JP4766638B2 - Indicator for heating transpiration drug - Google Patents

Indicator for heating transpiration drug Download PDF

Info

Publication number
JP4766638B2
JP4766638B2 JP2001199091A JP2001199091A JP4766638B2 JP 4766638 B2 JP4766638 B2 JP 4766638B2 JP 2001199091 A JP2001199091 A JP 2001199091A JP 2001199091 A JP2001199091 A JP 2001199091A JP 4766638 B2 JP4766638 B2 JP 4766638B2
Authority
JP
Japan
Prior art keywords
drug
indicator
mark
color
medicine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2001199091A
Other languages
Japanese (ja)
Other versions
JP2002293703A (en
Inventor
聡 山▲崎▼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fumakilla Ltd
Original Assignee
Fumakilla Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP2001199091A priority Critical patent/JP4766638B2/en
Application filed by Fumakilla Ltd filed Critical Fumakilla Ltd
Priority to AU2001284452A priority patent/AU2001284452B2/en
Priority to BRPI0116528-3A priority patent/BR0116528B1/en
Priority to EP01963465A priority patent/EP1356731B1/en
Priority to DE60144442T priority patent/DE60144442D1/en
Priority to HU0303003A priority patent/HU228096B1/en
Priority to AT01963465T priority patent/ATE505080T1/en
Priority to CNB018217141A priority patent/CN1291647C/en
Priority to MXPA03006740A priority patent/MXPA03006740A/en
Priority to US10/433,519 priority patent/US7449154B2/en
Priority to KR1020037008234A priority patent/KR100746520B1/en
Priority to CA002473552A priority patent/CA2473552A1/en
Priority to PCT/JP2001/007728 priority patent/WO2002060254A1/en
Priority to PL01363451A priority patent/PL363451A1/en
Priority to IL156333A priority patent/IL156333A/en
Priority to NZ526268A priority patent/NZ526268A/en
Priority to TW090126077A priority patent/TWI225772B/en
Priority to ARP010105057A priority patent/AR031166A1/en
Priority to MYPI20015024A priority patent/MY136846A/en
Priority to PE2001001109A priority patent/PE20020725A1/en
Priority to EG20011189A priority patent/EG23053A/en
Priority to GCP20021829 priority patent/GC0000383A/en
Publication of JP2002293703A publication Critical patent/JP2002293703A/en
Priority to HR20030529A priority patent/HRP20030529A2/en
Priority to HK03109171.9A priority patent/HK1056666A1/en
Publication of JP4766638B2 publication Critical patent/JP4766638B2/en
Application granted granted Critical
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Landscapes

  • Agricultural Chemicals And Associated Chemicals (AREA)

Description

【0001】
【発明の属する技術分野】
本発明は、主として薬剤加熱蒸散容器にセットし、加熱蒸散薬剤の薬剤始点、薬剤終点を表示する加熱蒸散薬剤用インジケータに関する。
【0002】
【従来の技術】
薬剤加熱蒸散容器に加熱蒸散薬剤を設け、発熱体で加熱蒸散薬剤を加熱して蒸散する薬剤加熱蒸散装置が種々提案されている。
この薬剤加熱蒸散装置においては、薬剤加熱蒸散容器にインジケータをセットし、このインジケータで薬剤の始点と薬剤の終点を表示し、薬剤の薬効成分が消滅したことを使用者が認識できるようにしている。
【0003】
前述のインジケータとしては、加熱することで変色する物、例えば特開昭55−152059号公報に示す熱変色性積層物を用い、加熱時間の経過とともに無色から着色に変化させ、その変色と薬剤の薬効成分の消滅(薬剤終点)を合わせたものが提案されている。
また、変色を利用して「おわり」の文字を表示したり、シート全体が終点色に変色するようにしたインジケータが提案されている。
【0004】
【発明が解決しようとする課題】
前述のように、無色から着色への変色、別の色への変色だけでは、薬剤終点の時の色、つまり終点色の判別があいまいで分かり難く、使用者が薬剤の薬効成分が消滅したことを認識し難い。
【0005】
そこで、本発明は前述の課題を解決できるようにした加熱蒸散薬剤用インジケータを提供することを目的とする。
【0006】
【課題を解決するための手段】
第1の発明は、加熱による不可逆反応で起こる色変化を利用した薬剤使用期限を表示するインジケータであって、一つの色変化によって、視認可能なマークを視認不可能なマークへ、視認不可能なマークを視認可能なマークへ、の二つの変化を異なる箇所において同時に起こすことで、薬剤始点から薬剤終点に到る経過とともに薬剤使用状態を表現することを特徴とする加熱蒸散薬剤用インジケータである。
【0007】
第2の発明は、第1の発明において、視認可能から視認不可能へ変化させられる第1のマークが薬剤終点色で表現され、視認不可能から視認可能へ変化させられる第2のマークが薬剤始点色で表現された加熱蒸散薬剤用インジケータである。
【0008】
第3の発明は、第1又は第2の発明に記載したマークが文字であること特徴とする加熱蒸散薬剤用インジケータである。
【0009】
第4の発明は、第1乃至第3の発明において、前記色変化は、突然ではなく加熱時間の経過に伴って徐々に進行する加熱蒸散薬剤用インジケータである。
【0010】
【作 用】
第1の発明によれば、インジケータ中に、視認可能なマークが視認不可能なマークへ変化して消滅していく第1のマークと、視認不可能なマークが視認可能なマークへ変化して現出してくる第2のマークの、二つのマークが存在するため、薬剤終点となって薬効成分が消滅したことを使用者がはっきりと認識できる。
【0011】
第2の発明によれば、第1のマークと第2のマークの視認上の変化で薬剤終点となって薬効成分が消滅したことを使用者がはっきりと認識できる。
【0012】
の発明によれば、加熱時間の経過に伴って、徐々に第1のマークが消滅し、第2のマークが現出してくる変化を観察することで、薬剤使用状態、つまり薬剤の薬効成分残存量を使用者がはっきりと認識できる。
【0013】
【発明の実施の形態】
図1に示すように、薬剤加熱蒸散容器1と、薬剤含有体保持容器2と、薬剤含有体3で薬剤加熱蒸散装置を形成する。
前記薬剤加熱蒸散容器1は、下部容器10と上部容器11をビス12で連結した形状である。前記下部容器10は一側面に開口した薬剤含有体挿入部13と、この薬剤含有体挿入部13の下部を下面に開口する空気取入部14を有し、発熱体15が取付けてある。この発熱体15の最高表面温度は50℃〜250℃である。
この発熱体15の発熱面15aは水平に対して斜めで、前記薬剤含有体挿入部13に開口している。
前記下部容器10にスイッチ部16、押釦17、ランプ18が取付けてある。この押釦17を押すことでスイッチ部16がONして発熱体15に通電されて発熱し、ランプ18が点灯する。
【0014】
前記薬剤含有体保持容器2は、上面板20と下面板21と前面板22と後面板23と両側面板24で略箱形状で、前面板22に空気出口25が形成され、後面板23に空気入口26が形成してある。
前記下面板21と前面板22との間に隙間27が有り、その下面板21は着脱自在である。
この薬剤含有体保持容器2は、薬剤含有体挿入部13内に挿入され、下面板21が発熱体15の発熱面15aに接すると共に、ストッパ19に当たる。
【0015】
前記薬剤含有体3は加熱することで蒸散する薬剤が含浸された矩形板状で、前記下面板21を外すことで薬剤含有体保持容器2内に設けられる。
この薬剤含有体3の内面と薬剤含有体3の表面との間に空気流通用の隙間があり、発熱体15を発熱することで矢印で示すように空気が流れ、蒸散した薬剤がスムーズに拡散される。
【0016】
前記加熱することで蒸散する薬剤とは、発熱体15の最高温度が常温より5℃以上の時に空気中に放出される薬剤である。
この薬剤としては、殺虫剤、殺ダニ剤、殺菌剤、防虫剤、芳香剤、消臭剤、害虫忌避剤等である。
【0017】
前記薬剤含有体保持容器2の前面板22にインジケータ30が取付けてある。
このインジケータ30は薬剤含有体挿入部13から目視可能である。
【0018】
前記インジケータ30は、加熱による不可逆反応で起こる色変化を利用した薬剤使用期限を表示するもので、前記色変化によって視認可能なマークを視認不可能なマークへ、視認不可能なマークを視認可能なマークへの二つの変化を同時に起こす、すなわち2ヶ所以上、色の視認変化を同時に起こすことで薬剤始点から薬剤終点に到る経過とともに薬剤使用状態を表現するものである。
詳しくは、加熱による不可逆反応で起こる色変化を利用して始点色から終点色に色変化する変色部と、この終点色で薬剤始点を表現する第1のマークと、前記始点色で薬剤終点を表現する第2のマークを有するインジケータである。
【0019】
前記変色部は、加熱時間の経過に伴って、始点色から終点色に徐々に色変化する。
これによって、薬剤使用状態、つまり薬剤の薬効成分残存量を使用者がはっきりと認識できる。
【0020】
前記色変化の程度が、色差Δ(デルタ)E=10以上である。
これによって、見た目の視認性が良い。
つまり、前記色差がΔE=10以下であると見た目の視認性が極端に落ちる。
【0021】
前記変色部の変色する最高温度は35℃〜200℃である。
【0022】
前記インジケータ30の具体形状を図2に基づいて説明する。
ベース層31と変色層32と印刷層33を重ね合わせたフィルムラミネート構成で、印刷層33の表面にプレート34が設けられる。
前記ベース層31と変色層32と印刷層33は図2で分離して図示してあるが、これらはあらかじめ変色層32を挟持する形で重ね合わせて密着してある。
この重ね合わせて密着したベース層31、変色層32、印刷層33が前記薬剤含有体保持容器2の前面板22に形成した凹部22aに嵌め込みして取付けられる。
前記プレート34は一対のピン34aを有し、そのピン34aを前記前面板22の孔22bに嵌合することで取付けられる。
【0023】
前記ベース層31は、隠蔽性の高い50ミクロン以上の不透明フィルムを基材とする。このベース層31は、インジケータを設置したときの薬剤含有体保持容器などの色の影響が、インジケータの色見に影響を及ぼし難くするための隠蔽機能と、打ち抜きやカッティングや整列、吸引、押出しといった製造に係わる基本物性を調整する役割を有している。
【0024】
前記変色層32は熱変色物質を保持する。この変色層32が変色部である。
前記変色層32の変色前の色(始点色)はベース層31と同じ色である。
【0025】
前記熱変色物質としては、例えば混合もしくは接触により呈色反応もしくは変色反応を示す2つの薬剤の一方を含浸もしくは被覆させた支持体あるいは皮膜形成成分中に溶解もしくは分解させて得られる皮膜である第1層、第1層上に設けられた所望温度にて2つの薬剤の少なくとも一方を拡散移行せしめる樹脂皮膜である第2層および第2層上に設けられたもう一方の薬剤を含む第3層からなり、前記呈色反応もしくは変色反応は、酸塩基物質あるいは酸塩基指示薬、酸化−還元剤および酸化還元指示剤、金属化合物とキレート化剤などの混合もしくは接触により起き、前記第1層と第3層を隔てる加熱により拡散移行せしめる第2層である樹脂皮膜は、ポリエステル、ポリアミド、アクリル系樹脂である熱変色性積層物が用いられる。
【0026】
前記印刷層33は5〜30ミクロンの透明フィルムを基材とする。
この透明フィルム、一般的には裏面(変色層32側の面)に表示マークが印刷されている。
前記透明フィルムは変色層32の保護機能、適度な酸素透過機能を有する。
【0027】
前記プレート34は透明フィルムで、紫外線吸収剤が混合してある。
このプレート34で紫外線が変色層32に当たることを防止し、紫外線で変色しないようにしてある。
また、印刷層33の基材フィルムに紫外線吸収剤をねり込み、又は塗布することもできる。
【0028】
次に第1の具体例を説明する。
ベース層31は白色である。変色層32は変色前が白色で、変色後が赤色である。
印刷層33には図2に示すように、赤色で「はじめ」の文字(つまり、薬剤始点を表現する第1のマーク)、白色で「おわり」の文字(つまり、薬剤終点を表現する第2のマーク)、「はじめ」の文字から「おわり」の文字に向う矢印が印刷してある。
前記矢印は「はじめ」の文字側部が赤色で、「おわり」の文字に向けて順次色がうすくなり、「おわり」の文字側部が白色のグラデーション印刷である。
【0029】
インジケータ30の薬剤加熱蒸散開始時は、図3(a)に示すように、「はじめ」の文字と「はじめ」の文字寄りの矢印が視認できる外観である。
薬剤加熱時間の経過とともに図3(b)に示すように変色層32がうすい赤色に変色し、「おわり」の文字がぼんやりと視認できる外観となる。
前記「おわり」の文字と変色層32の赤色の濃淡の差は小である。
薬剤加熱時間がさらに経過すると図3(c)に示すように変色層32がやや濃い赤色に変色し、「おわり」の文字がややはっきりと視認できる外観となる。
【0030】
このように外観が変化するので、「はじめ」の文字と変色層32の赤色の濃淡の差によって、薬剤加熱時間、つまり薬剤含有体3に含有されている薬剤の残量を使用者が認識できる。
【0031】
薬剤加熱時間が終了して薬剤終了、つまり薬剤含有体3に含有されている薬剤の残量が有効量を下回った時は、図3(d)に示すように「はじめ」の文字の赤色と変色層32の赤色が同じ濃度となるので、「はじめ」の文字は視認できずに「おわり」の文字がはっきりと視認できる外観となる。
【0032】
このようであるから、使用者は薬効成分が消滅したことをはっきりと認識することができる。
【0033】
次に第2の具体例を説明する。
ベース層31は白色である。変色層32は変色前が白色で、変色後が赤色である。
印刷層33には図4(a)に示すように、赤色で「はじめ」の文字、白色で「おわり」の文字、白色の第1帯状部35、うすい赤色の第2帯状部36、やや濃い赤色の第3帯状部37、「はじめ」の文字と同じ濃さの赤色の第4帯状部38が連続して印刷してある。
【0034】
薬剤加熱開始時は、図4(a)に示すように、「はじめ」の文字と第2・第3・第4帯状部36,37,38が視認できる外観である。
薬剤加熱時間の経過とともに図4(b)に示すように、変色層32がうすい赤色に変色し、第1・第3・第4帯状部35,37,38が視認できると共に、第2帯状部36が視認できなくなる。
薬剤加熱時間がさらに経過すると図4(c)に示すように、変色層32がやや濃い赤色に変色し、第1・第2・第4帯状部35,36,38が視認され、第3帯状部37が視認できなくなる。
【0035】
薬剤加熱時間が終了して薬剤終了した時には、図4(d)に示すように、「おわり」の文字と第1・第2・第3帯状部35,36,37が視認でき、第4帯状部38が視認できなくなる。
【0036】
このように、薬剤加熱時間を第1・第2・第3・第4帯状部35,36,37,38を視認することで認識できる。
なお、「はじめ」の文字、「おわり」の文字の視認は第1の具体例と同様に変化する。
【0037】
次に第3の具体例を説明する。
図5に示すように、透明なフィルムより成る印刷層33の左半分33aを「す」の文字形を除いて、赤色に印刷し、右半分33bを「せん」の文字形を除いて白色に印刷する。
前記左半分33aの赤色印刷層の中で透明に抜かれた「す」の文字の前に、更に白色で「使用できま」の文字を印刷する。
【0038】
薬剤加熱開始時には図6(a)に示すように、「使用できます」の文字が視認できる。
薬剤加熱時間の経過とともに変色層32が赤色に徐々に変色するので、図6(b)、図6(c)に示すように「す」の文字が徐々にうすく視認され、「せん」の文字が徐々にはっきりと視認される外観となる。
【0039】
薬剤加熱時間が終了し薬剤終了すると、図6(d)に示すように「す」の文字が視認できずに、「せん」の文字がはっきりと視認できる外観となるので、使用者は「使用できません」の文字を視認できる。
【0040】
前記インジケータ30は薬剤加熱蒸散容器1の発熱体15の近くで外部から目視可能な位置を設けるのが好ましい。
【0041】
【発明の効果】
請求項1に係る発明によれば、2ヶ所以上、色の視認変化を起こすので、薬剤終点となって薬効成分が消滅したことを使用者がはっきりと認識できる。
【0042】
請求項2に係る発明によれば、第1のマークと第2のマークの色の視認変化で薬剤終点となって薬効成分が消滅したことを使用者がはっきりと認識できる。
【0043】
請求項に係る発明によれば、加熱時間の経過に伴って、徐々に一つのマークが消滅していき、他方のマークが現出してくる変化を観察することで、薬剤使用状態、つまり薬剤の薬効成分残存量を使用者がはっきりと認識できる。
【図面の簡単な説明】
【図1】薬剤加熱蒸散装置の断面図である。
【図2】インジケータの取付部とインジケータの分解斜視図である。
【図3】インジケータの第1の具体例の色変化説明図である。
【図4】インジケータの第2の具体例の色変化説明図である。
【図5】インジケータの第3の具体例における印刷層の斜視図である。
【図6】第3の具体例の色変化説明図である。
【符号の説明】
1…薬剤加熱蒸散容器、2…薬剤含有体保持容器、3…薬剤含有体、15…発熱体、30…インジケータ、31…ベース層、32…変色層、33…印刷層。
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to an indicator for a heat transpiration drug which is mainly set in a drug heat transpiration container and displays a drug start point and a drug end point of the heat transpiration drug.
[0002]
[Prior art]
Various chemical heating transpiration devices have been proposed in which a thermal transpiration chemical is provided in a chemical heating transpiration container, and the thermal transpiration chemical is heated and evaporated by a heating element.
In this medicine heating transpiration device, an indicator is set in the medicine heating transpiration container, the starting point of the medicine and the ending point of the medicine are displayed by this indicator, and the user can recognize that the medicinal component of the medicine has disappeared. .
[0003]
As the above-mentioned indicator, a substance that changes color by heating, for example, a thermochromic laminate as shown in JP-A-55-152059, is changed from colorless to colored with the elapse of heating time, A combination of disappearance of medicinal components (end point of drug) has been proposed.
In addition, an indicator has been proposed in which a character “end” is displayed using discoloration, or the entire sheet is discolored to the end color.
[0004]
[Problems to be solved by the invention]
As mentioned above, the color change from colorless to colored, or only from a different color, the color at the end of the drug, that is, the end point color is ambiguous and difficult to understand, and the user has lost the medicinal component of the drug It is difficult to recognize.
[0005]
Therefore, an object of the present invention is to provide an indicator for a heat transpiration drug capable of solving the above-mentioned problems.
[0006]
[Means for Solving the Problems]
1st invention is an indicator which displays the chemical | medical agent expiration date using the color change which arises by the irreversible reaction by heating, Comprising: By one color change, a visible mark becomes an invisible mark. It is a heat evaporation medicine indicator characterized by expressing a medicine use state with progress from a medicine start point to a medicine end point by causing two changes of a mark to a visible mark simultaneously in different places .
[0007]
The second aspect, in the first aspect, the first mark that is allowed change to invisible from visible is represented by drug endpoint color, a second mark that is allowed change to visible from invisible Is an indicator for a heat-vaporized medicine expressed in the starting color of the medicine.
[0008]
3rd invention is the indicator for heat | fever evaporation chemical | medical agents characterized by the mark described in 1st or 2nd invention being a character .
[0009]
According to a fourth aspect of the present invention, in the first to third aspects, the color change is not an abrupt, but is an indicator for a heat transpiration agent that gradually progresses with the passage of heating time .
[0010]
[Operation]
According to the first invention, in the indicator, the visible mark changes to an invisible mark and disappears, and the invisible mark changes to a visible mark. Since there are two marks of the second mark that appears, the user can clearly recognize that the medicinal component has disappeared as the drug end point.
[0011]
According to the second aspect of the invention, the user can clearly recognize that the medicinal component has disappeared due to the visual change of the first mark and the second mark as the drug end point.
[0012]
According to the fourth aspect of the invention, by observing the change in which the first mark gradually disappears and the second mark appears as the heating time elapses, the drug use state, that is, the drug efficacy The user can clearly recognize the remaining amount of ingredients.
[0013]
DETAILED DESCRIPTION OF THE INVENTION
As shown in FIG. 1, the drug heating transpiration device 1, the drug containing body holding container 2, and the drug containing body 3 form a drug heating transpiration device.
The chemical heating transpiration container 1 has a shape in which a lower container 10 and an upper container 11 are connected by screws 12. The lower container 10 has a drug-containing body insertion part 13 opened on one side surface and an air intake part 14 that opens a lower part of the drug-containing body insertion part 13 on the lower surface, and a heating element 15 is attached. The maximum surface temperature of the heating element 15 is 50 ° C to 250 ° C.
The heat generating surface 15a of the heat generating body 15 is inclined with respect to the horizontal and opens to the medicine-containing body insertion portion 13.
A switch portion 16, a push button 17, and a lamp 18 are attached to the lower container 10. When the push button 17 is pressed, the switch unit 16 is turned on to energize the heating element 15 to generate heat, and the lamp 18 is turned on.
[0014]
The medicine-containing body holding container 2 is substantially box-shaped with an upper surface plate 20, a lower surface plate 21, a front surface plate 22, a rear surface plate 23, and both side surface plates 24, and an air outlet 25 is formed in the front surface plate 22. An inlet 26 is formed.
There is a gap 27 between the lower plate 21 and the front plate 22, and the lower plate 21 is detachable.
The medicine-containing body holding container 2 is inserted into the medicine-containing body insertion portion 13, and the lower surface plate 21 contacts the heat generating surface 15 a of the heat generating body 15 and hits the stopper 19.
[0015]
The drug-containing body 3 is a rectangular plate impregnated with a drug that evaporates when heated, and is provided in the drug-containing body holding container 2 by removing the lower surface plate 21.
There is a gap for air circulation between the inner surface of the drug-containing body 3 and the surface of the drug-containing body 3, and when the heating element 15 generates heat, the air flows as shown by the arrows, and the evaporated drug diffuses smoothly. Is done.
[0016]
The drug that evaporates by heating is a drug that is released into the air when the maximum temperature of the heating element 15 is 5 ° C. or more from room temperature.
Examples of such agents include insecticides, acaricides, bactericides, insect repellents, fragrances, deodorants, and insect repellents.
[0017]
An indicator 30 is attached to the front plate 22 of the medicine-containing body holding container 2.
This indicator 30 is visible from the medicine-containing body insertion portion 13.
[0018]
The indicator 30 displays the expiration date of the medicine using a color change caused by an irreversible reaction caused by heating. The visible mark can be changed from a visible mark to an invisible mark by the color change. Two changes to the mark are caused at the same time, that is, two or more places are visually changed at the same time to express the state of use of the medicine along with the progress from the medicine start point to the medicine end point.
Specifically, a color changing portion that changes from a start point color to an end point color using a color change caused by an irreversible reaction due to heating, a first mark that expresses a drug start point with this end point color, and a drug end point with the start point color It is an indicator which has the 2nd mark to express.
[0019]
The discoloration part gradually changes from the start color to the end color as the heating time elapses.
Thus, the user can clearly recognize the drug use state, that is, the remaining amount of the medicinal component of the drug.
[0020]
The degree of the color change is a color difference Δ (delta) E = 10 or more.
Thereby, the visual visibility is good.
That is, when the color difference is ΔE = 10 or less, the visual visibility is extremely lowered.
[0021]
The maximum temperature at which the color changing portion changes color is 35 ° C to 200 ° C.
[0022]
A specific shape of the indicator 30 will be described with reference to FIG.
A plate 34 is provided on the surface of the print layer 33 in a film laminate configuration in which the base layer 31, the color changing layer 32 and the print layer 33 are superposed.
The base layer 31, the color changing layer 32 and the printing layer 33 are shown separately in FIG. 2, but they are overlapped and adhered in advance so as to sandwich the color changing layer 32.
The base layer 31, the discoloration layer 32, and the printing layer 33 that are in close contact with each other are fitted into and attached to a recess 22 a formed on the front plate 22 of the drug-containing body holding container 2.
The plate 34 has a pair of pins 34 a and is attached by fitting the pins 34 a into the holes 22 b of the front plate 22.
[0023]
The base layer 31 is made of an opaque film having a high concealability of 50 microns or more. This base layer 31 has a concealing function for making the influence of the color of the medicine-containing body holding container or the like when the indicator is installed difficult to affect the color of the indicator, and punching, cutting, alignment, suction, extrusion, etc. It has the role of adjusting basic physical properties related to manufacturing.
[0024]
The color changing layer 32 holds a thermochromic material. The color change layer 32 is a color change portion.
The color (starting color) before the color change of the color change layer 32 is the same color as the base layer 31.
[0025]
Examples of the thermochromic substance include a support obtained by impregnating or coating one of two agents exhibiting a color reaction or a color change reaction by mixing or contact, or a film obtained by dissolving or decomposing in a film forming component. 1st layer, 2nd layer which is the resin film which carries out the diffusion transfer of at least one of 2 chemical | medical agents at the desired temperature provided on the 1st layer, and the 3rd layer containing the other chemical | medical agent provided on the 2nd layer The color reaction or color change reaction is caused by mixing or contacting an acid-base substance or an acid-base indicator, an oxidation-reduction agent and an oxidation-reduction indicator, a metal compound and a chelating agent, and the first layer and the color change reaction. A thermochromic laminate made of polyester, polyamide, or acrylic resin is used for the resin film that is the second layer that is diffused and transferred by heating that separates the three layers.
[0026]
The printing layer 33 is based on a transparent film of 5 to 30 microns.
A display mark is printed on the transparent film, generally the back surface (the surface on the side of the color changing layer 32).
The transparent film has a protective function for the discoloration layer 32 and an appropriate oxygen permeation function.
[0027]
The plate 34 is a transparent film and is mixed with an ultraviolet absorber.
The plate 34 prevents the ultraviolet rays from hitting the discoloration layer 32 and prevents the ultraviolet rays from being discolored.
Further, an ultraviolet absorber can be applied to the base film of the printing layer 33 or applied.
[0028]
Next, a first specific example will be described.
The base layer 31 is white. The color changing layer 32 is white before the color change and red after the color change.
As shown in FIG. 2, the print layer 33 has a red “beginning” character (that is, a first mark representing a medicine start point) and a white “finishing” character (ie, a second mark representing a medicine end point). ), An arrow from the character “start” to the character “end” is printed.
The arrow has a red gradation on the character side of “beginning”, the color gradually fades toward the character of “end”, and white character printing on the character side of “end”.
[0029]
At the start of the chemical heating transpiration of the indicator 30, as shown in FIG. 3A, the appearance is such that the characters “beginning” and the arrow near the “beginning” character are visible.
As shown in FIG. 3B, the discoloration layer 32 changes to a light red color as the chemical heating time elapses, and the appearance of the “end” character can be visually recognized.
The difference between the letters “End” and the red color of the discoloration layer 32 is small.
When the medicine heating time further elapses, the discoloration layer 32 changes to a slightly darker red color as shown in FIG. 3C, and the appearance that the “End” character can be visually recognized somewhat clearly.
[0030]
Since the appearance changes in this way, the user can recognize the drug heating time, that is, the remaining amount of the drug contained in the drug-containing body 3, based on the difference between the red letters on the discoloration layer 32 and the characters “beginning”. .
[0031]
When the medicine heating time is over and the medicine is finished, that is, when the remaining amount of the medicine contained in the medicine-containing body 3 is less than the effective amount, as shown in FIG. Since the red color of the discoloration layer 32 has the same density, the appearance of the character “start” cannot be visually recognized and the character “end” can be clearly recognized.
[0032]
As such, the user can clearly recognize that the medicinal component has disappeared.
[0033]
Next, a second specific example will be described.
The base layer 31 is white. The color changing layer 32 is white before the color change and red after the color change.
As shown in FIG. 4A, the print layer 33 has a red “start” character, a white “end” character, a white first strip 35, a light red second strip 36, and a slightly darker color. The red third belt-like portion 37 and the red fourth belt-like portion 38 having the same darkness as the characters “beginning” are continuously printed.
[0034]
At the start of the heating of the medicine, as shown in FIG. 4 (a), the appearance is such that the letters “beginning” and the second, third, and fourth belt-like portions 36, 37, and 38 can be visually recognized.
As shown in FIG. 4B, the discoloration layer 32 turns light red as the chemical heating time elapses, and the first, third, and fourth belt portions 35, 37, and 38 can be visually recognized, and the second belt portion. 36 becomes invisible.
When the medicine heating time further elapses, as shown in FIG. 4C, the discoloration layer 32 changes to a slightly dark red color, and the first, second, and fourth belt portions 35, 36, and 38 are visually recognized, and the third belt shape The part 37 becomes invisible.
[0035]
When the medicine heating time is over and the medicine is finished, as shown in FIG. 4 (d), the letters "End" and the first, second, and third belt portions 35, 36, and 37 can be visually recognized. The part 38 becomes invisible.
[0036]
Thus, the chemical heating time can be recognized by visually recognizing the first, second, third, and fourth belt-like portions 35, 36, 37, and 38.
Note that the visual recognition of the characters “beginning” and “end” changes in the same manner as in the first specific example.
[0037]
Next, a third specific example will be described.
As shown in FIG. 5, the left half 33a of the printing layer 33 made of a transparent film is printed in red except for the character shape “S”, and the right half 33b is white except for the character shape “Sen”. Print.
In front of the “su” character extracted transparently in the red print layer of the left half 33a, a white “usable” character is printed.
[0038]
At the start of the heating of the medicine, as shown in FIG.
Since the discoloration layer 32 gradually changes to red as the chemical heating time elapses, the letters “su” are gradually faded as shown in FIG. 6B and FIG. The appearance gradually becomes clearly visible.
[0039]
When the medicine heating time is over and the medicine is over, as shown in FIG. 6 (d), the character “SU” cannot be visually recognized but the appearance of the character “SEN” can be clearly seen. You can see the words "I can't do it".
[0040]
The indicator 30 is preferably provided at a position that is visible from the outside near the heating element 15 of the chemical heating transpiration container 1.
[0041]
【The invention's effect】
According to the first aspect of the present invention, the visual change of the color is caused at two or more places, so that the user can clearly recognize that the medicinal component has disappeared as the end point of the medicine.
[0042]
According to the second aspect of the present invention, the user can clearly recognize that the medicinal component has disappeared as a medicine end point due to a visual change in the colors of the first mark and the second mark.
[0043]
According to the invention according to claim 4 , by observing the change in which one mark gradually disappears and the other mark appears as the heating time elapses, the drug use state, that is, the drug The remaining amount of medicinal ingredients can be clearly recognized by the user.
[Brief description of the drawings]
FIG. 1 is a cross-sectional view of a chemical heating transpiration apparatus.
FIG. 2 is an exploded perspective view of an indicator mounting portion and an indicator.
FIG. 3 is an explanatory diagram of a color change of a first specific example of an indicator.
FIG. 4 is an explanatory diagram of a color change of a second specific example of the indicator.
FIG. 5 is a perspective view of a printed layer in a third specific example of an indicator.
FIG. 6 is an explanatory diagram of a color change of a third specific example.
[Explanation of symbols]
DESCRIPTION OF SYMBOLS 1 ... Drug heating evaporation container, 2 ... Drug containing body holding container, 3 ... Drug containing body, 15 ... Heat generating body, 30 ... Indicator, 31 ... Base layer, 32 ... Discoloring layer, 33 ... Printing layer.

Claims (4)

加熱による不可逆反応で起こる色変化を利用した薬剤使用期限を表示するインジケータであって、一つの色変化によって、視認可能なマークを視認不可能なマークへ、視認不可能なマークを視認可能なマークへ、の二つの変化を異なる箇所において同時に起こすことで、薬剤始点から薬剤終点に到る経過とともに薬剤使用状態を表現することを特徴とする加熱蒸散薬剤用インジケータ。  An indicator that displays the expiration date of a drug using a color change that occurs due to an irreversible reaction caused by heating. A mark that can be visually recognized is changed from a visible mark to an invisible mark by one color change. An indicator for a heat-evaporating drug that expresses the state of use of the drug along with the progress from the drug start point to the drug end point by causing the two changes to occur simultaneously at different locations. 視認可能から視認不可能へ変化させられる第1のマークが薬剤終点色で表現され、視認不可能から視認可能へ変化させられる第2のマークが薬剤始点色で表現されたことを特徴とする請求項1記載の加熱蒸散薬剤用インジケータ。  The first mark that is changed from visible to invisible is expressed by a medicine end point color, and the second mark that is changed from invisible to visible is expressed by a medicine start point color. Item 1. An indicator for a heat transpiration drug according to Item 1. 請求項1又は請求項2に記載したマークが文字であることを特徴とする加熱蒸散薬剤用インジケータ。  An indicator for a heat transpiration drug, wherein the mark according to claim 1 or 2 is a letter. 前記色変化は、突然ではなく加熱時間の経過に伴って徐々に進行することを特徴とする請求項1乃至請求項3いずれかに記載の加熱蒸散薬剤用インジケータ。The said color change progresses gradually not with a sudden but with progress of heating time, The indicator for heat | fever transpiration | evaporation chemical | medical agents in any one of Claim 1 thru | or 3 characterized by the above-mentioned.
JP2001199091A 2001-01-29 2001-06-29 Indicator for heating transpiration drug Expired - Fee Related JP4766638B2 (en)

Priority Applications (24)

Application Number Priority Date Filing Date Title
JP2001199091A JP4766638B2 (en) 2001-01-29 2001-06-29 Indicator for heating transpiration drug
IL156333A IL156333A (en) 2001-01-29 2001-09-06 Chemical-containing formed material of type enabling heating of the whole material, container for holding the chemical-containing formed material, device for heating and vaporizing the chemical and indicator of quantity of chemical to be heated and vaporized
EP01963465A EP1356731B1 (en) 2001-01-29 2001-09-06 Apparatus for heating and volatilizing a chemical
DE60144442T DE60144442D1 (en) 2001-01-29 2001-09-06 DEVICE FOR HEATING AND EVAPORATING A CHEMICAL
HU0303003A HU228096B1 (en) 2001-01-29 2001-09-06 Chemical-containing formed material of type of heating of whole the material container for holding chemical-containing formed material, device for heating and transpiring chemical and indicator for chemical to be heated and vaporized
AT01963465T ATE505080T1 (en) 2001-01-29 2001-09-06 DEVICE FOR HEATING AND VAPORIZING A CHEMICAL
CNB018217141A CN1291647C (en) 2001-01-29 2001-09-06 Chemical-containing formed material of type of heating of whole the material container for holding chemical-containing formed matzrial device for
MXPA03006740A MXPA03006740A (en) 2001-01-29 2001-09-06 Chemical-containing formed material of type of heating of whole the material, container for holding chemical-containing formed material, device for heating and transpiring chemical and indicator for chemical to be heated and vaporized.
US10/433,519 US7449154B2 (en) 2001-01-29 2001-09-06 Chemical-containing formed material of type of heating of whole the material, container for holding chemical-containing formed material, device for heating and transpiring chemical and indicator for chemical to be heated and vaporized
BRPI0116528-3A BR0116528B1 (en) 2001-01-29 2001-09-06 chemical volatilization body, chemical heating volatilization apparatus, and, indicator for a heat volatilization chemical.
CA002473552A CA2473552A1 (en) 2001-01-29 2001-09-06 Whole heated, chemical containing body, chemical containing body retaining receptacle, chemical heating, volatilizing apparatus and indicator for a heat volatilizing chemical
PCT/JP2001/007728 WO2002060254A1 (en) 2001-01-29 2001-09-06 Chemical-containing formed material of type of heating of whole the material, container for holding chemical-containing formed material, device for heating and transpiring chemical and indicator for chemical to be heated and vaporized
AU2001284452A AU2001284452B2 (en) 2001-01-29 2001-09-06 Whole-heated, chemical containing body, chemical containing body retaining receptacle, chemical heating, volatilizing apparatus and indicator for a heat volatilizing chemical
PL01363451A PL363451A1 (en) 2001-01-29 2001-09-06 Chemical-containing formed material of type of heating of whole the material, container for holding chemical-containing formed material, device for heating and transpiring chemical and indicator for chemical to be heated and vaporized
KR1020037008234A KR100746520B1 (en) 2001-01-29 2001-09-06 Chemical heating, volatilizing apparatus
NZ526268A NZ526268A (en) 2001-01-29 2001-09-06 Chemical-containing formed material of type of heating of whole the material, container for holding chemical- containing formed material, device for heating and transpiring chemical and indicator for chemical to be heated and vaporized
TW090126077A TWI225772B (en) 2001-01-29 2001-10-22 Chemical-transpiring body, device for heating and transpiring chemical and indicator for chemical to be heated and vaporized
ARP010105057A AR031166A1 (en) 2001-01-29 2001-10-29 BODY CONTAINING COMPLETELY WARMED CHEMICAL AGENT, BODY RETENTION RECEPTURE CONTAINING CHEMICAL AGENT, HEATING AND VOLATILIZATION DEVICE OF CHEMICAL AGENT AND INDICATOR FOR A CHEMICAL AGENT VOLATILIZABLE BY HEAT
MYPI20015024A MY136846A (en) 2001-01-29 2001-10-30 Whole heated, chemical containing body, chemical containing body retaining receptacle, chemical heating, volatilizing apparatus and indicator for a heat volatilizing chemical
PE2001001109A PE20020725A1 (en) 2001-01-29 2001-11-08 BODY CONTAINING FULLY HEATED CHEMICAL AGENT, RETENTION RECEPTACLE, BODY CONTAINING CHEMICAL AGENT, CHEMICAL AGENT VOLATILIZATION AND HEATING APPARATUS AND INDICATOR FOR A HEAT VOLATILIZABLE CHEMICAL AGENT
EG20011189A EG23053A (en) 2001-01-29 2001-11-10 Whole heated chemical containing body chemical containing body retaining receptacle chemical heatingvolatilizing apparatus and indicator for a heat v olatilizing chemical
GCP20021829 GC0000383A (en) 2001-01-29 2002-01-26 Whole heated, chemical containing body, chemical containing body retaining receptacle, chemical heating, volatilizing apparatus and indicator for a heat volatilizing chemical
HR20030529A HRP20030529A2 (en) 2001-01-29 2003-06-27 Chemical-containing formed material of type of heating of whole the material, container for holding
HK03109171.9A HK1056666A1 (en) 2001-01-29 2003-12-16 Apparatus for heating and volatilizing a chemical

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2001020007 2001-01-29
JP2001-20007 2001-01-29
JP2001020007 2001-01-29
JP2001199091A JP4766638B2 (en) 2001-01-29 2001-06-29 Indicator for heating transpiration drug

Publications (2)

Publication Number Publication Date
JP2002293703A JP2002293703A (en) 2002-10-09
JP4766638B2 true JP4766638B2 (en) 2011-09-07

Family

ID=26608435

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001199091A Expired - Fee Related JP4766638B2 (en) 2001-01-29 2001-06-29 Indicator for heating transpiration drug

Country Status (1)

Country Link
JP (1) JP4766638B2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4548570B2 (en) * 2003-06-02 2010-09-22 花王株式会社 Chemical discharge container
JP4548569B2 (en) * 2003-07-15 2010-09-22 花王株式会社 Chemical discharge container
US7670566B2 (en) * 2006-02-03 2010-03-02 S.C. Johnson & Son, Inc. Air treatment devices with use-up indicators

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3200977B2 (en) * 1992-07-02 2001-08-20 住友化学工業株式会社 Time indicator
JP3422825B2 (en) * 1993-09-21 2003-06-30 フマキラー株式会社 Heat evaporation of chemicals
JPH07260955A (en) * 1994-03-18 1995-10-13 Toppan Printing Co Ltd Time passage display unit
JP4361147B2 (en) * 1998-04-24 2009-11-11 アース製薬株式会社 Heat transpiration method
JP2001151605A (en) * 1999-11-30 2001-06-05 S T Chem Co Ltd Volatillizer of chemical and indicator

Also Published As

Publication number Publication date
JP2002293703A (en) 2002-10-09

Similar Documents

Publication Publication Date Title
US20230226334A1 (en) Microneedle patches and methods
US4292916A (en) Timer and storage condition indicator
US6106852A (en) Temporary tattoo device and method
KR101296010B1 (en) Solvatochromic Visual Indicator and the Use of the Same
US5633836A (en) Accelerated development time-delayed message system
US4408557A (en) Timer and storage condition indicator
US7280441B2 (en) Visual indicator chronograph and the use of the same
US20090143516A1 (en) Thermochromic responsive elastic polymer substrate
JPH10503595A (en) Time indicator with separated adhesive
JP4766638B2 (en) Indicator for heating transpiration drug
KR100746520B1 (en) Chemical heating, volatilizing apparatus
KR200419328Y1 (en) Film type sticker for painting
GB2401789A (en) Heat-activated vapour generating device
JP2525117Y2 (en) Time indicator
JPH0345174U (en)
JP3097002U (en) Stick-on Cairo
JP2000166955A (en) Heating element and its production
KR200203378Y1 (en) Car guiding plate for exhalating fragrance
JPH09117243A (en) Volatilizing material of chemical agent liquid also used as indicator, and chemical agent liquid-volatilizing device using the same material and also used as the indicator
JP4182511B2 (en) Simple chemical volatilizer
JP3046548U (en) Heating element
JPS6150901A (en) Insect-repelling material displaying insect-repelling capability
DE20017599U1 (en) Lighter with a fragrance-releasing surface
JPH09142543A (en) Chemicals vaporizer also serving as indicator
JP2000194254A (en) Braille seal

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20071217

RD04 Notification of resignation of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7424

Effective date: 20100217

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20101215

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110207

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20110413

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110414

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20110608

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20110613

R150 Certificate of patent or registration of utility model

Ref document number: 4766638

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20140624

Year of fee payment: 3

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees