JP4971686B2 - Wrinkle composition and eyelash cosmetics and hair cosmetics using the same - Google Patents

Description

  TECHNICAL FIELD The present invention relates to a cocoon composition, an eyelash cosmetic using the same, and a hair cosmetic, in particular, an cocoon composition containing an amino acid derivative-modified silicone, and an eyelash and hair cosmetic using the same. is there.

  From the viewpoint of moldability and workability, not only cosmetics and quasi-drugs, but also compositions having spinnability have been studied in various fields such as paints and resins. The spinnability is a characteristic that, for example, when the tip of a rod-like object is immersed in the spinnable composition and then lifted upward, it can be stretched to pull the thread. In order to apply this to various uses, a spinnability and an appropriate consistency according to the purpose are required.

For example, eyelash cosmetics can be used as the use of the cocoon composition. This eyelash cosmetic has the effect of clarifying the eyes by making the eyelashes thick and long, and for that purpose, it contains a thread component to give the eyelash a volume and long lash effect. Is planned. Specifically, there is a technique for increasing the volume of eyelashes and making them appear longer by blending high-polymerization polyethylene glycol, which is a water-soluble water-soluble polymer, with cosmetics for eyelashes (for example, Patent Document 1). See).
On the other hand, various techniques have been developed for blending fibers with eyelash cosmetics together with an adhesive film-forming agent and applying the fibers to the eyelashes to increase the volume of the eyelashes (see, for example, Patent Document 2).
Japanese Patent Laid-Open No. 11-79940 Special table 2004-517092 gazette

However, the eyelash cosmetics containing the above-mentioned spinnable water-soluble polymer can provide a certain level of volume, but the spinnability is not sufficient and the long lash effect is not fully satisfactory. Further, if the blending amount is increased in order to improve the effect, the transparency is lowered due to the poor compatibility with other oil components, and as a result, the aesthetic effect becomes inferior. .
Although the long lash effect is high, the cosmetics for eyelashes with fibers have an unnatural finish when the fibers are excessively applied to the eyelashes, and a glossy appearance is obtained due to light scattering by the fibers. Absent. Further, when the coating agent is too hard, the fibers may fall into powder under the eyes.
The present invention has been made in view of the above-mentioned circumstances, and the purpose thereof is a stringent composition excellent in transparency, and when it is used in eyelash cosmetics, it is not necessary to add fibers. When used in eyelash cosmetics, which have an excellent effect of making eyelashes look long and can give a natural finish, and when used in hair cosmetics, the hair can be set freely. The object is to provide a cosmetic for hair that is difficult to break.

（式中、Ｒ^１およびＲ^２は互いに同一でも異なっても良く、下記式（IV）で表される基を表し、xは１〜９００の整数を表す。）

（式中、Ｒ^３は炭素数２〜３０のアルキル基を表し、nおよびmは１〜２０の整数を表す。）

（式中、Ｒは水素原子または[（ＣＨ_３）_３ＳｉＯ] _３Ｓｉ（ＣＨ_２）_３ＮＨＣＯ基を意味する。） In order to achieve the above object, as a result of intensive studies by the present inventors, a spinnable crude composition having excellent transparency can be obtained in a composition containing a specific lysine derivative-modified silicone and a silicone-modified pullulan. And when it was used for cosmetics for eyelashes, it discovered that it was excellent in a long rush effect and a natural finish feeling, and came to complete this invention.
That is, the spinnable composition of the present invention is
(A) a lysine derivative-modified silicone represented by any one of the following general formulas (I) to (III);
(B) It contains siliconized pullulan represented by the following general formula (V).

(In the formula, R ¹ and R ² may be the same or different, represents a group represented by the following formula (IV), x represents an integer of from 1 to 900.)

(In the formula, R ³ represents an alkyl group having 2 to 30 carbon atoms, and n and m represent an integer of 1 to 20).

(In the formula, R means a hydrogen atom or a [(CH ₃ ) ₃ SiO] ₃ Si (CH ₂ ) ₃ NHCO group.)

  In the spinnable composition according to the present invention, (a) a lysine derivative-modified silicone represented by any one of the general formulas (I) to (III) and (b) represented by the general formula (V). It is preferable that the blending ratio ((a) / (b)) of the siliconized pullulan is 2/5 to 2/1.

The spinnable composition according to the present invention further includes (c) an oil component.
In addition, it is preferable that 20% by mass or more of the total weight of the (c) oil is silicone oil.

Moreover, this invention provides the cosmetics for eyelashes using the said spinnable composition.
Moreover, this invention provides the cosmetics for hair using the said spinnable composition.

  According to the present invention, in a spine composition containing a specific lysine derivative-modified silicone and a specific silicone-modified pullulan, the fiber composition has extremely excellent transparency, and when used in cosmetics for eyelashes, It is excellent in the effect of making the eyelashes look long without blending, and the cosmetics for eyelashes that can give a natural feeling of finish, and the hair makeup that can set the hair in a free shape and the hairstyle is difficult to break You can get a fee.

Hereinafter, embodiments of the present invention will be described in detail. The present invention is not limited thereby.
“Spinnability” in the spinnable composition according to the present invention means that the rod-like object can be stretched so as to pull the thread when it is lifted upward after being dipped in the spinnable composition. It is a characteristic and shall be visually confirmed.

（式中、Ｒ^１およびＲ^２は互いに同一でも異なっても良く、下記式（IV）で表される基を表し、xは１〜９００の整数を表す。）

（式中、Ｒ^３は炭素数２〜３０のアルキル基を表し、nおよびmは１〜２０の整数を表す。） (A) Lysine derivative-modified silicone The lysine derivative-modified silicone in the present invention is represented by any one of the following general formulas (I) to (III).

(In the formula, R ¹ and R ² may be the same or different, represents a group represented by the following formula (IV), x represents an integer of from 1 to 900.)

(In the formula, R ³ represents an alkyl group having 2 to 30 carbon atoms, and n and m represent an integer of 1 to 20).

Among the above compounds, particularly preferable compounds are compounds in which x is 50 to 200, n and m are 10, and R ³ is an ethyl group or an isobutyl group in the structures of the general formulas (I) and (II).
Specifically, it is a compound having a structure represented by the following formulas (VI) to (IX).

  When the spinnable composition according to the present invention is used in eyelash cosmetics or hair cosmetics, a suitable blending amount (actual amount) of lysine derivative-modified silicones represented by the above general formulas (I) to (III) Is 1 to 20% by mass, more preferably 3 to 10% by mass in the whole cosmetic. If the blending amount is less than 1% by mass, sufficient spinnability may not be obtained. On the other hand, if it exceeds 20% by mass, the spread may be poor and the natural finish may be inferior.

（式中、Ｒは水素原子または[（ＣＨ_３）_３ＳｉＯ] _３Ｓｉ（ＣＨ_２）_３ＮＨＣＯ基を意味する。）
本発明にかかる曳糸性組成物において、上記シリコーン化プルランは、公知の製法により製造したものを用いることができる（例えば、特開平１０−２９９１０号公報）。 (B) Siliconized pullulan The siliconeized pullulan contained in the spinnable composition according to the present invention is represented by the following general formula (V).

(In the formula, R means a hydrogen atom or a [(CH ₃ ) ₃ SiO] ₃ Si (CH ₂ ) ₃ NHCO group.)
In the spinnable composition according to the present invention, the siliconized pullulan can be produced by a known production method (for example, JP-A-10-29910).

  When using the cocoon composition according to the present invention for eyelash cosmetics or hair cosmetics, the preferred blending amount (actual amount) of the above siliconeized pullulan is preferably 1 to 20% by mass, more preferably the whole cosmetics. Is 3-10 mass%. If the blending amount is less than 1% by mass, sufficient spinnability may not be obtained. On the other hand, if it exceeds 20% by mass, the spread may be poor and the natural finish may be inferior.

  Furthermore, in the spinnable composition according to the present invention, the blending ratio ((a) / (b)) of (a) lysine derivative-modified silicone and (b) siliconeized pullulan is 2/5 to 2/1. Preferably there is. When the blending ratio is such, the spinnability having an appropriate consistency in the spinnable composition and excellent transparency can be obtained. In addition, when the cocoon composition is used in a cosmetic for eyelashes, it has a good stretch and an excellent long lash effect.

(C) Oil content Oils used in the present invention include oils that are liquid at room temperature such as silicone oils, hydrocarbon oils, ester oils, fatty acids, higher alcohols, waxes, waxes, fluorinated oils and fats, animal and vegetable oils, and room temperature. Solid and semi-solid oils are used as appropriate. Specifically, silicone oil such as methylpolysiloxane and methylphenylpolysiloxane, hydrocarbon oil such as liquid paraffin, isoparaffin, squalane and squalene, isopropyl myristate, 2-octyldecyl myristate, 2-octyldecyl myristate, Such as cetyl 2-ethylhexanoate, 2-ethylhexyl 2-ethylhexanoate, isononyl 2-ethylhexanoate, 2-ethylhexyl palmitate, 2-hexyldecyl stearate, ethyl isostearate, isopropyl isostearate, 2-ethylhexyl salicylate, etc. Examples thereof include waxes such as ester oil, paraffin wax, polyethylene wax and microcrystalline wax, and fats and oils such as olive oil, camellia oil, macadamia nut oil and castor oil.
In the present invention, one or more of the above oils may be used.
When the oil component is blended in the spinnable composition according to the present invention, the preferred blending amount is 60% by mass or more. When the blending amount is less than 60% by mass, an appropriate consistency, that is, the spinnability cannot be maintained, which is not preferable in the present invention.

Furthermore, it is preferable that silicone oil accounts for 20% by mass or more of the total weight of the oil. Including a silicone oil is preferable because the spinnable composition containing the component (a) lysine derivative-modified silicone and (b) siliconeized pullulan has good compatibility with the oil. Further, when the cocoon composition is used in a cosmetic for eyelashes, if it is a volatile silicone oil, the liquidity is lowered by the volatilization of most of the oil after being applied to the eyelashes, resulting in a long lash. This is preferable because the effect is maintained for a long time.
In addition, the “total weight of oil” as used herein refers to the total weight of oil in the spinnable composition, or the total weight of oil in the eyelash cosmetics and hair cosmetics using the spinnable composition. Means that.

  Here, “volatile” means a component having a boiling point in the range of 60 to 260 ° C. at normal pressure. Examples of the volatile silicone oil used in the present invention include linear polysiloxanes such as dimethylpolysiloxane, methylphenylpolysiloxane, and methylhydrogenpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and dodecamethyl. And cyclic polysiloxanes such as cyclohexasiloxane and tetramethyltetrahydrogencyclotetrasiloxane. Moreover, if these product examples are given, for example, KF96L-0.65, KF96L-1, KF96L-1.5, KF995 (Shin-Etsu Chemical Co., Ltd.), SH200-1cs, SH200-1.5cs, SH200-2cs (Toray Dow Corning Silicone), TSF404, TSF405, TSF4045 (Toshiba Silicone) and the like.

In the present invention, the above-described threadable composition can be used in eyelash cosmetics and hair cosmetics. In particular, when used in eyelash cosmetics, the effect of making eyelashes appear long and thick without adding fibers to the cosmetics is excellent. Taking advantage of the properties of the spinnable composition, a natural finish with excellent transparency can be obtained.
Further, when used in hair cosmetics, it is possible to give the hair “luster” and “freshness” and to obtain the smooth and waist-like hair-styling property of the spinnable composition according to the present invention.
The spinnable composition according to the present invention can be used as a thickener for various products such as paints and surface treatment agents in addition to the cosmetics.

  It is possible to mix | blend a coloring material with the eyelash cosmetics and hair cosmetics concerning this invention. The color material is not particularly limited as long as it is generally used for makeup cosmetics. For example, talc, mica, kaolin, silica, calcium carbonate, zinc white, titanium dioxide, red iron oxide, yellow iron oxide, black iron oxide, ultramarine, bitumen, carbon black, low-order titanium oxide, cobalt violet, chromium oxide, hydroxide Inorganic pigments such as chromium, cobalt titanate, bismuth oxychloride, titanium-mica pearl pigments; red 201, red 202, red 204, red 205, red 220, red 226, red 228, red Organic pigments such as zirconium, barium or aluminum lakes such as 405, orange 203, yellow 205, yellow 4, yellow 5, blue 1, blue 404, green 3, etc .; chlorophyll, β-carotene, etc. Natural pigments; dyes and the like. These color materials can be used alone or in combination of two or more.

  The blending amount of the color material is adjusted as appropriate. Preferably it is 0.1-30 mass%, More preferably, it is 3-20 mass%. When it exceeds 30 mass%, it is not preferable in terms of adhesion. If it is less than 0.1% by mass, the effect of the coloring material may be insufficient.

  Moreover, you may mix | blend film forming resin other than the said essential component with the eyelash cosmetics and hair cosmetics concerning this invention. Specifically, latexes such as polyvinyl alcohol, polyvinyl pyrrolidone, polyvinyl acetate, and polyalkyl acrylate, dextrin, cellulose derivatives such as alkyl cellulose and nitrocellulose, trimethylsiloxysilicic acid, and the like are used. One or more of these resins are selected and used.

Moreover, you may mix | blend polysaccharides and water-soluble polymers other than the said essential component with the eyelash cosmetics and hair cosmetics concerning this invention. Examples of the water-soluble polymer include polysaccharides, water-soluble natural polymers, semi-synthetic polymers, and inorganic polymers.
Specifically, as polysaccharides, cellulose, starch, glycogen, hyaluronic acid, chondroitin, guar gum, locust bin gum, quince seed, galactan, gum arabic, tragacanth gum, xanthan gum, dextran, succinoglucan, chondroitin sulfate, mucoitin sulfate, etc. Is mentioned.

Examples of water-soluble natural polymers include plant polymers such as carrageenan, glycyrrhizic acid, carob gum, pectin, karaya gum, and alge colloid (casso extract), microbial polymers such as dextran and bullulan, and animal polymers such as collagen and albumin. Etc.
Water-soluble semi-synthetic polymers include starch systems such as carboxymethyl starch and methylhydroxypropyl starch, methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, crystalline cellulose, methylhydroxypropylcellulose, cellulose sulfate Na, carboxymethylsesulose Examples thereof include celluloses such as Na (CMC) and cellulose powder, and alginic acids such as sodium alginate and propylene glycol alginate.
Examples of water-soluble synthetic polymers include polyvinyl alcohol, polyvinyl pyrrolidone, carboxy vinyl polymer, vinyl type such as polyvinyl methyl ether, polyoxyethylene type such as polyethylene glycol, copolymer such as polyoxyethylene / polyoxypropylene copolymer, etc. And acrylics such as poly (sodium acrylate), polyacrylamide and polyethyl acrylate, polyethyleneimine, and cationic polymers.
Examples of the water-soluble inorganic polymer include bentonite, laponite, and silicic anhydride. One or two or more of these polysaccharides and water-soluble polymers are selected and used.

In addition to the above components, the eyelash cosmetic and hair cosmetic according to the present invention can be blended with components that are usually used in cosmetics, quasi-drugs and the like within a range that does not impair the effects of the present invention. . Examples of such components include humectants, dispersants, preservatives, fragrances, drugs, ultraviolet absorbers, thickeners, and the like.
The form of the eyelash cosmetic and the hair cosmetic according to the present invention preferably takes a W / O emulsified or oily form, but is not limited thereto.
Hereinafter, the present invention will be described in more detail with reference to examples. The present invention is not limited to these examples. Unless otherwise specified, the blending amount indicates mass%.

で表されるＳｉ−Ｈ化合物９２．６ｇと１０−ウンデセノイルイソシアネート７．４ｇをトルエン１００ｇに加え、８５℃に加温した後、白金ジビニルテトラメチルジシロキサン錯体トルエン溶液（白金濃度０．３質量％）０．３３ｇを加え、３時間撹拌したートルエンと余剰のイソシアネート化合物を減圧留去した後、新たにトルエン１０００ｇとＮ^ε−ラウロイル−Ｌ−リジンイソブチルエステル１０．５ｇを加え、９０℃で６時間撹拌したートルエンを留去後、得られた透明ゴム状固体をヘキサン１０００ｇに加熱溶解させ、熱ろ過した。ろ液からヘキサンを留去後、固体を得た。
次に得られた固体を細かく砕き、２５℃のヘキサンでよく洗いながら吸引ろ過を行った後、減圧乾燥することで上記式（VI）で表される粉末状のリジン誘導体変成シリコーン（Ｎ^ε−ラウロイル−Ｌ−リジンイソブチルエステル誘導体変性シリコーン）２０．３ｇを得た。 [Production Example 1] N ^epsilon - lauroyl -L- lysine isobutyl ester derivative-modified silicone (1) 20.1 g of N ^epsilon - lauroyl -L- lysine in 205ml ethanol - were suspended in Le. After cooling the reaction solution with ice, dry hydrogen chloride gas was introduced until saturation, and the mixture was stirred for 6 hours.
Next, ethanol was distilled off, 250 ml of diisobutyl ether was added, and after suction filtration, 300 ml of purified water was added. To this solution, 55 g of morpholine dissolved in 70 ml of purified water was slowly added with stirring, and the precipitated white powder was filtered off. The obtained white powder was recrystallized from n-hexane to obtain 20.1 g of N ^ε -lauroyl-L-lysine isobutyl ester.
(2) 150 g of purified water was added to 45.5 g of sodium azide, and the mixture was stirred to obtain a completely homogeneous solution while cooling in ice water. A solution obtained by mixing 101.4 g of 10-undecenoyl chloride and 150 ml of acetone was added dropwise little by little so that the temperature of the solution was in the range of 10 to 15 ° C. After completion of the addition, the mixture was stirred at around 12 ° C. for 1 hour.
The solution was then transferred to a separatory funnel and the aqueous and organic layers were separated. The organic layer was slowly added to 500 ml of toluene maintained at 60 ° C., and stirred for 3 hours at a temperature in the range of 50 to 60 ° C. After distilling off the toluene and distilling under reduced pressure, 73.2 g of 10-undecenoyl isocyanate Got.
(3) The following formula

After adding 92.6 g of the Si—H compound represented by the following formula and 7.4 g of 10-undecenoyl isocyanate to 100 g of toluene and heating to 85 ° C., a platinum divinyltetramethyldisiloxane complex toluene solution (platinum concentration of 0.3 (Mass%) 0.33 g was added and stirred for 3 hours--toluene and excess isocyanate compound were distilled off under reduced pressure, and then 1000 g of toluene and 10.5 g of N ^ε -lauroyl-L-lysine isobutyl ester were newly added at 90 ° C. Stir for 6 hours--Toluene was distilled off, and the resulting transparent rubber-like solid was heated and dissolved in 1000 g of hexane and filtered hot. After removing hexane from the filtrate, a solid was obtained.
Next, the obtained solid is finely pulverized, suction filtered while thoroughly washing with hexane at 25 ° C., and then dried under reduced pressure, whereby powdered lysine derivative-modified silicone (N ^ε −) represented by the above formula (VI) is obtained. 20.3 g of lauroyl-L-lysine isobutyl ester derivative-modified silicone) was obtained.

Subsequently, the present inventors synthesized various lysine derivative-modified silicones according to the above synthesis examples, and evaluated the spinnable composition containing the lysine derivative-modified silicones. The blending composition and evaluation results of the spinnable composition of each test example are also shown below.
As component (b), silicone-treated pullulan (3- [tris (trimethylsiloxane) silyl] propylcarbadoic acid pullulan mixture, trade name: TSPL-30-D5, manufactured by Shin-Etsu Chemical Co., Ltd. 3- [tris (trimethylsiloxane) Containing 30% silyl] propylcarbadoic acid pullulan mixture). Further, decamethylcyclopentasiloxane, dimethylpolysiloxane, and isonononyl isononanoate were used as the component (c).

The evaluation criteria are as follows.
(1) Sensory evaluation: Spinnability 1 g of each sample containing the above components was applied to the back of the hand that had been washed with soap beforehand, and the fingernail when the finger was pulled upward after pressing the finger against the sample It was evaluated by visual observation of (20 persons). The evaluation criteria are 3 points if you feel very well, 2 points if you feel moderately stretched, 1 point if you feel slightly stretched, and 0 points if you feel you are not stretched. Was calculated.
A: The total score is 46 or more.
A: The total score is 36 to 45 points.
Δ: Total score of 26 to 35 points.
X: A total score is 25 or less.

(2) Sensory evaluation: Transparency The sample was poured into a transparent resin container so as to have a thickness of 5 mm, and the clearness of the characters of Times New Roman font 88 placed under the container at 25 ° C. ).
5 points: The characters look very clear and the sharpness is very high.
4 points: Characters are clearly visible and sharpness is high.
3 points: Characters can be seen, but sharpness is slightly inferior.
2 points: Characters are barely visible, but inferior in clarity.
1 point: Characters cannot be read and are opaque.
These total points were calculated.
A: The total score is 91 points or more.
A: The total score is 71 to 90 points.
(Triangle | delta): A total score is 41-70 points.
X: The total score is 40 or less.

The following items were also evaluated for the eyelash cosmetics using the cocoon composition according to the present invention.
(3) Application property A special panel (20 persons) performed sensory evaluation on the ease of application of mascara when each sample (mascara) was applied to the eyelashes. The evaluation criteria are 3 points if you feel that it is very easy to apply, 2 points if you feel it is easy to apply moderately, 1 point if you feel that it is difficult to apply, When it felt, it was set as 0 points, and the total score was calculated.
○: The total score is 41 points or more.
(Triangle | delta): A total score is 26-40 points.
X: A total score is 25 or less.

(4) Long lash effect Each sample (mascara) was applied 10 times to the eyelashes by a professional panel (20 persons), and the length of the eyelashes before and after the application was visually observed to evaluate the long lash effect with a sense. The evaluation criteria are 3 points when the eyelashes feel extremely long, 2 points when it feels moderately long, 1 point when it feels slightly longer, no change from before application In this case, the score was 0, and the total score was calculated.
○: The total score is 41 points or more.
(Triangle | delta): A total score is 26-40 points.
X: A total score is 25 or less.

(5) Natural finish feeling Each sample (mascara) was applied 10 times to the eyelashes by a professional panel (20 persons), and the natural finish feeling was visually evaluated. The evaluation criteria are 3 points if you feel that there is an excellent natural finish, 2 points if you feel that the finish is moderate, and 1 point if you feel that the finish is not very natural. When it was felt that the finish was extremely unnatural, the score was 0, and the total score was calculated.
○: The total score is 41 points or more.
(Triangle | delta): A total score is 26-40 points.
X: A total score is 25 or less.

<Types of lysine derivative-modified silicone>
In order to examine the suitability of lysine derivative-modified silicones, the following various lysine derivative-modified silicones were synthesized in accordance with the above-mentioned Production Example 1, and compositions containing them were evaluated. The results are shown in Table 1 below.
Structure of synthetic lysine derivative-modified silicone

※１：商品名 レオパールＫＬ、千葉製粉株式会社製
（製法）上記成分（１）〜（９）を９０℃に加熱し、攪拌混合した後冷却し、各々の試料を得た。

* 1: Product name Leopard KL, manufactured by Chiba Flour Milling Co., Ltd. (Production Method) The above components (1) to (9) were heated to 90 ° C., stirred and cooled, and each sample was obtained.

As is clear from the results in Table 1 above, compositions having excellent spinnability and transparency were obtained in Test Examples 1 to 4 in which various lysine derivative-modified silicones were combined with silicone-modified pullulan.
On the other hand, if the siliconeized pullulan was not blended as in Test Example 5, the desired spinnability could not be obtained, and the composition was a hard gel. Moreover, when it replaced with the lysine derivative modified silicone and the palmitic acid dextrin which is a thickener was mix | blended (Test Example 6), it became a somewhat viscous gel and lacked transparency.
Next, the composition which combined the lysine derivative modified silicone and the conventional oil-based film formation agent was evaluated. The results are shown in Table 2 below.

（製法）上記成分（１）〜（８）を９０℃に加熱し、攪拌混合した後冷却し、各々の試料を得た。

(Production Method) The above components (1) to (8) were heated to 90 ° C., stirred and mixed, and then cooled to obtain respective samples.

  As is clear from the results of Table 2 above, in Test Examples 7 to 9 in which a lysine derivative-modified silicone and a conventional oily film forming agent are combined, the transparency is inferior and the desired spinnability is sufficient. Instead, a hard gel was formed. In Test Example 10 in which aluminum isostearate, which is an oil-based film agent having spinnability, was mixed with an oil component, there was spinnability, but the silky yarn excellent in transparency seen in the spinnable composition according to the present invention Unlike sex, it was somewhat sticky. In addition, coexistence with ester oil, which is a polar oil component, may lead to a decrease in stability due to the destruction of the gel structure of aluminum isostearate. There is a drawback of being.

（製法）上記成分（１）〜（４）を９０℃に加熱し、攪拌混合した後冷却し、各々の試料を得た。 From the above results, the present inventors found extremely excellent spinnability and transparency in the combination of lysine derivative-modified silicone and silicone-modified pullulan, and conducted studies on suitable blending ratios of the above two components. . The results are shown in Table 3 below.
<Combination ratio of lysine derivative-modified silicone and siliconized pullulan>

(Production Method) The above components (1) to (4) were heated to 90 ° C., stirred and mixed, and then cooled to obtain respective samples.

As is apparent from Table 3 above, the blending amount of 3- (tris (trimethylsiloxane) silyl] propylcarbadoic acid pullulan mixture which is one of (a) lysine derivative-modified silicone (VI) and (b) siliconeized pullulan It can be seen that the spinnability of the spinnable composition is excellent when the ratio is 2/5 to 2/1. Test Example 1 1 outside this range, moderate spinnability sieved not have sufficient formability for the very extremely high fluidity, whereas Test Example 1 5 too hard the viscosity, such as pulling the yarn It lacked a smooth feel.
Next, various components to be blended together in the eyelash cosmetic using the spinnable composition according to the present invention were examined. First, Table 4 below shows the results of studying suitable blending amounts of component (a) lysine derivative-modified silicone.

※２：商品名 シリコーンＫＦ６０１７、信越化学工業株式会社製
※３：商品名 エマレックスＲＷＩＳ−３２０、日本エマルジョン株式会社製
（製法）成分（１）、（２）を含む油相部を９０℃に加熱し攪拌して均一にする。水相部も９０℃に加熱し、前記油相部に添加して乳化した後、室温まで冷却して各試料を得た。 <Preferred blending amount of (a) lysine derivative-modified silicone>

* 2: Product name Silicone KF6017, manufactured by Shin-Etsu Chemical Co., Ltd. * 3: Product name Emalex RWIS-320, Nippon Emulsion Co., Ltd. (Production) Components (1), (2) containing oil phase part at 90 ° C Heat and stir to homogenize. The aqueous phase was also heated to 90 ° C., added to the oil phase and emulsified, and then cooled to room temperature to obtain each sample.

As apparent from Table 4 above, in Test Example 16, since the blending amount of the lysine derivative-modified silicone is as small as 1% by mass, the viscosity is high and it is difficult to apply to the eyelashes. It also lacks a natural finish. Furthermore, since Test Example 20 contained a large amount of lysine derivative-modified silicone, it became a hard gel and was unsuitable as a cosmetic for eyelashes.
From the above results, it can be seen that when the spinnable composition according to the present invention is used in a cosmetic for eyelashes, the preferred amount of component (a) lysine derivative-modified silicone is 3 to 10% by mass. .
Then, the suitable compounding quantity of the component (b) silicone-ized pullulan in the cosmetics for eyelashes using the spinnable composition concerning this invention was examined. The results are shown in Table 5 below.

（製法）上記成分（１）〜（１０）を９０℃に加熱し、攪拌混合した後冷却し、各々の試料を得た。 <Preferred blending amount of (b) siliconeized pullulan>

(Production Method) The above components (1) to (10) were heated to 90 ° C., stirred and mixed, and then cooled to obtain respective samples.

As is apparent from Table 5 above, in Test Example 21, since the blended amount of siliconeized pullulan is as small as 1% by mass, a spinnable composition cannot be obtained, and no long lash effect is observed when applied to eyelashes. . Furthermore, since Test Example 25 has a lot of siliconeized pullulan, it has a high viscosity and is difficult to apply to eyelashes, and was unsuitable as a cosmetic for eyelashes.
From the above results, it can be seen that when the spinnable composition according to the present invention is used in a cosmetic for eyelashes, the preferred amount of component (b) siliconeized pullulan is 3 to 10% by mass.
Next, the oil content in the eyelash cosmetic using the spinnable composition according to the present invention was examined. The results are shown in Table 6 below.

※４：特開２００５−３４４０７６ 実施例７の化合物
（製法）上記成分（１）〜（１２）を９０℃に加熱し、攪拌混合した後冷却し、各々の試料を得た。 <Oil content>

* 4: Japanese Unexamined Patent Application Publication No. 2005-344076 Compound of Example 7 (Production Method) The above components (1) to (12) were heated to 90 ° C., mixed with stirring, and then cooled to obtain respective samples.

As is apparent from the results in Table 6 above, if the volatile silicone oil is not blended as an oil component in the eyelash cosmetic according to the present invention, the transparent natural finish is lacking. In addition, after the application to the eyelashes, the cosmetic material was not sufficiently solidified, and when the eyelashes were rubbed, there was a problem in terms of durability.
Even when volatile silicone oil is blended, if the proportion of volatile silicone oil in the total oil content is low (Test Example 30), there was a slight problem in terms of makeup removal as described above.
From the above results, the eyelash cosmetic using the spinnable composition according to the present invention preferably contains volatile silicone oil as the oil, and the volatile silicone oil accounts for 60% or more in the total amount of oil. It is clear that this is more preferable.
Furthermore, the present inventors compared and examined the eyelash cosmetic according to the present invention and the eyelash cosmetic conventionally blended with fibers for a long lash effect. The results are shown in Table 7 below.

（製法）上記成分（１）〜（１１）を９０℃に加熱し、攪拌混合した後冷却し、各々の試料を得た。

(Production Method) The above components (1) to (11) were heated to 90 ° C., stirred and mixed, and then cooled to obtain respective samples.

As is apparent from the results in Table 7 above, it can be seen that the eyelash cosmetic according to the present invention is excellent in the long lash effect without blending fibers. In Test Example 32 in which fibers were blended, the natural feeling of finish and applicability were poor. In addition, when a fiber-blended cosmetic is applied, there is a problem that with the passage of time, the stains under the eyes are worrisome due to fiber dropping and the possibility of entering into the eyes is feared.
From the above results, the eyelash cosmetics using the cocoon composition according to the present invention are excellent in the effect of making the eyelashes look long without blending fibers, and have good applicability and a natural finish. Is clear.

EXAMPLES Hereinafter, although the Example of the cosmetics using the spinnable composition concerning this invention is given and this invention is demonstrated further in detail, this invention is not limited to these.
Example 3-1 W / O mascara (1) Lysine derivative-modified silicone (VII) 6.0% by mass
(2) 3- [Tris (trimethylsiloxane) silyl] 6.0
Propylcarbadoic acid pullulan mixture (3) Dimethylpolysiloxane (6 mPa · s)
(4) Decamethylcyclopentasiloxane 10.0
(5) Light isoparaffin 7.0
(6) Trimethylsiloxysilicic acid 10.0
(7) Methyl polysiloxane emulsion appropriate amount (Brand name: BY22-080 cosmetic emulsion, manufactured by Toray Dow Corning Co., Ltd.)
(8) Polyethylene glycol dioleate 2.0
(9) Diglyceryl diisostearate 2.0
(10) 1,3-butylene glycol 4.0
(11) Sodium bicarbonate 0.2
(12) DL-α-tocopherol acetate 0.1
(13) Paraoxybenzoic acid ester appropriate amount (14) sodium dehydroacetate appropriate amount (15) black iron oxide 7.0
(16) Seaweed extract 0.1
(17) Bentonite 1.0
(18) Dimethyl distearyl ammonium hectorite 6.0
(19) Polyvinyl acetate emulsion 30.0
(Product name: Viniblanc S-40, manufactured by Nissin Chemical Industry Co., Ltd.)
(20) Purified water The oil phase portion containing the remainder (manufacturing method) (manufacturing method) components (1) and (2) is heated to 90 ° C. and stirred to make it uniform. The aqueous phase was also heated to 90 ° C., added to the oil phase and emulsified, then cooled to room temperature and filled into a mascara container.

（８）ヒマシ油 ２．０
（９）キャンデリラロウ ５．０
（１０）イソステアリン酸 ３．０
（１１）オレイン酸 １．０
（１２）トリ２−エチルヘキサン酸グリセリル ２．０
（１３）ムクロジエキス ０．１
（１３）カラスムギエキス ０．１
（１４）テトラデセン ０．１
（１５）ポリエチレン ５．０
（１６）マイクロクリスタリンワックス ５．０
（製法）上記成分（１）〜（１６）を９０℃に加熱し、攪拌混合した後冷却し、マスカラ容器に充填した。 Example 3-2: Oily mascara (1) Lysine derivative-modified silicone (VII) 5.0 mass%
(2) 3- [Tris (trimethylsiloxane) silyl] 5.0
Propylcarbadoic acid pullulan mixture (3) methyl hydrogen polysiloxane 1.0
(4) Decamethylcyclopentasiloxane 40.0
(5) Light isoparaffin remaining amount (6) Trimethylsiloxysilicic acid 15.0
(7) Poly (oxyethylene / oxypropylene)
Methylpolysiloxane copolymer 2.0
(In the following general formula (1), m = 400, n = 10, x = 3, y = 19, z = 19, R ⁸ = H having a molecular weight of about 55,000.)

(8) Castor oil 2.0
(9) Candelilla wax 5.0
(10) Isostearic acid 3.0
(11) Oleic acid 1.0
(12) Glyceryl tri-2-ethylhexanoate 2.0
(13) Mukuroji extract 0.1
(13) Oat extract 0.1
(14) Tetradecene 0.1
(15) Polyethylene 5.0
(16) Microcrystalline wax 5.0
(Production Method) The above components (1) to (16) were heated to 90 ° C., stirred and mixed, cooled, and filled into a mascara container.

Example 3-3: Hair cosmetic (hair wax)
(1) Lysine derivative-modified silicone (VII) 5.0 mass%
(2) 3- [Tris (trimethylsiloxane) silyl] 5.0
Propylcarbadoic acid pullulan mixture (3) Dimethylpolysiloxane (6 mPa · s) 10.0
(4) Methylphenylpolysiloxane 5.0
(5) Highly polymerized methylpolysiloxane 10.0
(6) Polyoxypropylene (40) Butyl ether Residue (7) White beeswax 10.0
(8) Mowl 5.0
(9) Carnauba wax 1.0
(10) Lipophilic glyceryl monostearate 8.0
(11) Self-emulsifying glyceryl monostearate 10.0
(12) Fragrance Appropriate amount (Manufacturing method) The above components (1) to (12) were heated to 90 ° C., stirred and mixed, and then cooled to obtain the desired cosmetic for hair.

Claims (3)

(A) a lysine derivative-modified silicone represented by any one of the following general formulas (I) to (III);
(B) a siliconized pullulan represented by the following general formula (V) :
(C) contains an oil component ,
The blending amounts of (a) and (b) are 3 to 10% by mass,
The ratio of the blending amount of (a) to (b) ((a) / (b)) is 2/5 to 2/1,
(C) 20% by mass or more of the total weight of the oil is silicone oil,
A spinnable composition characterized by the above.

(In the formula, R ¹ and R ² may be the same or different, represents a group represented by the following formula (IV), x represents an integer of from 1 to 900.)

(In the formula, R ³ represents an alkyl group having 2 to 30 carbon atoms, and n and m represent an integer of 1 to 20).

(In the formula, R means a hydrogen atom or a [(CH ₃ ) ₃ SiO] ₃ Si (CH ₂ ) ₃ NHCO group.) A cosmetic for eyelashes containing the spinnable composition according to claim 1 as a base. A cosmetic for hair containing the spinnable composition according to claim 1 as a base.