JP4907884B2 - Cosmetics - Google Patents

Description

  The present invention relates to a cosmetic containing a specific silicone polymer, a fluoroalkyl group-containing organopolysiloxane, and a fructooligosaccharide fatty acid ester, and can stably and effectively contain a fluorine-based compound having high water and oil repellency, and Providing cosmetics that have excellent adhesion to the skin and good comfort (do not slippery forever), and have a longer makeup duration against makeup collapse due to sebum, as well as sweat and water. Is. In addition, it is excellent in adhesion to skin and emollient effect by stably blending liquid oil, and in particular, it is excellent in usability and usability such as relaxation of oiliness by blending volatile silicone in particular. Is related to cosmetics.

  Conventionally, in order to prevent makeup collapse due to sweat, water, and sebum, it has been studied to impart water and oil repellency to cosmetics. Various fluorine compounds have been developed and applied to improve water and oil repellency. For example, cosmetics with a combination of linear fluorine-modified silicone, which prevents makeup from collapsing against external factors such as physical friction and swimming in addition to sweat and sebum (for example, patents) Document 1) and novel fluorine-modified silicone derivatives having improved oil repellency and usability (for example, Patent Documents 2 and 3) have been developed. In addition, the development of specific silicone polymers has been studied for the purpose of blending fluorine-modified silicones stably in cosmetics and having excellent sensory characteristics when applied to the skin, and also stably blending water. (For example, Patent Document 4)

JP-A-2-295912 Japanese Patent No. 2720127 Japanese Patent Laid-Open No. 9-268110 JP 2001-342255 A

  However, these fluorine compounds have high oil repellency, but have low compatibility with oily base materials such as hydrocarbons, esters, triglycerides and silicone oils that are blended in cosmetics, making it difficult to blend stably. For this reason, these oil repellency functions could not be fully utilized, and there were many cases where it was not fully satisfactory with respect to prevention of cosmetic breakup due to sebum. In addition, when the specific silicone polymer is used, fluorine-modified silicone and water can be stably blended, but many of them have poor affinity to the skin. There were cases where problems such as this occurred.

Under such circumstances, the present inventors have conducted extensive research to solve the above problems, and as a result, cosmetics containing a specific silicone polymer, a fluoroalkyl group-containing organopolysiloxane, and a fructooligosaccharide fatty acid ester are the above-mentioned problems. Fluorine compound with high water and oil repellency can be blended stably and effectively, and it has excellent adhesion to the skin and good cushioning. However, makeup lasting is increased and a uniform makeup film is formed. In addition, by stably blending liquid oil, it is excellent in adhesion to the skin and emollient effect, and among them, in particular, by stably blending volatile silicone, it is excellent in usability and usability, such as relaxation of oiliness. As a result, the present invention has been completed.
That is, the present invention includes the following components (A) to (C);
(A) Organohydrogenpolysiloxane represented by the following general formula (1) R ¹ _a H _b SiO _{(4-ab) / 2} (1)
And organopolysiloxane R ¹ _c R ² _d SiO _{(4-cd) / 2} (2) represented by the following general formula (2):
A silicone polymer having a three-dimensional cross-linking structure which is insoluble in an organic solvent and can contain penta-3,3,3-trifluoropropylpentamethylcyclopentasiloxane having the same mass or more as its own weight (however, In the formula, each R ¹ may be the same or different and is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms and having no aliphatic unsaturated bond, and 11 to 60 mol% thereof. Is a monovalent hydrocarbon group which is a fluorine-substituted monovalent hydrocarbon group, R ² is a monovalent hydrocarbon group having 2 to 10 carbon atoms having a terminal vinyl group, and a is 1.0 to 2.3, b is 0.001 to 1.0, c is 1.0 to 2.3, d is 0.001 to 1.0, and 1.5 ≦ a + b ≦ 2.6, 1.5 ≦ c + d ≦ 2. .6 is satisfied.)
(B) A fluoroalkyl group-containing organopolysiloxane (C) A cosmetic comprising a fructooligosaccharide fatty acid ester having a fatty acid substitution degree per monosaccharide unit of 2.2 or more is provided.

  Since the cosmetic composition of the present invention can stably and effectively contain a fluorine-based compound having high water and oil repellency, it has excellent adhesion to the skin and good cushioning. On the other hand, the makeup lasting time is increased and a uniform decorative film can be formed. Furthermore, since the cosmetic of the present invention can be stably blended with liquid oil, it is excellent in adhesion to the skin and emollient effect, and among them, particularly volatile silicone can be blended stably, so that it can be used to reduce oiliness, It has excellent usability.

Hereinafter, the present invention will be described in detail.
The specific silicone polymer of the component (A) used in the present invention is an organohydrogenpolysiloxane represented by the following general formula (1) R ¹ _a H _b SiO _{(4-ab) / 2} (1)
And organopolysiloxane R ¹ _c R ² _d SiO _{(4-cd) / 2} (2) represented by the following general formula (2):
A silicone having a three-dimensional crosslinked structure, characterized in that it can contain penta-3,3,3-trifluoropropylpentamethylcyclopentasiloxane that is insoluble in an organic solvent and has the same mass or more as its own weight. A polymer (provided that each R ¹ may be the same or different, and is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms and having no aliphatic unsaturated bond, 11 to 60 mol% is a monovalent hydrocarbon group which is a fluorine-substituted monovalent hydrocarbon group, R ² is a monovalent hydrocarbon group having 2 to 10 carbon atoms having a terminal vinyl group, and a is 1.0 2.3, b is 0.001 to 1.0, c is 1.0 to 2.3, d is 0.001 to 1.0, and 1.5 ≦ a + b ≦ 2.6. 5 ≦ c + d ≦ 2.6.), Specifically, JP-A-2001-342255. They include those described in JP.

Specific examples of R ¹ include hydrocarbon groups such as a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, a heptyl group, an octyl group, a nonyl group, a decyl group, a cyclopentyl group, and a cyclohexyl group, An aryl group such as a phenyl group and a tolyl group, a fluorine-substituted alkyl group such as a trifluoropropyl group, a nonafluorohexyl group, and a heptadecylfluorodecyl group can be exemplified, and a methyl group and a trifluoropropyl group are particularly preferable.
It is essential that 11 to 60 mol% of the organic group R ¹ is a fluorine-substituted monovalent hydrocarbon group. When the amount is less than 11 mol%, the affinity of the component (B) for the fluoroalkyl group-containing organopolysiloxane becomes poor, and when it exceeds 60 mol%, it is difficult to produce the organohydrogenpolysiloxane represented by the general formula (1). become. A preferred range is 20 to 50 mol%.
Specific examples of R ² include a vinyl group, an allyl group, a butenyl group, a pentenyl group, a hexenyl group, a heptenyl group, an octenyl group, a nonenyl group, and a decenyl group, and a vinyl group and an allyl group are particularly desirable.
a represents 1.0 to 2.3, and when a is smaller than 1.0, the degree of crosslinking becomes too high, and therefore penta-3,3,3-trifluoropropylpentamethylcyclopentasiloxane having the same mass or more as its own weight is required. If it is greater than 2.3, the degree of cross-linking is too low, making it difficult to form a three-dimensional cross-linked structure. A more preferable range is 1.2 to 2.1.
b is 0.001 to 1.0, and if b is less than 0.001, the degree of crosslinking becomes too low, so that it is difficult to form a three-dimensional crosslinked structure, and if it exceeds 1.0, the degree of crosslinking increases. Therefore, it cannot contain penta-3,3,3-trifluoropropylpentamethylcyclopentasiloxane having the same mass or more as its own weight. A more preferable range is 0.005 to 0.5.
c represents 1.0 to 2.3, and when c is smaller than 1.0, the degree of crosslinking becomes too high, so that penta-3,3,3-trifluoropropylpentamethylcyclopentasiloxane having the same mass or more as its own weight is added. If it is greater than 2.3, the degree of cross-linking is too low, making it difficult to form a three-dimensional cross-linked structure. A more preferable range is 1.2 to 2.1.
d is 0.001 to 1.0. If d is smaller than 0.001, the degree of crosslinking becomes too low, so that it is difficult to form a three-dimensional crosslinked structure, and if it exceeds 1.0, the degree of crosslinking is increased. Therefore, it cannot contain penta-3,3,3-trifluoropropylpentamethylcyclopentasiloxane having the same mass or more as its own weight. A more preferable range is 0.005 to 0.5.

  The organohydrogenpolysiloxane represented by the general formula (1) and the organopolysiloxane represented by the general formula (2) may be linear, branched or cyclic, but the polymerization reaction proceeds smoothly. For this purpose, it is preferably linear or mainly linear and partially containing branched units.

  In order to obtain a specific silicone polymer of component (A), an organohydrogenpolysiloxane represented by the general formula (1) and an organopolysiloxane represented by the general formula (2) are converted into a platinum compound (for example, platinum chloride). The reaction may be performed in the presence of an acid, alcohol-modified chloroplatinic acid, chloroplatinic acid-vinylsiloxane complex, or the like, or a rhodium compound at room temperature or under heating (about 50 ° C. to 120 ° C.). When carrying out the reaction, it may be carried out without a solvent, or an organic solvent may be used if necessary. Specific examples of the organic solvent include aliphatic alcohols such as methanol, ethanol, 2-propanol and butanol, aromatic hydrocarbons such as benzene, toluene and xylene, aliphatics such as n-pentane, n-hexane and cyclohexane or Examples thereof include alicyclic hydrocarbons, halogenated hydrocarbons such as dichloromethane, chloroform and carbon tetrachloride, and ketone solvents such as acetone and methyl ethyl ketone. However, for use as a cosmetic application, no solvent, ethanol, or 2-propanol is preferable.

  The specific silicone polymer of component (A) has a three-dimensional crosslinked structure and is insoluble in organic solvents. The organic solvent mentioned here is an aliphatic organic solvent such as linear or branched pentane, hexane, dodecane, hexadecane and octadecane, an aromatic organic solvent such as benzene, toluene and xylene, methanol, ethanol, propanol, Alcohol organic solvents such as butanol, hexanol and decanol, halogenated organic solvents such as chloroform and carbon tetrachloride, ketone organic solvents such as acetone and methyl ethyl ketone, as well as low-viscosity dimethylpolysiloxane, methylphenylpolysiloxane and cyclic dimethyl Examples thereof include silicone compounds such as polysiloxane. In addition, the specific silicone polymer of component (A) used in the present invention is characterized in that it may contain penta-3,3,3-trifluoropropylpentamethylcyclopentasiloxane having the same mass or more as its own weight.

  The component (A) can be used singly or in combination of two or more depending on the purpose, and its blending amount is not particularly limited, but is 0.01 to 40% by mass (hereinafter referred to as “%”) in the cosmetic. .) Is preferable, and 0.1 to 30% is particularly preferable. If it is this range, since the cosmetics excellent in a long-lasting makeup with a favorable feeling of use are obtained, it is preferable.

The component (B) fluoroalkyl group-containing organopolysiloxane is an organopolysiloxane having at least one fluoroalkyl group in the molecule as an organic group. Specific examples of the fluoroalkyl group include fluorine-substituted alkyl groups such as a trifluoropropyl group, a nonafluorohexyl group, and a heptadecylfluorodecyl group, with a trifluoropropyl group being particularly preferred.
The fluoroalkyl group-containing organopolysiloxane of the component (B) is preferably a fluoroalkyl group-containing organopolysiloxane having a viscosity at 25 ° C. of 200 mm ² / s or less, particularly preferably 20 to 180 mm ² / s. If it is this range, what is more favorable in affinity with the specific silicone polymer of a component (A) can be obtained.
The fluoroalkyl group-containing organopolysiloxane of component (B) may be linear, branched or cyclic. From the viscosity and affinity with the specific silicone polymer of component (A), A fluoroalkyl group-containing organopolysiloxane represented by the general formula (3) is particularly preferred.

(In the formula, p is an integer of 4 to 6.)
Specifically, as a linear thing, FL-100, X-22-819, X-22-820, X-22-821, X-22-822 (above, the Shin-Etsu Chemical Co., Ltd. make), FS -1265 (manufactured by Toray Dow Corning). Examples of the cyclic compound include those described in JP-A No. 09-268110. For example, trifluoropropylcyclotetrasiloxane / trifluoropropylcyclopentasiloxane (KF) under the INCI name (International Nomenclature Cosmetic Labeling Names). -5002: manufactured by Shin-Etsu Chemical Co., Ltd.).

In the present invention, the specific silicone polymer of component (A) can be kneaded with the fluoroalkyl group-containing organopolysiloxane of component (B) to obtain a paste-like composition. By producing a composition in which the component (A) and the component (B) are kneaded in advance, the flow characteristics of the component (B) can be adjusted, so that the operability during production is improved. As a result, there is an advantage that each makeup effect can be easily obtained.
In order to obtain the paste-like composition, a normal stirrer may be used, but it is preferable to perform a kneading treatment under a shearing force. This is because the specific silicone polymer of component (A) has a three-dimensional cross-linking structure insoluble in organic solvents, so that a paste-like composition can be obtained by giving sufficient dispersibility under shearing force. It is. As the kneading treatment, for example, three rolls, two rolls, a sand grinder, a colloid mill, a high viscosity mixer, a Gaurin homogenizer, a disperse mill, etc. can be used, but preferably a three roll, high viscosity mixer, disperse. A mill method is preferred.
Although the compounding quantity in the cosmetics of the obtained paste-like composition is not specifically limited, 0.1-90% is preferable and 1-70% is still more preferable. If it is in this range, cosmetics having sufficient cosmetic durability such as stability and water / oil repellency can be obtained, and cosmetics with good usability can be obtained. Further, the mass ratio of the component (A) to the component (B) is preferably 5:95 to 50:50, more preferably 10:90 to 30:70. A good one is obtained.

  The fructooligosaccharide fatty acid ester having a fatty acid substitution degree per monosaccharide unit of component (C) of 2.2 or more has an effect of imparting viscosity in a wide range, and in particular, component (D) described later. When liquid oils are blended at room temperature, these oils can be gelled. The fatty acid substitution degree shown here indicates the average number of moles obtained by esterifying three hydroxyl groups in a monosaccharide unit with a fatty acid. Examples thereof include those described in JP-A-3-197409 and JP-A-2002-193732. For example, a hydrogen atom of a hydroxyl group of a fructooligosaccharide having an average molecular weight of 300 to 10,000 is an acyl group RCO- (where R And a fructooligosaccharide fatty acid ester having a fatty acid substitution degree of 2.2 or more per monosaccharide unit. As a commercially available product of the fructooligosaccharide fatty acid ester of component (C), Leo Pearl ISK (manufactured by Chiba Flour Mills Co., Ltd.) and the like can be mentioned.

The fructooligosaccharide used as a raw material for the specific fructooligosaccharide fatty acid ester of the component (C) refers to an oligosaccharide having fructose as a main constituent sugar. Fructooligosaccharides are contained in various plants such as roots, stems, leaves, and seeds of Asteraceae, Gramineae and Liliaceae, and their structures are such that the main chain has a 2 → 1 bond and 2 → There are two types of 6 bonds. Examples of the 2 → 1 bond include fructooligosaccharides derived from inulin, asparagosin, asphodelan, triticane, criticzan, and bacmond, and examples of the 2 → 6 bond include Flaen, Levan, and Secaran. These fructooligosaccharides may be hydrolyzed by enzyme treatment or the like, and the average molecular weight is preferably in the range of 300 to 10,000. Among these fructooligosaccharides, inulin or hydrolyzed inulin is preferable from the viewpoint of supply.
In the present invention, the substitution degree of fatty acid per fructose unit of the fructooligosaccharide fatty acid ester of component (C) is 2.2 or more. When the degree of substitution is lower than 2.2, the solubility with the oil component and the gel structure are not sufficiently imparted, and it is difficult to ensure the stability over time.
In the acyl group of the ester, 60 mol% or more of the total acyl group is preferably an acyl group having a straight chain hydrocarbon skeleton having 16 to 22 carbon atoms, specifically, a hexadecanoyl group or an octadecanoyl group. , Eicosanoyl group and docosanoyl group. If the total amount of these acyl groups is less than 60 mol%, it may be difficult to ensure the stability of the cosmetic. With regard to the carbon chain length of the acyl group, an acyl group having a carbon number smaller than that of the hexadecanoyl group does not provide sufficient solubility or gel structure with the oil component, and conversely, an acyl group having a larger number of carbon atoms than the docosanoyl group. Then, it may be accompanied by a heavy feel during use or may precipitate over time.
Moreover, less than 40 mol% of the total acyl groups may be substituted with other acyl groups. Examples of other acyl groups include acetyl group, propionyl group, butyryl group, isobutyryl group, valeryl group, isovaleryl group, pivaloyl group, hexanoyl group, octanoyl group, decanoyl group, dodecanoyl group, tetradecanoyl group, tetracosanoyl group Hexacosanoyl group, octacosanoyl group, triacontanoyl group, oleoyl group, benzoyl group, naphthoyl group, isostearoyl group, isohexadecanoyl group, isodecanoyl group, isooctanoyl group and the like.

  A fructooligosaccharide fatty acid ester having a fatty acid substitution degree per monosaccharide unit of component (C) of 2.2 or more is produced by reacting the fructooligosaccharide with a fatty acid or a fatty acid derivative. Examples of fatty acid derivatives include acid halides and acid anhydrides. The reaction between fructooligosaccharide and fatty acid or fatty acid derivative can be easily performed by a conventionally known method. For example, it can be obtained by dispersing fructooligosaccharide in dimethylformamide and pyridine, adding a fatty acid halide or a fatty acid anhydride thereto, and reacting at about 60 ° C. for about 2 hours.

  The blending amount of the component (C) fructooligosaccharide fatty acid ester is not limited depending on the type of cosmetic preparation, the type of application, etc., but is preferably 0.1 to 30% in the cosmetic. If it is this range, it is preferable at the point of adjustment and stability of the viscosity and hardness which are related to the usability and usability of cosmetics. These fructooligosaccharide fatty acid esters can be used alone or in combination of two or more as required.

The cosmetic composition of the present invention can further improve adhesion and usability by further blending a liquid oil at room temperature as the component (D).
Examples of the oil agent of component (D) include natural animal and vegetable oils and semi-synthetic oils, hydrocarbon oils, ester oils, glyceride oils, and silicone oils.
As specific examples, natural animal and vegetable oils and semi-synthetic oils include avocado oil, linseed oil, almond oil, olive oil, kayak oil, liver oil, kyounin oil, wheat germ oil, sesame oil, rice germ oil, rice bran oil, sasanqua oil, Safflower oil, cinnamon oil, cinnamon oil, turtle oil, soybean oil, tea seed oil, camellia oil, evening primrose oil, corn oil, rapeseed oil, Japanese kiri oil, germ oil, persic oil, palm oil, palm kernel oil, castor Oil, sunflower oil, grape oil, jojoba oil, macadamia nut oil, cottonseed oil, palm oil, tricoconut oil fatty acid glyceride, peanut oil, liquid lanolin, reduced lanolin, lanolin alcohol, lanolin acetate, lanolin fatty acid isopropyl, POE lanolin alcohol ether, POE lanolin Alcohol acetate, lanolin fatty acid polyethylene glycol, OE hydrogenated lanolin alcohol ether, and egg yolk oil.
Examples of the hydrocarbon oil include squalane, squalene, liquid paraffin, pristane, polyisobutylene and the like.
Examples of ester oils include diisobutyl adipate, 2-hexyldecyl adipate, di-2-heptylundecyl adipate, N-alkyl glycol monoisostearate, isocetyl isostearate, trimethylolpropane triisostearate, 2-ethylhexanoic acid Cetyl, ethylene glycol di-2-ethylhexanoate, neopentyl glycol di-2-ethylhexanoate, trimethylolpropane tri-2-ethylhexanoate, pentaerythritol tetra-2-ethylhexanoate, cetyl octanoate, oleic acid Oleyl, octyldodecyl oleate, decyl oleate, neopentyl glycol dicaprate, triethyl citrate, 2-ethylhexyl succinate, amyl acetate, ethyl acetate, butyl acetate, stearic acid Cetyl, butyl stearate, diisopropyl sebacate, di-2-ethylhexyl sebacate, myristyl lactate, isopropyl palmitate, 2-ethylhexyl palmitate, 2-hexyldecyl palmitate, 2-heptyl undecyl palmitate, pentaerythritol fatty acid ester , Isopropyl myristate, 2-octyldodecyl myristate, 2-hexyldecyl myristate, myristyl myristate, hexyl dimethyloctanoate, ethyl laurate, hexyl laurate, N-lauroyl-L-glutamic acid-2-octyldodecyl ester And diisostearyl malate.
Examples of the glyceride oil include acetoglyceride, triisostearic acid glyceride, triisopalmitic acid glyceride, monostearic acid glyceride, di-2-heptylundecanoic acid glyceride, and trimyristic acid glyceride.
Examples of the silicone oil include dimethylpolysiloxane, methylphenylpolysiloxane, methylhydrogenpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, and alkyl-modified silicone.
Among these oily components, volatile silicones such as dimethylpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and dodecamethylcyclohexasiloxane draw out the effect of component (C), and the goodness of cushioning and oiliness It is more preferable in terms of usability such as relaxation, and usability.

  Although the compounding quantity of a component (D) is not specifically limited, 0.01 to 90% is preferable and especially 0.1 to 70% is more preferable. When the content falls within this range, the above-described effect can be further improved. In addition, these liquid oils at room temperature can be used alone or in combination of two or more as required.

  The cosmetics of the present invention include ingredients, oils, gelling agents, moisturizers, surfactants, powders, pigments, lower alcohols, UV absorbers, which are used in ordinary cosmetics as long as they do not interfere with the effects of the present invention. Agent, antiseptic, antibacterial agent, perfume, antioxidant, pH adjuster, chelating agent, refreshing agent, skin cleansing agent (whitening agent, cell activator, anti-inflammatory agent, blood circulation promoter, skin astringent, antiseborrhea Agents), vitamins, nucleic acids, hormones, inclusion compounds, and the like.

  Oils other than component (D) include hydrocarbons, waxes, hydrogenated oils, higher fatty acids, higher alcohols, etc., but any can be used as long as they are used in normal cosmetics. If necessary, one kind or two or more kinds can be used. Specifically, waxes such as paraffin wax, ceresin wax, microcrystalline wax, Fischer-Tropsch wax, polyethylene wax, ethylene / propylene copolymer, candelilla wax, carnauba wax, beeswax, mole, gay wax, jiro, and montan wax. Higher fatty acids such as stearic acid and behenic acid, silicone waxes such as stearyl-modified methylpolysiloxane and behenyl-modified methylpolysiloxane, and higher alcohols such as stearyl alcohol, cetyl alcohol, and behenyl alcohol.

Surfactants include anionic, cationic, nonionic, and amphoteric active agents, but any surfactant can be used as long as it is used in normal cosmetics. 1 type, or 2 or more types can be used.
For example, anionic surfactants include fatty acid soaps such as sodium stearate and triethanolamine palmitate, alkyl ether carboxylic acids and salts thereof, carboxylates such as condensates of amino acids and fatty acids, alkyl sulfonic acids, and alkene sulfones. Acid salts, sulfonates of fatty acid esters, sulfonates of fatty acid amides, sulfonates of alkyl sulfonates and their formalin condensates, alkyl sulfate esters, secondary higher alcohol sulfates, alkyl and allyl ether sulfates Ester salts, fatty acid ester sulfates, fatty acid alkylolamide sulfates, polyoxyethylene alkyl sulfates, sulfate salts such as funnel oil, alkyl phosphates, alkyl ether phosphates, alkyl allyl ethers Acid salts, amidophosphates, N-acylamino acid based activators, etc .; cationic surfactants include alkylamine salts, amine salts such as polyamines and aminoalcohol fatty acid derivatives, alkyl quaternary ammonium salts, aromatic quaternary ammonium Salts, pyridium salts, imidazolium salts and the like.
Nonionic surfactants include sorbitan fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, propylene glycol fatty acid ester, polyethylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyethylene alkyl ether, polyoxypropylene alkyl ether, poly Oxyethylene alkyl phenyl ether, polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitol fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene propylene glycol fatty acid ester, polyoxyethylene castor oil, polyoxyethylene Hydrogenated castor oil, polyoxyethylene phytostanol ether, polyoxyethylene N-phytosterol ether, polyoxyethylene cholestanol ether, polyoxyethylene cholesteryl ether, polyoxyalkylene-modified organopolysiloxane, polyoxyalkylene / alkyl co-modified organopolysiloxane, alkanolamide, sugar ether, sugar amide, etc .; amphoteric surfactant Examples thereof include betaines, aminocarboxylates, imidazoline derivatives, and the like.

  Examples of alcohols include lower alcohols such as ethanol and isopropanol, sugar alcohols such as sorbitol and maltose, and sterols include cholesterol, sitosterol, phytosterol, and lanosterol.

  Examples of the humectant include sorbitol, xylitol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, glycerin, diglycerin, polyethylene glycol, hyaluronic acid, chondroitin sulfate, and pyrrolidone carboxylate.

  Examples of aqueous thickeners or gelling agents include gum arabic, gum tragacanth, galactan, carob gum, guar gum, caraya gum, carrageenan, pectin, agar, quince seed (malmello) gum, starch (rice, corn, potato, wheat), alge colloid Plant polymers such as Tant gum, locust bean gum, microbial polymers such as xanthan gum, dextran, succinoglucan, pullulan, animal polymers such as collagen, casein, albumin, gelatin, carboxymethyl starch, methylhydroxypropyl Starch polymers such as starch, methylcellulose, methylhydroxypropylcellulose, carboxymethylcellulose, hydroxymethylcellulose, hydroxypropylcellulose, cellulose Cellulose polymers such as sodium acid, sodium carboxymethyl cellulose, alginic acid polymers such as sodium alginate and propylene glycol alginate, vinyl polymers such as carboxyvinyl polymer, polyoxyethylene polymers, polyoxyethylene polyoxypropylene Copolymer-based polymers, acrylic polymers such as sodium polyacrylate, polyacrylamide, polyethyleneimine, cationic polymers, bentonite, magnesium aluminum silicate, laponite, hectorite, silicic anhydride, etc. is there. Also included are film forming agents such as polyvinyl alcohol and polyvinyl pyrrolidone.

  Examples of oil gelling agents include metal soaps such as aluminum stearate, magnesium stearate, zinc myristate, amino acid derivatives such as N-lauroyl-L-glutamic acid, α, γ-di-n-butylamine, dextrin palmitate, Dextrin fatty acid esters such as dextrin stearic acid ester, dextrin 2-ethylhexanoic acid palmitic acid ester, sucrose fatty acid esters such as sucrose palmitic acid ester, sucrose stearic acid ester, benzylidene of sorbitol such as monobenzylidene sorbitol, dibenzylidene sorbitol Examples thereof include organically modified clay minerals such as derivatives, dimethylbenzyl dodecyl ammonium montmorillonite clay, and dimethyl dioctadecyl ammonium montmorillonite clay.

Any powder can be used regardless of shape (spherical, needle, plate, etc.), particle size (smoke, fine particles, pigment grade, etc.) and particle structure (porous, nonporous, etc.). be able to. For example, inorganic powders include titanium oxide, zirconium oxide, zinc oxide, cerium oxide, magnesium oxide, barium sulfate, calcium sulfate, magnesium sulfate, calcium carbonate, magnesium carbonate, talc, mica, kaolin, sericite, muscovite, Synthetic mica, phlogopite, saucite, biotite, lithia mica, silicic acid, anhydrous silicic acid, aluminum silicate, magnesium silicate, magnesium aluminum silicate, calcium silicate, barium silicate, strontium silicate, metal tungstate Salt, hydroxyapatite, vermiculite, hydrite, bentonite, montmorillonite, hectorite, zeolite, ceramic powder, dicalcium phosphate, alumina, aluminum hydroxide, boron nitride, boron nitride, silica, etc.
Organic powders include polyamide powder, polyester powder, polyethylene powder, polypropylene powder, polystyrene powder, polyurethane, benzoguanamine powder, polymethylbenzoguanamine powder, tetrafluoroethylene powder, polymethylmethacrylate powder, cellulose powder, silk powder, nylon powder ( 12 nylon, 6 nylon), styrene / acrylic acid copolymer, divinylbenzene / styrene copolymer, vinyl resin, urea resin, phenol resin, fluororesin, silicon resin, acrylic resin, melamine resin, epoxy resin, polycarbonate resin, Microcrystalline fiber powder, rice starch, lauroyl lysine, etc .; surfactant metal salt powder (metal soap) includes zinc stearate, stearic acid Luminium, calcium stearate, magnesium stearate, zinc myristate, magnesium myristate, zinc cetyl phosphate, calcium cetyl phosphate, sodium cetyl phosphate, etc .; as colored pigments, inorganic red pigments of iron oxide, iron hydroxide, iron titanate, Inorganic brown pigments such as γ-iron oxide, inorganic yellow pigments such as yellow iron oxide and loess, inorganic black pigments such as black iron oxide and carbon black, inorganic purple pigments such as manganese violet and cobalt violet, chromium hydroxide, Inorganic green pigments such as chromium oxide, cobalt oxide and cobalt titanate, inorganic blue pigments such as bitumen and ultramarine blue, tar dyes raked, natural dyes raked, and composites of these powders Composite powder and the like.
Examples of pearl pigments include titanium oxide-coated mica, titanium oxide-coated mica, bismuth oxychloride, titanium oxide-coated bismuth oxychloride, titanium oxide-coated talc, fish scale foil, titanium oxide-coated colored mica, and the like. Copper powder, stainless steel powder, etc .; As tar pigments, Red No. 3, Red No. 104, Red No. 106, Red No. 201, Red No. 202, Red No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 227 No., Red No. 228, Red No. 230, Red No. 401, Red No. 505, Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 203, Yellow No. 204, Yellow No. 401, Blue No. 1, Blue No. 2, Blue 201, Blue 404, Green 3, Green 201, Green 204, Green 205, Orange 201, Orange 20 No., orange No. 204, orange No. 206, orange No. 207, etc .; natural pigments are powders selected from carminic acid, laccaic acid, calsamine, bradylin, crocin, etc. It may be a powder that has been surface-treated with silicone or a fluorine compound, and may be used alone or in combination of two or more as required.

  Examples of UV absorbers include benzoic acid UV absorbers such as paraaminobenzoic acid, anthranilic UV absorbers such as methyl anthranilate, salicylic acid UV absorbers such as methyl salicylate, and cinnamon such as octyl paramethoxycinnamate. Examples thereof include acid ultraviolet absorbers, benzophenone ultraviolet absorbers such as 2,4-dihydroxybenzophenone, urocanic acid ultraviolet absorbers such as ethyl urocanate, and the like.

  As preservatives, paraoxybenzoic acid alkyl esters, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, phenoxyethanol, etc. Antibacterial agents include salicylic acid, coalic acid, sorbic acid, parachlorometacresol, hexachlorophene, benzaldehyde chloride Examples include ruthenium, chlorhexidine chloride, trichlorocarbanilide, and photosensitizer.

  Examples of antioxidants include tocopherol, butylhydroxyanisole, and dibutylhydroxytoluene. Examples of pH adjusters include lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, dl-malic acid, potassium carbonate, sodium bicarbonate, and hydrogen carbonate. As chelating agents such as ammonium, alanine, sodium edetate, sodium polyphosphate, sodium metaphosphate, phosphoric acid, etc., as refreshing agents, L-menthol, camphor, etc., as anti-inflammatory agents, allantoin, glycyrrhetic acid, Examples include tranexamic acid and azulene.

  As skin beautifying ingredients, whitening agents such as arbutin, glutathione, and yukinoshita extract, royal jelly, photosensitizer, cholesterol derivatives, cell activators such as calf blood extract, rough skin improver, nonyl acid wallenyl amide, nicotinic acid benzyl ester Nicotinic acid β-butoxyethyl ester, capsaicin, gingerone, cantalis tincture, ictamol, caffeine, tannic acid, α-borneol, tocopherol nicotinate, inositol hexanicotinate, cyclandrate, cinnarizine, trazoline, acetylcholine, verapamil, Examples thereof include blood circulation promoters such as cephalanthin and γ-oryzanol, skin astringents such as zinc oxide and tannic acid, and antiseborrheic agents such as sulfur and thianthol.

  Vitamins such as vitamin A oil, retinol, retinol acetate, retinol palmitate, etc., vitamin B2 such as riboflavin, riboflavin butyrate, flavin adenine nucleotide, vitamin B6 such as pyridoxine hydrochloride, pyridoxine dioctanoate Vitamins such as L-ascorbic acid, L-ascorbic acid dipalmitate, L-ascorbic acid-2-sodium sulfate, dl-α-tocopherol-L-ascorbic acid diester dipotassium, calcium pantothenate, Pantothenic acids such as D-pantothenyl alcohol, pantothenyl ethyl ether, acetyl pantothenyl ethyl ether, vitamin Ds such as ergocalciferol and cholecalciferol, nicotinic acid, benzyl nicotinate Nicotine acids such as nicotinic acid amide, dl-alpha-tocopherol, vitamin E acetate dl-alpha-tocopherol, nicotinic acid dl-alpha-tocopherol, and succinic acid dl-alpha-tocopherol, vitamin P, biotin, or the like.

  Examples of amino acids include arginine, aspartic acid, cystine, cysteine, methionine, serine, leucine, and tryptophan. Examples of nucleic acids include deoxyribonucleic acid. Examples of hormones include estradiol and ethinylestradiol.

The cosmetics of the present invention include skin care cosmetics such as milky lotion, cream, cosmetic liquid, cosmetic oil, lip balm, hand cream, face wash, foundation, makeup base, blusher, eye shadow, mascara, eyeliner, eyebrow. In addition, makeup cosmetics such as overcoat agents and lipsticks can be mentioned, and the dosage form can be appropriately selected from forms such as liquid, emulsion, solid, paste, and gel.
The cosmetic of the present invention is produced by a method for producing an ordinary cosmetic, and the production method is not limited.

Synthesis Example 1 Silicone Polymer 1
In the reactor, the following average composition formula (4)

118 parts by mass of an organohydrogenpolysiloxane represented by the following average composition formula (5)

175 parts by weight of a vinyl-modified organopolysiloxane represented by the formula (1) was added, 0.1 part by weight of a divinyltetramethyldisiloxane solution containing 2% by weight of chloroplatinic acid was added, and the internal temperature was maintained at 70 to 80 ° C., followed by stirring for 2 hours. An elastic silicone polymer 1 was obtained.

Synthesis Example 2 Silicone polymer 2
In the reactor, the following average composition formula (6)

567 parts by mass of an organohydrogenpolysiloxane represented by the following average composition formula (7)

955 parts by weight of a vinyl-modified organopolysiloxane represented by the formula (1) is added, 0.1 part by weight of a divinyltetramethyldisiloxane solution containing 2% by weight of chloroplatinic acid is added, and the internal temperature is maintained at 70 to 80 ° C. under reduced pressure. The mixture was stirred for a time to obtain a silicone polymer 2 having elasticity.

Synthesis Example 3 Fructooligosaccharide fatty acid ester 1 (inulin stearate ester)
To 10.8 g of inulin, 500 g of dimethylformamide was added and dissolved by stirring at 60 ° C. To this was added 16 g of pyridine, and 60.5 g of stearoyl chloride was added dropwise with stirring. After reacting for 2 hours, the pyridine salt was filtered off, and dimethylformamide was distilled off. Toluene was added to the residue for extraction, and the solvent was distilled off after drying with bow glass. The residue was washed with methanol to obtain 55 g of inulin stearate.
The average fatty acid substitution degree (indicating the number of fatty acid molecules added per monosaccharide unit) of this product was 2.7 from its saponification value.

Synthesis Example 4 Fructooligosaccharide fatty acid ester 2 (inulin stearate ester)
200 g of dimethylformamide and 30 g of pyridine were added to 16.2 g of inulin and dissolved at 60 ° C. with stirring. To this, 91 g of stearoyl chloride was added dropwise with stirring. After reacting for 5 hours, the mixture was poured into 1 L of purified water to precipitate a solid content. This was filtered off and the residue was washed with methanol to obtain 57 g of inulin stearate.
The fatty acid average substitution degree of this product was 2.8.

Synthesis Example 5 Fructooligosaccharide fatty acid ester 3 (hydrolyzed inulin (palmitic acid / 2-ethylhexanoic acid) ester)
200 g of dimethylformamide and 30 g of pyridine were added to 16.2 g of hydrolyzed inulin and dissolved at 60 ° C. with stirring. 30.5 g of palmitoyl chloride and 32.5 g of 2-ethylhexanoyl chloride were added dropwise thereto, reacted for 5 hours, extracted with n-hexane, dried over bow glass, and the solvent was distilled off. The residue was washed with methanol to obtain 42 g of hydrolyzed inulin (palmitic acid / 2-ethylhexanoic acid) ester.
The average fatty acid substitution degree of this product was 2.5.

Synthesis Example 6 Fructooligosaccharide fatty acid ester 4 (inulin stearate ester (low substitution degree))
Except for using 60 g of stearoyl chloride, the same operation as in Synthesis Example 3 was performed to obtain 45 g of inulin stearate.
The average fatty acid substitution degree of this product was 1.3.

Production Example 1 Preparation of Pasty Composition 1 As a fluoroalkyl group-containing organopolysiloxane, 20 parts by mass of the silicone polymer 1 of Synthesis Example 1 and tetra-3,3,3-trifluoropropyltetramethylcyclotetrasiloxane / By mixing 80 parts by mass of a penta-3,3,3-trifluoropropylpentamethylcyclopentasiloxane mixture (1/1 mass ratio, viscosity 60 mm ² / s) and sufficiently kneading with three rolls, thixotropy is improved. A semitransparent paste-like composition 1 was obtained.

Production Example 2 Preparation of Pasty Composition 2 30 parts by mass of silicone polymer 2 of Synthesis Example 2 and the following average composition formula (8)

A semitransparent paste-like composition 2 having thixotropy was obtained by mixing 70 parts by mass of a fluoroalkyl group-containing organopolysiloxane (viscosity 150 mm ² / s) represented by .

Invention products 1 to 5 and comparative products 1 to 5 W / O emulsified liquid foundation W / O emulsified liquid foundation having the composition shown in Table 1 was prepared, and its feeling of use (adhesion to skin, good fit) The usability (film uniformity, makeup retention) and stability over time were evaluated and judged according to the following methods. The results are also shown in Table 1.

* 1: KF96-10cs (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 2: Esther gum HP (Arakawa Chemical Industries)
* 3: KF-6019 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 4: Trifluoropropylcyclotetrasiloxane / trifluoropropylcyclopentasiloxane (KF-5002 (manufactured by Shin-Etsu Chemical Co., Ltd.))
* 5: Trifluoropropyl-modified methylpolysiloxane (FL100-450cs (manufactured by Shin-Etsu Chemical Co., Ltd.))
* 6: Leopard KL (Chiba Flour Mills)
* 7: Powder treated with 3% dimethylpolysiloxane

(Production method)
A: Components 1 to 13 are dissolved by heating, and then components 14 to 19 are added and sufficiently dispersed.
B: Components 20 to 23 are mixed.
C: After emulsification while adding B to A, component 24 was added and mixed uniformly to obtain a W / O emulsified liquid foundation.

(Evaluation item)
(I) Adhesion to the skin (b) Good comfort (c) Uniformity of the film (d) Long-lasting makeup

(sensory evaluation)
Regarding the evaluation items of (i) to (d), a use test is conducted by 20 specialist panels, and each panel member evaluates it according to the following absolute evaluation and gives a score. The average value was calculated and judged according to the following four-step criteria. However, with regard to makeup holding, evaluation was performed after having a normal life for about 4 hours.
(Absolute evaluation)
(Score): (Evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad (4 step criteria)
(Average score): (Judgment)
More than 5 points: Very good: ◎
3 points to 5 points or less: Good: ○
More than 1 point and 3 points or less: Somewhat bad: △
1 point or less: Defect: ×
(E) Evaluation method of stability over time It was stored in a constant temperature bath at 40 ° C. for 3 months, and the change in appearance (texture, presence / absence of separation) was evaluated and judged according to the following criteria.
(Judgment)
A: No change in appearance.
○: slight change in appearance (Slightly bad but no separation)
Δ: Some change in appearance. (There is a tendency to separate badly)
X: There is a large change in appearance. (With separation)

As is apparent from the results in Table 1, the product of the present invention has a water and oil repellency improved by stably blending a fluorine-based compound, resulting in a cosmetic with a very long lasting makeup and high adhesion to the skin. It has a beautiful finish with a uniform makeup film, and it has excellent adhesion to the skin and emollient effect, among them volatile silicone. It was an excellent cosmetic material that alleviated the oily feeling during application by blending stably.
It should be noted that, when the component (A) and the component (B) were mixed in advance and blended as a paste-like composition, particularly excellent in adhesion to the skin, film uniformity and stability over time were obtained.
On the other hand, the comparative products are inferior to the products of the present invention. In particular, the comparative products 1 and 2 that do not use the specific silicone polymer of component (A) and the fructooligosaccharide fatty acid ester of component (C) are all evaluated items. It was inferior. Comparative product 3 not using the component (B) fluoroalkyl group-containing organopolysiloxane was inferior to all, but in particular, inferior in adhesion to the skin, film uniformity, and makeup lasting. Comparative products 4 and 5 that do not use the fructooligosaccharide fatty acid ester of component (C) were particularly unsatisfactory in size, inferior in film uniformity, and poor in stability over time. Further, even when a liquid oil agent, particularly volatile silicone, was blended, the adhesion to the skin, the emollient effect, and the oiliness were hardly alleviated.

Invention products 6 to 8 and comparative products 6 to 9 Sunscreen emulsions Sunscreen emulsions having the compositions shown in Table 2 were prepared, and the evaluation items were evaluated and judged according to each evaluation method. The results are also shown in Table 2.

* 8: KF96A-6cs (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 9: ABIL EM-90 (Gold Schmidt)
* 10: Fomblin HC / 04 (Ausumont)
* 11: Trifluoropropyl-modified methylpolysiloxane (X-22-820 (manufactured by Shin-Etsu Chemical Co., Ltd.))
(Production method)
A: Components 1 to 14 are dissolved by heating, and then thoroughly mixed and dispersed.
B: Components 15 to 19 are mixed uniformly.
C: After emulsification while adding B to A, component 20 was added and mixed to obtain a sunscreen emulsion.

As is apparent from the results in Table 2, the product of the present invention has a water and oil repellency improved by stably blending a fluorine-based compound, thereby obtaining a cosmetic with excellent cosmetic durability and high adhesion to the skin. It has a beautiful finish with a uniform makeup film, and it has excellent adhesion to the skin and emollient effect, among them volatile silicone. It was an excellent cosmetic material that alleviated the oily feeling during application by blending stably.
On the other hand, all of the comparative products were inferior to the products of the present invention. In particular, the comparative product 6 using a low substitution degree of the fructooligosaccharide fatty acid ester of the component (C) contains a large amount of volatile silicone, so that the solubility and gel structure are not sufficiently imparted. It became inferior in the goodness of a package and the uniformity of a film | membrane. Comparative product 7 containing no specific silicone polymer of component (A) is inferior in all evaluation items, and comparative product 8 using perfluoropolyether instead of fluoroalkyl group-containing organopolysiloxane of component (B) is In particular, the comparative product 9 that does not contain the fluoroalkyl group-containing organopolysiloxane of the component (B) is inferior in adhesion to the skin, good fit, uniformity of the film, stability over time, and the adhesion to the skin It was inferior in property, uniformity of film, and longevity. Further, even when a liquid oil agent, particularly volatile silicone, was blended, the adhesion to the skin, the emollient effect, and the oiliness were hardly alleviated.

Mascara (ingredient) (%)
1. Paraffin wax 5
2. Light liquid isoparaffin * 12 Dextrin (palmitic acid / 2-ethylhexanoic acid)
Ester * 13 5
4). Decamethylcyclopentasiloxane 20
5. Fructooligosaccharide fatty acid ester * 14 5
6). Pasty composition 1 (Production Example 1) 10
7). Fluorine compound surface-treated black iron oxide * 15 6
8). Sucrose fatty acid ester * 16 4
9. Beeswax 5
10. Rosin acid pentaerythlit * 2 5
11. Preservative appropriate amount 12. Perfume appropriate amount13. Purified water 5
* 12: IP solvent 1620 (manufactured by Idemitsu Petrochemical Co., Ltd.)
* 13: Leopard TT (Chiba Flour Mills)
* 14: Leopard ISK (Chiba Flour Mills)
* 15: Perfluoroalkyl phosphate diethanolamine 3% treated product * 16: Sugar wax S-10E (Daiichi Kogyo Seiyaku Co., Ltd.)
(Production method)
A: Components 1 to 10 are heated and dissolved, and then thoroughly mixed and dispersed.
B: Ingredients 11 and 13 are dissolved by heating.
C: Add B to A at 80 ° C., mix and disperse, then cool.
D: Component 12 was added to C and mixed to obtain a mascara.
The mascara of the present invention obtained as described above has excellent adhesion to eyelashes, does not cause unevenness, finishes quickly into a clean cosmetic film, and does not smear with sebum, sweat, or tears, and has excellent makeup. It has been proved that it exhibits extremely excellent effects in usability, usability, and stability over time.

Lip overcoat (component) (%)
1. Pasty composition 2 (Production Example 2) 20
2. Partially cross-linked polyoxyethylene-modified silicone /
Silicone mixture * 17 15
3. Perfluoropolyether * 10 20
4). Decamethylcyclopentasiloxane 10
5. Fructooligosaccharide fatty acid ester 3 (Synthesis Example 5) 2
6). Perfume appropriate amount 7. Preservative appropriate amount 8. Ethanol 5
9. Purified water remaining amount * 17: KSG-210 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Production method)
A: Components 4 to 5 are dissolved by heating and then cooled.
B: Components 1 to 3 and A are mixed.
C: Components 7 to 9 are mixed uniformly.
D: After emulsification while adding C to B, component 6 was added and mixed uniformly to obtain a lip overcoat.
The lip overcoat of the product of the present invention obtained as described above has excellent adhesion to the lips and lipstick, does not cause unevenness, quickly finishes into a beautiful makeup film, prevents stickiness, lipstick bleeding and dropping, It has been demonstrated that it has excellent makeup, has a high emollient effect, and exhibits extremely excellent effects in terms of usability, feeling of use, and stability over time.

Base cream (ingredient) (%)
1. Pasty composition 1 (Production Example 1) 15
2. Dimethylpolysiloxane * 8 5
3. Fructooligosaccharide fatty acid ester 2 (Synthesis Example 4) 7
4). Decamethylcyclopentasiloxane 5
5. Cetyl 2-ethylhexanoate 3
6). Silicone branched polyether-modified silicone * 18 2
7). Ethanol 7
8.1,3-Butylene glycol 10
9. Spherical nylon powder 2
10. Cross-linked acrylamide copolymer dispersion * 19 0.3
11. Preservative appropriate amount 12. Purified water remaining amount 13. Perfume appropriate amount * 18: KF-6028 (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 19: Sepigel 305 (manufactured by Sepic)
(Production method)
A: Components 1 to 6 are dissolved by heating and mixed uniformly.
B: Components 7 to 8 and components 10 to 12 are uniformly dissolved.
C: B is added to A and emulsified.
D: Component 9 and component 13 were added to C and sufficiently dispersed to obtain a base cream.
The foundation cream of the present invention obtained as described above is excellent in adhesion to the skin, has a good fit, and does not feel oily. In addition, a uniform film is formed, and the foundation applied on the top is finished with a clean makeup film with no unevenness. It has excellent makeup without bleeding into sebum and sweat, has a high emollient effect, and is easy to use, feel good, and stable over time. It was proved to show an extremely excellent effect.

O / W emulsified liquid foundation (component) (%)
1. Stearic acid 1
2. Cetanol 0.5
3.2 Cetyl 2-ethylhexanoate 5
4). Glyceryl tri-2-ethylhexanoate 3
5. Pasty composition 1 (Production Example 1) 1.5
6). Sorbitan sesquioleate 2
7). Fructooligosaccharide fatty acid ester 1 (Synthesis Example 3) 1
8). N-lauroyl-L-glutamate * 20 0.5
9. Glycerin 3
10. Carboxyvinyl polymer * 21 0.15
11. Triethanolamine 0.15
12.1,3-butylene glycol 10
13. Soy lecithin 0.5
14 Preservative appropriate amount15. Purified water remaining amount 16. Silica 4
17. Inorganic color pigment Appropriate amount 18. Titanium oxide 7
19. Perfume appropriate amount * 20: Erdu CL-301 (Ajinomoto Co., Inc.)
* 21: Carbopol 940 (Goodrich Chemical)
(Production method)
A: Components 1 to 8 are dissolved by heating and mixed and dispersed.
B: Components 9 to 18 are mixed and dissolved, and then sufficiently dispersed.
C: Emulsify while adding B to A at 80 ° C.
D: After cooling C, component 19 was added and mixed to obtain an O / W emulsified liquid foundation.
The O / W emulsified liquid foundation of the present invention obtained as described above is excellent in adhesion to the skin, finished in a clean makeup film without unevenness, and has excellent makeup without bleeding into sebum and sweat. The emollient effect is also high, and it has been proved that it exhibits extremely excellent effects in terms of usability, usability, and stability over time.

Pasty lipstick (ingredient) (%)
1. Polyglycerin fatty acid ester * 22 10
2. Fructooligosaccharide fatty acid ester 2 (Synthesis Example 4) 10
3. Rosin acid pentaerythritol * 2 5
4). Vaseline 10
5. Pasty composition 2 (Production Example 2) 20
6). Refined jojoba oil 20
7). Propylene glycol dicaprate 15
8). Dodecamethylcyclopentasiloxane 7
9. 10. Diisostearyl malate remaining amount Titanium oxide 1
11. Coloring pigment appropriate amount12. Perfume appropriate amount * 22: TAISET50 (manufactured by Taiyo Chemical Co., Ltd.)
(Production method)
A: Components 1 to 9 are dissolved by heating.
B: Components 10 to 12 are added to A and mixed and dispersed uniformly.
C: B is heated and filled in a container, and then cooled to obtain a pasty lipstick.
The paste-like lipstick of the present invention obtained as described above is excellent in adhesion to the lips, finished in a clean makeup film without unevenness, excellent in makeup with no bleeding or dropping, and has a high emollient effect, It was proved that it exhibits extremely excellent effects in terms of usability, usability, and stability over time.

Essence (Ingredient) (%)
1. Stearic acid 3
2. Cetanol 1
3. Glyceryl tri-2-ethylhexanoate 5
4). Fructooligosaccharide fatty acid ester * 14 0.3
5. Pasty composition 1 (Production Example 1) 0.1
6). Silicone branched polyglycerin-modified silicone * 23 2
7). Polysorbate 60 2
8). Sorbitol 5
9. Glycerin 3
10.1,3-butylene glycol 10
11. Triethanolamine 1
12 Preservative appropriate amount13. Perfume appropriate amount14. Purified water remaining amount * 23: KF-6100 (manufactured by Shin-Etsu Chemical Co., Ltd.)
(Production method)
A: Components 1 to 4 are heated and dissolved, and then components 5 to 7 and components 12 and 13 are mixed uniformly.
B: Components 8 to 11 and Component 14 are dissolved by heating.
C: After emulsification while adding A to B at 80 ° C., cool to obtain a serum.
The cosmetic liquid of the present invention obtained as described above has excellent adhesion to the skin, affinity, good fit, smooth skin, excellent skin protection, non-stickiness and high emollient effect. It has been proved that it exhibits extremely excellent effects in usability, usability, and stability over time.

Hand cream (ingredient) (%)
1. Pasty composition 2 (Production Example 2) 90
2. 2. Trifluoropropyl-modified methylpolysiloxane * 11 Residual amount 3. Fructooligosaccharide fatty acid ester 3 (Synthesis Example 5) 3
4). Vaseline 5
5. Preservative appropriate amount 6. Perfume appropriate amount (production method)
A: Components 3 to 4 are dissolved by heating.
B: Components 1 and 2 and components 5 and 6 are added to A and mixed uniformly to obtain a hand cream.
The hand cream of the present invention obtained as described above has an effect of guarding hands from dirt and water, a feeling of close contact with the skin, affinity, good fit, no stickiness, emollient effect, etc. It has been proved that it has an extremely excellent effect on feeling and stability over time.

Claims (4)

The following components (A) to (C):
(A) Organohydrogenpolysiloxane represented by the following general formula (1) R ¹ _a H _b SiO _{(4-ab) / 2} (1)
And organopolysiloxane R ¹ _c R ² _d SiO _{(4-cd) / 2} (2) represented by the following general formula (2):
A silicone polymer having a three-dimensional cross-linking structure which is insoluble in an organic solvent and can contain penta-3,3,3-trifluoropropylpentamethylcyclopentasiloxane having the same mass or more as its own weight (however, In the formula, each R ¹ may be the same or different and is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 20 carbon atoms and having no aliphatic unsaturated bond, and 11 to 60 mol% thereof. Is a monovalent hydrocarbon group which is a fluorine-substituted monovalent hydrocarbon group, R ² is a monovalent hydrocarbon group having 2 to 10 carbon atoms having a terminal vinyl group, and a is 1.0 to 2.3, b is 0.001 to 1.0, c is 1.0 to 2.3, d is 0.001 to 1.0, and 1.5 ≦ a + b ≦ 2.6, 1.5 ≦ c + d ≦ 2. .6 is satisfied.)
(B) Fluoroalkyl group-containing organopolysiloxane represented by the following general formula (3)
(In the formula, p is an integer of 4 to 6.)
(C) A hydrogen atom of a hydroxyl group of a fructooligosaccharide having an average molecular weight of 300 to 10000 is single by an acyl group (RCO-, where R represents a linear or branched alkyl group or alkenyl group having 7 to 31 carbon atoms). A cosmetic comprising a fructooligosaccharide fatty acid ester having a fatty acid substitution degree per saccharide unit of 2.2 or more. The hydrogen atom of the hydroxyl group of the fructooligosaccharide having an average molecular weight of 300 to 10,000 of the component (C) is an acyl group (RCO-, where R represents a linear or branched alkyl group or alkenyl group having 7 to 31 carbon atoms). The fructooligosaccharide fatty acid ester having a fatty acid substitution degree per monosaccharide unit of 2.2 or more and an inulin and / or hydrolyzed inulin sugar fatty acid ester having a fatty acid esterification degree per monosaccharide unit of 2.2 or more An inulin in which 60 mol% or more of the total acyl groups in the acyl group of the ester is one or more selected from a hexadecanoyl group, an octadecanoyl group, an eicosanoyl group, and a docosanoyl group, and / or the cosmetic according to claim 1, characterized in that the hydrolysis inulin sugar fatty acid ester. The cosmetic according to claim 1 or 2 , further comprising an oil that is liquid at room temperature as the component (D). 4. The cosmetic according to claim 3, wherein the liquid agent at room temperature of the component (D) is volatile silicone.