JP4960197B2 - Ips液晶パネルおよびips液晶表示装置 - Google Patents
Ips液晶パネルおよびips液晶表示装置 Download PDFInfo
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- JP4960197B2 JP4960197B2 JP2007281913A JP2007281913A JP4960197B2 JP 4960197 B2 JP4960197 B2 JP 4960197B2 JP 2007281913 A JP2007281913 A JP 2007281913A JP 2007281913 A JP2007281913 A JP 2007281913A JP 4960197 B2 JP4960197 B2 JP 4960197B2
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- JP
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- Prior art keywords
- liquid crystal
- polarizing plate
- transparent protective
- protective film
- meth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
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- ADFPJHOAARPYLP-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;styrene Chemical compound COC(=O)C(C)=C.C=CC1=CC=CC=C1 ADFPJHOAARPYLP-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
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- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- JTHNLKXLWOXOQK-UHFFFAOYSA-N n-propyl vinyl ketone Natural products CCCC(=O)C=C JTHNLKXLWOXOQK-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 125000002560 nitrile group Chemical group 0.000 description 1
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- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 1
- 125000003518 norbornenyl group Chemical group C12(C=CC(CC1)C2)* 0.000 description 1
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- 229960000969 phenyl salicylate Drugs 0.000 description 1
- LYKRPDCJKSXAHS-UHFFFAOYSA-N phenyl-(2,3,4,5-tetrahydroxyphenyl)methanone Chemical compound OC1=C(O)C(O)=CC(C(=O)C=2C=CC=CC=2)=C1O LYKRPDCJKSXAHS-UHFFFAOYSA-N 0.000 description 1
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- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Polarising Elements (AREA)
- Liquid Crystal (AREA)
Description
前記第1偏光板および第2偏光板は、いずれも、偏光子の両面に接着剤層を介して透明保護フィルムが積層されており、
前記第1偏光板および第2偏光板における、液晶セル側に配置される透明保護フィルムは、当該透明保護フィルムの面内屈折率が最大となる方向をX軸、X軸に垂直な方向をY軸、フィルムの厚さ方向をZ軸とし、それぞれの軸方向の波長590nmにおける屈折率をnx、ny、nz、フィルムの厚さd(nm)として、
面内位相差:Re=(nx−ny)×d、
厚み方向位相差:Rth=(nx−nz)×d、をそれぞれ定義した場合に、
いずれも、面内位相差が10nm以下であり、かつ、前記液晶セル側に配置される透明保護フィルムの厚み方向位相差は、それぞれの絶対値の和が10〜40nmであり、かつ、
前記第1偏光板および第2偏光板における、液晶セル側に配置される透明保護フィルムは、いずれか少なくとも一方が、ラクトン環構造を有する(メタ)アクリル系樹脂を含有してなることを特徴とする特徴とするIPS液晶パネル、に関する。
透明保護フィルムの波長590nmにおける屈折率nx、ny、nzを、平行ニコル回転法を原理とする自動複屈折測定装置(王子計測機器株式会社製,自動複屈折計KOBRA21ADH)により計測し、面内位相差Re、厚み方向位相差Rthを算出した。
調製した接着剤水溶液(常温:23℃)を、レオメーター(RSI‐HS,HAAKE社製)により測定した。
アルミナコロイド水溶液を粒度分布計(日機装社製,ナノトラックUPA150)により、動的光散乱法(光相関法)で測定した。
厚み75μmのポリビニルアルコールを主成分とする高分子フィルム[クラレ(株)製商品名「9P75R」](平均重合度2400、けん化度99.9モル%)を30±3℃に保持したヨウ素とヨウ化カリウム配合の染色浴にて、ロール延伸機を用いて、染色しながら2.5倍に一軸延伸した。次いで、60±3℃に保持したホウ酸とヨウ化カリウム配合の水溶液浴中で、架橋反応を行いながら、ポリビニルアルコールフィルムの元長の6倍となるように一軸延伸した。得られたフィルムを50±1℃の空気循環式恒温オーブン内で30分間乾燥させて、水分率26%、厚み28μmの偏光子を得た。
以下に示すものを用いた。
TACフィルム:厚さ80μmのトリアセチルセルロースフィルム(富士フィルム(株)製,TDY‐80UL,Re=2nm,Rth=40nm)を用いた。
透明保護フィルム1:前記一般式(1)中、R1は水素原子、R2およびR3はメチル基であるラクトン環構造を有する(メタ)アクリル系樹脂[共重合モノマーの重量比:メタクリル酸メチル/2−(ヒドロキシメチル)アクリル酸メチル=8/2;ラクトン環化率約100%]を押出成膜した後、二軸延伸した透明保護フィルム(厚さ40μm,Re=2nm,Rth=13nm)を用いた。
透明保護フィルム2:前記一般式(1)中、R1は水素原子、R2およびR3はメチル基であるラクトン環構造を有する(メタ)アクリル系樹脂[共重合モノマーの重量比:メタクリル酸メチル/2−(ヒドロキシメチル)アクリル酸メチル=8/2;ラクトン環化率約100%]を押出成膜した後、二軸延伸した透明保護フィルム(厚さ40μm,Re=2nm,Rth=26nm)を用いた。
0‐TACフィルム:押出製膜後、二軸延伸した厚さ80μmのトリアセチルセルロースフィルムフィルム(富士フィルム(株)製,商品名:Z‐TAC,Re=1nm,Rth=0nm)を用いた。
アセトアセチル基を含有するポリビニルアルコール系樹脂(平均重合度:1200,ケン化度:98.5モル%,アセトアセチル化度:5モル%)100部に対し、メチロールメラミン50部を、30℃の温度条件下に、純水に溶解し、固形分濃度3.7%に調整した水溶液を調製した。前記水溶液100部に対し、アルミナコロイド水溶液(平均粒子径15nm,固形分濃度10%,正電荷)18部を加えて接着剤水溶液を調製した。接着剤水溶液の粘度は9.6mPa・sであった。接着剤水溶液のpHは、4−4.5の範囲であった。これを接着剤1とする。また、前記接着剤1において、アルミナコロイド水溶液を加えなかった接着剤水溶液を調製した。接着剤水溶液の粘度は7.0mPa・sであった。接着剤水溶液のpHは、4−4.5の範囲であった。これを接着剤2とする。
(偏光板の作成)
上記TACフィルム1の片面に、上記接着剤1を乾燥後の接着剤層の厚みが80nmとなるように塗布した。また、上記透明保護フィルム1の片面に、上記接着剤1を乾燥後の接着剤層の厚みが80nmとなるように塗布した。接着剤の塗布は、その調製から30分間後に23℃の温度条件下で行なった。次いで、23℃の温度条件下で偏光子の両面に、それぞれ前記接着剤付きの透明保護フィルムをロール機で貼り合せた後、55℃で6分間乾燥して偏光板を作成した。
IPSモードの液晶セルを含む液晶表示装置[日立製作所(株)製 液晶テレビ 商品名「Wooo(型番:W32−L7000)」(画面サイズ:698mm×392mm)]から、液晶パネルを取り出し、液晶セルの上下に配置されていた光学フィルムを全て取り除いて、上記液晶セルのガラス面(表裏)を洗浄した。このようにして作製した液晶セルを用いた。当該液晶セルの視認側の表面に、アクリル系粘着剤層(厚み20μm)を介して、上記偏光板のTACフィルム側が最表面(透明保護フィルム1側が液晶セル側)になるように貼り合わせた。なお、上記偏光板は、透明保護フィルム1の遅相軸が、液晶セルの長辺と平行になるようにした。一方、液晶セルのバックライト側の表面に、アクリル系粘着剤層(厚み20μm)を介して、上記偏光板の透明保護フィルム1側がバックライト側(透明保護フィルム1側が液晶セル側)になるように貼り合わせた。なお、上記偏光板は、透明保護フィルム1の遅相軸が、液晶セルの長辺と直交するようにした。こうして、液晶パネルを得た。
実施例1において、液晶パネルの作成にあたり用いる偏光板を表1に示すように変えたこと以外は実施例1と同様にして液晶パネルを作成した。なお、各例において用いる偏光板は、表1に示すように、透明保護フィルムの種類、接着剤の種類を変えたこと以外は実施例1と同様にして作成した。
得られた液晶パネルおよび用いた偏光板について下記評価を行った。結果を表2に示す。
得たれた液晶パネルをバックライトの上に設置し、液晶表示装置とした。液晶表示装置に黒画像を表示させ、23℃の暗室でバックライトを点灯させてから、30分経過した後、ELDIM社製 製品名「EZ Contrast160D」を用いて、表示画面の法線方向(方位角0°、極角0°)の色相(x0,y0)と、斜め方向(方位角60°、極角60°)の色相(x60,y60)とを測定し、カラーシフトを、次式:Δxy={(x0−x60)2+(y0−y60)2}1/2から算出した。液晶パネル長辺方向を方位角0°とし、液晶パネルの法線方向を極角0°とした。正面コントラストは、液晶表示装置を白画像および黒画像を表示させた場合の法線方向(方位角0°、極角0°)について、斜めコントラストは斜め方向(方位角60°、極角60°)についての、各コントラストである。正面コントラストおよび斜めコントラストは、値が高いほど良好であり、カラーシフトは値が小さいほど良好である。
偏光板の端部において、偏光子と透明保護フィルムとの間にカッターの刃先を挿入した。当該挿入部において、偏光子と透明保護フィルムとを掴み、それぞれ反対方向に引っ張った。このとき、偏光子および/または透明保護フィルムが破断して剥離できなかった場合は、密着性が良好:「○」と判断した。一方、偏光子と透明保護フィルムとの間で一部または全部は剥離した場合は、密着性に乏しい:「×」と判断した。
偏光板を、偏光子の吸収軸方向に50mm、吸収軸に直交する方向に25mmになるように切り出してサンプルを調製した。当該サンプルを、60℃の温水に浸漬し、時間経過とともにサンプルの端部の剥がれ量(mm)を測定した。剥がれ量(mm)の測定は、ノギスにより行なった。5時間経過後の剥がれ量(mm)を表2に示す。
偏光板を1000mm×1000mmになるように切り出してサンプルを調製した。サンプルの偏光板を、蛍光灯下に置いた。サンプルの偏光板の光源側に別の偏光板を、それぞれの吸収軸が直行するように設置し、この状態で、光抜けする箇所(クニック欠陥)の個数をカウントした。
P2 第2偏光板
a1、a2 偏光子
b1、b2 透明保護フィルム
c1、c2 透明保護フィルム
LC IPSモード液晶セル
Claims (6)
- IPSモードにて駆動される液晶セルと、当該液晶セルの両側に配置された、第1偏光板および第2偏光板を有するIPS液晶パネルであって、
前記第1偏光板および第2偏光板は、いずれも、偏光子の両面に接着剤層を介して透明保護フィルムが積層されており、
前記第1偏光板および第2偏光板における、液晶セル側に配置される透明保護フィルムは、当該透明保護フィルムの面内屈折率が最大となる方向をX軸、X軸に垂直な方向をY軸、フィルムの厚さ方向をZ軸とし、それぞれの軸方向の波長590nmにおける屈折率をnx、ny、nz、フィルムの厚さd(nm)として、
面内位相差:Re=(nx−ny)×d、
厚み方向位相差:Rth=(nx−nz)×d、をそれぞれ定義した場合に、
いずれも、面内位相差が10nm以下であり、前記液晶セル側に配置される透明保護フィルムの厚み方向位相差は、それぞれの絶対値の和が10〜40nmであり、かつ、いずれか一方の透明保護フィルムの厚み方向位相差の絶対値が10〜30nmの範囲であり、
かつ、
前記第1偏光板および第2偏光板における、液晶セル側に配置される透明保護フィルムは、いずれか少なくとも一方が、ラクトン環構造を有する(メタ)アクリル系樹脂を含有してなることを特徴とするIPS液晶パネル。 - 前記接着剤層は、ポリビニルアルコール系樹脂、架橋剤および平均粒子径が1〜100nmの金属化合物コロイドを含有してなる樹脂溶液であって、かつ、
金属化合物コロイドは、ポリビニルアルコール系樹脂100重量部に対して、200重量部以下の割合で配合されている偏光板用接着剤から形成されたものであることを特徴とする請求項1記載のIPS液晶パネル。 - 金属化合物コロイドが、アルミナコロイド、シリカコロイド、ジルコニアコロイド、チタニアコロイドおよび酸化スズコロイドから選ばれるいずれか少なくとも1種であることを特徴とする請求項2記載のIPS液晶パネル。
- 金属化合物コロイドが、正電荷を有することを特徴とする請求項2または3記載のIPS液晶パネル。
- 金属化合物コロイドが、アルミナコロイドであることを特徴とする請求項4記載のIPS液晶パネル。
- 請求項1〜5のいずれかに記載の液晶パネルを有することを特徴とするIPS液晶表示装置。
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