fuel cell stack 50 having an operation temperature of 100 ° C. or more is moved to the adjacent second steam generator 51. Since it can be used for steam generation necessary for reforming reaction, it is used in the fuel reforming treatment system that has been carried out in the conventional low temperature type (operating temperature 70-80 [° C]) polymer electrolyte fuel cell power generation system. The first steam generator 31 (FIG. 10) provided in FIG. 10 does not need to be supplied with heat equivalent to the generation of reformed steam, and the raw material gas input to the fuel cell power generation system can be reduced. As a result, since operation with a higher fuel utilization rate is possible, higher electric efficiency of the fuel cell power generation system can be achieved.

(1-2) Detailed Configuration of Heat Transfer Medium Next, the heat transfer medium 60 used in the present invention will be described with reference to FIGS. 3 (A) and 3 (B). The heat transfer medium 60 has a plate-type heat pipe structure, and a loop-type meandering capillary 65 is disposed or formed in a conductive metal plate, and a working fluid as a heat transport medium is enclosed in the capillary. ing. As the conductive plate, a metal or carbon material having excellent conductivity and workability such as aluminum, stainless steel, and copper is used. In particular, the reason why the heat transfer medium 60 of the present invention requires conductivity is to electrically connect the fuel cells 59 sandwiching the heat transfer medium 60 in series.

  As the hydraulic fluid, HFC134a (alternative chlorofluorocarbon) or butane (Bu) -based hydraulic fluid suitable for the operating temperature range of the fuel cell stack 50 of the present invention is used, and is enclosed in the loop-type meandering capillary 65. The feature of the heat transfer medium 60 having a plate heat pipe structure is that there is no significant change in heat transport capability depending on the application posture, so that the heat receiving part and the heat radiating part can be exchanged at both ends of the heat transfer medium 60. Accordingly, heat can be input and output in both directions between the fuel cell tank 50 and the second steam generator 51. Moreover, an example of the performance of the heat transfer medium 60 having a commercially available plate-type heat pipe structure is shown below.

The fuel cell stack 50 configuration (for example, heat transfer) with the heat transfer capacity performance of an example of the heat transfer medium 60 shown in Table 2 with respect to the calorific value 0.89 [kW] of the 1 kW class fuel cell stack shown in Table 1 When calculating the contact area at the time of medium insertion of 100 [cm ² ], for example, 9 sheets (insertion for every 5 unit cells) even if the temperature distribution in the fuel cell stack 50 is reduced. If the heat transfer medium 60 is inserted, a predetermined heat balance in the fuel cell power generation system can be realized without any operational problems.

  As described above, when the heat transfer medium 60 of the embodiment described above is used, the heat transfer medium 60 has a plate-type heat pipe structure, so that the heat generated in the fuel cell stack 50 is transferred to the working fluid inside the heat transfer medium 60. The hydraulic fluid becomes high-temperature and high-pressure steam bubbles, and heat can be quickly transferred to the second steam generator 51 by the circulation or vibration phenomenon of the hydraulic fluid toward the low-temperature second steam generator 51. I can do it.

  As a result, even in medium-temperature fuel cell power generation systems with an operating temperature of 100 [° C] or more, facilities such as a pressure-resistant circulation pump and cooling circulation water piping that were required when water was conventionally used as the heat transfer medium Without the necessity, heat generation of the fuel cell stack 50 can be quickly and efficiently moved to the second steam generator 51 to generate steam.

(1-3) Configuration of Fuel Cell Power Generation System Next, the configuration of the fuel cell power generation system of the present invention will be described. FIG. 4, in which the same reference numerals are assigned to the parts corresponding to those in FIG. As shown in the figure, the fuel cell power generation system 70 of the embodiment receives a raw material gas supplied from the outside and reforms the raw material gas into a hydrogen-rich reformed gas, and a reformer gas in the reformed gas. A shift reactor 25 that reduces carbon oxides into fuel gas, a fuel cell stack 50 that receives supply of the fuel gas and air and generates electric power through an electrochemical reaction, a cooling water and a hot water storage tank 23 of the fuel cell stack 50 A heat exchanger 71 that performs heat exchange with low-temperature water, a DC / DC converter 28 that adjusts the voltage and current of DC power from the fuel cell stack 50 to convert it to desired DC power, and the converted DC power An inverter 29 is provided that converts AC power in phase with the commercial power source (system) and supplies power to the commercial power source (system).

  The pure water stored in the pure water tank 22 is supplied to the first steam generator 31 via the pure water supply pump 30, and further to the second steam generator 51 via the shut-off valve 72. Are arranged in series so as to be finally supplied to the inlet of the reformer 24 via the steam control valve 32. A bypass line 74 of the first steam generator 31 connected to the downstream of the shutoff valve 72 is provided after the piping is branched and the bypass valve 73 is arranged downstream of the pure water supply pump 30. The second steam generator 51 is provided with a liquid level meter 75 and a pressure gauge 76 for measuring the liquid level and pressure in the second steam generator 51, and receives these signals. A return line 78 to the pure water tank 22 provided with the shutoff valve 77 is provided so as to be controlled to a predetermined liquid level and pressure.

  In the reformer 24 and the shift reactor 25, the raw material gas supplied from the raw material gas line via the booster pump 33, the desulfurizer 34 that removes sulfur, and the control valve 35, and the first steam from the pure water tank 22. Hydrogen-rich reforming by the steam reforming reaction and shift reaction of the above formulas (1) and (2) with the steam whose flow rate is adjusted by the control valve 32 via the generator 31 and the second steam generator 51 It is configured to generate gas. The reformer 24 is provided with a combustion section 36 that supplies heat necessary for such a reaction. The combustion section 36 is supplied with the exhaust gas on the anode side of the fuel cell stack 50, and is included in the anode off-gas. Unreacted hydrogen can be used as a fuel.

  The fuel cell stack 50 generates power by an electrochemical reaction between hydrogen in the fuel gas from the shift reactor 25 and oxygen in the air from the air blower 79. As described above, the heat transfer medium 60 is disposed between the fuel cell stack 50 and the second steam generator 51, so that heat transfer between the two can be efficiently performed.

Here, for example, according to Table 1 showing the heat balance of a 1 kW class stationary fuel cell power generation system,
(The amount of heat generated by the 1 kW class stack during rated operation)> (The amount of heat necessary for generating reformed steam during rated operation) (4)
Therefore, the discharge flow rate of the deionized water supply pump 30 and the pressure in the second steam generator 51 are detected so that the difference in the amount of heat in the equation (4) is returned to the deionized water tank 22. By controlling the shut-off valve 77 disposed in the return line 78 that operates, a part of the heat generated by the fuel cell stack 50 can be moved to the pure water tank 22. Further, the pure water tank 22 is provided with a heat exchanger 71, which receives a part of the heat generated by the fuel cell stack 50 and supplies the pump 80 from the hot water storage tank 23 by heat exchange with the heated pure water. The low-temperature water to be heated is heated and stored in the hot water tank 23.

  According to the polymer electrolyte fuel cell power generation system 70 of the present embodiment described above, the calorific value of the fuel cell stack 50 operated at 100 [° C.] or higher is transferred via the heat transfer medium 60 to the second steam. Since it can be efficiently transmitted to the generator 51, the second steam generator 51 has approximately twice as much steam as the reformed steam necessary for the rated power generation operation (the heat release to the outside of the system is “0”). Can be generated).

  During the rated operation of the fuel cell power generation system 70 of this embodiment, the shutoff valve 72 is closed and the shutoff valve 73 is opened, so that pure water supplied from the pure water pump 30 bypasses the first steam generator 31. Directly supplied to the second steam generator 51. As a result, during the rated operation, the second steam generator 51 that uses only the heat generated by the fuel cell stack 50 is operated independently, so that the conventional low-temperature solid polymer fuel cell power generation system 20 (FIG. 10) is used. The generation of reformed steam by the first steam generator 31 using the combustion heat of unreacted hydrogen in the anode off-gas as has been performed can be stopped. As a result, since the input amount of the raw material gas corresponding to the amount of heat used for steam generation in the first steam generator 31 can be reduced, the power generation efficiency can be increased. (By increasing the fuel utilization rate Uf in the equation (3), the power generation efficiency is increased.)

(1-3) Start-up operation of the fuel cell power generation system Next, the operation when the fuel cell power generation system 70 of the present invention is started will be described. 5 and 6 are flowcharts showing an example of the start operation executed in the present invention.

  When the start command for the fuel cell power generation system 70 is executed, the air blower 79 is operated to supply air to the combustion unit 36. Thereafter, the booster pump 33 of the raw material gas line is operated, and the raw material gas that has passed through the desulfurizer 34 is supplied to the combustion unit 36 via a pipe (not shown). Next, the burner 36A disposed in the combustion unit 36 is ignited, so that the supplied air and the raw material gas heat the inside of the combustion unit 36, and the reformer 24 and the adjacent shift reactor 25 and the first steam are heated. The generator 31 is heated.

  When the temperature of the combustion unit 36 reaches a predetermined temperature at which the first steam generator 31 can sufficiently generate steam, the pure water supply pump 30 is operated, and from the pure water tank 22, Pure water is supplied to the steam generator 31. At this time, since the shutoff valve 72 is in an open state, the steam generated by the first steam generator 31 is supplied to the second steam generator 51 connected in series.

  The steam supplied to the second steam generator 51 gives heat to the fuel cell stack 50 via the heat transfer medium 60, whereby the temperature raising operation of the fuel cell stack 50 is performed. In the second steam generator 51, the supplied steam condenses after giving heat to the fuel cell stack 50, and the condensed liquid level rises, but the liquid level meter 75 detects the predetermined liquid level. When the pressure exceeds the level, the shut-off valve 77 is opened, and the liquid level of the second steam generator 51 is controlled by operating the condensed water to return to the pure water tank 22 through the return line 78.

  When the fuel cell stack 50 reaches a predetermined operating temperature, for example, 150 [° C.], the pressure gauge 76 detects the vapor pressure corresponding to the temperature, the shut-off valve 77 is opened, and the vapor is returned to the return line 78. The temperature of the second steam generator 51 and the fuel cell stack 50 is controlled to a predetermined value by operating to discharge to the pure water tank 22. When the temperature raising operation of the reformer 24 and the fuel cell stack 50 is performed and both of them reach a predetermined temperature, the fuel gas introduction mode is entered.

  The steam staying in the second steam generator 51 is supplied to the reformer 24 by opening the steam control valve 32. Thereafter, the control gas 35 disposed downstream of the desulfurizer 34 is opened to supply the raw material gas to the reformer 24. As a result, in the reformer 24 and the shift reactor 25, the steam reforming reaction shown in the formula (1) and the shift reaction shown in the formula (2) respectively occur, so that the anode of the fuel cell stack 50 The fuel gas is rich in hydrogen. Thereafter, the control valve 81 is opened, and air is supplied to the cathode of the fuel cell stack 50, whereby the fuel cell stack 50 shifts to a power generation operation standby state, and a load is applied to the system.

  Next, when the hydrogen-rich fuel gas and air equivalent to the rated operation are supplied, the load is increased and the operation shifts to the rated load operation. After reaching the rated load operation, simultaneously closing the shutoff valve 72 disposed downstream of the first steam generator 31 and simultaneously opening the shutoff valve 73 disposed in the bypass line 74 that bypasses the first steam generator 31, Pure water in the pure water tank 22 is directly supplied to the second steam generator 51. As a result, the pure water supplied from the pure water tank 22 is converted into steam in the second steam generator 51 by the heat generated by the fuel cell stack 50 that has moved through the heat transfer medium 60, and reformed. Used as reformed steam supplied to the vessel 24. Therefore, in the rated load mode, the reformed steam supply to the reformer 24 is continued by the single operation of the second steam generator 51.

  According to the start-up operation method of the polymer electrolyte fuel cell power generation system 70 of the present embodiment described above, during the system start-up, a part of the combustion heat generated in the combustion unit 36 of the reformer 24 is obtained. Using the steam generated by the first steam generator 31, heat is transferred through the heat transfer medium 60 disposed in the second steam generator 51, thereby performing the temperature raising operation of the fuel cell stack 50, Furthermore, during the transient state of load application and transition to the rated load, the amount of heat transfer from the fuel cell stack 50 to the second steam generator 51 is still insufficient, so that the modification of the second steam generator 51 alone is not possible. Control is performed so that the steam continuously generated from the first steam generator 31 can be supplied to the reformer 24 as reformed steam in a state where the quality steam supply cannot be realized.

  As a result, the intermediate temperature fuel cell stack 50 having an operating temperature of 100 [° C.] or higher can be provided with facilities such as a pressure-resistant circulation pump and cooling circulation water piping that were required when water was conventionally used as the heat transfer medium. The temperature raising operation of the fuel cell stack 50 can be completed quickly and efficiently without the need.

(2) Second Embodiment (2-1) Configuration of Fuel Cell Stack FIGS. 7 and 8 show the configuration of a fuel cell stack 90 according to the second embodiment of the present invention.
As shown in FIG. 7, in the present invention, a flat solid polymer electrolyte membrane, a fuel electrode and an oxidizer electrode joined to each of the main surfaces of the solid polymer electrolyte membrane, and each of both outer surfaces thereof A plurality of fuel cell cells each including a fuel gas separator having a fuel gas flow channel and an oxidant gas separator having an oxidant gas flow channel are stacked, and a fuel cell stack 90 having a flat stacked end surface is formed.

  One or more plate-shaped heat transfer media 92 are arranged in parallel on two stacked side surfaces corresponding to the long sides of the stacked end surfaces of the fuel cell stack 90 via an insulating sheet 91. One end of the fuel cell stack 90 protrudes from the stacking side surface of the fuel cell stack 90, and is arranged in a shape sandwiching the second steam generator 51 as shown in FIG.

  The connection between the heat transfer medium 92 and the fuel cell stack 90 via the insulating sheet 91 and the connection with the second steam generator 51 are small in order to reduce contact thermal resistance and facilitate heat transfer. It is designed to be deployed with the contact surface pressure. In addition, a heat insulating material (not shown) for preventing heat dissipation is disposed around the fuel cell stack 90, the heat transfer medium 92, and the second steam generator 51.

  In the fuel cell power generation stack 90 of the present embodiment, the heat generated in the fuel cell during the power generation operation is transferred to the adjacent separator and transferred to the heat transfer medium 92 that is in contact with the stacked side surface. In this case, since the heat generated in the fuel cell stack 90 passes through the cross section of the long side of the separator having a flat shape, the thickness of the separator and the flat shape (vertically and horizontally) are adjusted to meet a predetermined heat transfer amount. Ratio) can be designed to achieve cooling design.

For example, assuming that the separator thickness of the 1 kW class fuel cell stack 90 is 3 [mm], the long side length is 30 [cm], and the number is 50 sheets, the total area of the two sides of the long side stack side surface of the fuel cell stack 90 Is 900 [cm ² ]. Therefore, even when the heat conduction loss due to the thermal resistance between the fuel cell stack 90 and the heat transfer medium 92 is taken into consideration, the calorific value of the 1 kW class fuel cell stack 90 is 0.89 [kW]. If the heat transfer medium 92 having the performance shown in Table 2 as an example is employed (see Table 1), the heat transfer medium 92 can be moved to the second steam generator 51 and used for steam generation necessary for the reforming reaction. I can do it.

  As described above, according to the fuel cell stack configuration of the embodiment described above, since the heat transfer medium 92 is disposed outside the stacked end surface of the fuel cell stack 90, the gas seal required when disposed in the stacked end surface. The structure and the manifold structure arranged to distribute the fuel cells to the stacked fuel cells are not required, so the cost of the heat transfer medium 92 is simplified and the fuel cell stack 90 is manufactured. It is possible to obtain the advantage of saving time and effort. In addition, since the heat transfer medium 92 is disposed outside the stacked end face of the fuel cell stack 90, the heat transfer medium 92 does not need to be restricted by a conductive material, and a non-conductive material is used. If there is, the insulating sheet 91 can be deleted.

  The present invention can be applied to a fuel cell system that realizes effective use of stack heat generation in a medium temperature fuel cell stack having a stack operating temperature of 100 ° C. or higher.

1 is a schematic diagram illustrating a configuration of a fuel cell stack according to a first embodiment of the present invention. FIG. 3 is a schematic plan view showing configurations of a fuel cell stack and a second evaporation generator according to the first embodiment of the present invention. 1 is a structural diagram showing a heat transfer medium according to a first embodiment of the present invention. It is a block diagram which shows the outline of a structure of the stationary fuel cell power generation system which concerns on embodiment of this invention. It is a flowchart which shows starting operation performed with the stationary fuel cell power generation system which concerns on embodiment of this invention. It is a flowchart which shows starting operation performed with the stationary fuel cell power generation system which concerns on embodiment of this invention. It is a basic diagram which shows the structure of the fuel cell stack which concerns on the 2nd Embodiment of this invention. It is a block diagram which shows the structure of the conventional fuel cell main body, and a stationary fuel cell power generation system structure. It is a rough-line top view which shows the structure of the fuel cell stack concerning the 2nd Embodiment of this invention, and a 2nd evaporation generator. It is a basic diagram which shows the structure of the conventional fuel cell stack. It is a block diagram which shows the conventional stationary fuel cell power generation system structure.

Explanation of symbols

  DESCRIPTION OF SYMBOLS 1, 50, 90 ... Fuel cell stack, 2, 52 ... Solid polymer electrolyte membrane, 3, 53 ... Fuel electrode, 4, 54 ... Oxidant electrode, 6, 56 ... Fuel gas separator, 8 58 ... Oxidant gas separator, 9, 59 ... Fuel cell, 11 ... Cooling plate, 20, 70 ... Fuel cell system, 22 ... Pure water tank, 23 ... Hot water tank, 24 ... Reformer, 25 ... shift reactor, 31 ... (first) steam generator, 36 ... combustion section, 51 ... second steam generator, 60, 92 ... heat transfer medium, 61, 91 ... Insulating sheet, 72, 77 ... Shut-off valve, 73 ... Bypass valve, 74 ... Bypass line.

Claims (5)

A cell composed of an electrolyte and a pair of electrodes composed of an anode and a cathode sandwiching the electrolyte, and a fuel gas containing hydrogen to the anode of the electrode is supplied / discharged, and an oxidant gas containing oxygen is supplied / discharged to the cathode A fuel cell stack in which a plurality of pairs of separators having gas flow paths are alternately stacked, a fuel reforming processing system for generating fuel gas to be supplied from a raw material gas to the fuel cell main body, and the fuel reforming processing system In a fuel cell power generation system having a pure water system for supplying exhaust water to a first steam generator for supplying steam necessary for causing a reforming reaction and at the same time effectively using exhaust heat,
A heat transfer medium engaged with all or a part of the plurality of cells stacked in the fuel cell stack with thermal conductivity;
Disposed adjacent to the fuel cell stack so as to connect the heat transfer medium and the heat conduction, and a second steam generator for generating steam based on the heat supplied through the heat transfer medium,
The first steam generator and the second steam generator are connected in series via a first shut-off valve, and the second steam generator is connected via a steam control valve. A fuel cell power generation system comprising: a line connected to an inlet of the fuel reforming treatment system; and a line returning to the pure water system via a second shut-off valve . The system during startup, the first shut-off valve in the open state, by supplying the steam generated in said first steam generator to said second steam generator, the second steam generator The heat of the steam staying inside is given to the fuel cell stack through the heat transfer medium to raise the temperature,
Further, after completion of the temperature rise of the fuel cell stack, when the system load is turned on, the steam control valve is opened, and the steam generated by the first steam generator is passed through the second steam generator, By supplying the fuel reforming system, the system shifts to system load operation.
Further, after the load operation is set, the first shut-off valve disposed between the first steam generator and the second steam generator is closed, and the second shut-off valve is opened. Then, the fuel cell power generation system according to claim 1, wherein the second steam generator is switched to a single operation. 3. The heat transfer medium according to claim 1, wherein the plurality of cells stacked in the fuel cell stack are inserted for each predetermined number of stacked sheets or alternately with each of the cells. 4. Fuel cell power generation system. The said heat transfer medium is a meandering capillary type heat pipe structure in which meandering tubules are arranged or formed in a plate, and a working fluid as a heat transport medium is enclosed in said tubules. Fuel cell power generation system. 3. The fuel according to claim 1, wherein the heat transfer medium is disposed in contact with at least one of the stacked end faces of the plurality of cells with an electrically insulating inclusion disposed. Battery power generation system.

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