JP4656677B2 - Deteriorated battery detector - Google Patents

Deteriorated battery detector Download PDF

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Publication number
JP4656677B2
JP4656677B2 JP18144098A JP18144098A JP4656677B2 JP 4656677 B2 JP4656677 B2 JP 4656677B2 JP 18144098 A JP18144098 A JP 18144098A JP 18144098 A JP18144098 A JP 18144098A JP 4656677 B2 JP4656677 B2 JP 4656677B2
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Japan
Prior art keywords
battery
cell
temperature
deterioration
cells
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Expired - Fee Related
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JP18144098A
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Japanese (ja)
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JP2000003732A (en
JP2000003732A5 (en
Inventor
貴彦 鈴木
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GS Yuasa International Ltd
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GS Yuasa International Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Charge And Discharge Circuits For Batteries Or The Like (AREA)
  • Secondary Cells (AREA)
  • Electric Propulsion And Braking For Vehicles (AREA)

Description

【0001】
【発明の属する技術分野】
本発明は、電気自動車、運搬車、AGV用など、多数個の電池をシリ−ズに接続して高電圧の電源として使用する組電池の劣化電池の検出装置に関するものである。
【0002】
【従来の技術】
電気自動車、運搬車、AGV用など、多数個の電池をシリ−ズに接続し、高電圧の電源として使用される電池には補水の必要な液式電池と補水不要の密閉電池とがある。
【0003】
液式電池の場合、充放電を繰り返すと電解液中の水が電気分解されて減少するので、月1回程度の補水が必要である。この補水時に、1〜2セルが補水されず、電池内部の電解液が消失してしまうことがある。また、極板の劣化等で極板群が短絡するとそのセルのみ極端に液減りが早くなり、電池内部の電解液が消失してしまうことがある。
【0004】
電池内部の電解液を消失したセルは極板の反応面積が減るため内部抵抗が上昇し、充放電により異常に大きな発熱をし、更なる液減りと発熱を繰り返す。このような電池は、大きな電圧降下をきたし車両性能に影響を及ぼすこととなるが、場合によっては異常発熱のため、電池破損に至ることもある。
【0005】
一方、密閉電池では、正負極板間に微細繊維のガラスマットを配置し、そのマットに所定量の電解液を保持させて、充電時に正極から発生するO2 ガスを負極で反応吸収することにより、補水不要としている。これらの密閉電池も組電池として使用すると製造及び使用環境等のバラツキから、ある1〜2セルが他のセルに比べて、異常に液が減るドライアップという現象が生じることがある。この場合、セルは内部抵抗が極端に増大し、異常発熱を起こすと共に、やがて内部抵抗は無限大となり車両は走行不能となる。
【0006】
このように液式電池でも密閉電池でも組み電池の中の特定の1〜2セル程度が異常な劣化を起こした場合、異常な発熱を起こし、そのまま電池を使用し続けると突然走行不能を引き起こすことがある。
【0007】
液式電池、密閉電池のいずれの電池も充放電を繰り返すことにより電池の容量は徐々に低下し、それとともに車両の走行性能は低下するのが一般的である。容量がある値まで低下すると、車両は走行できなくなり電池は寿命として交換されることになる。多数個の電池がほぼ一様に劣化し、一様に容量低下する場合には車両の走行性能も徐々に低下するため、電池の寿命を車両に取付けられた容量計から把握でき、計画的な電池交換が可能である。
【0008】
しかし、1セル、2セルが極端に劣化して、全体の組電池に影響を及ぼす場合は、既存の容量計では検出することができない。
【0009】
【発明が解決しようとする課題】
以上のことから、特定セルの異常を検出することは車両を安全に使用する上で重要であるが、セル数が多い組電池にあって1セルの異常な電圧降下も、全体の組電池電圧からみればわずかで、組電池全体の電圧を監視してもこれを検出することはできなかった。また、全電池に電圧線を引きだして各電池の電圧をモニタ−すれば、不具合電池を検出できるが、組み込み時などに短絡の危険があり,構成が複雑となり費用も増大する欠点があった。
【0010】
【課題を解決するための手段】
本発明は、簡易に、確実な車両用電池の劣化検出装置を供給するものであり、特定セルの劣化や異常な液切れによるエレメントの発熱を、蓋や電槽の表面温度で検出し、その温度や正常なセルと異常発熱したセル間での温度差によりブザー等の音声で警報を出すことを特徴とする。
【0011】
また、異常警報を出した状態においては、充電をできなくする信号を出力することを特徴とする。
【0012】
【発明の実施の形態】
本発明による劣化電池の検出装置は、多数のモノブロック電池からなる組電池温度を、熱電対やサーミスタなどの温度検出センサーにより検出する。これにより、特定セルの劣化や異常な液切れによるエレメントの発熱を検出し、この検出温度が一定値以上になった場合やセル間での温度差が一定値以上に達したとき、異常劣化セルが存在すると判断して警報を発するものである。このようにすることにより、劣化セルを確実に簡単に安価に検出でき、液切れ等異常セルによる走行不良や電池破損がなくなり、安全に安心して組電池を使用することができる。
【0013】
【実施例】
以下に、本発明を実施例により説明する。
【0014】
図1は本発明劣化電池検出装置の一実施例を示す模式図であり、6セルから構成される12Vタイプの電気自動車用のモノブロック式鉛蓄電池2のフタ上面の2セル目と5セル目とに熱電対やサーミスタなどの温度検出センサー1を装着したものである。ここでは2セル目と5セル目に熱電対やサーミスタなどの温度検出センサー1を取り付けたが、劣化などにより異常発熱したセルが発生した場合に、隣接したセルも同様にエレメントに熱が伝わり、そのセルの蓋上や電槽側面の温度が上昇し、2セル目と5セル目に熱電対やサーミスタなどの温度検出センサーを付けることにより、隣接するセルの温度も監視できるので、6セルとも温度を監視することができるからである。また、正常なセルの蓋上や電池側面は充電中でも60℃を越えることはほとんどなく、異常発熱したセルは、100℃を越えることもある。正常なセルと比較すると極端な温度差を発生するので、処理装置3へ情報が伝わり、処理装置3から警報が出される。
【0015】
図2は本発明劣化電池検出装置の他の一実施例を示す模式図であり、処理装置3からは劣化電池の検出警報を出すと共に、充電器4や電気自動車に検出信号を出力し、劣化電池を検出後は、充電をできなくするものである。
【0016】
【発明の効果】
以上説明したとおり、劣化セルを確実に簡単に安価に検出できることにより、液切れ等異常セルによる走行不良や電池破損がなくなり、安全に安心して組電池を使用でき、電気自動車への効果は絶大である。
【図面の簡単な説明】
【図1】本発明劣化電池検出装置の一実施例を示す模式図
【図2】本発明劣化電池検出装置の他の一実施例を示す模式図
【符号の説明】
1 温度検出センサー
2 モノブロック式鉛蓄電池
3 処理装置
4 充電器
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to an apparatus for detecting a deteriorated battery of an assembled battery in which a large number of batteries are connected to a series and used as a high voltage power source, such as for electric vehicles, transport vehicles, and AGVs.
[0002]
[Prior art]
A number of batteries, such as those for electric vehicles, transport vehicles, and AGVs, connected to the series and used as a high-voltage power source include liquid batteries that require replenishment and sealed batteries that do not require replenishment.
[0003]
In the case of a liquid battery, if charging and discharging are repeated, water in the electrolytic solution is electrolyzed and decreases, so replenishment about once a month is necessary. During this water replenishment, 1 to 2 cells may not be refilled, and the electrolyte inside the battery may disappear. Further, when the electrode plate group is short-circuited due to deterioration of the electrode plate or the like, the liquid in the cell is extremely quickly reduced, and the electrolyte in the battery may be lost.
[0004]
In the cell in which the electrolyte solution in the battery has disappeared, the reaction area of the electrode plate decreases, the internal resistance increases, and abnormally large heat generation occurs due to charge / discharge, and further liquid reduction and heat generation are repeated. Such a battery causes a large voltage drop and affects the vehicle performance. However, in some cases, the battery may be damaged due to abnormal heat generation.
[0005]
On the other hand, in a sealed battery, a glass mat of fine fibers is arranged between positive and negative electrode plates, a predetermined amount of electrolyte is held on the mat, and O 2 gas generated from the positive electrode during charging is reacted and absorbed by the negative electrode. , Replenishment is unnecessary. When these sealed batteries are also used as assembled batteries, a phenomenon of dry-up in which one or two cells are abnormally reduced in comparison with other cells may occur due to variations in manufacturing and use environments. In this case, the internal resistance of the cell increases extremely, causing abnormal heat generation, and eventually the internal resistance becomes infinite and the vehicle cannot run.
[0006]
In this way, if a specific battery of about 1 or 2 cells in a battery pack, whether it is a liquid battery or a sealed battery, is abnormally deteriorated, abnormal heat generation will occur, and if the battery is used as it is, it will suddenly become impossible to run. There is.
[0007]
Generally, the capacity of a battery is gradually reduced by repeatedly charging and discharging both a liquid battery and a sealed battery, and the traveling performance of the vehicle is generally lowered. When the capacity drops to a certain value, the vehicle cannot run and the battery is replaced as a lifetime. When a large number of batteries deteriorate almost uniformly and the capacity decreases uniformly, the vehicle's running performance also gradually decreases, so the battery life can be grasped from the capacity meter attached to the vehicle, Battery replacement is possible.
[0008]
However, when one cell or two cells are extremely deteriorated and affect the entire assembled battery, it cannot be detected by an existing capacity meter.
[0009]
[Problems to be solved by the invention]
From the above, it is important to detect an abnormality in a specific cell in order to use the vehicle safely. However, in an assembled battery with a large number of cells, an abnormal voltage drop of one cell can cause an overall assembled battery voltage. From the point of view, it was very small, and this could not be detected by monitoring the voltage of the entire assembled battery. In addition, if a voltage line is drawn out to all the batteries and the voltage of each battery is monitored, a defective battery can be detected. However, there is a risk that a short circuit may occur at the time of incorporation, and the configuration becomes complicated and the cost is increased.
[0010]
[Means for Solving the Problems]
The present invention simply and reliably supplies a vehicle battery deterioration detection device, and detects the heat generation of an element due to deterioration of a specific cell or abnormal liquid leakage by the surface temperature of a lid or a battery case. A warning is given by a sound such as a buzzer according to a temperature or a temperature difference between a normal cell and an abnormally heated cell.
[0011]
In addition, in a state where an abnormality alarm is issued, a signal that disables charging is output.
[0012]
DETAILED DESCRIPTION OF THE INVENTION
The apparatus for detecting a deteriorated battery according to the present invention detects an assembled battery temperature composed of a large number of monoblock batteries by a temperature detection sensor such as a thermocouple or a thermistor. As a result, the heat generation of the element due to the deterioration of a specific cell or abnormal liquid breakage is detected, and when the detected temperature exceeds a certain value or when the temperature difference between cells reaches a certain value, the abnormally deteriorated cell It is determined that there is an alarm and issues an alarm. By doing so, the deteriorated cell can be reliably and easily detected at a low cost, and there is no running failure or battery damage due to an abnormal cell such as a liquid shortage, and the assembled battery can be used safely and safely.
[0013]
【Example】
Hereinafter, the present invention will be described by way of examples.
[0014]
FIG. 1 is a schematic view showing an embodiment of the deteriorated battery detection device of the present invention. The second cell and the fifth cell on the upper surface of a lid of a monoblock lead-acid battery 2 for a 12V type electric vehicle composed of 6 cells. And a temperature detection sensor 1 such as a thermocouple or a thermistor. Here, the temperature detection sensor 1 such as a thermocouple or thermistor is attached to the second cell and the fifth cell. However, when a cell that is abnormally heated due to deterioration or the like is generated, heat is transferred to the element in the adjacent cell as well, The temperature on the lid of the cell and the side of the battery case rises, and the temperature of adjacent cells can be monitored by attaching temperature detection sensors such as thermocouples and thermistors to the second and fifth cells. This is because the temperature can be monitored. In addition, the normal cell top and battery side hardly exceed 60 ° C. even during charging, and abnormally heated cells may exceed 100 ° C. Compared with a normal cell, an extreme temperature difference occurs, so that information is transmitted to the processing device 3 and an alarm is issued from the processing device 3.
[0015]
FIG. 2 is a schematic diagram showing another embodiment of the deteriorated battery detection device of the present invention. The processing device 3 issues a detection alarm for a deteriorated battery, and outputs a detection signal to the charger 4 and the electric vehicle. After the battery is detected, charging is disabled.
[0016]
【The invention's effect】
As described above, the ability to reliably and inexpensively detect deteriorated cells eliminates run-off and battery damage due to abnormal cells such as running out of liquid, so that the assembled battery can be used safely and safely, and the effect on electric vehicles is enormous. is there.
[Brief description of the drawings]
FIG. 1 is a schematic diagram showing an embodiment of a deteriorated battery detection device of the present invention. FIG. 2 is a schematic diagram showing another embodiment of the deterioration battery detection device of the present invention.
DESCRIPTION OF SYMBOLS 1 Temperature detection sensor 2 Monoblock type lead acid battery 3 Processing apparatus 4 Charger

Claims (1)

ノブロック式電池の劣化を検出する劣化電池検出装置であって、前記劣化電池検出装置は複数の温度検出センサーと処理装置とを備え、前記処理装置は前記複数の温度検出センサーによる検出温度があらかじめ設定した値以上に達した場合に異常警報を出すものであり、前記複数の温度センサーは前記モノブロック式電池を構成するセルの蓋または電槽壁に1セルないし数セルおきに取り付けられていることを特徴とする劣化電池検出装置。A deterioration battery detecting device for detecting deterioration of a mono block type battery, the with the deterioration battery detection device with a plurality of temperature detecting sensor processing unit and, in the processing device temperature detected by the plurality of temperature detection sensor When a predetermined value or more is reached, an abnormality alarm is issued , and the plurality of temperature sensors are attached to the lid or battery wall of the cell constituting the monoblock battery every other cell or several cells. deterioration battery detection apparatus characterized by there.
JP18144098A 1998-06-12 1998-06-12 Deteriorated battery detector Expired - Fee Related JP4656677B2 (en)

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JP2000003732A5 JP2000003732A5 (en) 2005-10-20
JP4656677B2 true JP4656677B2 (en) 2011-03-23

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Families Citing this family (7)

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Publication number Priority date Publication date Assignee Title
JP5050300B2 (en) * 2001-06-01 2012-10-17 株式会社Gsユアサ Storage battery
JP2012052857A (en) * 2010-08-31 2012-03-15 Panasonic Corp Abnormality detection circuit for secondary battery and battery power supply device
JP2012125121A (en) * 2010-12-10 2012-06-28 Nippon Telegr & Teleph Corp <Ntt> Charging system and storage battery degradation determination method
JP2014022282A (en) * 2012-07-20 2014-02-03 Sharp Corp Secondary battery abnormality detector, secondary battery, and method for detecting secondary battery abnormality
JP2015035299A (en) * 2013-08-08 2015-02-19 株式会社Gsユアサ State detecting method of lead storage battery, device thereof and vehicle
JP6532401B2 (en) * 2015-12-28 2019-06-19 株式会社日立製作所 Power storage system and control method of power storage system
KR102439932B1 (en) * 2017-07-26 2022-09-05 삼성전자주식회사 Method and apparatus for detecting battery fault

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0398428A (en) * 1989-09-08 1991-04-24 Nec Corp Maintenance control system for battery
JPH07203634A (en) * 1993-12-30 1995-08-04 Kenji Harada Charger for secondary cell
JP3669127B2 (en) * 1997-11-05 2005-07-06 日産自動車株式会社 Electric vehicle charging device
JP3656379B2 (en) * 1997-11-20 2005-06-08 日立工機株式会社 Battery charger
JPH11219732A (en) * 1998-02-03 1999-08-10 Toyo System Kk Charging and discharging apparatus for battery

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