JP4789478B2 - Fuel cell stack and assembly method thereof - Google Patents

Description

  The present invention relates to a fuel cell stack in which a laminate in which a plurality of electrolyte / electrode structures each having a pair of electrodes provided on both sides of an electrolyte and a separator are stacked in a horizontal direction is accommodated in a box-shaped casing, and It relates to the assembly method.

  For example, a polymer electrolyte fuel cell employs an electrolyte membrane (electrolyte) made of a polymer ion exchange membrane. An electrolyte membrane / electrode structure having an anode side electrode and a cathode side electrode in which a noble metal-based electrode catalyst layer is bonded to a base material mainly composed of carbon is sandwiched by a separator on both sides of the electrolyte membrane. A battery is configured.

  In this type of fuel cell, a fuel gas supplied to the anode side electrode, for example, a gas mainly containing hydrogen (hereinafter, also referred to as a hydrogen-containing gas) is ionized by hydrogen on the electrode catalyst, via an electrolyte. It moves to the cathode side electrode side. Electrons generated during that time are taken out to an external circuit and used as direct current electric energy.

  Normally, this fuel cell is used as a fuel cell stack in which a predetermined number (for example, several tens to several hundreds) is stacked in order to obtain a desired power generation. In this fuel cell stack, the stacked fuel cells need to be reliably pressurized and held in order to prevent an increase in the internal resistance of the fuel cell and a decrease in the sealing performance of the reaction gas.

  Therefore, for example, a fuel cell stack of Patent Document 1 is known. As shown in FIG. 14, the fuel cell stack includes a stacked body 2 in which a plurality of unit cells 1 are stacked, and auxiliary plates 4a with end plates 3 and 3 interposed at both ends in the stacking direction of the stacked body 2. 4b are arranged.

  A pair of fastening bands 5 and 5 are disposed along both side portions of the laminate 2. Cylindrical bosses 6 are provided at the ends of the fastening bands 5 and 5 and the auxiliary plates 4a and 4b so that the respective holes are aligned in a straight line. The fastening pins 5 and 5 and the auxiliary plates 4a and 4b are integrally connected by inserting the metal pin 7 into each boss portion 6.

  A plurality of bolts 8 are screwed onto the auxiliary plate 4a, while a plurality of disc springs 9 are disposed on the auxiliary plate 4b. Therefore, when the bolt 8 is screwed in, the end plate 3 is pressed downward, and the disc spring 9 disposed on the auxiliary plate 4b is compressed, which is necessary for the laminated body 2 via the pair of end plates 3. The fastening pressure is applied.

JP 2001-135344 A (FIG. 5)

  However, in Patent Document 1 described above, a plurality of bolts 8 and a plurality of disc springs 9, which are dedicated parts, are provided in order to adjust the tightening load of the fuel cell stack. Therefore, there is a problem in that the weight of the entire fuel cell stack increases due to the addition of dedicated parts.

  Moreover, since a tightening load is applied to the auxiliary plates 4a and 4b via the pair of fastening bands 5 and 5, the auxiliary plates 4a and 4b themselves are likely to be twisted. For this reason, there exists a possibility that auxiliary | assistant plates 4a and 4b may deform | transform, and there exists a problem that the torsional rigidity of the whole fuel cell stack falls.

  The present invention solves this type of problem, and the laminate can be accommodated in the casing, and the deformation of the casing can be satisfactorily prevented and the rigidity can be improved with a simple and compact configuration. It is an object of the present invention to provide a fuel cell stack and a method for assembling the same.

  The present invention is a fuel cell stack in which an electrolyte / electrode structure in which a pair of electrodes are provided on both sides of an electrolyte and a laminate in which a plurality of separators are laminated in a horizontal direction are accommodated in a box-shaped casing. .

  The casing includes end plates disposed at both ends in the stacking direction of the laminate, a plurality of side plates disposed at the side portions of the laminate, and an angle member disposed at a corner of the laminate, The angle member is provided with a first receiving part capable of abutting and supporting the end face of one side plate and a second receiving part capable of abutting and supporting the end face of the other side plate.

  Further, it is preferable that the angle member is provided between the laminate and the side plate, and is provided with a flat portion that supports the flat portion of the side plate. Furthermore, it is preferable that the surface of the angle member and the surface of the side plate are substantially flush with the side plate supported by the angle member. Furthermore, it is preferable that the angles of the first and second receiving portions of the angle member are set to be substantially the same as the angle of the end face of the side plate.

  In addition, the present invention accommodates in a box-shaped casing a laminate in which a plurality of electrolyte / electrode structures provided with a pair of electrodes on both sides of an electrolyte and a separator are stacked, and the casing includes the laminate An end plate disposed at both ends in the stacking direction of the body, a plurality of side plates disposed at a side portion of the stack, an angle member disposed at a corner of the stack, the end plate and the side plate; And a connecting member for connecting the fuel cell stack.

  First, a plurality of electrolyte / electrode structures and separators are laminated to obtain a laminated body, and after the laminated body is surrounded by an end plate and a side plate, an angle member is laminated on the laminated body from one end plate side. It inserts between the said side plates along a direction, and the end surface of the said side plate is abutted and supported by the receiving part provided in the said angle member.

  According to the present invention, the end surface of one side plate is abutted and supported by the first receiving portion of the angle member, and the end surface of the other side plate is abutted and supported by the second receiving portion of the angle member. . For this reason, the end surface of the side plate is securely held by the angle member, and it is possible to satisfactorily prevent the side plate from being deformed by twisting or the like. Thereby, with a simple and compact configuration, it is possible to satisfactorily prevent the casing from being deformed and to improve the rigidity.

  Further, according to the present invention, after the laminated body is accommodated and the casing is assembled, the angle plate is inserted between the side plates along the lamination direction of the laminated body, and the side plate is received by the receiving portion of the angle member. Can be supported easily and reliably. Accordingly, the assembly operation of the casing can be performed easily and quickly, and deformation of the casing can be satisfactorily prevented.

  FIG. 1 is a partially exploded schematic perspective view of a fuel cell stack 10 according to the first embodiment of the present invention, and FIG. 2 is a partial sectional side view of the fuel cell stack 10.

  As shown in FIG. 1, the fuel cell stack 10 includes a stacked body 14 in which a plurality of unit cells 12 are stacked in the horizontal direction (arrow A direction). A terminal plate 16a, an insulating plate 18 and an end plate 20a are sequentially disposed at one end in the stacking direction (arrow A direction) of the stacked body 14 toward the outside. At the other end in the stacking direction of the stacked body 14, a terminal plate 16b, an insulating spacer member 22 and an end plate 20b are sequentially disposed outward. The fuel cell stack 10 is integrally held by a box-shaped casing 24 including end plates 20a and 20b each having a substantially rectangular shape as end plates.

  As shown in FIGS. 2 and 3, each unit cell 12 includes an electrolyte membrane / electrode structure (electrolyte / electrode structure) 30, and a thin plate-shaped first and second sandwiching the electrolyte membrane / electrode structure 30. Second metal separators 32 and 34 are provided.

  One end edge of the unit cell 12 in the horizontal direction (in the direction of arrow B in FIG. 3) communicates with each other in the direction of arrow A to communicate with an oxidant gas, for example, an oxygen-containing gas. A hole 36a, a cooling medium supply communication hole 38a for supplying a cooling medium, and a fuel gas discharge communication hole 40b for discharging a fuel gas, for example, a hydrogen-containing gas, are provided.

  At the other end edge of the unit cell 12 in the horizontal direction, a fuel gas supply communication hole 40a for supplying fuel gas and a cooling medium discharge communication hole 38b for discharging the cooling medium communicate with each other in the direction of arrow A. , And an oxidant gas discharge passage 36b for discharging the oxidant gas.

  The electrolyte membrane / electrode structure 30 includes, for example, a solid polymer electrolyte membrane 42 in which a perfluorosulfonic acid thin film is impregnated with water, and an anode side electrode 44 and a cathode side electrode 46 that sandwich the solid polymer electrolyte membrane 42. With.

  The anode side electrode 44 and the cathode side electrode 46 are uniformly coated with a gas diffusion layer (not shown) made of carbon paper or the like and porous carbon particles carrying a platinum alloy on the surface thereof. And an electrode catalyst layer (not shown) formed. The electrode catalyst layers are formed on both surfaces of the solid polymer electrolyte membrane 42.

  A fuel gas flow path 48 that connects the fuel gas supply communication hole 40 a and the fuel gas discharge communication hole 40 b is formed on the surface 32 a of the first metal separator 32 facing the electrolyte membrane / electrode structure 30. The fuel gas channel 48 is constituted by, for example, a plurality of grooves extending in the arrow B direction. On the surface 32b of the first metal separator 32, a cooling medium flow path 50 that connects the cooling medium supply communication hole 38a and the cooling medium discharge communication hole 38b is formed. The cooling medium flow path 50 is configured by a plurality of grooves extending in the arrow B direction.

  The surface 34a of the second metal separator 34 facing the electrolyte membrane / electrode structure 30 is provided with, for example, an oxidant gas flow path 52 composed of a plurality of grooves extending in the direction of arrow B, and this oxidant gas. The flow path 52 communicates with the oxidant gas supply communication hole 36a and the oxidant gas discharge communication hole 36b. A cooling medium flow path 50 is integrally formed on the surface 34 b of the second metal separator 34 so as to overlap the surface 32 b of the first metal separator 32.

  A first seal member 54 is integrally formed on the surfaces 32 a and 32 b of the first metal separator 32 around the outer peripheral end of the first metal separator 32. The first seal member 54 surrounds the fuel gas supply communication hole 40a, the fuel gas discharge communication hole 40b, and the fuel gas flow path 48 on the surface 32a so as to communicate with each other, and on the surface 32b, the cooling medium supply communication hole 38a, The medium discharge communication hole 38b and the cooling medium flow path 50 are surrounded and communicated with each other.

  A second seal member 56 is integrally formed on the surfaces 34 a and 34 b of the second metal separator 34 around the outer peripheral end of the second metal separator 34. The second seal member 56 surrounds and communicates the oxidant gas supply communication hole 36a, the oxidant gas discharge communication hole 36b, and the oxidant gas flow path 52 on the surface 34a, while the cooling medium supply communication hole on the surface 34b. 38a, the cooling medium discharge communication hole 38b, and the cooling medium flow path 50 are surrounded and communicated. As shown in FIG. 2, a seal 57 is interposed between the first and second seal members 54 and 56 to prevent the outer periphery of the solid polymer electrolyte membrane 42 from directly contacting the casing 24.

  As shown in FIGS. 1 and 2, plate-like terminal portions 58a and 58b protruding in the surface direction are formed at the ends of the terminal plates 16a and 16b. For example, a load such as a traveling motor is connected to the terminal portions 58a and 58b.

  As shown in FIG. 1, the casing 24 includes end plates 20 a and 20 b that are end plates, a plurality of side plates 60 a to 60 d disposed on the side of the laminated body 14, and end portions of the side plates 60 a to 60 d that are close to each other. Angle members (for example, L angles) 62a to 62d that connect the portions, and connecting pins 64a and 64b having different lengths that connect the end plates 20a and 20b and the side plates 60a to 60d, respectively.

  Two boss portions 66a and 66b are formed on the upper and lower sides of the end plates 20a and 20b, respectively, and two boss portions 66a and 66b are formed on the both sides.

  Two boss portions 70a and 70b are formed at both ends in the longitudinal direction of the side plates 60a and 60c arranged on both sides of the laminated body 14, respectively. Three boss portions 72a and 72b are formed at both ends in the longitudinal direction of the side plates 60b and 60d arranged above and below the laminated body 14, respectively.

  The boss portions 70a and 70b of the side plates 60a and 60c and the boss portions 66a and 66b on both sides of the end plates 20a and 20b are alternately arranged, and a short connecting pin 64a is integrally formed therewith. The side plates 60a and 60c are inserted and attached to the end plates 20a and 20b.

  Similarly, the boss portions 72a and 72b of the side plates 60b and 60d and the boss portions 66a and 66b on the upper side and the lower side of the end plates 20a and 20b are alternately arranged, and a long connecting pin 64b is integrally formed therewith. The side plates 60b and 60d are attached to the end plates 20a and 20b. In the side plates 60a to 60d, a plurality of holes 74 are formed at both edge portions in the short direction.

  As shown in FIGS. 4 and 5, the angle members 62 a to 62 d are interposed between the laminate 14 and the side plates 60 a to 60 d and are disposed at the four corners (corner portions) of the laminate 14. The angle member 62a has a column body portion 76 having a substantially arc-shaped cross section, and flat portions 80a and 80b are integrally formed on both sides of the column body portion 76 via a first receiving portion 78a and a second receiving portion 78b. (See FIGS. 5 and 6).

  The first receiving portion 78a can abut and support the end surface 82a of the side plate 60a (one side plate), while the second receiving portion 78b can abut and support the end surface 82b of the side plate 60b (the other side plate). . The flat portions 80a and 80b support the flat portions 84a and 84b of the side plates 60a and 60b, and screw holes 86 are formed in the flat portions 80a and 80b corresponding to the holes 74 (see FIG. 1). .

  When the screws 88 inserted into the holes 74 are screwed into the screw holes 86, the end portions of the side plates 60a and 60b are integrally fixed to the angle member 62a, and the side plates 60a and 60b A substantially uniform surface is formed from the outer surface to the outer surface of the columnar portion 76 of the angle member 62a (see FIGS. 4 and 5).

  The angle members 62b to 62d are configured in the same manner as the angle member 62a described above, and the same components are denoted by the same reference numerals, and detailed description thereof is omitted. The casing 24 is configured by fixing the end portions of the side plates 60a to 60d to the angle members 62a to 62d (see FIG. 4).

  As shown in FIGS. 1 and 2, the spacer member 22 has a rectangular shape set to a predetermined size so as to be positioned on the inner periphery of the casing 24. The spacer member 22 is adjusted in thickness in order to absorb a variation in the length of the stacked body 14 in the stacking direction and to apply a desired tightening load to the stacked body 14. Note that the spacer member 22 may not be used if the variation in the length of the stacked body 14 in the stacking direction can be absorbed by the elasticity of the first and second metal separators 32 and 34 themselves.

  Next, an operation for assembling the fuel cell stack 10 will be described.

  First, with respect to an assembling apparatus (not shown), the end plate 20a, the insulating plate 18 and the terminal plate 16a are inclined surfaces (FIG. 1) such that each corner is directed downward and the height direction is sequentially increased. (See FIG. 7). 7 to 11 are oriented horizontally in the drawing, but are arranged in an inclined posture along the inclined surface.

  Further, a plurality of unit cells 12 are arranged on the terminal plate 16a. At that time, the unit cell 12 is preferably handled as a unit in which the electrolyte membrane / electrode structure 30 and the first and second metal separators 32 and 34 are integrally fixed by a fixture or the like (not shown).

  After a predetermined number of unit cells 12 are stacked along the inclined surface, the terminal plate 16b, the spacer member 22, and the end plate 20b are stacked. A pressing force is applied between the end plates 20a and 20b in the stacking direction, and in this state, side plates 60a to 60d are disposed on the side portions of the stacked body 14 (see FIG. 8).

  Next, as shown in FIG. 9, the boss portion 66a of the end plate 20a and the boss portions 70a and 70b of the side plates 60a and 60c are arranged on the same axis, and the boss portion 66a and the boss portions 70a and 70b include A short connecting pin 64a is inserted integrally. Similarly, the boss portion 66a of the end plate 20a and the boss portions 72a and 72b of the side plates 60b and 60d are arranged coaxially, and a long connecting pin 64b is integrally inserted therein. Thereby, the end plate 20a and the one end part side of the side plates 60a-60d are fixed.

  Therefore, as shown in FIG. 10, the angle members 62a to 62d are inserted between the side plates 60a to 60d along the stacking direction of the stacked body 14 from the end plate 20b side (one end plate side) (in FIG. 10). , Arrow A1 direction). Specifically, the angle member 62a inserts the flat portions 80a and 80b between the adjacent portions of the laminate 14 and the side plates 60a and 60b, and also inserts the side plate 60a into the first and second receiving portions 78a and 78b. , 60b with the end faces 82a and 82b being abutted and supported, inserted in the direction of arrow A1. The angle members 62b to 62d are inserted in the same manner as the angle member 62a.

  When the insertion of the angle members 62a to 62d is completed, a short connecting pin 64a is integrally inserted into the boss portion 66b of the end plate 20b and the boss portions 70a and 70b of the side plates 60a and 60c, and the end plate 20b. The long connecting pin 64b is integrally inserted into the boss portion 66b of the boss portion and the boss portions 72a and 72b of the side plates 60b and 60d (see FIG. 11). For this reason, both ends of the angle members 62a to 62d in the longitudinal direction are supported by both ends of the connecting pins 64a and 64b and are prevented from coming off.

  On the other hand, the angle members 62 a to 62 d and the side plates 60 a and 60 d are fixed by screwing the tips of the screws 88 inserted into the hole portions 74 into the screw holes 86. Thereby, the fuel cell stack 10 is assembled.

  In this case, in the first embodiment, the laminated body 14 is accommodated in the casing 24, and one end portions of the side plates 60a to 60d are fixed to the end plate 20a so as to correspond to the four corners of the laminated body 14. Angle members 62a to 62d are inserted in the stacking direction (arrow A1 direction). For this reason, the first and second receiving portions 78a and 78b provided on the angle members 62a to 62d are in sliding contact with the end faces 82a and 82b of the side plates 60a to 60d, and can position the side plates 60a to 60d. Thereby, the effect that the casing 24 can be assembled with high accuracy by a simple process is obtained.

  The operation of the fuel cell stack 10 configured as described above will be described below.

  First, as shown in FIG. 4, in the fuel cell stack 10, an oxidant gas such as an oxygen-containing gas is supplied to the oxidant gas supply communication hole 36a of the end plate 20a, and hydrogen is contained in the fuel gas supply communication hole 40a. Fuel gas such as gas is supplied. Further, a cooling medium such as pure water, ethylene glycol, or oil is supplied to the cooling medium supply communication hole 38a. For this reason, in the stacked body 14, the oxidant gas, the fuel gas, and the cooling medium are supplied in the arrow A direction to the plurality of sets of unit cells 12 superimposed in the arrow A direction.

  As shown in FIG. 3, the oxidant gas is introduced into the oxidant gas flow path 52 of the second metal separator 34 through the oxidant gas supply communication hole 36 a, and along the cathode side electrode 46 of the electrolyte membrane / electrode structure 30. Move. On the other hand, the fuel gas is introduced into the fuel gas passage 48 of the first metal separator 32 through the fuel gas supply communication hole 40 a and moves along the anode side electrode 44 of the electrolyte membrane / electrode structure 30.

  Therefore, in each electrolyte membrane / electrode structure 30, the oxidant gas supplied to the cathode side electrode 46 and the fuel gas supplied to the anode side electrode 44 are consumed by an electrochemical reaction in the electrode catalyst layer, Power generation is performed.

  Next, the oxidant gas consumed by being supplied to the cathode side electrode 46 flows along the oxidant gas discharge communication hole 36b, and then is discharged to the outside from the end plate 20a. Similarly, the fuel gas consumed by being supplied to the anode side electrode 44 is discharged to the fuel gas discharge communication hole 40b, flows, and is discharged from the end plate 20a to the outside.

  The cooling medium flows in the direction of arrow B after being introduced into the cooling medium flow path 50 between the first and second metal separators 32 and 34 from the cooling medium supply communication hole 38a. The cooling medium cools the electrolyte membrane / electrode structure 30, and then moves through the cooling medium discharge communication hole 38b and is discharged from the end plate 20a.

  In this case, in the first embodiment, the angle members 62 a to 62 d disposed at the four corners of the stacked body 14 include the columnar part 76 having an arcuate cross section and the first and second ends at both ends of the columnar part 76. Receiving portions 78a and 78b and flat portions 80a and 80b formed in the first and second receiving portions 78a and 78b are provided. Therefore, as shown in FIGS. 5 and 6, in the angle member 62a, the end surface 82a of the side plate 60a is abutted and supported by the first receiving portion 78a, and the end surface 82b of the side plate 60b is abutted by the second receiving portion 78b. It is supported.

  For this reason, the end faces 82a and 82b of the side plates 60a and 60b are securely held by the angle member 62a, and when the tightening load is applied to the casing 24, the side plates 60a and 60b are deformed by twisting or the like. It can be successfully blocked. Thereby, it is possible to obtain an effect that the deformation of the casing 24 can be satisfactorily prevented and the rigidity of the casing 24 can be improved with a simple and compact configuration.

  Furthermore, in the first embodiment, the flat portions 80a and 80b provided on the angle member 62a support the flat portions 84a and 84b of the side plates 60a and 60b. Accordingly, the side plates 60a and 60b are held by the angle member 62a over a relatively wide area by the flat portions 80a and 80b in addition to the first and second receiving portions 78a and 78b, and the rigidity of the casing 24 as a whole is further improved. There is an advantage that you can.

  Furthermore, the surfaces of the side plates 60a and 60b and the surface of the columnar portion 76 of the angle member 62a are substantially flush with each other, and no stepped portion is generated between them. For this reason, for example, when the auxiliary devices (not shown) are arranged directly or close to the casing 24, the wires and harnesses of the auxiliary devices do not interfere with each other, and the mountability and maintenance of the auxiliary devices are prevented. Improves. Moreover, when the side plates 60a and 60b are assembled to the angle member 62a, the assembly accuracy of the casing 24 can be effectively improved by using the surface of the angle member 62a as a reference plane.

  FIG. 12 is a partially enlarged front explanatory view of the casing 100 constituting the fuel cell stack according to the second embodiment of the present invention. In addition, the same referential mark is attached | subjected to the component same as the casing 24 which comprises the fuel cell stack 10 which concerns on 1st Embodiment, and the detailed description is abbreviate | omitted. Similarly, in the third embodiment described below, detailed description thereof is omitted.

  In the second embodiment, the angle member 62a is provided with first and second receiving portions 102a and 102b that are inclined by an angle α (α ≠ 90 °) with respect to the flat portions 80a and 80b, and the side plates 60a and 60b. Are provided with end faces 104a, 104b inclined at the same angle α. Although not shown, the other angle members 62b to 62d are configured in the same manner as the angle member 62a.

  As described above, in the second embodiment, the angle member 62a is provided with the first and second receiving portions 102a and 102b that are inclined by the angle α, respectively, while the side plates 60a and 60b are inclined by the same angle α. End surfaces 104a and 104b are provided. For this reason, the contact area of the angle member 62a and the side plates 60a and 60b is enlarged. As a result, when a tightening load is applied to the casing 100, the side plates 60a and 60b have an effect that deformation against twisting and the like can be more reliably suppressed.

Figure 13 is a partially enlarged front view of a casing 110 of a fuel cell stack that are related to the present invention.

In this case , the angle member 62a has a shape that does not have a flat portion, that is, only the column body portion 76, and first and second receiving portions 112a and 112b are formed at both ends of the column body portion 76. Is done. The first and second receiving portions 112a and 112b may be configured at right angles to each other as in the first embodiment, or configured to be inclined by a predetermined angle α as in the second embodiment. May be. Here, the first and second receiving portions 112a and 112b are set to be inclined by an angle α.

  The angle member 62a only needs to have a function of supporting the end surfaces 104a and 104b of the side plates 60a and 60b. The angle member 62a and the end portions of the side plates 60a and 60b that are close to each other are, for example, brazed or It is fixed with an adhesive or the like.

1 is a partially exploded schematic perspective view of a fuel cell stack according to a first embodiment of the present invention. It is a partial cross section side view of the said fuel cell stack. It is a disassembled perspective explanatory drawing of the unit cell which comprises the said fuel cell stack. It is a perspective view of the fuel cell stack. It is front explanatory drawing of the casing which comprises the said fuel cell stack. It is a partially expanded front explanatory view of the casing. It is explanatory drawing at the time of laminating | stacking the said unit cell. It is explanatory drawing when a side plate is arrange | positioned at the laminated body in which the said unit cell was laminated | stacked. It is explanatory drawing at the time of connecting one end plate and the said side plate. It is explanatory drawing at the time of inserting an angle member in the said casing. It is explanatory drawing at the time of connecting the other end plate and the said side plate. It is a partially expanded front explanatory view of the casing constituting the fuel cell stack according to the second embodiment of the present invention. It is a partially enlarged front view of a casing constituting the fuel cell stack that are related to the present invention. 1 is a schematic explanatory diagram of a fuel cell of Patent Document 1. FIG.

Explanation of symbols

DESCRIPTION OF SYMBOLS 10 ... Fuel cell stack 12 ... Unit cell 14 ... Laminated body 16a, 16b ... Terminal plate 18 ... Insulating plate 20a, 20b ... End plate 22 ... Spacer member 24, 100, 110 ... Casing 30 ... Electrolyte membrane electrode structure 32, 34 ... Metal separator 42 ... Solid polymer electrolyte membrane 44 ... Anode side electrode 46 ... Cathode side electrode 48 ... Fuel gas passage 50 ... Coolant flow passage 52 ... Oxidant gas passage 54, 56 ... Seal members 60a-60d ... Side plates 62a to 62d ... Angle members 64a, 64b ... Connecting pins 66a, 66b, 70a, 70b, 72a, 72b ... Boss portions 76 ... Column bodies 78a, 78b, 102a, 102b, 112a, 112b ... Receiving portions 80a, 80b ... Flat part 82a, 82b, 104a, 104b ... end face 84a, 84b ... flat part

Claims (5)

A fuel cell stack in which a stacked body in which a plurality of electrolyte / electrode structures each having a pair of electrodes provided on both sides of an electrolyte and a separator are stacked in a horizontal direction is housed in a box-shaped casing,
The casing includes end plates disposed at both ends in the stacking direction of the stacked body,
A plurality of side plates disposed on the side of the laminate;
An angle member disposed at a corner of the laminate;
Equipped with a,
The side plate is fixed to the end plate and the angle member Rutotomoni,
The angle member includes a first receiving portion that can be supported by abutting the end face of one side plate;
A second receiving portion capable of abutting and supporting the end face of the other side plate;
A flat portion disposed between the laminate and the side plate and supporting a flat portion of the side plate;
A fuel cell stack characterized by comprising: The fuel cell stack according to claim 1 Symbol placement, the while supporting the side plate by angle members, the fuel cell stack, characterized in that the surfaces of said side plate of said angle member is substantially flush. 3. The fuel cell stack according to claim 1, wherein an angle of the first and second receiving portions of the angle member is set to be substantially the same as an angle of an end surface of the side plate. The fuel cell stack according to any one of claims 1 to 3, wherein a first boss portion is formed on each side of the end plate,
A second boss part is formed at both ends of the side plate,
A fuel cell stack, wherein the first boss portion and the second boss portion are alternately arranged, and a connection pin is inserted integrally therewith. A laminate in which a plurality of electrolyte / electrode structures each having a pair of electrodes provided on both sides of an electrolyte and a separator are stacked is housed in a box-shaped casing, and the casing includes both end portions in the stacking direction of the stack. an end plate disposed, a plurality of side plates disposed on the side of the laminate, and a angle member disposed at a corner of the laminate, the side plate is in said end plate and said angle member A method for assembling a fixed fuel cell stack,
A step of laminating a plurality of the electrolyte / electrode structure and the separator to obtain the laminate, and surrounding the laminate with the end plate and the side plate;
The angle member is inserted between the side plates along the stacking direction of the laminate from one end plate side, and a flat portion provided on the angle member is inserted between the laminate and the side plate. And supporting the flat surface portion of the side plate, and abutting and supporting the end surface of the side plate by a receiving portion provided on the angle member;
A method of assembling a fuel cell stack, comprising:

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