JP4865234B2 - Fuel cell stack - Google Patents

Description

  The present invention includes a unit cell in which an electrolyte / electrode structure in which a pair of electrodes are provided on both sides of an electrolyte is sandwiched between separators, and a stacked body in which a plurality of the unit cells are stacked is contained in a box-shaped casing. It relates to a battery stack.

  For example, a polymer electrolyte fuel cell employs an electrolyte membrane (electrolyte) made of a polymer ion exchange membrane. A fuel cell is configured by sandwiching an electrolyte membrane / electrode structure in which an anode side electrode and a cathode side electrode are disposed on both sides of the electrolyte membrane with a separator.

  In this fuel cell, a fuel gas, for example, a gas mainly containing hydrogen (hereinafter also referred to as hydrogen-containing gas) is supplied to the anode side electrode, while an oxidant gas, for example, A gas or air mainly containing oxygen (hereinafter also referred to as oxygen-containing gas) is supplied. In the fuel gas supplied to the anode side electrode, hydrogen is ionized on the electrode catalyst and moves to the cathode side electrode side through the electrolyte membrane. Electrons generated during that time are taken out to an external circuit and used as direct current electric energy.

  Normally, this fuel cell is used as a fuel cell stack in which a predetermined number (for example, several tens to several hundreds) is stacked in order to obtain a desired power generation. In this fuel cell stack, the stacked fuel cells need to be reliably pressurized and held in order to prevent an increase in the internal resistance of the fuel cell and a decrease in the sealing performance of the reaction gas.

  Therefore, for example, a fuel cell stack of Patent Document 1 is known. As shown in FIG. 7, the fuel cell stack includes a stacked body 2 in which a plurality of unit cells 1 are stacked, and an auxiliary plate 4 a with end plates 3 and 3 interposed at both ends in the stacking direction of the stacked body 2. 4b are arranged.

  A pair of fastening bands 5 and 5 are disposed along both side portions of the laminate 2. Cylindrical bosses 6 are provided at the ends of the fastening bands 5 and 5 and the auxiliary plates 4a and 4b so that the respective holes are aligned in a straight line. The fastening pins 5 and 5 and the auxiliary plates 4a and 4b are integrally connected by inserting the metal pin 7 into each boss portion 6.

  A plurality of bolts 8 are screwed onto the auxiliary plate 4a, while a plurality of disc springs 9 are disposed on the auxiliary plate 4b. Therefore, when the bolt 8 is screwed in, the end plate 3 is pressed downward, and the disc spring 9 disposed on the auxiliary plate 4b is compressed, which is necessary for the laminated body 2 via the pair of end plates 3. The fastening pressure is applied.

JP 2001-135344 A (FIG. 5)

  However, in Patent Document 1 described above, a plurality of bolts 8 and a plurality of disc springs 9, which are dedicated parts, are provided in order to adjust the tightening load of the fuel cell stack. Therefore, there is a problem in that the weight of the entire fuel cell stack increases due to the addition of dedicated parts.

  Moreover, between the auxiliary plates 4a and 4b, the laminated body 2 is pressed and held by bolts 8 and disc springs 9 from both ends in the laminating direction. For this reason, there is a space where the stacked body 2 is not disposed between the auxiliary plates 4a and 4b, and the fuel cell stack is considerably enlarged in the stacking direction of the unit cells 1 so that the space can be efficiently used. There is a problem that can not be.

  The present invention solves this type of problem, and provides a fuel cell stack capable of effectively utilizing a space in a casing, and having a simple and compact configuration and capable of well expanding an electrode area. For the purpose.

  The present invention is a fuel cell stack in which a stacked body in which a plurality of electrolyte / electrode structures each having a pair of electrodes provided on both sides of an electrolyte and a plurality of separators are stacked is housed in a box-shaped casing.

  The casing includes end plates arranged at both ends in the stacking direction of the laminated body, a plurality of side plates arranged at the side parts of the laminated body, and connecting pins that connect the end plates and the side plates. And the thickness center of at least one side plate is offset outward of the casing with respect to the center of the connection pin, and the side surface of the laminate is the inner wall surface of the side plate and the inner wall surface of the connection pin. It is arrange | positioned between the virtual surface which passes along the outer peripheral surface of an other side, and is parallel to the said inner wall surface.

  Moreover, it is preferable that the boss | hub part which inserts a connection pin, and an inner wall surface are continuously connected by the curved surface at least 1 side plate. When a stack tightening load is applied between the pair of connecting pins, the pair of stress concentration points acting on the side plate is close to the inner end of the curved surface, and the distance between the stress concentration points is shortened. For this reason, it is possible to satisfactorily prevent the side plate from being bent and deformed.

  In the present invention, since the thickness center of the side plate is offset outward of the casing with respect to the center of the connecting pin, the inner wall surface of the side plate can be separated from the laminate side. For this reason, by disposing the side surface of the laminate close to the inner wall surface of the side plate, the entire casing is not enlarged, and the electrode area of the laminate can be favorably expanded.

  FIG. 1 is a partially exploded schematic perspective view of a fuel cell stack 10 according to an embodiment of the present invention, and FIG. 2 is a partial cross-sectional side view of the fuel cell stack 10.

  As shown in FIG. 1, the fuel cell stack 10 includes a stacked body 14 in which a plurality of unit cells 12 are stacked in the horizontal direction (arrow A direction). A terminal plate 16a, an insulating plate 18 and an end plate 20a are sequentially disposed at one end in the stacking direction (arrow A direction) of the stacked body 14 toward the outside. At the other end in the stacking direction of the stacked body 14, a terminal plate 16b, an insulating spacer member 22 and an end plate 20b are sequentially disposed outward. The fuel cell stack 10 is integrally held by a casing 24 including end plates 20a and 20b each having a rectangular shape as end plates.

  As shown in FIGS. 2 and 3, each unit cell 12 includes an electrolyte membrane / electrode structure (electrolyte / electrode structure) 30, and a thin plate-shaped first and second sandwiching the electrolyte membrane / electrode structure 30. Second metal separators 32 and 34 are provided. Instead of the first and second metal separators 32 and 34, for example, a carbon separator may be used.

  An oxidant gas supply for supplying an oxidant gas, for example, an oxygen-containing gas, communicates with each other in the arrow A direction at one end edge of the unit cell 12 in the long side direction (the arrow B direction in FIG. 3). A communication hole 36a, a cooling medium supply communication hole 38a for supplying a cooling medium, and a fuel gas discharge communication hole 40b for discharging a fuel gas, for example, a hydrogen-containing gas, are provided.

  The other end edge in the long side direction of the unit cell 12 communicates with each other in the direction of arrow A, and a fuel gas supply communication hole 40a for supplying fuel gas, and a cooling medium discharge communication hole for discharging the cooling medium. 38b and an oxidizing gas discharge communication hole 36b for discharging the oxidizing gas are provided.

  The electrolyte membrane / electrode structure 30 includes, for example, a solid polymer electrolyte membrane 42 in which a perfluorosulfonic acid thin film is impregnated with water, and an anode side electrode 44 and a cathode side electrode 46 that sandwich the solid polymer electrolyte membrane 42. With.

  The anode side electrode 44 and the cathode side electrode 46 are uniformly coated with a gas diffusion layer (not shown) made of carbon paper or the like and porous carbon particles carrying a platinum alloy on the surface thereof. And an electrode catalyst layer (not shown) formed. The electrode catalyst layers are formed on both surfaces of the solid polymer electrolyte membrane 42.

  A fuel gas flow path 48 that connects the fuel gas supply communication hole 40 a and the fuel gas discharge communication hole 40 b is formed on the surface 32 a of the first metal separator 32 facing the electrolyte membrane / electrode structure 30. The fuel gas channel 48 is constituted by, for example, a plurality of grooves extending in the arrow B direction. On the surface 32b of the first metal separator 32, a cooling medium flow path 50 that connects the cooling medium supply communication hole 38a and the cooling medium discharge communication hole 38b is formed. The cooling medium flow path 50 is configured by a plurality of grooves extending in the arrow B direction.

  The surface 34a of the second metal separator 34 facing the electrolyte membrane / electrode structure 30 is provided with, for example, an oxidant gas flow path 52 composed of a plurality of grooves extending in the direction of arrow B, and this oxidant gas. The flow path 52 communicates with the oxidant gas supply communication hole 36a and the oxidant gas discharge communication hole 36b. A cooling medium flow path 50 is integrally formed on the surface 34 b of the second metal separator 34 so as to overlap the surface 32 b of the first metal separator 32.

  A first seal member 54 is integrally formed on the surfaces 32 a and 32 b of the first metal separator 32 around the outer peripheral end of the first metal separator 32. The first seal member 54 surrounds the fuel gas supply communication hole 40a, the fuel gas discharge communication hole 40b, and the fuel gas flow path 48 on the surface 32a so as to communicate with each other, and on the surface 32b, the cooling medium supply communication hole 38a, The medium discharge communication hole 38b and the cooling medium flow path 50 are surrounded and communicated with each other.

  A second seal member 56 is integrally formed on the surfaces 34 a and 34 b of the second metal separator 34 around the outer peripheral end of the second metal separator 34. The second seal member 56 surrounds and communicates the oxidant gas supply communication hole 36a, the oxidant gas discharge communication hole 36b, and the oxidant gas flow path 52 on the surface 34a, while the cooling medium supply communication hole on the surface 34b. 38a, the cooling medium discharge communication hole 38b, and the cooling medium flow path 50 are surrounded and communicated.

  As shown in FIG. 2, a seal 57 is interposed between the first and second seal members 54 and 56 in order to prevent the outer periphery of the solid polymer electrolyte membrane 42 from directly contacting the casing 24. Is done.

  As shown in FIG. 1, plate-like terminal portions 58a and 58b protruding in the surface direction are formed at the end portions of the terminal plates 16a and 16b. For example, a load such as a traveling motor is connected to the terminal portions 58a and 58b.

  The casing 24 is an angle member that connects end plates 20a and 20b, which are end plates, a plurality of side plates 60a to 60d disposed on the side of the laminated body 14, and end portions of the side plates 60a to 60d that are close to each other. (For example, L angle) 62a to 62d, and connection pins 64a and 64b having different lengths for connecting the end plates 20a and 20b and the side plates 60a to 60d, respectively. The side plates 60a to 60d are composed of thin metal plates.

  Two first boss portions 66a, 66b are formed to project from the upper and lower sides of the end plates 20a, 20b, respectively, and one first boss portion 66c, 66d is formed to project from each side of each side. The Holes 67a to 67d are formed through the first boss portions 66a to 66d. Mount bosses 68a and 68b are formed at the lower ends of the respective sides of the end plates 20a and 20b. The boss portions 68a and 68b are fixed to a mounting portion (not shown) via a bolt or the like, so that the fuel cell stack 10 is mounted on, for example, a vehicle.

  Two second boss portions 70a and 70b are formed at both ends in the longitudinal direction (arrow A direction) of the side plates 60a and 60c arranged on both sides in the arrow B direction of the laminate 14. Three second boss portions 72a and 72b are formed at both ends in the longitudinal direction of the side plates 60b and 60d disposed on both the upper and lower sides of the laminated body 14, respectively. Holes 71a and 71b are formed in the second boss portions 70a and 70b, and holes 73a and 73b are formed in the second boss portions 72a and 72b.

  Between the second boss portions 70a and 70b of the side plates 60a and 60c, first boss portions 66c and 66d on both sides of the end plates 20a and 20b are arranged, and a short connecting pin 64a is integrally formed therewith. The side plates 60a and 60c are attached to the end plates 20a and 20b.

  Similarly, the second boss portions 72a and 72b of the side plates 60b and 60d are alternately arranged with the first boss portions 66a and 66b on the upper and lower sides of the end plates 20a and 20b, and a long connecting pin 64b is provided on these. The side plates 60b and 60d are attached integrally to the end plates 20a and 20b.

  The side plates 60a to 60d are formed with a plurality of screw holes 74 at both edges in the short direction, respectively, while the sides 76 of the angle members 62a to 62d are formed with holes 76 corresponding to the screw holes 74. Is done. When the screws 77 inserted into the holes 76 are screwed into the screw holes 74, the side plates 60a to 60d are fixed to each other via the angle members 62a to 62d. Thereby, the casing 24 is configured (see FIG. 4).

  In addition, while forming screw holes in the angle members 62a to 62d and forming holes in the side plates 60a to 60d and arranging the angle members 62a to 62d inward of the side plates 60a to 60d, these are integrated. Alternatively, it may be screwed.

  As shown in FIGS. 2 and 5, at least in the side plate 60b, the thickness center PC of the side plate 60b is outward of the casing 24 with respect to the center O of the connecting pin 64b, that is, in a direction away from the laminate 14. Offset by distance h. The second boss portion 72 a and the inner wall surface 78 of the side plate 60 b are continuously connected by the curved surface 80. R of the curved surface 80 can be variously set, and the center is set at a position that does not interfere with the laminate 14 at least.

  The side surface (upper surface) 14 a of the laminate 14 is disposed between the inner wall surface 78 and a virtual surface 82 that passes through the outer peripheral surface of the connecting pin 64 b opposite to the inner wall surface 78 and is parallel to the inner wall surface 78. Is done. More preferably, the virtual surface 82 is set at a position passing through the center O of the connecting pin 64 b and parallel to the inner wall surface 78. In the side plate 60b, when a stack fastening load in the direction of the arrow is applied to the connecting pins 64b and 64b, a pair of stress concentration points 84 acting on the side plate 60b are generated near the inner end of the curved surface 80.

  As shown in FIG. 2, the side plate 60d is configured in the same manner as the side plate 60b described above, and a detailed description thereof is omitted. Further, the side plates 60a and 60b are configured similarly to the side plate 60b as required (see FIG. 1).

  As shown in FIGS. 1 and 2, the spacer member 22 has a rectangular shape set to a predetermined size so as to be positioned on the inner periphery of the casing 24. The spacer member 22 is adjusted in thickness in order to absorb a variation in the length of the stacked body 14 in the stacking direction and to apply a desired tightening load to the stacked body 14. Note that the spacer member 22 may not be used if the variation in the length of the stacked body 14 in the stacking direction can be absorbed by the elasticity of the first and second metal separators 32 and 34 themselves.

  The operation of the fuel cell stack 10 configured as described above will be described below.

  In the fuel cell stack 10, first, as shown in FIG. 4, an oxidant gas such as an oxygen-containing gas is supplied to the oxidant gas supply communication hole 36a of the end plate 20a, and hydrogen is supplied to the fuel gas supply communication hole 40a. Fuel gas such as contained gas is supplied. Further, a coolant such as pure water or ethylene glycol is supplied to the coolant supply passage 38a. For this reason, in the stacked body 14, the oxidant gas, the fuel gas, and the cooling medium are supplied in the arrow A direction to the plurality of unit cells 12 stacked in the arrow A direction.

  As shown in FIG. 3, the oxidant gas is introduced into the oxidant gas flow path 52 of the second metal separator 34 through the oxidant gas supply communication hole 36 a, and along the cathode side electrode 46 of the electrolyte membrane / electrode structure 30. Move. On the other hand, the fuel gas is introduced into the fuel gas passage 48 of the first metal separator 32 through the fuel gas supply communication hole 40 a and moves along the anode side electrode 44 of the electrolyte membrane / electrode structure 30.

  Therefore, in each electrolyte membrane / electrode structure 30, the oxidant gas supplied to the cathode side electrode 46 and the fuel gas supplied to the anode side electrode 44 are consumed by an electrochemical reaction in the electrode catalyst layer, Power generation is performed.

  Next, the oxidant gas consumed by being supplied to the cathode side electrode 46 flows along the oxidant gas discharge communication hole 36b, and then is discharged to the outside from the end plate 20a. Similarly, the fuel gas consumed by being supplied to the anode side electrode 44 is discharged to the fuel gas discharge communication hole 40b, flows, and is discharged from the end plate 20a to the outside.

  The cooling medium flows in the direction of arrow B after being introduced into the cooling medium flow path 50 between the first and second metal separators 32 and 34 from the cooling medium supply communication hole 38a. The cooling medium cools the electrolyte membrane / electrode structure 30, and then moves through the cooling medium discharge communication hole 38b and is discharged from the end plate 20a.

  In this case, in this embodiment, as shown in FIGS. 2 and 5, for example, in the side plate 60b, the thickness center PC of the side plate 60b is offset to the outside of the casing 24 with respect to the center O of the connecting pin 64b. In addition, the inner wall surface 78 of the side plate 60b can be separated from the laminated body 14 side. Therefore, the side surface 14a of the laminated body 14 is disposed close to the inner wall surface 78 of the side plate 60b, that is, the side surface 14a is disposed between the inner wall surface 78 and the virtual surface 82 passing through the outer peripheral surface of the connecting pin 64b. It becomes possible.

  Thereby, the casing 24 whole is not enlarged, the dimension of each unit cell 12 can be lengthened, and the effect that it becomes possible to enlarge an electrode area favorably is acquired.

  Furthermore, as shown in FIG. 5, in the side plate 60 b, the second boss portion 72 a into which the pair of connecting pins 64 b are inserted and the inner wall surface 78 are continuously connected by the curved surface 80. For this reason, when a stack tightening load is applied between the pair of connecting pins 64b, the pair of stress concentration points 84 acting on the side plate 60b are generated at positions close to the inner end of the curved surface 80.

  On the other hand, as shown in FIG. 6, in the side plate 60b1 without a curved surface, when a stack tightening load is applied between the connecting pins 64b, 64b, a pair of stress concentration points 84a acting on the side plate 60b1 is It occurs at the base end portion of the second boss portion 72a. Therefore, in the side plate 60b provided with the curved surface 80, the distance between the pair of stress concentration points 84 is shortened more effectively than between the pair of stress concentration points 84a of the side plate 60b1, and the amount of bending deformation of the side plate 60b is as described above. There is an advantage that the amount of deformation of the side plate 60b1 is considerably reduced.

1 is a partially exploded schematic perspective view of a fuel cell stack according to an embodiment of the present invention. It is a partial cross section side view of the said fuel cell stack. It is a disassembled perspective explanatory drawing of the unit cell which comprises the said fuel cell stack. It is a perspective view of the fuel cell stack. It is explanatory drawing of the side plate which comprises a casing. It is explanatory drawing of the side plate which does not provide a curved surface. 2 is an explanatory diagram of a fuel cell stack of Patent Document 1. FIG.

Explanation of symbols

DESCRIPTION OF SYMBOLS 10 ... Fuel cell stack 12 ... Unit cell 14 ... Laminated body 16a, 16b ... Terminal plate 18 ... Insulating plate 20a, 20b ... End plate 22 ... Spacer member 24 ... Casing 30 ... Electrolyte membrane and electrode structure 32, 34 ... Metal separator DESCRIPTION OF SYMBOLS 42 ... Solid polymer electrolyte membrane 44 ... Anode side electrode 46 ... Cathode side electrode 48 ... Fuel gas flow path 50 ... Cooling medium flow path 52 ... Oxidant gas flow path 54, 56 ... Sealing member 60a-60d ... Side plate 62a-62d ... Angle members 64a and 64b ... Connecting pins 66a to 66d, 70a, 70b, 72a and 72b ... Boss part 78 ... Inner wall surface 80 ... Curved surface 82 ... Virtual surface 84 ... Stress concentration point

Claims (1)

A fuel cell stack that accommodates a laminate in which a plurality of separators and an electrolyte / electrode structure in which a pair of electrodes are provided on both sides of an electrolyte is contained in a box-shaped casing,
The casing includes end plates disposed at both ends in the stacking direction of the stacked body,
A plurality of side plates disposed on the side of the laminate;
A connecting pin for connecting the end plate and the side plate;
With
A tensile load along the lamination direction of the laminate acts on the side plate,
The thickness center of at least one of the side plates is offset outward of the casing with respect to the center of the connecting pin, and
The side surface of the laminate passes through the outer wall surface of the side plate and the outer peripheral surface of the connecting pin on the opposite side to the inner wall surface side with respect to the center of the connecting pin, and is parallel to the inner wall surface. Arranged between the virtual plane ,
In at least one of the side plates, the boss portion into which the connecting pin is inserted and the inner wall surface are continuously connected by a curved surface,
The curved surface is provided only on the laminated body side, and gradually curves toward the inner side of the casing as it goes from the center side of the side plate to the connecting pin side in the lamination direction,
The fuel cell stack , wherein a position where the inner wall surface and the curved surface are connected is located closer to a center side of the side plate than the boss portion in the stacking direction .

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