JP4516098B2 - Storage battery - Google Patents

Storage battery Download PDF

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JP4516098B2
JP4516098B2 JP2007180604A JP2007180604A JP4516098B2 JP 4516098 B2 JP4516098 B2 JP 4516098B2 JP 2007180604 A JP2007180604 A JP 2007180604A JP 2007180604 A JP2007180604 A JP 2007180604A JP 4516098 B2 JP4516098 B2 JP 4516098B2
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exhaust
lid
storage battery
gas
lid body
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JP2009021017A (en
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秋夫 瀬尾
浩二 渡部
久士 大内
修一 矢吹
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Furukawa Battery Co Ltd
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Furukawa Battery Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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Description

本発明は、蓄電池に関する。   The present invention relates to a storage battery.

蓋本体上面に電槽の各セル室に対応する個所に凹部を形成してこの凹部内に排気筒を備え、その上面を上蓋で覆って成る二重蓋構造から成り、該二重蓋間に、各排気筒に連通する排気通路を介し、セル室から排出されるガスを導出し、上蓋に設けたガスフィルターを介しガス排出口を外部に排出するようにした漏液防止装置を備えた蓄電池は一般に広く知られている。此種蓄電池において、該蓄電池が横転した場合、各セル室内の電解液が外部に漏れ出ないようにエアロック機構を具備した蓄電池が開発され、特許文献1に記載されている。
即ち、該特許文献1に記載の蓄電池は、電槽に施される蓋本体に、電槽のセル室に対応してガス排気筒が蓋本体を貫通して形成され、その排気筒の外周にこれを囲む隔壁に上蓋の裏面に設けた囲繞隔壁を当接されて成るエアロック機構を具備しており、これにより、横転時、各セル室から上蓋裏面に流出した電解液が該囲繞隔壁内から外部に漏れ出ないようにし、その転倒状態から該蓄電池を正立状態に戻した時は、該囲繞隔壁内の電解液は該排気筒外周の開口部を介し各セル室内へ還流するように構成されている。
特開昭57-143261号公報
A concave portion is formed in a portion corresponding to each cell chamber of the battery case on the upper surface of the lid body, and an exhaust pipe is provided in the concave portion, and the upper face is covered with an upper lid, and each exhaust pipe is provided between the double lids. Storage batteries equipped with a liquid leakage prevention device that leads out gas discharged from the cell chamber via an exhaust passage communicating with the gas chamber and discharges the gas discharge port to the outside via a gas filter provided on the upper lid are generally widely known. It has been. In this type of storage battery, a storage battery equipped with an air lock mechanism has been developed and described in Patent Document 1 so that the electrolyte in each cell chamber does not leak outside when the storage battery rolls over.
That is, in the storage battery described in Patent Document 1, a gas exhaust tube is formed in the lid body applied to the battery case so as to correspond to the cell chamber of the battery case, and is formed on the outer periphery of the exhaust tube. An air lock mechanism is provided in which the surrounding partition wall is in contact with the surrounding partition wall provided on the back surface of the upper lid, so that the electrolyte flowing out from each cell chamber to the back surface of the upper lid during rollover When the storage battery is returned to the upright state from the fall state, the electrolytic solution in the surrounding partition wall is circulated into each cell chamber through the opening on the outer periphery of the exhaust tube. It is configured.
JP 57-143261 A

しかし乍ら、上記特許文献1の公報7頁右上欄第13行〜第17行の記載及び図4,図5及び図6,図7に明らかなように、バッフル(排気筒)82には、セル室内の電解液面がその該排気筒の下端に到達しても、排気ガスの逃げ場を確保するために、基底部20より垂下突出するその下部筒体の周側壁に、その下端に該基底部20に配設した液還流用開口部88の位置近傍まで達する長矩形状の切欠きから成る貫通孔(符号なし)を形成し、セル室内のガスは、矢示90のように、即ち、該貫通孔を有する該バッフル82内へ流入し、上方向に進み、即ち、上昇し、それから矢示92,94のように下方から上方に進み、室70に至るように構成している。また、例示しないが、前記の切欠きから成る貫通孔に代え、排気筒の下部筒体の周側壁に透孔から成る貫通孔を設ける場合も知られている。然るに、該特許文献1の蓄電池は、該排気筒の下部筒体の周側壁前記の貫通孔が形成されているため、その横倒状態から正立状態にしたとき、該上蓋の裏面に溜まっていた電解液の全量が、セル室内へ戻る速度が遅くなる。下部筒体の周側壁に透孔から成る貫通孔を穿設した場合も同様である。従って、蓄電池を正立状態に戻した時の還流速度を早くすることが望まれる。
本発明は、かゝる課題を解消し、上記の要望を満足した蓄電池を提供する。
However, as is apparent from the description in the upper right column of lines 13 to 17 of the publication 7 of the above-mentioned Patent Document 1 and FIGS. 4 , 5, 6, and 7 , the baffle ( exhaust pipe ) 82 includes: Even if the electrolyte surface in the cell chamber reaches the lower end of the exhaust cylinder, in order to secure a place for exhaust gas to escape, the peripheral wall of the lower cylinder projecting from the base part 20 is placed on the lower end of the base. A through hole (not shown) having a long rectangular notch reaching the position of the liquid reflux opening 88 disposed in the portion 20 is formed, and the gas in the cell chamber is indicated by an arrow 90, that is, the gas It flows into the baffle 82 having a through-hole and proceeds upward, that is, ascends, and then proceeds upward from below as indicated by arrows 92 and 94 to reach the chamber 70. Although not illustrated, it is also known that a through hole made of a through hole is provided on the peripheral side wall of the lower cylinder of the exhaust pipe instead of the through hole made of the notch. However, the storage battery of the Patent Document 1, since the through hole of the in the peripheral side wall of the lower cylinder of the exhaust cylinder is formed, when the back from the fallen down state to the upright state, the rear surface of the upper lid The speed at which the total amount of the accumulated electrolyte returns to the cell chamber is slow . The same applies to a case where a through hole made of a through hole is formed in the peripheral side wall of the lower cylindrical body. Therefore, it is desired to quickly reflux rate at the time of return the battery to erect state.
The present invention solves such problems and provides a storage battery that satisfies the above-mentioned requirements.

本発明の蓄電池は、請求項1に記載の通り、内部を仕切壁により区画された複数のセル室を有する電槽の上面に、蓋板を貫通して形成したその夫々のセル室に連通する夫々の排気筒と相隣る排気筒間を隔離し且つ囲繞する囲繞隔壁により夫々独立した排気通路を形成した蓋本体を気密に施し、該蓋本体の上面に、該蓋本体の夫々の独立した排気通路に対応して夫々独立した排気通路を裏面に設けた上蓋を気密に施して成る二重蓋構造から成ると共に、少なくとも1つのガスフィルターを介し排気せしめるガス排出口を具備し、更に、各セル室内の電解液が外部へ漏れ出ることを防止するエアロック機構を具備した蓄電池において、各排気筒の外周の前記蓋板に複数個の電解液環流孔を穿設し、更に該排気筒の該蓋板の裏面より下方に延びる下部筒体の周側壁該電解液還流孔の位置から下端までの高さHを有し、且つ透孔や切欠きなどから成る貫通孔のない周側壁に形成することにより、該周側壁の内部に前記の高さHに相当する空気柱の圧力を生ぜしめるようにしたことを特徴とする。
更に、本発明は、上記の蓄電池において、請求項2に記載の通り、前記排気筒は、そのガス排出側の上端の開口面傾斜開口面に形成すると共に、そのガス流入側の下端の開口面を傾斜開口面に形成したことを特徴とする。
As described in claim 1, the storage battery of the present invention communicates with each cell chamber formed through the cover plate on the upper surface of the battery case having a plurality of cell chambers that are partitioned by partition walls. A lid body in which an independent exhaust passage is formed by a surrounding partition wall that isolates and surrounds each of the adjacent exhaust cylinders is hermetically applied, and each lid body is independently provided on an upper surface of the lid body. Each cell chamber is provided with a gas discharge port for exhausting through at least one gas filter. of the storage battery provided with the air lock mechanism that electrolyte is prevented from leaking to the outside, bored a plurality of electrolyte recirculation hole in the cover plate of the outer periphery of the exhaust pipe, further to the of the stack lower extending downward from the rear surface of the cover plate By having the height H of the peripheral side wall of the body from the position of the electrolytic solution refluxed hole to the lower end, and is formed on the free peripheral side wall of the through hole made of a-out through hole or notch, inside of the peripheral side wall An air column pressure corresponding to the height H is generated .
Further, in the above storage battery, as claimed in claim 2, wherein the exhaust pipe is configured to form an opening surface of the upper end of the gas discharge side of the inclined opening surface, the opening of the lower end of the gas inlet side The surface is formed as an inclined opening surface.

請求項1に係る発明によれば、蓄電池を、その転倒状態から正立状態に戻したときに該下部筒体内に生ずる前記の高さHに相当する空気柱の圧力が該排気筒の下端に加わるので、空気を上方に押し上げる圧力が強くなるので、その外周の電解液還流孔から流下する電解液と置換する電槽内の空気は該排気筒内を上昇するガスの流速は促進され、これに伴い、電解液の還流速度は促進されるので、上記従来の蓄電池に比し、正立状態に戻した時のセル室内への電解液の還流速度は早くなる。
請求項2に係る発明によれば、前記排気筒のガス排出側の上端の開口面を傾斜面に形成すると共に、そのガス流入側の下端の開口面を傾斜開口面に形成したので、該上端の開口面及び該下端の開口面に液膜の形成が防止されるので、正立時の排気や倒立から正立状態に戻したときの液還流が支障なく円滑に行うことができる。
According to the invention of claim 1, the pressure of the air column corresponding to the height H generated in the lower cylinder when the storage battery is returned from the overturned state to the upright state is applied to the lower end of the exhaust cylinder. As a result, the pressure that pushes the air upward increases, so the air in the battery case that replaces the electrolyte flowing down from the electrolyte reflux hole on the outer periphery accelerates the flow rate of the gas rising in the exhaust tube. Accordingly, the reflux rate of the electrolytic solution is accelerated, so that the reflux rate of the electrolytic solution into the cell chamber when returning to an upright state is faster than that of the conventional storage battery.
According to the invention of claim 2, thereby forming an opening surface of the upper end of the gas discharge side of the exhaust pipe on the inclined surface, so to form an opening surface of the lower end of the gas inlet side to the inclined opening surface, upper end since the formation of the liquid film on the opening surface of the opening surface and the lower end of the can be prevented, the liquid reflux can be performed smoothly without trouble upon reconstitution erecting when the exhaust or inverted to upright state.

本発明の実施の形態の1例を添付図面につき説明する。
図1は、合成樹脂成形体から成る方形箱形の蓋本体の上面図を示す。参照符号1で示す該蓋本体の蓋板1aの上面の一部を、該蓋本体1が施される電槽の内部を仕切壁により区画形成されセル室の数に相当する数の、図示の例では、6個のセル室に跨る面域を底面とする長方形の凹面1a1に成形し、その凹面の空間内に、次のような排気構造を構成する。即ち、その長方形の凹面1a1空間内に、その四周内側壁面に沿い、且つその凹面空間1a1の底面、即ち、該蓋板1aの上面から所望の高さの方形の四周囲枠2を突設する。その高さは、その上端が図示の例では、該凹部空間1a1の左右に形成した後述する筒状のガス排出口を嵌装するための凹溝1b,1bの底面と同じ或いはそれより高い高さとした。更に、該蓋板1aの上面に、該四周囲枠2で囲繞される凹部空間内に、該電槽の内部を区画形成された6個のセル室40b,40b,…に対応する位置で、該蓋板1aに、各セル室に連通する排気孔3a及び注液口4を穿設し、その夫々の外周に、該蓋板1aを貫通する排気筒3と該蓋板1aの底面から突出する注液筒4aの一組ずつを配設する。各排気筒3は、該四周囲枠2の高さよりも高い適当な高さに突設せしめ、各注液筒4aは、該四周囲枠2の高さと同じ高さに突設せしめた。
更に、該四周囲枠2内には、下記するように6つの夫々独立した排気通路を形成した。即ち、該四周囲枠2内に、各相隣る排気筒3,3間を隔離すると共に各排気筒3を囲繞する隔壁5a,5a,…を該四周囲枠2と同じ高さに突設し、6個の排気筒3,3,…の夫々が互いに連通することなく独立した6個の排気通路6a,6a,…を区画形成した。更に、各独立した排気通路6a内に、各独立した注液筒4aの側面から該排気筒3の側方を横切り、該四周囲枠2の一方の長辺側枠2aの近傍まで延び、且つ該四周囲枠2aと同じ高さの隔壁7aを突設し、これにより、各該排気通路6aを該排気筒3側に、これを囲繞する小室に形成された内側通路6a1と該隔壁7aと該長辺側枠2aの内側面との間に存せしめた間隙8aを介して該内側通路6a1と連通する外側の通路6a2とに区分した。更に、その小室に形成された内側通路6a1内に、該長辺側枠2aの内側面から該排気筒3と該隔壁7aとの間に延び且つ該四周囲枠2と同じ高さの隔壁9aを突設し、これにより、電槽内の各セル室から該排気筒3を介し内側通路6a1に進入したガスが、直接、該間隙8aから該外側通路6a2へ排出されることが妨げられ、該隔壁9aと該隔壁7aとの間に形成された通路6a3を通過した後、該間隙8aから該外側通路6a2に排出せしめるように、その通過距離を延長して、電解液ミストの捕集効果を高めるようにした。尚また、該隔壁7aの外側面から側面に該外側通路6a2内へ突設して、該隔壁7aと同じ高さの防沫壁10aを突設した。該防沫壁10aは、外側通路6a2内に突出するようにその複数枚を配設してもよい。
図面で、11は該蓋本体1が施される電槽の仕切壁に対応して該蓋本体1の裏面から下垂突出させた仕切壁、12は正極端子、13は負極端子、14は比重液面表示栓を示す。
An example of an embodiment of the present invention will be described with reference to the accompanying drawings.
FIG. 1 shows a top view of a rectangular box-shaped lid body made of a synthetic resin molding. A part of the upper surface of the lid plate 1a of the lid body indicated by reference numeral 1 is formed in a number corresponding to the number of cell chambers formed by partitioning the interior of the battery case in which the lid body 1 is provided by a partition wall. In the example, a rectangular concave surface 1a1 whose bottom surface is a surface area extending over six cell chambers is formed, and the following exhaust structure is configured in the space of the concave surface. That is, in the rectangular concave surface 1a1 space, a rectangular four-circumference frame 2 having a desired height is projected from the bottom surface of the concave space 1a1, that is, the upper surface of the lid plate 1a, along the four inner circumferential wall surfaces. . In the illustrated example, the height of the upper end is the same as or higher than the bottom surfaces of the concave grooves 1b and 1b for fitting cylindrical gas discharge ports (described later) formed on the left and right sides of the concave space 1a1. Say it. Further, on the upper surface of the lid plate 1a, in a recessed space surrounded by the four peripheral frames 2, at positions corresponding to the six cell chambers 40b, 40b,. The cover plate 1a is provided with exhaust holes 3a and liquid injection ports 4 communicating with the respective cell chambers, and the outer periphery of the cover plate 1a protrudes from the exhaust tube 3 passing through the cover plate 1a and the bottom surface of the cover plate 1a. One set of liquid injection cylinders 4a is arranged. Each exhaust cylinder 3 protruded to an appropriate height higher than the height of the four surrounding frame 2, and each liquid injection cylinder 4 a protruded to the same height as the four surrounding frame 2.
Further, six independent exhaust passages were formed in the four peripheral frames 2 as described below. That is, the four surrounding frames 2 are provided with partition walls 5a, 5a,... Projecting at the same height as the four surrounding frames 2 so as to isolate the adjacent exhaust tubes 3 and 3 from each other and surround each exhaust tube 3. Then, the six exhaust cylinders 3, 3,... Are partitioned into six independent exhaust passages 6a, 6a,. Further, in each independent exhaust passage 6a, it crosses the side of the exhaust cylinder 3 from the side surface of each independent liquid injection cylinder 4a, extends to the vicinity of one long side frame 2a of the four peripheral frame 2, and A partition wall 7a having the same height as that of the four peripheral frames 2a is projected so that each of the exhaust passages 6a is formed on the exhaust tube 3 side, and an inner passage 6a1 formed in a small chamber surrounding the exhaust passage 6a and the partition wall 7a. It was divided into an outer passage 6a2 communicating with the inner passage 6a1 through a gap 8a existing between the inner side surface of the long side frame 2a. Further, in the inner passage 6a1 formed in the small chamber, a partition wall 9a extending between the exhaust tube 3 and the partition wall 7a from the inner surface of the long side frame 2a and having the same height as the four peripheral frames 2 Thus, the gas that has entered the inner passage 6a1 from each cell chamber in the battery case via the exhaust tube 3 is prevented from being directly discharged from the gap 8a to the outer passage 6a2. After passing through the passage 6a3 formed between the partition wall 9a and the partition wall 7a, the passage distance is extended so as to be discharged from the gap 8a to the outer passage 6a2, thereby collecting the electrolyte mist. I tried to increase. Further, a splash-proof wall 10a having the same height as the partition wall 7a was projected from the outer surface to the side surface of the partition wall 7a so as to project into the outer passage 6a2. A plurality of the splash-proof walls 10a may be disposed so as to protrude into the outer passage 6a2.
In the drawing, 11 is a partition wall projecting downward from the back surface of the lid body 1 corresponding to the partition wall of the battery case to which the lid body 1 is applied, 12 is a positive terminal, 13 is a negative terminal, and 14 is a specific gravity liquid A surface indicator plug is shown.

図2は、上記の蓋本体1の該四周囲枠2の上面に当接して施されるに適した大きさ、形状を有する合成樹脂成形による上蓋20の裏面図、図3は、該上蓋20の上面図を示す。該上蓋20は、実施例では、裏側に凹面空間を形成した箱形とした。
該上蓋20は、蓋板20aとその四周縁から所望高さ下向きに延びる四周側壁20bとから成り、その四周側壁20bの下端は、該上蓋20を該蓋本体1の該四周囲枠2に施されるとき、該四周囲枠2とその外側の該凹面1a1の四周内面との間の空隙に挿入される外側壁20b1と、該四周囲枠2の上端に当接する内側の四周側壁20b2とから成る嵌合係止用段差を有する下端に形成されている。かくして、該上蓋20は、該蓋本体1の該四周囲枠2の上端部に当接係合し、熱融着、接着により互いに結着されるようにした。該蓋板20aには、該蓋本体1上に載せたときに、該蓋本体1の夫々の注液筒4a,4a,…に対応する位置に6個の注液口が穿設されており、更に、該上蓋の裏面の凹状空間内に、蓋本体1の裏面に設けた6つの夫々独立した排気通路6a,6a,…に対応する夫々独立した排気通路を下記のように形成した。
即ち、更に詳細には、その蓋板20aの裏面には、該蓋本体1の該四周囲枠2内に配設した6つの注液口4,4,…と注液筒4a,4a,…に対応する位置に、6つの注液口4,4,…とその外周縁に6つの注液筒4b,4b,…を該四周側壁20b1と同じ高さに突出せしめて配設し、更に、該蓋本体1の該四周囲枠2内で該蓋板1aの上面から突出せしめた囲繞隔壁5a,5a,…に対応する位置に囲繞隔壁5b,5b,…を該四周側壁20b2と同じ高さに突出せしめて配設し、これにより、該蓋本体1に形成された夫々独立した排気通路6a,6a,…に対応する夫々独立した排気通路6b,6b,…が形成されるようにした。更に、該蓋本体1に配設した該隔壁7aに対応する位置に隔壁7b、該隔壁9aに対応する位置に隔壁9b及び該隔壁7aの側面に付設した防沫壁10aに対応する位置に防沫壁10bを夫々その蓋板20aの裏面から該四周側壁20b2と同じ高さに突出して配設し、これにより、蓋本体1に形成された間隙8a、小室に形成された内側通路6a1及び外側通路6a2に対応する位置に、間隙8b、小室に形成された内側通路6b1及び外側通路6b2を夫々形成せしめた。
FIG. 2 is a rear view of the upper lid 20 made of a synthetic resin having a size and shape suitable for being applied in contact with the upper surface of the four peripheral frames 2 of the lid body 1, and FIG. The top view of is shown. In the embodiment, the upper lid 20 has a box shape with a concave space formed on the back side.
The upper lid 20 includes a lid plate 20a and a four-circumferential side wall 20b extending downward from the four peripheral edges to a desired height, and the lower end of the four-circumferential side wall 20b applies the upper lid 20 to the four peripheral frames 2 of the lid main body 1. The outer wall 20b1 inserted into the gap between the four peripheral frame 2 and the outer peripheral surface of the concave surface 1a1, and the inner peripheral wall 20b2 in contact with the upper end of the four peripheral frame 2. It forms in the lower end which has the level | step difference for fitting latching which consists. Thus, the upper lid 20 is brought into contact with and engaged with the upper end of the four peripheral frame 2 of the lid main body 1 and is bonded to each other by heat fusion and adhesion. The lid plate 20a has six liquid injection holes formed at positions corresponding to the liquid injection cylinders 4a, 4a,... Of the lid main body 1 when placed on the lid main body 1. Further, independent exhaust passages corresponding to the six independent exhaust passages 6a, 6a,... Provided on the back surface of the lid body 1 were formed in the concave space on the back surface of the upper lid as follows.
More specifically, on the back surface of the lid plate 20a, there are six liquid injection ports 4, 4,... And liquid injection cylinders 4a, 4a,. Are arranged at the same height as the four peripheral side walls 20b1, and six liquid injection ports 4b, 4b,... The surrounding partition walls 5b, 5b,... Are flush with the surrounding wall 20b2 at positions corresponding to the surrounding partition walls 5a, 5a,... Projected from the upper surface of the lid plate 1a within the four peripheral frames 2 of the lid body 1. In this way, independent exhaust passages 6b, 6b, ... corresponding to the independent exhaust passages 6a, 6a, ... formed in the lid body 1 are formed. Further, the partition wall 7b is disposed at a position corresponding to the partition wall 7a disposed on the lid body 1, the partition wall 9b is disposed at a position corresponding to the partition wall 9a, and the position corresponding to the splash-proof wall 10a attached to the side surface of the partition wall 7a. Each of the spray walls 10b is disposed so as to protrude from the back surface of the lid plate 20a to the same height as the four-side wall 20b2, so that the gap 8a formed in the lid body 1, the inner passage 6a1 formed in the small chamber, and the outer side A gap 8b and an inner passage 6b1 and an outer passage 6b2 formed in the small chamber were formed at positions corresponding to the passage 6a2.

尚、図示の例では、蓋本体1に形成した上記6本の排気通路6a,6a,…及び該上蓋20に形成した上記6本の排気通路6b,6b…は、図1及び図2に明らかなように、その夫々の左半部と右半部が左右対象となるように中央の囲繞隔壁5a,5aにより分割構成され、該蓋本体1の上面に該上蓋20を重合結着したとき、図面で、該蓋本体1の左側の3つの夫々独立した排気通路6a,6a,6aと該上蓋20の左側の3つの夫々独立した排気通路6b,6b,6bとは、上下方向で連通して排気通路6,6,6が形成されると共に、これら排気通路6,6,6は、上蓋20側の左側方の該四周側壁20bの左側のコーナー部内に設けた防爆用のガスフィルター21に連通するようにする一方、図面で、該蓋本体1の右側の3つの夫々独立した排気通路6a,6a,6aと該上蓋20の右側の3つの夫々独立した排気通路6b,6b,6bとは、上下方向で連通して排気通路6,6,6が形成されると共に、これら排気通路6,6,6は、上蓋20側の右側方の該四周側壁20bの右側のコーナー部内に設けた防爆用のガスフィルター21に連通するようにした。   In the illustrated example, the six exhaust passages 6a, 6a,... Formed in the lid body 1 and the six exhaust passages 6b, 6b formed in the upper lid 20 are clearly shown in FIGS. As shown, the left half and the right half of each of the left and right halves are divided by the central surrounding partition walls 5a and 5a so that the left and right objects are left and right, and when the upper lid 20 is superposed on the upper surface of the lid body 1, In the drawing, the three independent exhaust passages 6a, 6a, 6a on the left side of the lid body 1 and the three independent exhaust passages 6b, 6b, 6b on the left side of the upper lid 20 are communicated in the vertical direction. Exhaust passages 6, 6, 6 are formed, and these exhaust passages 6, 6, 6 communicate with an explosion-proof gas filter 21 provided in the left corner of the four-side wall 20b on the left side on the upper lid 20 side. On the other hand, in the drawing, the three independent exhaust passages 6a, 6a, 6a on the right side of the lid body 1 and the three independent exhaust passages 6b, 6b, 6b on the right side of the upper lid 20 are Communicate vertically The exhaust passages 6, 6, 6 are formed, and the exhaust passages 6, 6, 6 are formed in the right corner of the four-side wall 20b on the right side on the upper lid 20 side, and an explosion-proof gas filter 21 is provided. To communicate with.

更に詳細には、図2に示すように、上蓋20側の3つの夫々独立した排気通路6b,6b,6bは、該四周側壁20bの左側のコーナー部内まで延び、右側の3つの夫々独立した排気通路6b,6b,6bは、該四周側壁20bの右側のコーナー部内まで延び、左右の夫々のコーナー部内には、左右の夫々の3つの排気通路6b,6b,6b及び6b,6b,6bを区画する隔壁5b,5b,5b及び5b,5b,5bの上端と同じレベル位置、或いはそれより低い位置、即ち、該上蓋20の該蓋板20aに近くなる側の位置に、これらの隔壁の外側端面に圧入又は接着するなどの任意の手段で防爆用のガスフィルター21が装着されたガスフィルター装着筒22,22を夫々固設し、その夫々のフィルター装着筒22,22の側方に位置してこれら装着筒22,22内と連通するガス排出口23,23を設ける。図示の例では、筒状ガス排気口23,23とし、その内端をこれらフィルター装着筒22,22内と連通開口せしめた。夫々の筒状ガス排気口23,23は、例えば、断面が中空矩形状の筒とし、該四周側壁20bの左右の短い側の側壁に設けた孔を気液密に貫通して固設せしめたものであり、かくして、該上蓋20を該蓋本体1の上面に施したとき、該左右のフィルター装着筒22,22は、左右の夫々3つの排気通路の外端の上面開口が集合している該蓋本体1の該四周囲枠2の左右のコーナー部内の空間部2c,2cの上方の円形の仮想線で示す位置に来ると同時に、該左右のガス排出口23,23は、該蓋本体1の上面の左右の前記した嵌合凹溝1b,1bに位置するようにした。   More specifically, as shown in FIG. 2, the three independent exhaust passages 6b, 6b, 6b on the upper lid 20 side extend into the left corner of the four-side wall 20b, and the three independent exhaust passages on the right side. The passages 6b, 6b, 6b extend to the right corner of the four-side wall 20b, and the left and right corners are divided into three exhaust passages 6b, 6b, 6b and 6b, 6b, 6b. The partition walls 5b, 5b, 5b and 5b, 5b, 5b are at the same level as the upper ends of the partition walls 5b, 5b, 5b, or lower, that is, on the side closer to the cover plate 20a of the upper cover 20, the outer end surfaces of these partitions. The gas filter mounting cylinders 22 and 22 to which the gas filter 21 for explosion prevention is mounted are fixed by any means such as press-fitting or bonding to each other, and are located on the sides of the respective filter mounting cylinders 22 and 22. Gas discharge ports 23, 23 communicating with the inside of the mounting cylinders 22, 22 are provided. In the illustrated example, cylindrical gas exhaust ports 23 and 23 are provided, and the inner ends thereof are opened to communicate with the filter mounting cylinders 22 and 22, respectively. Each of the cylindrical gas exhaust ports 23 and 23 is, for example, a cylinder having a hollow rectangular cross section, and the holes provided in the left and right short side walls of the four-side wall 20b are gas-liquid tightly penetrated and fixed. Thus, when the upper lid 20 is applied to the upper surface of the lid body 1, the left and right filter mounting cylinders 22 and 22 have upper surface openings at the outer ends of the left and right exhaust passages, respectively. The left and right gas exhaust ports 23 and 23 are located at the positions indicated by the circular phantom lines above the space portions 2c and 2c in the left and right corner portions of the four peripheral frames 2 of the lid body 1 and the lid body 1 1 is located in the above-described fitting grooves 1b and 1b on the left and right of the upper surface of 1.

而して、鉛蓄電池に組み立てるには、常法により、図3及び図4に示す電槽40の上面開口部を閉塞するべく、該蓋本体1の四周側壁1cの下端とその裏面各仕切壁11,11,…を対応する電槽40の四周側壁40aと該電槽40内を6個のセル室40bに仕切る各仕切壁40cに熱融着、接着などで固着し、その蓋本体1の上面に、該上蓋20を施し、該蓋本体1の該四周囲枠2の上面に該上蓋20の該四周囲枠2bを嵌着し、互いに熱融着、接着などで気液密に結着し、これにより、該上蓋20の該四周側壁20bと該蓋本体1の該四周囲枠2との合体により、夫々対向する囲繞隔壁5a,5a,…と5b,5b,…の合体した囲繞隔壁により、夫々の排気筒3,3,…を囲んだ夫々独立した該蓋本体1側の排気通路6a,6a,…と該上蓋20側の排気通路6b,6b,…が上下方向で連通した6本の夫々独立した排気通路6,6,…が得られ、更に、各排気通路6,6,…内において、隔壁7a,7bが合体した隔壁、隔壁9a,9aが合体した隔壁、該防沫壁10a,10bが合体した防沫壁が得られ、これにより、上下方向に連通する小室に形成された内側通路、外側通路及び間隙が夫々形成された鉛蓄電池が得られる。而して、該蓄電池の上蓋20の各注液口4,4より電解液を注入し、各セル室40b,40b,…内に夫々収容されている極板群(図示しない)を浸漬した遊離電解液を保有せしめ、夫々の注液口4に密封栓(図示しない)を施し、鉛蓄電池を構成する。   Thus, to assemble the lead-acid battery, in order to close the upper surface opening of the battery case 40 shown in FIGS. 11, 11,... Are fixed to the four peripheral side walls 40 a of the corresponding battery case 40 and the partition walls 40 c partitioning the inside of the battery case 40 into six cell chambers 40 b by heat fusion, adhesion, etc. The upper lid 20 is provided on the upper surface, and the four peripheral frames 2b of the upper lid 20 are fitted on the upper surface of the four peripheral frames 2 of the lid body 1, and are bonded to each other in a gas-liquid tight manner by heat fusion, adhesion, or the like. Thus, the surrounding partition walls 5a, 5a,..., 5b, 5b,... Are combined by the combination of the four peripheral side walls 20b of the upper lid 20 and the four peripheral frames 2 of the lid body 1. , And the independent exhaust passages 6a, 6a,... On the lid body 1 side surrounding the respective exhaust cylinders 3, 3,... And the exhaust passages 6b, 6b,. Each of the books has independent exhaust passages 6, 6,. In each exhaust passage 6,6, ..., a partition wall in which the partition walls 7a, 7b are combined, a partition wall in which the partition walls 9a, 9a are combined, and a splash-proof wall in which the splash-proof walls 10a, 10b are combined are obtained. A lead storage battery in which an inner passage, an outer passage, and a gap formed in a small chamber communicating with each other in the vertical direction are obtained. Thus, the electrolytic solution is injected from the liquid injection ports 4 and 4 of the upper lid 20 of the storage battery, and the electrode plates (not shown) accommodated in the cell chambers 40b, 40b,. The electrolyte solution is held, and a sealing plug (not shown) is applied to each liquid injection port 4 to constitute a lead storage battery.

上記の鉛蓄電池の充電時又は過充電時に電槽の各セル室に発生したガスは、夫々対応する排気筒3,3,…を介し、その夫々の排気通路6,6,…に進入し、次いで、左側と右側の夫々3本ずつの独立した排気通路6,6,6からのガスは、その前方の空間部2c,2cに至り、次いで、その上方に配設した左右のガスフィルター21,21を介し左右のガス排出口23,23から外部に夫々一括排気される。   The gas generated in each cell chamber of the battery case at the time of charging or overcharging of the lead storage battery enters the respective exhaust passages 6, 6, ... through the corresponding exhaust pipes 3, 3, ... Next, the gas from each of the three independent exhaust passages 6, 6, 6 on the left side and the right side reaches the front space portions 2c, 2c, and then the left and right gas filters 21, The gas is exhausted from the left and right gas outlets 23 and 23 to the outside through the gas outlet 21 and the gas outlet 23, respectively.

かくして、その夫々の独立した排気用通路6,6,…をガスが通過する間に、上記の種々の隔壁や防沫壁などに衝突するので、ガス中の電解液ミストは捕捉され、ガスのみが外部に排出されるので、排気中の液漏れが防止される。一方、捕集した電解液は、相互に交じり合うことがない。尚、夫々の独立した排気通路6,6,…内に捕捉された電解液を流下し、夫々の排気筒3,3,…を介して夫々セル室に還流させるには、該蓋本体1の蓋板1aの上面に相当する各独立した排気通路6,6,…の底面を、各該排気通路6の外端側から該排気孔3aに至るに従い下り坂の傾斜底面とすることが必要である。   Thus, while the gas passes through each of the independent exhaust passages 6, 6,..., It collides with the various partition walls and splash-proof walls, so that the electrolyte mist in the gas is captured and only the gas is captured. Is discharged to the outside, so that liquid leakage in the exhaust is prevented. On the other hand, the collected electrolytes do not mix with each other. In order to flow down the electrolytic solution trapped in each of the independent exhaust passages 6, 6,... And return them to the cell chambers through the respective exhaust cylinders 3, 3,. It is necessary that the bottom surfaces of the individual exhaust passages 6, 6,... Corresponding to the upper surface of the cover plate 1a are inclined down slopes from the outer end side of the exhaust passages 6 to the exhaust holes 3a. is there.

更に、上記に例示した蓄電池において、蓄電池が倒立した場合でも、液漏れが防止されるように下記のようにエアロック機構を具備せしめた。
即ち、該蓋本体1の該蓋板1aに、該蓋板1aを貫通し、電槽40の各セル室40b内と該上蓋20の裏面の凹面空間内に連通する該排気筒3の外周にこれを囲むように複数個の電解液の液還流孔を、図示の例では4個の液還流孔31,31,…を穿設した。
Furthermore, in the storage battery illustrated above, even when the storage battery is inverted, an air lock mechanism is provided as described below so that liquid leakage is prevented.
That is, on the outer periphery of the exhaust tube 3 that penetrates the lid plate 1a of the lid body 1 and communicates with the inside of each cell chamber 40b of the battery case 40 and the concave space on the back surface of the upper lid 20. A plurality of liquid reflux holes for the electrolytic solution, and four liquid reflux holes 31, 31,...

更に、該蓋本体1の各排気通路6a内に、該排気筒3の上部筒体3Aの外周に、図1、図4に明示のように、環状空間S1を存して、該蓋板1aの上面から突出して環状隔壁33aを設けると共に、該環状隔壁33aの一部に、上方に開口する切欠口34を該環状空間S1とその外側の内側通路6a1と連通せしめるようにした。 Further, in the exhaust passage 6a of the lid body 1, the outer circumference of the upper cylinder 3A of the exhaust cylinder 3, Fig. 1, as clearly shown in FIG. 4, and presence of the annular space S 1, the lid plate It protrudes from the upper surface of the 1a provided with an annular partition wall 33a, a portion of the annular partition wall 33a, and a notch port 34 opening upward as allowed to communicate with the inner passage 6a1 of the outer annular space S 1.

一方、該上蓋20には、図2に示すように、その裏面の夫々独立した排気用通路6b,6b,…内に、該蓋本体1に配設した上記の夫々の環状隔壁33a,33a,…に対向する位置に、各該環状隔壁33aと同じ大きさ、形状の環状隔壁33b,33b,…を該上蓋20の裏面から突設した。   On the other hand, as shown in FIG. 2, the upper lid 20 is provided with the respective annular partition walls 33a, 33a, 33a, 33a, etc. disposed in the lid body 1 in independent exhaust passages 6b, 6b,. Are projected from the back surface of the upper lid 20 at positions opposite to the annular partition walls 33a. The annular partition walls 33b, 33b,.

尚、該蓋本体1の四周囲枠2の長辺側枠2aから内側へ延びて配設した夫々の隔壁9a,9a,…は、その夫々の内端が対応する夫々の該環状隔壁33a,33a,…の外周側面に合体するものに形成する一方、該上蓋20の裏面にも同様に、その四周側壁20bの長辺側壁20b1から内側に延びて配設した夫々の隔壁9b,9b,…は、その夫々の内端が対応する夫々の該環状隔壁33b,33b,…の外周側面に合体するものに形成する。
かくして、各排気通路6aの各小室に形成された内側通路6a1は、該環状隔壁33aをめぐる迂回通路に形成される。而して、図1、図5に明示のように、夫々の環状隔壁33a,33a,…の該切欠口34,34,…を該長辺側壁2a,2a,…に向けて配設したときは、該排気筒3から排出されるガスは、その長辺側壁2a,2aに衝突後、夫々の環状隔壁33a,33a,…の周側壁に沿い迂回した後、夫々の外側通路6a2,6a2,…に進入するようになるので、ミストの捕集性能を更に向上せしめることができるようにした。
Each of the partition walls 9a, 9a,... Disposed inwardly extending from the long side frame 2a of the four peripheral frame 2 of the lid body 1 has an annular partition 33a, each corresponding to its inner end. 33a,... Are formed so as to be combined with the outer peripheral side surfaces of the upper lid 20, and the partition walls 9b, 9b,. Are formed so as to be combined with the outer peripheral side surfaces of the corresponding annular partition walls 33b, 33b,.
Thus, the inner passages 6a1 formed in the small chambers of the exhaust passages 6a are formed as bypass passages around the annular partition wall 33a. 1 and FIG. 5, when the notches 34, 34,... Of the respective annular partition walls 33a, 33a,... Are arranged toward the long side walls 2a, 2a,. The gas discharged from the exhaust cylinder 3 collides with the long side walls 2a, 2a and then detours along the peripheral side walls of the respective annular partition walls 33a, 33a,. Since it enters into ..., the mist collection performance can be further improved.

かくして、該蓋本体1の上面に該上蓋20を気密に施したとき、図6に示すように、該上蓋2の裏面から下垂する該環状隔壁33bの下端は、該蓋本体1の上面から上方に延びる該環状隔壁33aの上端に当接し、相互に融着、接着などにより結着するが、この当接状態において、該上蓋20の蓋板20aとその裏面から下垂する環状隔壁33bとで形成される断面コ字状のコップ状被覆部35で、該排気筒3の上方に空隙S2を存してコップ空間S3とその下方に環状空間S1を存した状態で、これら排気筒の上部を被覆するようにした。
また、該蓋本体1の蓋板1aから上面に突設した環状隔壁33aの高さ、従って、該環状隔壁33aに上端を開口して切り欠いた矩形状などの切欠口34の上面開口端34aの高さは、該排気筒3の該排気孔3aの上端の傾斜開口面3a11の下端と同じ高さ或いはそれより低い位置に設定することが好ましい。尚又、該排気筒3の下端の開口面3a21は水平開口面としてもよいが、傾斜面とすることが好ましい。このようにして、蓄電池にエアロック機構を具備せしめた。
Thus, when the upper lid 20 is airtightly applied to the upper surface of the lid body 1, the lower end of the annular partition wall 33b depending from the back surface of the upper lid 2 is located above the upper surface of the lid body 1 as shown in FIG. The upper end of the annular partition wall 33a extending to the upper end of the upper lid 20 is bonded to the upper end of the annular partition wall 33a by fusion, adhesion, or the like. With the cup-shaped covering portion 35 having a U-shaped cross section, a gap S 2 exists above the exhaust tube 3, and a cup space S 3 and an annular space S 1 exist below the cup space S 3 . The upper part was covered.
Further, the height of the annular partition wall 33a projecting on the upper surface from the lid plate 1a of the lid body 1, and accordingly, the upper surface opening end 34a of the notch 34 such as a rectangular shape with the upper end opened to the annular partition wall 33a. This height is preferably set at the same height as the lower end of the inclined opening surface 3a11 at the upper end of the exhaust hole 3a of the exhaust tube 3 or at a position lower than that. The opening surface 3a21 at the lower end of the exhaust tube 3 may be a horizontal opening surface, but is preferably an inclined surface. In this way, the storage battery was provided with an air lock mechanism.

上記のように構成の該蓄電池は、通常の正立状態においては、各セル室40b内に発生するミストを含んだガスは、該排気筒3及びその外周の液還流孔31,31,…から該排気筒3のコップ状被覆部35内の空間に排出され、更にその切欠口34を介し排気通路6a、即ち、内側通路6a1及び外側通路6a2に導かれ、ガスフィルター21を介し、該ガス排出口23から外部へ一括排気される。その間に、排気通路6aで捕捉された電解液は、該切欠口34を介し、該排気筒3外周の液還流孔31,31,…からセル室40b内に流下し戻る。この場合、前記の該排気筒3の中間部3Cの外周面を下向きの傾斜面に形成し、該切欠口34の下方の内側通路6a1とこれから直角に下垂する筒体32との角部を図5に示すような傾斜面34bに形成するときは、該液還流を円滑迅速に行うことができる。   In the storage battery configured as described above, in a normal upright state, the gas containing mist generated in each cell chamber 40b is discharged from the exhaust tube 3 and the liquid reflux holes 31, 31,. The gas is discharged into the space in the cup-shaped covering portion 35 of the exhaust cylinder 3 and further led to the exhaust passage 6a, that is, the inner passage 6a1 and the outer passage 6a2 through the notch 34, and the gas exhaust is passed through the gas filter 21. The exhaust gas is exhausted from the outlet 23 to the outside. Meanwhile, the electrolytic solution captured in the exhaust passage 6a flows down into the cell chamber 40b from the liquid reflux holes 31, 31,... In this case, the outer peripheral surface of the intermediate portion 3C of the exhaust cylinder 3 is formed as a downward inclined surface, and the corners of the inner passage 6a1 below the notch 34 and the cylindrical body 32 that hangs at right angles from this are shown. When formed on the inclined surface 34b as shown in FIG. 5, the liquid reflux can be performed smoothly and rapidly.

上記のエアロック機構を備えた蓄電池が横倒しや逆さになったときは、図示しないが、各セル室40b内の電解液は、上下反転した該排気筒3及びその外周の液還流孔31,31,…による気液置換により、電解液は、当初は小室内の排気通路6a1内へ流出するも、直ちに、その流出した電解液はコップ空間S3内に溜まり、やがて、該排気筒3の排気孔3aの上端開口部3a11を閉塞する。すると、排気筒3及びその外周の液還流孔31,31,…を介しての気液置換が行われず、所謂エアロックを生じ、これにより、これ以上の電解液の流出がない液漏れ防止効果をもたらす。 When the storage battery equipped with the air lock mechanism is laid down or inverted, the electrolyte in each cell chamber 40b is not shown in the figure, and the exhaust tube 3 that is turned upside down and the liquid reflux holes 31 and 31 on the outer periphery thereof are arranged. , by ... the gas-liquid replacement with, the electrolyte, also initially flows out to the small room in the exhaust passage 6a1, immediately, the leaked electrolyte reservoir in the cup space S 3, before long, the exhaust of the exhaust cylinder 3 The upper end opening 3a11 of the hole 3a is closed. Then, the gas-liquid replacement is not performed through the exhaust tube 3 and the liquid reflux holes 31, 31,... On the outer periphery thereof, so-called air lock is generated, thereby preventing the leakage of the electrolyte without any further outflow of the electrolyte. Bring.

尚、図示の蓄電池の実施例では、該排気筒3の該排気孔3aは、図示のように、該排気通路6aに開口する上部筒体3Aの孔の径をセル室40b側に開口する下部筒体3Bの孔径より著しく小径とすることにより、蓄電池の横倒しや倒立時におけるセル室からの電解液の漏出を困難にする効果をもたらす。
また、該排気筒3の小径の上部筒体3Aの上端開口面3a11と大径の下部筒体3Bの下端開口面3a21を夫々傾斜開口面に形成することにより、該上端開口面及び該下端面に液膜形成が防止できるので、蓄電池の正立状態における排気及び横倒しや倒立状態から成立状態に戻したときの液還流が支障なく円滑に行うことができる。
また、該上部筒体3Aと該下部筒体3Bの中間部3Cの外周面、図5に明示のように、下向きの傾斜面に形成することにより、電解液の流下を促進することができる。
図面で、前記の筒体32は、図4及び図6に示すように、前記の該排気筒3と液還流孔31,31,…を囲繞し、且つ該蓋本体1の蓋板1aからセル室40b内に下垂する筒体に形成することにより防沫効果をもたらす。尚、該下垂筒体32の一部には、下端に開口する切欠口32aを設けてもよい。
In the embodiment of the storage battery shown in the figure, the exhaust hole 3a of the exhaust cylinder 3 is, as shown in the drawing, the diameter of the hole of the upper cylindrical body 3A that opens to the exhaust passage 6a. By making the diameter significantly smaller than the hole diameter of the cylindrical body 3B, an effect of making it difficult to leak the electrolytic solution from the cell chamber when the storage battery is laid down or inverted is brought about.
Further, the upper end opening surface 3a11 of the small-diameter upper cylindrical body 3A and the lower end opening surface 3a21 of the large-diameter lower cylindrical body 3B are formed as inclined opening surfaces, respectively, so that the upper end opening surface and the lower end surface are formed. In addition, since the formation of a liquid film can be prevented, the exhaust of the storage battery in the upright state and the liquid recirculation when the storage battery is returned from the sideways or inverted state to the established state can be smoothly performed.
Further, the outer peripheral surface of the intermediate portion 3C of the upper cylindrical body 3A and the lower part cylinder 3B, as best seen in FIG. 5, by forming the downwardly inclined surface, it is possible to facilitate the stream of electrolyte .
As shown in FIGS. 4 and 6, the cylinder 32 surrounds the exhaust cylinder 3 and the liquid reflux holes 31, 31,... And the cell from the lid plate 1a of the lid body 1 By forming a cylindrical body that hangs down into the chamber 40b, a splash-proof effect is brought about. A part of the drooping cylinder 32 may be provided with a notch 32a that opens at the lower end.

この状態から、該蓄電池を元の正立状態に戻すと、コップ空間S3内の電解液の自重により各セル室40b内へ該液還流孔31,31,…を介し流下し、セル室40b内に戻るが、本発明によれば、該排気筒3の下部筒体3Bの周側壁を、該電解液還流孔31の位置から下端までの高さHを有し、且つ切欠きや透孔などから成る貫通孔のい周側壁に形成したことにより、電解液還流孔31,31,…の下方において、電解液が下方へ還流する圧力に、前記の高さHに相当する空気柱の圧力がガス排気筒下端に加わり、空気を押し上げる圧力が強くなるので、空気と電解液との気液置換がより円滑迅速に行われ、セル室40b内への液還流速度が速くなり、従って、液還流時間が電解液の自重のみによる液還流時間に比し、著しく短縮する効果をもたらす。 In this state, when returned to the upright position of the basis of the storage battery, the liquid reflux hole 31, 31 to each cell chamber 40b by the weight of the electrolyte in the cup space S 3, ... it flows down through the cell chamber 40b returning within, according to the present invention, the peripheral side wall of the lower cylindrical body 3B of the exhaust cylinder 3 has a height H to the lower end from the position of the electrolytic solution reflux hole 31, and notch Kiya hole by forming the not name the peripheral side wall of the through hole and the like, electrolytic Ekikae Nagareana 31, in ... lower, the pressure electrolytic solution refluxed downward air column corresponding to the height H pressure is applied to the lower end of the gas exhaust pipe, the pressure pushing up the air becomes strong, gas-liquid replacement between the air and the electrolytic solution is performed more smoothly quickly, the liquid reflux rate to the cell chamber 40b becomes faster, Therefore, the liquid reflux time is significantly shortened compared to the liquid reflux time due to the weight of the electrolyte alone.

次に、比較試験例を示す。
図示の実施形態に示す本発明の蓄電池と、比較のため、本発明の該蓄電池の該排気筒3の下部筒体3Bに、特許文献1の蓄電池に倣い、その周側壁の下端から該電解液還流孔31の近傍まで達する長矩形状の切欠きから成る貫通孔を形成して作製した従来型の蓄電池とを用意し、その両蓄電池を倒立させ、その倒立状態に30分放置した後、正立状態に戻し、その時点から該上蓋の凹部空間に溜まっている電解液がセル室に還流して空となるまでの時間を測ったところ、従来型の蓄電池では30秒かかったが、本発明の蓄電池では10秒と3分の1に短縮することができた。
Next, comparative test examples are shown.
For comparison with the storage battery of the present invention shown in the illustrated embodiment, the lower cylindrical body 3B of the exhaust cylinder 3 of the storage battery of the present invention is modeled on the storage battery of Patent Document 1, and the electrolyte solution from the lower end of its peripheral side wall Prepare a conventional storage battery made by forming a through-hole consisting of a long rectangular notch that reaches the vicinity of the reflux hole 31, invert both storage batteries, leave them in the inverted state for 30 minutes, and then erect It was returned to the state, and when the time from the time when the electrolyte accumulated in the concave space of the upper lid was circulated back to the cell chamber and emptied was measured, it took 30 seconds with the conventional storage battery. The storage battery could be shortened to 10 seconds and 1/3.

上記から明らかなように、該排気筒3の下部筒体3Bの周側壁高さHを有し、且つ切欠きや透孔などから成る貫通孔のない周側壁に形成したので、その内部に高さHに相当する空気柱Hを生ぜしめることができるので、蓄電池を正立状態に戻したときのセル室内への液還流時間を短縮することができるようにし、上記従来の課題を解消したものである As apparent from the above, it has a height H of the peripheral side wall of the lower cylinder 3B of the exhaust cylinder 3, so and was formed without peripheral side wall of the through hole made of a cut-out Kitani holes, therein to the height H can Rukoto caused the corresponding air column H in, to be able to reduce the liquid reflux time to the cell interior upon reconstitution a storage battery erected state, the above problems It has been solved .

本発明の蓄電池の実施の1例の蓋本体の平面図。The top view of the lid body of one example of implementation of the storage battery of this invention. 同蓋本体の上面に施される上蓋の裏面図。The back view of the upper cover given to the upper surface of the cover main body. 電槽の上面に該蓋本体と該上蓋とを順次施して組み立てた蓄電池の該上蓋の一部を截除した上面図。The upper side figure which removed a part of this upper cover of the storage battery assembled by sequentially applying the lid body and the upper cover to the upper surface of the battery case. 図3のIV-IV線裁断面図。Fig. 4 is a sectional view taken along line IV-IV in Fig. 3. 図3のV-V線拡大縦断面図。FIG. 5 is an enlarged vertical sectional view taken along line V-V in FIG. 3. 図5の該上蓋を除去した上面図。FIG. 6 is a top view with the upper lid of FIG. 5 removed.

1 蓋本体
1a 蓋板
3 排気筒
3A 上部筒体
3B 下部筒体
3a 排気孔
20 上蓋
23 ガス排気口
31 電解液還流孔
33a 環状隔壁
33b 環状隔壁
34 切欠口
35 コップ状被覆部
S1 環状空間
S2 空隙
S3 コップ状空
3a11 上端開口
3a21 下端開口
H 下部筒体の周側壁の高さ
1 Lid body
1a Cover plate
3 Exhaust pipe
3A upper cylinder
3B lower cylinder
3a Exhaust hole
20 Upper lid
23 Gas exhaust port
31 Electrolyte reflux hole
33a Annular bulkhead
33b Annular bulkhead
34 Notch
35 Cup cover
S 1 annular space
S 2 gap
S 3 cup-shaped sky between
3 a1 1 Upper end opening surface
3a2 1 lower opening surface
H Height of the peripheral side wall of the lower cylinder

Claims (2)

内部を仕切壁により区画された複数のセル室を有する電槽の上面に、蓋板を貫通して形成したその夫々のセル室に連通する夫々の排気筒と相隣る排気筒間を隔離し且つ囲繞する囲繞隔壁により夫々独立した排気通路を形成した蓋本体を気密に施し、該蓋本体の上面に、該蓋本体の夫々の独立した排気通路に対応して夫々独立した排気通路を裏面に設けた上蓋を気密に施して成る二重蓋構造から成ると共に、少なくとも1つのガスフィルターを介し排気せしめるガス排出口を具備し、更に、各セル室内の電解液が外部へ漏れ出ることを防止するエアロック機構を具備した蓄電池において、各排気筒の外周の前記蓋板に複数個の電解液環流孔を穿設し、更に該排気筒の該蓋板の裏面より下方に延びる下部筒体の周側壁該電解液還流孔の位置から下端までの高さHを有し、且つ透孔や切欠きなどから成る貫通孔のない周側壁に形成することにより、該周側壁の内部に前記の高さHに相当する空気柱の圧力を生ぜしめるようにしたことを特徴とする蓄電池。 On the upper surface of the battery case having a plurality of cell chambers, the interior of which is partitioned by a partition wall, the respective exhaust tubes communicating with the respective cell chambers formed through the cover plate are isolated from each other. In addition, a lid body in which an independent exhaust passage is formed by surrounding wall partitions is airtightly provided, and an independent exhaust passage corresponding to each independent exhaust passage of the lid body is provided on the back surface of the lid body. An air lock that has a double lid structure that is airtightly applied to the upper lid, has a gas exhaust port that exhausts air through at least one gas filter, and prevents the electrolyte in each cell chamber from leaking outside in the storage battery provided with the mechanism, the peripheral side wall of the exhaust pipe a plurality of electrolyte recirculation hole in the cover plate of the outer periphery of the bored and further extends downward from the rear surface of the lid plate of the stack the lower cylinder From the position of the electrolyte reflux hole. By forming it on a peripheral side wall having a height H to the end and having no through hole made of a through hole or a notch , the pressure of the air column corresponding to the height H is set inside the peripheral side wall. storage battery, characterized in that it was set to give rise. 前記排気筒は、そのガス排出側の上端の開口面傾斜開口面に形成すると共に、そのガス流入側の下端の開口面を傾斜開口面に形成したことを特徴とする請求項1に記載の蓄電池。 The chimney is configured to form an opening surface of the upper end of the gas discharge side of the inclined opening surface, according to claim 1, characterized in that the formation of the opening surface of the lower end of the gas inlet side to the inclined opening surface Storage battery.
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US10319969B2 (en) 2015-03-30 2019-06-11 Gs Yuasa International Ltd. Lead-acid battery and method of manufacturing lid member of lead-acid battery

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JP5348951B2 (en) * 2008-06-30 2013-11-20 古河電池株式会社 Storage battery exhaust structure with double lid
WO2019097575A1 (en) * 2017-11-14 2019-05-23 日立化成株式会社 Lead storage battery
JP7210924B2 (en) * 2018-07-27 2023-01-24 株式会社Gsユアサ lead acid battery

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US10135048B2 (en) 2015-02-27 2018-11-20 GS Yuasa Internationl Ltd. Lead-acid battery
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