JP4712949B2 - Transparent gel fragrance composition - Google Patents
Transparent gel fragrance composition Download PDFInfo
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- JP4712949B2 JP4712949B2 JP2000294211A JP2000294211A JP4712949B2 JP 4712949 B2 JP4712949 B2 JP 4712949B2 JP 2000294211 A JP2000294211 A JP 2000294211A JP 2000294211 A JP2000294211 A JP 2000294211A JP 4712949 B2 JP4712949 B2 JP 4712949B2
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- Prior art keywords
- aluminum
- fragrance
- fragrance composition
- transparent gel
- gel
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Description
【０００１】
【発明の属する技術分野】
本発明は、透明ゲル状芳香剤組成物に関する。更に詳しくは、本発明はジ−２−エチルへキサン酸アルミニウムを主成分として含有するオクチル酸アルミニウム、揮発性炭化水素化合物及び／又は香料、二塩基酸類及び多塩基酸類又はそのアルミニウム塩を含有する芳香剤組成物に関する。
【０００２】
【従来の技術】
従来、炭化水素類のゲル化剤として、金属石鹸、特にステアリン酸アルミニウム(モノ、ジ、トリ塩)及びジ−２−エチルへキサン酸アルミニウムが知られている。特に、ジ−２−エチルへキサン酸アルミニウムは、炭化水素類を透明にゲル化することが知られている(「油がかたまるくすり」、化学の領域Vol.36 No.10,p697−701(1982))。
しかし、ジ−２−エチルへキサン酸アルミニウムをゲル化剤として使用した従来のゲル状芳香剤は、非常に柔らかく流動性があるため容器が転倒した際に短時間で内容物が流出したり、また、ラメやパール化剤等の固形物を配合すると比重の重いものが経時的に沈んでしまうなどの問題がある。
【０００３】
【発明が解決しようとする課題】
本発明の目的は、ジ−２−エチルへキサン酸アルミニウムを用いた透明ゲル状芳香剤において、ゲルを固くし、流動性を抑制し、容器からのゲルの流出や比重の重いラメやパール化剤等の固形物の沈降を抑制又は防止しうる透明ゲル状芳香剤組成物を提供することにある。
【０００４】
【課題を解決するための手段】
本発明によれば、ジ−２−エチルヘキサン酸アルミニウムを主成分として含むオクチル酸アルミニウムと、揮発性炭化水素化合物及び／又は香料と、二塩基酸類、そのアルミニウム塩、多塩基酸類及びそのアルミニウム塩からなる群より選択される１種又は２種以上のゲル強度向上剤（但し、ダイマー酸を除く）とを含有することを特徴とする透明ゲル状芳香剤組成物が提供される。
【０００５】
【発明の実施の形態】
以下、本発明を詳細に説明する。
本発明の透明ゲル状芳香剤組成物は、ジ−２−エチルヘキサン酸アルミニウムを主成分として含むオクチル酸アルミニウムと、揮発性炭化水素化合物及び／又は香料と、特定のゲル強度向上剤とを含有する。
【０００６】
本発明において用いる前記オクチル酸アルミニウムは、ジ−２−エチルへキサン酸アルミニウムを主成分とし、ゲル化剤等として作用するものであれば特に限定されない。通常、少量のトリ−２−エチルヘキサン酸アルミニウムを含むオクチル酸アルミニウムを好適に用いることができる。ここで、主成分とは、通常５０質量％以上を意味する。
前記オクチル酸アルミニウムの含有割合は、組成物全量に対して１〜１５質量％が好ましい。この含有割合が１質量％未満では、得られる組成物のゲル強度が不十分となる恐れがあり、１５質量％を超えると、ゲル状芳香剤が揮散した後の残量が多くなるので好ましくない。
【０００７】
本発明に用いることができる前記揮発性炭化水素化合物としては、テルペン系炭化水素、イソパラフィン系炭化水索、ノルマルパラフィン系炭化水素又はこれらの混合物等が挙げられる。
前記テルペン系炭化水素としては、例えば、α−ピネン、β−ピネン、ｄ−リモネン、Ｌ−リモネン、ジペンテン、ｐ−メンタン、ピナン又はこれらの混合物等が挙げられる。
前記ノルマルパラフィン系炭化水素又はイソパラフィン系炭化水素としては、Ｃ8Ｈ18〜Ｃ18Ｈ38、好ましくはＣ10Ｈ22〜Ｃ16Ｈ34のものが挙げられる。
本発明に用いる前記香料としては、特に限定されず、どのような香りを賦香するものであっても使用できる。
前記揮発性炭化水素化合物及び／又は香料の含有割合は、特に限定されないが、組成物全量に対して、通常、０．１〜９９質量％程度である。
【０００８】
本発明に用いる前記特定のゲル強度向上剤は、二塩基酸類、そのアルミニウム塩、多塩基酸類及びそのアルミニウム塩からなる群より選択される１種又は２種以上を必須成分とする。必要に応じて他のゲル強度向上作用を示す化合物を含んでいても良い。
前記特定のゲル強度向上剤としては、例えば、アジピン酸、ピメリン酸、スべリン酸、アゼライン酸、セバシン酸、ウンデカン二酸、ドデカン二酸、ブラシル酸、カルボキシオクタデカン酸及びこれらのアルミニウム塩、またはこれらの混合物等が挙げられる。
前記特定のゲル強度向上剤の含有割合は、組成物全量に対して０．００１〜５．０質量％が望ましい。０．００１質量％未満では所望の効果を得ることができず、５．０質量％を超えるとゲル強度向上剤自体が溶解せず、ゲル化しない恐れがあるので好ましくない。
【０００９】
本発明の透明ゲル状芳香剤組成物は、必要に応じて、油溶性の消臭剤等を含んでいても良い。このような油用性消臭剤としては、例えば、ピルビン酸エステル類、メタクリル酸エステル類等が好ましく挙げられる。該油溶性の消臭剤の含有割合は、その目的等に応じて適宜選択して決定することができる。
【００１０】
本発明の透明ゲル状芳香剤組成物は、必要に応じて他の添加剤を適宜配合することができる。他の添加剤としては、例えば、ＢＨＴ等の酸化防止剤；紫外線吸収剤；エチルセルロース等の増粘剤；酸化亜鉛、酸化チタン、その他の着色顔料等の色素若しくは顔料等が挙げられる。これら他の添加剤の含有割合は、その目的等に応じて適宜選択して決定することができる。
【００１１】
本発明の透明ゲル状芳香剤組成物は、例えば、上述の必須成分、必要に応じて添加しうる他の成分を混合、撹拌し、放置することによって得ることができる。
本発明の透明ゲル状芳香剤組成物は、例えば、室内の芳香消臭剤、自動車内の芳香消臭剤、トイレ内の芳香消臭剤、下駄箱内の芳香消臭剤、台所周りの芳香消臭剤、浴室内の芳香消臭剤等として好適に用いることができるがこれらに限定されるものではない。
【００１２】
【発明の効果】
本発明の透明ゲル状芳香剤組成物は、特定のオクチル酸アルミニウムと、揮発性炭化水素化合物及び／又は香料と、特定のゲル強度向上剤とを含有するので、組成物の流動性が抑制でき、容器が転倒した際に短時間で内容物が流出したり、また、ラメやパール化剤等の比重の重い固形物を配合した際に、該固形物が経時的に沈降すること等を抑制若しくは防止することができる。
【００１３】
【実施例】
以下実施例により更に詳細に説明するが、本発明はこれらに限定されるものではない。
実施例１
ジ−２−エチルヘキサン酸アルミニウムを５０質量％以上含有するオクチル酸アルミニウム４．５ｇ、酸化防止剤０．５ｇ、紫外線吸収剤０．５ｇ、ｄ−リモネン１１ｇ、揮発性イソパラフィン７５．４ｇ、香料(スカッシュの香り)８．０ｇ及びセバシン酸０．１ｇを混合、撹拌した。続いて、１００ｇ容量のガラス瓶に５０ｇ充填して放置したところ、透明ゲル状芳香剤組成物が得られた。
このガラス瓶を横倒しにして、内容物の流出にかかる時間を測定した。結果を表１に示す。
【００１４】
実施例２
セバシン酸０．１ｇの代わりにブラシル酸０．０５ｇを用い、更に揮発性イソパラフィンの配合量を７５．４５ｇに代えた以外は、実施例１と同様にガラス瓶に充填した透明ゲル状芳香剤組成物を調製し、実施例１と同様に内容物の流出にかかる時間を測定した。結果を表１に示す。
【００１５】
実施例３
セバシン酸０．１ｇの代わりにブラシル酸０．１ｇを用いた以外は、実施例１と同様にガラス瓶に充填した透明ゲル状芳香剤組成物を調製し、実施例１と同様に内容物の流出にかかる時間を測定した。結果を表１に示す。
【００１６】
実施例４
セバシン酸０．１ｇの代わりにブラシル酸アルミニウム０．１ｇを用いた以外は、実施例１と同様にガラス瓶に充填した透明ゲル状芳香剤組成物を調製し、実施例１と同様に内容物の流出にかかる時間を測定した。結果を表１に示す。
【００１７】
比較例１
セバシン酸０．１ｇを配合せずに、揮発性イソパラフィンの配合量を７５．５ｇに代えた以外は、実施例１と同様にガラス瓶に充填した透明ゲル状芳香剤組成物を調製し、実施例１と同様に内容物の流出にかかる時間を測定した。結果を表１に示す。
【００１８】
【表１】
BACKGROUND OF THE INVENTION
The present invention relates to a transparent gel fragrance composition. More specifically, the present invention contains aluminum octylate, volatile hydrocarbon compound and / or fragrance, dibasic acid and polybasic acid or aluminum salt thereof containing aluminum di-2-ethylhexanoate as a main component. you about the fragrance composition.
[0002]
[Prior art]
Conventionally, metal soaps, particularly aluminum stearate (mono, di, tri salts) and aluminum di-2-ethylhexanoate are known as gelling agents for hydrocarbons. In particular, di-2-ethylhexanoic acid aluminum is known to transparently gel hydrocarbons ("Agglomeration of oil", Chemistry Vol. 36 No. 10, p697-701 ( 1982)).
However, the conventional gel-like fragrance using di-2-ethylhexanoic acid aluminum as a gelling agent is very soft and fluid, so when the container falls, the contents flow out in a short time, Moreover, when solid substances, such as a lame and a pearling agent, are blended, there is a problem that a heavy specific gravity sinks with time.
[0003]
[Problems to be solved by the invention]
The object of the present invention is to provide a transparent gel-like fragrance using aluminum di-2-ethylhexanoate, harden the gel, suppress fluidity, flow out of the container, lame or pearlizing with heavy specific gravity. The object of the present invention is to provide a transparent gel-like fragrance composition capable of suppressing or preventing the sedimentation of solid substances such as an agent.
[0004]
[Means for Solving the Problems]
According to the present invention, aluminum octylate containing aluminum di-2-ethylhexanoate as a main component, volatile hydrocarbon compounds and / or fragrances, dibasic acids, aluminum salts thereof, polybasic acids and aluminum salts thereof A transparent gel-like fragrance composition comprising one or more gel strength improvers selected from the group consisting of (excluding dimer acid) is provided.
[0005]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, the present invention will be described in detail.
The transparent gel fragrance composition of the present invention contains aluminum octylate containing aluminum di-2-ethylhexanoate as a main component, a volatile hydrocarbon compound and / or a fragrance, and a specific gel strength improver. To do.
[0006]
The aluminum octylate used in the present invention is not particularly limited as long as it has aluminum di-2-ethylhexanoate as a main component and acts as a gelling agent or the like. Usually, aluminum octylate containing a small amount of aluminum tri-2-ethylhexanoate can be suitably used. Here, the main component usually means 50% by mass or more.
As for the content rate of the said aluminum octylate, 1-15 mass% is preferable with respect to the composition whole quantity. If this content is less than 1% by mass, the gel strength of the resulting composition may be insufficient, and if it exceeds 15% by mass, the remaining amount after the gel-like fragrance is volatilized is not preferable. .
[0007]
Examples of the volatile hydrocarbon compound that can be used in the present invention include terpene hydrocarbons, isoparaffin hydrocarbon hydrocarbons, normal paraffin hydrocarbons, and mixtures thereof.
Examples of the terpene hydrocarbon include α-pinene, β-pinene, d-limonene, L-limonene, dipentene, p-menthane, pinane, and mixtures thereof.
Examples of the normal paraffinic hydrocarbon or isoparaffinic hydrocarbon include C 8 H 18 to C 18 H 38 , preferably C 10 H 22 to C 16 H 34 .
It does not specifically limit as said fragrance | flavor used for this invention, What kind of fragrance | flavor is scented can be used.
Although the content rate of the said volatile hydrocarbon compound and / or a fragrance | flavor is not specifically limited, It is about 0.1-99 mass% normally with respect to the composition whole quantity.
[0008]
The specific gel strength improver used in the present invention contains, as an essential component, one or more selected from the group consisting of dibasic acids, aluminum salts thereof, polybasic acids and aluminum salts thereof. If necessary, it may contain other compounds exhibiting an effect of improving gel strength.
Examples of specific gel strength enhancing agent, for example, adipic acid, pimelic acid, scan base phosphoric acid, azelaic acid, sebacic acid, undecanoic acid, dodecanedioic acid, brassylic acid, carboxymethyl octadecane San及 beauty these aluminum salts or their, And the like.
As for the content rate of the said specific gel strength improvement agent, 0.001-5.0 mass% is desirable with respect to the composition whole quantity. If it is less than 0.001% by mass, the desired effect cannot be obtained, and if it exceeds 5.0% by mass, the gel strength improving agent itself is not dissolved and may not be gelled.
[0009]
The transparent gel-like fragrance composition of the present invention may contain an oil-soluble deodorant and the like as necessary. Preferred examples of such an oily deodorant include pyruvate esters and methacrylic acid esters. The content ratio of the oil-soluble deodorant can be appropriately selected and determined according to the purpose and the like.
[0010]
The transparent gel fragrance composition of the present invention can be appropriately mixed with other additives as necessary. Other additives include, for example, antioxidants such as BHT; ultraviolet absorbers; thickeners such as ethyl cellulose; dyes or pigments such as zinc oxide, titanium oxide, and other colored pigments. The content ratio of these other additives can be selected and determined as appropriate according to the purpose and the like.
[0011]
The transparent gel fragrance composition of the present invention can be obtained, for example, by mixing, stirring and leaving the above-mentioned essential components and other components that can be added as necessary.
The transparent gel fragrance composition of the present invention includes, for example, indoor fragrance deodorants, fragrance deodorants in automobiles, fragrance deodorants in toilets, fragrance deodorants in clog boxes, and fragrances around the kitchen. Although it can use suitably as a deodorizing agent, the aromatic deodorizing agent in a bathroom, etc., it is not limited to these.
[0012]
【The invention's effect】
Since the transparent gel-like fragrance composition of the present invention contains a specific aluminum octylate, a volatile hydrocarbon compound and / or a fragrance, and a specific gel strength improver, the fluidity of the composition can be suppressed. In addition, the contents flow out in a short time when the container falls, and when solids with heavy specific gravity such as lame and pearlizing agent are blended, the solids are prevented from settling with time. Or it can be prevented.
[0013]
【Example】
Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited thereto.
Example 1
4.5 g of aluminum octylate containing 50% by mass or more of aluminum di-2-ethylhexanoate, 0.5 g of antioxidant, 0.5 g of UV absorber, 11 g of d-limonene, 75.4 g of volatile isoparaffin, fragrance ( Squash scent) 8.0 g and sebacic acid 0.1 g were mixed and stirred. Subsequently, when a glass bottle having a capacity of 100 g was filled with 50 g and allowed to stand, a transparent gel-like fragrance composition was obtained.
The glass bottle was laid down and the time taken for the contents to flow out was measured. The results are shown in Table 1.
[0014]
Example 2
Using a brush Le acid 0.05g instead of sebacic acid 0.1 g, and more except that the amount of volatile isoparaffin was changed to 75.45g, Example 1 and the transparent gel-like fragrance was filled in a glass bottle as well composition A product was prepared, and the time taken for the contents to flow out was measured in the same manner as in Example 1. The results are shown in Table 1.
[0015]
Example 3
Except for using the brush Le acid 0.1g instead of sebacic acid 0.1g is a clear gel-like fragrance composition was filled in a glass bottle in the same manner as in Example 1 was prepared, similarly content as in Example 1 The time taken for spilling was measured. The results are shown in Table 1.
[0016]
Example 4
Except for using the brush Le aluminum 0.1g instead of sebacic acid 0.1g is a clear gel-like fragrance composition was filled in a glass bottle in the same manner as in Example 1 was prepared similarly content as in Example 1 The time taken for the spill was measured. The results are shown in Table 1.
[0017]
Comparative Example 1
A transparent gel-like fragrance composition filled in a glass bottle was prepared in the same manner as in Example 1 except that 0.1 g of sebacic acid was not used and the amount of volatile isoparaffin was changed to 75.5 g. The time taken for the contents to flow out was measured as in 1. The results are shown in Table 1.
[0018]
[Table 1]
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000294211A JP4712949B2 (en) | 2000-09-27 | 2000-09-27 | Transparent gel fragrance composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000294211A JP4712949B2 (en) | 2000-09-27 | 2000-09-27 | Transparent gel fragrance composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2002102325A JP2002102325A (en) | 2002-04-09 |
| JP4712949B2 true JP4712949B2 (en) | 2011-06-29 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2000294211A Expired - Lifetime JP4712949B2 (en) | 2000-09-27 | 2000-09-27 | Transparent gel fragrance composition |
Country Status (1)
| Country | Link |
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| JP (1) | JP4712949B2 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003335602A (en) * | 2002-05-20 | 2003-11-25 | S T Chem Co Ltd | Gel state insecticide composition, gel state insecticide and method for producing the same |
| JP5071996B2 (en) * | 2004-08-18 | 2012-11-14 | 長谷川香料株式会社 | Oily gel composition |
| JP7454950B2 (en) * | 2020-01-24 | 2024-03-25 | 東邦インターナショナル株式会社 | Small aroma generator |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH039758A (en) * | 1989-06-08 | 1991-01-17 | Taiyo Koryo Kk | Transparent gel-like aromatic composition |
| JPH09316436A (en) * | 1996-05-30 | 1997-12-09 | Hope Seiyaku Kk | Oil-disposing agent |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04348182A (en) * | 1991-04-03 | 1992-12-03 | Seiken Kagaku Kk | Oily gel composition |
| JP3803141B2 (en) * | 1996-08-01 | 2006-08-02 | 生研化学株式会社 | Transparent oily gel air freshener composition |
| JPH11276567A (en) * | 1998-03-31 | 1999-10-12 | S T Chem Co Ltd | Aromatic with decoration of natural plant |
| JP4224175B2 (en) * | 1999-08-11 | 2009-02-12 | 長谷川香料株式会社 | Transparent gel fragrance / deodorant composition |
-
2000
- 2000-09-27 JP JP2000294211A patent/JP4712949B2/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH039758A (en) * | 1989-06-08 | 1991-01-17 | Taiyo Koryo Kk | Transparent gel-like aromatic composition |
| JPH09316436A (en) * | 1996-05-30 | 1997-12-09 | Hope Seiyaku Kk | Oil-disposing agent |
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| Publication number | Publication date |
|---|---|
| JP2002102325A (en) | 2002-04-09 |
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