JP4987221B2 - Coated paper for printing - Google Patents

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JP4987221B2
JP4987221B2 JP2004031416A JP2004031416A JP4987221B2 JP 4987221 B2 JP4987221 B2 JP 4987221B2 JP 2004031416 A JP2004031416 A JP 2004031416A JP 2004031416 A JP2004031416 A JP 2004031416A JP 4987221 B2 JP4987221 B2 JP 4987221B2
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paper
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printing
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coated paper
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JP2004131922A (en
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秀昭 二艘木
潤 牧原
健秀 笠原
隆 越智
博一 森井
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Nippon Paper Industries Co Ltd
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本発明は印刷用塗被紙に関し、嵩高(低密度)でありながら柔軟性に優れる印刷用塗被紙に関するものである。   The present invention relates to a coated paper for printing, and relates to a coated paper for printing that is bulky (low density) and excellent in flexibility.

近年、印刷物のビジュアル化やカラー化が進み、印刷用紙の高品質化の要求が高まっている。一方で、輸送および郵送コストの削減などのため、印刷物の軽量化に対する要求も高い。従来、これらの二つの要望は相反するものであり、高品質印刷塗被紙は原紙坪量および塗工量が多く、また表面処理による平滑化などにより、同一坪量で比較して密度の高いものであった。印刷物の軽量化には低坪量の用紙を選択することが可能であるが、密度が同等であれば軽量化に伴い紙厚も低くなり、冊子のボリューム感を損なうため好まれない。このため嵩高な、すなわち同一坪量で比較して紙厚の高いもしくは同一紙厚で比較して坪量の低く、かつ高級印刷用途としての塗被紙の要求を満たす高品質な塗被紙が求められている。   In recent years, with the progress of visualization and colorization of printed matter, there is an increasing demand for higher quality printing paper. On the other hand, there is a high demand for weight reduction of printed materials in order to reduce transportation and mail costs. Conventionally, these two demands are contradictory, and high-quality printed coated paper has a large base weight and coating amount, and has a higher density than the same basis weight due to smoothing by surface treatment, etc. It was a thing. It is possible to select a low basis weight paper for weight reduction of the printed matter, but if the density is equal, the paper thickness decreases with weight reduction, which is not preferable because the volume of the booklet is impaired. For this reason, a high-quality coated paper that is bulky, that is, has a high paper thickness compared to the same basis weight or a low basis weight compared to the same paper thickness, and satisfies the requirements of coated paper for high-grade printing applications. It has been demanded.

また近年、ムックやポケットガイドと呼ばれる、版型が小さく携帯に便利な情報誌が好まれる傾向にある。これらの用紙に要求される特性としては柔軟性が重要である。剛直な用紙を使用した場合、冊子の版型が小さくなるほどページをめくる際にページが立ち易くなり、例えば外出先などで、冊子を片手で開いて読むには非常に不便であった。用紙の柔軟性の指標としては、クラークこわさ等が用いられるが、こわさは紙厚の3乗に比例して高くなるため、嵩高化により同一坪量で紙厚が高くなる場合剛度はそれに伴い高くなることから、用紙の柔軟性と嵩高を両立させることは極めて困難であると考えられてきた。   In recent years, information magazines called “mooks” and “pocket guides”, which have small plates and are convenient to carry, tend to be preferred. Flexibility is important as a characteristic required for these sheets. When rigid paper is used, the smaller the template of the booklet, the easier it is for the page to stand when turning the page, and it is very inconvenient to open and read the booklet with one hand, for example, on the go. Clark stiffness is used as an index of paper flexibility, but stiffness increases in proportion to the cube of the paper thickness, so if the paper thickness increases with the same basis weight due to the increase in bulk, the stiffness increases accordingly. For this reason, it has been considered extremely difficult to achieve both the flexibility and bulkiness of the paper.

嵩高化のための手法としては、嵩高なパルプおよび嵩高な填料の使用による塗被紙用原紙の嵩高化、および塗被液組成物塗被量減少、および得られる塗被紙の表面処理の緩和等が考えられる。   To increase the bulk, the use of bulky pulp and bulky filler increases the bulk of the base paper for coated paper, reduces the coating amount of the coating liquid composition, and reduces the surface treatment of the resulting coated paper. Etc. are considered.

製紙用パルプとしては、化学薬品により繊維中のリグニンを抽出した化学パルプと、化学薬品を使用せずグラインダーで木材を磨り潰した砕木パルプやリファイナーで木材を解繊したサーモメカニカルパルプ等の機械パルプに大別される。一般的には、化学パルプと比較して機械パルプの方が繊維が剛直で低密度化には効果的である。しかしこれらの機械パルプは上質紙への配合は規格上問題があり、また中質紙においても、結束繊維等による紙ムケ等印刷欠陥を生じ易いためその配合量には限界がある。また、近年の環境保護気運の高まりや資源保護の必要性から、古紙パルプが配合されることが多くなっている。しかし古紙パルプは一般的に、上質紙、新聞紙、雑誌、塗被紙等が混合されてパルプ化されることが多いため、バージン(紙に抄かれていない未使用の)機械パルプと比較して密度が高い。以上のように、パルプ面のみで十分な用紙の嵩高化を達成することは、木材資源の保護や用紙の品質設計を考えた場合困難である。また、上述のパルプを配合したのみでは嵩高化と剛度が高くなるため、用紙に十分な柔軟性を付与することは不可能であった。   Pulp for papermaking includes chemical pulp extracted from lignin in fibers with chemicals, and mechanical pulp such as ground mechanical pulp that has been crushed with a grinder without using chemicals, and thermomechanical pulp that has been defibrated with refiners It is divided roughly into. In general, mechanical pulp is more rigid and more effective in reducing density than chemical pulp. However, these mechanical pulps have a problem in terms of standardization when used in high-quality paper, and even in medium-quality paper, there is a limit to the amount of mixing because printing defects such as paper scumming due to bundling fibers are likely to occur. In addition, waste paper pulp is often blended due to the recent increase in environmental protection and the need for resource protection. However, waste paper pulp is generally mixed with fine paper, newsprint, magazines, coated paper, etc., so it is often pulped. Compared with virgin (unused paper) mechanical pulp. High density. As described above, it is difficult to achieve sufficient paper bulkiness only by the pulp surface when considering protection of wood resources and quality design of paper. Moreover, since the bulkiness and the rigidity are increased only by blending the above-described pulp, it is impossible to impart sufficient flexibility to the paper.

また、塗被紙用原紙の嵩高化として嵩高な填料の使用が考えられる。例えば、特許文献1には、中空の合成有機物カプセルを配合することにより低密度化する手法が開示されている。しかしながらこのような合成有機物は紙力を低下させるため、印刷時の紙ムケや断紙などの問題がある上、十分な嵩高効果を得るには高配合する必要があるため、製造原価が高くなる等の問題もあった。特許文献2にはシラスバルーンを用いる方法が提案されている。しかしこれは、製紙用パルプとの混合性が悪く、また、それを配合した用紙も印刷むらが発生するなどの問題があった。また、以上の手法を用いても、用紙に柔軟性を付与することは不可能であった。   Moreover, use of a bulky filler can be considered as an increase in bulk of the base paper for coated paper. For example, Patent Document 1 discloses a technique for reducing the density by blending a hollow synthetic organic capsule. However, since such synthetic organic materials reduce paper strength, there are problems such as paper scumming and paper breakage during printing, and in order to obtain a sufficient bulky effect, it is necessary to add a high amount, which increases the manufacturing cost. There were also problems such as. Patent Document 2 proposes a method using a shirasu balloon. However, this has a problem in that the miscibility with the pulp for papermaking is poor, and the paper blended with it also has uneven printing. Further, even if the above method is used, it is impossible to impart flexibility to the paper.

塗被紙の塗被層は一般的に原紙に比較して密度が高い。このため、塗被層を設けない印刷用紙と比較して塗被紙の密度は高い。塗被紙の嵩高化のためには、塗被組成物の塗被量を少なくする事によっても達成される。これは、塗被紙全体に占める塗被層の比率が小さくなるためである。しかし、塗被層を少なくする事は同時に、塗被層による原紙の被覆性を低下させるため、白紙光沢度、平滑性、印刷光沢度などの印刷品質を低下せしめるため、目標とする品質を維持しながら塗被量を減少させることには限界があった。   The coated layer of the coated paper is generally higher in density than the base paper. For this reason, compared with the printing paper which does not provide a coating layer, the density of a coated paper is high. Increasing the bulk of the coated paper can also be achieved by reducing the coating amount of the coating composition. This is because the ratio of the coating layer to the entire coated paper is small. However, reducing the coating layer at the same time lowers the coverage of the base paper by the coating layer, thus reducing the printing quality such as blank paper glossiness, smoothness, and printing glossiness, so the target quality is maintained. However, there was a limit to reducing the coating amount.

塗被紙の印刷品質、特にインクの着肉濃度や画線部の光沢度(以下、印刷光沢度という)を向上するためには、塗被紙の平滑性を高める事が有効な手段の一つである。このため、光沢紙やダル調と呼ばれる艶消し塗被紙と光沢紙の中間的な白紙光沢度を有する塗被紙では、スーパーカレンダーやソフトニップカレンダー等の表面平滑化処理を施すことが一般的である。しかし、これらの処理は用紙を加圧して表面の平滑性を高めるものであるため、同時に用紙の紙厚が低くなり、目標とする印刷品質を得るには十分な嵩高化が達成できない場合があった。   In order to improve the print quality of the coated paper, particularly the ink density and the glossiness of the image area (hereinafter referred to as the print glossiness), it is effective to improve the smoothness of the coated paper. One. For this reason, surface smoothing such as super calenders and soft nip calenders is generally applied to glossy paper or coated paper having a glossiness between white and glossy paper called dull tone. It is. However, since these treatments pressurize the paper to increase the smoothness of the surface, the paper thickness of the paper decreases at the same time, and there is a case where sufficient bulkiness cannot be achieved to obtain the target print quality. It was.

以上のように、従来の技術単独もしくは組み合わせだけでは、嵩高(低密度)でありながら柔軟性に優れる印刷用塗被紙を得ることは不可能であった。   As described above, it has been impossible to obtain a coated paper for printing that is bulky (low density) and excellent in flexibility with only the conventional technique alone or in combination.

特開平5−339898号公報JP-A-5-339898 特開昭52−74001号公報JP-A-52-74001

この様な状況に鑑みて、本発明の課題は、嵩高でありながら柔軟性に優れ、また印刷機での断紙が発生しにくく、作業性の良好な印刷用塗被紙を提供することにある。   In view of such a situation, an object of the present invention is to provide a coated paper for printing that is bulky and excellent in flexibility, is less likely to cause paper breakage in a printing press, and has good workability. is there.

本発明者らは、上記の如き困難な状況において鋭意検討を重ねた結果、原紙上に、顔料と接着剤を含有する塗被層を有する印刷用塗被紙において、紙の坪量、密度、抄紙方向のヤング率および抄紙方向の裂断長の4者の積が1.0×10212・N/m以上4.0×10212・N/m以下であり、顔料100重量部対して5〜50重量部の接着剤を含有することにより、嵩高であり、かつ柔軟性に優れ、また印刷機での断紙が発生しにくく、作業性が良好な印刷用塗被紙が得られることを見出した。4者の積は、2.0×10212・N/m以上3.5×10212・N/m以下となるように特定することが好ましい。本発明においては、特に塗被層の塗被量を少なくとも片面当たり9〜25g/m2塗被した場合においても、嵩高で、柔軟性があり、良好な印刷品質の印刷用塗被紙が得られるものである。 As a result of intensive studies in the difficult situation as described above, the present inventors have found that on a base paper, a printing paper having a coating layer containing a pigment and an adhesive, the basis weight of paper, density, The product of Young's modulus in the paper making direction and the tear length in the paper making direction is 1.0 × 10 21 g 2 · N / m 6 or more and 4.0 × 10 21 g 2 · N / m 6 or less, and the pigment By containing 5 to 50 parts by weight of the adhesive with respect to 100 parts by weight, the coating for printing is bulky and excellent in flexibility, is less likely to cause paper breakage in a printing press, and has good workability. We found that paper was obtained. It is preferable that the product of the four members is specified to be 2.0 × 10 21 g 2 · N / m 6 or more and 3.5 × 10 21 g 2 · N / m 6 or less. In the present invention, particularly when the coating amount of the coating layer is at least 9 to 25 g / m 2 per side, it is bulky, flexible, and has a good printing quality. It is

本発明者らは、用紙の柔軟性を検討する上で、冊子のめくりやすさに着目した。一般的に用紙のこわさはクラークこわさ、純曲げこわさ等で定量的に評価される。各種の冊子について被験者によるページのめくりやすさと、抄紙方向および幅方向の純曲げこわさとの相関について調査した結果、こわさが低い紙は柔軟となる傾向にあったが、こわさが同等であってもページのめくりやすさの官能評価は異なる用紙があった。すなわち、曲げこわさだけでは用紙の柔軟性は評価できないことが判明した。   The inventors paid attention to the ease of turning a booklet when examining the flexibility of paper. Generally, paper stiffness is quantitatively evaluated by Clark stiffness, pure bending stiffness, and the like. As a result of investigating the correlation between ease of page turning by subjects and pure bending stiffness in the paper making direction and width direction for various booklets, low stiffness paper tended to be flexible. There were different papers for the sensory evaluation of page turnability. That is, it has been found that the flexibility of the paper cannot be evaluated only by bending stiffness.

ページがめくられる際に、用紙には曲げ応力が加えられ、凸となる表面では引張り応力を、凹となる面では圧縮応力を受ける。そこで、幅方向および抄紙方向のヤング率とめくりやすさとの相関を求めた。その結果、幅方向の純曲げこわさが同等であっても、幅方向および抄紙方向のヤング率が低いほど、ページがめくりやすくなることが確認された。試験した多くの用紙で幅方向と抄紙方向のヤング率は正相関の関係にあったが、特に抄紙方向のヤング率が低い場合、ページがめくりやすく柔軟であることに加えて、オフセット輪転印刷機で印刷する際に、給紙部、およびクーリングロール部等での張力の変動が少ないため、紙匹の走行安定性が増し、断紙が発生しにくいことが判明した。   When the page is turned, bending stress is applied to the paper, and tensile stress is applied to the convex surface and compressive stress is applied to the concave surface. Therefore, the correlation between the Young's modulus in the width direction and the papermaking direction and the ease of turning was determined. As a result, it was confirmed that even if the pure bending stiffness in the width direction is the same, the lower the Young's modulus in the width direction and the paper making direction, the easier the page is turned. In many of the papers tested, the Young's modulus in the width direction and the papermaking direction had a positive correlation, but when the Young's modulus in the papermaking direction was low, in addition to being easy to turn pages and being flexible, an offset rotary printing press. When printing with, it was found that the fluctuation in tension in the paper feed unit, the cooling roll unit, etc. is small, so that the running stability of the web is increased and the paper breakage hardly occurs.

また本発明者等は、用紙の強度と柔軟性の関係についても調査した。その結果、紙厚が同等の用紙で比較した場合、裂断長が低い紙の方が柔軟性が高くなる傾向にあることが判明した。例えば裂断長が高い用紙の場合、用紙内のパルプ繊維の間で水素結合の形成量が多く、紙力は相対的に強くなる傾向にあるが、反面繊維の自由度が低下するため、同一の曲げひずみ、もしくは引っ張りひずみを得るために必要な曲げ応力、もしくは引張り応力が相対的に大きくなり、これによりページがめくりにくくなると考えられる。   The inventors also investigated the relationship between paper strength and flexibility. As a result, it was found that the paper with a shorter tear length tends to be more flexible when compared with paper having the same paper thickness. For example, in the case of paper with a high breaking length, the amount of hydrogen bonds formed between the pulp fibers in the paper is large, and the paper strength tends to be relatively strong. It is considered that the bending stress or tensile stress necessary for obtaining the bending strain or tensile strain of the sheet becomes relatively large, which makes it difficult to turn the page.

以上のことから、用紙のヤング率と裂断長を同時に、バランス良く低下させることにより、用紙の柔軟性が向上し、これは嵩高な、すなわち同等の坪量で比較して紙厚の高い紙にも応用可能な手法であることを見出した。さらに鋭意検討した結果、目的とする柔軟性が得られるヤング率、裂断長の範囲は、密度および坪量により異なり、用紙の坪量が高いほどヤング率、もしくは裂断長を低下させなければ、良好な柔軟性が得られなかった。すなわち、用紙の柔軟性は坪量、密度、抄紙方向のヤング率、および抄紙方向の裂断長の4者の積の値と良好な相関を示すことが判明した。4者の積が1.0×10212・N/m以上4.0×10212・N/m以下、好ましくは2.0×10212・N/m以上3.5×10212・N/m以下の範囲であれば印刷物を製本して冊子にした時のページのめくりやすさが良好で、嵩高であるためにボリューム感があり、また印刷時の断紙などの発生が少なく作業性が良好な印刷用塗被紙であることを見出した。従来の技術単独もしくは組み合わせによる用紙の嵩高化では得られなかった柔軟性を、ヤング率と裂断長をバランス良く低下させることで達成し、かつ、印刷機での作業性も良好な用紙が得られた。 From the above, by simultaneously reducing the Young's modulus and tear length of the paper in a well-balanced manner, the flexibility of the paper is improved, which is bulky, that is, a paper having a high paper thickness compared with an equivalent basis weight. It was found that this technique can also be applied. As a result of further intensive studies, the range of Young's modulus and tear length that provides the desired flexibility depends on the density and basis weight, and the higher the basis weight of the paper, the lower the Young's modulus or tear length must be. Good flexibility was not obtained. That is, it has been found that the flexibility of the paper shows a good correlation with the values of the four products of the basis weight, density, Young's modulus in the paper making direction, and tear length in the paper making direction. The product of the four members is 1.0 × 10 21 g 2 · N / m 6 or more and 4.0 × 10 21 g 2 · N / m 6 or less, preferably 2.0 × 10 21 g 2 · N / m 6 or more If it is in the range of 3.5 × 10 21 g 2 · N / m 6 or less, it is easy to turn the page when the printed material is bound into a booklet. It has been found that the coated paper for printing has good workability with little occurrence of paper breakage. Flexibility that cannot be obtained by increasing the bulk of paper using conventional technology alone or in combination is achieved by reducing the Young's modulus and tear length in a well-balanced manner, and paper with good workability on a printing press can be obtained. It was.

同一の坪量で比較して、密度が通常の値で4者の積の値が1.0×10212・N/m未満である用紙は、過度にヤング率が低いもしくは裂断長が低いことであり、過度に柔軟であるために紙腰が無くページがめくりにくい、もしくは印刷機での張力に対する紙のひずみが大きくなり、弾性限界を超えて伸びた紙は破壊されてしまうため、断紙が起こり易い。また同一の坪量で比較して、ヤング率および裂断長が通常の値で4者の積の値が1.0×10212・N/m未満である用紙は、過度に密度が低い用紙であり、このような紙は抄紙工程でのプレスやカレンダー処理圧力を極端に低下させる必要があり、このため平滑度が著しく低く印刷することが困難である。 Compared with the same basis weight, the paper whose density is normal and the product of the four is less than 1.0 × 10 21 g 2 · N / m 6 has too low Young's modulus or tearing The length is low and the paper is not flexible because it is too flexible, or the paper is not easily turned due to the tension in the printing press, and the paper stretched beyond the elastic limit is destroyed. Therefore, the paper break is likely to occur. Compared with the same basis weight, the paper whose Young's modulus and tear length are normal and the product of the four is less than 1.0 × 10 21 g 2 · N / m 6 is excessively dense. However, it is necessary to extremely reduce the press and calendering pressure in the paper making process, so that it is difficult to print with extremely low smoothness.

一方で、同一の坪量で比較して、密度が通常の値で4者の積の値が4.0×10212・N/mを超える用紙は、過度に裂断長が高い、もしくはヤング率が高いことであり、用紙が剛直となり柔軟な用紙が得られず、またヤング率が高い場合剛直になる上に更に、印刷時の張力変動を吸収しきれず部分的に高い応力がかかってしまうために断紙などのトラブルが発生しやすい。また同一の坪量で比較して、ヤング率および裂断長が通常の値で4者の積の値が4.0×10212・N/mを超える用紙は、極端に密度が高いことであり、本発明の目的とする嵩高でボリューム感のある印刷用塗被紙とはならない。 On the other hand, compared with the same basis weight, the paper whose density is a normal value and the value of the product of the four members exceeds 4.0 × 10 21 g 2 · N / m 6 has an excessively high tear length. Or the Young's modulus is high, the paper becomes rigid and flexible paper cannot be obtained, and when the Young's modulus is high, the paper becomes stiff, and furthermore, it cannot absorb the fluctuation in tension during printing, and partially has high stress. Therefore, troubles such as paper breakage are likely to occur. Compared with the same basis weight, paper whose Young's modulus and tear length are normal values and the product of the four members exceeds 4.0 × 10 21 g 2 · N / m 6 has an extremely high density. That is, it is not a bulky and voluminous coated paper intended for the present invention.

本発明により、嵩高(低密度)で、柔軟性に優れ、印刷機での断紙が発生しにくく、作業性が良好な印刷用塗被紙を得ることができる。   According to the present invention, it is possible to obtain a coated paper for printing that is bulky (low density), excellent in flexibility, hardly breaks in a printing press, and has good workability.

用紙の坪量、密度、抄紙方向のヤング率、および抄紙方向の裂断長の4者の積を1.0×10212・N/m以上4×10212・N/m以下の範囲にするためには、用紙の密度、抄紙方向のヤング率、および抄紙方向の裂断長を各々低下させる手段を組み合わせることが好ましい。用紙の密度を低下させる方法としては、低密度のパルプおよび低密度の填料の配合率を向上させる方法、あるいは嵩高薬品の使用、あるいは抄紙工程のプレス圧やマシンキャレンダーの処理線圧低減等が挙げられる。用紙のヤング率を低下させる方法としては、柔軟化剤の使用などが挙げられる。用紙の抄紙方向の裂断長を低下させる方法としては、填料の配合率を上げる等の方法が挙げられる。 The product of the basis weight, density, Young's modulus in the paper making direction, and tear length in the paper making direction is 1.0 × 10 21 g 2 · N / m 6 or more and 4 × 10 21 g 2 · N / m In order to obtain a range of 6 or less, it is preferable to combine means for reducing the paper density, the Young's modulus in the papermaking direction, and the tearing length in the papermaking direction. Methods for reducing the density of the paper include a method of improving the blending ratio of low density pulp and low density filler, use of bulky chemicals, reduction of press pressure in the paper making process and processing linear pressure of the machine calendar, etc. Can be mentioned. Examples of a method for reducing the Young's modulus of the paper include the use of a softening agent. Examples of a method for reducing the breaking length of the paper in the paper making direction include a method of increasing the blending ratio of the filler.

本発明においては、柔軟化剤を使用することが好ましい。使用する柔軟化剤とは、パルプ繊維間結合を阻害する作用を有するか、繊維自体を柔軟化するものである。例えば、疎水基と親水基を持つ化合物であり、油脂系非イオン界面活性剤、糖アルコール系非イオン界面活性剤、糖系非イオン界面活性剤、多価アルコール型非イオン界面活性剤、高級アルコール、多価アルコールと脂肪酸のエステル化合物、高級アルコールまたは高級脂肪酸のポリオキシアルキレン化合物、多価アルコールと脂肪酸のエステル化合物のポリオキシアルキレン付加物、脂肪酸ポリアミドアミンなどを使用することができる。ヤング率の低下に加えて純曲げこわさおよび密度の低下も可能なものが好ましく、多価アルコールと脂肪酸のエステル化合物等を使用することが好ましい。   In the present invention, it is preferable to use a softening agent. The softening agent to be used has an action of inhibiting the binding between pulp fibers or softens the fibers themselves. For example, it is a compound having a hydrophobic group and a hydrophilic group, and is an oil-based nonionic surfactant, a sugar alcohol-based nonionic surfactant, a sugar-based nonionic surfactant, a polyhydric alcohol-type nonionic surfactant, a higher alcohol Polyesters of polyhydric alcohols and fatty acids, polyoxyalkylene compounds of higher alcohols or higher fatty acids, polyoxyalkylene adducts of ester compounds of polyhydric alcohols and fatty acids, fatty acid polyamidoamines, and the like can be used. Those capable of reducing the pure bending stiffness and density in addition to the decrease in Young's modulus are preferable, and it is preferable to use an ester compound of a polyhydric alcohol and a fatty acid.

本発明において原紙に配合されるパルプの種類等は、例えば広葉樹晒クラフトパルプ(以下、LBKP)、針葉樹晒クラフトパルプ(以下、NBKP)、サーモメカニカルパルプ、砕木パルプ、古紙パルプ等が使用される。印刷機上のラフニングを良好にするためには、LBKP、NBKPの化学パルプを使用することが好ましい。また、紙中に填料を含有させると、ヤング率が低下する傾向にあるため、填料を含有させることは好ましく、填料としては、重質炭酸カルシウム、軽質炭酸カルシウム、カオリン、クレー、タルク、水和珪酸、ホワイトカーボン、酸化チタン、合成樹脂填料などの公知の填料を使用することができる。填料の使用量は、パルプ重量対して6重量%が好ましく、より好ましくは10重量%以上である。さらに必要に応じて、硫酸バンド、サイズ剤、紙力増強剤、柔軟化剤、歩留まり向上剤、着色剤、染料、消泡剤などを含有しても良い。   In the present invention, for example, hardwood bleached kraft pulp (hereinafter referred to as LBKP), softwood bleached kraft pulp (hereinafter referred to as NBKP), thermomechanical pulp, ground wood pulp, waste paper pulp, and the like are used as the type of pulp blended into the base paper. In order to improve roughening on the printing press, it is preferable to use chemical pulp of LBKP or NBKP. Moreover, since Young's modulus tends to decrease when a filler is contained in the paper, it is preferable to contain a filler. As the filler, heavy calcium carbonate, light calcium carbonate, kaolin, clay, talc, hydration Known fillers such as silicic acid, white carbon, titanium oxide, and synthetic resin fillers can be used. The amount of filler used is preferably 6% by weight, more preferably 10% by weight or more, based on the weight of the pulp. Further, if necessary, a sulfuric acid band, a sizing agent, a paper strength enhancer, a softening agent, a yield improver, a colorant, a dye, an antifoaming agent and the like may be contained.

更に密度、ヤング率および裂断長に影響しない範囲で、表面強度やサイズ性の向上の目的で、原紙に水溶性高分子を主成分とする表面処理剤の塗布を行っても良い。水溶性高分子としては、酸化澱粉、ヒドロキシエチルエーテル化澱粉、酵素変性澱粉、ポリアクリルアミド、ポリビニルアルコール等の、表面処理剤として通常使用されるものを単独、あるいはこれらの混合物を使用することができる。また、表面処理剤の中には、水溶性高分子の他に耐水化、表面強度向上を目的とした紙力増強剤やサイズ性付与を目的とした外添サイズ剤を添加することができる。表面処理剤は、2ロールサイズプレスコーターや、ゲートロールコーター、およびブレードメタリングサイズプレスコーター、およびロッドメタリングサイズプレスコーター、シムサイザー等のフィルム転写型ロールコーター等の塗工機によって塗布することができる。また、本発明に使用される印刷用塗被紙用原紙のpHは、酸性、中性、アルカリ性の何れでも良い。   Furthermore, a surface treatment agent mainly composed of a water-soluble polymer may be applied to the base paper for the purpose of improving the surface strength and sizing properties within a range that does not affect the density, Young's modulus, and tearing length. As the water-soluble polymer, those usually used as surface treating agents such as oxidized starch, hydroxyethyl etherified starch, enzyme-modified starch, polyacrylamide, polyvinyl alcohol, etc. can be used alone or a mixture thereof. . In addition to the water-soluble polymer, a paper strength enhancer for the purpose of water resistance and surface strength improvement and an external sizing agent for the purpose of imparting sizing can be added to the surface treatment agent. The surface treatment agent can be applied by a coating machine such as a two-roll size press coater, a gate roll coater, a blade metering size press coater, a rod metering size press coater, or a film transfer type roll coater such as a shim sizer. it can. The pH of the base paper for coated paper used in the present invention may be any of acidic, neutral and alkaline.

本発明においては、密度、ヤング率、および裂断長に影響しない範囲で、原紙に顔料と接着剤を有する塗被層を設ける。   In the present invention, a coating layer having a pigment and an adhesive is provided on the base paper within a range not affecting the density, Young's modulus, and tearing length.

塗被層に用いる顔料として塗工紙用に従来から用いられている、カオリン、クレー、デラミネーテッドクレー、重質炭酸カルシウム、軽質炭酸カルシウム、タルク、二酸化チタン、硫酸バリウム、硫酸カルシウム、酸化亜鉛、ケイ酸、ケイ酸塩、コロイダルシリカ、サチンホワイトなどの無機顔料、プラスチックピグメントなどの有機顔料であり、これらの顔料は必要に応じて1種以上を適宜選択して使用することが出来る。   Kaolin, clay, delaminated clay, heavy calcium carbonate, light calcium carbonate, talc, titanium dioxide, barium sulfate, calcium sulfate, zinc oxide conventionally used for coated paper as a pigment used in the coating layer Inorganic pigments such as silicic acid, silicate, colloidal silica, and satin white, and organic pigments such as plastic pigments, and these pigments can be used by appropriately selecting one or more kinds as necessary.

本発明において使用する接着剤は、塗工紙用に従来から用いられている、スチレン・ブタジエン系、スチレン・アクリル系、エチレン・酢酸ビニル系、ブタジエン・メチルメタクリレート系、酢酸ビニル・ブチルアクリレート系等の各種共重合およびポリビニルアルコール、無水マレイン酸共重合体、アクリル酸・メチルメタクリレート系共重合体等の合成系接着剤;カゼイン、大豆蛋白、合成蛋白等の蛋白質類;酸化澱粉、陽性澱粉、尿素燐酸エステル化澱粉、ヒドロキシエチルエーテル化澱粉などのエーテル化澱粉、デキストリン等の澱粉類;カルボキシメチルセルロース、ヒドロキシエチルセルロース、ヒドロキシメチルセルロース等のセルロース誘導体等の通常の塗工紙用接着剤1種類以上を適宜選択して使用される。これらの接着剤は顔料100重量部対して5〜50重量部使用することが必要であり、好ましくは5〜25重量部程度の範囲で使用される。また、必要に応じて、分散剤、増粘剤、保水剤、消泡剤、耐水化剤、着色剤等、通常の塗工紙用顔料に配合される各種助剤が適宜使用される。   Adhesives used in the present invention are conventionally used for coated paper, such as styrene / butadiene, styrene / acrylic, ethylene / vinyl acetate, butadiene / methyl methacrylate, vinyl acetate / butyl acrylate, etc. And various synthetic copolymers such as polyvinyl alcohol, maleic anhydride copolymer, acrylic acid / methyl methacrylate copolymer; proteins such as casein, soy protein, synthetic protein; oxidized starch, positive starch, urea Appropriate selection of one or more adhesives for ordinary coated paper such as phosphated starch, etherified starch such as hydroxyethyl etherified starch, starch such as dextrin; cellulose derivatives such as carboxymethylcellulose, hydroxyethylcellulose, hydroxymethylcellulose Used. These adhesives are required to be used in an amount of 5 to 50 parts by weight, preferably in the range of about 5 to 25 parts by weight with respect to 100 parts by weight of the pigment. Moreover, various auxiliary | assistant mix | blended with the pigment for normal coated papers, such as a dispersing agent, a thickener, a water retention agent, an antifoamer, a water-resistant agent, and a coloring agent, are used suitably as needed.

原紙上に設ける塗被層は、密度、ヤング率、および裂断長に影響しない範囲で、原紙の片面あるいは両面に、単層あるいは二層以上設ける事も可能である。塗被層の塗被量は、より好ましくは片面当たり10〜20g/m2を塗被することである。 The coating layer provided on the base paper can be provided as a single layer or two or more layers on one side or both sides of the base paper as long as the density, Young's modulus, and tearing length are not affected. The coating amount of the coating layer is more preferably 10 to 20 g / m 2 per side.

塗被組成物を原紙に塗被するための方法としては、2ロールサイズプレスコーターや、ゲートロールコーター、およびブレードメタリングサイズプレスコーター、およびロッドメタリングサイズプレスコーター、シムサイザー等のフィルム転写型ロールコーターや、フラデッドニップ/ブレードコーター、ジェットファウンテン/ブレードコーター、ショートドウェルタイムアプリケート式コーターの他、ブレードの替わりにグルーブドロッド、プレーンロッド等を用いたロッドメタリングコーターや、カーテンコーター、ダイコーター等の公知のコーターにより塗被することができる。   Film transfer type rolls such as a two-roll size press coater, a gate roll coater, a blade metalling size press coater, a rod metalling size press coater, and a shim sizer are used as methods for coating the coating composition on the base paper. In addition to coaters, flooded nip / blade coaters, jet fountains / blade coaters, short dwell time application type coaters, rod metering coaters that use grooved rods, plain rods, etc. instead of blades, curtain coaters, die coaters It can be coated with a known coater such as a coater.

また、用紙の平滑性向上、および印刷品質向上等のため、上述の手法で得られた塗被紙を、密度に影響しない範囲で表面処理することができる。表面処理方法としては弾性ロールにコットンロールを用いたスーパーカレンダーや、弾性ロールに合成樹脂ロールを用いたソフトニップカレンダー等、公知の表面処理装置を用いることができる。ソフトニップカレンダーは合成樹脂ロール表面の耐熱温度がコットンロールに比べて高く設定することが可能なため、高温での処理が可能である。同一の平滑性を目標とした場合、スーパーカレンダーに比べて処理線圧が低く設定できる場合があるため、より低密度で平滑性の高い塗被紙が得られるため好ましい。本発明の印刷用塗被紙は、好ましくは密度が1.00g/cm3以下であり、より好ましくは0.90g/cm3以下である。 In addition, the coated paper obtained by the above-described method can be surface-treated within a range that does not affect the density in order to improve paper smoothness and print quality. As the surface treatment method, a known surface treatment apparatus such as a super calender using a cotton roll as an elastic roll or a soft nip calender using a synthetic resin roll as an elastic roll can be used. The soft nip calender can be set at a higher heat resistance temperature on the surface of the synthetic resin roll than that of the cotton roll, so that it can be processed at a high temperature. When the same smoothness is targeted, the treatment linear pressure may be set lower than that of the super calender, which is preferable because a coated paper with lower density and higher smoothness can be obtained. The coated paper for printing of the present invention preferably has a density of 1.00 g / cm 3 or less, more preferably 0.90 g / cm 3 or less.

以下、本発明の実施例および比較例を挙げてさらに詳細に説明するが、本発明はこれらにより何等限定されるものではない。尚、特に断らない限り、例中の部、および%はそれぞれ、重量部および重量%を示す。得られた印刷用塗被紙について、以下に示すような評価法に基づいて試験を行った。
<評価方法>
(坪量) JIS P 8124:1998に従った。
(密度) JIS P 8118:1998に従った。
(ヤング率) JIS P 8113:1998に従い、引張り弾性率を測定し、この値をヤング率とした。
(裂断長) JIS P 8113:1998に従った
(柔軟性:ページのめくりやすさ)白紙100枚をA5版サイズに断裁し、クリップで挟んで冊子のモデルを作成し、ページをめくった際のめくりやすさを10人のモニターにより、◎非常に優れる、○優れる、△やや問題あり、×問題ありの4段階で評価した。
(印刷機での作業性) サンプル巻き取りを、オフセット輪転印刷機にて、印刷速度250m/minで、6,000mの長さを印刷し、印刷中のインフィード部とクーリングロール部の張力変動を、○小さい、△やや大きい、×大きいまたは断紙が発生するの3段階で評価した。
[実施例1]
製紙用パルプとして化学パルプを100部、填料として軽質炭酸カルシウムを12部、柔軟化剤として多価アルコールと脂肪酸のエステル化合物(KB−110、花王株式会社製)を0.3部含有する坪量64g/m2の原紙に、顔料として重質炭酸カルシウムを80部、2級カオリンを10部、微粒カオリンを10部、分散剤としてポリアクリル酸ソーダを0.05部、バインダーとしてカルボキシ変性スチレンブタジエンラテックスを11部、燐酸エステル化澱粉を4部を加え、さらに水を加えて固形分濃度65%に調整した塗被液を、塗被量が片面あたり14g/m2となるように、塗被速度800m/分のブレードコーターで両面塗被を行い、印刷用塗被紙を得た。
[実施例2]
塗被液に含まれる顔料として、重質炭酸カルシウムを80部、微粒カオリンを20部とした以外は、実施例1と同様の方法で印刷用塗被紙を得た。
[実施例3]
製紙用パルプとして化学パルプを100部、填料として軽質炭酸カルシウムを12部、柔軟化剤として多価アルコールと脂肪酸のエステル化合物(KB−110、花王株式会社製)を0.5部含有する坪量76g/m2の原紙に、顔料として重質炭酸カルシウムを65部、2級カオリンを7部、微粒カオリンを28部、分散剤としてポリアクリル酸ソーダを0.05部、バインダーとしてカルボキシ変性スチレンブタジエンラテックスを9部、燐酸エステル化澱粉を2.5部を加え、さらに水を加えて固形分濃度64%に調整した塗被液を、塗被量が片面あたり13g/m2となるように、塗被速度500m/分のブレードコーターで両面塗被を行い、印刷用塗被紙を得た。
[実際例4]
製紙用パルプとして化学パルプを100部、填料として軽質炭酸カルシウムを12部、柔軟化剤として多価アルコールと脂肪酸のエステル化合物(KB−115、花王株式会社製)を0.3部含有する坪量64g/m2の原紙に、顔料として重質炭酸カルシウムを80部、2級カオリンを10部、微粒カオリンを10部、分散剤としてポリアクリル酸ソーダを0.05部、バインダーとしてカルボキシ変性スチレンブタジエンラテックスを11部、燐酸エステル化澱粉を4部を加え、さらに水を加えて固形分濃度65%に調整した塗被液を、塗被量が片面あたり14g/m2となるように、塗被速度800m/分のブレードコーターで両面塗被を行い、印刷用塗被紙を得た。
[比較例1]
製紙用パルプとして化学パルプを100部、填料として軽質炭酸カルシウムを12部含有する坪量76g/m2の原紙に、顔料として重質炭酸カルシウムを80部、2級カオリンを10部、微粒カオリンを10部、分散剤としてポリアクリル酸ソーダを0.05部、バインダーとしてカルボキシ変性スチレンブタジエンラテックスを11部、燐酸エステル化澱粉を4部を加え、さらに水を加えて固形分濃度65%に調整した塗被液を、塗被量が片面あたり14g/m2となるように、塗被速度800m/分のブレードコーターで両面塗被を行い、印刷用塗被紙を得た。
[比較例2]
製紙用パルプとして化学パルプを100部し、填料として軽質炭酸カルシウムを12部含有する坪量103g/m2の原紙に、顔料として重質炭酸カルシウムを65部、2級カオリンを7部、微粒カオリンを28部、分散剤としてポリアクリル酸ソーダを0.05部、バインダーとしてカルボキシ変性スチレンブタジエンラテックスを9部、燐酸エステル化澱粉を2.5部を加え、さらに水を加えて固形分濃度64%に調整した塗被液を、塗被量が片面あたり13g/m2となるように、塗被速度500m/分のブレードコーターで両面塗被を行い、印刷用塗被紙を得た。
[比較例3]
製紙用パルプとして化学パルプを100部含有し、填料として軽質炭酸カルシウムを12%含有する坪量55g/m2の原紙に、顔料として重質炭酸カルシウムを95部、2級カオリンを5重量部、分散剤としてポリアクリル酸ソーダを0.05部、バインダーとしてカルボキシ変性スチレンブタジエンラテックスを4部、燐酸エステル化澱粉を20部を加え、さらに水を加えて40%濃度に調整した塗被液を、塗被量が片面あたり3g/m2となるように、塗被速度1000m/minのフィルムトランスファーロールコーターで両面塗被を行い、さらに、顔料として重質炭酸カルシウムを80部、微粒カオリンを20部、分散剤としてポリアクリル酸ソーダを0.05部、バインダーとしてカルボキシ変性スチレンブタジエンラテックスを11部、燐酸エステル化澱粉を4部を加え、さらに水を加えて固形分濃度64%に調整した塗被液を、塗被量が片面あた11g/m2となるように、塗被速度900m/分のブレードコーターで両面塗被を行い印刷用塗被紙を得た。
[比較例4]
原紙の坪量を82g/m2とした以外は、比較例3と同様の方法で印刷用塗被紙を得た。
[比較例5]
原紙の坪量を40g/m2、塗被量を片面あたり12g/m2にした以外は実施例1と同様の方法で印刷用塗被紙を得た。
EXAMPLES Hereinafter, although the Example and comparative example of this invention are given and demonstrated further in detail, this invention is not limited at all by these. In addition, unless otherwise indicated, the part and% in an example show a weight part and weight%, respectively. The obtained coated paper for printing was tested based on the following evaluation method.
<Evaluation method>
(Weight) According to JIS P 8124: 1998.
(Density) According to JIS P 8118: 1998.
(Young's modulus) The tensile elastic modulus was measured according to JIS P 8113: 1998, and this value was defined as Young's modulus.
(Tearing length) According to JIS P 8113: 1998 (Flexibility: Ease of turning pages) When cutting a blank sheet of 100 sheets into A5 size, creating a booklet model with clips, and turning the page The ease of turning was evaluated by a monitor of 10 people in four stages: ◎ very excellent, ◯ excellent, △ somewhat problematic, and 問題 problematic.
(Workability on the printing machine) Sample winding is printed on a rotary offset printing machine at a printing speed of 250 m / min, and a length of 6,000 m is printed. The tension fluctuation of the infeed part and cooling roll part during printing Were evaluated in three stages: small, large, slightly large, large or paper breakage occurred.
[Example 1]
Basis weight containing 100 parts of chemical pulp as paper pulp, 12 parts of light calcium carbonate as filler, 0.3 part of ester compound of polyhydric alcohol and fatty acid (KB-110, manufactured by Kao Corporation) as softening agent On a base paper of 64 g / m 2 , 80 parts of heavy calcium carbonate as a pigment, 10 parts of secondary kaolin, 10 parts of fine kaolin, 0.05 part of sodium polyacrylate as a dispersant, carboxy-modified styrene butadiene as a binder Add 11 parts of latex and 4 parts of phosphate esterified starch, and then add water to adjust the solid content to 65% so that the coating amount is 14 g / m 2 per side. Double-side coating was performed with a blade coater at a speed of 800 m / min to obtain a coated paper for printing.
[Example 2]
A coated paper for printing was obtained in the same manner as in Example 1, except that 80 parts of heavy calcium carbonate and 20 parts of fine kaolin were used as pigments contained in the coating solution.
[Example 3]
Basis weight containing 100 parts of chemical pulp as paper pulp, 12 parts of light calcium carbonate as filler, 0.5 part of ester compound of polyhydric alcohol and fatty acid (KB-110, manufactured by Kao Corporation) as softening agent A base paper of 76 g / m 2 , 65 parts of heavy calcium carbonate as a pigment, 7 parts of secondary kaolin, 28 parts of fine kaolin, 0.05 part of sodium polyacrylate as a dispersant, carboxy-modified styrene butadiene as a binder 9 parts of latex and 2.5 parts of phosphate esterified starch were added, and water was further added to adjust the solid content concentration to 64%, so that the coating amount was 13 g / m 2 per side. Double-sided coating was performed with a blade coater at a coating speed of 500 m / min to obtain a coated paper for printing.
[Practical example 4]
Basis weight containing 100 parts of chemical pulp as paper pulp, 12 parts of light calcium carbonate as filler, 0.3 part of ester compound of polyhydric alcohol and fatty acid (KB-115, manufactured by Kao Corporation) as softening agent On a base paper of 64 g / m 2 , 80 parts of heavy calcium carbonate as a pigment, 10 parts of secondary kaolin, 10 parts of fine kaolin, 0.05 part of sodium polyacrylate as a dispersant, carboxy-modified styrene butadiene as a binder Add 11 parts of latex and 4 parts of phosphate esterified starch, and then add water to adjust the solid content to 65% so that the coating amount is 14 g / m 2 per side. Double-side coating was performed with a blade coater at a speed of 800 m / min to obtain a coated paper for printing.
[Comparative Example 1]
A base paper with a basis weight of 76 g / m 2 containing 100 parts of chemical pulp as paper pulp and 12 parts of light calcium carbonate as a filler, 80 parts of heavy calcium carbonate as a pigment, 10 parts of secondary kaolin, and fine kaolin 10 parts, 0.05 part of polyacrylic acid soda as a dispersant, 11 parts of carboxy-modified styrene butadiene latex as a binder, 4 parts of phosphate esterified starch, and water were added to adjust the solid content concentration to 65%. The coating liquid was coated on both sides with a blade coater at a coating speed of 800 m / min so that the coating amount was 14 g / m 2 per side to obtain a coated paper for printing.
[Comparative Example 2]
100 parts of chemical pulp as paper pulp, 12 parts of light calcium carbonate as filler, base paper with a basis weight of 103 g / m 2 , 65 parts of heavy calcium carbonate as pigment, 7 parts of secondary kaolin, fine kaolin 28 parts, 0.05 parts of sodium polyacrylate as a dispersant, 9 parts of carboxy-modified styrene butadiene latex as a binder, 2.5 parts of phosphate esterified starch, and water to add a solid content concentration of 64% The coating liquid prepared in the above manner was coated on both sides with a blade coater at a coating speed of 500 m / min so that the coating amount was 13 g / m 2 per side to obtain a coated paper for printing.
[Comparative Example 3]
A base paper having a basis weight of 55 g / m 2 containing 100 parts of chemical pulp as papermaking pulp and 12% of light calcium carbonate as a filler, 95 parts of heavy calcium carbonate as a pigment, 5 parts by weight of secondary kaolin, A coating solution prepared by adding 0.05 part of sodium polyacrylate as a dispersant, 4 parts of carboxy-modified styrene butadiene latex as a binder, 20 parts of phosphate esterified starch, and adjusting the concentration to 40% by adding water, Double-side coating is performed with a film transfer roll coater with a coating speed of 1000 m / min so that the coating amount is 3 g / m 2 per side, and further 80 parts of heavy calcium carbonate and 20 parts of fine kaolin as a pigment. 0.05 parts of polyacrylic acid soda as a dispersant and carboxy-modified styrene butadiene latex as a binder 11 parts, 4 parts of phosphoric acid esterified starch, water was added, and the coating solution adjusted to a solid content concentration of 64% was applied at a coating speed of 11 g / m 2 per side. Double-side coating was performed with a blade coater at 900 m / min to obtain a coated paper for printing.
[Comparative Example 4]
A coated paper for printing was obtained in the same manner as in Comparative Example 3 except that the basis weight of the base paper was 82 g / m 2 .
[Comparative Example 5]
A coated paper for printing was obtained in the same manner as in Example 1 except that the basis weight of the base paper was 40 g / m 2 and the coating amount was 12 g / m 2 per side.

上記条件で製造した印刷用塗被紙において、坪量、密度、抄紙方向のヤング率、および抄紙方向の裂断長を測定し、4者の積を算出した。さらに同用紙について冊子に製本した際のページのめくりやすさの評価と印刷機での作業性についての評価を行い、結果を表1に示した。   The coated paper for printing produced under the above conditions was measured for basis weight, density, Young's modulus in the papermaking direction, and tear length in the papermaking direction, and the product of the four was calculated. Further, the evaluation of the ease of turning pages when the book was bound to a booklet and the workability on a printing press were performed, and the results are shown in Table 1.

Figure 0004987221
表1から明らかなように、坪量、密度、抄紙方向のヤング率、および抄紙方向の裂断長の4者の積の値が1.0×10212・N/m以上4.0×10212・N/m以下の範囲にあれば、原紙、顔料塗被層の組成の違いの有無にかかわらず、柔軟性に優れるためページがめくりやすく、かつ嵩高で、印刷機での作業性も優れる印刷用塗被紙であることが明らかである。
Figure 0004987221
As is clear from Table 1, the value of the four products of basis weight, density, Young's modulus in the paper making direction, and breaking length in the paper making direction is 1.0 × 10 21 g 2 · N / m 6 or more. If it is in the range of 0 × 10 21 g 2 · N / m 6 or less, regardless of the difference in the composition of the base paper and the pigment coating layer, it is excellent in flexibility and the page is easy to turn and bulky. It is clear that the coated paper for printing has excellent workability.

Claims (3)

油脂系非イオン界面活性剤、糖アルコール系非イオン界面活性剤、糖系非イオン界面活性剤、多価アルコール型非イオン界面活性剤、高級アルコール、多価アルコールと脂肪酸のエステル化合物、高級アルコールまたは高級脂肪酸のポリオキシアルキレン化合物、多価アルコールと脂肪酸のエステル化合物のポリオキシアルキレン付加物、脂肪酸ポリアミドアミンのうちの1種以上を使用して得られた原紙上に、顔料と接着剤を含有する塗被層を有する印刷用塗被紙において、密度が1.00g/cm以下、坪量、密度、抄紙方向のヤング率および抄紙方向の裂断長の4者の積が1.0×10212・N/m以上4.0×10212・N/m以下であり、該塗被層が顔料100重量部に対して5〜50重量部の接着剤を含有することを特徴とする印刷用塗被紙。 Oil-based nonionic surfactant, sugar alcohol-based nonionic surfactant, sugar-based nonionic surfactant, polyhydric alcohol-type nonionic surfactant, higher alcohol, ester compound of polyhydric alcohol and fatty acid, higher alcohol or A pigment and an adhesive are contained on a base paper obtained by using at least one of a polyoxyalkylene compound of a higher fatty acid, a polyoxyalkylene adduct of a polyhydric alcohol and a fatty acid ester compound, and a fatty acid polyamidoamine. In a coated paper having a coating layer, the density is 1.00 g / cm 3 or less, the basis weight, the density, the Young's modulus in the paper making direction, and the breaking length in the paper making direction are 1.0 × 10 4 21 g 2 · N / m 6 or more and 4.0 × 10 21 g 2 · N / m 6 or less, and the coating layer contains 5 to 50 parts by weight of the adhesive with respect to 100 parts by weight of the pigment. The Characteristic coated paper for printing. 坪量、密度、抄紙方向のヤング率および抄紙方向の裂断長の4者の積が2.0×10212・N/m以上3.5×10212・N/m以下であることを特徴とする請求項1に記載の印刷用塗被紙。 The product of the basis weight, density, Young's modulus in the paper making direction, and tear length in the paper making direction is 2.0 × 10 21 g 2 · N / m 6 or more and 3.5 × 10 21 g 2 · N / m 6 The coated paper for printing according to claim 1, wherein: 塗被層の塗被量を少なくとも片面当たり9〜25g/m2塗被することを特徴とする請求項1または2に記載の印刷用塗被紙。 The coated paper for printing according to claim 1 or 2, wherein the coating amount of the coating layer is at least 9 to 25 g / m 2 per side.
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