JPS59108100A - Solid fragrant cleaner for water closet - Google Patents
Solid fragrant cleaner for water closetInfo
- Publication number
- JPS59108100A JPS59108100A JP57217336A JP21733682A JPS59108100A JP S59108100 A JPS59108100 A JP S59108100A JP 57217336 A JP57217336 A JP 57217336A JP 21733682 A JP21733682 A JP 21733682A JP S59108100 A JPS59108100 A JP S59108100A
- Authority
- JP
- Japan
- Prior art keywords
- cleaner
- detergent
- solid aromatic
- solid
- water closet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Bidet-Like Cleaning Device And Other Flush Toilet Accessories (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Detergent Compositions (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
この発明は水洗便所用固形芳香清浄剤に関するものであ
る。DETAILED DESCRIPTION OF THE INVENTION This invention relates to a solid aromatic cleaner for flush toilets.
水洗便所内に芳香を漂わせ、かつ便器を清浄に保つ目的
で、液状あるいは固形の芳香清浄剤が種々開発されてい
る。これらの芳香清浄剤は水洗便所のタンク内に設置さ
れ、芳香清浄成分が少しずつタンク内の水中に分散する
ようになされている。Various liquid or solid aromatic cleaners have been developed for the purpose of creating an aromatic atmosphere in a flush toilet and keeping the toilet bowl clean. These aromatic cleaners are installed in the tank of a flush toilet, and the aromatic cleaner components are gradually dispersed into the water in the tank.
水中に分散される１回分の芳香清浄成分は微量であるが
、使用頻度が高いため、耐用期間が通常１り月程度と短
く、芳香清浄剤の取換えを頻繁にしなければならないと
いう繁雑さがあった。The amount of aromatic cleaning ingredients dispersed in water is small, but because they are used frequently, their useful life is usually short, about one month, and the fragrance cleaning agent has to be replaced frequently, which is a hassle. there were.
この発明は、このような事情に鑑みてなされたものであ
シ、ある種のＮ、Ｎ−ジ置換脂肪族アミドを添加するこ
とによシ、固形芳香清浄剤の効果）
が持続化されるという知見に基づいてなされだものであ
る。This invention was made in view of these circumstances, and it is possible to sustain the effects of a solid aromatic detergent by adding a certain type of N,N-disubstituted aliphatic amide. This was done based on this knowledge.
この発明の水洗便所用固形芳香清浄剤は、色素、香料、
清浄剤および固化剤を含有する従米の水洗便所用固形芳
香清浄剤に一般式
〔式中、Ｒは高級脂肪族基、ｍおよびｎはそれぞれ１以
上で、かつｍ十ｎ（平均付加モル数）が４以上である整
数を意味する〕
で表わされるＮ、Ｎ−ジ置換脂肪族・アミドを添加した
組成からなる。The solid aromatic cleaner for flush toilets of this invention includes pigments, fragrances,
A solid aromatic detergent for flush toilets containing a detergent and a solidifying agent has the general formula [wherein R is a higher aliphatic group, m and n are each 1 or more, and m10n (average number of moles added)] means an integer of 4 or more.
この発明の固形芳香清浄剤における色素、香料、清浄剤
および固化剤は特に限定されるものでなく、その組成割
合も任意である。The pigment, fragrance, detergent, and solidifying agent in the solid aromatic detergent of this invention are not particularly limited, and their composition ratios are also arbitrary.
これら各種成分からなる固形芳香清浄剤に添加されるＮ
、Ｎ−ジ置換脂肪族アミド（１）としては、前記の一般
式（１）においてＲで示される高級脂肪族基が硬化生能
残基であり、ｍ＋ｎ、すなわち平均付加モル数が５であ
るものが好ましく、最も好ましいのはエソマイトＨＴ／
１５ （商標、ライオンてクシ株式会社製）である。Ｎ
、Ｎ−ジ置換脂肪族アミド（１）の添加割合は、目的と
する搏続化の程度にもよるが、通常Ｚ〜１０重量係が好
ましい。N added to solid aromatic detergents made of these various components
, as the N-disubstituted aliphatic amide (1), the higher aliphatic group represented by R in the above general formula (1) is a curing biogenic residue, and m+n, that is, the average number of moles added is 5. is preferable, and the most preferable is Esomite HT/
15 (trademark, manufactured by Lion Tekushi Co., Ltd.). N
The addition ratio of the N-disubstituted aliphatic amide (1) depends on the desired degree of continuousization, but is usually preferably Z to 10% by weight.
なお、この発明の固形芳香清浄剤には、上記のような色
素、香料、清浄剤および固化剤のほかに、何らかの適当
な成分が加えられていてもよい。In addition to the above-described dyes, fragrances, detergents, and solidifying agents, the solid aromatic detergent of the present invention may contain any suitable components.
次に、この発明の固形芳香清浄剤の効果を試験例により
説明する。Next, the effects of the solid aromatic detergent of the present invention will be explained using test examples.
試験例
後記の各成分からなる固形芳香清浄剤（３５，Ｆ）を１
５１容量のタンク内に装置し、水がタンク内に満たされ
ると自動的に排水される装置を用いて、有効使用回数を
測定した。同一の固形芳香清浄剤について上記の試験を
５回くシ返し、その都度測定された有効使用回数の平均
値を次表に示す。1 solid aromatic detergent (35, F) consisting of each component listed below in the test example
The number of effective uses was measured using a device that was installed in a 51-capacity tank and automatically drained when the tank was filled with water. The above test was repeated five times for the same solid aromatic cleaner, and the average number of effective uses measured each time is shown in the following table.
（米 エマルミンＬ−５ＱＱ：商標、三洋化成工業株式
会社製、ポリオキシエチレン（５０モ／ｌ／）ラウリル
エーテル）
上記の試験結果からも明らかなように、Ｎ、Ｎ−ジ置換
脂肪族アミド（１）を添加したこの発明の固形芳香清浄
剤では、有効使用回数が著しく増大している。(U.S. Emulmin L-5QQ: trademark, manufactured by Sanyo Chemical Industries, Ltd., polyoxyethylene (50 mol/l/) lauryl ether) As is clear from the above test results, N,N-disubstituted aliphatic amide ( In the solid aromatic detergent of the present invention to which 1) is added, the number of effective uses is significantly increased.
実施例１
香 料 １５．０％青色
１号 ６．５％ホリエチレン
グリコール６０００ ２０．０％エマルミンＬ−５０
０５１，５％
エソマイトＨＴ／１’５ ７％ポリエ
チレングリコ−／Ｉ／６ｏｏｏ（２０重量部）、ニーｒ
）レミ：／Ｌ−５００（５１，５重量部）およびエソマ
イトＨＴ／１５（７重量部）を６０〜７０°Ｃで加熱溶
融混合したものと、香料（１５重量部）に青色１号（６
，５重量部）を混合分散させたものとを、５５〜６０″
Ｃで攪拌混合したのち、容器に充填して冷却固化させて
、固形の芳香清浄剤を製した。Example 1 Fragrance 15.0% Blue No. 1 6.5% Polyethylene Glycol 6000 20.0% Emulmin L-50
051.5% Esomite HT/1'5 7% polyethylene glycol/I/6ooo (20 parts by weight), knee r
) Remy:/L-500 (51.5 parts by weight) and Esomite HT/15 (7 parts by weight) were heated and melted and mixed at 60 to 70°C, fragrance (15 parts by weight) and Blue No. 1 (6 parts by weight).
, 5 parts by weight) mixed and dispersed in a 55-60"
After stirring and mixing at C, the mixture was filled into a container and solidified by cooling to produce a solid aromatic detergent.
実施例２
香 料 １５．０％青色１
号 ６．５係ポリエヅレングリコ
ー）ｖ６０００ ２０．’０悸エマルミンＬ−５００４
８，５％
ｘｙ’ｖイドＨＴ／１５． １０．０１上記の各
成分を用い、実施例１と同様にして、固形の芳香清浄剤
を製した。Example 2 Fragrance 15.0% Blue 1
No. 6.5 Polyethylene glycol) v6000 20. '0 Yuki Emulmin L-5004
8.5% xy'v id HT/15. 10.01 A solid aromatic detergent was prepared in the same manner as in Example 1 using the above components.
特許出願人 藤沢薬品工業株式会社Patent applicant: Fujisawa Pharmaceutical Co., Ltd.
Claims (1)
固形芳香清浄剤においそ、 −・般式 〔式中、Ｒは高級脂肪族基、ｍおよびｎはそれぞれ１以
上で、かつｍ＋ｎ （平均付加上歩数）が４以上である
整数を意味する〕 で表わされるＮ、Ｎ−ジ置換脂肪族アミドを添加したこ
とを特徴とする水洗便所用固形芳香清浄剤。[Scope of Claims] A solid aromatic detergent for flush toilets containing a pigment, a fragrance, a detergent, and an assimilating agent, which has the following general formula: [In the formula, R is a higher aliphatic group, and m and n are each 1 or more] and m+n (average number of additional steps) is an integer of 4 or more.] A solid aromatic cleaner for flush toilets, characterized in that it contains an N,N-disubstituted aliphatic amide represented by:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57217336A JPS59108100A (en) | 1982-12-10 | 1982-12-10 | Solid fragrant cleaner for water closet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57217336A JPS59108100A (en) | 1982-12-10 | 1982-12-10 | Solid fragrant cleaner for water closet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS59108100A true JPS59108100A (en) | 1984-06-22 |
Family
ID=16702577
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57217336A Pending JPS59108100A (en) | 1982-12-10 | 1982-12-10 | Solid fragrant cleaner for water closet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59108100A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6183300A (en) * | 1984-09-28 | 1986-04-26 | ア−ス製薬株式会社 | Detergent aroma composition |
| JPS6389598A (en) * | 1986-10-02 | 1988-04-20 | 株式会社 白元 | Gel like detergent and aromatic agent composition |
| EP0844303A3 (en) * | 1996-11-25 | 1999-02-03 | Buck-Chemie GmbH & Co. | Solid article for use in toilets |
-
1982
- 1982-12-10 JP JP57217336A patent/JPS59108100A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6183300A (en) * | 1984-09-28 | 1986-04-26 | ア−ス製薬株式会社 | Detergent aroma composition |
| JPH0512942B2 (en) * | 1984-09-28 | 1993-02-19 | Earth Chemical Co | |
| JPS6389598A (en) * | 1986-10-02 | 1988-04-20 | 株式会社 白元 | Gel like detergent and aromatic agent composition |
| JPH0474400B2 (en) * | 1986-10-02 | 1992-11-26 | ||
| EP0844303A3 (en) * | 1996-11-25 | 1999-02-03 | Buck-Chemie GmbH & Co. | Solid article for use in toilets |
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