JP4848554B2 - Production method of perovskite complex oxide with pore distribution with high catalytic activity - Google Patents

Description

The present invention relates to a method for producing a perovskite complex oxide having high activity suitable as a carrier for an automobile exhaust gas purification catalyst.

  In the latter half of 1960, automobile exhaust gas was regarded as a problem as one of the sources of air pollutants, and the purification technology was developed. Among them, automobile exhaust gas purification catalysts have been put into practical use since 1975, and are now adopted in most automobiles in the United States and Japan, and are being adopted rapidly in the EU and other countries, and have become established as environmental purification catalysts. .

As a purification catalyst for automobile exhaust gas, a three-way catalyst that simultaneously oxidizes or reduces hydrocarbons (HC), carbon monoxide (CO), and nitrogen oxides (NO _x ), which are air pollutants contained in the exhaust gas, is the mainstream. is there. The structure is such that a honeycomb-shaped substrate is coated with γ-alumina having a large specific surface area, and a noble metal such as Pt, Pd, and Rh, which are active species, is supported thereon, and further, a Ce oxide having oxygen absorbing / releasing capability. Is added.

  In the 1990s, environmental changes on a global scale are regarded as a problem, and further technological innovation is required for automobile exhaust gas purification catalysts. Under such circumstances, many attempts have been made to apply a perovskite complex oxide as a novel catalyst material to an automobile exhaust gas purification catalyst. The following patent documents are mentioned as the example.

Japanese Patent No. 1020168 Japanese Patent No. 2620624 Japanese Patent No. 1877483 Japanese Patent No. 3222184 JP-A-9-86928 JP-A-11-169711 JP-A-8-12334 JP 2004-41866 A

  However, despite many attempts as described above, the purification performance and the manufacturability of the perovskite complex oxide itself are still inadequate and have not yet been put into practical use. In addition, because of the characteristics of exhaust gas purification catalysts, the purification efficiency at low temperatures is generally low, so automakers can place the catalyst position as upstream as possible in the exhaust gas flow path to improve the purification efficiency immediately after engine startup. Measures are taken, such as keeping the exhaust gas until it reaches the catalyst by making the flow path a double pipe. However, such measures limit the degree of freedom in designing automobiles and increase the cost of exhaust gas flow path members, and it is strongly desired to establish a technique for improving the purification efficiency of the catalyst itself in a low temperature range.

  The present invention develops and provides a functional material capable of improving the removal efficiency of harmful gas components in a relatively low temperature region, and provides an excellent exhaust gas purification catalyst using the functional material.

  As shown in the above-mentioned patent document, the development of perovskite-type composite oxide catalysts in the field of exhaust gas purification catalysts has so far been centered on the investigation of the components and compositions of their own, as well as the precious metals and heat-resistant oxides to be combined. Therefore, little attention has been paid to the physical properties of the perovskite complex oxide itself.

  The inventors have investigated in detail the physical properties of perovskite complex oxides, and found, for example, that perovskite complex oxides produced by heating directly from amorphous materials can be realized with very high activity. It was. When this perovskite type complex oxide is used as a catalyst, the high activity of the complex oxide itself can improve the catalytic activity from a relatively low temperature, and as a result, the exhaust gas purification performance in a low temperature range is greatly improved. . It has been found that the high activity of the perovskite complex oxide is due to the fact that the powder has a very advantageous pore distribution for enhancing the catalytic activity. The present invention has been completed based on such findings.

That is, the perovskite complex oxide provided by the present invention has a total pore volume occupied by pores having a pore radius of 10 to 50 nm of 0.05 cc / g or more, and particularly supports a noble metal element. It is suitable for use as a catalyst.
As a method for producing such a perovskite complex oxide,
A step of reacting an aqueous solution containing ions of R element and T element with a carbonate containing ammonium ions at a reaction temperature of 60 ° C. or lower and a pH of 6 to 11 to obtain an amorphous precipitate,
Drying the precipitate to obtain an amorphous precursor;
By firing the amorphous precursor in an oxidizing atmosphere (including the case where it is air), the total pore volume occupied by pores having a pore radius of 10 to 50 nm is 0.05 cc / g or more. Obtaining a perovskite complex oxide (RTO ₃ );
There is provided a method for producing a perovskite complex oxide for exhaust gas purification catalyst having the following.

  Here, as the total value of the pore volume occupied by pores having a pore radius of 10 to 50 nm, a value determined from a pore distribution determined by a nitrogen gas adsorption method is employed.

In the above, R represents is composed of one or more rare earth element species and one T is constituted by one or more transition metal elements, or alternatively, R represents a 1 or more rare earth elements, alkali metal elements and alkaline is composed of at least one member selected from the group consisting of earth metal element, T is Ru is composed of one or more transition metal elements. Among these, the latter has a structure in which a part of the rare earth elements constituting the former R is substituted with one or more elements selected from alkali metal elements and alkaline earth metal elements.
The “rare earth elements” refers to a group of elements obtained by adding Y to a rare earth element.

  According to the present invention, a perovskite complex oxide having high activity at a relatively low temperature is provided. When this perovskite type complex oxide is used for an automobile exhaust gas purification catalyst, the purification efficiency of CO gas and the like is improved in a relatively low temperature range immediately after the start of the engine start, and various kinds of preventive measures for preventing the temperature reduction of exhaust gas reaching the catalyst Countermeasures can be reduced. Therefore, the present invention can contribute to the widespread use of exhaust gas purification catalysts with high practical value.

  As a result of detailed experiments, the inventors have found that even if the perovskite type complex oxide has the same composition, the calcined product has a difference in catalytic activity when Pd or the like is supported. And what has a high catalyst activity has a large improvement effect of the catalyst activity especially in a low temperature range.

  The inventors have conducted various studies on the relationship between the characteristics of the perovskite complex oxide and the exhaust gas purification efficiency of the catalyst using the perovskite complex oxide. As a result, it has been found that high catalytic activity can be obtained in the powder of the perovskite complex oxide having a specific pore distribution.

  The solid catalyst is composed of primary particles as one crystallite and secondary particles as an aggregate thereof, and generally pores are formed in the secondary particles, that is, in the gaps between the primary particles. When the pore radius of the composite oxide is too small, the gas diffusibility is lowered, so that the reaction activity under a condition with a high space velocity is lowered. On the other hand, if the pore radius is too large, the primary particles are rearranged and aggregated at a high temperature, and the pore volume tends to decrease. For this reason, it is considered that high catalytic activity can be obtained in a powder having a structure in which many pores having appropriate pore radii exist.

  As a result of various investigations, it has been found that a suitable range of pore radius in the perovskite-type composite oxide is 10 to 50 nm, which leads to an improvement in catalytic activity that leads to an improvement in exhaust gas purification performance particularly in a low temperature range. It was. That is, the perovskite type complex oxide having many pores having a pore radius of 10 to 50 nm has improved catalytic activity compared with conventional ones, and brings about improvement of exhaust gas purification performance particularly in a low temperature range.

  Specifically, when the total pore volume occupied by pores having a pore radius of 10 to 50 nm is 0.05 cc / g or more, the perovskite complex oxide powder provides high catalytic activity. When the total pore volume occupied by pores having a pore radius of 10 to 50 nm is 0.10 cc / g or more, the effect of improving the catalytic activity becomes more remarkable, and more preferably 0.15 cc / g or more.

The perovskite complex oxide having a pore distribution exhibiting high catalytic activity as described above can be suitably realized in a composition containing one or more rare earth elements and one or more transition metal elements. For example, in the general formula RTO ₃ of the perovskite complex oxide, R may be composed of one or more rare earth elements, and T may be composed of one or more transition metal elements. Alternatively, R is composed of one or more rare earth elements and one or more selected from alkali metal elements and alkaline earth metal elements, and T is composed of one or more transition metal elements. Can be adopted.

  Although it does not specifically limit as rare earth elements which comprise R, Y, La, Ce, Nd, Sm, Pr etc. are mentioned. The transition metal element constituting T is not particularly limited, and examples thereof include Co, Fe, Ni, Mn, Cu, Cr, V, Nb, Ti, Zr, Pt, Pd, Ru, Rh, Au, Ag, and the like. Examples of elements other than the rare earth elements constituting R include alkali metal elements or alkaline earth metal elements that are contained in the form of replacing a part of the rare earth elements. For example, Li, K, Na, Mg, Sr, Ca, Ba, etc.

  Conventionally, the production of perovskite complex oxides generally employs a method of synthesizing from intermediate substances such as hydroxides, carbonates, oxalates, acetates, cyanates and oxides. However, the perovskite complex oxide having a high catalytic activity as described above could not be produced from such a crystalline intermediate material. As a result of detailed experiments, the inventors have found that perovskite-type composite oxides exhibiting excellent catalytic activity with a large effect of improving exhaust gas purification performance in a low temperature range are not passing through the above-described crystalline intermediate substances. It has been found that a perovskite complex oxide can be obtained directly from a crystalline precursor material under low-temperature and short-time heat treatment conditions.

  That is, the perovskite type complex oxide of the present invention that provides excellent catalytic activity can be obtained by heat-treating a powdery amorphous precursor material containing an R element and a T element at a low temperature. This precursor material contains, for example, at least one kind of rare earth elements and at least one kind of transition metal element as main constituents, and contains R and T components in a quantity ratio necessary for producing a target composite oxide. It is an amorphous material. Therefore, the X-ray diffraction pattern remains in a broad state and there is no clear peak. It is desirable that the amorphous state be maintained until the heat treatment temperature for obtaining the perovskite complex oxide.

Such amorphous precursor with an aqueous solution containing ions of the element R and the element T, carbonate containing A Nmo ions (precipitating agent) and the reaction temperature 60 ° C. or less, are reacted in pH6 or precipitation The product can be made and the filtrate can be dried.

  More specifically, first, water-soluble mineral salts such as nitrates, sulfates, and chlorides of R and water-soluble mineral salts such as nitrates, sulfates, and chlorides of T, R elements and elements of T An aqueous solution in which the molar ratio is approximately 1: 1 is prepared. The molar ratio of R element to T element is ideally about 1: 1, but a perovskite complex oxide may be formed even if it is not exactly 1: 1. Therefore, even if the molar ratio of the R element and the T element slightly deviates from 1: 1, the value may be a value that can form a perovskite complex oxide. The R element may be two or more components, and the T element may be two or more components. In that case, each component may be dissolved so that the ratio of the total number of moles of elements constituting R to the total number of moles of elements constituting T is approximately 1: 1.

  It is also possible to add a material such as alumina, silica, titania, zirconia, or a heat resistant material such as a composite oxide thereof to the precursor material as long as the effect of the present invention is not hindered. In this case, by heat-treating the precursor material together with these materials, a material in which the perovskite complex oxide is interposed in these heat-resistant materials can be obtained.

  The upper limit of the ion concentration of R and T in the liquid for generating the precipitate is determined by the solubility of the salt used, but it is desirable that the R or T crystalline compound does not precipitate. Usually, the total ion concentration of R and T is desirably in the range of about 0.01 to 0.60 mol / L, but in some cases, it may exceed 0.60 mol / L.

To this solution to obtain a precipitate of amorphous, good to use a precipitating agent consisting of carbonates containing ammonium ions, as such precipitant, be used ammonium carbonated, ammonium hydrogen carbonate, etc. It is also possible to add a base such as sodium hydroxide or ammonia as necessary. Further, it is possible to obtain after the formation of the precipitate with ammonia or the like, an amorphous precursor also suitable for the perovskite-type composite oxide of the present invention by blowing carbon dioxide gas. When obtaining an amorphous precipitate, the pH of the liquid should be controlled in the range of 6-11. In the region where the pH is less than 6, the rare earth elements constituting R may not form a precipitate, which is inappropriate. On the other hand, in the region where the pH exceeds 11, in the case of the precipitating agent alone, the generated precipitate may not be sufficiently amorphized and a crystalline precipitate such as a hydroxide may be formed. The reaction temperature is preferably 60 ° C. or lower. When the reaction is started at a temperature exceeding 60 ° C., crystalline compound particles of R or T may be generated, which is not preferable because it prevents the precursor material from becoming amorphous.

  The produced precipitate is preferably separated into solid and liquid by filtration, centrifugal sedimentation, decantation, etc., and washed with water to reduce the residual impurity ions. The obtained amorphous precipitate is dried by a method such as natural drying, heat drying, or vacuum drying, and after the drying treatment, pulverization treatment or classification treatment is performed as necessary. The amorphous material thus obtained is suitable as a precursor material for obtaining a perovskite complex oxide having high catalytic activity.

The perovskite complex oxide having high catalytic activity, which is the object of the present invention , is directly synthesized by heat-treating this precursor material. If the heat treatment temperature is too low, a perovskite complex oxide is difficult to be formed. Therefore, it is necessary to raise the temperature to at least 450 ° C., preferably 500 ° C. or more. On the other hand, if the heat treatment temperature is too high, the catalytic activity of the product is lowered, so that the temperature is 1000 ° C. or lower, preferably 800 ° C. or lower, more preferably 700 ° C. or lower. The heat treatment atmosphere may be any of acid oxidizing atmosphere (including those which are atmospheric) oxygen concentration perovskite-type composite oxide is obtained, it may be if the temperature range nitrogen atmosphere or the like.

When a noble metal element is supported on the perovskite-type composite oxide fired body having a pore distribution with high catalytic activity obtained in this way, a catalyst having excellent catalytic activity in a low temperature range is obtained. Excellent exhaust gas purification performance at low temperatures. In addition, when a noble metal element that can be an active species such as Pt, Pd, and Rh is included in the T element of the RTO ₃ structure, the perovskite complex oxide itself can function as a catalyst exhibiting excellent activity. It is also effective to add a noble metal element such as Pt, Pd, Rh or the like to the T element, and further support the noble metal element using this as a carrier.

[Example 1]
Lanthanum nitrate, strontium nitrate, and iron nitrate were mixed so that the molar ratio of lanthanum element, strontium element, and iron element was 0.8: 0.2: 1. This mixture was added to water so that the total molar concentration of lanthanum element, strontium element and iron element in the liquid was 0.2 mol / L to obtain a raw material solution. While stirring the solution, the temperature of the solution was adjusted to 25 ° C., and when the temperature reached 25 ° C., the pH was adjusted to 8 while adding an ammonium carbonate solution as a precipitant. Thereafter, stirring was continued for 12 hours while maintaining the reaction temperature at 25 ° C., thereby sufficiently causing precipitation. The resulting precipitate was collected by filtration, washed with water, and dried at 110 ° C. The obtained powder is called precursor powder.

When this precursor powder was subjected to X-ray powder diffraction (using Co-Kα rays), a broad diffraction result without a peak as shown in FIG. 1 was obtained, and it was confirmed to be an amorphous material.
Next, this precursor powder was baked by heat treatment at 600 ° C. in an air atmosphere. The obtained fired product was subjected to X-ray powder diffraction (using Co—Kα ray), and as shown in FIG. 1, it was confirmed that it was a single phase of (La _0.8 Sr _0.2 ) FeO ₃ perovskite complex oxide. It was done.

  About the sintered body of the said perovskite type complex oxide, pore distribution was calculated | required by the nitrogen gas adsorption method using BELSORP28SA by Nippon Bell Co., Ltd. The results are shown in FIG. FIG. 2 is an integral pore distribution curve in which the abscissa represents the pore radius r (logarithmic scale) and the ordinate represents the volume of the pore having a radius larger than r (FIGS. 3 to 11 described later also). The same). When the total pore volume occupied by pores having a pore radius of 10 to 50 nm was determined from this pore distribution, it was 0.220 cc / g.

[Example 2]
Example 1 was repeated except that lanthanum nitrate and iron nitrate were mixed so that the molar ratio of lanthanum element to iron element was 1: 1.
When the obtained fired body was subjected to X-ray powder diffraction, it was confirmed to be a single phase of LaFeO ₃ perovskite complex oxide.
The pore distribution of the sintered body of the perovskite complex oxide was determined in the same manner as in Example 1. The result is shown in FIG. When the total pore volume occupied by pores having a pore radius of 10 to 50 nm was determined from this pore distribution, it was 0.169 cc / g.

Example 3
Example 1 was repeated except that lanthanum nitrate, strontium nitrate, and manganese nitrate were mixed so that the molar ratio of lanthanum element, strontium element, and manganese element was 0.8: 0.2: 1.
Obtained was subjected to X-ray powder diffraction of the fired product _{(La 0. 8 Sr 0.} 2) was confirmed to be a perovskite complex oxide single phase of MnO _3.
The pore distribution of the sintered body of the perovskite complex oxide was determined in the same manner as in Example 1. The result is shown in FIG. When the total pore volume occupied by pores having a pore radius of 10 to 50 nm was determined from this pore distribution, it was 0.328 cc / g.

[Comparative Example 1]
A perovskite type complex oxide was produced by a coprecipitation method, which is one of the common complex oxide production methods.
Except for adjusting the pH to 12 while adding sodium hydroxide as a precipitant, a precipitate was produced in the same manner as in Example 1, and this was filtered, washed with water, and dried to obtain a precursor powder. This precursor powder was baked by heat treatment at 600 ° C. in an air atmosphere. However not the perovskite complex oxide single phase, was raised successively heat treatment temperature, when heat-treated at _{900 ℃ (La 0. 8 Sr} 0. 2) perovskite FeO ₃ type composite oxide single phase It was confirmed by X-ray powder diffraction that a fired body comprising Therefore, in this comparative example, the firing temperature was set to 900 ° C.
Obtained at a firing temperature of _{900 ℃ (La 0. 8 Sr} 0. 2) Firing of FeO ₃ perovskite complex oxide was similarly measured with respect to the pore distribution as in Example 1. The result is shown in FIG. When the total pore volume occupied by pores having a pore radius of 10 to 50 nm was determined from this pore distribution, it was 0.012 cc / g.

[Comparative Example 2]
A perovskite type complex oxide was produced by a citric acid complex method, which is one of the common complex oxide production methods.
Similarly to Example 2, lanthanum nitrate and iron nitrate were mixed so that the molar ratio of the lanthanum element to the iron element was 1: 1. This mixture was added to water so that the total molar concentration of lanthanum and iron elements in the liquid was 0.2 mol / L, and 1.2% of the total molar concentration of lanthanum and iron elements in the liquid. Double amount of citric acid was added to obtain a raw material solution.
This raw material solution was evaporated to dryness in a hot water bath at 80 ° C. for about 3 hours while reducing the pressure with a rotary evaporator to prepare a citric acid complex.

The obtained citrate complex precursor powder was heat-treated at 600 ° C. in an air atmosphere and fired. X-ray powder diffraction of the fired product confirmed that it was a single phase of LaFeO ₃ perovskite complex oxide.
The pore distribution of the sintered body of the perovskite complex oxide was determined in the same manner as in Example 1. The result is shown in FIG. The total pore volume occupied by pores having a pore radius of 10 to 50 nm was determined from this pore distribution to be 0.032 cc / g.

[Catalyst performance evaluation]
About each baked body obtained in the said Examples 1-3 and Comparative Examples 1 and 2, Pd was carry | supported as follows and the catalyst performance was evaluated.
(A) Pd support: The fired body was impregnated with an aqueous palladium nitrate solution having a Pd content of 2.0% by weight to obtain a raw material slurry. This raw material slurry was evaporated to dryness in an oil bath at 110 ° C. for about 3 hours while reducing the pressure with a rotary evaporator, and further heat-treated at 600 ° C. in an air atmosphere to obtain a Pd-supported perovskite complex oxide.
With respect to the Pd-supported perovskite complex oxide fired body, the pore distribution was determined by the same method as described above. The results are shown in FIGS. The total pore volume occupied by pores having a pore radius of 10 to 50 nm was determined from these pore distributions.
(B) Pellet preparation: Pd-supported fired body is pulverized into powder, which is pressed with a tablet molding machine to form a plate having a thickness of about 2 to 3 mm, and then crushed and sieved to give 1 to 2 mm pellets The particles were sized.
(C) Evaluation of catalyst activity: After filling the above-mentioned pellets in a flow-through fixed bed to a volume of 3 cc, the vehicle exhaust model gas (equivalent point composition) shown in Table 1 was contacted at a space velocity of 60000 / h, and the outlet The HC concentration was measured with a general-purpose gas analysis unit FIA-510 (manufactured by Horiba, Ltd.), and the CO concentration was measured with a general-purpose gas analysis unit VIA-510 (manufactured by Horiba, Ltd.). At the time of measurement, while raising the temperature from room temperature to 600 ° C. at a rate of temperature rise of 10 ° C./min, the temperature of the pellet at which the purification rate of each gas component of HC and CO reaches 50% (hereinafter referred to as “T50”) ) Was used as an index of activity. The results are shown in Table 2.

  As can be seen from Table 2, the examples in which the perovskite type complex oxide having a total pore volume occupied by pores having a pore radius of 10 to 50 nm as large as 0.05 cc / g or more are used as the support Also in the supported catalyst, the total pore volume occupied by pores having a pore radius of 10 to 50 nm was 0.05 cc / g or more. As a result, it was confirmed that the T50 of the CO gas was particularly lower than that of the comparative example, and the exhaust gas purification performance in the low temperature range immediately after the start of the engine was improved. The HC gas also showed a low temperature purification performance equivalent to or better than that of the comparative example.

The figure which illustrated the X-ray-diffraction pattern about the amorphous precursor in Example 1, the perovskite type complex oxide, and the perovskite type complex oxide after carrying | supporting Pd. 3 is a graph showing the pore distribution of the perovskite complex oxide of Example 1. FIG. 6 is a graph showing the pore distribution of the perovskite complex oxide of Example 2. 6 is a graph showing the pore distribution of the perovskite complex oxide of Example 3. 6 is a graph showing the pore distribution of the perovskite complex oxide of Comparative Example 1. 6 is a graph showing the pore distribution of the perovskite complex oxide of Comparative Example 2. 2 is a graph showing the pore distribution of “Pd-supported perovskite complex oxide” in which Pd is supported on the perovskite complex oxide of Example 1. FIG. 7 is a graph showing the pore distribution of “Pd-supported perovskite complex oxide” in which Pd is supported on the perovskite complex oxide of Example 2. FIG. 7 is a graph showing the pore distribution of “Pd-supported perovskite complex oxide” in which Pd is supported on the perovskite complex oxide of Example 3. FIG. 3 is a graph showing the pore distribution of “Pd-supported perovskite complex oxide” in which Pd is supported on the perovskite complex oxide of Comparative Example 1; 7 is a graph showing the pore distribution of “Pd-supported perovskite complex oxide” in which Pd is supported on the perovskite complex oxide of Comparative Example 2.

Claims (1)

A step of adding a carbonate containing ammonium ion to an aqueous solution containing ions of R element and T element, and reacting at a reaction temperature of 60 ° C. or lower and pH 6-11 to obtain an amorphous precipitate;
Drying the precipitate to obtain an amorphous precursor;
By firing the amorphous precursor in an oxidizing atmosphere (including the case where it is air) at 450 to 1000 ° C., the total pore volume occupied by pores having a pore radius of 10 to 50 nm Obtaining a perovskite type complex oxide (RTO ₃ ) having an A of 0.05 cc / g or more,
A method for producing a perovskite complex oxide for an exhaust gas purification catalyst.
However, R includes only La, or includes both La and Sr, and T includes Fe or Mn .

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