JP4929818B2 - 新規な構造を有する12−ヒドロキシステアリン酸亜鉛とその製造方法 - Google Patents
新規な構造を有する12−ヒドロキシステアリン酸亜鉛とその製造方法 Download PDFInfo
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- JP4929818B2 JP4929818B2 JP2006121977A JP2006121977A JP4929818B2 JP 4929818 B2 JP4929818 B2 JP 4929818B2 JP 2006121977 A JP2006121977 A JP 2006121977A JP 2006121977 A JP2006121977 A JP 2006121977A JP 4929818 B2 JP4929818 B2 JP 4929818B2
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- Prior art keywords
- zinc
- hydroxystearate
- aqueous solution
- potassium
- range
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- FRZSCIVUSFMNBX-UHFFFAOYSA-L zinc;12-hydroxyoctadecanoate Chemical compound [Zn+2].CCCCCCC(O)CCCCCCCCCCC([O-])=O.CCCCCCC(O)CCCCCCCCCCC([O-])=O FRZSCIVUSFMNBX-UHFFFAOYSA-L 0.000 title claims description 41
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 239000007864 aqueous solution Substances 0.000 claims description 34
- 150000003751 zinc Chemical class 0.000 claims description 17
- 239000011148 porous material Substances 0.000 claims description 15
- IFQCEOKSFPQHTD-UHFFFAOYSA-M potassium;12-hydroxyoctadecanoate Chemical compound [K+].CCCCCCC(O)CCCCCCCCCCC([O-])=O IFQCEOKSFPQHTD-UHFFFAOYSA-M 0.000 claims description 12
- 238000004438 BET method Methods 0.000 claims description 8
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 24
- 239000000344 soap Substances 0.000 description 16
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 15
- 229910052751 metal Inorganic materials 0.000 description 13
- 239000002184 metal Substances 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 12
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 11
- 229940114926 stearate Drugs 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 238000000635 electron micrograph Methods 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 6
- 229940114930 potassium stearate Drugs 0.000 description 6
- 239000012266 salt solution Substances 0.000 description 6
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 6
- 229960001763 zinc sulfate Drugs 0.000 description 6
- 229910000368 zinc sulfate Inorganic materials 0.000 description 6
- 239000000843 powder Substances 0.000 description 5
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 238000001878 scanning electron micrograph Methods 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229940114069 12-hydroxystearate Drugs 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- RXPKHKBYUIHIGL-UHFFFAOYSA-L calcium;12-hydroxyoctadecanoate Chemical compound [Ca+2].CCCCCCC(O)CCCCCCCCCCC([O-])=O.CCCCCCC(O)CCCCCCCCCCC([O-])=O RXPKHKBYUIHIGL-UHFFFAOYSA-L 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Substances [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- 235000019359 magnesium stearate Nutrition 0.000 description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- 235000019341 magnesium sulphate Nutrition 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002071 nanotube Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- RZLVQBNCHSJZPX-UHFFFAOYSA-L zinc sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Zn+2].[O-]S([O-])(=O)=O RZLVQBNCHSJZPX-UHFFFAOYSA-L 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 159000000009 barium salts Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000002041 carbon nanotube Substances 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 150000001879 copper Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 229910052588 hydroxylapatite Inorganic materials 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- WRUGWIBCXHJTDG-UHFFFAOYSA-L magnesium sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Mg+2].[O-]S([O-])(=O)=O WRUGWIBCXHJTDG-UHFFFAOYSA-L 0.000 description 1
- 229940061634 magnesium sulfate heptahydrate Drugs 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000005649 metathesis reaction Methods 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- -1 oleic acid Chemical compound 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
80℃の温水90Lに12−ヒドロキシステアリン酸2.0kgを懸濁させ、これに560g/L濃度の水酸化カリウム水溶液680mLを加え、30分間攪拌して、12−ヒドロキシステアリン酸をケン化した。これに水40Lを加えて、温度を60℃に調整した。別に、60℃の温水30Lに硫酸亜鉛7水塩の結晶1Kgを加えて溶解させて、硫酸亜鉛水溶液を調製した。
80℃の温水110Lに12−ヒドロキシステアリン酸2.0kgを懸濁させ、これに560g/L濃度の水酸化カリウム水溶液680mLを加え、30分間攪拌して、12−ヒドロキシステアリン酸をケン化した。これに水20Lを加えて、温度を70℃に調整した。別に、70℃の温水30Lに硫酸亜鉛7水塩の結晶1Kgを加えて溶解させて、硫酸亜鉛水溶液を調製した。
80℃の温水90Lに12−ヒドロキシステアリン酸2.0kgを懸濁させ、これに400g/L濃度の水酸化ナトリウム水溶液680mLを加え、30分間攪拌して、12−ヒドロキシステアリン酸をケン化した。これに水40Lを加えて、温度を60℃に調整した。これ以外は、実施例1と同様にして、12−ヒドロキシステアリン酸亜鉛の粉体を得た。
60℃の温水30Lに硫酸マグネシウム7水塩の結晶900gを溶解させて、硫酸マグネシウム水溶液を調製した。硫酸亜鉛水溶液に代えて、上記硫酸マグネシウム水溶液を用いた以外は、実施例1と同様にして、12−ヒドロキシステアリン酸マグネシウムの粉体を得た。
60℃の温水30Lに300g/L濃度の塩化カルシウム水溶液1.3Lを加えて塩化カルシウム水溶液を調製した。硫酸亜鉛水溶液に代えて、上記塩化カルシウム水溶液を用いた以外は、実施例1と同様にして、12−ヒドロキシステアリン酸カルシウムの粉体を得た。
Claims (4)
- 長さの平均値が0.1〜10μmの範囲にあり、外径の平均値が0.05〜0.5μmの範囲にあり、上記長さの平均値/上記外径の平均値にて規定されるアスペクト比が2以上であると共に、少なくとも一方の端面から長さ方向に少なくともある長さにわたって延びる空孔を有する構造を有する12−ヒドロキシステアリン酸亜鉛。
- BET法による比表面積が25m2/g以上である請求項1に記載の12−ヒドロキシステアリン酸亜鉛。
- 12−ヒドロキシステアリン酸カリウムの0.1〜10重量%濃度の水溶液と0.1〜10重量%濃度の亜鉛塩水溶液とを45〜95℃の範囲の温度で混合し、反応させることを特徴とする請求項1に記載の12−ヒドロキシステアリン酸亜鉛の製造方法。
- 12−ヒドロキシステアリン酸カリウム水溶液と亜鉛塩水溶液とを50〜80℃の範囲の温度で混合し、反応させる請求項3に記載の12−ヒドロキシステアリン酸亜鉛の製造方法。
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JP2006121977A JP4929818B2 (ja) | 2006-04-26 | 2006-04-26 | 新規な構造を有する12−ヒドロキシステアリン酸亜鉛とその製造方法 |
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JP2006121977A JP4929818B2 (ja) | 2006-04-26 | 2006-04-26 | 新規な構造を有する12−ヒドロキシステアリン酸亜鉛とその製造方法 |
Publications (2)
Publication Number | Publication Date |
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JP2007291025A JP2007291025A (ja) | 2007-11-08 |
JP4929818B2 true JP4929818B2 (ja) | 2012-05-09 |
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JP2006121977A Expired - Fee Related JP4929818B2 (ja) | 2006-04-26 | 2006-04-26 | 新規な構造を有する12−ヒドロキシステアリン酸亜鉛とその製造方法 |
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Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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JP4299878B1 (ja) | 2008-10-06 | 2009-07-22 | 株式会社パラエルモサ | 化粧料 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS548606A (en) * | 1977-06-21 | 1979-01-23 | Adeka Argus Chem Co Ltd | Production of metallic soap |
JP2668941B2 (ja) * | 1988-05-28 | 1997-10-27 | 日本油脂株式会社 | 金属石鹸の連続製造法 |
JP4092403B2 (ja) * | 2003-08-27 | 2008-05-28 | 独立行政法人産業技術総合研究所 | 高純度カルボン酸リチウム結晶とその製造方法 |
JP2004292794A (ja) * | 2003-12-26 | 2004-10-21 | National Institute Of Advanced Industrial & Technology | 液体炭化水素固形用固形化材とその使用及び液体炭化水素の固形化方法 |
JP4466091B2 (ja) * | 2004-01-30 | 2010-05-26 | 日油株式会社 | 金属石鹸の製造方法 |
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