JP4515960B2 - Hairdressing detergent and method for using the same - Google Patents

Description

  The present invention relates to a hair styling detergent and a method for using the same.

A hairdressing agent is a product used to condition hairstyles or to maintain a set hairstyle and to moisturize hair. Examples of hair styling materials include hair foams, hair sprays, gels, set lotions, and the like that form hair with a resin film, and hair waxes, hair sticks, pomades, hair creams, and the like mainly composed of solid or pasty oils and fats.
In the state where these hair styling materials (particularly oil-based hair styling materials) are applied, the foaming of the shampoo is poor and the satisfaction of “washing hair” cannot be obtained. In addition, if the hair styling material remains even after shampooing, the finish after drying becomes poor. For this reason, when a hairdressing material is applied, it is necessary to wash the hair multiple times.

However, repeated washing with shampoo not only degreases the scalp and hair more than necessary and causes rough hands, but also is inconvenient for individuals and hair salons.
Under these circumstances, there has been a need for a cleaning agent that can easily remove the hair styling before washing with a shampoo, but it has not existed so far.
The present invention has been made in view of the above-described problems, and an object of the present invention is to provide a hair styling detergent that is used before normal shampooing and has a high cleaning effect on the hair styling and a method for using the same.

In view of the above circumstances, as a result of intensive studies by the present inventors, hair styling capable of effectively washing hair styling by combining a compound having an IOB of 0.66 to 1.5 and an amphoteric surfactant. The present inventors have found that a cleaning agent can be obtained and have completed the present invention.
Specifically, a first subject of the present invention, (A) Ri IOB is 0.66 to 1.5 der in the organic conceptual diagram, random-type alkylene oxide derivative represented by the following general formula (I) and diethoxy succinate A compound that is one or more selected from ethyl ; (B) an amphoteric surfactant that is one or more selected from the group consisting of alkylbetaines and amidopropylbetaines; and a cationic polymer; , And a ratio of the amount of (B) to (A) is (B) / (A) = 0.03 to 1.0, and is a hair styling detergent, which is used before shampooing A hair styling detergent characterized by being a pre-shampoo for hair rinsing, or a hair styling detergent characterized by being applied to dry hair with a hair styling applied and then washed with water. .

( Chemical formula 1)
_{^{R 1 O - [(AO)}} m (EO) n] -R 2 (I)
(In the formula, AO is an oxyalkylene group having 3 to 4 carbon atoms, EO is an oxyethylene group, m and n are average addition moles of the oxyalkylene group and oxyethylene group, respectively, 1 ≦ m ≦ 70, 1 ≦ n ≦ 70 The ratio of the oxyethylene group to the total of the oxyalkylene group having 3 to 4 carbon atoms and the oxyethylene group is 20 to 80% by mass, and the oxyalkylene group and oxyethylene group having 3 to 4 carbon atoms are R ¹ and R ^{2, which} may be the same or different, are hydrocarbon groups or hydrogen atoms having 1 to 4 carbon atoms, and the number of hydrogen atoms relative to the number of hydrocarbon groups of R ¹ and R ² The ratio is 0.15 or less.)

The second subject of the present invention, the hair hair dressing is applied, the hair cleanser was applied in a state where the hair had dry, washed with water, the hair cleanser characterized by shampooing How to use.
As a specific method of use, it is preferable to fill a tisspencer container with a trigger with a hairdressing detergent and spray the hair.
Alternatively, it is preferable to fill the hair former cleaning agent into a pump former container and apply it to the hair in the form of foam.

  The hair styling detergent of the present invention has a high hair styling cleaning effect by combining a compound having an IOB of 0.66 to 1.5 and an amphoteric surfactant.

Hereinafter, preferred embodiments of the present invention will be described.
The hair styling detergent of the present invention is characterized by containing a compound having an IOB of 0.66 to 1.5 in an organic conceptual diagram and an amphoteric surfactant.
(A) Compound whose IOB is 0.66 to 1.5 in the organic conceptual diagram The organic conceptual diagram was proposed by Satoshi Fujita.
Bulletin ", vol.2, 2, pp.163-173 (1954)," Chemistry "vol.11,10, pp.719-725 (1957)," Fragrance Journal ", vol.50, pp.79 -82 (1981), “Organic Conceptual Diagram: Basics and Applications” (by Yoshio Koda, Sankyo Publishing, 1984).
That is, all the organic compounds are regarded as derivatives of methane (CH ₄ ), and certain numbers are set for the carbon number, substituent, transformation part, ring, etc., and the numbers are added to obtain an organic value or an inorganic value. The property value is obtained and plotted on a diagram with the organic value on the X axis and the inorganic value on the Y axis.
The IOB in the organic conceptual diagram means the ratio of the inorganic value (IV) to the organic value (OV) in the organic conceptual diagram, that is, “inorganic value (IV) / organic value (OV)”.

In the present invention, the “compound having an IOB of 0.66 to 1.5 in the organic conceptual diagram” is selected from random alkylene oxide derivatives represented by the following general formula (I) and diethoxyethyl succinate: It is a seed or two or more kinds .
(Chemical formula 2)
_{^{R 1 O - [(AO)}} m (EO) n] -R 2 (I)
(In the formula, AO is an oxyalkylene group having 3 to 4 carbon atoms, EO is an oxyethylene group, m and n are average addition moles of the oxyalkylene group and oxyethylene group, respectively, 1 ≦ m ≦ 70, 1 ≦ n ≦ 70 The ratio of the oxyethylene group to the total of the oxyalkylene group having 3 to 4 carbon atoms and the oxyethylene group is 20 to 80% by mass, and the oxyalkylene group and oxyethylene group having 3 to 4 carbon atoms are R ¹ and R ^{2, which} may be the same or different, are hydrocarbon groups or hydrogen atoms having 1 to 4 carbon atoms, and the number of hydrogen atoms relative to the number of hydrocarbon groups of R ¹ and R ² The ratio is 0.15 or less.)

In the general formula (I), AO is an oxyalkylene group having 3 to 4 carbon atoms, and specifically includes an oxypropylene group, an oxybutylene group, an oxyisobutylene group, an oxytrimethylene group, an oxytetramethylene group, and the like. Can be mentioned. Preferably, an oxypropylene group and an oxybutylene group are mentioned.
m is the average number of added moles of an oxyalkylene group having 3 to 4 carbon atoms, and 1 ≦ m ≦ 70, preferably 2 ≦ m ≦ 41. n is the average number of added moles of oxyethylene groups, and 1 ≦ n ≦ 70, preferably 14 ≦ n ≦ 55. When the oxyalkylene group or oxyethylene group having 3 to 4 carbon atoms is 0, the smoothness is lowered, and when it exceeds 70, a sticky feeling tends to appear.

Moreover, in the said general formula (I), it is preferable that the ratio of the oxyethylene group with respect to the sum total of a C3-C4 oxyalkylene group and an oxyethylene group is 20-80 mass%. When the proportion of the oxyethylene group is less than 20% by mass, it tends to be inferior in smoothness, and when it exceeds 80% by mass, it tends to cause stickiness after use.
The order in which the oxyethylene group and the oxyalkylene group having 3 to 4 carbon atoms are added is not particularly specified, and is added randomly. Random ones are superior in use feeling compared to block ones.

R ¹ and R ² are each a hydrocarbon group having 1 to 4 carbon atoms or a hydrogen atom, and examples of the hydrocarbon group include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, a sec-butyl group, Examples thereof include a tert-butyl group. A methyl group and an ethyl group are preferred. Hydrocarbon groups having 5 or more carbon atoms are less hydrophilic and less moist. R ¹ and R ² may be the same or different.
R ¹ and R ² may be the same type, or a hydrogen atom and a hydrocarbon group having 1 to 4 carbon atoms may be mixed, or different hydrocarbon groups having 1 to 4 carbon atoms may be mixed. Good. However, in R ¹ and R ² , the proportion of hydrocarbon groups and hydrogen atoms is such that the ratio Y / X of the number of hydrogen atoms (Y) to the number of hydrocarbon groups (X) is 0.15 or less, preferably 0 0.06 or less. When the ratio of Y / X exceeds 0.15, a sticky feeling comes out.

Specific examples of the random alkylene oxide derivative represented by the above formula (I) include POE (14) POP (7) dimethyl ether (IOB 1.19), POE (36) POP (41) dimethyl ether (IOB 0.90), POE ( 55) POP (28) dimethyl ether (IOB 1.20), POE (36) POP (41) dimethyl ether (IOB 0.90) and the like.
The POE and POP are abbreviations for polyoxyethylene and polyoxypropylene, respectively, and may be abbreviated as follows.

The random alkylene oxide derivative of the present invention can be produced by a known method. For example, it can be obtained by subjecting a compound having a hydroxyl group to addition polymerization of ethylene oxide and an alkylene oxide having 3 to 4 carbon atoms, and then subjecting an alkyl halide to an ether reaction in the presence of an alkali catalyst. Hereinafter, synthesis examples of random alkylene oxide derivatives will be described.
(Synthesis example)
POE (10) POP (10) Dimethyl ether (Random type)
CH ₃ O [(EO) ₁₀ / (PO) ₁₀ ] CH ₃
76 g of propylene glycol and 3.1 g of potassium hydroxide as a catalyst were charged into an autoclave. After the air in the autoclave was replaced with dry nitrogen, the catalyst was completely dissolved at 140 ° C. with stirring. Next, a mixture of 440 g of ethylene oxide and 522 g of propylene oxide was dropped with a dropping device and stirred for 2 hours.
Next, 224 g of potassium hydroxide was charged and the inside of the system was replaced with dry nitrogen, and then 188 g of methyl chloride was injected at a temperature of 80 to 130 ° C. and reacted for 5 hours. Thereafter, the reaction composition was taken out from the autoclave, neutralized with hydrochloric acid to pH 6 to 7, and treated at a reduced pressure of -0.095 MPa (50 mmHg) at 100 ° C for 1 hour in order to remove the contained water. Further, filtration was performed to remove the salt generated after the treatment, and the random alkylene oxide derivative was obtained.

  As a compounding quantity of the compound whose IOB in an organic conceptual diagram is 0.66-1.5, it is desirable that it is 1.0-20 mass% in total. If it is less than 1.0% by mass, the effect of the present invention is not sufficient, and if it is 20% by mass or more, the usability may be deteriorated.

(B) Amphoteric surfactant Examples of the amphoteric surfactant include alkylbetaine-type amphoteric surfactants, amide betaine-type amphoteric surfactants, imidazolinium betaine-type amphoteric surfactants, and sulfobetaine-type amphoteric surfactants. It is done.
In the present invention, the amphoteric surfactant is one or more selected from the group consisting of alkylbetaines represented by the following general formula (II) and amidopropyl betaines represented by the following general formula (III). It is .

（式中、Ｒ^３は炭素原子数１０〜２０のアルキル基、Ｒ^４及びＲ^５は炭素原子数１〜３のアルキル基、Ｍはアルカリ金属原子である。） (Chemical formula 3)

(In the formula, R ³ is an alkyl group having 10 to 20 carbon atoms, R ⁴ and R ⁵ are alkyl groups having 1 to 3 carbon atoms, and M is an alkali metal atom.)

(A) IOB is the amount ratio of (B) an amphoteric surfactant to the compound is from 0.66 to 1.5, from the viewpoint of detergency and the like, it is from 0.03 to 1.0. Moreover, it is desirable that the amount of amphoteric surfactant is 0.1 to 5.0% by mass.

The hair styling detergent of the present invention preferably further contains a cationic polymer.
Here, the cationic polymer refers to a polymer having a cationic group or a group that can be ionized into a cationic group, and includes an amphoteric polymer that becomes cationic as a whole.
Cationic polymers include cationic cellulose derivatives, cationic starch, cationized guar gum derivatives, poly (dimethyldiallylammonium halide) type cationic polymers, dimethyldiallylammonium halide / acrylamide copolymer type cationic polymers; polyethylene glycol, Cationic polymer which is a condensation product type of taroylamine obtained from epichlorohydrin, propyleneamine and beef tallow fatty acid; Cationic polymer which is a condensation product type of cocoylamine obtained from polyethylene glycol, epichlorohydrin, propyleneamine and coconut oil fatty acid; vinyl Pyrrolidone / dimethylaminoethyl methacrylate copolymer type cationic polymer; quaternary nitrogen-containing cellulose ether type cationic polymer Rimmer, and the like.
The cationic polymers used in the present invention are hydroxypropyltrimonium chloride starch (ie O- [2-hydroxy-3- (trimethylammonio) propyl] starch), cationized hydroxyethylcellulose-2, polyquaternium-39 (ie It is preferable that it is 1 type (s) or 2 or more types selected from the polydimethylnium-7 (namely, acrylic acid / acrylic acid amide / dimethyldiallylammonium chloride copolymer).

The cationic polymer demonstrates the effect of preventing squeakiness, stickiness, and entanglement at the stage where the hair is wet from the time of rinsing the hairdressing detergent to the time of drying the hair through shampoo treatment, etc. It also contributes to the effect of giving gloss, softness, smoothness, moist feeling and ease of uniting to the hair.
As a compounding quantity of a cationic polymer, 0.1-1.0 mass% is desirable. If it is less than 0.1% by mass, the effect of addition is not sufficient, and if it is added in an amount of 1.0% by mass or more, the viscosity of the liquid becomes so high that it becomes difficult to use.

A sequestering agent can also be added to the hair styling detergent of the present invention in order to increase the viscosity of the liquid or to further improve the finished feeling. Examples of sequestering agents include hydroxyethane diphosphonic acids such as 1-hydroxyethane-1,1-diphosphonic acid and 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt; disodium edetate, trisedoate Edetic acids such as sodium and tetrasodium edetate; N-acylethylenediaminetriacetate such as lauroylethylenediaminetriacetate, trisodium ethylenediaminehydroxyethyltriacetate, sodium polyphosphate, sodium metaphosphate, gluconic acid, phosphoric acid, citric acid Sodium citrate, ascorbic acid, succinic acid and the like are preferably used, and one or two or more can be used in combination. In particular, it is preferable to adjust the pH to about 6 to 8 by a combination of citric acid / triethanolamine or the like because product stability can be kept good.
As a compounding quantity of a sequestering agent, 0.1-3.0 mass% is desirable. If it is less than 0.1% by mass, the effect of addition is not sufficient, and if it is 3.0% by mass or more, the finished feeling may be inferior.

The hair styling detergent of the present invention is produced according to a conventional method by appropriately blending components used in normal cosmetics and quasi drugs in addition to the above essential components.
Using hairdressing preparation cleanser of the present invention, the hair dressing is attached hair, after application in a state that had dry before shampooing, a method of washing with water. Can also be used in wet, the advance takes time to wet hair and, from the viewpoint of effect, it is preferably used in a state where the hair had dry.

As a usage form, for example, it can be used by filling a tisspencer container with a trigger and spraying an appropriate amount onto the hair, or it can be used in the form of foam in a pump former container, but is not limited thereto.
After using the hair styling detergent of the present invention, it is preferable to wash the hair with a normal shampoo. Since the hair styling agent is dropped in advance with the present hair styling detergent, the hair washing with the shampoo does not require a plurality of times, and the foaming property of the shampoo is improved.
After shampooing, it is preferable to use a rinse, treatment, hair conditioner or the like. By using the hair styling detergent in advance, the finished feeling is improved.

The hair styling detergent of the present invention is used by being applied to dry hair, and has an excellent cleaning effect for hair styling that is difficult to remove with conventional shampoos.
In the hair styling detergent of the present invention, the hair styling agent has a function of pulling the hair styling away from the hair by a combination of a compound having an IOB of 0.66 to 1.5 and an amphoteric surfactant in the organic conceptual diagram. Since it has a function of preventing re-adhesion during rinsing, it exhibits an excellent cleaning effect.
The present invention will be described in more detail with reference to the following examples, but the present invention is not limited thereto. Unless otherwise specified, the blending amount is expressed in mass% with respect to the system in which the component is blended.

The evaluation method and evaluation criteria used in the present invention will be described.
Evaluation (1) Stability (Appearance)
Immediately after manufacture, evaluated by appearance over time (after one month at room temperature) ○: No change (pass)
Δ: Cloudy (failed)
×: Precipitation (failed)

Evaluation (2) Cleaning rate (%)
1. Adjustment of hair bundles After washing a hair bundle of about 10 cm with a commercial shampoo, apply a commercial hair conditioner and wash it off. After air-drying in a room, leave it overnight in a constant temperature and humidity room at a temperature of 25 ° C. and a humidity of 50% and weigh precisely. Let this value be P.
2. Application of hairdressing agent Oily hairdressing agent (commercially available hair wax (PPG-40 butyl and petrolatum / beeswax)) 0.1g is uniformly applied to the hair bundle, air-dried indoors, and the above-mentioned constant temperature and humidity Leave overnight in the room and weigh accurately. Let this value be Q.
3. Washing With the hair bundle in a dry state, 1.0 g of the sample is applied (sprayed), applied by hand for 30 seconds, and then rinsed in running water at about 35 ° C. for 30 seconds. After air-drying in the room, leave it overnight in the constant temperature and humidity room and weigh precisely. Let this value be R.
Cleaning rate (%) = (R−P) / (Q−P) × 100

Evaluation (3) Smoothness at the time of rinsing The sensory evaluation is performed on the smoothness at the time of rinsing when each sample is washed.
○: Smooth ×: Not smooth

Evaluation (4) Stickiness after rinsing The stickiness after rinsing when each sample is washed is sensory evaluated.
○: No sticky feeling ×: Sticky feeling

Evaluation (5) Feeling of dryness after drying Sensory evaluation of the feeling of dryness after drying when each sample was washed.
○: No sensation ×: Sense of sensation

First, a hair shampoo was tried using a commercial shampoo (mainly sodium laureth sulfate and cocamidopropyl betaine).
The cleaning rate (%) was calculated by the above method. However, washing was performed after the hair bundle was previously wetted in running water of about 35 ° C. for 3 seconds.
In the above process, the foaming of the shampoo was poor and the washing rate was 13%. The hair bundle after the shampoo had a sticky feeling with the hair styling material remaining, resulting in a stiff finish.
When shampoo is used in this way, it is necessary to wash the hair multiple times in order to remove the hair styling agent, but this not only causes the scalp and hair to be degreased more than necessary, but also causes rough hands, as well as costs. It is not preferable also in terms.

（製法）
成分Eで成分Cを加熱溶解後、成分A及びBを加えて透明溶解確認する。その後、成分DでｐＨ７に調整する。 Therefore, using the samples of each formulation shown in Table 1 below, the dry hair bundle was washed and evaluated as follows.
(Table 1)

(Manufacturing method)
After component C is heated and dissolved with component E, components A and B are added to confirm transparent dissolution. Thereafter, the pH is adjusted to 7 with Component D.

In Test Example 1-12 in which a compound having an IOB of 0.66 to 1.5 in the organic conceptual diagram was not blended, the washing rate was low and the usability was poor.
On the other hand, also in Test Example 1-8 in which lauryl betaine or cocamidopropyl betaine, which is an amphoteric surfactant, was not blended, the washing rate was low and the usability was poor.
Moreover, in Test Examples 1-3 to 1-7 in which an anionic surfactant was blended in place of the amphoteric surfactant, it was found that precipitation occurred with time and it was not realized as a hairdressing detergent.

In contrast, in Test Examples 1-1 to 1-2 and Test Examples 1-9 to 1-11 which are hairdressing detergents of the present invention, the product stability is excellent, the cleaning rate is high, and the feeling of use is also good. there were.
In addition to the function of separating the hairdressing agent from the hair by blending (A) a compound having an IOB of 0.6 to 1.5 and (B) an amphoteric surfactant, It has a function of preventing the hair styling agent from re-adhering at the time of rinsing, and is thus considered to exhibit an excellent cleaning effect.

（製法）
成分Eで成分Cを加熱溶解後、成分A及びBを加えて透明溶解確認する。その後、成分DでｐＨ７に調整する。 Next, in order to investigate the relationship between the compounding ratio of (A) a compound having an IOB of 0.6 to 1.5 and (B) an amphoteric surfactant, the cleaning rate is shown in Table 2 below. The above evaluation was performed on the sample of the prescription.
(Table 2)

(Manufacturing method)
After component C is heated and dissolved with component E, components A and B are added to confirm transparent dissolution. Thereafter, the pH is adjusted to 7 with Component D.

From Table 2, it was found that (A) / (B) is preferably 0.03 to 1.0 from the viewpoint of detergency.
Further examination by the inventor shows that the compounding amount of the compound having an IOB of 0.66 to 1.5 in the organic conceptual diagram is preferably 1.0 to 20% by mass, and the compounding amount of the amphoteric surfactant is It was confirmed that the content is preferably 0.1 to 5.0% by mass.
In conventional shampoos, in general, the greater the amount of surfactant added, the higher the detergency. On the other hand, in the hairdressing detergent of the present invention, it was confirmed that the detergency is high when the blending amount of the amphoteric surfactant is within a certain range, and if it exceeds this, the detergency is rather lowered.
This is considered to be because the compound having an IOB of 0.66 to 1.5 in the organic conceptual diagram and the amphoteric surfactant exhibit some interaction with the detergency in the hair styling detergent of the present invention. It is done.

[Pump former type hair conditioner cleaner]
Compounding ingredients (mass%)
Dipropylene glycol 9.0
PEG / PPG-55 / 28 dimethyl ether 9.0
Cationized hydroxyethyl cellulose-2 0.3
Sodium citrate 0.2
Methylparaben 0.2
Phenoxyethanol 0.4
Lauryl betaine solution (40%) 3.0
Edetate 0.1
Fragrance 0.1
Purified water 77.7
(Manufacturing method)
Cationized hydroxyethyl cellulose-2 is dissolved in purified water. To this, methyl paraben is dissolved in dipropylene glycol and then added, and once heated to 60 ° C., transparent dissolution is confirmed. Thereafter, other blending components are added, and after transparent dissolution is confirmed, the mixture is cooled.

Claims (7)

(A) IOB in the organic conceptual diagram Ri der 0.66 to 1.5, one or more selected from a random-type alkylene oxide derivative and diethoxyethyl succinate represented by the following general formula (I) A compound that is
(B) an amphoteric surfactant that is one or more selected from the group consisting of alkylbetaines and amidopropylbetaines ;
A cationic polymer,
The blending ratio of (B) to (A) is (B) / (A) = 0.03 to 1.0,
A hair styling detergent, which is a pre-shampoo for washing hair styling used before shampooing .
(Chemical formula 1)
^{_{R 1 O - [(AO)}} m (EO) n] -R 2 (I)
(In the formula, AO is an oxyalkylene group having 3 to 4 carbon atoms, EO is an oxyethylene group, m and n are average addition moles of the oxyalkylene group and oxyethylene group, respectively, 1 ≦ m ≦ 70, 1 ≦ n ≦ 70 The ratio of the oxyethylene group to the total of the oxyalkylene group having 3 to 4 carbon atoms and the oxyethylene group is 20 to 80% by mass, and the oxyalkylene group and oxyethylene group having 3 to 4 carbon atoms are R ¹ and R ^{2, which} may be the same or different, are hydrocarbon groups or hydrogen atoms having 1 to 4 carbon atoms, and the number of hydrogen atoms relative to the number of hydrocarbon groups of R ¹ and R ² The ratio is 0.15 or less.) (A) The IOB in the organic conceptual diagram is 0.66 to 1.5 , and one or more selected from random alkylene oxide derivatives represented by the following general formula (I) and diethoxyethyl succinate A compound,
(B) an amphoteric surfactant that is one or more selected from the group consisting of alkylbetaines and amidopropylbetaines;
A cationic polymer,
The blending ratio of (B) to (A) is (B) / (A) = 0.03 to 1.0,
A hair styling detergent, wherein the hair styling composition is applied to dry hair coated with a hair styling and then washed with water.
(Chemical formula 1)
_{^{R 1 O - [(AO)}} m (EO) n] -R 2 (I)
(In the formula, AO is an oxyalkylene group having 3 to 4 carbon atoms, EO is an oxyethylene group, m and n are average addition moles of the oxyalkylene group and oxyethylene group, respectively, 1 ≦ m ≦ 70, 1 ≦ n ≦ 70 The ratio of the oxyethylene group to the total of the oxyalkylene group having 3 to 4 carbon atoms and the oxyethylene group is 20 to 80% by mass, and the oxyalkylene group and oxyethylene group having 3 to 4 carbon atoms are R ¹ and R ^{2, which} may be the same or different, are hydrocarbon groups or hydrogen atoms having 1 to 4 carbon atoms, and the number of hydrogen atoms relative to the number of hydrocarbon groups of R ¹ and R ² The ratio is 0.15 or less.) The hair styling detergent according to claim 2, wherein the hair styling detergent is a pre-shampoo for washing hair styling used before shampooing . The hair styling detergent according to any one of claims 1 to 3, which does not contain an anionic surfactant . The hair dressing is applied hair, the hair cleanser according to any one of claims 1 to 4, applied in a state where the hair had dry, washed with water, hairdressing cleanser characterized by shampooing How to use. 6. The method of using a hairdressing detergent according to claim 5 , wherein the hairdressing detergent is filled in a trigger tispenser container and sprayed onto the hair. 6. The method of using a hairdressing detergent according to claim 5 , wherein the hairdressing detergent is filled in a pump former container and foamed and applied to the hair.