JP4584448B2 - ラジカル重合開始剤としてのグリシジル又はアルキルカルボニル基を有するニトロキシル誘導体 - Google Patents

ラジカル重合開始剤としてのグリシジル又はアルキルカルボニル基を有するニトロキシル誘導体 Download PDF

Info

Publication number
JP4584448B2
JP4584448B2 JP2000535640A JP2000535640A JP4584448B2 JP 4584448 B2 JP4584448 B2 JP 4584448B2 JP 2000535640 A JP2000535640 A JP 2000535640A JP 2000535640 A JP2000535640 A JP 2000535640A JP 4584448 B2 JP4584448 B2 JP 4584448B2
Authority
JP
Japan
Prior art keywords
alkyl
monomer
group
polymerization
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2000535640A
Other languages
English (en)
Japanese (ja)
Other versions
JP2002506070A5 (https=
JP2002506070A (ja
Inventor
フソ，フランチェスコ
ロース，ミヒャエル
ヴンダーリッヒ，ヴィーブケ
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba Holding AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Holding AG filed Critical Ciba Holding AG
Publication of JP2002506070A publication Critical patent/JP2002506070A/ja
Publication of JP2002506070A5 publication Critical patent/JP2002506070A5/ja
Application granted granted Critical
Publication of JP4584448B2 publication Critical patent/JP4584448B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/06—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members
    • C07D211/36—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D211/40—Oxygen atoms
    • C07D211/44—Oxygen atoms attached in position 4
    • C07D211/46—Oxygen atoms attached in position 4 having a hydrogen atom as the second substituent in position 4
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/04—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D211/68—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
    • C07D211/72—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D211/74—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94—Oxygen atom, e.g. piperidine N-oxide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Polymerization Catalysts (AREA)
  • Hydrogenated Pyridines (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Paper (AREA)
JP2000535640A 1998-03-09 1999-02-26 ラジカル重合開始剤としてのグリシジル又はアルキルカルボニル基を有するニトロキシル誘導体 Expired - Fee Related JP4584448B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP98810194 1998-03-09
EP98810194.5 1998-03-09
PCT/EP1999/001233 WO1999046261A1 (en) 1998-03-09 1999-02-26 Nitroxyl derivatives with glycidyl or alkylcarbonyl groups as initiators for radical polymerisation

Publications (3)

Publication Number Publication Date
JP2002506070A JP2002506070A (ja) 2002-02-26
JP2002506070A5 JP2002506070A5 (https=) 2006-04-13
JP4584448B2 true JP4584448B2 (ja) 2010-11-24

Family

ID=8235977

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2000535640A Expired - Fee Related JP4584448B2 (ja) 1998-03-09 1999-02-26 ラジカル重合開始剤としてのグリシジル又はアルキルカルボニル基を有するニトロキシル誘導体

Country Status (8)

Country Link
US (1) US6566468B1 (https=)
EP (1) EP1071681B1 (https=)
JP (1) JP4584448B2 (https=)
AU (1) AU2929699A (https=)
CA (1) CA2321792C (https=)
DE (1) DE69933020T2 (https=)
TW (1) TW495515B (https=)
WO (1) WO1999046261A1 (https=)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG82601A1 (en) * 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
TWI225483B (en) * 1998-10-16 2004-12-21 Ciba Sc Holding Ag Heterocyclic alkoxyamines as regulators in controlled radical polymerization process
US6472486B2 (en) 1999-03-09 2002-10-29 Symyx Technologies, Inc. Controlled stable free radical emulsion polymerization processes
AU3733800A (en) 1999-03-09 2000-09-28 Symyx Technologies, Inc. Controlled free radical emulsion and water-based polymerizations and seeded methodologies
JP4829447B2 (ja) * 1999-07-02 2011-12-07 チバ ホールディング インコーポレーテッド 官能化されたマクロマーの製造のための１および多官能価アルコキシアミン
US6716948B1 (en) 1999-07-31 2004-04-06 Symyx Technologies, Inc. Controlled-architecture polymers and use thereof as separation media
AU6279900A (en) 1999-08-12 2001-03-13 Ciba Specialty Chemicals Holding Inc. Polymer blends with improved impact resistance
TW546311B (en) 1999-11-25 2003-08-11 Ciba Sc Holding Ag Composition and method for color improvement of nitroxyl containing polymers
JP2001253916A (ja) * 2000-03-10 2001-09-18 Nippon Chem Ind Co Ltd フルオロアルキル基含有ホスホン酸オリゴマー類およびその製造方法、並びにその用途
TW572896B (en) * 2000-05-26 2004-01-21 Ciba Sc Holding Ag Process for the synthesis of amine ethers from secondary amino oxides
US20030031675A1 (en) 2000-06-06 2003-02-13 Mikesell Glen E. B7-related nucleic acids and polypeptides useful for immunomodulation
TWI274053B (en) * 2000-12-14 2007-02-21 Ciba Sc Holding Ag N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization
US6544304B2 (en) 2001-04-02 2003-04-08 Ciba Specialty Chemicals Corporation Candle wax stabilized with morpholinones
US7868171B2 (en) * 2001-11-12 2011-01-11 Ciba Specialty Chemicals Corp. N-alkoxy-4, 4-dioxy-polyalkyl-piperidines as radical polymerization initiators
US7144691B2 (en) 2002-03-05 2006-12-05 Ciba Specialty Chemicals Corporation Color photographic recording material
AU2003267011A1 (en) * 2002-09-04 2004-03-29 Ciba Specialty Chemicals Holding Inc. Method of producing comb or star copolymers using epoxy-functionalized nitroxylethers
CA2496989A1 (en) 2002-09-26 2004-04-08 Ciba Specialty Chemicals Holding Inc. Thermoplastic compositions with enhanced melt flow and compatibility
WO2004069887A2 (en) * 2003-02-10 2004-08-19 Ciba Specialty Chemicals Holding Inc. Comb copolymers with defined side chains and process for their manufacture
US6967228B2 (en) 2003-05-01 2005-11-22 Firestone Polymers, Llc Stable free radical polymers
US20060079624A1 (en) * 2004-10-08 2006-04-13 Hildeberto Nava Crosslinkable polymer systems
US20060173142A1 (en) * 2005-02-01 2006-08-03 Hildeberto Nava Functionalized thermosetting resin systems
US20090299013A1 (en) * 2005-04-04 2009-12-03 Jochen Fink Process for the Preparation of Star and Block-Copolymers Via Epoxy-Functionalized Alkoxyamines
US7279527B2 (en) 2005-04-22 2007-10-09 Bridgestone Corporation Method of converting anionic living end to protected free radical living end and applications thereof
US20100311920A1 (en) * 2005-08-26 2010-12-09 Cid Centro De Investigacion Y Desarrollo Tecnologico Sa De Cv Using Reactive Block Copolymers as Chain Extenders and Surface Modifiers
US8357759B2 (en) * 2005-08-26 2013-01-22 CID Centro de Investigación y Desarrollo Tecnológico S.A. de C.V. Reactive block copolymers
EP2038701B1 (en) 2006-07-06 2017-04-12 Basf Se Encapsulated dispersions comprising electrophoretically mobile organic colorants
US20100311849A1 (en) * 2006-08-23 2010-12-09 Cid Centro De Investigacion Y Desarrollo Tecnologico Sa De Cv Using Reactive Block Copolymers as Chain Extenders and Surface Modifiers
US7985826B2 (en) 2006-12-22 2011-07-26 Reichhold, Inc. Molding resins using renewable resource component
US7560509B2 (en) 2006-12-29 2009-07-14 Bridgestone Corporation Method of directing grafting by controlling the location of high vinyl segments in a polymer
US7396887B1 (en) 2006-12-29 2008-07-08 Bridgestone Corporation Insitu removal of chelator from anionic polymerization reactions
US7737218B2 (en) 2006-12-29 2010-06-15 Bridgestone Corporation Method for generating free radical capable polymers using tin or silicon halide compounds
US8030410B2 (en) 2006-12-29 2011-10-04 Bridgestone Corporation Method for generating free radical capable polymers using carbonyl-containing compounds
US8270063B2 (en) 2007-09-07 2012-09-18 Basf Se Encapsulated dispersions comprising electrophoretically mobile organic colorants
CN106699639A (zh) * 2016-12-22 2017-05-24 甘肃省化工研究院 一种光稳定剂hs‑112的合成方法
US11917906B2 (en) * 2018-11-05 2024-02-27 Merck Patent Gmbh Compounds that can be used in an organic electronic device
FR3152278A1 (fr) 2023-08-24 2025-02-28 Snf Sa polymère hydrosoluble ramifié comme liant pour batterie
FR3152279A1 (fr) 2023-08-24 2025-02-28 Snf Sa Polymere hydrosoluble comme liant pour batterie

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6089452A (ja) * 1983-07-11 1985-05-20 コモンウエルス　サイエンテイフイツク　アンド　インダストリアル　リサ−チ　オ−ガニゼ−シヨン 遊離基重合開始用化合物
AU571240B2 (en) * 1983-07-11 1988-04-14 Commonwealth Scientific And Industrial Research Organisation Alkoxy-amines, useful as initiators
EP0155912A3 (de) * 1984-03-20 1986-06-04 Ciba-Geigy Ag Strahlenstabilisierte polymere Zusammensetzungen
TW270131B (https=) 1993-07-13 1996-02-11 Ciba Geigy
HU220138B (hu) * 1996-03-29 2001-11-28 The Dow Chemical Co. Szabadgyökös tömbpolimerizálási eljárás kaucsukkal módosított polimerek vinil-aromás monomerekből való előállítására
AU4773997A (en) 1996-09-25 1998-04-17 Akzo Nobel N.V. No-compounds for pseudo-living radical polymerization
TWI225483B (en) * 1998-10-16 2004-12-21 Ciba Sc Holding Ag Heterocyclic alkoxyamines as regulators in controlled radical polymerization process

Also Published As

Publication number Publication date
DE69933020T2 (de) 2007-04-05
WO1999046261A1 (en) 1999-09-16
AU2929699A (en) 1999-09-27
TW495515B (en) 2002-07-21
CA2321792A1 (en) 1999-09-16
JP2002506070A (ja) 2002-02-26
US6566468B1 (en) 2003-05-20
CA2321792C (en) 2009-12-29
EP1071681A1 (en) 2001-01-31
EP1071681B1 (en) 2006-08-30
DE69933020D1 (de) 2006-10-12

Similar Documents

Publication Publication Date Title
JP4584448B2 (ja) ラジカル重合開始剤としてのグリシジル又はアルキルカルボニル基を有するニトロキシル誘導体
US6455706B2 (en) Polymerizable compositions containing alkoxyamine compounds derived from nitroso- or nitrone compounds
JP3660687B2 (ja) 末端不飽和オリゴマーの合成
EP1322674B1 (en) Control agents for living-type free radical polymerization, methods of polymerizing, emulsions and polymers with same
JP4651137B2 (ja) １−アルコキシ−ポリアルキル−ピペリジン誘導体および重合調節剤としてのその使用
EP1527079A2 (fr) Alcoxyamines issues de nitroxydes beta-phosphores
JP4546027B2 (ja) ラジカル重合開始剤としてのｎ−アルコキシ−４，４−ジオキシ−ポリアルキル−ピペリジン
JP4593786B2 (ja) Ｎ→ｏ末端基を含むポリマーの製造方法
TWI246519B (en) Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators
JP4389247B2 (ja) ４−イミノ−ｎ−アルコキシまたはオキシポリアルキルピペリジン化合物および重合調節剤としてのそれらの使用
KR100920465B1 (ko) 폴리알킬피페리딘, 폴리알킬피페라지논 및폴리알킬모르폴리논을 기본으로한 다작용성 알콕시아민 및이들의 중합조절제／개시제로서의 용도
JP2003503474A (ja) 官能化されたマクロマーの製造のための１および多官能価アルコキシアミン
EP0891986A1 (en) Polymerizable compositions containing alkoxyamine compounds derived from nitrogen oxide
US20040002606A1 (en) Process for the synthesis for alkoxy amines and their use in controlled radical polymerization
MXPA00008767A (en) Nitroxyl derivatives with glycidyl or alkylcarbonyl groups as initiators for radical polymerisation
KR100778770B1 (ko) 제어 자유 라디칼 중합반응을 향상시키기 위한 조성물 및방법
JP2005537371A (ja) エポキシ官能化したニトロキシルエーテルを使用する櫛型または星型コポリマーの生成方法
MXPA01002844A (es) Metodo para la preparacion de copolimeros en bloques mediante polimerizacion radicalica cuasi-.viviente basada en nuevos agentes de transferencia de cadena.

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20060213

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20060213

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20091021

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20091110

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20100204

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20100831

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20100902

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130910

Year of fee payment: 3

LAPS Cancellation because of no payment of annual fees