JP2016158507A - Spicy feeling improver - Google Patents

Spicy feeling improver Download PDF

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JP2016158507A
JP2016158507A JP2015037080A JP2015037080A JP2016158507A JP 2016158507 A JP2016158507 A JP 2016158507A JP 2015037080 A JP2015037080 A JP 2015037080A JP 2015037080 A JP2015037080 A JP 2015037080A JP 2016158507 A JP2016158507 A JP 2016158507A
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spice
food
feeling
amino acid
sugar
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JP6587813B2 (en
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政宏 高谷
Masahiro Takaya
政宏 高谷
加代子 清水
Kayoko Shimizu
加代子 清水
忠与次 勝又
Tadayoshi Katsumata
忠与次 勝又
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MC Food Specialties Inc
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Abstract

PROBLEM TO BE SOLVED: To provide a spicy feeling improver, a seasoning excellent in spicy feeling, a method for improving spicy feeling in food and drink, and a production method of food and drink having improved spicy feeling.SOLUTION: A spicy feeling improver contains a product obtained by generating a heating reaction between a sugar and an amino acid in the presence of alcohol under an alkali condition. A production method of food and drink includes a step for adding the spicy feeling improver into food and drink. A seasoning contains the spicy feeling improver and a spice.SELECTED DRAWING: None

Description

本発明は、香辛料感向上剤、香辛料感の優れた調味料、飲食品の香辛料感を向上させる方法、および香辛料感の向上した飲食品の製造方法に関する。   The present invention relates to a spice feeling improver, a seasoning excellent in spice feeling, a method for improving the spice feeling of food and drink, and a method for producing a food and drink with improved spice feeling.

従来、飲食品における香辛料の香りや味、風味の強さを向上させる、すなわち「香辛料感」を強くかつ好ましいものとするためには、香辛料自体もしくはその抽出物、または香料や風味料が一般的に用いられている。これまで、このような香辛料感を向上させる方法として、スクラロースによってハーブ成分であるカルボン又はメントールの香気性を向上させる方法(特許文献1)、スクラロースによって生姜風味を向上させる方法(特許文献2)、アセスルファムカリウムなどのいくつかの高甘味度甘味料の組み合わせによってスパイス感を向上させる方法(特許文献3)、イソ酪酸およびイソ吉草酸を含有する酵母由来物によって香辛料香気を増強する方法(特許文献4)、糖アルコールによって辛みやスパイシー感を増強する方法(特許文献5)、紅茶抽出物によってスパイス感を増強する方法(特許文献6)等が報告されている。   Conventionally, in order to improve the strength and flavor of spices in foods and beverages, that is, to make the “spicy feeling” strong and preferable, spices themselves or their extracts, or flavors and flavors are generally used. It is used for. Until now, as a method of improving such a spice feeling, a method of improving the aroma of carban or menthol which is an herb component by sucralose (Patent Document 1), a method of improving ginger flavor by sucralose (Patent Document 2), A method of improving the feeling of spice by combining several high-intensity sweeteners such as acesulfame potassium (Patent Document 3), and a method of enhancing spice flavor by a yeast-derived product containing isobutyric acid and isovaleric acid (Patent Document 4) ), A method of enhancing the spiciness and spicy feeling with sugar alcohol (Patent Document 5), a method of enhancing the spice feeling with black tea extract (Patent Document 6), and the like have been reported.

また、アルコール(例えば、エタノール)によって香辛料等の辛味が向上することが一般的に知られているが、この効果は熱に弱く、熱履歴の大きくなる工業スケールではアルコールによる辛味の増強効果や全体的な香辛料感の向上効果を得ることは難しい。   In addition, it is generally known that spices such as spices are improved by alcohol (for example, ethanol), but this effect is weak to heat, and in industrial scale where the heat history becomes large, the effect of enhancing the pungent taste by alcohol and the whole It is difficult to obtain an effect of improving the feeling of spice.

特開2010−42021号公報JP 2010-42021 A 特開2000−135066号公報JP 2000-135066 A 特開2013−158302号公報JP 2013-158302 A 特開2010−166886号公報JP 2010-166886 A 特開2008−35799号公報JP 2008-35799 A 特開2006−34146号公報JP 2006-34146 A

本発明の目的は、香辛料感向上剤、香辛料感の優れた調味料、飲食品の香辛料感を向上させる方法、および香辛料感の向上した飲食品の製造方法を提供することにある。   The objective of this invention is providing the seasoning excellent in the spice feeling, the method of improving the spice feeling of food / beverage products, and the manufacturing method of the food / beverage products which improved the spice feeling.

本発明は、以下の(1)〜(5)に関する。
(1)アルコール存在下で糖とアミノ酸とを加熱反応させて得られる生成物を含有する香辛料感向上剤。
(2)前記加熱反応が、アルカリ条件下で行われる、(1)に記載の香辛料感向上剤。
(3)前記(1)または(2)の香辛料感向上剤を、香辛料を含有する飲食品に添加することを特徴とする、飲食品の香辛料感向上方法。
(4)前記(1)または(2)の香辛料感向上剤を飲食品に添加する工程を含む、飲食品の製造方法。
(5)前記(1)または(2)の香辛料感向上剤および香辛料を含有することを特徴とする調味料。
The present invention relates to the following (1) to (5).
(1) A spice feeling improver containing a product obtained by heating and reacting sugar and amino acid in the presence of alcohol.
(2) The spice feeling improver according to (1), wherein the heating reaction is performed under alkaline conditions.
(3) A method for improving the feeling of spices in foods or drinks, comprising adding the spice feeling improver of (1) or (2) to foods or drinks containing spices.
(4) The manufacturing method of food / beverage products including the process of adding the spice feeling improvement agent of said (1) or (2) to food / beverage products.
(5) A seasoning comprising the spice sensation improving agent and the spice of (1) or (2).

本発明によれば、飲食品の香辛料感を向上させることができる香辛料感向上剤、香辛料感の優れた調味料、飲食品の香辛料感を向上させる方法、および香辛料感の向上した飲食品の製造方法を提供することができる。   ADVANTAGE OF THE INVENTION According to this invention, the spice feeling improving agent which can improve the spice feeling of food / beverage products, the seasoning which was excellent in the spice feeling, the method of improving the spice feeling of food / beverage products, and manufacture of the food / beverage products with improved spice feeling A method can be provided.

本発明の香辛料感向上剤は、アルコール存在下で糖とアミノ酸とを加熱反応させて得られる生成物を含有する。   The spice improvement agent of the present invention contains a product obtained by heating and reacting sugar and amino acid in the presence of alcohol.

本明細書において「香辛料感」とは、香辛料やその抽出物または香辛料の香りを再現した香料から感じられる香辛料の香りや味、風味の強さを意味する。   In the present specification, the “spicy sensation” means the scent, taste and flavor of spices that can be felt from spices and their extracts or spices that reproduce the scent of spices.

本発明において用いるアルコールは、飲食品に使用できるアルコールであれば特に限定はされないが、例えば、エタノール、ブタノール、プロパノール、イソプロパノール、ペンタノール、2−ペンタノールなどの1価アルコール、プロピレングリコール等の2価アルコール、グリセロール等の3価アルコール、または、糖アルコール等があげられるが、エタノールが好ましい。また、醸造アルコール、ワイン、ビール、日本酒、焼酎、みりん、ウィスキー、ブランデー等の上記アルコールの含有物を用いてもよい。   The alcohol used in the present invention is not particularly limited as long as it is an alcohol that can be used for food and drink. For example, monohydric alcohols such as ethanol, butanol, propanol, isopropanol, pentanol, and 2-pentanol, and 2 such as propylene glycol. Examples thereof include trihydric alcohols such as monohydric alcohols and glycerol, sugar alcohols and the like, and ethanol is preferred. Moreover, you may use the said alcohol content, such as brewing alcohol, wine, beer, sake, shochu, mirin, whiskey, brandy.

糖としては、例えば、グルコース、フルクトース、キシロース等の単糖類、スクロース、ラクトース、マルトース等の二糖類、ラフィノース、マルトトリオースの三糖類、フラクトオリゴ糖、ガラクトオリゴ糖等のオリゴ糖類、デンプン、デキストリン、セルロース、イヌリン等の多糖類があげられる。これらの糖はそのまま用いてもよいし、二糖類以上の糖は分解して用いてもよい。また、糖として、これらの糖を含有する飲食品を用いることができ、当該飲食品はそのまま用いてもよく、または加工して用いてもよい。上記の糖、または糖を含有する飲食品は単独で用いてもよく、2種以上を組み合わせて用いてもよい。   Examples of the sugar include monosaccharides such as glucose, fructose and xylose, disaccharides such as sucrose, lactose and maltose, trisaccharides such as raffinose and maltotriose, oligosaccharides such as fructooligosaccharide and galactooligosaccharide, starch, dextrin and cellulose And polysaccharides such as inulin. These sugars may be used as they are, or sugars of disaccharides or higher may be decomposed and used. Moreover, the food / beverage products containing these sugars can be used as sugar, The said food / beverage products may be used as it is, or may be processed and used. Said saccharide | sugar or food-drinks containing saccharide | sugar may be used independently, and may be used in combination of 2 or more type.

アミノ酸としては、アラニン、アルギニン、アスパラギン、アスパラギン酸、システイン、シスチン、グルタミン、グルタミン酸、グリシン、ヒスチジン、ロイシン、イソロイシン、リジン、メチオニン、フェニルアラニン、プロリン、ヒドロキシプロシン、セリン、トレオニン、トリプトファン、チロシン、バリン、オルニチン、シトルリン等があげられるが、アラニン、グルタミン酸、アスパラギン酸、アルギニン、ロイシンが好ましい。また、アミノ酸は、これらの酸付加塩、金属塩、アンモニウム塩等の塩であってもよい。アミノ酸は、単独で用いてもよいし、2種以上を組み合わせて用いてもよい。   Amino acids include alanine, arginine, asparagine, aspartic acid, cysteine, cystine, glutamine, glutamic acid, glycine, histidine, leucine, isoleucine, lysine, methionine, phenylalanine, proline, hydroxyprocin, serine, threonine, tryptophan, tyrosine, valine, Examples include ornithine and citrulline, and alanine, glutamic acid, aspartic acid, arginine and leucine are preferred. The amino acid may be a salt such as an acid addition salt, a metal salt, or an ammonium salt. An amino acid may be used independently and may be used in combination of 2 or more type.

また、アミノ酸としては、その含有物を用いてもよい。アミノ酸の含有物としては、ペプチドやタンパク質、酵母エキス、動植物エキス、食肉、魚介類、トウモロコシ、大豆、米、小麦、動植物蛋白加水分解物等があげられる。アミノ酸の含有物を用いる場合、そのまま用いてもよいが、加水分解等により遊離のアミノ酸を増加させて用いることが好ましい。   Moreover, as an amino acid, you may use the content. Examples of the amino acid content include peptides, proteins, yeast extracts, animal and plant extracts, meat, fish and shellfish, corn, soybeans, rice, wheat, and animal and plant protein hydrolysates. When the amino acid content is used, it may be used as it is, but it is preferable to increase the free amino acid by hydrolysis or the like.

アルコール存在下で糖とアミノ酸との加熱反応を行う際には、糖とアミノ酸とがアルコール中で共存している状況であればよい。たとえば、糖またはその含有物およびアミノ酸またはその含有物を含有する飲食品にアルコールを加えてもよく、逆に糖またはその含有物およびアミノ酸またはその含有物を含有する飲食品をアルコールに加えてもよい。また、当初よりアルコール、糖またはその含有物、およびアミノ酸またはその含有物を含有する飲食品に、必要に応じてアルコール、糖またはその含有物、およびアミノ酸またはその含有物を加えてもよい。当初より糖、アミノ酸、およびアルコールを含有する飲食品としては、例えば、清酒醪、酒粕、みりん醪、みりん粕、醸造調味料、醸造調味料粕等があげられる。   When the sugar and amino acid are heated in the presence of alcohol, the sugar and amino acid may coexist in the alcohol. For example, alcohol may be added to a food or drink containing a sugar or a content thereof and an amino acid or a content thereof, and conversely, a food or drink containing a sugar or a content thereof and an amino acid or a content thereof may be added to the alcohol. Good. Moreover, you may add alcohol, sugar or its content, and an amino acid or its content to the food / beverage products containing alcohol, sugar or its content, and an amino acid or its content from the beginning as needed. Examples of foods and drinks containing sugar, amino acid, and alcohol from the beginning include sake lees, sake lees, mirin lees, mirin lees, brew seasonings, and brew seasonings.

糖とアミノ酸とを加熱反応させる際のアルコールの存在量は、アルコール、糖およびアミノ酸を共存させてなる組成物(以下、反応に供する組成物という)の通常0.5〜100重量%であり、好ましくは3〜60重量%、より好ましくは5〜50重量%である。糖およびアミノ酸の反応に供する組成物における含有量は特に限定されないが、反応効率を考慮すると、糖は0.01重量%以上、好ましくは0.1重量%以上、より好ましくは1重量%以上、さらに好ましくは2重量%以上であり、アミノ酸は0.001重量%以上、好ましくは0.01重量%以上、より好ましくは0.1重量%以上、さらに好ましくは1重量%以上である。糖およびアミノ酸の含有量に特に上限はないが、反応効率上、反応に供する組成物中に溶解可能な量であることが好ましい。糖とアミノ酸との存在比に特に限定はないが、通常は1:10〜10:1である。   The amount of alcohol present when sugar and amino acid are reacted by heating is usually 0.5 to 100% by weight of a composition in which alcohol, sugar and amino acid coexist (hereinafter referred to as a composition used for the reaction), Preferably it is 3 to 60 weight%, More preferably, it is 5 to 50 weight%. The content in the composition used for the reaction of sugar and amino acid is not particularly limited, but considering the reaction efficiency, sugar is 0.01 wt% or more, preferably 0.1 wt% or more, more preferably 1 wt% or more, More preferably, it is 2% by weight or more, and the amino acid is 0.001% by weight or more, preferably 0.01% by weight or more, more preferably 0.1% by weight or more, and further preferably 1% by weight or more. There is no particular upper limit on the content of sugar and amino acid, but it is preferably an amount that can be dissolved in the composition to be subjected to the reaction in view of reaction efficiency. The abundance ratio of sugar to amino acid is not particularly limited, but is usually 1:10 to 10: 1.

アルコール存在下で糖とアミノ酸とを加熱反応させる際のpHは特に限定はされないが、pH5.0〜9.0、好ましくはpH7.0〜9.0である。pHを調整する必要がある場合は、水酸化ナトリウム、水酸化カリウム、水酸化カルシウム等の飲食品に許容されるアルカリ、または塩酸、酢酸、乳酸、クエン酸、リン酸等の飲食品に許容される酸を添加することによって調整することができる。   The pH when the sugar and amino acid are heated and reacted in the presence of alcohol is not particularly limited, but is pH 5.0 to 9.0, preferably pH 7.0 to 9.0. When pH needs to be adjusted, it is acceptable for foods and drinks such as sodium hydroxide, potassium hydroxide and calcium hydroxide, or food and drinks such as hydrochloric acid, acetic acid, lactic acid, citric acid and phosphoric acid. It can be adjusted by adding an acid.

また、加熱反応させる温度は60〜140℃、好ましくは75〜120℃であり、加熱反応させる時間は30〜180分間、好ましくは30〜90分間である。   The temperature for the heat reaction is 60 to 140 ° C., preferably 75 to 120 ° C., and the time for the heat reaction is 30 to 180 minutes, preferably 30 to 90 minutes.

また、加熱反応は、本発明の効果の妨げとならない限り、香辛料、ビタミン類、無機塩類、有機酸、乳化剤、増粘剤、香料、油脂類、酸化防止剤、保存料、および機能性素材等の他の食品添加物とともに行ってもよい。   In addition, as long as the heating reaction does not interfere with the effect of the present invention, spices, vitamins, inorganic salts, organic acids, emulsifiers, thickeners, fragrances, fats and oils, antioxidants, preservatives, functional materials, etc. You may carry out with other food additives.

上記加熱反応により得られる生成物(以下、本明細書において単に「生成物」と記載する場合がある)は、そのまま本発明の香辛料感向上剤として用いることができるが、必要に応じて濃縮処理、熱風乾燥、蒸気乾燥、凍結乾燥、噴霧乾燥等の乾燥処理、分離精製処理、脱色処理等に供して、濃縮物や乾燥物等にしたものを本発明の香辛料感向上剤として用いてもよい。   The product obtained by the above heating reaction (hereinafter sometimes simply referred to as “product” in the present specification) can be used as it is as a spice feeling improver of the present invention, but if necessary, a concentration treatment. A condensate or dry product that has been subjected to drying treatment such as hot air drying, steam drying, freeze drying, spray drying, etc., separation and purification treatment, decolorization treatment, etc., may be used as the spice feeling improver of the present invention. .

本発明の香辛料感向上剤の形態は、固形状または液状のいずれであってもよい。固形状としては、たとえば、粉末状、顆粒状、ブロック状、カプセル状等があげられる。液状の場合は、溶媒は、水、アルコール(例えば、エタノール)等の有機溶媒、酢酸や液糖等の液状物質のいずれであってもよい。   The form of the spice feeling improver of the present invention may be either solid or liquid. Examples of the solid form include powder form, granule form, block form, and capsule form. In the case of liquid, the solvent may be water, an organic solvent such as alcohol (for example, ethanol), or a liquid substance such as acetic acid or liquid sugar.

本発明の香辛料感向上剤は、香辛料感向上の妨げとならない限り、前記の他の食品添加物を含有してもよい。他の食品添加物として香辛料を含有する本発明の香辛料感向上剤は、強く、かつ好ましい香辛料感を有する調味料として好適に用いることができる。   The spice sensation improving agent of the present invention may contain the other food additives as long as the spice sensation improvement is not hindered. The spice feeling improver of the present invention containing a spice as another food additive can be suitably used as a seasoning having a strong and preferable spice feeling.

本発明の調味料に香辛料感向上剤とともに含有させる香辛料は、植物の果実、果皮、花、蕾、樹皮、茎、葉、種子、根、地下茎等、植物体の一部であって、特有の香り、辛味、色調を有し、飲食物に香り付け、消臭、調味、着色等の目的で用いるものであればよい。例えば、ニンニク、ショウガ、ごま、唐辛子、ホースラディシュ、マスタード(芥子)、ケシノミ、ゆず、胡椒、ナツメグ、シナモン、パプリカ、カルダモン、クミン、サフラン、オールスパイス、クローブ、山椒、オレンジピール、ウイキョウ、カンゾウ、フェネグリーク、ディルシード、カショウ、ロングペパー、クレソン、コリアンダーリーフ(香菜)、紫蘇、セロリー、タラゴン、チャイブ、チャービル、ニラ、パセリ、マスタードグリーン(芥子菜)、ミョウガ、ヨモギ、バジル、オレガノ、ローズマリー、ペパーミント、サボリー、レモングラス、ワサビ葉、山椒の葉等があげられる。   The spices to be included in the seasoning of the present invention together with the spice sensation improver are plant fruits, fruit peels, flowers, persimmons, bark, stems, leaves, seeds, roots, rhizomes, etc. What is necessary is just to have a fragrance, a pungent taste, and a color tone, and to use for purposes, such as fragrance, deodorizing, seasoning, coloring, etc. to food and drink. For example, garlic, ginger, sesame, chili, horseradish, mustard, eggplant, yuzu, pepper, nutmeg, cinnamon, paprika, cardamom, cumin, saffron, allspice, cloves, yam, orange peel, fennel, licorice, Fenegree Creek, Dill Seed, Pepper, Long Pepper, Watercress, Coriander Leaf (Kasai), Shiso, Celery, Tarragon, Chives, Chervil, Leek, Parsley, Mustard Green (Chinese Vegetables), Ginger, Mugwort, Basil, Oregano, Rosemary, Peppermint, savory, lemongrass, wasabi leaves, and yam leaves.

本発明の香辛料感向上剤を、香辛料を含有する飲食品に添加することにより、飲食品の香辛料感を向上させることができるほか、その飲食品の有する風味を所望の風味に改善、改質、または向上させたり、所望のレベルに風味を増強したりする効果も期待できる。本発明の香辛料感向上剤の香辛料を含有する飲食品への添加は、飲食品を製造する際に原材料の一部として添加してもよく、飲食品を喫食する際に添加してもよい。   By adding the spice feeling improver of the present invention to a food or drink containing a spice, the spice feeling of the food or drink can be improved, and the flavor of the food or drink is improved to a desired flavor, modified, Alternatively, an effect of improving or enhancing the flavor to a desired level can be expected. Addition of the spice feeling improver of the present invention to a food or drink containing the spice may be added as a part of the raw material when producing the food or drink, or may be added when eating the food or drink.

香辛料を含有する飲食品に本発明の香辛料感向上剤を添加する方法は、飲食品の香辛料感を向上する方法として好適に用いられる。   The method of adding the spice feeling improver of the present invention to a food or drink containing a spice is suitably used as a method for improving the spice feeling of the food or drink.

本発明の香辛料感向上剤の香辛料を含有する飲食品への添加量は特に限定されず、香辛料の種類や量、飲食品の種類や性質に応じて適宜設定すればよいが、例えば、飲食品100重量部中、本発明の香辛料感向上剤を乾燥重量として好ましくは0.001〜10重量部、より好ましくは0.05〜5重量部添加する。   The amount of the spice feeling improver of the present invention added to the food or drink containing the spice is not particularly limited, and may be appropriately set according to the kind and amount of the spice and the kind and nature of the food and drink. In 100 parts by weight, the spice feeling improver of the present invention is preferably added in a dry weight of 0.001 to 10 parts by weight, more preferably 0.05 to 5 parts by weight.

本発明の飲食品の製造方法は、本発明の香辛料感向上剤を飲食品に添加する以外は、当該飲食品の通常の製造方法で行えばよい。本発明の香辛料感向上剤を添加する飲食品は、上記香辛料を含有する飲食品があげられるが、香辛料を含まない飲食品の場合は、別途香辛料を添加してもよい。本発明の飲食品の製造方法により得られる飲食品は、香辛料感が強く、かつ風味の好ましい飲食品である。   What is necessary is just to perform the manufacturing method of the food / beverage products of this invention by the normal manufacturing method of the said food / beverage products except adding the spice feeling improvement agent of this invention to food / beverage products. The food / beverage products which add the spice feeling improvement agent of this invention can mention the food / beverage products containing the said spice, However, In the case of the food / beverage products which do not contain a spice, you may add a spice separately. The food / beverage products obtained by the method for producing a food / beverage product of the present invention is a food / beverage product having a strong spice and a preferred flavor.

本発明の飲食品の香辛料感改良方法および飲食品の製造方法は、飲食品に、本発明の香辛料感向上剤を添加する以外にも、飲食品に、糖、アミノ酸および必要に応じてアルコールを逐次添加した後、本発明の香辛料感向上剤の製造における条件に準じて加熱反応させる方法であってもよい。   The method for improving the spice feeling of foods and drinks according to the present invention and the method for producing foods and drinks include, in addition to adding the spice feeling improver of the present invention to foods and drinks, sugars, amino acids and alcohol as needed. After adding sequentially, the method of making it heat-react according to the conditions in manufacture of the spice feeling improvement agent of this invention may be sufficient.

以下に、本発明の内容について実施例を用いて説明する。ただし、本発明の技術範囲はこれらの実施例に限定されるものではない。   Hereinafter, the contents of the present invention will be described using examples. However, the technical scope of the present invention is not limited to these examples.

(実施例1)
下記表1に示す組成に準じて水溶液を調製し、それぞれ反応液1〜3とした。なお、蛋白加水分解物としては、市販のビール酵母の酸加水分解物(MCフードスペシャリティーズ社製。1g中、総アミノ酸を275mg含有する。そのうち約91%が遊離アミノ酸である。)を用いた。
Example 1
Aqueous solutions were prepared according to the compositions shown in Table 1 below, and designated as reaction solutions 1 to 3, respectively. As the protein hydrolyzate, a commercially available acid hydrolyzate of brewer's yeast (manufactured by MC Food Specialties, Inc. containing 275 mg of total amino acids in 1 g, of which about 91% are free amino acids) was used. .

Figure 2016158507
Figure 2016158507

調製した反応液1〜3のpHを、それぞれ水酸化ナトリウムにてpH8に調整し、110℃で60分間加熱反応させて生成物1〜3を得た。当該生成物1〜3を、市販のカレールウ(エスビー食品社製)を用いて調製したカレースープに、それぞれ1重量%となるように添加した。各添加区(試験区1〜3)の香辛料感について、熟練した7名のパネラーにより官能評価を行った。   The pH of the prepared reaction liquids 1 to 3 was adjusted to pH 8 with sodium hydroxide, respectively, and reacted by heating at 110 ° C. for 60 minutes to obtain products 1 to 3. The said products 1-3 were added to the curry soup prepared using commercially available curry roux (made by SBI Foods) so that it might become 1 weight%, respectively. The sensory evaluation was performed by seven skilled panelists about the spice feeling of each addition group (test groups 1-3).

官能評価は、加熱反応生成物を添加しないカレースープをコントロール(無添加区)とし、添加区のコントロール(無添加区)に対する香辛料感を以下に示す3点尺度法にて評価することで行った。
0点:向上していない(コントロールと同程度)
1点:やや向上している
2点:向上している
3点:非常に向上している
Sensory evaluation was performed by evaluating curry soup with no added heat reaction product as a control (no addition group) and evaluating the spice feeling with respect to the control of the addition group (no addition group) by the following three-point scale method. .
0 points: not improved (same as control)
1 point: Somewhat improved 2 points: Improved 3 points: Very improved

各パネラーの評点の平均を表2に示す。   The average score of each panel is shown in Table 2.

Figure 2016158507
Figure 2016158507

表2に示すとおり、エタノール存在下でグルコースと蛋白加水分解物とを加熱反応させて得られた生成物1および2を添加して得られたカレースープ(試験区1および2)は、無添加区のカレースープに対して有意に香辛料感の向上が認められた。一方、グルコースおよび蛋白加水分解物の使用量の少ない加熱反応物を用いたカレースープ(試験区3)では香辛料感の向上がほとんど認められなかったことから、この効果はアルコール存在下で糖と蛋白質加水分解物中の成分とが加熱反応することにより生じたと言える。   As shown in Table 2, curry soup (test sections 1 and 2) obtained by adding products 1 and 2 obtained by heating and reacting glucose and protein hydrolyzate in the presence of ethanol was not added. A significant improvement in the spice feeling was recognized for the curry soup in the ward. On the other hand, curry soup using a heated reaction product with a small amount of glucose and protein hydrolyzate (test group 3) showed almost no improvement in the feeling of spice, so this effect was achieved with sugar and protein in the presence of alcohol. It can be said that it was caused by a heat reaction between the components in the hydrolyzate.

(実施例2)
実施例1記載の方法に準じてエタノール存在下でグルコースと蛋白加水分解物とを加熱反応させて得られた生成物中の遊離アミノ酸の分析を行ったところ、加熱反応の前後で遊離アミノ酸の含有量に変化が認められた。遊離アミノ酸の中で減少量の大きかったアミノ酸について、減少量の大きかった順に下記表3に示す。また、減少量の少なかったアミノ酸について、減少量の少ない順に下記表4に示す。
(Example 2)
According to the method described in Example 1, analysis of free amino acids in a product obtained by heating and reacting glucose and a protein hydrolyzate in the presence of ethanol revealed that free amino acids were contained before and after the heating reaction. A change in quantity was noted. Among the free amino acids, amino acids having a large decrease amount are shown in the following Table 3 in the order of the large decrease amount. Moreover, it shows in following Table 4 in order with a little reduction amount about the amino acid with little reduction amount.

Figure 2016158507
Figure 2016158507

Figure 2016158507
Figure 2016158507

表3および4記載のアミノ酸を用いて、該表記載の配合量のアミノ酸混合物1および2を調製した。エタノール、D−グルコース、アミノ酸混合物1および2、ならびに水を用いて、下記表5に示す記載の組成に準じて水溶液を調製し、それぞれ反応液4〜7とした。   Using the amino acids described in Tables 3 and 4, amino acid mixtures 1 and 2 having the compounding amounts described in the table were prepared. Using ethanol, D-glucose, amino acid mixtures 1 and 2, and water, aqueous solutions were prepared according to the compositions shown in Table 5 below, and designated as reaction solutions 4 to 7, respectively.

Figure 2016158507
Figure 2016158507

調製した反応液4〜7のpHをそれぞれ水酸化ナトリウムにてpH8に調整し、110℃で60分間加熱反応させて生成物4〜7を得た。当該生成物4〜7を、実施例1で調製したカレースープにそれぞれ1重量%となるように添加した。各添加区(試験区4〜7)の香辛料感について、実施例1記載の方法に準じて官能評価を、熟練した7名のパネラーにより行った。各パネラーの評点の平均を表6に示す。   The pH of the prepared reaction liquids 4 to 7 was adjusted to pH 8 with sodium hydroxide, respectively, and reacted at 110 ° C. for 60 minutes to obtain products 4 to 7. The said products 4-7 were added to the curry soup prepared in Example 1 so that it might become 1 weight%, respectively. The sensory evaluation was performed by seven skilled panelists according to the method described in Example 1 for the spice feeling in each of the added groups (test groups 4 to 7). The average score of each panel is shown in Table 6.

Figure 2016158507
Figure 2016158507

表6に示すとおり、エタノール存在下でグルコースとアミノ酸混合物との加熱反応を行って得た生成物を加えたカレースープ(試験区6および7)では無添加区に対して有意に香辛料感が向上していた。特に、エタノール存在下でのグルコースと蛋白加水分解物との加熱反応において加熱反応後に減少量の多かったアミノ酸(アミノ酸混合物1:アラニン、アスパラギン酸、グルタミン酸、ロイシン、アルギニン)を用いて得た生成物6では、その効果は顕著であった。   As shown in Table 6, in the curry soup (test groups 6 and 7) to which the product obtained by heating reaction of glucose and amino acid mixture in the presence of ethanol was added, the feeling of spice was significantly improved compared to the additive-free group. Was. In particular, a product obtained by using an amino acid (amino acid mixture 1: alanine, aspartic acid, glutamic acid, leucine, arginine) whose amount of decrease was large after the heating reaction in the heating reaction between glucose and a protein hydrolyzate in the presence of ethanol. In 6, the effect was remarkable.

このことから、実施例1で示した香辛料感の向上効果は、蛋白加水分解物中のアミノ酸が関係していること、さらに該アミノ酸はいずれのアミノ酸であってもよいが、アラニン、アスパラギン酸、グルタミン酸、ロイシン、アルギニンが特に好ましいことが示された。   From this, the improvement effect of the spice feeling shown in Example 1 is related to the amino acid in the protein hydrolyzate, and the amino acid may be any amino acid, but alanine, aspartic acid, Glutamic acid, leucine and arginine have been shown to be particularly preferred.

(実施例3)
実施例1で調製した反応液1のpHを、塩酸または水酸化ナトリウムでpH8.0、pH3.0、およびpH5.5の3通りに調整し、それぞれ110℃で60分間加熱反応させて生成物8〜10を得た。当該生成物8〜10を、実施例1で調製したカレースープにそれぞれ1重量%となるように添加した。各添加区(試験区8〜10)の香辛料感について実施例1記載の方法に準じて官能評価を、熟練した7名のパネラーにより行った。各パネラーの評点の平均を表7に示す。
(Example 3)
The pH of the reaction solution 1 prepared in Example 1 was adjusted to 3 levels of pH 8.0, pH 3.0, and pH 5.5 with hydrochloric acid or sodium hydroxide, and each product was reacted by heating at 110 ° C. for 60 minutes. 8-10 were obtained. The said products 8-10 were added to the curry soup prepared in Example 1 so that it might become 1 weight%, respectively. In accordance with the method described in Example 1, the sensory evaluation was performed by seven skilled panelists regarding the spice feeling in each additive group (test groups 8 to 10). The average score of each panel is shown in Table 7.

Figure 2016158507
Figure 2016158507

表7に示すとおり、エタノール存在下でのグルコースと蛋白加水分解物との加熱反応は、pH5以上で行うことが好ましいことがわかった。   As shown in Table 7, it was found that the heating reaction between glucose and protein hydrolyzate in the presence of ethanol is preferably performed at pH 5 or higher.

(実施例4)
下記表8に示す組成に準じて水溶液を調製し、それぞれ反応液11〜13とした。なお、各反応液のグルコース濃度およびエタノール濃度は等量となるようにグルコースおよびエタノールの添加量を調整してある。
Example 4
Aqueous solutions were prepared according to the compositions shown in Table 8 below, and designated as reaction solutions 11 to 13, respectively. In addition, the addition amount of glucose and ethanol is adjusted so that the glucose concentration and ethanol concentration of each reaction solution become equal.

Figure 2016158507
Figure 2016158507

調製した反応液11〜13のpHをそれぞれ水酸化ナトリウムにてpH8に調整し、110℃で60分間加熱反応させて生成物11〜13を得た。当該生成物11〜13を、実施例1で調製したカレースープにそれぞれ1重量%となるように添加した。各添加区(試験区11〜13)の香辛料感について、実施例1記載の方法に準じて官能評価を、熟練した7名のパネラーにより行った。各パネラーの評点の平均を表9に示す。   The pH of the prepared reaction liquids 11 to 13 was adjusted to pH 8 with sodium hydroxide, respectively, and reacted by heating at 110 ° C. for 60 minutes to obtain products 11 to 13. The said products 11-13 were added to the curry soup prepared in Example 1 so that it might become 1 weight%, respectively. For the sense of spices in each of the added sections (test sections 11 to 13), sensory evaluation was performed by seven skilled panelists according to the method described in Example 1. The average score of each panel is shown in Table 9.

Figure 2016158507
Figure 2016158507

表9に示すとおり、アルコールを含有する日本酒、ワインのいずれを用いても香辛料感の向上効果が認められたが、酒粕(エタノール量は調整)を用いた場合、より高い向上効果が認められた。   As shown in Table 9, the effect of improving the feeling of spice was recognized when using either sake or wine containing alcohol, but when using sake lees (the amount of ethanol was adjusted), a higher improvement effect was observed. .

本発明は、香辛料を含む調味料および香辛料感の向上した飲食品の製造・加工分野において利用できる。   INDUSTRIAL APPLICATION This invention can be utilized in the manufacturing / processing field | area of the food / beverage products which the seasoning containing a spice and spices improved.

Claims (5)

アルコール存在下で糖とアミノ酸とを加熱反応させて得られる生成物を含有する香辛料感向上剤。   A spice-feel improving agent containing a product obtained by heating and reacting sugar and amino acid in the presence of alcohol. 前記加熱反応が、アルカリ条件下で行われる、請求項1に記載の香辛料感向上剤。   The spice-feel improving agent according to claim 1, wherein the heating reaction is performed under alkaline conditions. 請求項1または2に記載の香辛料感向上剤を、香辛料を含有する飲食品に添加することを特徴とする、飲食品の香辛料感向上方法。   A method for improving the feeling of spices in foods or drinks, comprising adding the spice feeling improver according to claim 1 or 2 to foods or drinks containing spices. 請求項1または2に記載の香辛料感向上剤を飲食品に添加する工程を含む、飲食品の製造方法。   The manufacturing method of food-drinks including the process of adding the spice feeling improvement agent of Claim 1 or 2 to food-drinks. 請求項1または2に記載の香辛料感向上剤および香辛料を含有することを特徴とする調味料。
A seasoning comprising the spice sensation improving agent according to claim 1 or 2 and a spice.
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WO2021172219A1 (en) * 2020-02-25 2021-09-02 三菱商事ライフサイエンス株式会社 Spice flavor enhancing method
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