JP4994337B2 - Method for producing acidic liquid seasoning - Google Patents

Method for producing acidic liquid seasoning Download PDF

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JP4994337B2
JP4994337B2 JP2008262891A JP2008262891A JP4994337B2 JP 4994337 B2 JP4994337 B2 JP 4994337B2 JP 2008262891 A JP2008262891 A JP 2008262891A JP 2008262891 A JP2008262891 A JP 2008262891A JP 4994337 B2 JP4994337 B2 JP 4994337B2
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soy sauce
acidic liquid
liquid seasoning
raw
fish
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JP2010088371A (en
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綾 小笠原
力 玉置
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Kewpie Jyozo KK
QP Corp
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QP Corp
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Description

本発明は、醤油のまろやかな風味に優れた酸性液状調味料の製造方法に関する。 The present invention relates to a method for producing an acidic liquid seasoning excellent in the mild flavor of soy sauce.

醤油は、日本を代表する発酵調味料の一種である。醤油は刺身や寿司などの液状調味料としてそのまま利用されることが多いが、醤油は独特の旨味を有することから、ドレッシングなどの酸性液状調味料にも利用されている。しかしながら、醤油をベースとした酸性液状調味料を製した場合、醤油を原材料の一部として用いていること、また食酢、柑橘類などの酸材でpHを低くしているためか、醤油のまろやかな風味に欠けるという問題があった。 Soy sauce is a type of fermented seasoning that represents Japan. Soy sauce is often used as a liquid seasoning such as sashimi and sushi, but since soy sauce has a unique taste, it is also used in acidic liquid seasonings such as dressings. However, when making an acidic liquid seasoning based on soy sauce, the soy sauce is mellow because the soy sauce is used as a part of the raw materials, and because the pH is lowered with acid materials such as vinegar and citrus. There was a problem of lack of flavor.

醤油の良好な風味を増強させた液体調味料として、特開平7−313097号公報(特許文献1)には、醤油及びだしを含有する調味料に含硫化合物を添加し加熱する製造方法が開示されている。また、同文献は、だし原料としてかつお節など魚節から水抽出したもの、あるいは醤油中で抽出したものを用いている。しかしながら、スーパーなどで市販されている醤油とかつお節から水抽出しただしを用いて上記液状調味料を製し、当該液状調味料に更に食酢を添加して酸性液状調味料を製したところ、満足できる程の醤油のまろやかな風味を有するとは言い難いものであった。 As a liquid seasoning that enhances the good flavor of soy sauce, JP-A-7-313097 (Patent Document 1) discloses a production method in which a sulfur-containing compound is added to a seasoning containing soy sauce and dashi and heated. Has been. In addition, this document uses, as a raw material, a material extracted from a fish clause such as bonito and water or a material extracted in soy sauce. However, it is satisfactory when the above-mentioned liquid seasoning is produced using water extracted from soy sauce and bonito, which is commercially available at supermarkets, and vinegar is further added to the liquid seasoning to produce an acidic liquid seasoning. It was hard to say that it had a mild flavor of soy sauce.

特開平7−313097号公報JP-A-7-313097 特開2007−159550号公報JP 2007-159550 A

そこで、本発明の目的は、醤油のまろやかな風味に優れた酸性液状調味料の製造方法を提供するものである。 Then, the objective of this invention provides the manufacturing method of the acidic liquid seasoning excellent in the mellow flavor of soy sauce.

本発明者は、上記目的を達成すべく酸性液状調味料に使用されている様々な配合原料について鋭意研究を重ねた。その結果、特定の醤油と特定の方法より抽出した魚節抽出液とを混合した混合液を加熱して製したところ、意外にも醤油のまろやかな風味に優れた酸性液状調味料が得られることを見出し、本発明を完成するに至った。 In order to achieve the above-mentioned object, the present inventor has intensively studied various compounding raw materials used in acidic liquid seasonings. As a result, when a mixed liquid obtained by mixing a specific soy sauce and a fish knot extract extracted by a specific method is heated, an acidic liquid seasoning that is surprisingly excellent in the mild flavor of soy sauce is obtained. As a result, the present invention has been completed.

すなわち、本発明は、
(1)生(なま)醤油を%以上60%以下配合した酸性液状調味料であって、75℃以上95℃の0.7%酢酸水溶液で抽出した魚節抽出液と生(なま)醤油とを混合後、該混合液を65℃以上85℃以下で加熱処理し、前記混合液中の魚節抽出液と生(なま)醤油の質量比が2:8〜9:1である酸性液状調味料の製造方法、
(2)前記混合液を1回のみ60℃以上で加熱処理する(1)の酸性液状調味料の製造方法、
である。
That is, the present invention
(1) An acidic liquid seasoning containing 8 % or more and 60% or less of raw soy sauce, which is extracted with a fish knot extract and raw ( 75 to 95 ° C, 0.7 to 4 % aqueous acetic acid) After mixing with soy sauce, the mixture is heat-treated at 65 ° C. or more and 85 ° C. or less , and the mass ratio of fish knot extract to raw soy sauce in the mixture is 2: 8-9: 1, a method for producing an acidic liquid seasoning,
(2) The method for producing an acidic liquid seasoning according to (1), wherein the mixed solution is heated only once at 60 ° C. or higher,
It is.

なお、特開2007−159550号公報(特許文献2)には、酢酸水溶液で抽出した魚節抽出液が開示されており、当該魚節抽出液をドレッシングに用いても良い旨が記載されている。しかしながら、特許文献2記載の魚節抽出液は50℃以下で抽出しており、当該明細書の試験例では酢酸濃度が30%未満では魚節の香りが弱いことが記載されている。また、特許文献2には、魚節抽出液と生(なま)醤油の混合液を加熱処理した酸性液状調味料については何ら開示されていない。 Japanese Patent Application Laid-Open No. 2007-159550 (Patent Document 2) discloses a fish extract extracted with an aqueous acetic acid solution and describes that the fish extract may be used for dressing. . However, the fish knot extract described in Patent Document 2 is extracted at 50 ° C. or less, and the test example of the specification describes that the aroma of fish knot is weak when the acetic acid concentration is less than 30%. Further, Patent Document 2 does not disclose any acidic liquid seasoning obtained by heat-treating a mixed solution of a fish knot extract and raw soy sauce.

本発明の製造方法によれば、醤油のまろやかな風味に優れた酸性液状調味料が得られることから、醤油をベースとした酸性液状調味料更なる需要の拡大が期待される。 According to the production method of the present invention, an acidic liquid seasoning excellent in the mellow flavor of soy sauce can be obtained, so that further expansion of demand for the acidic liquid seasoning based on soy sauce is expected.

以下本発明を詳細に説明する。なお、本発明において「%」は「質量%」、「部」は「質量部」をそれぞれ意味する。 The present invention will be described in detail below. In the present invention, “%” means “mass%” and “part” means “part by mass”.

本発明の酸性液状調味料とは、常温流通を可能ならしめるためにpHを4.6以下に調整された液状の調味料であり、本発明においては、サラサラしたタイプばかりでなく、ペースト状のものも含まれる。このような酸性液状調味料としては、例えば、分離液状ドレッシング、乳化液状ドレッシング、ノンオイルドレッシング、マヨネーズ、マヨネーズ様調味料、サラダドレッシング、たれ、ポン酢などが挙げられる。また、上記pHは、分離液状ドレッシングの場合、下層の水相あるいは乳化相、乳化液状ドレッシングなどの乳化タイプの場合、当該乳化相を測定したときの値である。 The acidic liquid seasoning of the present invention is a liquid seasoning whose pH is adjusted to 4.6 or lower in order to enable normal temperature distribution. In the present invention, not only a smooth type but also a paste-like seasoning is used. Also included. Examples of such acidic liquid seasonings include separation liquid dressings, emulsified liquid dressings, non-oil dressings, mayonnaise, mayonnaise-like seasonings, salad dressings, sauce, and ponzu. Further, the pH is a value obtained by measuring the emulsified phase in the case of a separate liquid dressing, in the case of an emulsified type such as an aqueous phase or emulsified phase in the lower layer or an emulsified liquid dressing.

本発明の酸性液状調味料は、醤油をベースとした、具体的には、醤油を5%以上、好ましくは8%以上含有したものにおいて、醤油の一部あるいは全部を生(なま)醤油に置き換えたものであり、生(なま)醤油を製品に対し5%以上、好ましくは8%以上配合したものである。醤油の配合量が前記値より少ないと、醤油風味を有した酸性液状調味料が得られ難い。また、たとえ醤油の配合量が前記値を満たしたとしても、生(なま)醤油の配合量が前記値より少ないと、醤油のまろやかな風味に優れた酸性液状調味料が得られ難く好ましくない。生(なま)醤油も含め醤油の上限の配合量は、特に規定していないが、酸性液状調味料に用いられている上限量を配合すればよい。具体的には、好ましくは80%以下、より好ましく60%以下である。 The acidic liquid seasoning of the present invention is based on soy sauce, specifically containing 5% or more, preferably 8% or more of soy sauce, and part or all of the soy sauce is made into raw soy sauce. This is a replacement of raw soy sauce with 5% or more, preferably 8% or more of the product. When the amount of soy sauce is less than the above value, it is difficult to obtain an acidic liquid seasoning having a soy sauce flavor. Moreover, even if the blending amount of soy sauce satisfies the above value, if the blending amount of raw soy sauce is less than the above value, it is difficult to obtain an acidic liquid seasoning excellent in the mild flavor of soy sauce. . The upper limit amount of soy sauce including raw soy sauce is not particularly defined, but the upper limit amount used in acidic liquid seasonings may be added. Specifically, it is preferably 80% or less, more preferably 60% or less.

一般的に市販されている醤油は、例えば、通常の濃口醤油、薄口醤油、溜り醤油などの製造工程において、製造原料の発酵、熟成を行った熟成諸味を圧搾濾過して得られた生揚げ醤油を火入れ工程である加熱殺菌を施したものである。一方、本発明で用いる生(なま)醤油は、火入れ工程である加熱殺菌を施していない醤油のことであり、前記生揚げ醤油を、菌数管理を目的にマイクロフィルター、精密濾過膜などを用いて微生物を取り除いたものを用いることが工業的規模の生産に適し好ましい。 The soy sauce that is generally marketed is, for example, freshly-fried soy sauce obtained by pressing and filtering the ripening moromi that has been fermented and aged in the production process of ordinary concentrated soy sauce, thin soy sauce, and soy sauce. It is subjected to heat sterilization, which is a heating process. On the other hand, the raw soy sauce used in the present invention is a soy sauce that has not been subjected to heat sterilization, which is a heating process, and the raw fried soy sauce is used with a microfilter, a microfiltration membrane or the like for the purpose of controlling the number of bacteria. It is preferable to use a product from which microorganisms have been removed for industrial scale production.

本発明の調味料の製造方法は、前記生(なま)醤油に加え特定の方法で製した魚節抽出液を用いる。つまり、本発明は、70℃以上100℃未満、好ましくは75〜95℃に加熱した酢酸濃度0.5〜5%、好ましくは0.7〜4%の酢酸水溶液で抽出した魚節抽出液を用いる必要がある。魚節抽出液の抽出溶媒として用いる酢酸水溶液の液温が前記範囲より低い場合、あるいは酢酸濃度が前記範囲より低い場合は、得られた魚節抽出液と生(なま)醤油との混合液を加熱処理して酸性液状調味料を製造したとしても、得られる調味料は醤油のまろやかな風味に優れたものとならず好ましくない。一方、酢酸水溶液の液温が前記範囲より高い場合、あるいは酢酸濃度が前記範囲より高い場合は、得られた魚節抽出液がえぐ味を有し、得られる酸性液状調味料は醤油のまろやかな風味に優れたものとならず好ましくない。 The seasoning production method of the present invention uses a fish knot extract prepared by a specific method in addition to the raw soy sauce. That is, the present invention provides a fish knot extract extracted with an acetic acid aqueous solution heated to 70 ° C. or more and less than 100 ° C., preferably 75 to 95 ° C., with an acetic acid concentration of 0.5 to 5%, preferably 0.7 to 4%. It is necessary to use it. When the liquid temperature of the acetic acid aqueous solution used as the extraction solvent for the fish knot extract is lower than the above range, or when the acetic acid concentration is lower than the above range, the mixed solution of the obtained fish knot extract and raw soy sauce Even if it heat-processes and it manufactures an acidic liquid seasoning, the seasoning obtained does not become the thing excellent in the mellow flavor of soy sauce, and is unpreferable. On the other hand, when the liquid temperature of the acetic acid aqueous solution is higher than the above range, or when the acetic acid concentration is higher than the above range, the obtained fish knot extract has a pungent taste, and the resulting acidic liquid seasoning is a mild soy sauce It is not preferable because the flavor is not excellent.

魚節抽出液の調製方法について詳述する。まず製造で用いる魚節および酢酸水溶液を準備する。魚節とは、魚体を茹で干した「なまり節」、それを燻製した「荒節」、さらに黴付けした「枯節」のことである。特に、「荒節」は、燻煙に由来する重たい香りを有するためか、本発明の製造方法により醤油のまろやかな風味に優れた酸性液状調味料が得られ易く好ましい。本発明で用いる魚節は市販されているものであればいずれのものでも良く、例えば、鰹節、宗田鰹節、鯖節、鰯節、鰺節、鮪節などが挙げられる。また、家庭では魚節からだしを調理する場合、通常、魚節を削ったものを用いる。本発明も魚節を削ったものを用いても良いが、工業的規模での生産性および抽出効率を考慮すると0.1〜5mm程度に粉砕した魚節を用いたほうが好ましい。 A method for preparing the fish knot extract will be described in detail. First, prepare fish clauses and an aqueous acetic acid solution for use in production. Fish buns are “namari buns” that are dried with a cocoon, “arab buns” that are smoked, and “dead buns” that are brazed. In particular, “coarse bonito” is preferred because it has a heavy fragrance derived from soot smoke, and it is easy to obtain an acidic liquid seasoning excellent in the mild flavor of soy sauce by the production method of the present invention. The fish bun used in the present invention may be any commercially available one, and examples include bonito, soda bonito, bonito, bonito, bonito, and bonito. In addition, when cooking fish buns from home, the fish buns are usually used. In the present invention, a fish knot may be used, but it is preferable to use a fish knot pulverized to about 0.1 to 5 mm in consideration of productivity and extraction efficiency on an industrial scale.

酢酸水溶液は、酢酸を含有した原材料に清水などの水を加え0.5〜5%の酢酸濃度に調製する。酢酸を含有した原材料としては、例えば、食酢、氷酢酸などが挙げられるが、コストや入手し易さを考慮し、食酢を用いたほうが好ましい。酢酸水溶液には、本発明の効果を損なわない範囲で他の原材料、例えば、ショ糖、ブドウ糖果糖液糖、デキストリン、あるいはこれらの還元物などの糖類、エタノール、酒精などのアルコール類、食塩、醤油などの各種調味料などを加えても良いが、酢酸を含有した原材料に清水などの水を単に加えた酢酸水溶液を用いたほうが醤油のまろやかな風味に優れた酸性液状調味料が得られ易く好ましい。 The aqueous acetic acid solution is prepared by adding water such as fresh water to the raw material containing acetic acid to a concentration of 0.5 to 5% acetic acid. Examples of the raw material containing acetic acid include vinegar, glacial acetic acid, and the like, but it is preferable to use vinegar in consideration of cost and availability. In the aqueous acetic acid solution, other raw materials are used as long as the effects of the present invention are not impaired, for example, sugars such as sucrose, glucose fructose liquid sugar, dextrin or reduced products thereof, alcohols such as ethanol and alcohol, salt, soy sauce The use of an acetic acid aqueous solution in which water such as fresh water is simply added to the raw material containing acetic acid is preferable because an acidic liquid seasoning excellent in the mild flavor of soy sauce can be easily obtained. .

準備した魚節および所定濃度の酢酸水溶液を用いて、70℃以上100℃未満の0.5〜5%酢酸水溶液で抽出した魚節抽出液を調製する。具体的には、例えば、上記所定温度に加熱した酢酸水溶液100部に魚節を好ましくは1〜30部、より好ましくは2〜20部を投入し、攪拌させながら好ましくは5分〜2時間、より好ましくは10分〜1.5時間抽出工程を行う。次いで、ストレーナーなどの濾過器などを用いて抽出後の魚節を除いた後、冷却して魚節抽出液を調製する。魚節の投入量が前記範囲より少ない場合、あるいは抽出時間が前記範囲より短い場合は、得られた魚節抽出液と生(なま)醤油との混合液を加熱処理して酸性液状調味料を製造したとしても、得られる調味料は醤油のまろやかな風味に優れたものとならず好ましくない。一方、魚節の投入量が前記範囲より多い場合、あるいは抽出時間が前記範囲より長い場合は、投入量あるいは抽出時間に応じた本発明の効果が期待するほど得られず経済的でない。なお、本発明は、抽出過程で上記所定温度に加熱した酢酸水溶液で魚節より抽出すれば良く、例えば、70℃未満の酢酸水溶液に魚節を投入して抽出を開始し、その後加熱して上記所定温度の範囲で抽出することも本発明に含まれる。 Using the prepared fish knot and an aqueous acetic acid solution having a predetermined concentration, a fish knot extract extracted with a 0.5 to 5% acetic acid solution at 70 ° C. or more and less than 100 ° C. is prepared. Specifically, for example, 1 to 30 parts, more preferably 2 to 20 parts of fishfish is added to 100 parts of the acetic acid aqueous solution heated to the predetermined temperature, and preferably 5 minutes to 2 hours while stirring. More preferably, the extraction step is performed for 10 minutes to 1.5 hours. Next, after the extracted fish clauses are removed using a strainer or the like filter, the fish slice extract is prepared by cooling. When the input amount of fish bun is less than the above range, or when the extraction time is shorter than the above range, the liquid mixture of the obtained fish bun extract and raw soy sauce is heat-treated to produce an acidic liquid seasoning Even if it is manufactured, the obtained seasoning is not preferable because it does not have a mellow flavor of soy sauce. On the other hand, when the input amount of fish bun is larger than the above range, or when the extraction time is longer than the above range, the effect of the present invention according to the input amount or the extraction time cannot be obtained as much as expected, which is not economical. In the present invention, the extraction may be performed from the fish knot with the acetic acid aqueous solution heated to the predetermined temperature in the extraction process. For example, the fish knot is poured into an acetic acid aqueous solution of less than 70 ° C., and the extraction is started. Extraction within the range of the predetermined temperature is also included in the present invention.

本発明の酸性液状調味料の製造方法は、上記生(なま)醤油を5%以上配合した酸性液状調味料であって、上記魚節抽出液と生(なま)醤油を混合後、当該混合液を60℃以上で加熱処理することを特徴とする。これにより、醤油のまろやかな風味に優れた酸性液状調味料が得られる。これに対し、例えば、前記60℃での加熱処理を行わない場合や、本発明で用いる生(なま)醤油に換えて生(なま)醤油を60℃以上で先に加熱処理した醤油、つまり、火入れ工程を施した通常の醤油を用いて本発明と同様の製造方法を行った場合は、醤油のまろやかな風味に優れた酸性液状調味料が得られず好ましくない。 The method for producing an acidic liquid seasoning according to the present invention is an acidic liquid seasoning containing 5% or more of the above raw soy sauce, and after mixing the fish salmon extract and raw soy sauce, The mixed solution is heat-treated at 60 ° C. or higher. Thereby, the acidic liquid seasoning excellent in the mellow flavor of soy sauce is obtained. On the other hand, for example, when the heat treatment at 60 ° C. is not performed, or soy sauce in which raw soy sauce is first heat-treated at 60 ° C. or higher instead of raw soy sauce used in the present invention, That is, when the same manufacturing method as this invention is performed using the normal soy sauce which performed the burning process, the acidic liquid seasoning excellent in the mild flavor of soy sauce cannot be obtained, and it is unpreferable.

ここで、魚節抽出液と生(なま)醤油を混合後、当該混合液を60℃以上で加熱処理するとは、本発明の製造方法において、魚節抽出液と生(なま)醤油との混合工程、および当該混合液を60℃以上で加熱処理する工程を有することを意味する。具体的には、例えば、魚節抽出液と生(なま)醤油のみを混合した後、当該混合液を60℃以上で加熱処理し、これを本発明の調味料の一原料として用いる方法、また、魚節抽出液と生(なま)醤油、さらに本発明の効果を損なわない範囲で他の原料を混合し、当該混合液を60℃以上で加熱処理したもの本発明の一原料として用いたり、前記加熱処理したものをそのまま本発明の調味料として用いる方法などが挙げられる。 Here, after mixing the fish knot extract and raw soy sauce, the mixed solution is heat-treated at 60 ° C. or higher. In the production method of the present invention, the fish knot extract and raw soy sauce are used. And a step of heat-treating the mixed solution at 60 ° C. or higher. Specifically, for example, after mixing only fish syrup extract and raw soy sauce, the mixture is heated at 60 ° C. or higher, and this is used as a raw material for the seasoning of the present invention, In addition, fish stock extract and raw soy sauce, and other raw materials are mixed within a range that does not impair the effects of the present invention, and the mixed liquid is heat-treated at 60 ° C. or higher and used as one raw material of the present invention. Or a method of using the heat-treated product as it is as the seasoning of the present invention.

また、魚節抽出液と生(なま)醤油の混合割合は、醤油のまろやかな風味に優れた酸性液状調味料が得られる程度の割合で混合すれば良く、具体的には、混合液中の魚節抽出液と生(なま)醤油の質量比が好ましくは1:9〜9:1、より好ましくは2:8〜9:1である。混合液の加熱処理は60℃以上で行う必要があり、好ましくは65℃以上である。加熱処理が前記液温より低い場合は、醤油のまろやかな風味に優れた酸性液状調味料が得られるず好ましくない。加熱処理時間は、混合液が前記所定の温度に達しさえすれば良いが、工業的規模を考慮し好ましくは5秒〜60分、より好ましくは5秒〜30分であり、例えば、プレートヒーター、ニーダーなど食品製造で用いられる加熱装置であればいずれのものでも良い。本発明は上限の加熱温度は特に規定していないが、酸性液状調味料の外観に影響する場合があるので、好ましくは90℃以下、より好ましくは85℃以下である。混合液の60℃以上での加熱処理の回数は、特に制限するものではないが、1回のみ行うことが醤油のまろやかな風味がより優れた酸性液状調味料が得られ好ましい。 Moreover, the mixing ratio of the fish paste extract and raw soy sauce may be mixed at such a ratio that an acidic liquid seasoning excellent in the mild flavor of soy sauce is obtained. The mass ratio of the fish syrup extract and raw soy sauce is preferably 1: 9 to 9: 1, more preferably 2: 8 to 9: 1. The heat treatment of the mixed solution needs to be performed at 60 ° C. or higher, preferably 65 ° C. or higher. When the heat treatment is lower than the liquid temperature, an acidic liquid seasoning excellent in the mild flavor of soy sauce cannot be obtained, which is not preferable. The heat treatment time is sufficient as long as the mixed solution reaches the predetermined temperature, but it is preferably 5 seconds to 60 minutes, more preferably 5 seconds to 30 minutes in consideration of an industrial scale. For example, a plate heater, Any heating device used in food production such as a kneader may be used. In the present invention, the upper limit heating temperature is not particularly defined, but it may affect the appearance of the acidic liquid seasoning, and is preferably 90 ° C. or lower, more preferably 85 ° C. or lower. The number of heat treatments of the mixed solution at 60 ° C. or higher is not particularly limited, but it is preferable to perform the heat treatment only once because an acidic liquid seasoning with a more mellow flavor of soy sauce is obtained.

本発明の酸性液状調味料には、上述した生(なま)醤油および魚節抽出液を配合する他、本発明の効果を損なわない範囲で酸性液状調味料に通常用いられている各種原料を適宜選択し配合させることができる。例えば、菜種油、コーン油、綿実油、サフラワー油、オリーブ油、紅花油、大豆油、パーム油、ゴマ油、魚油、卵黄油等の動植物油及びこれらの精製油、並びにMCT(中鎖脂肪酸トリグリセリド)、ジグリセリドなどのように化学的あるいは酵素的処理を施して得られる油脂などの食用油脂、食酢、クエン酸、乳酸などの酸材、グルタミン酸ナトリウム、食塩、砂糖、みりん、醤油、味噌などの各種調味料、馬鈴薯澱粉、コーンスターチ、タピオカ澱粉、小麦澱粉、米澱粉、これらの澱粉をアルファ化、架橋などの処理を施した加工澱粉、並びに湿熱処理澱粉などの澱粉類、キサンタンガム、タマリンド種子ガム、ローカストビーンガム、ジェランガム、グアーガム、サイリュウムシードガムなどのガム質、動植物のエキス類、からし粉、胡椒などの香辛料、並びに各種蛋白質やこれらの分解物、大根おろし、ゴマペースト、ジンジャーペーストなどの野菜類の粉砕物などが挙げられる。 The acidic liquid seasoning of the present invention is blended with the raw soy sauce and fish knot extract described above, and various raw materials usually used for acidic liquid seasonings within a range not impairing the effects of the present invention. It can be appropriately selected and blended. For example, rapeseed oil, corn oil, cottonseed oil, safflower oil, olive oil, safflower oil, soybean oil, palm oil, sesame oil, fish oil, egg yolk oil and other animal and vegetable oils and refined oils thereof, and MCT (medium chain fatty acid triglyceride), diglyceride Edible fats and oils such as fats and oils obtained by chemical or enzymatic treatment such as, acid materials such as vinegar, citric acid and lactic acid, various seasonings such as sodium glutamate, salt, sugar, mirin, soy sauce, miso, Potato starch, corn starch, tapioca starch, wheat starch, rice starch, processed starch obtained by subjecting these starches to alpha, cross-linking, and starches such as wet heat-treated starch, xanthan gum, tamarind seed gum, locust bean gum, Gums such as gellan gum, guar gum, and syrup seed gum, animal and plant extracts, mustard flour, Spices such as pepper, as well as various proteins and their degradation products, radish, sesame paste, pulverized vegetables such as ginger paste, and the like.

以下、本発明の酸性液状調味料の製造方法について、実施例、比較例並びに試験例に基づき具体的に説明する。なお、本発明は、これらに限定するものではない。 Hereinafter, the manufacturing method of the acidic liquid seasoning of this invention is demonstrated concretely based on an Example, a comparative example, and a test example. The present invention is not limited to these.

[実施例1]
<魚節抽出液の調製>
4%酢酸濃度の食酢に清水を加え1%酢酸水溶液を調製した。次いで1%酢酸水溶液100部を液温85℃に加熱し、荒節である鰹節粉砕物(0.1〜5mm)10部を投入し、同温でゆっくり攪拌させながら30分間抽出した。次いで抽出後の鰹節粉砕物をストレーナーで除去し後、常温(約25℃)まで冷却し魚節抽出液を調製した。
[Example 1]
<Preparation of fishfish extract>
Fresh water was added to 4% acetic acid vinegar to prepare a 1% aqueous acetic acid solution. Next, 100 parts of a 1% aqueous acetic acid solution was heated to a liquid temperature of 85 ° C., 10 parts of coarse koji mash (0.1-5 mm) was added, and the mixture was extracted for 30 minutes while stirring slowly at the same temperature. Next, the crushed bonito pulverized product was removed with a strainer, and then cooled to room temperature (about 25 ° C.) to prepare a fish shoot extract.

<酸性液状調味料の調製>
下記の配合割合に準じ、まず生(なま)醤油と魚節抽出液を混合後、当該混合液をニーダーで75℃×5分間加熱処理し、常温(約25℃)まで冷却した。次いで、冷却した前記混合液に残りの原材料を添加し攪拌して酸性液状調味料を調製した。得られた酸性液状調味料は、醤油のまろやかな風味に大変優れていた。
<Preparation of acidic liquid seasoning>
In accordance with the following blending ratio, first, raw soy sauce and fish knot extract were mixed, and then the mixture was heat-treated with a kneader at 75 ° C. for 5 minutes and cooled to room temperature (about 25 ° C.). Next, the remaining raw materials were added to the cooled mixture and stirred to prepare an acidic liquid seasoning. The obtained acidic liquid seasoning was very excellent in the mellow flavor of soy sauce.

<配合割合>
生(なま)醤油 20%
魚節抽出液 20%
食酢(酢酸5%) 20%
醤油(生(なま)醤油でない) 5%
砂糖 5%
食塩 1%
グルタミン酸ソーダ 0.5%
キサンタンガム 0.1%
清水 残余
――――――――――――――――――――
合計 100%
<Combination ratio>
Raw soy sauce 20%
Fish Bun Extract 20%
Vinegar (acetic acid 5%) 20%
Soy sauce (not raw soy sauce) 5%
5% sugar
Salt 1%
Sodium glutamate 0.5%
Xanthan gum 0.1%
Shimizu Residue ――――――――――――――――――――
Total 100%

[実施例2]
実施例1と同一の原材料、同一の配合割合で以下の方法により酸性液状調味料の調製した。つまり、全原料を混合後、当該混合液をニーダーで75℃×5分間加熱処理し、常温(約25℃)まで冷却して酸性液状調味料の調製した。得られた酸性液状調味料は、醤油のまろやかな風味に大変優れていた。
[Example 2]
An acidic liquid seasoning was prepared by the following method using the same raw materials and the same blending ratio as in Example 1. That is, after mixing all the raw materials, the liquid mixture was heat-treated with a kneader at 75 ° C. for 5 minutes, and cooled to room temperature (about 25 ° C.) to prepare an acidic liquid seasoning. The obtained acidic liquid seasoning was very excellent in the mellow flavor of soy sauce.

[比較例1]
実施例1において、生(なま)醤油を原料の一つとして用いた醤油(生(なま)醤油でない)に置き換えた以外は、実施例1と同様の方法で酸性液状調味料の調製した。得られた酸性液状調味料は、醤油のまろやかな風味に欠けていた。
[Comparative Example 1]
In Example 1, an acidic liquid seasoning was prepared in the same manner as in Example 1 except that raw soy sauce was replaced with soy sauce (not raw soy sauce) used as one of the raw materials. . The obtained acidic liquid seasoning lacked the mild flavor of soy sauce.

[比較例2]
実施例1において、生(なま)醤油と魚節抽出液の混合液を加熱処理(75℃×5分間)を行わなかった以外は、実施例1と同様の方法で酸性液状調味料の調製した。得られた酸性液状調味料は、醤油のまろやかな風味に欠けていた。
[Comparative Example 2]
Preparation of an acidic liquid seasoning in the same manner as in Example 1, except that the mixture of raw soy sauce and fish knot extract was not heat-treated (75 ° C. × 5 minutes) in Example 1. did. The obtained acidic liquid seasoning lacked the mild flavor of soy sauce.

[比較例3]
実施例1において、魚節抽出液の調製の際に用いた1%酢酸水溶液を清水に換えた以外は、実施例1と同様の方法で酸性液状調味料の調製した。得られた酸性液状調味料は、醤油のまろやかな風味にやや欠けていた。
[Comparative Example 3]
In Example 1, an acidic liquid seasoning was prepared in the same manner as in Example 1 except that the 1% acetic acid aqueous solution used in the preparation of the fish knot extract was replaced with fresh water. The obtained acidic liquid seasoning was somewhat lacking in the mild flavor of soy sauce.

[比較例4]
実施例1において、生(なま)醤油と魚節抽出液を混合せずに、生(なま)醤油のみをニーダーで75℃×5分間加熱処理した以外は実施例1と同様の方法で酸性液状調味料の調製した。得られた酸性液状調味料は、醤油のまろやかな風味に欠けていた。
[Comparative Example 4]
In Example 1, the raw soy sauce and fish knot extract were not mixed, but only raw soy sauce was heat-treated with a kneader at 75 ° C. for 5 minutes in the same manner as in Example 1. An acidic liquid seasoning was prepared. The obtained acidic liquid seasoning lacked the mild flavor of soy sauce.

本発明の実施品である実施例1および2で得られた酸性液状調味料は、醤油のまろやかな風味に大変優れていたが、生(なま)醤油を用いなかった比較例1、加熱処理を施さなかった比較例2、酢酸水溶液で抽出しなかった魚節抽出液を用いた比較例3、生(なま)醤油を魚節抽出液の存在下で加熱処理しなかった比較例4で得られた酸性液状調味料は、醤油のまろやかな風味に欠けることが理解される。 The acidic liquid seasonings obtained in Examples 1 and 2 which are the products of the present invention were very excellent in the mild flavor of soy sauce, but Comparative Example 1 in which raw soy sauce was not used, heat treatment In Comparative Example 2 in which no soy sauce was applied, in Comparative Example 3 in which the fish knot extract was not extracted with an aqueous acetic acid solution, and in Comparative Example 4 in which the raw soy sauce was not heat-treated in the presence of the fish knot extract. It is understood that the obtained acidic liquid seasoning lacks the mild flavor of soy sauce.

[試験例1]
生(なま)醤油の配合量の違いによる醤油のまろやかな風味への影響を調べた。つまり実施例1において、生(なま)醤油とそうでない醤油の合計配合量は変えずに、生(なま)醤油を下表の配合量とし残りを生(なま)醤油でないものを用いて、実施例1と同様の方法で酸性液状調味料を調製した。得られた各酸性液状調味料を試食して醤油のまろやかな風味について評価した。
[Test Example 1]
The effect of soy sauce on the mellow flavor of raw soy sauce was examined. That is, in Example 1, the total amount of raw soy sauce and other soy sauce is not changed, and raw soy sauce is used as shown in the table below, and the rest is not raw soy sauce. In the same manner as in Example 1, an acidic liquid seasoning was prepared. Each acidic liquid seasoning obtained was sampled and evaluated for the mild flavor of soy sauce.

Figure 0004994337
Figure 0004994337

<評価基準>
◎:醤油のまろやかな風味に大変優れている。
○:醤油のまろやかな風味に優れている。
△:醤油のまろやかな風味にやや欠ける。
×:醤油のまろやかな風味に欠ける。
<Evaluation criteria>
A: Excellent in the mild flavor of soy sauce.
○: Excellent mellow flavor of soy sauce.
Δ: Slightly lacking in the mild flavor of soy sauce.
X: The mellow flavor of soy sauce is lacking.

生(なま)醤油を5%以上配合しないと醤油のまろやかな風味に優れた酸性液状調味料が得られないことが理解される。特に、8%以上配合したものは大変優れていた。 It is understood that an acidic liquid seasoning excellent in the mild flavor of soy sauce cannot be obtained unless 5% or more of raw soy sauce is blended. In particular, those containing 8% or more were very excellent.

[試験例2]
魚節抽出液の抽出温度の違いによる醤油のまろやかな風味への影響を調べた。つまり実施例1において、魚節抽出液の調製の際、下記の液温に加熱した酢酸水溶液を用いてた以外は実施例1と同様の方法で酸性液状調味料を調製した。得られた各酸性液状調味料を試食して醤油のまろやかな風味について評価した。なお、評価基準は、試験例1と同じである。また、液温110℃のものは、酢酸水溶液と鰹節粉砕物を耐熱性パウチに充填密封し、110℃×30分間レトルト処理を行って抽出した。
[Test Example 2]
The effect of soy sauce on the mellow flavor of the fish knot extract was investigated. That is, in Example 1, an acidic liquid seasoning was prepared in the same manner as in Example 1 except that an acetic acid aqueous solution heated to the following liquid temperature was used when preparing the fish knot extract. Each acidic liquid seasoning obtained was sampled and evaluated for the mild flavor of soy sauce. The evaluation criteria are the same as in Test Example 1. In the case of a liquid temperature of 110 ° C., an acetic acid aqueous solution and crushed bonito were filled in a heat-resistant pouch and sealed, and subjected to retorting at 110 ° C. for 30 minutes.

Figure 0004994337
Figure 0004994337

70℃以上100℃未満の酢酸水溶液で抽出した魚節抽出液を用いた酸性液状調味料は、醤油のまろやかな風味に優れたものが得られることが理解される。特に、75〜95℃の酢酸水溶液で抽出した魚節抽出液を用いた酸性液状調味料は大変優れていた。なお、110℃で抽出した魚節抽出液を用いたものは、ややえぐ味を有していた。 It is understood that an acidic liquid seasoning using a fish knot extract extracted with an acetic acid aqueous solution of 70 ° C. or higher and lower than 100 ° C. can be obtained with an excellent mellow flavor of soy sauce. In particular, an acidic liquid seasoning using a fish knot extract extracted with an aqueous acetic acid solution at 75 to 95 ° C. was very excellent. In addition, the thing using the fish knot extract extracted at 110 degreeC had a slight taste.

[試験例3]
魚節抽出液の抽出溶媒である酢酸水溶液の酢酸濃度の違いによる醤油のまろやかな風味への影響を調べた。つまり実施例1において、魚節抽出液の調製の際、下記の酢酸濃度の酢酸水溶液を用いてた以外は実施例1と同様の方法で酸性液状調味料を調製した。得られた各酸性液状調味料を試食して醤油のまろやかな風味について評価した。なお、評価基準は、試験例1と同じである。
[Test Example 3]
The effect on the mellow flavor of soy sauce by the difference in acetic acid concentration of acetic acid aqueous solution as an extraction solvent for fish knot extract was investigated. That is, in Example 1, an acidic liquid seasoning was prepared in the same manner as in Example 1 except that an acetic acid aqueous solution having the following acetic acid concentration was used when the fish knot extract was prepared. Each acidic liquid seasoning obtained was sampled and evaluated for the mild flavor of soy sauce. The evaluation criteria are the same as in Test Example 1.

Figure 0004994337
Figure 0004994337

酢酸濃度0.5〜5%の酢酸水溶液で抽出した魚節抽出液を用いた酸性液状調味料は、醤油のまろやかな風味に優れたものが得られることが理解される。特に、酢酸濃度0.7〜4%の酢酸水溶液で抽出した魚節抽出液を用いた酸性液状調味料は大変優れていた。なお、酢酸濃度8%の酢酸水溶液で抽出した魚節抽出液を用いたものは、ややえぐ味を有していた。 It is understood that an acidic liquid seasoning using a fish knot extract extracted with an acetic acid aqueous solution having an acetic acid concentration of 0.5 to 5% can be obtained with an excellent mellow flavor of soy sauce. In particular, an acidic liquid seasoning using a fish knot extract extracted with an acetic acid aqueous solution having an acetic acid concentration of 0.7 to 4% was very excellent. In addition, the thing using the fish knot extract extracted with the acetic acid aqueous solution with an acetic acid concentration of 8% had a slight taste.

[試験例4]
生(なま)醤油と魚節抽出液の混合液の加熱処理温度の違いによる醤油のまろやかな風味への影響を調べた。つまり実施例1において、混合液の加熱処理温度を下記の温度で行った以外は実施例1と同様の方法で酸性液状調味料を調製した。得られた各酸性液状調味料を試食して醤油のまろやかな風味について評価した。なお、評価基準は、試験例1と同じである。
[Test Example 4]
The influence on the mild flavor of soy sauce by the difference in the heat treatment temperature of the mixture of raw soy sauce and fish knot extract was investigated. That is, in Example 1, the acidic liquid seasoning was prepared by the same method as Example 1 except having performed the heat processing temperature of the liquid mixture at the following temperature. Each acidic liquid seasoning obtained was sampled and evaluated for the mild flavor of soy sauce. The evaluation criteria are the same as in Test Example 1.

Figure 0004994337
Figure 0004994337

生(なま)醤油と魚節抽出液の混合液を60℃以上で加熱して製した酸性液状調味料は、醤油のまろやかな風味に優れていることが理解される。特に、65〜85℃の範囲で加熱して製した酸性液状調味料は大変優れていた。 It is understood that an acidic liquid seasoning produced by heating a mixture of raw soy sauce and fish knot extract at 60 ° C. or higher is excellent in the mild flavor of soy sauce. In particular, the acidic liquid seasoning produced by heating in the range of 65 to 85 ° C. was very excellent.

[試験例5]
魚節抽出液と生(なま)醤油の混合比の違いによる醤油のまろやかな風味への影響を調べた。つまり実施例1において、生(なま)醤油の配合量を8%に変え下記の混合比となるように魚節抽出液の配合量を変えた以外は実施例1と同様の方法で酸性液状調味料を調製した。得られた各酸性液状調味料を試食して醤油のまろやかな風味について評価した。なお、評価基準は、試験例1と同じである。
[Test Example 5]
The effect on the mellow flavor of soy sauce due to the difference in the mixing ratio between fish salmon extract and raw soy sauce was investigated. That is, in Example 1, the amount of raw soy sauce was changed to 8%, and the amount of fish knot extract was changed to the following mixing ratio. A seasoning was prepared. Each acidic liquid seasoning obtained was sampled and evaluated for the mild flavor of soy sauce. The evaluation criteria are the same as in Test Example 1.

Figure 0004994337
Figure 0004994337

魚節抽出液と生(なま)醤油の混合比が1:9〜9:1の範囲の酸性液状調味料は、醤油のまろやかな風味に優れていることが理解される。特に、混合比が2:8〜9:1の範囲の酸性液状調味料は大変優れていた。 It is understood that the acidic liquid seasoning in which the mixing ratio of the fish paste extract and raw soy sauce is in the range of 1: 9 to 9: 1 is excellent in the mild flavor of soy sauce. In particular, the acidic liquid seasoning having a mixing ratio in the range of 2: 8 to 9: 1 was very excellent.

[実施例3]
実施例1で得られた酸性液状調味料を、再度ニーダーで75℃×5分間加熱処理し、常温(約25℃)まで冷却して酸性液状調味料を調製した。得られた酸性液状調味料を実施例1で得られたものと比較したところ、実施例1で得られた酸性液状調味料は醤油のまろやかな風味に大変優れていたが、実施例3で得られたものはやや劣るものの醤油のまろやかな風味に優れていた。
[Example 3]
The acidic liquid seasoning obtained in Example 1 was again heat-treated with a kneader at 75 ° C. for 5 minutes, and cooled to room temperature (about 25 ° C.) to prepare an acidic liquid seasoning. When the obtained acidic liquid seasoning was compared with that obtained in Example 1, the acidic liquid seasoning obtained in Example 1 was very excellent in the mild flavor of soy sauce, but obtained in Example 3. The food was slightly inferior, but it was excellent in the mild flavor of soy sauce.

[実施例4]
実施例1で得られた酸性液状調味料を250mL容量のガラス瓶に220mL充填し、次いで植物油を30mL充填し分離液状ドレッシングを調製した。得られた分離液状ドレッシングを上下に振って1次乳化させて試食したところ、醤油のまろやかな風味に大変優れていた。
[Example 4]
The acidic liquid seasoning obtained in Example 1 was filled in a glass bottle having a capacity of 250 mL, and then filled with 30 mL of vegetable oil to prepare a separate liquid dressing. When the obtained separated liquid dressing was shaken up and down to be primary emulsified and sampled, it was very excellent in the mild flavor of soy sauce.

[実施例5]
下記の配合割合に準じ、まず生(なま)醤油と魚節抽出液を混合後、当該混合液をニーダーで75℃×5分間加熱処理し、常温(約25℃)まで冷却した。次いで、冷却した前記混合液に植物油以外の残りの原材料を添加し攪拌して全体を均一にした後、植物油を徐々に注加して乳化液状ドレッシングを調製した。得られた乳化液状ドレッシングは、醤油のまろやかな風味に大変優れていた。なお、原料として用いた魚節抽出液は、実施例1で調製したものを用いた。
[Example 5]
In accordance with the following blending ratio, first, raw soy sauce and fish knot extract were mixed, and then the mixture was heat-treated with a kneader at 75 ° C. for 5 minutes and cooled to room temperature (about 25 ° C.). Next, the remaining raw materials other than the vegetable oil were added to the cooled mixed liquid and stirred to make the whole uniform, and then the vegetable oil was gradually added to prepare an emulsified liquid dressing. The obtained emulsified liquid dressing was very excellent in the mild flavor of soy sauce. The fish knot extract used as a raw material was the one prepared in Example 1.

<配合割合>
植物油 30%
生(なま)醤油 10%
魚節抽出液 10%
食酢(酢酸5%) 20%
醤油(生(なま)醤油でない) 5%
砂糖 5%
生卵黄 2%
食塩 1%
グルタミン酸ソーダ 0.5%
キサンタンガム 0.1%
清水 残余
――――――――――――――――――――
合計 100%
<Combination ratio>
30% vegetable oil
10% raw soy sauce
Fish Bun Extract 10%
Vinegar (acetic acid 5%) 20%
Soy sauce (not raw soy sauce) 5%
5% sugar
Raw egg yolk 2%
Salt 1%
Sodium glutamate 0.5%
Xanthan gum 0.1%
Shimizu Residue ――――――――――――――――――――
Total 100%

Claims (2)

生(なま)醤油を%以上60%以下配合した酸性液状調味料であって、75℃以上95℃の0.7%酢酸水溶液で抽出した魚節抽出液と生(なま)醤油とを混合後、該混合液を65℃以上85℃以下で加熱処理し、前記混合液中の魚節抽出液と生(なま)醤油の質量比が2:8〜9:1であることを特徴とする酸性液状調味料の製造方法。 Raw (raw) an acidic liquid seasoning blended 8 percent to 60 percent of the soy sauce, 75 ° C. or higher 95 ° C. of 0.7 to 4 percent extracted smoked fish extract with aqueous acetic acid and raw (raw) After mixing with soy sauce, the mixed solution is heat-treated at 65 ° C. or more and 85 ° C. or less , and the mass ratio of fish knot extract to raw soy sauce in the mixed solution is 2: 8 to 9: 1. The manufacturing method of the acidic liquid seasoning characterized by the above-mentioned. 前記混合液を1回のみ60℃以上で加熱処理する請求項1記載の酸性液状調味料の製造方法。 The process according to claim 1 Symbol placement acidic liquid seasoning to heating the mixture at only 60 ° C. or more times.
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